Spatial and Temporal Distribution of Dust‐Bound Trace Metal Elements around Kuhdasht Watershed Area in Iran

Dust, as a source of trace metal elements, affects the health of society. The spatial and temporal concentrations of dust‐bound trace metals (Cd, Pb, Ni, Zn, Cu, and Mn) in Kuhdasht watershed (456 km²), Lorestan Province, Iran, is investigated. Dust is collected using glass traps placed in ten research stations in the region. The spatial and temporal distribution of dust trace metals are plotted using ARC‐GIS. The highest and the lowest concentrations of Zn (9751150 mg kg^?1), Pb (46.352.9 mg kg^?1), and Cd (2.443.30 mg kg^?1) are obtained in winter, of Ni (98110 mg kg^?1) and Cu in autumn (16.053.5 mg kg^?1), and of Mn in summer (385505 mg kg^?1). The spatial concentrations of dust‐bound trace metals indicate all, except Cu, show a decreasing trend from the mountains toward the plains, similar to that of soil and of dust, except for Zn, which shows higher concentrations in dust than in soil. The potential sources of dust‐bound trace metals and their rate of contamination are also investigated using the enrichment and contamination factors. The major sources of Cd and Zn in the dust of watershed are due to anthropogenic activities or from activities outside the borders.     

Beryllium‐7 wet deposition variation with storm height,synoptic classification,and tree canopy state in the mid‐Atlantic USA

Short‐lived fallout isotopes, such as beryllium‐7 (⁷Be), are increasingly used as erosion and sediment tracers in watersheds. ⁷Be is produced in the atmosphere and delivered to the Earth's surface primarily in precipitation. However, relatively little has been published about the variation in ⁷Be wet deposition caused by storm type and vegetation cover. Our analysis of precipitation, throughfall, and sediments in two forested, headwater catchments in the mid‐Atlantic USA indicates significant variation in isotope deposition with storm type and storm height. Individual summer convective thunderstorms were associated with ⁷Be activity concentrations up to 5.0 Bq l^?1 in precipitation and 4.7 Bq l^?1 in throughfall, while single‐event wet depositional fluxes reached 168 Bq m^?2 in precipitation and 103 Bq m^?2 in throughfall. Storms originating from the continental USA were associated with lower ⁷Be activity concentrations and single‐event wet depositional fluxes for precipitation (0.7–1.2 Bq l^?1 and 15.8–65.0 Bq m^?2) and throughfall (0.1–0.3 Bq l^?1 and 13.5–98.9 Bq m^?2). Tropical systems had relatively low activity concentrations, 0.2–0.5 Bq l^?1 in precipitation and 0.2–1.0 Bq l^?1 in throughfall, but relatively high single‐event depositional fluxes due to large rainfall volumes, 32.8–67.6 Bq m^?2 in precipitation and 25.7–134 Bq m^?2 in throughfall. The largest sources of ⁷Be depositional variation were attributed to storm characteristics including precipitation amount and maximum storm height. ⁷Be activity associated with fluvial suspended sediments also exhibited the highest concentration and variability in summer (175–1450 Bq kg^?1). We conclude the dominant source of variation on event‐level ⁷Be deposition is storm type. Our results illustrate the complex relationships between ⁷Be deposition in precipitation and throughfall and demonstrate event‐scale relationships between the ⁷Be in precipitation and on suspended sediment. Copyright © 2015 John Wiley & Sons, Ltd.     

Effect of rock fragment embedding on the aeolian deposition of dust on stone‐covered surfaces

