Hydrological and catchment controls on event-scale dissolved organic carbon dynamics in boreal headwater streams

Hydrological events transport large proportions of annual or seasonal dissolved organic carbon (DOC) loads from catchments to streams. The timing, magnitude and intensity of these events are very sensitive to changes in temperature and precipitation patterns, particularly across the boreal region where snowpacks are declining and summer droughts are increasing. It is important to understand how landscape characteristics modulate event-scale DOC dynamics in order to scale up predictions from sites across regions, and to understand how climatic changes will influence DOC dynamics across the boreal forest. The goal of this study was to assess variability in DOC concentrations in boreal headwater streams across catchments with varying physiographic characteristics (e.g., size, proportion of wetland) during a range of hydrological events (e.g., spring snowmelt, summer/fall storm events). From 2016 to 2017, continuous discharge and sub-daily chemistry grab samples were collected from three adjacent study catchments located at the International Institute for Sustainable Development-Experimental Lakes Area in northwestern Ontario, Canada. Catchment differences were more apparent in summer and fall events and less apparent during early spring melt events. Hysteresis analysis suggested that DOC sources were proximal to the stream for all events at a catchment dominated by a large wetland near the outlet, but distal from the stream at the catchments that lacked significant wetland coverage during the summer and fall. Wetland coverage also influenced responses of DOC export to antecedent moisture; at the wetland-dominated catchment, there were consistent negative relationships between DOC concentrations and antecedent moisture, while at the catchments without large wetlands, the relationships were positive or not significant. These results emphasize the utility of sub-daily sampling for inferring catchment DOC transport processes, and the importance of considering catchment-specific factors when predicting event-scale DOC behaviour.     

Defining hydrochemical evolution of streamflow through flowpath dynamics in Kawakami headwater catchment,Central Japan

The hydrochemical behaviour of catchments is often investigated by inferring stream chemistry through identification of source areas involved in hydrograph separation analysis, yet its dynamic evolution of hydrologic pathways has received little attention. Intensive hydrometric and hydrochemical measurements were performed during two different storms on March 29, 2001 and August 21–22, 2001 to define hydrochemical evolution under the dynamic of flow pathways in a 5·2 ha first‐order drainage of the Kawakami experimental basin (KEB), Central Japan, a forested headwater catchment with various soil depths (1·8 to 5 m) overlying late Neogene of volcanic bedrocks. The hydraulic potential distribution and flow lines data showed that the change in flow direction, which was controlled by rainfall amount and antecedent wetness of the soil profile, agreed well with the hydrochemical change across the slope segment during the storm. Hydrograph separation predicted by end‐member mixing analysis (EMMA) using Ca²⁺ and SiO₂ showed that near surface riparian, hillslope soil water and deep riparian groundwater were important in stream flow generation. The evidence of decrease in solutes concentration at a depth of 1 m in the hillslope and 0·6 m in the near surface riparian during peak storm suggested a flushing of high solutes concentration. Most of the solutes accumulated in the deep riparian groundwater zone, which was due to prominent downward flow and agreed well with the residence time. The distinct flow pathways and chemistry between the near surface riparian and deep riparian groundwater zones and the linkage hillslope aquifer and near surface riparian reservoir, which controls rapid flow and solutes flushing during the storm event, are in conflict with the typical assumption that the whole riparian zone resets flow pathways and chemical signature of hillslope soil water, as has been reported in a previous study. Copyright © 2005 John Wiley & Sons, Ltd.     

