A primary analysis of microwave brightness temperature of lunar surface from Chang-E 1 multi-channel radiometer observation and inversion of regolith layer thickness

In China’s first lunar exploration project, Chang-E 1 (CE-1), a multi-channel microwave radiometer was aboard the satellite, with the purpose of measuring microwave brightness temperature (Tb) from lunar surface and surveying the global distribution of lunar regolith layer thickness. In this paper, the primary 621 tracks of swath data measured by CE-1 microwave radiometer from November 2007 to February 2008 are collected and analyzed. Using the nearest neighbor interpolation to collect the Tb data under the same Sun illumination, global distributions of microwave brightness temperature from lunar surface at lunar daytime and nighttime are constructed. Based on the three-layer media modeling (the top dust-soil, regolith and underlying rock media) for microwave thermal emission of lunar surface, the CE-1 measured Tb and its dependence upon latitude, frequency and FeO + TiO₂ content, etc. are discussed. The CE-1 Tb data at Apollo landing sites are especially chosen for validation and calibration on the basis of available ground measurements. Using the empirical dependence of physical temperature upon the latitude verified by the CE-1 multi-channel Tb data at Apollo landing sites, the global distribution of regolith layer thickness is further inverted from the CE-1 brightness temperature data at 3 GHz channel. Those inversions at Apollo landing sites and the characteristics of regolith layer thickness for lunar maria are well compared with the Apollo in situ measurements and the regolith thickness derived from the Earth-based radar data. Finally, the statistical distribution of regolith thickness is analyzed and discussed.     

Computer Simulation of Sputtering of Lunar Regolith by Solar Wind Protons: Contribution to Change of Surface Composition and to Hydrogen Flux at the Lunar Poles

A computer simulation of the sputtering of lunar soil by solar wind protons was performed with the TRIM program. The rate of the sputtering-induced erosion of regolith particles was shown to be less than 0.2 Å per year. A preferential sputtering of Ca, Mg, and O was found along with a less intense sputtering of Fe, Si, and Ti. However, with no other selection mechanisms, surface concentrations of the atoms would differ from the volume ones by no more than 6 %. The enrichment of rims of regolith particles with iron occurs as a result of selective removal of lighter atoms from the lunar surface because of different energies of escape from the Moon's gravity. The energy distributions proved to be the same for all sorts of the sputtered atoms, except for implanted hydrogen; thus, a greater fraction of the atoms left on the lunar surface corresponds to heavier elements. According to simulation results, the concentration of reduced iron observed in the mature regolith could be attained during the time of regolith particle exposure to the present flux of solar wind (10⁵ years). Thus, sputtering can provide the concentration of Fe₀ observed in regolith. On periphery of a cloud of impact vapor the temperature is too low for an irreversible selective removal of evaporation products; thus, a meteoritic bombardment contributes to the formation of composition of the rims of regolith particles mainly through enrichment of the rims with elements from the bulk of the particles. The estimates of fluxes of backscattered solar wind protons and of sputtered protons, earlier implanted to the regolith, demonstrated that their contribution to the proton flux near the poles is only 10⁴ cm^–2 s^–1. This is by two orders of magnitude smaller than the proton flux from the Earth's magnetosphere which is, therefore, the main source of protons for permanently shaded polar craters of the Moon.     

Regolith history of lunar meteorites

Abstract— The regolith evolution of the lunar meteorites Dhofar (Dho) 081, Northwest Africa (NWA) 032, NWA 482, NWA 773, Sayh al Uhaymir (SaU) 169, and Yamato (Y‐) 981031 was investigated by measuring the light noble gases He, Ne, and Ar. The presence of trapped solar neon in Dho 081, NWA 773, and Y‐981031 indicates an exposure at the lunar surface. A neon three‐isotope diagram for lunar meteorites yields an average solar ²⁰Ne/²²Ne ratio of 12.48 ± 0.07 representing a mixture of solar energetic particles neon at a ratio of 11.2 and solar wind neon at a ratio of 13.8. Based on the production rate ratio of ²¹Ne and ³⁸Ar, the shielding depth in the lunar regolith of NWA 032, NWA 482, SaU 169, and Y‐981031 was obtained. The shielding depth of these samples was between 10.5 g/cm² and >500 g/cm². Based on spallogenic Kr and Xe, the shielding depth of Dho 081 was estimated to be most likely between 120 and 180 g/cm². Assuming a mean density of the lunar regolith of 1.8 g/cm³, 10.5 g/cm² corresponds to a depth of 5.8 cm and 500 g/cm² to 280 cm below the lunar surface. The range of regolith residence time observed in this study is 100 Ma up to 2070 Ma.     