Many stone‐covered surfaces on Earth are subject to aeolian deposition of atmospheric dust. This study investigates how the deposition of dust is affected when rock fragments become gradually more embedded in the ground or, inversely, become more concentrated on the surface. Experiments were executed in an aeolian dust wind tunnel with eight different types of pebbles. The following parameters were measured: dust deposition on the pebbles, dust deposition between and underneath pebbles, total dust deposition (pebbles + inter‐pebble space), and the fraction, of total deposition, of dust caught by the pebbles alone. The absolute amount of dust deposition and the dust deposition density (dust deposition per unit surface) were studied for each parameter. The effects exerted by pebble size, pebble flattening, pebble elongation and wind speed were also investigated. Dust patterns on and around pebbles were also studied via flow visualization. The absolute amount of dust settling on pebbles decreases the more that the pebbles become embedded. Dust deposition density on pebbles, on the other hand, increases with embedding. The more pebbles become embedded in the soil, the more efficient the process of dust deposition on pebbles becomes. Dust deposition between and underneath pebbles increases with pebble embedding. Dust deposition density between and underneath pebbles is maximum at 50 per cent embedding, showing that in this area dust deposition is most efficient when pebbles are halfway embedded. Total deposition slightly decreases the more pebbles become embedded, but total dust deposition density increases with embedding. Aerodynamic flow separation and diverging and converging airflow play an important role in the process of dust deposition on stone‐covered surfaces. The more pebbles protrude above the soil, the more they act as an obstacle and the more they disturb the air and dust flow creating scouring zones, flow separation bubbles and shelter areas for the dust. All these effects diminish as pebbles become more embedded in the soil. However, perturbations in dust patterns remain visible until pebbles have disappeared entirely. Copyright © 2005 John Wiley & Sons, Ltd.     

Comparison of methods for quantifying surface sublimation over seasonally snow‐covered terrain

Snow sublimation can be an important component of the snow‐cover mass balance, and there is considerable interest in quantifying the role of this process within the water and energy balance of snow‐covered regions. In recent years, robust eddy covariance (EC) instrumentation has been used to quantify snow sublimation over snow‐covered surfaces in complex mountainous terrain. However, EC can be challenging for monitoring turbulent fluxes in snow‐covered environments because of intensive data, power, and fetch requirements, and alternative methods of estimating snow sublimation are often relied upon. To evaluate the relative merits of methods for quantifying surface sublimation, fluxes calculated by the EC, Bowen ratio–energy balance (BR), bulk aerodynamic flux (BF), and aerodynamic profile (AP) methods and their associated uncertainty were compared at two forested openings in the Colorado Rocky Mountains. Biases between methods are evaluated over a range of environmental conditions, and limitations of each method are discussed. Mean surface sublimation rates from both sites ranged from 0.33 to 0.36 mm day^?1, 0.14 to 0.37 mm day^?1, 0.10 to 0.17 mm day^?1, and 0.03 to 0.10 mm day^?1 for the EC, BR, BF and AP methods, respectively. The EC and/or BF methods are concluded to be superior for estimating surface sublimation in snow‐covered forested openings. The surface sublimation rates quantified in this study are generally smaller in magnitude compared with previously published studies in this region and help to refine sublimation estimates for forested openings in the Colorado Rocky Mountains. Copyright © 2016 John Wiley & Sons, Ltd.     

On the winter evolution of snow thermophysical properties over land‐fast first‐year sea ice

The geophysical, thermodynamic and dielectric properties of snow are important state variables that are known to be sensitive to Arctic climate variability and change. Given recent observations of changes in the Arctic physical system (Arctic Climate Impact Assessment, 2004), it is important to focus on the processes that give rise to variability in the horizontal, vertical and temporal dimensions of the life‐history of snow on sea ice. The objectives in this study are to present these ‘state’ variables and to investigate the processes that govern variability in the vertical, horizontal and temporal dimension by using a case study over land‐fast first‐year sea ice for the period December 2003 to June 2004. Results from two sampling areas (thin and thick snowpacks) show that differences in snowpack thickness can substantially change the vertical and temporal evolution of snow properties. During the late fall and early winter (cooling period) we measured no significant changes in the physical properties, except for thin snow‐cover salinity, which decreased throughout the period. Fall‐snow desalination was only observed under thin snowpacks with a rate of ?0·12 ppt day^?1. Significant changes occurred in the late winter and early spring (warming period), especially for snow grain size. Snow grain kinetic growth of 0·25–0·48 mm·day^?1 was measured coincidently with increasing salinity and wetness for both thin and thick snowpacks. Copyright © 2006 John Wiley & Sons, Ltd.     

