Multivariate water quality assessment from the Tamiraparani river basin,Southern India

The hydrochemistry of a perennial river has been investigated with multivariate cluster analysis (CA) and principal component analysis/factor analysis (PCA/FA). The aim was to investigate parameters responsible for spatial and temporal variations of river water quality. Water quality was monitored along the river basin at 20 different sites over a period of 1 year from July, 2008 to June, 2009. Multivariate statistics revealed that Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ^?, Cl^?, H₄SiO₄, SO₄ ^2?, NO₂ ^?, and PO₄ ^3? were influenced by seasonal and spatial variations and that water quality was in the first place determined more by natural weathering processes than by anthropogenic activities. We could prove by (a) Box and Whisker plot, (b) matrix scatter score mean plot, (c) ternary plot, and (d) Gibbs plot that the chemistry of river water is controlled by lithogenic weathering processes. The higher concentration of dissolved silica during summer and the pre-monsoon season is explained by natural and tropical climatic conditions of the environment.     

Groundwater Environment of a Tropical East Flowing River of Western Ghats,Southern India

Abstraction of groundwater resources is increasing over the years to meet its ever-increasing demand for industrial, agricultural and domestic purposes throughout the world. The scenario is even worse in the east flowing rivers of the Western Ghats, where the demand of water is high under changing climatic conditions. Such situation may affect the groundwater resources of the river basin on a long run. The aim of the present study is to characterize the geochemistry of groundwater in Tamiraparani sub-basin through geochemical modeling and deduce the ionic interactions with the aid of geostatistical and multivariate statistical techniques. A total of 40 groundwater samples from shallow aquifers were collected randomly throughout the sub-basin for assessing its physicochemical parameters, which include physical properties of the water, major ions and nutrients. Two major hydrogeochemical facies were identified such as mixed Ca-Mg-Cl and Ca-HCO₃ groups. The nutrients derived from agricultural runoff, urban discharge and organic decomposition alters the nutrient level in the groundwater. The dissolution/precipitation of minerals such as calcite and dolomite controls the chemical constituents of the groundwater. The multivariate statistical analysis indicates that natural weathering of source rocks is the main contributors of ions in the groundwater followed by anthropogenic activities such as agricultural practices and urbanization. The insights obtained from this study can be helpful for sustainable groundwater management and long-term monitoring studies.     

Hydrogeochemistry and groundwater quality in the coastal sandy clay aquifers of Alappuzha district, Kerala

Groundwater qualities of coastal aquifers in the Chennam-Pallippuram Panchayath of Alappuzha district, Kerala have been extensively monitored in summer from January to May, 2007 to assess its suitability in relation to domestic and agricultural uses. The water samples (n=36) were analyzed for various physico-chemical attributes like temperature, pH, electrical conductivity (EC), dissolved oxygen (DO), Na, K, Ca, Mg, alkalinity, hardness, silica, chloride, salinity, total dissolved solids (TDS) and sulphate (SO₄ ^2?). Values of most of these parameters fall within permissible limits. Major ionic relationships indicate that weathering reactions have insignificant role in the hydrochemical processes of the shallow groundwater system. Hydrogeochemical processes controlling the water chemistry are precipitation rather than rock-water interaction. Various determinants such as Sodium Absorption Ratio (SAR), Percent Sodium (Na %), Residual Sodium Carbonate (RSC), and Kelley’s Ratio revealed that most of the samples are suitable for irrigation.     

Hydrogeochemistry of coal mine water of North Karanpura coalfields,India: implication for solute acquisition processes,dissolved fluxes and water quality assessment

