Biogas charging and dissipating process and its accumulation in the Sebei gasfield,Qaidam Basin,China

The Sebei gasfield is the largest biogas accumulation found in China and many reservoirs and seal rocks superposed on a syndepositional anticline in Quaternary.The biogas charging and dissipating process and its distribution have been a research focus for many years.The authors suggest a diffusing and accumulating model for the biogas,as they find that the shallower the gas producer,the more methane in the biogas,and the lighter stable carbon isotope composition of methane.Based on the diffusing model,diffused biogas is quantitatively estimated for each potential sandy reservoir in the gasfield,and the gas charging quantity for the sandy reservoir is also calculated by the diffused gas quantity plus gas reserve in-place.A ratio of diffusing quantity to charging quantity is postulated to describe biogas accumulating state in a sandy reservoir,if the ratio is less than 0.6,the reservoir forms a good gas-pool and high-production layer in the gasfield,which often occurs in the reservoirs deeper than 900 m;if the ratio is greater than 0.6,a few gas accumulated in the reservoir,which frequently exists in the reservoirs shallower than 900 m.Therefore,a biogas accumulation model is built up as lateral direct charging from gas source for the sands deeper than 900 m and indirect charging from lower gas-bearing sands by diffusion at depth shallower than 900 m.With this charging and diffusion quantitative model,the authors conducted re-evaluation on each wildcat in the central area of the Qaidam Basin,and found many commercial biogas layers.     

Biogas charging and dissipating process and its accumulation in the Sebei gasfield,Qaidam Basin,China

The Sebei gasfield is the largest biogas accumulation found in China and many reservoirs and seal rocks superposed on a syndepositional anticline in Quaternary. The biogas charging and dissipating process and its distribution have been a research focus for many years. The authors suggest a diffusing and accumulating model for the biogas, as they find that the shallower the gas producer, the more methane in the biogas, and the lighter stable carbon isotope composition of methane. Based on the diffusing model, diffused biogas is quantitatively estimated for each potential sandy reservoir in the gasfield, and the gas charging quantity for the sandy reservoir is also calculated by the diffused gas quantity plus gas reserve in-place. A ratio of diffusing quantity to charging quantity is postulated to describe biogas accumulating state in a sandy reservoir, if the ratio is less than 0.6, the reservoir forms a good gas-pool and high-production layer in the gasfield, which often occurs in the reservoirs deeper than 900 m; if the ratio is greater than 0.6, a few gas accumulated in the reservoir, which frequently exists in the reservoirs shallower than 900 m. Therefore, a biogas accumulation model is built up as lateral direct charging from gas source for the sands deeper than 900 m and indirect charging from lower gas-bearing sands by diffusion at depth shallower than 900 m. With this charging and diffusion quantitative model, the authors conducted re-evaluation on each wildcat in the central area of the Qaidam Basin, and found many commercial biogas layers.

     

Low resistivity oil(gas)-bearing reservoir conductive model --Dual water clay matrix conductive model in the north area of Tarim Basin, Xinjiang, China

Shaly sands reservoir is one of the most distributive types of the oil(gas)-bearing reservoirs discovered in China, and low resistivity oil(gas)-bearing reservoirs are mostly shaly sands reservoirs. Therefore, shaly sands reservoir conductive model is the key to evaluate low resistivity oil(gas)-bearing reservoirs using logging information. Some defects were found when we studied the clay distribution type conductive model, dual-water conductive model, conductive rock matrix model, etc. Some models could not distinguish the conductive path and nature of microporosity water and clay water and some models did not consider the clay distribution type and the mount of clay volume. So, we utilize the merits,overcome the defects of the above models, and put forward a new shaly sands conductive model-dual water clay matrix conductive model (DWCMCM) in which dual water is the free water and the microporosity water in shaly sands and the clay matrix(wet clay) is the clay grain containing water. DWCMCM is presented here, the advantages of which can tell the nature and conductive path from different water (microporosity water and freewater), in consid-eration of the clay distribution type and the mount of clay volume in shaly sands. So, the results of logging interpretation in the oil(gas)-bearing reservoirs in the north of Tarim Basin area, China with DWCMCM are better than those interpreted by the above models.     