Preservation potential of implanted solar wind volatiles in lunar paleoregolith deposits buried by lava flows

The lunar surface is bathed in a variety of impacting particles originating from the solar wind, solar flares, and galactic cosmic rays. These particles can become embedded in the regolith and/or produce a range of other molecules as they pass through the target material. The Moon therefore contains a record of the variability of the solar and galactic particle fluxes through time. To obtain useful temporal snapshots of these processes, discrete regolith units must be shielded from continued bombardment that would rewrite the record over time. One mechanism for achieving this preservation is the burial of a regolith deposit by a later lava flow. The archival value of such deposits sandwiched between lava layers is enhanced by the fact that both the under- and over-lying lava can be dated by radiometric techniques, thereby precisely defining the age of the regolith layer and the geologic record contained therein. The implanted volatile species would be vulnerable to outgassing by the heat of the over-lying flow, at temperatures exceeding 300-700 °C. However, the insulating properties of the finely particulate regolith would restrict significant heating to shallow depths. We have therefore modeled the heat transfer between lunar mare basalt lavas and the regolith in order to establish the range of depths below which implanted volatiles would be preserved. We find that the full suite of solar wind volatiles, consisting predominantly of H and He, would survive at depths of ∼13-290 cm (for 1-10 m thick lava flows, respectively). A substantial amount of CO, CO₂, N₂ and Xe would be preserved at depths as shallow as 3.7 cm beneath meter-thick flows. Given typical regolith accumulation rates during mare volcanism, the optimal localities for collecting viable solar wind samples would involve stacks of thin mare lava flows emplaced a few tens to a few hundred Ma apart, in order for sufficient regolith to develop between burial events. Obtaining useful archives of Solar System processes would therefore require extraction of regolith deposits buried at quite shallow depths beneath radiometrically-dated mare lava flows. These results provide a basis for possible lunar exploration activities.     

Regolith thickness over the lunar nearside: Results from Earth-based 70-cm Arecibo radar observations

The inversion of regolith thickness over the nearside hemisphere of the Moon from newly acquired Earth-based 70-cm Arecibo radar data is investigated using a quantitative radar scattering model. The radar scattering model takes into account scattering from both the lunar surface and buried rocks in the lunar regolith, and three parameters are critically important in predicting the radar backscattering coefficient: the dielectric constant of the lunar regolith, the surface roughness, and the size and abundance of subsurface rocks. The measured dielectric properties of the Apollo regolith samples at 450 MHz are re-analyzed, and an improved relation among the complex dielectric constant, bulk density and regolith composition is obtained. The complex dielectric constant of the lunar regolith is estimated globally from this relation using the regolith composition derived from Lunar Prospector gamma-ray spectrometer data. To constrain the lunar surface roughness and abundance of subsurface rocks from radar data, nine regions are selected as calibration sites where the regolith thickness has been estimated using independent analysis techniques. For these sites, scattering from the lunar surface and buried rocks cannot be perfectly distinguished, and a tradeoff relationship exists between the size and abundance of buried rocks and surface roughness. Using these tradeoff relations as guidelines for globally representative parameters, the regolith thickness of four regions over the lunar nearside is inverted, and the inversion uncertainties caused by calibration errors of the radar data and model input parameters are analyzed. The regolith thickness of the maria is generally smaller than that of highlands, and older surfaces have thicker regolith thicknesses. Our approach cannot be applied to regions where the surface roughness is very high, such as with young rocky craters and regions in the highly rugged highlands.     

Cosmic ray interactions with lunar materials: Nature and composition of species formed