Hydrological control of dissolved organic carbon dynamics in a forested headwater catchment,Kiryu Experimental Watershed,Japan

To evaluate the influence of hydrological processes on dissolved organic carbon (DOC) dynamics in a forested headwater catchment, DOC concentration was observed along the flow path from rainfall to stream water via throughfall, soil water, groundwater, and spring water for 4 years, and DOC flux through the catchment was calculated. The spatial and temporal variations in DOC concentration and flux were compared with physical hydrological observations and the mean residence time of water. In the upslope soil layer, DOC concentrations were not significantly correlated with water fluxes, suggesting that DOC concentrations were not strictly controlled by water fluxes. In the upslope perennial groundwater, DOC concentration was affected by the change in the amount of microbial degradation of DOC produced by changes in the mean residence time of water. In stream water, the temporal variation in DOC concentration was usually affected by changes in DOC concentration of the inflow component via vertical infiltration from above the perennial groundwater. During dry periods, however, the component from inflow via vertical infiltration was negligible and DOC in the upslope perennial groundwater became the major component of stream water DOC. The temporal variation in stream water DOC concentration during baseflow was affected by rainfall patterns over several preceding months. Therefore, records of rainfall over several preceding months are one of the most important factors for predicting changes in DOC concentration on a catchment scale. Copyright © 2007 John Wiley & Sons, Ltd.     

Searching for similarity in topographic controls on carbon,nitrogen and phosphorus export from forested headwater catchments

Topography influences hydrological processes that in turn affect biogeochemical export to surface water on forested landscapes. The differences in long‐term average annual dissolved organic carbon (DOC), organic and inorganic nitrogen [NO₃^?‐N, dissolved organic nitrogen (DON)], and phosphorus (total dissolved phosphorus, TDP) export from catchments in the Algoma Highlands of Ontario, Canada, with similar climate, geology, forest and soil were established. Topographic indicators were designed to represent topographically regulated hydrological processes that influence nutrient export, including (1) hydrological storage potential (i.e. effects of topographic flats/depressions on water storage) and (2) hydrological flushing potential (i.e. effects of topographic slopes on potential for variable source area to expand and tap into previously untapped areas). Variations in NO₃^?‐N export among catchments could be explained by indicators representing both hydrological flushing potential (91%, p < 0.001) and hydrological storage potential (65%, p < 0.001), suggesting the importance of hydrological flushing in regulating NO₃^?‐N export as well as surface saturated areas in intercepting NO₃^?‐N‐loaded runoff. In contrast, hydrological storage potential explained the majority of variations among catchments in DON (69%, p < 0.001), DOC (94%, p < 0.001) and TDP (82%, p < 0.001) export. The lower explanatory power of DON (about 15% less) compared with that of DOC and TDP suggests another mechanism influencing N export, such as controls related to alternative fates of nitrogen (e.g. as gas). This study shows that simple topographic indicators can be used to track nutrient sources, sinks and their transport and export to surface water from catchments on forest landscapes. Copyright © 2013 John Wiley & Sons, Ltd.     

Phosphorus storage,transport and export dynamics in the Foron River watershed

Phosphorus (P) export from the Foron River watershed was intensively monitored. Water was analysed for total P, soluble total P, soluble orthophosphate and suspended solids. Watershed soils and river sediments were sampled and the size fraction <0·2 mm analysed for total P, water extractable P, bioavailable P, 1 minute exchangeable P and P fixation capacity. Interstitial waters were analysed for soluble total P. Four hydrological conditions recurred, two during low river flows and two during increased flow. The first occurs in dry weather with a constant or decreasing flow over at least seven days and when there is no surface runoff. Exported phosphorus, predominately soluble and bioavailable, is from point sources. Phosphorus inputs exceed P export so P accumulates in the river. The second condition occurs when a small storm flow increases the average seven-day flow to exceed the preceding weekly average. Phosphorus export exceeds P inputs and originates from urban runoff, point sources and release of P stored in the river. Exported P is largely particulate but highly bioavailable. The third condition is when substantial runoff follows at least a seven-day period of constant or decreasing flow. Phosphorus export is from diffuse urban runoff. All the P stored is exported. Exported P is highly bioavailable. High concentrations and fluxes of P export are often seen. The fourth condition happens when the soils are wet and increased flow is from both urban and agricultural runoff. Phosphorus export from diffuse agricultural runoff predominates and is largely not bioavailable. Phosphorus concentrations are low but export fluxes are high when flows are high. These hydrological conditions, when integrated with concepts of mass balance define a phosphorus export typology comprising four regimes. These regimes explain total phosphorus (TP) storage, transport and export patterns, changes in P speciation and allow identification of probable sources of TP in the Foron river watershed. © 1998 John Wiley & Sons, Ltd.     