Mine water samples collected from different mines of the North Karanpura coalfields were analysed for pH, electrical conductivity, total dissolved solids (TDS), total hardness (TH), major anions, cations and trace metals to evaluate mine water geochemistry and assess solute acquisition processes, dissolved fluxes and its suitability for domestic, industrial and irrigation uses. Mine water samples are mildly acidic to alkaline in nature. The TDS ranged from 185 to 1343 mg L^?1 with an average of 601 mg L^?1. Ca²⁺ and Mg²⁺ are the dominant cations, while SO₄ ^2? and HCO₃ ^? are the dominant anions. A high concentration of SO₄ ^2? and a low HCO₃ ^?/(HCO₃ ^? + SO₄ ^2?) ratio (<0.50) in the majority of the water samples suggest that either sulphide oxidation or reactions involving both carbonic acid weathering and sulphide oxidation control solute acquisition processes. The mine water is undersaturated with respect to gypsum, halite, anhydrite, fluorite, aluminium hydroxide, alunite, amorphous silica and oversaturated with respect to goethite, ferrihydrite, quartz. About 40% of the mine water samples are oversaturated with respect to calcite, dolomite and jarosite. The water quality assessment shows that the coal mine water is not suitable for direct use for drinking and domestic purposes and needs treatment before such utilization. TDS, TH, F^?, SO₄ ^2?, Fe, Mn, Ni and Al are identified as the major objectionable parameters in these waters for drinking. The coal mine water is of good to suitable category for irrigation use. The mines of North Karanpura coalfield annually discharge 22.35 × 10⁶ m³ of water and 18.50 × 10³ tonnes of solute loads into nearby waterways.     

Environmental geochemistry and quality assessment of surface and subsurface water of Mahi River basin, western India

The hydrogeochemical study of surface and subsurface water of Mahi River basin was undertaken to assess the major ion chemistry, solute acquisition processes and water quality in relation to domestic and irrigation uses. The analytical results show the mildly acidic to alkaline nature of water and dominance of Na⁺ and Ca²⁺ in cationic and HCO₃ ⁻ and Cl⁻ in anionic composition. In general, alkaline-earth elements (Ca²⁺ + Mg²⁺) exceed alkalis (Na⁺ + K⁺) and weak acids (HCO₃ ⁻) dominate over strong acids (SO₄ ²⁺ + Cl⁻) in majority of the surface and groundwater samples. Ca²⁺–Mg²⁺–HCO₃ ⁻ is the dominant hydrochemical facies both in surface and groundwater of the area. The weathering of rock-forming minerals mainly controlled the solute acquisition process with secondary contribution from marine and anthropogenic sources. The higher concentration of sodium and dissolved silica, high equivalent ratios of (Na⁺ + K⁺/TZ⁺), (Na⁺ + K⁺/Cl⁻) and low ratio of (Ca²⁺ + Mg²⁺)/(Na⁺ + K⁺) suggest that the chemical composition of the water is largely controlled by silicate weathering with limited contribution from carbonate weathering and marine and anthropogenic sources. Kaolinite is the possible mineral that is in equilibrium with the water, implying that the chemistry of river water favors kaolinite formation. Assessment of water samples for drinking purposes suggests that the majority of the water samples are suitable for drinking. At some sites concentrations of TDS, TH, F⁻, NO₃ ⁻ and Fe are exceeding the desirable limit of drinking. However, these parameters are well within the maximum permissible limit except for some cases. To assess the suitability for irrigation, parameters like SAR, RSC and %Na were calculated. In general, both surface and groundwater is of good to suitable category for irrigation uses except at some sites where high values of salinity, %Na and RSC restrict its uses.     

Earth Observations based Conservation Prioritization in Western Ghats,India

Earth Observation with large suite of sensors and with capabilities to address natural resources at multiple scales has proven to be a critical resource in setting conservation priorities of a region. The role of earth observation data was recognized towards achieving international biodiversity targets by 2020. Ecosystem irreplaceability and ecosystem vulnerability are two concepts key to understanding and preparing conservation priority maps. This study presents spatial conservation prioritization analysis for forests of ‘Western Ghats biodiversity hotspot’. Earth observation data products have been used for prioritization of areas of irreplaceability and vulnerability that are significant for conservation planning. The spatial surrogates of biodiversity in terms of very dense forest, biological richness, intactness and rarity of habitat are analyzed for evaluation of ecosystem irreplaceability. Fragmentation, forest fires, plant invasion and disturbance index are surrogates included for spatial analysis of ecosystem vulnerability. Vegetation type wise analysis indicates dry deciduous forests are under high vulnerability, followed by moist deciduous forests. The high concentration of irreplaceability is observed in Shola followed by wet evergreen forests and semi-evergreen forests. Spatial prioritization approach has identified about 18% of the forest area as irreplaceable which represents overlapped area of very dense forest, shola, intact forest and high biological richness. We observed that the overlap of forest areas of irreplaceability with vulnerability in southern Western Ghats, which needs high priority of conservation. This study is the first of its kind wherein multi-source earth observation data has been analysed to examine the quantitative criteria at regional level in Western Ghats.     