The solar and galactic cosmic rays interact directly with lunar surface materials, and the dominant nature of interactions is essentially the complete absorption of corpuscles. These corpuscles damage the lattice structure, and induce a complex set of reactions in the materials producing various species. The cosmic ray damage of the lattice would not produce an amorphous layer, similar to that produced by the solar wind, because the solar wind erosion rate is faster than the cosmic ray-induced amorphous layer formation rate. The species formation rate considered in this paper are those produced by protons, the dominant component of cosmic rays. Protons produce H, H₂, OH, H₂O, and hydrogenated species of carbon, nitrogen, sulfur, etc. These species, while migrating in the material, encounter oncoming cosmic ray corpuscles, and undergo a complex set of reactions. Although a variety of species are produced by protons, the dominant contributor to the atmosphere is H₂. The H₂ flux (molecules cm^–2 sec^–1) is about 1.5 × 10⁵ as compared to the H flux of 8.4 × 10¹ and the H₂O flux of 4.6 × 10^–2. These fluxes are about 10^–3 smaller than the fluxes of the same species produced by the solar wind protons. Thus the contributions of the cosmic ray-induced species to the atmosphere is very small compared to the solar wind-induced species. Although simulated experiments showed high concentractions of OH and H₂O in the terrestrial materials of lunar type, these species concentrations in the lunar materials under the lunar environment is much smaller than those observed in the simulated experiments.     

The Monahans chondrite and halite: Argon‐39/argon‐40 age,solar gases,cosmic‐ray exposure ages,and parent body regolith neutron flux and thickness

Abstract— The Monahans H‐chondrite is a regolith breccia containing light and dark phases and the first reported presence of small grains of halite. We made detailed noble gas analyses of each of these phases. The ³⁹Ar‐⁴⁰Ar age of Monahans light is 4.533 ± 0.006 Ma. Monahans dark and halite samples show greater amounts of diffusive loss of ⁴⁰Ar and the maximum ages are 4.50 and 4.33 Ga, respectively. Monahans dark phase contains significant concentrations of He, Ne and Ar implanted by the solar wind when this material was extant in a parent body regolith. Monahans light contains no solar gases. From the cosmogenic ³He, ²¹Ne, and ³⁸Ar in Monahans light we calculate a probable cosmic‐ray, space exposure age of 6.0 ± 0.5 Ma. Monahans dark contains twice as much cosmogenic ²¹Ne and ³⁸Ar as does the light and indicates early near‐surface exposure of 13–18 Ma in a H‐chondrite regolith. The existence of fragile halite grains in H‐chondrites suggests that this regolith irradiation occurred very early. Large concentrations of ³⁶Ar in the halite were produced during regolith exposure by neutron capture on ³⁵Cl, followed by decay to ³⁶Ar. The thermal neutron fluence seen by the halite was (2–4) × 10¹⁴ n/cm². The thermal neutron flux during regolith exposure was ～0.4‐0.7 n/cm²/s. The Monahans neutron fluence is more than an order of magnitude less than that acquired during space exposure of several large meteorites and of lunar soils, but the neutron flux is lower by a factor of ≤5. Comparison of the ³⁶Ar_n/²¹Ne_cos ratio in Monahans halite and silicate with the theoretically calculated ratio as a function of shielding depth in an H‐chondrite regolith suggests that irradiation of Monahans dark occurred under low shielding in a regolith that may have been relatively shallow. Late addition of halite to the regolith can be ruled out. However, irradiation of halite and silicate for different times at different depths in an extensive regolith cannot be excluded.     

Solar wind contribution to surficial lunar water: Laboratory investigations

Remote infrared spectroscopic measurements have recently re-opened the possibility that water is present on the surface of the Moon. Analyses of infrared absorption spectra obtained by three independent space instruments have identified water and hydroxyl (-OH) absorption bands at ∼3 μm within the lunar surface. These reports are surprising since there are many mechanisms that can remove water but no clear mechanism for replenishment. One hypothesis, based on the spatial distribution of the -OH signal, is that water is formed by the interaction of the solar wind with silicates and other oxides in the lunar basalt. To test this hypothesis, we have performed a series of laboratory simulations that examine the effect of proton irradiation on two minerals: anorthite and ilmenite. Bi-directional infrared reflection absorption spectra do not show any discernable enhancement of infrared absorption in the 3 μm spectral region following 1 or 100 keV proton irradiation at fluences between 10¹⁶ and 10¹⁸ ions cm⁻². In fact, the post-irradiation spectra are characterized by a decrease in the residual O-H band within both minerals. Similarly, secondary ion mass spectrometry shows a decrease rather than an increase of the water group ions following proton bombardment of ilmenite. The absence of significant formation of either -OH or H₂O is ascribed to the preferential depletion of oxygen by sputtering during proton irradiation, which is confirmed by post-irradiation surface analysis using X-ray photoelectron spectroscopy measurements. Our results provide no evidence to support the formation of H₂O in the lunar regolith via implantation of solar wind protons as a mechanism responsible for the significant O-H absorption in recent spacecraft data. We determine an upper limit for the production of surficial -OH on the lunar surface by solar wind irradiation to be 0.5% (absorption depth).     