Variability of particulate (SS,POC) and dissolved (DOC,NO3) matter during storm events in the Alegria agricultural watershed

The temporal variability of suspended sediment, nitrates (NO₃) and dissolved (DOC) and particulate organic carbon concentrations was analysed in the Alegria agricultural watershed over a 2‐year period. Nine storm events were studied, including an exhaustive analysis of hydrometeorological conditions, quantification of fluxes, and concentration‐discharge hysteresis loop characterization. The overall aim was to study the variability in these components during storm events and determine the mechanisms (flow paths) affecting the trajectories, from the source to the stream. The forms, rotational patterns and trends of hysteretic loops were investigated, and relationships between hysteresis features and hydrological parameters were studied. The results revealed clear differences between particulate (suspended sediment, particulate organic carbon) and dissolved (DOC, NO₃) matter transport responses. Movement of the particulate matter was attributed to surface water, as reflected in clockwise hysteresis loops, whereas dissolved matter showed, in general, counterclockwise hysteresis loops, indicating a time delay in the arrival of solutes to the stream. This could be related to subsurface flow paths for DOC and a groundwater source for NO₃. Copyright © 2013 John Wiley & Sons, Ltd.     

Spatial variation of wetlands and flux of dissolved organic carbon in boreal headwater streams

In order to investigate the relation between water chemistry and functional landscape elements, spatial data sets of characteristics for 68 small (0·2–1·5 km²) boreal forest catchments in western central Sweden were analysed in a geographical information system (GIS). The geographic data used were extracted from official topographic maps. Water sampled four times at different flow situations was analysed chemically. This paper focuses on one phenomenon that has an important influence on headwater quality in boreal, coniferous forest streams: generation and export of dissolved organic carbon (DOC). It is known that wetland cover (bogs and fens) in the catchment is a major source of DOC. In this study, a comparison was made between a large number of headwater catchments with varying spatial locations and areas of wetlands. How this variation, together with a number of other spatial variables, influences the DOC flux in the streamwater was analysed by statistical methods. There were significant, but not strong, correlations between the total percentages of wetland area and DOC flux measured at a medium flow situation, but not at high flow. Neither were there any significant correlations between the percentage of wetland area connected to streams, nor the percentage of wetland area within a zone 50 m from the stream and the DOC flux. There were, however, correlations between catchment mean slope and the DOC flux in all but one flow situations. This study showed that, considering geographical data retrieved from official sources, the topography of a catchment better explains the variation in DOC flux than the percentage and locations of distinct wetland areas. This emphasizes the need for high‐resolution elevation models accurate enough to reveal the sources of DOC found in headwater streams. Copyright © 2007 John Wiley & Sons, Ltd.     

Effectivity of dissolved SF6 tracer for clarification of rainfall–runoff processes in a forested headwater catchment

Understanding rainfall‐runoff processes is crucial for prevention and prediction of water‐related natural disasters. Sulfur hexafluoride (SF₆) is a potential tracer, but few researches have applied it for rainfall‐runoff process studies. We observed multiple tracers including SF₆ in spring water at 1‐ to 2‐hr intervals during rainstorm events to investigate the effectivity of SF₆ tracer in rainfall–runoff studies through the clarification of rainfall–runoff process. The target spring is a perennial spring in a forested headwater catchment with an area of 0.045 km² in Fukushima, Japan. The relationship between the SF₆ concentration in spring water and the spring discharge volume was negative trend; the SF₆ concentration in spring water becomes low as the spring discharge volume increases especially during rainstorms. The hydrograph separation using SF₆ and chloride ion tracers was applied for determining the contribution of principal sources on rainfall–runoff water. It suggested more than 60% contribution of bedrock groundwater at the rainfall peak and high percentage contribution continued even in the hydrograph recession phase. Based on observed low SF₆ concentration in groundwater after heavy rainfall, the replacement of groundwater near the spring with bedrock groundwater is indicated as a mechanism for water discharge with low SF₆ concentration during rainfall events. Consequently, rainstorm events play an important role as triggers in discharging water stored in the deeper subsurface area. In addition, SF₆ tracer is concluded as one of the strongest tracers for examining rainfall–runoff process studies. And, therefore, this study provided new insights into the dynamics of groundwater and its responses to rainfall in terms of SF₆ concentration variance in water in headwater regions.     