Nested‐Scale Nutrient Flux in a Mixed‐Land‐Use Urbanizing Watershed

To improve quantitative understanding of mixed‐land‐use impacts on nutrient yields, a nested‐scale experimental watershed study design (n = 5) was applied in a 303(d), clean water act impaired urbanizing watershed of the lower Missouri River Basin, USA. From 2010 to 2013, water samples (n = 858 sample days per site) were analysed for total inorganic nitrogen (TIN‐N), nitrite (NO₂–N) nitrate (NO₃–N), ammonia (NH₃–N), and total phosphorus (TP‐P). Annual, seasonal, and monthly flow‐weighted concentrations (FWCs) and nutrient yields were estimated. Mean nutrient concentrations were highest where agricultural land use comprised 58% of the drainage area (NH₃ = 0.111 mg/l; NO₂ = 0.045 mg/l; NO₃ = 0.684 mg/l, TIN = 0.840 mg/l; TP = 0.127 mg/l). Average TP‐P increased by 15% with 20% increased urban land use area. Highly variable annual precipitation was observed during the study with highest nutrient yields during 2010 (record setting wet year) and lowest nutrient yields during 2012 (extreme drought year). Annual TIN‐N and TP‐P yields exceeded 10.3 and 2.04 kg ha^?1 yr^?1 from the agricultural dominated headwaters. Mean annual NH₃–N, NO₂–N, NO₃–N, TIN‐N, and TP‐P yields were 0.742, 0.400, 4.24, 5.38, and 0.979 kg ha^?1 yr^?1, respectively near the watershed outlet. Precipitation accounted for the majority of the explained variance in nutrient yields (R² values from 0.68 to 0.85). Nutrient yields were also dependent on annual precipitation of the preceding year (R² values from 0.87 to 0.91) thus enforcing the great complexity of variable mixed‐land‐use mediated source‐sink nutrient yield relationships. Study results better inform land managers and best management practices designed to mitigate nutrient pollution issues in mixed‐land‐use freshwater ecosystems. Copyright © 2015 John Wiley & Sons, Ltd.     

Variability and trends in the annual snow‐cover cycle in Northern Hemisphere land areas, 1972–2000

This study investigated variability and trends in the annual snow‐cover cycle in regions covering high‐latitude and high‐elevation land areas in the Northern Hemisphere. The annual snow‐cover cycle was examined with respect to the week of the last‐observed snow cover in spring (WLS), the week of the first‐observed snow cover in autumn (WFS), and the duration of the snow‐free period (DSF). The analysis used a 29‐year time‐series (1972–2000) of weekly, visible‐band satellite observations of Northern Hemisphere snow cover from NOAA with corrections applied by D. Robinson of Rutgers University Climate Laboratory. Substantial interannual variability was observed in WLS, WFS and DSF (standard deviations of 0·8–1·1, 0·7–0·9 and 1·0–1·4 weeks, respectively), which is related directly to interannual variability in snow‐cover area in the regions and time periods of snow‐cover transition. Over the nearly three‐decade study period, WLS shifted earlier by 3–5 days/decade as determined by linear regression analysis. The observed shifts in the annual snow‐cover cycle underlie a significant trend toward a longer annual snow‐free period. The DSF increased by 5–6 days/decade over the study period, primarily as a result of earlier snow cover disappearance in spring. The observed trends are consistent with reported trends in the timing and length of the active growing season as determined from satellite observations of vegetation greenness and the atmospheric CO₂ record. Copyright © 2002 John Wiley & Sons, Ltd.     

The use of short‐lived radionuclides to quantify transitional bed material transport in a regulated river

We investigate the use of the short‐lived fallout radionuclide beryllium‐7 (⁷Be; t_1/2 = 53·4 days) as a tracer of medium and coarse sand (0·25–2 mm), which transitions between transport in suspension and as bed load, and evaluate the effects of impoundment on seasonal and spatial variations in bed sedimentation. We measure ⁷Be activities in approximately monthly samples from point bar and streambed sediments in one unregulated and one regulated stream. In the regulated stream our sampling spanned an array of flow and management conditions during the annual transition from flood control in the winter and early spring to run‐of‐the‐river operation from late spring to autumn. Sediment stored behind the dam during the winter quickly became depleted in ⁷Be activity. This resulted in a pulse of ‘dead’ sediment released when the dam gates were opened in the spring which could be tracked as it moved downstream. Measured average sediment transport velocities (30–80 metres per day (m d^?1)) exceed those typically reported for bulk bed load transport and are remarkably constant across varied flow regimes, possibly due to corresponding changes in bed sand fraction. Results also show that the length scale of the downstream impact of dam management on sediment transport is short (c. 1 km); beyond this distance the sediment trapped by the dam is replaced by new sediment from tributaries and other downstream sources. Copyright © 2006 John Wiley & Sons, Ltd.     

