Effects of basin activities and land use on water quality trends in Tahtali Basin, Turkey

Bi-weekly water quality data from seven monitoring stations located within Tahtali Watershed, ?zmir, Turkey and digital land use/land cover data of the same watershed are analyzed in this study. To examine the changes in land use associated with urbanization, the satellite images of the main pool of the Tahtali reservoir prior to filling and subsequent to filling, respectively, are analyzed. Aerial photos of the basin taken in 1995 (October) are compared with images taken in 2005 (November) from the IKONOS satellite through use of several GIS techniques. New residential buildings, greenhouses, and industrial buildings are presented in separate layers, and changes in basin activities are quantified. The effects of urbanization on the water quality are investigated through statistical analysis. The seasonal Kendall test is applied to the water quality parameters monitored bi-weekly at seven stations within the basin for the duration 1997–2005. There was no trend in phosphorus, but there was a negative trend in boron and nitrate and a positive trend in the parameters of biological oxygen demand (BOD) and chemical oxygen demand (COD). The improvement in nitrate concentrations is attributed to the new regulations on the use of fertilizers in greenhouses. However, increase of BOD and COD concentrations is related to the growing settlement areas and industrial zones, which point to the insufficient wastewater treatment within the basin. Soil erosion within the basin is also quantified by the universal soil loss equation using available maps. Estimated total soil loss rate increased about 2.5 times that of 1995 when the changed land use composition in 2005 is considered in the calculations.     

Investigation of water pollution in the Yalvac basin into Egirdir Lake,Turkey

The aim of this study is to understand the effects of pollution of anthropogenic origin on water quality in Yalvac Basin, part of the Egirdir Lake catchment. Surface discharge from the basin to the lake is 63 m³/year and underground discharge is 114 m³/year. Possible water pollution is categorized into domestic, industrial and agricultural origin. Domestic and industrial wastewaters, including effluents from leather tanneries are discharged, without being purified, into Yalvac Stream, which flows into Egirdir Lake directly or via the drainage canal. Surface waters flowing into the lake are used in winter for irrigation of agricultural areas. In agricultural areas natural and synthetic fertilizers and pesticides are used extensively. Lake Egirdir is used as a source of drinking water. Sampling sites were established for surface and underground waters, taking into account the known point sources of pollution. These sites were sampled in May and October of 2002, and analysed chemically. Cr³⁺ and Pb²⁺ concentrations exceed standard limits, meaning that pollution caused by effluent from the tanneries is adversely affecting the water quality in the lake.     

Effects of road-deicing salt (NaCl) and saline water on water quality in the Urmia area,northwest of Iran

Increased application of road salt for winter maintenance has resulted in increased concentration of deicer constituents in the environment. The runoffs from the deicing operation have a deteriorating effect on water quality. The existence of salt super saturated Urmia lake and easy access to it, causes Urmia municipality to over use the super saturated water of this lake and salt (NaCl) during winter for snow melting, freezing prevention and traffic load facilitation. The aim of this study was investigation of surface and groundwater contaminations in consequence of salt (NaCl) and saline water usage in Urmia city and its surroundings. Studying the chloride ion concentration as a tracer in runoff result snowmelts during winter shows that its amount is differential with respect to time and place sampling. Results indicate that runoff result of snowmelts effected groundwater, soil and plant growth. The contamination of groundwater in study area by road salt and saline water is a slow process and directly related to the amount of road salt and saline water applied.     

Hydrochemical,isotopic, and reservoir characterization of the Pasinler (Erzurum) geothermal field,eastern Turkey

The reservoir temperature and conceptual model of the Pasinler geothermal area, which is one of the most important geothermal areas in Eastern Anatolia, are determined by considering its hydrogeochemical and isotope properties. The geothermal waters have a temperature of 51 °C in the geothermal wells and are of Na–Cl–HCO₃ type. The isotope contents of geothermal waters indicate that they are of meteoric origin and that they recharge on higher elevations than cold waters. The geothermal waters are of immature water class and their reservoir temperatures are calculated as 122–155 °C, and their cold water mixture rate is calculated as 32%. According to the δ¹³C_VPDB values, the carbon in the geothermal waters originated from the dissolved carbon in the groundwaters and mantle-based CO₂ gases. According to the δ³⁴S_CDT values, the sources of sulfur in the geothermal waters are volcanic sulfur, oil and coal, and limestones. The sources of the major ions (Na⁺, Ca²⁺, Mg²⁺, Cl^?, and HCO₃ ^?) in the geothermal waters are ion exchange and plagioclase and silicate weathering. It is determined that the volcanic rocks in the area have effects on the water chemistry and elements like Zn, Rb, Sr, and Ba originated from the rhyolite, rhyolitic tuff, and basalts. The rare earth element (REE) content of the geothermal waters is low, and according to the normalized REE diagrams, the light REE are getting depleted and heavy REE are getting enriched. The positive Eu and negative Ce anomalies of waters indicate oxygen-rich environments.     