Constraints on the flux of meteoritic and cometary water on the Moon from volatile element (N–Ar) analyses of single lunar soil grains,Luna 24 core

We report new nitrogen and argon isotope and abundance results for single breccia clasts and agglutinates from four different sections of the Luna 24 drill core in order to re-evaluate the provenance of N trapped in lunar regolith, and to place limits on the flux of planetary material to the Moon’s surface. Single Luna 24 grains with ⁴⁰Ar/³⁶Ar ratios <1 show δ¹⁵N values between ?54.5‰ and +123.3‰ relative to terrestrial atmosphere. Thus, low-antiquity lunar soils record both positive and negative δ¹⁵N signatures, and the secular increase of the δ¹⁵N value previously postulated by Kerridge (Kerridge, J.F. [1975]. Science 188(4184), 162–164. doi:10.1126/science.188.4184.162) is no longer apparent when the Luna and Apollo data are combined. Instead, the N isotope signatures, corrected for cosmogenic ¹⁵N, are consistent with binary mixing between isotopically light solar wind (SW) N and a planetary N component with a δ¹⁵N value of +100‰ to +160‰. The lower δ¹⁵N values of Luna 24 grains compared to Apollo samples reflect a higher relative proportion of solar N, resulting from the higher SW fluence in the region of Mare Crisium compared to the central near side of the Moon. Carbonaceous chondrite-like micro-impactors match well the required isotope characteristics of the non-solar N component trapped in low-antiquity lunar regolith. In contrast, a possible cometary contribution to the non-solar N flux is constrained to be ?3–13%. Based on the mixing ratio of SW to planetary N obtained for recently exposed lunar soils, we estimate the flux of micro-impactors to be (2.2–5.7) × 10³ tons yr^?1 at the surface of the Moon. Our estimate for Luna 24 agrees well with that for young Apollo regolith, indicating that the supply of planetary material does not depend on lunar location. Thus, the continuous influx of water-bearing cosmic dust may have represented an important source of water for the lunar surface over the past ～1 Ga, provided that water removal rates (i.e., by meteorite impacts, photodissociation, and sputtering) do not exceed accumulation rates.     

Noble gases in interplanetary dust particles,I: The excess helium‐3 problem and estimates of the relative fluxes of solar wind and solar energetic particles in interplanetary space

Abstract— We report mass‐spectrometric measurements of light noble gases pyrolytically extracted from 28 interplanetary dust particles (IDPs) and discuss these new data in the context of earlier analyses of 44 IDPs at the University of Minnesota. The noble gas database for IDPs is still very sparse, especially given their wide mineralogic and chemical variability, but two intriguing differences from isotopic distributions observed in lunar and meteoritic regolith grains are already apparent. First are puzzling overabundances of ³He, manifested as often strikingly elevated ³He/⁴He ratios—up to >40x the solar‐wind value—‐and found primarily but not exclusively in shards of some of the larger IDPs (“cluster particles”) that fragmented on impact with the collectors carried by high‐altitude aircraft. It is difficult to attribute these high ratios to ³He production by cosmic‐ray‐induced spallation during estimated space residence times of IDPs, or by direct implantation of solar‐flare He. Minimum exposure ages inferred from the ³He excesses range from ～50 Ma to an impossible >10 Ga, compared to Poynting‐Robertson drag lifetimes for low‐density 20–30 μm particles on the order of ～0.1 Ma for an asteroidal source and ～10 Ma for origin in the Kuiper belt. The second difference is a dominant contribution of solar‐energetic‐particle (SEP) gases, to the virtual exclusion of solar‐wind (SW) components, in several particles scattered throughout the various datasets but most clearly and consistently observed in recent measurements of a group of individual and cluster IDPs from three different collectors. Values of the SEP/SW fluence ratio in interplanetary space from a simple model utilizing these data are ～1% of the relative SEP/SW abundances observed in lunar regolith grains, but still factors of approximately 10–100 above estimates for this ratio in low‐energy solar particle emission.     