Low resistivity oil(gas)-bearing reservoir conductive model Dual water clay matrix conductive model in the north area of Tarim Basin, Xinjiang, China

Shaly sands reservoir is one of the most distributive types of the oil(gas)-bearing reservoirs discovered in China, and low resistivity oil(gas)-bearing reservoirs are mostly shaly sands reservoirs. Therefore, shaly sands reservoir conductive model is the key to evaluate low resistivity oil(gas)-bearing reservoirs using logging information. Some defects were found when we studied the clay distribution type conductive model, dual-water conductive model, conductive rock matrix model, etc. Some models could not distinguish the conductive path and nature of microporosity water and clay water and some models did not consider the clay distribution type and the mount of clay volume. So, we utilize the merits,overcome the defects of the above models, and put forward a new shaly sands conductive model—dual water clay matrix conductive model (DWCMCM) in which dual water is the free water and the microporosity water in shaly sands and the clay matrix(wet clay) is the clay grain containing water. DWCMCM is presented here, the advantages of which can tell the nature and conductive path from different water (microporosity water and free-water), in consideration of the clay distribution type and the mount of clay volume in shaly sands. So, the results of logging interpretation in the oil(gas)-bearing reservoirs in the north of Tarim Basin area, China with DWCMCM are better than those interpreted by the above models.     

Controls on Methane Occurrences in Aquifers Overlying the Eagle Ford Shale Play,South Texas

Assessing natural vs. anthropogenic sources of methane in drinking water aquifers is a critical issue in areas of shale oil and gas production. The objective of this study was to determine controls on methane occurrences in aquifers in the Eagle Ford Shale play footprint. A total of 110 water wells were tested for dissolved light alkanes, isotopes of methane, and major ions, mostly in the eastern section of the play. Multiple aquifers were sampled with approximately 47 samples from the Carrizo‐Wilcox Aquifer (250‐1200 m depth range) and Queen City‐Sparta Aquifer (150‐900 m depth range) and 63 samples from other shallow aquifers but mostly from the Catahoula Formation (depth <150 m). Besides three shallow wells with unambiguously microbial methane, only deeper wells show significant dissolved methane (22 samples >1 mg/L, 10 samples >10 mg/L). No dissolved methane samples exhibit thermogenic characteristics that would link them unequivocally to oil and gas sourced from the Eagle Ford Shale. In particular, the well water samples contain very little or no ethane and propane (C1/C2+C3 molar ratio >453), unlike what would be expected in an oil province, but they also display relatively heavier δ¹³C_methane (>?55‰) and δD_methane (>?180‰). Samples from the deeper Carrizo and Queen City aquifers are consistent with microbial methane sourced from syndepositional organic matter mixed with thermogenic methane input, most likely originating from deeper oil reservoirs and migrating through fault zones. Active oxidation of methane pushes δ¹³C_methane and δD_methane toward heavier values, whereas the thermogenic gas component is enriched with methane owing to a long migration path resulting in a higher C1/C2+C3 ratio than in the local reservoirs.     

Methane hydrates in controlled-source electromagnetic surveys – analysis of a recent data example

Data from a recently acquired sea-bed logging deep-water survey are analysed for resistive bodies at depths below mudline shallower than about 300 m. A model consistent with known methane hydrate properties is found to explain near-offset structures over an offset scale of a few hundred metres observed in the data. The lateral near-seabed resolution of the sea-bed logging method was determined to less than 100 m for source frequencies of up to 10 Hz. The importance of accurate hydrate maps to improve data processing is demonstrated by placing synthetic reservoirs below hydrates and observing their effects on reference model processing. The phase is shown to be less perturbed by shallow resistors than the amplitude, which is an important quality control of standard anomaly maps. While patchy shallow resistors can generally be mapped with simple normalized magnitude-versus-offset and phase-versus-offset difference analyses, large area distributions of hydrates over kilometres are hard to distinguish from deeper structures using controlled-source electromagnetic data only, short of conducting a full 3D inversion of a sufficiently large survey. Beyond, the study confirms the applicability of controlled-source electromagnetic techniques in general to map shallow resistive structures for drilling hazards and possible future exploration of methane hydrates as an energy source.     