Estimating sublimation of intercepted and sub‐canopy snow using eddy covariance systems

Direct measurements of winter water loss due to sublimation were made in a sub‐alpine forest in the Rocky Mountains of Colorado. Above‐and below‐canopy eddy covariance systems indicated substantial losses of winter‐season snow accumulation in the form of snowpack (0·41 mm d^?1) and intercepted snow (0·71 mm d^?1) sublimation. The partitioning between these over and under story components of water loss was highly dependent on atmospheric conditions and near‐surface conditions at and below the snow/atmosphere interface. High above‐canopy sensible heat fluxes lead to strong temperature gradients between vegetation and the snow‐surface, driving substantial specific humidity gradients at the snow surface and high sublimation rates. Intercepted snowfall resulted in rapid response of above‐canopy latent heat fluxes, high within‐canopy sublimation rates (maximum = 3·7 mm d^?1), and diminished sub‐canopy snowpack sublimation. These results indicate that sublimation losses from the sub‐canopy snowpack are strongly dependent on the partitioning of sensible and latent heat fluxes in the canopy. This compels comprehensive studies of snow sublimation in forested regions that integrate sub‐canopy and over‐story processes. Copyright © 2007 John Wiley & Sons, Ltd.     

Adsorption of Cationic Dyes from Aqueous Solution by Termite Feces,a Non‐Conventional Adsorbent

The adsorption of three cationic dyes (rhodamine B, RB; crystal violet, CV; and malachite green, MG) onto termite feces, a low‐cost adsorbent, was investigated. The adsorbent was characterized by IR spectroscopy, point of zero charge measurement, and the Boehm titration method. The adsorption follows the pseudo‐second‐order kinetic model and the Langmuir–Freundlich isotherm with maximum adsorption capacities of 95.53 mg g^?1 (RB), 75.71 mg g^?1 (CV), and 44.78 mg g^?1 (MG). The study of thermodynamics showed that the adsorption is a spontaneous and endothermic process. This works suggest that termite feces can be used as a new low‐cost adsorbent for cationic dye removal.     

Groundwater–surface‐water interactions in a braided river: a tracer‐based assessment

Natural tracers (alkalinity and silica) were used to infer groundwater–surface‐water exchanges in the main braided reach of the River Feshie, Cairngorms, Scotland. Stream‐water samples were collected upstream and downstream of the braided section at fortnightly intervals throughout the 2001–2002 hydrological year and subsequently at finer resolution over two rainfall events. The braided reach was found to exert a significant downstream buffering effect on the alkalinity of these waters, particularly at moderate flows (4–8 m³ s^?1/?Q_30–70). Extensive hydrochemical surveys were undertaken to characterize the different source waters feeding the braids. Shallow groundwater flow systems at the edge of the braided floodplain, recharged by effluent streams and hillslope drainage, appeared to be of particular significance. Deeper groundwater was identified closer to the main channel, upwelling through the hyporheic zone. Both sources contributed to the significant groundwater–surface‐water interactions that promote the buffering effect observed through the braided reach. Their impact was less significant at higher flows (>15 m³ s^?1/>Q₁₀) when acidic storm runoff from the peat‐covered catchment headwaters dominated, as well as under baseflow conditions (<4 m³ s^?1/<Q₇₀), when upstream alkalinity was already buffered owing to headwater groundwater sources assuming dominance. The significant temporally and spatially dynamic influence of these groundwater–surface‐water interactions was therefore seen to have important implications for both catchment functioning and instream ecology. Copyright © 2004 John Wiley & Sons, Ltd.     