Impact of Rainfall Variability on River Hydrology: A Case Study of Southern Western Ghats,India

The Western Ghats plays a pivotal role in determining the hydrological and hydroclimatic regime of Peninsular India. The mountainous catchments of the Ghats are the primary contributors of flow in the rivers that sustains the life and agricultural productivity in the area. Although many studies have been conducted in the past decades to understand long term trends in the meteorological and hydrological variables of major river basins, not much attention have been made to unfold the relationship existing among rainfall and river hydrology of natural drainages on either side of the Western Ghats which host one of the unique biodiversity hotspots across the world. Therefore, an attempt has been made in this paper to examine the short term (last three decades) changes in the rainfall pattern and its influence on the hydrological characteristics of some of the important rivers draining the southern Western Ghats as a case study. The short term, annual and seasonal trends in the rainfall, and its variability and discharge were analyzed using Mann-Kendall test and Sen’s estimator of slope. The study showed a decreasing trend in rainfall in the southwest monsoon while a reverse trend is noticed in northeast monsoon. Correspondingly, the discharge of the west and east flowing rivers also showed a declining trend in the southwest monsoon season. The runoff coefficient also followed the trends in the discharge. The runoff coefficient of the Periyar river showed a decreasing trend, whereas the Cauvery river exhibited an increasing trend. A high-resolution analysis of rainfall data revealed that the number of moderate rainfall events showed a decreasing trend throughout the southern Western Ghats, whereas the high intensity rainfall events showed an opposite trend. The decline in groundwater level in the areas which recorded an increase in high intensity rainfall events and decrease in moderate rainfall events showed that the groundwater recharge process is significantly affected by changes in the rainfall pattern of the area.     

Hydrogeochemical assessment of groundwater quality along the coastal aquifers of southern Tamil Nadu,India

Hydrogeochemical investigation of groundwater has been carried out in the coastal aquifers of southern Tamil Nadu, India. Seventy-nine dug well samples were collected and analyzed for various physicochemical parameters. The result of the geochemical analysis indicates the groundwater in the study area is slightly alkaline with moderate saline water. The cation and anion concentrations confirm most of the groundwater samples belong to the order of Na⁺ > Mg²⁺ > Ca²⁺ > K⁺ and Cl^? > SO₄ ^2? > HCO₃ ^?. Thereby three major hydrochemical facies (Ca–Cl, mixed Ca–Mg–Cl and Na–Cl) were identified. Based on the US Salinity diagram, majority of the samples fall under medium to very high salinity with low to high sodium hazard. The cross plot of Ca²⁺ + Mg²⁺ versus chloride shows 61 % of the samples fall under saline water category. Higher EC, TDS and Cl concentrations were observed from Tiruchendur to Koodankulam coastal zone. It indicates that these regions are significantly affected by saltwater contamination due to seawater intrusion, saltpan deposits, and beach placer mining activities.     

Application of Archimedean copulas to the impact assessment of hydro-climatic variables in semi-arid aquifers of western India

The effects of rainfall and the El Niño Southern Oscillation (ENSO) on groundwater in a semi-arid basin of India were analyzed using Archimedean copulas considering 17 years of data for monsoon rainfall, post-monsoon groundwater level (PMGL) and ENSO Index. The evaluated dependence among these hydro-climatic variables revealed that PMGL-Rainfall and PMGL-ENSO Index pairs have significant dependence. Hence, these pairs were used for modeling dependence by employing four types of Archimedean copulas: Ali-Mikhail-Haq, Clayton, Gumbel-Hougaard, and Frank. For the copula modeling, the results of probability distributions fitting to these hydro-climatic variables indicated that the PMGL and rainfall time series are best represented by Weibull and lognormal distributions, respectively, while the non-parametric kernel-based normal distribution is the most suitable for the ENSO Index. Further, the PMGL-Rainfall pair is best modeled by the Clayton copula, and the PMGL-ENSO Index pair is best modeled by the Frank copula. The Clayton copula-based conditional probability of PMGL being less than or equal to its average value at a given mean rainfall is above 70% for 33% of the study area. In contrast, the spatial variation of the Frank copula-based probability of PMGL being less than or equal to its average value is 35–40% in 23% of the study area during El Niño phase, while it is below 15% in 35% of the area during the La Niña phase. This copula-based methodology can be applied under data-scarce conditions for exploring the impacts of rainfall and ENSO on groundwater at basin scales.     