Greenhouse gas emissions (CO2, CH4, and N2O) from several perialpine and alpine hydropower reservoirs by diffusion and loss in turbines

We investigated greenhouse gas emissions (CO₂, CH₄, and N₂O) from reservoirs located across an altitude gradient in Switzerland. These are the first results of greenhouse gas emissions from reservoirs at high elevations in the Alps. Depth profiles were taken in 11 reservoirs located at different altitudes between the years 2003 and 2006. Diffusive trace gas emissions were calculated using surface gas concentrations, wind speeds and transfer velocities. Additionally, methane entering with the inflowing water and methane loss at the turbine was assessed for a subset of the reservoirs. All reservoirs were emitters of carbon dioxide and methane with an average of 970?±?340?mg?m^?2?day^?1 (results only from four lowland and one subalpine reservoir) and 0.20?±?0.15?mg?m^?2?day^?1, respectively. One reservoir (Lake Wohlen) emitted methane at a much higher rate (1.8?±?0.9?mg?m^?2?day^?1) than the other investigated reservoirs. There was no significant difference in methane emissions across the altitude gradient, but average dissolved methane concentrations decreased with increasing elevation. Only lowland reservoirs were sources for N₂O (72?±?22???g?m^?2?day^?1), while the subalpine and alpine reservoirs were in equilibrium with atmospheric concentrations. These results indicate reservoirs from subalpine/alpine regions to be only minor contributors of greenhouse gases to the atmosphere compared to other reservoirs.     

唐山地震时北京及邻区砂土液化深度的探讨

砂土液化深度历来是工程界颇为关心的问题.以往研究砂土液化深度多靠间接或宏观的方法, 因而取得的结果彼此间差别很大, 本文提出一种建立在喷砂同地下砂层直接对比基础上的矿物学方法.唐山地震之后, 作者等收集北京通县的西集、王庄(以上为 Ⅷ 度烈度区), 河北香河县的骡子王、渠口、县城大气所(以上为 Ⅶ 度区)等五个钻孔剖面上的砂样及地表喷砂、并进行矿物与颗粒成分的研究.结果表明, 西集喷砂同地下12.26米砂层类似;王庄喷砂同地下11.02米砂层类似;骡子王喷砂同地下12.3米砂层类似;大气所喷砂同地下9.2米砂层类似;渠口喷砂同地下11.28米砂层类似.据此可以认为, 唐山地震时北京通县与河北香河等地的 Ⅶ 和 Ⅷ 度烈度区的最大液化深度不超过12.30米, 变化在9.2——12.30米之间, Ⅶ 度区有可能更浅些.      

部分饱和砂岩储层地震物理模拟及含气饱和度预测分析

含气饱和度预测是天然气储层地震解释工作的重要目标.本文将岩石物理分析与地震物理模拟技术相结合,构建了部分;饱和砂岩储层物理模型并进行含气饱和度预测分析.物理模型中设置了高孔渗常规砂岩和低孑孔渗致密砂岩两种模拟储层,每种储层都是由具有不同含水饱和度的气-水双相饱和砂体组成.岩石物理分析结果显示在低孔渗致密砂岩中气-水混合流体更加倾向于非均匀的斑块分布,而结合了Brie等效流体公式的Gassmann流体替换理论可以更准确地描述纵波速度随含水饱和度的变化趋势.对物理模型进行地震资料采集处理后,对比了AVO特征和叠前同步反演结果对两种砂岩储层含气饱和度预测能力的差异.AVO特征结果显示,对于混合流体均匀分布的高孔渗砂岩储层,AVO响应曲线和属性变化很难对含气饱和度进行估算;对于混合流体斑块分布的致密砂岩储层,AVO特征可以定性地分辨出储层是否为高、中、低含气情况.反演结果显示,密度及纵横波速度比分别对高孔渗及致密砂岩储层的含气饱和度有着较好的指示能力.     