Multiple lithic clasts in lunar breccia Northwest Africa 7948 and implication for the lithologic components of lunar crust

This study presents the petrography, mineralogy, and bulk composition of lunar regolith breccia meteorite Northwest Africa (NWA) 7948. We identify a range of lunar lithologies including basaltic clasts (very low-titanium and low-titanium basalts), feldspathic lithologies (ferroan anorthosite, magnesian-suite rock, and alkali suite), granulites, impact melt breccias (including crystalline impact melt breccias, clast-bearing impact melt breccias, and glassy melt breccias), as well as regolith components (volcanic glass and impact glass). A compositionally unusual metal-rich clast was also identified, which may represent an impact melt lithology sourced from a unique Mg-suite parent rock. NWA 7948 has a mingled bulk rock composition (Al₂O₃ = 21.6 wt% and FeO = 9.4 wt%) and relatively low concentrations of incompatible trace elements (e.g., Th = 1.07 ppm and Sm = 2.99 ppm) compared with Apollo regolith breccias. Comparing the bulk composition of the meteorite with remotely sensed geochemical data sets suggests that the sample was derived from a region of the lunar surface distal from the nearside Th-rich Procellarum KREEP Terrane. Our investigations suggest that it may have been ejected from a nearside highlands-mare boundary (e.g., around Mare Crisium or Orientale) or a cryptomare region (e.g., Schickard-Schiller or Mare smythii) or a farside highlands-mare boundary (e.g., Mare Australe, Apollo basin in the South Pole–Aitken basin). The distinctive mineralogical and geochemical features of NWA 7948 suggest that the meteorite may represent lunar material that has not been reported before, and indicate that the lunar highlands exhibit wide geological diversity.     

Optical measurements of the Moon as a tool to study its surface

This survey is a general overview of modern optical studies of the Moon and their diagnostic meaning. It includes three united parts: phase photometry, spectrophotometry, and polarimetry. The first one is devoted to the progress in the photometry of the Moon, which includes absolute albedo determination to refine the albedo scale (e.g., to connect lunar observations and the data of lunar sample measurements) and mapping the parameters of a lunar photometric function (e.g., the phase-angle ratios method) with the aim of making qualitative estimates of regolith structure variations. This part also includes observations of the lunar opposition effect as well as photogrammetry and photoclinometry techniques. In particular, available data show that because of the low albedo of the lunar surface, the coherent backscattering enhancement hardly influences the lunar opposition spike, with the exception of the brightest lunar areas measured in the NIR. The second part is devoted to chemical/mineral mapping of the Moon's surface using spectrophotometric measurements. This section also includes analyses related to the detection of water ice or hydroxyl, prognoses of maturity, and helium-3 abundance mapping. In particular, we examine the relationship between superficial OH/H₂O compounds spectrally detected recently and bulk “water ice” found earlier by the Lunar Prospector GRS and LRO LEND, assuming that the compounds are delivered to cold traps (permanently shadowed regions) with electrostatically levitated dust saturated by solar wind hydrogen. Significant problems arise with the determination of TiO₂ content, as the correlation between this parameter and the color ratio C(750/415 nm) is very non-linear and not universal for different composition types of the lunar surface; a promising way to resolve this problem is to use color ratios in the UV spectral range. The third part is devoted to mapping of polarization parameters of the lunar surface, which enable estimates of the average size of regolith particles and their optical inhomogeneity. This includes considerations of the Umov effect and results of spectropolarimetry, negative polarization imagery, and measurements of other polarimetric parameters, including the third Stokes parameter. Although these three research divisions have not been developed equally and the numbers of proper references are very different, we try to keep a balance between them, depicting a uniform picture. It should be emphasized that many results presented in this review can be applied to other atmosphereless celestial bodies as well.     

Global survey of lunar regolith depths from LROC images

We performed the first global survey of lunar regolith depths using Lunar Reconnaissance Orbiter Camera (LROC) data and the crater morphology method for determining regolith depth. We find that on both the lunar farside and in the nearside, non-mare regions, the regolith depth is twice as deep as it is within the lunar maria. Our data compare favorably with previous studies where such data exist. We also find that regolith depth correlates well with density of large craters (>20 km diameter). This result is consistent with the gradual formation of regolith by rock fracture during impact events.     

