Large in‐stream wood studies: a call for common metrics

During the past decade, research on large in‐stream wood has expanded beyond North America's Pacific Northwest to diverse environments and has shifted toward increasingly holistic perspectives that incorporate processes of wood recruitment, retention, and loss at scales from channel segments to entire watersheds. Syntheses of this rapidly expanding literature can be facilitated by agreement on primary variables and methods of measurement. In this paper we address these issues by listing the variables that we consider fundamental to studies of in‐stream wood, discussing the sources of variability in their measurement, and suggesting more consistency in future studies. We recommend 23 variables for all studies of in‐stream wood, as well as another 12 variables that we suggest for studies with more specific objectives. Each of these variables relates either to the size and characteristics of in‐stream wood, to the geomorphic features of the channel and valley, or to the ecological characteristics of the riparian zone adjacent to the study reach. The variables were derived from an overview of those cited in the literature and from our collective field experiences. Copyright © 2010 John Wiley & Sons, Ltd.     

Field application of close‐range digital photogrammetry (CRDP) for grain‐scale fluvial morphology studies

In situ measurement of grain‐scale fluvial morphology is important for studies on grain roughness, sediment transport and the interactions between animals and the geomorphology, topics relevant to many river practitioners. Close‐range digital photogrammetry (CRDP) and terrestrial laser scanning (TLS) are the two most common techniques to obtain high‐resolution digital elevation models (DEMs) from fluvial surfaces. However, field application of topography remote sensing at the grain scale is presently hindered mainly by the tedious workflow challenges that one needs to overcome to obtain high‐accuracy elevation data. A recommended approach for CRDP to collect high‐resolution and high‐accuracy DEMs has been developed for gravel‐bed flume studies. The present paper investigates the deployment of the laboratory technique on three exposed gravel bars in a natural river environment. In contrast to other approaches, having the calibration carried out in the laboratory removes the need for independently surveyed ground‐control targets, and makes for an efficient and effective data collection in the field. Optimization of the gravel‐bed imagery helps DEM collection, without being impacted by variable lighting conditions. The benefit of a light‐weight three‐dimensional printed gravel‐bed model for DEM quality assessment is shown, and confirms the reliability of grain roughness data measured with CRDP. Imagery and DEM analysis evidences sedimentological contrasts between gravel bars within the reach. The analysis of the surface elevations shows the effect variable grain‐size and sediment sorting have on the surface roughness. By plotting the two‐dimensional structure functions and surface slopes and aspects we identify different grain arrangements and surface structures. The calculation of the inclination index allows determining the surface‐forming flow direction(s). We show that progress in topography remote sensing is important to extend our knowledge on fluvial morphology processes at the grain scale, and how a technique customized for use by fluvial geomorphologists in the field benefits this progress. Copyright © 2016 John Wiley & Sons, Ltd.     

Coprecipitation with Cu(II)‐4‐(2‐Pyridylazo)‐resorcinol for Separation and Preconcentration of Fe(III) and Ni(II) in Water and Food Samples

The coprecipitation method is widely used for the preconcentration of trace metal ions prior to their determination by flame atomic absorption spectrometry (FAAS). A simple and sensitive method based on coprecipitation of Fe(III) and Ni(II) ions with Cu(II)‐4‐(2‐pyridylazo)‐resorcinol was developed. The analytical parameters including pH, amount of copper (II), amount of reagent, sample volume, etc., were examined. It was found that the metal ions studied were quantitatively coprecipitated in the pH range of 5.0–6.5. The detection limits (DL) (n = 10, 3s/b) were found to be 0.68 µg L^?1 for Fe(III) and 0.43 µg L^?1 for Ni(II) and the relative standard deviations (RSD) were ≤4.0%. The proposed method was validated by the analysis of three certified reference materials (TMDA 54.4 fortified lake water, SRM 1568a rice flour, and GBW07605 tea) and recovery tests. The method was successfully applied to sea water, lake water, and various food samples.     