Hydrogeology,water quality,and microbial assessment of a coastal alluvial aquifer in western Saudi Arabia: potential use of coastal wadi aquifers for desalination water supplies

Wadi alluvial aquifers located along coastal areas of the Middle East have been assumed to be suitable sources of feed water for seawater reverse osmosis facilities based on high productivity, connectedness to the sea for recharge, and the occurrence of seawater with chemistry similar to that in the adjacent Red Sea. An investigation of the intersection of Wadi Wasimi with the Red Sea in western Saudi Arabia has revealed that the associated predominantly unconfined alluvial aquifer divides into two sand-and-gravel aquifers at the coast, each with high productivity (transmissivity?=?42,000 m²/day). This aquifer system becomes confined near the coast and contains hypersaline water. The hydrogeology of Wadi Wasimi shows that two of the assumptions are incorrect in that the aquifer is not well connected to the sea because of confinement by very low hydraulic conductivity terrigenous and marine muds and the aquifer contains hypersaline water as a result of a hydraulic connection to a coastal sabkha. A supplemental study shows that the aquifer system contains a diverse microbial community composed of predominantly of Proteobacteria with accompanying high percentages of Gammaproteobacteria, Alphaproteobacteria and Deltaproteobacteria.     

Water level variations in fractured,semi-confined aquifers of Anantapur district,Southern India

The study on water level conditions of fractured aquifer system in northeastern part of Anantapur district is of immense importance as the area is covered by varied geological formations and has different irrigation patterns. The monthly groundwater level data of 154 observation wells for five year period (2001–06) is analyzed to decipher the behavior of water levels in different seasons and geo-environments. The hydrographs of the average water level data of each Mandal (group of villages) indicate steady declining trend ranging from 0.50 to 2.91m/yr. Yellanuru Mandal has both the shallowest and the deepest water levels among eight Mandals, highly undulating terrain could be one of the reasons for this contrasting condition. The pre-monsoon water levels show decline of 8.22 m in one year from May 2002 to 2003. A negative seasonal fluctuation of ?1.49m has occurred in the year 2002 during which the area received 32% less than normal rainfall. The mean water levels are deeper by 42% in areas covered by sedimentary formations than those of granite terrain. Raise in water levels is significant where monthly rainfall is more than 200 mm. Due to erratic rainfall in space and time, deeper water levels are noticed even in post-monsoon period and shallow in February month at some locations. The water levels in command areas are deep and exhibit falling trend as the area forms the tail end part of the Tunga Bhadra High Level Canal. The deeper water level conditions and its declining feature is directly related to groundwater development in the form of increased agriculture activity, reduced area under rain-fed crops, high horticulture development. Arid climatic conditions, low precipitation and continuous exploitation of groundwater resources could be other factors contributing for steady decline in water levels in the area. The wide variations in groundwater levels could be due to uneven topography, heterogeneous and anisotropic conditions of granites and poor porosity — permeability of shales, lack of vegetation, and increased groundwater extraction.     

Springs in a headwater basin in the Deccan Trap country of the Western Ghats, India