墨西哥湾GC955H井天然气水合物储层声波衰减特征

墨西哥湾GC955H井钻遇两种不同的水合物储层,浅层裂隙充填型水合物和深层砂岩型水合物.浅层水合物充填在细粒泥质沉积物的裂隙中,由电阻率测井计算的饱和度平均值为25%.深层水合物充填在砂岩孔隙中,由电阻率计算的饱和度平均为65%.基于声波全波形数据,本文计算了GC955H井储层的声波衰减大小,结果发现两种水合物层对声波衰减的影响不同.泥岩水合物层中的声波衰减与上覆背景泥岩沉积层基本相当.砂岩水合物层的声波衰减大于0.1,最大0.15,远高于上覆和下伏的背景砂岩层.对声波频率的分析发现,GC955H井泥岩层中水合物对声波频率的影响不大,砂岩水合物层的声波频谱与上下背景砂岩层相比发生变化,主频增大.通过对比两种水合物储层的特征,本文初步定性分析了造成水合物对储层声波传播影响不同的原因,包括岩性、水合物饱和度、水合物赋存方式等;但对此的定量描述需要未来更详尽地讨论和研究水合物的声波衰减机制.     

Characteristics,genesis and accumulation history of natural gas in Hetianhe gasfield,Tarim Basin,China

Hetianhe gasfield in Bachu region of the Tarim Basin is mainly composed of three reservoir-caprock assembly, namely regional caprock of upper mudstone, middle mudstone and lower mudstone of the Carboniferous and reservoir of Bachu bioclastic limestone, glutenite and the Ordovician carbonate buried hill. Natural gas in Hetianhe gasfield sourced from the Cambrian source rock. It is thought that gases in Ma4 well block in the east of Hetianhe gasfield are mainly crude-oil cracked gases, while those in Ma3 and Ma8 well blocks in the west are the mixture gases of kerogen cracked gases and crude-oil cracked gases. Natural gas is rich in H₂S and accumulated in multiply stages as the result of TSR. The accumulation history is divided into three stages, namely accumulation and breakage in the late Caledonian-early Hercynian, migration and dissipation in the late Hercynian and accumulation in Himalayan. The main accumulation of reformed gas reservoir is in Himalayan.

     

Characteristics,genesis and accumulation history of natural gas in Hetianhe gasfield,Tarim Basin,China

Hetianhe gasfield in Bachu region of the Tarim Basin is mainly composed of three reservoir-caprock assembly, namely regional caprock of upper mudstone, middle mudstone and lower mudstone of the Carboniferous and reservoir of Bachu bioclastic limestone, glutenite and the Ordovician carbonate buried hill. Natural gas in Hetianhe gasfield sourced from the Cambrian source rock. It is thought that gases in Ma4 well block in the east of Hetianhe gasfield are mainly crude-oil cracked gases, while those in Ma3 and Ma8 well blocks in the west are the mixture gases of kerogen cracked gases and crude-oil cracked gases. Natural gas is rich in H₂S and accumulated in multiply stages as the result of TSR. The accumulation history is divided into three stages, namely accumulation and breakage in the late Caledonian-early Hercynian, migration and dissipation in the late Hercynian and accumulation in Himalayan. The main accumulation of reformed gas reservoir is in Himalayan.     

Characteristics,genesis and accumulation history of natural gas in Hetianhe gasfield,Tarim Basin,China

Hetianhe gasfield in Bachu region of the Tarim Basin is mainly composed of three reservoir-caprock assembly,namely regional caprock of upper mudstone,middle mudstone and lower mudstone of the Carboniferous and reservoir of Bachu bioclastic limestone,glutenite and the Ordovician carbonate buried hill.Natural gas in Hetianhe gasfield sourced from the Cambrian source rock.It is thought that gases in Ma4 well block in the east of Hetianhe gasfield are mainly crude-oil cracked gases,while those in Ma3 and Ma8 well blocks in the west are the mixture gases of kerogen cracked gases and crude-oil cracked gases.Natural gas is rich in H2S and accumulated in multiply stages as the result of TSR.The accumulation history is divided into three stages,namely accumulation and breakage in the late Caledonian-early Hercynian,migration and dissipation in the late Hercynian and accumulation in Himalayan. The main accumulation of reformed gas reservoir is in Himalayan.     