Mechanism of Seasonal Deterioration of Water Quality in Lake Baihua,China

Water quality of Lake Baihua was found worsening in the autumn of 1994.Studies have shown that the decomposition of organic matter in the upper-level sediments resulted in seasonal anoxia with the release of P,Mn,and S^2- from the sediments to the overlying water column,and the increase of NO2^- concentration led to blackening of the water column,deat of fishes and secondary Mn pollution.     

Formation of the Upper Pleistocene terraces of Lake Van (Turkey)

Sedimentological and geomorphological studies of terraces around Lake Van (1647 m) provided a preliminary framework for lake‐level variations. The elevations of terraces and past lake level were measured with a differential global positioning system. A chronology is developed using ²³⁴U/²³⁰Th dating of travertines, ³⁹Ar/⁴⁰Ar dating of pyroclastites and ¹⁴C dating of organic matter. Facies and stratigraphic correlations identify four transgressions (C1′, C1″, C2′ and C2″), each followed by a regression which ended with low lake levels that caused river incision and terrace formation. Evidence of the oldest transgression (C1′) is found in the uppermost reaches of valleys up to 1755 m, an altitude higher than the present lake threshold (1736 m). This C1′ transgression may be related to pyroclastic flows which dammed an outlet located in the western part of the lake basin and which is dated to before 105 ka. After 100 ka, a second transgression (C1″) reached 1730/1735 m, possibly related to a younger ignimbrite flow, in association with high water inflow (warm and/or wetter conditions). The two younger transgressions reached 1700–1705 m. The first one (C2′) is dated to 26–24.5 cal. ka BP and the second one (C2″) to 21–20 cal. ka BP. Available data suggest that the long‐term lake‐level changes responded mainly to climate oscillations. Additional events such as river captures caused by volcanic falls filling valleys, tectonism, erosion and karstic diversion may have impacted these long‐term lake‐level changes. Copyright © 2010 John Wiley & Sons, Ltd.     

A geohazard reconnaissance study based on geoscientific information for development needs of the western region of Istanbul (Turkey)

The role of geoenvironmental information is becoming increasingly important as legislative changes have forced developers and planning authorities to consider more implications and impact on the environment of large-scale development initiatives. Therefore, integration of surface and subsurface geoscientific information for development needs has prime importance and provides a means of identifying potential problems and opportunities at an early stage in any planned development. However, from the experience of recent natural disasters, it is evident that this was not case the taken into consideration in many countries. In addition to thousands of casualties, many urbanized areas, industrial districts and large-scale engineering structures suffered severe damages from the natural hazards due to many reasons including the lack of preliminary engineering geological maps and zoning maps of the settlement areas. Turkey is one of the countries which is exposed to natural hazards such as earthquakes, landslides and floods. In particular, the devastating 1999 Kocaeli earthquake, which affected the Marmara Region of Turkey, focused the attention on densely urbanized and industrialized metropolitan areas such as Istanbul. The rapid growth of Istanbul, particularly towards west with minimal geoscientific information resulted in an overwhelming pressure on the natural environment. In addition, a large earthquake, which is expected to occur in the Marmara Sea within the next 30 years, also pose a threat to the city and its surroundings. In this study, on the basis of the geological, geomorphological and geophysical reconnaissance study, an integrated geoscientific data were collected from the western region of Istanbul and evaluated for geohazards. The paper focuses on the geological and geomorphological aspects that control the occurrence of some geohazards such as earthquake-induced liquefaction, landslides and flooding. In this context, the geological map of the region was revised and Quaternary deposits were classified into 11 units, in detail. Liquefaction-prone areas were evaluated by using geomorphological criteria based on field investigation, by the examination of the available records from 88 boreholes drilled on recent deposits and by the data from resistivity profiles. The landslides within the region were classified according to their type, relative depth and activity. In addition, fluvial and marine flood-prone areas were also delimited within the region. Finally, a series of maps such as landslide inventory maps, and maps showing liquefaction- and flood-prone areas were produced with the aid of Geographic Information Systems (GIS) to assist in designing further detailed site investigations and to reduce costs by ensuring a more focused approach to strategic planning and site selection.     