Available literature reveals that little work has been done on the origin of springs in a basaltic terrain. Close examination of such springs in about 2,000 km² of the upper Koyna River basin in the Deccan Trap country of the Western Ghats (hills), India, reveals that their origins are dependent on the lithologic character of different basaltic flow units and the existing physiography. Although rainfall, its seasonality and areas of recharge, play vital roles in the recharge of these springs, their yields are also controlled by lithological variations and hydraulic characteristics of their source-aquifers. Chemical concentrations of these springs are heavily dependent on the lithological compositions of the source-aquifers and the residence time of groundwater in these aquifers. Currently, basaltic springs are classified with those issuing from other terrains. However, because the emergence of groundwater in the form of springs is largely controlled by the lithology and the resulting water-bearing properties of the formations, a new classification scheme is proposed that classifies the springs on the basis of their source-aquifers. While tapping springs for drinking/irrigation purposes, it must be remembered that they also sustain thousands of other life forms vital to a balanced ecosystem. Changes in the uses of these springs may also affect other human communities downstream. Therefore, before developing spring flow, a trade-off must be made considering local needs and downstream users. Emphasizing only local human needs may lead to severe intercommunity conflict and negative environmental consequences. Electronic Publication     

Hydrogeochemistry of the Koyna River basin,India

Hydrogeochemistry of the Koyna River basin, famous for the Koyna earthquake (magnitude 7) of 1967, has been studied. Basalt is the primary aquifer; laterites, alluvium, and talus deposits form aquifers of secondary importance. Groundwater generally occurs under water table conditions in shallow aquifers. Deeper aquifers are associated only with basalts. One hundred and 87 water samples were collected from various sources, such as dugwells, borewells, springs, and surface water, including 40 samples for analysis of iron. Only major constituents were analyzed. Analyses show that the concentrations of Ca²⁺ exceed that of Mg²⁺ in almost all water samples; the concentrations of Na⁺ are generally next to Ca²⁺ and are always higher than that of K⁺; and CO₃ ^2– and SO₄ ^2– are very low and are often negligible. Groundwater in borewells tapping deeper aquifers has higher mineralization compared to that in dugwells representing shallow aquifers. Majority of the water samples are dominated by alkaline earths (Ca²⁺, Mg²⁺) and weak acids (HCO₃ ⁻, CO₃ ^2–). Groundwater from shallow aquifers is generally calcium-bicarbonate type (53%) and calcium-magnesium-bicarbonate type (27%). In case of deeper aquifer, it is mostly calcium-magnesium-bicarbonate type (29%), sodium-bicarbonate type (24%), calcium-bicarbonate type (19%), calcium-magnesium-sodium-bicarbonate type (19%) and sodium-calcium-bicarbonate type (9%). Groundwater water is generally fit for drinking and irrigation purposes, except in the lower reaches of the Koyna River basin, which is affected by near water logging conditions.     

Geographical Information System based assessment of spatiotemporal characteristics of groundwater quality of upland sub-watersheds of Meenachil River,parts of Western Ghats,Kottayam District,Kerala, India

Hydrogeochemistry of groundwater in upland sub-watersheds of Meenachil river, parts of Western Ghats, Kottayam, Kerala, India was used to assess the quality of groundwater for determining its suitability for drinking and agricultural purposes. The study area is dominated by rocks of Archaean age, and Charnonckite is dominated over other rocks. Rubber plantation dominated over other types of the vegetation in the area. Though the study area receives heavy rainfall, it frequently faces water scarcity as well as water quality problems. Hence, a Geographical Information System (GIS) based assessment of spatiotemporal behaviour of groundwater quality has been carried out in the region. Twenty-eight water samples were collected from different wells and analysed for major chemical constituents both in monsoon and post-monsoon seasons to determine the quality variation. Physical and chemical parameters of groundwater such as pH, dissolved oxygen (DO), total hardness (TH), chloride (Cl), nitrate (NO₃) and phosphate (PO₄) were determined. A surface map was prepared in the ArcGIS 8.3 (spatial analyst module) to assess the quality in terms of spatial variation, and it showed that the high and low regions of water quality varied spatially during the study period. The influence of lithology over the quality of groundwater is negligible in this region because majority of the area comes under single lithology, i.e. charnockite, and it was found that the extensive use of fertilizers and pesticides in the rubber, tea and other agricultural practices influenced the groundwater quality of the region. According to the overall assessment of the basin, all the parameters analysed are below the desirable limits of WHO and Indian standards for drinking water. Hence, considering the pH, the groundwater in the study area is not suitable for drinking but can be used for irrigation, industrial and domestic purposes. The spatial analysis of groundwater quality patterns of the study area shows seasonal fluctuations and these spatial patterns of physical and chemical constituents are useful in deciding water use strategies for various purposes.