Dissolved nitrous oxide (N2O) dynamics in agricultural field drains and headwater streams in an intensive arable catchment

Indirect nitrous oxide (N₂O) emissions produced by nitrogen (N) leaching into surface water and groundwater bodies are poorly understood in comparison to direct N₂O emissions from soils. In this study, dissolved N₂O concentrations were measured weekly in both lowland headwater streams and subsurface agricultural field drain discharges over a 2‐year period (2013–2015) in an intensive arable catchment, Norfolk, UK. All field drain and stream water samples were found to have dissolved N₂O concentrations higher than the water–air equilibrium concentration, illustrating that all sites were acting as a net source of N₂O emissions to the atmosphere. Soil texture was found to significantly influence field drain N₂O dynamics, with mean concentrations from drains in clay loam soils (5.3 μg N L^?1) being greater than drains in sandy loam soils (4.0 μg N L^?1). Soil texture also impacted upon the relationships between field drain N₂O concentrations and other water quality parameters (pH, flow rate, and nitrate (NO₃) and nitrite (NO₂) concentrations), highlighting possible differences in N₂O production mechanisms in different soil types. Catchment antecedent moisture conditions influenced the storm event mobilisation of N₂O in both field drains and streams, with the greatest concentration increases recorded during precipitation events preceded by prolonged wet conditions. N₂O concentrations also varied seasonally, with the lowest mean concentrations typically occurring during the summer months (JJA). Nitrogen fertiliser application rates and different soil inversion regimes were found to have no effect on dissolved N₂O concentrations, whereas higher N₂O concentrations recorded in field drains under a winter cover crop compared to fallow fields revealed cover crops are an ineffective greenhouse gas emission mitigation strategy. Overall, this study highlights the complex interactions governing the dynamics of dissolved N₂O concentrations in field drains and headwater streams in a lowland intensive agricultural catchment.     

Intra‐ and interannual export of nitrogen and phosphorus in the subtropical Richmond River catchment,Australia

Nitrogen and phosphorus concentrations were measured and exports were calculated in the subtropical Richmond River catchment between July 1994 and June 1996. A stratified sampling approach was adopted owing to the extreme and rapid changes in riverine discharge, which varied by up to 10 000 times over the study period. Nutrient concentrations were lowest during baseflow. During storm discharge, dissolve inorganic and organic and particulate nitrogen and phosphorus concentrations increased two‐ to five fold, and followed hysteresis patterns that were attributed to the integration and/or depletion of catchment nutrient sources during an event. Dissolved organic nitrogen and particulate phosphorus were the dominant nutrient forms. Land use and antecedent conditions had a large influence on nutrient concentrations and exports. During the 1995–96 year (slightly above the mean annual discharge) 96% of nitrogen and 98% of phosphorus loads were transported in less than 6% of the time. When averaged across the catchment, monthly riverine nutrient loads varied by up to 1061‐fold during the study and exports were approximately four‐fold greater during the second year relative to the first. The subtropical Richmond River catchment has greater intra‐ and potential interannual variability in nutrient loads and exports when compared with temperate catchments from other parts of the world. It is suggested that in tropical and subtropical Australian catchments with large intra‐ and interannual variation in discharge, the need for parameterizing the antecedent conditions, such as the degree of nutrient storage, may make it difficult to model spatial and temporal (short time‐scale) nutrient exports. Copyright © 2000 John Wiley & Sons, Ltd.     