Primary migration and secondary alteration of the Upper Paleozoic gas reservoir in Ordos Basin,China — Application of fluid inclusion gases

The composition of fluid inclusions (FI) often represents the initial geochemical characteristics of palaeo-fluid in reservoir rock. Influence on composition and carbon isotopic composition of gas during primary migration, reservoir-forming and subsequent secondary alterations are discussed through comparing fluid inclusion gas with coal-formed gas and natural gas in present gas reservoirs in the Ordos Basin. The results show that primary migration of gas has significant effect on the molecular but not on the carbon isotopic composition of methane. Migration and diffusion fractionation took place during the secondary migration of gas in Upper Paleozoic gas reservoir according to carbon isotopic composition of methane in Fls. Composition and carbon isotopic composition of natural gas were nearly unchanged after the gas reservoir forming through comparing the FI gases with the natural gas in present gas reservoir.

     

Shallow gas accumulations and seepage in the sediments of the Northeast Persian Gulf

Shallow gas accumulations and gas seepage may indicate deeper hydrocarbon reservoirs. Sonar and high resolution seismic recordings were carried out to obtain gas migration and accumulation below seabed in Northeast Persian Gulf. Results revealed some structures and reflectivity effects, for example few pockmarks, gas seepage, and other surface structures in sonar and seismic data. Most of the features observed on seismic data were located at depths between 5 and 10 m (sub-sea bed) that include acoustic blanking and turbidity, gas packets, gas chimneys, and enhanced reflection. Most of the gas is accumulated on young and thin parallel layers, but the presence of acoustic effect in Aghajari Formation indicates that the origin of the gas accumulation in shallow strata may be located in a deeper reservoir.     

Shallow-water benthic macroinvertebrate community of the limnic part of a lowland Polish dam reservoir

Biodiversity, abundance and taxonomic composition of shallow-water zoobenthos were studied in the W?oc?awek Dam Reservoir (the lower Vistula River, central Poland). The following habitats located near the shore were studied: (1) sandy bottom in the flooded part of the reservoir; (2) sandy bottom close to the main riverine flow in the reservoir and (3) organic-rich bottom covered by a thick layer of plant remnants in a shallow, isolated cove. In each habitat we investigated two sites (ca. 0.5 and 1 m depth). Also examined was the bottom of a phytolittoral site (sandy bottom, with elodeids and nympheids, 1 m depth), located in the flooded zone. In general, the bottom fauna was highly diverse and abundant in these habitats. The highest biodiversity (38 taxa, Shannon-Wiener index=4.3) was found on the bottom rich in organic matter. However, the zoobenthos abundance in this habitat was comparatively low, probably due to periodical oxygen deficiencies. The highest density of bottom fauna (>30,000 individuals per m²), accompanied by its high biodiversity, occurred at the phytolittoral site. The benthic community of the organic-rich sediments was the most distinct, with many taxa occurring exclusively in this area. The composition of the bottom fauna, from the two sandy habitats and phytolittoral, also differed from one another. The differences in taxonomic composition between the shallower and deeper sites were less pronounced. Lower densities at the shallower sandy sites and a very high variability of taxonomic composition among particular samples from these sites indicated lower stability of their environmental conditions. These were certainly due to water level fluctuations and/or destructive wave action. On the other hand, no such differences were found between the sites of various depths from the organic-rich sediments, showing that this substratum provided better protection against adverse hydrodynamical factors.     