Determination of Copper in Water Samples after Solid‐phase Extraction Using Dimethylglyoxime‐modified Silica

This work describes the modification of silica gel with dimethylglyoxime, in order to prepare an effective sorbent for the preconcentration and determination of copper. The sorption capacity of dimethylglyoxime‐modified silica‐gel (DMGMS) was 71.37 mg g^–1 and the optimum pH for the quantitative recovery of copper was found to be 5.0. The optimum flow rate, sorbent amount, and sample volume were 1 mL min^–1, 300 mg, and 50 mL, respectively. 10 mL of 0.1 mol L^–1 HCl was the most suitable eluent. The detection limit of copper was 6.0 ng mL^–1. The recommended method, for the determination of copper, is simple and reliable, without any notable matrix effect and can be successfully applied to environmental water samples. Copper recovery in the range from 99–100% was obtained from seawater and thermal spring water using this method. The method was applied to standard reference materials, NIST‐1515 (apple leaves) and NIST‐1643e (simulated fresh water), for the determination of copper and the results were in good agreement with certified values.     

Slope‐area thresholds of road‐induced gully erosion and consequent hillslope–channel interactions

Pikes Peak Highway is a partially paved road between Cascade, Colorado and the summit of Pikes Peak. Significant gully erosion is occurring on the hillslopes due to the concentration of surface runoff, the rearrangement of drainage pathways along the road surface and adjacent drainage ditches, and the high erodibility of weathered Pikes Peak granite that underlies the area. As a result, large quantities of sediment are transported to surrounding valley networks causing significant damage to water quality and aquatic, wetland, and riparian ecosystems. This study establishes the slope/drainage area threshold for gullying along Pikes Peak Highway and a cesium‐137 based sediment budget highlighting rates of gully erosion and subsequent valley deposition for a small headwater basin. The threshold for gullying along the road is S_cr = 0 · 21A^–0·45 and the road surface reduces the critical slope requirement for gullying compared to natural drainages in the area. Total gully volume for the 20 gullies along the road is estimated at 5974 m³, with an erosion rate of 64 m³ yr^–1 to 101 m³ yr^–1. Net valley deposition is estimated at 162 m³ yr^–1 with 120 m³ yr^–1 unaccounted for by gullying. The hillslope–channel interface is decoupled with minimal downstream sediment transport which results in significant local gully‐derived sedimentation. Copyright © 2013 John Wiley & Sons, Ltd.     

Long‐term assessment of nutrient flow pathway dynamics and in‐stream fate in a temperate karst agroecosystem watershed

Nutrient dynamics in karst agroecosystems remain poorly understood, in part due to limited long‐term nested datasets that can discriminate upland and in‐stream processes. We present a 10‐year dataset from a karst watershed in the Inner‐Bluegrass Region of central Kentucky, consisting of nitrate (nitrate‐N [NO₃^?]), dissolved reactive phosphorus (DRP), total organic carbon (TOC), and total ammoniacal‐N (TAN) measurements at nested spring and stream sites as well as flowrate at the watershed outlet. Hydrograph separation techniques were coupled with multiple linear regression and Empirical Mode Decomposition time‐series analysis to determine significance of seasonal processes and to generate continuous estimates of nutrient pathway loadings. Further, we used model results of benthic algae growth and decomposition dynamics from a nearby watershed to assess if transient storage in algal biomass could explain differences in spring and downstream watershed nutrient loading. Results highlight statistically significant seasonality for all nutrients at stream sites, but only for NO₃^? at springs with longitudinal variability showing significant decreases occurring from spring to stream sites for NO₃^? and DRP, and significant increases for TOC and TAN. Pathway loading analysis highlighted the importance of slow flow pathways to source approximately 70% of DRP and 80% of NO₃^?. Results for in‐stream dynamics suggest that benthic autotroph dynamics can explain summer deviations for TOC, TAN, and DRP but not NO₃^?. Regarding upland dynamics, our findings agree well with existing perceptions in karst for N pathways and upland source seasonality but deviate from perceptions that karst conduits are retentive of P, reflecting the limited buffering capacity of the soil profile and conduit sediments in the Inner‐Bluegrass. Regarding in‐stream fate, our findings highlighted the significance of seasonally driven nutrient processing in the bedrock‐controlled streambed to influence nutrient fluxes at the watershed outlet. Contrary to existing perceptions, we found high N attenuation and an unexplained NO₃^? sink in the bedrock stream, leading us to postulate that floating macrophytes facilitate high rates of denitrification.     