Influence of gold mine on groundwater quality (Efemçukuru, Izmir, Turkey)

. Currently, exploration of gold ores is under discussion in Turkey, without considering its adverse affect on the environment. Studying the adverse affect on environment is extremely important because significant civic activities are already taking place on the geological units that contain gold ore bodies in Turkey. Such an area is located at the southeast of Izmir City (Turkey), and approximately 2-km-long gold-bearing ore veins occur close to the Efemçukuru Village. The objective of this study was to describe the characteristics and seasonal variation of the groundwater chemistry and pollution of the aquifer in the ore deposit site, and to determine the impact of ore deposits on groundwater quality. The gold-bearing formation is highly weathered and fractured. The fractures in the geological units control the permeability and the depth of groundwater in the area. The concentrations of Al, Ag, Cu, Cd, Cr, Fe, Pb, Mn, Zn, Ni, and Sb were determined for four well samples and two stream waters for wet and dry seasons. The results showed that the concentrations of most of these elements were below the USA EPA (Environmental Protection Agency) limits; however, Pb and Cd concentrations are slightly above the limits. The results indicate that minerals in gold bodies do not dissolve although the weathering of formations is high. The low concentration of elements in groundwater and streams may be attributed to the high velocity of ground and surface water.     

Identifying sources of groundwater recharge in the Merguellil basin (Tunisia) using isotopic methods: implication of dam reservoir water accounting

Thirty-two groundwater samples collected from the Merguellil Wadi basin (central Tunisia) complemented by the Haouareb dam reservoir water samples have been isotopically analysed in order to investigate the implication of the reservoir water to recharging the aquifer, and also to infer the sources, relative ages and mixing processes in the aquifer system. Plots of the stable isotopes data against the local meteoric lines of Tunis-Carthage and Sfax indicate a strong implication of the dam water noticeable up to a distance of 6–7 km. A contribution as much as 80% of the pumped water has been evidenced using isotopic mass balance. In addition, poorly distinguished water clusters in the stable isotope plots, but clearly identified in the diagrams δ¹⁸O versus ³H and ³H versus ¹⁴C, indicate various water types related to sources and timing of recharge. The isotopic signatures of the dam accounting water, the “old” and “native” recharged waters, have been evidenced in relation to their geographical distribution and also to their radiogenic isotopes (³H and ¹⁴C) contents. In the south-western part of the aquifer, mixing process occurs between the dam reservoir water and both the “old” and “native” water components.     

Local warming of groundwaters caused by the urban heat island effect in Istanbul, Turkey

The urban heat island (UHI) is a result of urbanization, causing local microclimatologic changes such as increase in ambient temperature. Factors causing the UHI effect are anthropogenic energy release, energy absorption by concrete, tarmac structures and traffic, although the main factor is the replacement of vegetation with man-made structures. These factors cause heating of not only local air but also subsurface and groundwater. Observations of groundwater temperatures from the urban, southern part of Istanbul (Turkey) and the rural, northern part of Istanbul revealed that the urban groundwater temperatures were 3.5°C higher than the rural. Urbanization is a direct consequence of improvements in technology and modern life. However, this comes at the cost of an ever-increasing demand for energy. Exploitation of low-enthalpy geothermal energy is an attractive alternative to fossil fuel based energies. From the environmental point of view, clean and cheap energy is the most preferable, with heat pumps being the best choice for recovery purposes. Usage of elevated groundwater temperature in the heat pumps in urban areas increases the efficiency of the heat pump system and yields more thermal energy than that of rural groundwater. This system may be applicable to Istanbul.     

Application of multivariate statistical techniques in the assessment of water quality in Sakarya River,Turkey

In this paper, the surface water quality of the Sakarya River in Turkey is assessed by using multivariate statistical techniques. These techniques were applied to the chemical parameters obtained from the five different surface water quality observation stations. Factor and principal component analysis results reveal that the agricultural, anthropogenic and domestic pollution caused differences in terms of water quality. Cluster analysis revealed two different clusters of similarities between the stations, reflecting different chemical properties and pollution levels in the studied river. Surface water quality downstream of the river was different from the water quality upstream. Thus, this study shows the usefulness of multivariate statistical techniques for analysis and interpretation in the surface water quality problem.     