Severe soil erosion during a 3‐day exceptional rainfall event: combining modelling and field data for a fallow cereal field

Exceptional rainfall events cause significant losses of soil, although few studies have addressed the validation of model predictions at field scale during severe erosive episodes. In this study, we evaluate the predictive ability of the enhanced Soil Erosion and Redistribution Tool (SERT‐2014) model for mapping and quantifying soil erosion during the exceptional rainfall event (~235 mm) that affected the Central Spanish Pyrenees in October 2012. The capacity of the simulation model is evaluated in a fallow cereal field (1.9 ha) at a high spatial scale (1 × 1 m). Validation was performed with field‐quantified rates of soil loss in the rills and ephemeral gullies and also with a detailed map of soil redistribution. The SERT‐2014 model was run for the six rainfall sub‐events that made up the exceptional event, simulating the different hydrological responses of soils with maximum runoff depths ranging between 40 and 1017 mm. Predicted average and maximum soil erosion was 11 and 117 Mg ha^?1 event^?1, respectively. Total soil loss and sediment yield to the La Reina gully amounted to 16.3 and 9.0 Mg event^?1. These rates are in agreement with field estimations of soil loss of 20.0 Mg event^?1. Most soil loss (86%) occurred during the first sub‐event. Although soil accumulation was overestimated in the first sub‐event because of the large amount of detached soil, the enhanced SERT‐2014 model successfully predicted the different spatial patterns and values of soil redistribution for each sub‐event. Further research should focus on stream transport capacity. Copyright © 2014 John Wiley & Sons, Ltd.     

Influence of Surfactants on Degradation of 1‐(2‐Chlorobenzoyl)‐3‐(4‐chlorophenyl) Urea by Nanoscale Zerovalent Iron

Nanoscale zerovalent iron (NZVI) has been proved to be effective in the degradation of environmental pollutants and exhibits advantages in the removal of 1‐(2‐chlorobenzoyl)‐3‐(4‐chlorophenyl) urea (CCU), an analog of diflubenzuron. This present study focused on the influence of surfactants in the degradation procedure with NZVI in order to provide a simple and rapid removal method for CCU. Triton X‐100, Tween 20, Tween 80, sodium dodecyl sulfonate (SDS), and cetyltrimethylammonium bromide (CTAB) were investigated under anaerobic conditions. The experimental results demonstrated that the degradation rate increased sharply with the presence of SD during the first 15 min, up to 99.97% with addition of 0.01 g L^?1 SDS, whereas the presence of Triton X‐100, Tween 80, and Tween 20 resulted in a slight enhancement of the degradation of CCU. The enhancement strength of them was in the order Tween 20, Triton X‐100, and Tween 80. However, addition of the cationic surfactant CTAB resulted in a significant inhibitive effect. In contrast, the mixed surfactants did not result in the expected performance, and the performance was lower than that using some certain single surfactant among the mixed surfactants.     

Evaluation of Zerovalent Zinc for Treatment of 1,2,3‐Trichloropropane‐Contaminated Groundwater: Laboratory and Field Assessment

The efficacy and feasibility of using zerovalent zinc (ZVZ) to treat 1,2,3‐trichloropropane (TCP)‐contaminated groundwater was assessed in laboratory and field experiments. In the first portion of the study, the reactivity of commercially available granular ZVZ toward TCP was measured in bench‐scale batch‐reactor and column experiments. These results were used to design columns for on‐site pilot‐scale treatment of contaminated groundwater at a site in Southern California. Two of the ZVZ materials tested were found to produce relatively high rates of TCP degradation as well as predictable behavior when scaling from bench‐scale to field testing. In addition, there was little decrease in the rates of TCP degradation over the duration of field testing. Finally, no secondary impacts to water quality were identified. The results suggest that ZVZ may be an effective and feasible material for use in engineered treatment systems, perhaps including permeable reactive barriers.     