Solar-wind interactions with the moon: Nature and composition of nitrogen compounds

The lunar atmosphere and magnetic field are very tenuous. The solar wind, therefore, interacts directly with the lunar surface material and the dominant nature of interaction is essentially complete absorption of solar-wind particles by the surface material resulting in no upstream bowshock, but a cavity downstream. The solar-wind nitrogen ion species induce and undergo a complex set of reactions with the elements of lunar material and the solar-wind-derived trapped elements. The nitrogen concentration indigeneous to the lunar surface material is practically nil. Therefore any nitrogen and nitrogen compounds found in the lunar surface material are due to the solar-wind implantation of nitrogen ions. The flux of the solar-wind nitrogen ion species is about 6×10³ cm^–2 s^–1. Since there is no evidence for accumulation of nitrogen species in the lunar surface material, the outflux of nitrogen species from the lunar material to the atmosphere is the same as the solar-wind nitrogen ion flux. The species of the outflux are primarily NO and NH₃, and their respective concentrations in the near surface lunar atmosphere are found by calculation to be 327 and 295 cm^–3. The calculated concentration of NH₃ seems to be consistent with the sunrise concentration results of the mass spectrometer implanted on the lunar surface. This is not the case for the concentration of NO. According to the presently calculated concentration value of NO, the mass spectrometer should have detected NO at sunrise, but no report was made for its detection. There is also discrepancy about the concentration of N₂ which is explained in this paper. The concentrations of nitrogen species in the lunar material at the time of sample collection on the Moon remained about the same when the samples were analyzed on the Earth. However, no specific experiment was planned to detect the nitrogen species in the lunar material samples.     

Water and other volatiles on the moon: A review

This paper presents a review of research findings on the various forms of water on the Moon. First, this is the water of the Moon’s interior, which has been detected by sensitive mass spectrometric analysis of basaltic glasses delivered by the Apollo 15 and Apollo 17 missions. The previous concepts that lunar magmas are completely dehydrated have been disproved. Second, this is H₂O and/or OH in a thin layer (a few upper millimeters) of the lunar regolith, which is likely a result of bombardment of the oxygen contained in the lunar regolith with solar wind protons. This form of water is highly unstable and quite easily escapes from the surface, possibly being one of the sources of the water ice reservoirs at the Moon’s poles. Third, this is water ice associated with other frozen gases in cold traps at the lunar poles. Its possible sources are impacts of comets and meteorites, the release of gas from the Moon’s interior, and solar wind protons. The ice trapped at the lunar polars could be of practical interest for further exploration of the Moon.     

The antiquity indicator argon‐40/argon‐36 for lunar surface samples calibrated by uranium‐235‐xenon‐136 dating

Abstract— Several solar gas rich lunar soils and breccias have trapped ⁴⁰Ar/³⁶Ar ratios >10, although solar Ar is expected to yield a ratio of <0.01. Radiogenic ⁴⁰Ar produced in the lunar crust from ⁴⁰K decay was outgassed into the lunar atmosphere, ionized, accelerated in the electromagnetic field of the solar wind, and reimplanted into lunar surface material. The ⁴⁰Ar loss rate depends on the decreasing abundance of ⁴⁰K. In order to calibrate the time dependence of the ⁴⁰Ar/³⁶Ar ratio in lunar surface material, the period of reimplantation of lunar atmospheric ions and of solar wind Ar was determined using the ²³⁵U‐¹³⁶Xe dating method that relies on secondary cosmic‐ray neutron‐induced fission of ²³⁵U. We identified the trapped, fissiogenic, and cosmogenic noble gases in lunar breccia 14307 and lunar soils 70001‐8, 70181, 74261, and 75081. Uranium and Th concentrations were determined in the 74261 soil for which we obtain the ²³⁵U‐¹³⁶Xe time of implantation of 3.25^+0.38_‐0.60 Ga ago. On the basis of several cosmogenic noble gas signatures we calculate the duration of this near surface exposure of 393 ± 45 Ma and an average shielding depth below the lunar surface of 73 ± 7 g/cm². A second, recent exposure to solar and cosmic‐ray particles occurred after this soil was excavated from Shorty crater 17.2 ± 1.4 Ma ago. Using a compilation of all lunar data with reliable trapped Ar isotopic ratios and pre‐exposure times we infer a calibration curve of implantation times, based on the trapped⁴⁰ Ar/³⁶Ar ratio. A possible trend for the increase with time of the solar ³He/⁴He and ²⁰Ne/²²Ne ratios of about 12%/Ga and about 2%/Ga, respectively, is also discussed.     