Incremental distributed modelling investigation in a small agricultural catchment: 2. Erosion and phosphorus transport

Distributed physically based erosion and phosphorus (P) transport models, run by the overland flow model described in Taskinen and Bruen (2006. Hydrological Processes 20 : this issue), are described. In the erosion model, the additional components to the basic model were the outflow of the particles by infiltration and a new model component, i.e. deposition when rainfall stops. Two ways of calculating the shielding factor due to the flow depth were compared. The P transport model had both dissolved P (DP) and particulate P (PP) components. The processes included in the DP model were desorption from the soil surface, advection, storage in the overland flow and infiltration. The PP model accounted for advection, storage in the flow, infiltration, detachment from the soil surface by flow and rainfall and deposition both when transport capacity of suspended solids (SS) is exceeded and when rainfall ceases. When the models were developed and validated in small agricultural fields of cohesive soil types in southern Finland, comparisons were made between corresponding processes and the significance of added components were estimated in order to find out whether increased model complexity improves the model performance. The sedigraphs were found to follow the dynamics of rainfall, emphasizing the importance of the rainfall splash component. The basic model was too slow to react to changes in rainfall and flow rates, but infiltration and deposition that acts during the cessation in rainfall improved the model significantly by enabling the modelled SS to fall sharply enough. The shielding effect of flow depth from the splash detachment was found to play a significant role. Transport capacity should also be included in erosion models when they are applied to cohesive soils. In this study, the Yalin method worked well. A strong correlation was obvious between the measured SS and total P concentrations, indicating that the main form of P in runoff is PP. This emphasizes the importance of a good sediment transport model in P transport modelling. The submodel used for DP desorption from the soil surface produced plausible results without any calibration. Copyright © 2006 John Wiley & Sons, Ltd.     

Changes in dissolved organic matter (DOM) amount and composition along nested headwater stream locations during baseflow and stormflow

Amount and composition of dissolved organic matter (DOM) were evaluated for multiple, nested stream locations in a forested watershed to investigate the role of hydrologic flow paths, wetlands and drainage scale. Sampling was performed over a 4‐year period (2008–2011) for five locations with drainage areas of 0.62, 3.5, 4.5, 12 and 79 ha. Hydrologic flow paths were characterized using an end‐member mixing model. DOM composition was determined using a suite of spectrofluorometric indices and a site‐specific parallel factor analysis model. Dissolved organic carbon (DOC), humic‐like DOM and fluorescence index were most sensitive to changes with drainage scale, whereas dissolved organic nitrogen, specific UV absorbance, Sr and protein‐like DOM were least sensitive. DOM concentrations and humic‐like DOM constituents were highest during both baseflow and stormflow for a 3.5‐ha catchment with a wetland near the catchment outlet. Whereas storm‐event concentrations of DOC and humic DOM constituents declined, the mass exports of DOC increased with increasing catchment scale. A pronounced dilution in storm‐event DOC concentration was observed at peak stream discharge for the 12‐ha drainage location, which was not as apparent at the 79‐ha scale, suggesting key differences in supply and transport of DOM. Our observations indicate that hydrologic flow paths, especially during storms, and the location and extent of wetlands in the catchment are key determinants of DOM concentration and composition. This study furthers our understanding of changes in DOM with drainage scale and the controls on DOM in headwater, forested catchments. Copyright © 2014 John Wiley & Sons, Ltd.     