Stereophotogrammetry of archive data and topographic approaches to debris‐flow torrent measurements: calculation of channel‐sediment states and a partial sediment budget for Manival torrent (Isère,France)

This paper focuses on a topographic methodology to characterize the amount of sediment stored in channels and the use of historical photographs for aerial survey by stereophotogrammetry, as part of wider research on debris‐flow magnitude prediction. The topographic methodology uses equidistant four‐point cross‐sections along the long profile of the channel. Each cross‐section is representative of a 50‐m reach of the channel. To calculate the volume of each reach, the difference is calculated between a reference level and the topographic surface. The reference level is the lowest level where the debris flow can erode, and in the current method this level is estimated from fixed points along the long profile of the channel. The accuracy of the method has been estimated by comparing results of a detailed topographic survey, with a standard deviation corresponding to about 6 per cent of the total calculated sediment volume. This topographic methodology has been used on aerial photographs by photogrammetry. This tool was applied to photographs taken on 12 past dates. The scales of the archive photographs used range from 1:3000 to 1:30 000, but results are consistent and permit us to calculate sediment states of the channel for different past dates with an uncertainty of about 6 per cent of the total volume. The application of the technique to the Manival debris‐flow torrent has permitted us to propose some partial sediment budgets and erosion‐rate estimates. Copyright © 2006 John Wiley & Sons, Ltd.     

Seismic performance of a 1 : 15‐scale 25‐story RC flat‐plate core‐wall building model

Earthquake simulation tests were conducted on a 1 : 15‐scale 25‐story building model to verify the seismic performance of high‐rise reinforced‐concrete flat‐plate core‐wall building structures designed per the recent seismic code KBC 2009 or IBC 2006. The following conclusions can be drawn from the test results: (1) The vertical distribution of acceleration during the table excitations revealed the effect of the higher modes, whereas free vibration after the termination of the table excitations was governed by the first mode. The maximum values of base shear and roof drift during the free vibration are either similar to or larger than the values of the maximum responses during the table excitation. (2) With a maximum roof drift ratio of 0.7% under the maximum considered earthquake in Korea, the lateral stiffness degraded to approximately 50% of the initial stiffness. (3) The crack modes appear to be a combination of flexure and shear in the slab around the peripheral columns and in the coupling beam. Energy dissipation via inelastic deformation was predominant during free vibration after the termination of table excitation rather than during table excitation. Finally, (4) the walls with special boundary elements in the first story did not exhibit any significant inelastic behavior, with a maximum curvature of only 21% of the ultimate curvature, corresponding to an ultimate concrete compressive strain of 0.00638 m/m intended in the displacement‐based design approach. Copyright © 2014 John Wiley & Sons, Ltd.     

A new technique for non‐destructive field measurement of rock‐surface strength: an application of the Equotip hardness tester to weathering studies

Tafone‐like depressions have developed on the Aoshima sandstone blocks used for a masonry bridge pier in the coastal spray zone. A thin layer of partial granular disintegration was found on the surface in depressions. To evaluate quantitatively the strength of the thin weathered layer, the hardness was measured at the surface of the sandstone blocks using both an Equotip hardness tester and an L‐type Schmidt hammer. Comparison of the two testing results indicates that the Equotip hardness value is more sensitive in evaluating the strength of a thin layer of weathered surface rock than the Schmidt hardness value. By applying two methods, i.e. both the repeated impact method and the single impact method, the Equotip tester can evaluate the strengths of fresh internal and weathered surficial portions of rocks having a thin weathering layer. Comparison of the two strengths enables evaluation of strength reduction due to weathering. Copyright © 2007 John Wiley & Sons, Ltd.     

Synthesis and Characterization of Poly(2‐hydroxyethylmethacrylate‐hydroxyapatite) a Novel Composite for the Removal of Lead(II) from Aqueous Solutions

In the present study, a novel adsorbent, poly (2‐hydroxyethylmethacrylate‐hydroxyapatite) [P(HEMA‐Hap)], was prepared and characterized. The synthesis was achieved by means of free‐radical polymerization and a number of structural characterization methods, including FT‐IR, XRD, TGA, SEM, BET‐porosity, and swelling tests. Pb²⁺ adsorption was performed using a series of pH, time, and temperature ranges. The reusability of the composite was also tested. The results obtained indicated that the novel adsorbent is able to bind Pb²⁺ ions with strong chemical affinity. The adsorption results were fitted to the classic Langmuir, Freundlich, and Dubinin–Radushkevich (D–R) sorption models. Thermodynamic parameters obtained demonstrated that the sorption process was spontaneous (ΔG < 0), endothermic (ΔH > 0), as expected. The process was also consistent with the pseudo‐second‐order model, and chemical adsorption was determined to be the rate‐controlling step. It was also shown that the composite could be used for five consecutive adsorption processes.     