Side lobes of wavelets impact identification of thin sand bodies

Recently, we found that side lobes of wavelets have a large impact on the identification of thin sand reservoirs when studying some gas fields in a basin in Northwest China. Reflections from the top of the H Formation, in which there are gas-bearing thin sand bodies, have the main wavelet lobe between two weak peak side lobes. The lower one always mixes with another peak reflected from the top of a thin sand reservoir. That makes it difficult to identify the sand reservoir. In order to solve this, many forward models were set up using typical well logs. 2D synthetic profiles were produced using Ricker wavelets to study the relationships between the effects of wavelet side lobes and thin sand position and frequency and between amplitude and the thin sand body. We developed the following conclusions： First, it is easier to identify thin sands in a shallower position. Second, a good way to tell sand body reflections from side lobes is by comparing profiles with different frequency windows. Third, it is helpful and effective to describe sand extent using amplitude attributes.     

水合物脊ODP1247站位天然气水合物藏的甲烷来源和成藏过程模拟

海洋天然气水合物体系天然气水合物成藏受甲烷供给及埋藏的控制.根据海洋天然气水合物体系甲烷的质量守恒,建立了海洋环境沉积物孔隙水溶解甲烷对流和扩散作用及微生物原位产甲烷作用供给甲烷形成天然气水合物的数值模型,对水合物脊ODP1247站位天然气水合物成藏过程进行了模拟研究,结果表明该站位孔隙水溶解甲烷的对流和扩散作用是天然气水合物成藏过程中最主要的甲烷供给方式,微生物原位生成甲烷供给的比例很小,并且在1.67 Ma以来天然气水合物藏受沉积速率变化而动态变化,但幅度不大,至今形成的水合物饱和度约0~3%,与钻探确定的饱和度接近.     

Application of 3D vertical seismic profile multi‐component data to tight gas sands‡

Due to the complicated geophysical character of tight gas sands in the Sulige gasfield of China, conventional surface seismic has faced great challenges in reservoir delineation. In order to improve this situation, a large‐scale 3D‐3C vertical seismic profiling (VSP) survey (more than 15 000 shots) was conducted simultaneously with 3D‐3C surface seismic data acquisition in this area in 2005. This paper presents a case study on the delineation of tight gas sands by use of multi‐component 3D VSP technology. Two imaging volumes (PP compressional wave; PSv converted wave) were generated with 3D‐3C VSP data processing. By comparison, the dominant frequencies of the 3D VSP images were 10–15 Hz higher than that of surface seismic images. Delineation of the tight gas sands is achieved by using the multi‐component information in the VSP data leading to reduce uncertainties in data interpretation. We performed a routine data interpretation on these images and developed a new attribute titled ‘Centroid Frequency Ratio of PSv and PP Waves’ for indication of the tight gas sands. The results demonstrated that the new attribute was sensitive to this type of reservoir. By combining geologic, drilling and log data, a comprehensive evaluation based on the 3D VSP data was conducted and a new well location for drilling was proposed. The major results in this paper tell us that successful application of 3D‐3C VSP technologies are only accomplished through a synthesis of many disciplines. We need detailed analysis to evaluate each step in planning, acquisition, processing and interpretation to achieve our objectives. High resolution, successful processing of multi‐component information, combination of PP and PSv volumes to extract useful attributes, receiver depth information and offset/ azimuth‐dependent anisotropy in the 3D VSP data are the major accomplishments derived from our attention to detail in the above steps.     

地震子波旁瓣对薄砂体识别的影响

我们研究中国西部某盆地一些气田时,发现地震子波旁瓣在很大程度上影响着薄砂体的识别和解释。该区目的层段H段地层中,辫状河流相薄砂岩储层与湖相泥岩成互层。在地震资料上,来自H段地层顶面的强波谷总跟随一个弱波峰(源于子波旁瓣),此弱波峰与薄砂体顶面反射波峰相互叠合,掩盖了砂体反射,造成了薄砂体识别和解释的困难。为此,我们设计了一套正演模型,利用不同频率的零相位雷克子波合成人工地震剖面,来研究砂体位置、频率与地震子波旁瓣效应的关系,以及振幅类属性与薄砂体关系。提出处于高位置的砂体反射形态清晰,易于识别解释;认为通过对比不同带通滤波处理后的地震资料,可很好辨别旁瓣效应和砂体反射;同时发现振幅类属性可作为薄砂体识别表征参数,可有效合理地描述砂体分布范围和特征。