Spatial and temporal variability of water table dynamics in an afforested catchment of the Central Spanish Pyrenees

Human-induced afforestation has been one of the main policies for environmental management of farmland abandonment in Mediterranean areas. Over the last decades, several studies have reviewed the impact of afforestation activities on geomorphological and hydrological responses and soil properties, although few studies have evaluated the effects on water table dynamics. In parallel to human-induced afforestation activities, natural revegetation occurred in abandoned fields and in fields where the intensity of human activity declined, driving the expansion of shrubs. This research addresses the spatial and temporal variability of water table dynamics in a small afforested sub-catchment located in the Central Spanish Pyrenees. Differences between afforestation (Pinus nigra and Pinus sylvestris) and natural plant colonization (shrubs, mainly Genista scorpius, Buxus sempervirens, and Juniperus communis) and early abandoned meadows (G. scorpius), are analysed in terms of runoff generation and seasonal water table depth dynamics. Precipitation, runoff and water table datasets recorded for the 2014–2019 period are used. Results show a high temporal and spatial variability with large fluctuations in discharge and water table. Groundwater dynamics varied markedly over the year, identifying a wet and dry period with different responses suggesting different runoff generation processes (Hortonian flow during dry and wet periods, and saturation excess runoff during wet conditions). Furthermore, important differences are noted among the various land cover types: (i) in the natural revegetation area (shrubland and meadows) a marked seasonal cycle was observed with short saturation periods during winter and spring; and (ii) in the afforestation areas, the water table dynamics showed a seasonal cycle with a high variability, with fast responses and rapid oscillations. Likewise, the relationship between the depth of water table and hydrological variables was not straightforward, suggesting complex hydrological behaviour.     

Using radiometric fingerprinting and phosphorus to elucidate sediment transport dynamics in an agricultural watershed

The major goals of this study were to determine stream bed sediment erosion/deposition rates, sediment age, percent ‘new’ sediment, and suspended sediment origin during two storm events of contrasting magnitudes (11.9 mm over 5 h and 58.9 mm over 39 h) using fallout radionuclides (excess lead 210 – ²¹⁰Pb_xs and beryllium 7 – ⁷Be) and link the nature and type of sediment source contributions to potential phosphorus (P) off‐site transport. The study was conducted in cropland‐dominated and mixed land use subwatersheds in the non‐glaciated Pleasant Valley watershed (50 km²) in South Central Wisconsin. Fine sediment deposition and erosion rates on stream beds varied from 0.76 to 119.29 mg cm^?2 day^?1 (at sites near the watershed outlet) and 1.72 to 7.72 mg cm^?2 day^?1 (at sites in the headwaters), respectively, during the two storm events. The suspended sediment age ranged from 123 ± 12 to 234 ± 33 days during the smaller storm event; however, older sediment was more prevalent (p = 0.037) in the streams during the larger event with suspended sediment age ranging from 226 ± 9 to 322 ± 114 days. During the small and large storm event, percent new sediment in suspended sediment ranged from 5.3 ± 2.1 to 21.0 ± 2.9% and 5.3 ± 2.7 to 6.7 ± 5.7%, respectively. In the cropland‐dominated subwatershed, upland soils were the major source of suspended sediment, whereas in the mixed land use subwatershed, both uplands and stream banks had relatively similar contributions to suspended sediment. In‐stream (suspended and bed) sediment P levels ranged from 703 ± 193 to 963 ± 84 mg kg^?1 during the two storm events. The P concentrations in suspended and bed sediment were reflective of the dominant sediment source (upland or stream bank or mixed). Overall, sediment transport dynamics showed significant variability between subwatersheds of different land use characteristics during two contrasting storm events. Copyright © 2014 John Wiley & Sons, Ltd.     