Effects of groundwater exploitation on the Borjomi mineral water reservoir in Georgia

The mineral water at Borjomi has been bottled since the 19th century. Currently, the production comes from the regulated artesian flow of 11 boreholes. The total yield is about 540 m³/day. The mineral water is of sodium, hydrogen carbonate and CO₂ type with mineralization up to 7.5 g/l and a temperature up to 40°C. Long-term observation has enabled the history of the structure of the Borjomi mineral water to be reconstructed from the beginning of its exploitation until the present. The hydrogeological structure of the Borjomi locality is very complex, but on the regional scale it occupies a relatively small area. The hydraulically well-defined and closed structure allows a simple conceptual model for each of the three main sectors to be designed. These are, namely, the Central, the Vaschlovani and the Likani sectors. The long-term extraction limits are about 190 m³/day in the Central sector, 300 m³/day in the Vashlovani sector and 77 m³/ day in the Likani sector.     

Assessment of liquefaction and lateral spreading on the shore of Lake Sapanca during the Kocaeli (Turkey) earthquake

The 1999 Kocaeli earthquake of Turkey (M_w = 7.4) caused great destruction to buildings, bridges and other facilities, and a death tall of about 20,000. During this earthquake, severe damages due to soil liquefaction and associated ground deformations also occurred widespread in the eastern Marmara Region of Turkey. Soil liquefaction was commonly observed along the shorelines. One of these typical sites is Sapanca town founded on the shore of Lake Sapanca. This study was undertaken as quantitative measurement of ground deformations induced by liquefaction along the southern shore of Lake Sapanca. The permanent lateral ground deformation was measured through the aerial photogrammetry technique at several locations both along the shoreline and in the town. In situ soil profiles and material properties at Sapanca area were obtained based on the data from 55 borings and standard penetration tests (SPT), and laboratory tests, respectively. The data and the empirical methods recommended by an NCEER workshop were employed to evaluate the liquefaction resistance of the soils. In addition, simple shaking tests on a limited number of samples were also performed. The permanent ground displacements were estimated from the existing empirical models, sliding block method and residual visco-elastic finite element methods. Then these estimations were compared with the observed ground displacements. The assessments suggested that liquefaction at Sapanca have occurred within Quaternary alluvial fan deposits at depths 1 and 14 m, and the major regions of liquefaction and associated ground deformations were located along the shore and creeks. The evaluations also indicated that for sites with no sand boils but with ground displacement greater than 1 m, thickness of the non-liquefiable layer was large. It is also noted that no liquefaction-induced ground surface disruption is expected at the site when the thickness of the liquefiable and non-liquefiable layers vary between 0.5 and 1.5 m, and 3.5 and 5.5 m, respectively. Except one model, all the empirical models employed in the study over-predicted the observed lateral ground displacements, while sliding block method and residual visco-elastic finite element methods yielded reasonably good results if the known properties of liquefied soils are used.     

An assessment of environmental impacts of quarry-blasting operation: a case study in Istanbul, Turkey

This study evaluates the impacts resulting from quarry-blasting operation on nearby buildings and structures as it generates ground vibration, air blast, and fly rocks. In this paper, first blasting operation and its possible environmental effects are defined. Then the methods of blast-vibration prediction and commonly accepted criteria to prevent damage were introduced. A field experimental work was conducted to minimize the vibration effects at Saribayir quarry as it is an identical case for the many quarries situated in and around Istanbul, Turkey. Although the local surrounding geology and rock mechanics have great influence on vibrations as uncontrollable parameter, the charge weight per delay, delay period, geometric parameters of the blasts were changed to solve the existing vibration problem in the studied quarry. To obtain a realistic result, 10 blasts were carried out and 30 seismic records were made in different places mainly very close the buildings and the other vulnerable structures around the quarry. The evaluation is performed whether the vibration level are within safe limits or not. The prediction equation based on scaled distance concept is also determined, however, it is a site-specific model and need to be updated when the quarry advances. The safe blast parameters which minimize the environmental effect were determined for the Saribayir quarry.     