Lunar Clinopyroxene and Plagioclase: Surface Distribution and Composition

The Clementine UVVIS images and the spectral and chemical (mineral) characteristics of lunar soil samples previously measured by the Lunar Samples Characterization Consortium were used to map the plagioclase and clinopyroxene abundance in the lunar surface material. An excess of plagioclase was found in young highland craters (e.g., in the crater Tycho) and in their ray systems. For clinopyroxenes, analogous behavior was observed in mare craters (e.g., in the crater Aristarchus). The maps for the FeO and Al₂O₃ bulk contents and the contents of these oxides in plagioclase and clinopyroxene were estimated by the same technique. These maps were compared to each other and to the predicted distribution of the lunar regolith maturity. The regolith of highland ray systems (e.g., the Tycho crater system) is characterized not only by low maturity but also by peculiar iron and aluminum contents: the lower the soil maturity degree, the smaller the iron content and the greater the aluminum content. This is confirmed by the data for the lunar soil samples from the Apollo 16 landing site. A cluster analysis of the “clinopyroxene content-maturity” and “plagioclase content-maturity” correlation diagrams allowed the mineral mapping of the lunar surface to be performed.__________Translated from Astronomicheskii Vestnik, Vol. 39, No. 4, 2005, pp. 291–303.Original Russian Text Copyright © 2005 by Shkuratov, Kaydash, Pieters.     

The variability of Mercury's exosphere by particle and radiation induced surface release processes

Mercury's close orbit around the Sun, its weak intrinsic magnetic field and the absence of an atmosphere (P_surface<1×10⁻⁸ Pa) results in a strong direct exposure of the surface to energetic ions, electrons and UV radiation. Thermal processes and particle-surface-collisions dominate the surface interaction processes leading to surface chemistry and physics, including the formation of an exosphere (N?10¹⁴ cm⁻²) in which gravity is the dominant force affecting the trajectories of exospheric atoms. NASA's Mariner 10 spacecraft observed the existence of H, He, and O in Mercury's exosphere. In addition, the volatile components Na, K, and Ca have been observed by ground based instrumentation in the exosphere. We study the efficiency of several particle surface release processes by calculating stopping cross-sections, sputter yields and exospheric source rates. Our study indicates surface sputter yields for Na between values of about 0.27 and 0.35 in an energy range from 500 eV up to 2 keV if Na⁺ ions are the sputter agents, and about 0.037 and 0.082 at an energy range between 500 eV up to 2 keV when H⁺ are the sputter agents and a surface binding energy of about 2 eV to 2.65 eV. The sputter yields for Ca are about 0.032 to 0.06 and for K atoms between 0.054 to 0.1 in the same energy range. We found a sputter yield for O atoms between 0.025 and 0.04 for a particle energy range between 500 eV up to 2 keV protons. By taking the average solar wind proton surface flux at the open magnetic field line area of about 4×10⁸ cm⁻² s⁻¹ calculated by Massetti et al. (2003, Icarus, in press) the resulting average sputtering flux for O is about 0.8-1.0×10⁷ cm⁻² s⁻¹ and for Na approximately 1.3-1.6×10⁵ cm⁻² s⁻¹ depending on the assumed Na binding energies, regolith content, sputtering agents and solar activity. By using lunar regolith values for K we obtain a sputtering flux of about 1.0-1.4×10⁴ cm⁻² s⁻¹. By taking an average open magnetic field line area of about 2.8×10¹⁶ cm² modelled by Massetti et al. (2003, Icarus, in press) we derive an average surface sputter rate for Na of about 4.2×10²¹ s⁻¹ and for O of about 2.5×10²³ s⁻¹. The particle sputter rate for K atoms is about 3.0×10²⁰ s⁻¹ assuming lunar regolith composition for K. The sputter rates depend on the particle content in the regolith and the open magnetic field line area on Mercury's surface. Further, the surface layer could be depleted in alkali. A UV model has been developed to yield the surface UV irradiance at any time and latitude over a Mercury year. Seasonal and diurnal variations are calculated, and Photon Stimulated Desorption (PSD) fluxes along Mercury's orbit are evaluated. A solar UV hotspot is created towards perihelion, with significant average PSD particle release rates and Na fluxes of about 3.0×10⁶ cm⁻² s⁻¹. The average source rates for Na particles released by PSD are about 1×10²⁴ s⁻¹. By using the laboratory obtained data of Madey et al. (1998, J. Geophys. Res. 103, 5873-5887) for the calculation of the PSD flux of K atoms we get fluxes in the order of about 10⁴ cm⁻² s⁻¹ along Mercury's orbit. However, these values may be to high since they are based on idealized smooth surface conditions in the laboratory and do not include the roughness and porosity of Mercury's regolith. Further, the lack of an ionosphere and Mercury's small, temporally and spatially highly variable magnetosphere can result in a large and rapid increase of exospheric particles, especially Na in Mercury's exosphere. Our study suggests that the average total source rates for the exosphere from solar particle and radiation induced surface processes during quiet solar conditions may be of the same order as particles produced by micrometeoroid vaporization. We also discuss the capability of in situ measurements of Mercury's highly variable particle environment by the proposed NPA-SERENA instrument package on board ESA's BepiColombo Mercury Planetary Orbiter (MPO).     