Extra-terrestrial 53Mn in Antarctic ice

The reasons why⁵³Mn (a cosmogenic radionuclide with a half-life of 3.7 × 10⁶ y) appears as one of the best indicators of the presence of interplanetary dust are summarized. This paper reports the detection of⁵³Mn in pre-1952 snow samples collected on the Eastern Antarctic Plateau in the vicinity of Plateau Station. The measurements were carried out by neutron activation and X-ray spectrometry on three samples weighing a few hundred kg and covering each the time interval 1935–1950. The specific activity of⁵³Mn was found to be (0.82 ± 0.17) disint.min^?1/10³ tons of snow, corresponding to a deposition rate at Plateau Station of (2.2 ± 0.5) × 10^?5 disint. min^?1 m^?2 y^?1. The mean global deposition rate would be three times higher if⁵³Mn were assumed to behave in the same way as stratospheric⁹⁰Sr. By comparing this figure with existing data on the meteorite flux reaching the earth and with the galactic and solar production rates of⁵³Mn, it is concluded that the bulk of the⁵³Mn found at Plateau Station is associated with interplanetary dust in which it had been produced by the action of solar protons on iron. The deposition rate of extra-terrestrial dust-borne iron must be between 1.3 × 10^?5 and 1.3 × 10^?4 g m^?2 y^?1 at Plateau Station. These results support jointly with other studies the concept of an interplanetary zodiacal cloud of dust with a chemical composition and density not essentially different from chondritic meteorites, with a relatively ‘flat’ grain size distribution and a mass influx to the earth of the order of 10⁵ tons/y.     

Spatial and temporal perspectives on spring break‐up flooding in the Slave River Delta,NWT

Spatial and temporal patterns of spring break‐up flooding in the Slave River Delta (SRD), Northwest Territories, are characterized during three years (2003–2005) using water isotope tracers and total inorganic suspended sediment (TSS) concentrations measured from lakewater samples collected shortly after the spring melt. Strongly contrasting spring melt periods led to a moderate flood in 2003, no flooding in 2004 and widespread flooding in 2005. Flooded lakes have isotopically‐depleted δ¹⁸O (δ²H) signatures, ranging between ? 19·2‰ (?145‰) and ? 17·1‰ (?146‰) and most have high TSS concentrations (>10 mg L^?1), while non‐flooded lakes have more isotopically‐enriched δ¹⁸O (δ²H) signatures, ranging between ? 18·2‰ (?149‰) and ? 10·6‰ (?118‰) and low TSS concentrations (<10 mg L^?1). These results, in conjunction with the isotopic signatures of Slave River water and snowmelt, are used to estimate the proportion of river‐ or snowmelt‐induced dilution in delta lakes during the spring of each study year. Calculations indicate river flooding caused dilution of ～70–100% in delta lakes, while snowmelt dilution in the absence of river flooding ranged from ～0–56%. A positive relationship exists between the spatial extent of spring flooding in the SRD and level and discharge on the Slave River and upstream tributaries, suggesting that upstream flow generation plays a key role in determining the magnitude of spring flooding in the SRD. Parallel variations in the 46‐year instrumental Slave River discharge record and flood stratigraphy in the active delta indicate that there is potential for extending the flood history of the SRD, a development that will contribute to a more robust understanding of the drivers of historic, contemporary and future flood frequency in the delta. Copyright © 2008 John Wiley & Sons, Ltd.     