Diel discharge variations in dormant and growing seasons in a headwater catchment suggest potential sources of an evapotranspiration signal

Diel fluctuations in discharge not associated with precipitation have been identified in streams around the world and attributed to evapotranspiration of both hillslope and near-stream vegetation. Several mechanisms have been hypothesized to explain the generation of these signals, but a consensus has not been reached. In order to investigate the origin of these daily discharge fluctuations, we measured discharge and groundwater levels in a 43-ha headwater catchment near Cullowhee, NC, USA. The catchment was logged at least twice in the past 120 years, allowing the evergreen invasive Chinese privet (Ligustrum sinense) to become established in near-stream areas. Stream discharge was measured at the outlet, and stream stage and near-stream groundwater level were measured at a second location higher in the catchment. Daily fluctuations in discharge were quantified and found to increase in magnitude with daily mean discharge. Interestingly, daily discharge fluctuations were observed in the dormant season, and our analysis suggests that their magnitude may increase more with discharge than during the growing season. Two previously hypothesized processes may explain our observations. A decrease in signal dampening due to faster transmission of an evapotranspiration signal at elevated flows may explain the increased diel fluctuation magnitude at higher flows. Additionally, because the primary active vegetation in our catchment in the dormant season is in near-stream areas, we suggest that this indicates most of the evapotranspiration signal in stream discharge is derived from near-stream vegetation, not hillslopes.     

Fluvial transport of suspended sediment and organic carbon during flood events in a large agricultural catchment in southwest France

Water draining from a large agricultural catchment of 1 110 km² in southwest France was sampled over an 18‐month period to determine the temporal variability in suspended sediment (SS) and dissolved (DOC) and particulate organic carbon (POC) transport during flood events, with quantification of fluxes and controlling factors, and to analyze the relationships between discharge and SS, DOC and POC. A total of 15 flood events were analyzed, providing extensive data on SS, POC and DOC during floods. There was high variability in SS, POC and DOC transport during different seasonal floods, with SS varying by event from 513 to 41 750 t; POC from 12 to 748 t and DOC from 9 to 218 t. Overall, 76 and 62% of total fluxes of POC and DOC occurred within 22% of the study period. POC and DOC export from the Save catchment amounted to 3090 t and 1240 t, equivalent to 1·8 t km^?2 y^?1 and 0·7 t km^?2 y^?1, respectively. Statistical analyses showed that total precipitation, flood discharge and total water yield were the major factors controlling SS, POC and DOC transport from the catchment. The relationships between SS, POC and DOC and discharge over temporal flood events resulted in different hysteresis patterns, which were used to deduce dissolved and particulate origins. In both clockwise and anticlockwise hysteresis, POC mainly followed the same patterns as discharge and SS. The DOC‐discharge relationship was mainly characterized by alternating clockwise and anticlockwise hysteresis due to dilution effects of water originating from different sources in the whole catchment. Copyright © 2011 John Wiley & Sons, Ltd.     

Particulate carbon and nitrogen dynamics in a headwater catchment in Northern Thailand: hysteresis,high yields,and hot spots

Rivers of South and Southeast Asia disgorge large suspended sediment loads, reflecting exceptionally high rates of erosion promoted by natural processes (tectonic and climatic) and anthropogenic (land‐use change) activities that are characteristic of the region. While particulate carbon and nitrogen fluxes have been characterized in some large Asian rivers, less is known about the headwater systems where much sediment and organic material are initially mobilized. This study, conducted in the 74‐km² Mae Sa Experimental Catchment in northern Thailand, shows that the Sa River is an important source for particulate organic carbon (POC) and particulate organic nitrogen (PON) transported to larger river systems and downstream reservoirs. However, the yields during three years of investigation varied greatly: 5.0–22.3 Mg POC km^?2 y^?1 and 0.48–2.02 Mg PON km^?2 y^?1. The 22.3 Mg POC km^?2 y^?1 yield is the highest reported for any river on the Asian continent. Stream samples collected during 12 storms showed that almost 3% of the total suspended solid load is POC 0.7 µm to 2.0 mm in size. This percentage is higher than other values for most large rivers on the continent. Further, we documented a strong pulse hysteretic behaviour in the stream, whereby peak fluxes of POC and PON are often delayed (anticlockwise hysteresis) or accelerated (clockwise hysteresis) relative to stream flow peaks (or are complex), complicating the prediction of storm‐based or annual particulate carbon and nitrogen fluxes. Stream turbidity and total suspended sediment are reasonable proxies for POC and PON concentrations, while stream discharge is not a good predictor variable. Observed C:N ratios for measured particulate samples range from 3 to 83, with the high‐end values likely associated with fresh (non‐decomposed) vegetative material greater than 2 mm in diameter. The C:N ratio (weighted based on three sediment sizes) for 12 events ranges from 7.5 to 15.3. These modest values reflect the relatively low C:N ratios for small size fractions (0.7–0.63 µm) that comprise 50–90% of the TSS load in the events. Overall, organic material <0.63 µm contribute about 75% of the total POC load and 80% of the PON load. The annual C:N ratio for the river is approximately 10–11. Collectively, our findings indicate the occasionally high yields make the Sa River—and potentially other similar headwater rivers—a hot spot for POC and PON transported to downstream water bodies. Complex hysteresis patterns and high year‐to‐year variability hinders our ability to calculate and predict these yields without continuous, automated monitoring of discharge and turbidity. Copyright © 2016 John Wiley & Sons, Ltd.     