Case studies of damage to 19‐storey irregular steel moment‐frame buildings under near‐source ground motion

This paper describes the three‐dimensional nonlinear analysis of six 19‐storey steel moment‐frame buildings, designed per the 1997 Uniform Building Code, under strong ground motion records from near‐source earthquakes with magnitudes in the range of 6.7–7.3. Three of these buildings possess a reentrant corner irregularity, while the remaining three possess a torsional plan irregularity. The records create drift demands of the order of 0.05 and plastic rotation demands of the order of 4–5% of a radian in the buildings with reentrant corners. These values point to performance at or near ‘Collapse Prevention’. Twisting in the torsionally sensitive buildings causes the plastic rotations on the moment frame on one face of the building (4–5% of a radian) to be as high as twice of that on the opposite face (2–3% of a radian). The asymmetric yield pattern implies a lower redundancy in the lateral force‐resisting system as the failure of the heavily loaded frame could result in a total loss of resistance to torsion. Copyright © 2006 John Wiley & Sons, Ltd.     

Assessment of focal mechanisms of microseismic events computed from two three‐component receivers: application to the Arkema‐Vauvert field (France)

We have developed a method that enables computing double‐couple focal mechanisms with only a few sensors. This method is based on a non‐linear inversion of the P, Sv and Sh amplitudes of microseismic events recorded on a set of sensors. The information brought by the focal mechanism enables determining the geometry of the rupture on the associated geological structure. It also provides a better estimate of the conventional source parameters. Full analysis has been performed on a data set of 15 microseismic events recorded in the brine production field of Vauvert. The microseismic monitoring network consisted of two permanent tools and one temporary borehole string. The majority of the focal mechanisms computed from both permanent tools are similar to those computed from the whole network. This result indicates that the double‐couple focal mechanism determination is reliable for both permanent 3C receivers in this field.     

Range imaging: a new method for high‐resolution topographic measurements in small‐ and medium‐scale field sites

Topographic measurements are essential for the study of earth surface processes. Three‐dimensional data have been conventionally obtained through terrestrial laser scanning or photogrammetric methods. However, particularly in steep and rough terrain, high‐resolution field measurements remain challenging and often require new creative approaches. In this paper, range imaging is evaluated as an alternative method for obtaining surface data in such complex environments. Range imaging is an emerging time‐of‐flight technology, using phase shift measurements on a multi‐pixel sensor to generate a distance image of a surface. Its suitability for field measurements has yet not been tested. We found ambient light and surface reflectivity to be the main factors affecting error in distance measurements. Low‐reflectivity surfaces and strong illumination contrasts under direct exposure to sunlight lead to noisy distance measurements. However, regardless of lighting conditions, the accuracy of range imaging was markedly improved by averaging multiple images of the same scene. For medium ambient lighting (shade) and a light‐coloured surface the measurement uncertainty was approximately 9 mm. To further test the suitability of range imaging for field applications we measured a reach of a steep mountain stream with a horizontal resolution of approximately 1 cm (in the focal plane of the camera), allowing for the interpolation of a digital elevation model on a 2 cm grid. Comparison with an elevation model obtained from terrestrial laser scanning for the same site revealed that both models show similar degrees of topographic detail. Despite limitations in measurement range and accuracy, particularly at bright ambient lighting, range imaging offers three‐dimensional data in real time and video mode without the need of post‐processing. Therefore, range imaging is a useful complement or alternative to existing methods for high‐resolution measurements in small‐ to medium‐scale field sites. Copyright © 2012 John Wiley & Sons, Ltd.