Dry aeolian dust accumulation in rocky deserts: ­a medium‐term field experiment based on short‐term wind tunnel simulations

The spatial pattern of medium‐term (a few months) dry aeolian dust accumulation in rocky deserts is predicted using short‐term deposition and erosion experiments in a wind tunnel. The predictions are tested in a field experiment set up in the northern Negev Desert of Israel. The results show that superimposing wind tunnel deposition and erosion maps usually leads to correct predictions of medium‐term dust accumulation. The predictions are somewhat less confident near the inflection lines of windward hillslopes, where small‐scale irregularities in the local topography make it difficult to locate the exact position of the areas of little accumulation. Elsewhere in the topography predictions are good, and the method works satisfactorily. Highest accumulation occurs on concave windward slopes and, to a lesser extent, on slopes parallel to the wind. Little accumulation occurs on the convex windward slopes and in dust separation bubbles. The smallest accumulation rates are observed immediately upwind of the top of pronounced hills and on leeslopes. The rate of dry dust accumulation measured during the field experiment varied from 17 to 93 g m⁻² a⁻¹, depending on the topographic position of the accumulation plots. For most plots, it was of the order of 30–60 g m⁻² a⁻¹. Copyright © 2000 John Wiley & Sons, Ltd.     

Provenance of long‐travelled dust determined with ultra‐trace‐element composition: a pilot study with samples from New Zealand glaciers

We report high‐precision inductively coupled plasma mass spectrometric (ICP‐MS) compositional data for 39 trace elements in a variety of dust deposits, trapped sediments and surface samples from New Zealand and Australia. Dusts collected from the surface of alpine glaciers in the Southern Alps, New Zealand, believed to have undergone long‐distance atmospheric transport from Australia, are recognizable on account of their overabundances of Pb and Cu with respect to typical upper crustal values. Long‐travelled dust from Australia therefore scavenges these and other metals (e.g. Zn, Sb and Cd) from the atmosphere during transport and deposition. Hence, due to anthropogenic pollution, long‐travelled Australian dusts can be recognized by elevated metal contents. The relative abundance of 25 other elements that are not affected by atmospheric pollution, mineral sorting (Zr and Hf) and weathering[sol ]solubility (alkali and earth alkali elements) reflects the geochemistry of the dust source sediment. As a result, we are able to establish the provenance of dust using ultra‐trace‐element chemistry at regional scale. Comparison of long‐travelled dust chemistry with potential Australian sources shows that fits of variable quality are obtained. We propose that the best fitting potential source chemistry most likely represents the major dust source area. A binary mixing model is used to demonstrate that admixture of small quantities of local dust provides an even better fitting dust chemistry for the long‐travelled dusts. Copyright © 2005 John Wiley & Sons, Ltd.     

Identifying regional dust transport pathways: ­application of kinematic trajectory modelling to a trans‐Tasman case

A kinematic trajectory model is used to investigate potential pathways of dust transport from Australia to New Zealand. Historically, these have been assumed to follow rather direct west–east trajectories spanning 2 to 3 days, often resulting in red snow events in the Southern Alps of New Zealand. However, results from the present study which examined the route taken by air parcels originating in southern Australia during dust storms on 24 and 25 May 1994, indicate that trans‐Tasman dust transport trajectories are more diverse than previously thought, and display considerable variation during single events. These more divergent pathways tie in more closely with aeolian dust sedimentation patterns identified by ocean coring in the Tasman Sea, and may account for the deposition of Australian dust on sub‐Antarctic islands located well south of the Australian continent. Copyright © 2000 John Wiley & Sons, Ltd.     

Long‐term investigations of the snow cover in a subalpine semi‐forested catchment

To improve spring runoff forecasts from subalpine catchments, detailed spatial simulations of the snow cover in this landscape is obligatory. For more than 30 years, the Swiss Federal Research Institute WSL has been conducting extensive snow cover observations in the subalpine watershed Alptal (central Switzerland). This paper summarizes the conclusions from past snow studies in the Alptal valley and presents an analysis of 14 snow courses located at different exposures and altitudes, partly in open areas and partly in forest. The long‐term performance of a physically based numerical snow–vegetation–atmosphere model (COUP) was tested with these snow‐course measurements. One single parameter set with meteorological input variables corrected to the prevailing local conditions resulted in a convincing snow water equivalent (SWE) simulation at most sites and for various winters with a wide range of snow conditions. The snow interception approach used in this study was able to explain the forest effect on the SWE as observed on paired snow courses. Finally, we demonstrated for a meadow and a forest site that a successful simulation of the snowpack yields appropriate melt rates. Copyright © 2006 John Wiley & Sons, Ltd.