Estimation of suspended sediment loads and delivery in an incised upland headwater catchment,south‐eastern Australia

Historically upland headwater catchments in south‐eastern Australia have undergone extensive gully erosion that has removed large amounts of sediment to lowlands. Recent research suggests these upland areas may continue to dominate fine sediment loads in lowland rivers. Improved understanding of sediment transfer through upland headwater catchments may have implications for interpreting downstream sediment supply. In this study a nested catchment design was utilized to examine suspended sediment yields and delivery from a small tributary sub‐catchment (1·64 km²) to the study catchment outlet (53·5 km²). Monitoring of suspended sediment concentration and discharge was undertaken for a period of nearly two years and used to estimate suspended sediment loads. Estimated total suspended sediment exports over the period of monitoring were 24·16 t from the sub‐catchment and 550·3 t from the catchment, which are generally less than previous reported small catchment yields in south‐eastern Australia. The extent of sediment delivery was examined using between‐site ratios of specific sediment yield per unit area and incised channel length. Sediment delivery was high under average rainfall conditions, but seasonally dependent. Both suspended sediment yields and the extent of delivery peaked over spring months, supplemented by remobilization of sediment stored during summer months in the main catchment channel. The findings of this study suggest much of the suspended sediment exported from small incised upland sub‐catchments (1–2 km²) may be delivered to downstream reaches under average rainfall conditions, which, in conjunction with the findings of previous research supports the potential importance of contributions from these areas to suspended sediment loads in lowland rivers during high flow periods. Copyright © 2007 John Wiley & Sons, Ltd.     

Constraining water age dynamics in a south-eastern Australian catchment using an age-ranked storage and stable isotope approach

Improving our knowledge of the travel times of water through catchments is critical for the management and protection of water resources and to improve our understanding of fundamental catchment behaviour. In this study we use the age-ranked storage framework StorAge Selection (SAS) to investigate travel times in the Corin catchment, a headwater catchment in the south-east of Australia covered by native Eucalyptus species. Few studies have applied the SAS framework globally and in energy-intensive areas where catchment losses are heavily in favour of evapotranspiration relative to streamflow. A combination of observed and modelled values of oxygen-18 (δ¹⁸O ), the stable isotope in water, are used to constrain storage selection preferences of streamflow and evapotranspiration and the size of the catchment active storage. The highest performing parameter combinations that could reproduce δ¹⁸O in streamflow were dependent on a strong preference for young water in evapotranspiration, and a mixture of weak young and old water preference in streamflow. The mean travel time of streamflow over the study period 2007–2019, weighted by the flow rate, is limited to within a probable range of 2.81–9.77 years. The size of the active storage, a key parameter in the SAS framework, was poorly identified, and in combination with the isotopic inputs into the model, contributed to the uncertainty of the results. We discuss the implications of the results with respect to the study area, as well as within the context of SAS research globally and identify ways to improve the modelling process.