The petrology,geochemistry, and age of lunar regolith breccias Miller Range 090036 and 090070: Insights into the crustal history of the Moon

Meteorites ejected from the surface of the Moon as a result of impact events are an important source of lunar material in addition to Apollo and Luna samples. Here, we report bulk element composition, mineral chemistry, age, and petrography of Miller Range (MIL) 090036 and 090070 lunar meteorites. MIL 090036 and 090070 are both anorthositic regolith breccias consisting of mineral fragments and lithic clasts in a glassy matrix. They are not paired and represent sampling of two distinct regions of the lunar crust that have protoliths similar to ferroan anorthosites. ⁴⁰Ar‐³⁹Ar chronology performed on two subsplits of MIL 090070,33 (a pale clast impact melt and a dark glassy melt component) shows that the sample underwent two main degassing events, one at ~3.88 Ga and another at ~3.65 Ga. The cosmic ray exposure data obtained from MIL 090070 are consistent with a short (~8–9 Ma) exposure close to the lunar surface. Bulk‐rock FeO, TiO₂, and Th concentrations in both samples were compared with 2‐degree Lunar Prospector Gamma Ray Spectrometer (LP‐GRS) data sets to determine areas of the lunar surface where the regolith matches the abundances observed on the sample. We find that MIL 090036 bulk rock is compositionally most similar to regolith surrounding the Procellarum KREEP Terrane, whereas MIL 090070 best matches regolith in the feldspathic highlands terrane on the lunar farside. Our results suggest that some areas of the lunar farside crust are composed of ferroan anorthosite, and that the samples shed light on the evolution and impact bombardment history of the ancient lunar highlands.     

Solar wind and other gases in the regoliths of the Pesyanoe parent object and the moon

We report new data from Pesyanoe‐90,1 (dark lithology) on the isotopic signature of solar wind (SW) Xe as recorded in this enstatite achondrite which represents a soil‐breccia of an asteroidal regolith. The low temperature (≤800°C) steps define the Pesyanoe‐S xenon component, which is isotopically consistent with SW Xe reported for the lunar regolith. This implies that the SW Xe isotopic signature was the same at two distinct solar system locations and, importantly, also at different times of solar irradiation. Further, we compare the calculated average solar wind “SW‐Xe” signature to Chass‐S Xe, the indigenous Xe observed in SNC (Mars) meteorites. Again, a close agreement between these compositions is observed, which implies that a mass‐dependent differential fractionation of Xe between SW‐Xe and Chass‐S Xe is >1.5%_o per amu. We also observe fractionated (Pesyanoe‐F) Xe and Ar components in higher temperature steps and we document a fission component due to extinct ²⁴⁴Pu. Interestingly, the Pesyanoe‐F Xe component is revealed only at the highest temperatures (>1200°C). The Pesyanoe‐F gas reveals Xe isotopic signatures that are consistent with lunar solar energetic particles (SEP) data and may indicate a distinct solar energetic particle radiation as was inferred for the moon. However, we cannot rule out fractionation processes due to parent body processes. We note that ratios ³⁶Ar/³⁸Ar≤5 are also consistent with SEP data. Calculated abundances of the fission component correlate well with radiogenic ⁴⁰Ar concentrations, revealing rather constant ²⁴⁴Pu/K ratios in Pesyanoe, and separates thereof, and indicate that both components were retained. We identify a nitrogen component (δ¹⁵N = 44%_o) of non‐solar origin with an isotopic signature distinct from indigenous N (δ¹⁵N = ?33%^o). While large excesses at ¹²⁸Xe and ¹²⁹Xe are observed in the lunar regolith samples, these excesses in Pesyanoe are small. On the other hand, significant ¹²⁶Xe isotopic excesses, comparable to relative excesses observed in lunar soils and breccias, are prominent in the intermediate temperature steps of Pesyanoe‐90,1.