Effects of Hurricane Ivan on water quality in Pensacola Bay, Florida

Pensacola Bay, Florida, was in the strong northeast quadrant of Hurricane Ivan when it made landfall on September 16, 2004 as a category 3 hurricane on the Saffir-Simpson scale. We present data describing the timeline and maximum height of the storm surge, the extent of flooding of coastal land, and the magnitude of the freshwater inflow pulse that followed the storm. We computed the magnitude of tidal flushing associated with the surge using a tidal prism model. We also evaluated hurricane effects on water quality using water quality surveys conducted 20 and 50 d after the storm, which we compared with a survey 14 d before landfall. We evaluated the scale of hurricane effects relative to normal variability using a 5-yr monthly record. Ivan's 3.5 m storm surge inundated 165 km² of land, increasing the surface area of Pensacola Bay by 50% and its volume by 230%. The model suggests that 60% of the Bay's volume was flushed, initially increasing the average salinity of Bay waters from 23 to 30 and lowering nutrient and chlorophylla concentrations. Additional computations suggest that wind forcing was sufficient to completely mix the water column during the storm. Freshwater discharge from the largest river increased twentyfold during the subsequent 4 d, stimulating a modest phytoplankton bloom (chlorophyll up to 18 μg l⁻¹) and maintaining hypoxia for several months. Although the immediate physical perturbation was extreme, the water quality effects that persisted beyond the first several days were within the normal range of variability for this system. In terms of water quality and phytoplankton productivity effects, this ecosystem appears to be quite resilient in the face of a severe hurricane effect.     

Diagnosis of groundwater quality and assessment of contamination sources in the Megara basin (Attica,Greece)

In this study, hydrochemical analysis, statistical analysis and GIS database have been successfully used to explain the main factors and mechanisms controlling the distribution of major and trace elements in groundwater. The groundwater of Megara basin is subject to intense exploitation to accommodate all the water demands of this agricultural area. Water quality data obtained from 58 sampling sites of the Megara basin, aims to describe groundwater quality in relation to geology and anthropogenic activities. Factor analysis revealed that four factors accounted for 79.96% of the total data variability. The contribution of each factor at sampling sites was calculated. Evaluation of water samples by comparing quality standards and levels recorded in the literature for both drinking and irrigation uses is discussed.     

The hydrogeochemistry of the Lake Waco drainage basin,Texas

The origin of surface water chemistry in highly impacted drainage basins must be investigated on a drainage-basin scale if the causes of the pollution are to be elucidated. This study characterizes and deciphers the surface water chemistry of a nutrient polluted river system in central Texas. Four tributaries of the Lake Waco reservoir were chemically characterized temporally and spatially in order to gain a complete understanding of the nature and origin of dissolved solids being transported into the lake. Temporal chemical variations measured at the base of each of the drainage basins are repetitive and seasonal. The most periodic and well-defined variation is exhibited by nitrate concentrations although many of the other solutes show seasonal changes as well. These temporal chemical changes are controlled by seasonal precipitation. During rainy seasons, the shallow aquifer is recharged resulting in stream discharge that is high in nitrate, calcium, and bicarbonate. When the shallow flow system is depleted in the summer, stream waters are dominated by deeper groundwater and become rich in sodium. Spatial variations in the chemistry of South Bosque surface waters were characterized using the snapshot technique. The spatial distribution of nitrate in surface waters is controlled by fertilizer application to row crops and the location of a munitions factory. The concentrations of naturally derived solutes such as Ca⁺, Na⁺, Cl^–, and SO₄^–2are controlled by underlying lithologies.     

Review of water and soil contamination in and around Salihli geothermal field (Manisa,Turkey)

The town of Salihli is situated in Gediz Graben in the western Anatolia. This region is important in terms of industry, mining, geothermal energy, water sources, and agricultural production. Geothermal flow and anthropogenic activities in Salihli threaten the surrounding environment due to the contamination of cold groundwater, surface water, and soil. The goal of the present study is to determine the environmental effects of the geothermal and anthropogenic activities in Salihli on soil, stream sediments, and water. Stream sediments and farm soil have been contaminated by substances derived from geothermal and industrial effluents. To this end, the quality review of the water was completed and the heavy metal levels in stream sediment samples were measured to determine the extent of contamination. The elements As, B, Br, Fe, and Ni are the major contaminants present in surface water and groundwater in the study area. The concentrations of these elements excess tolerance limits of international water standards. Gibbsite, K-mica, kaolinite, sepiolite, halite, sulfur, willemite, and Pb(OH)₂ might be precipitated as scales at low temperatures on the soil; this could be interpreted as a resultant from soil contamination. The concentrations of 17 elements (As, Ba, B, Cd, Co, Cr, Cu, Fe, Hg, Li, Mo, Mn, Ni, Pb, Sb, Sr, and Zn) were measured in samples from stream sediments and surface soils. In the study area, especially geothermal and anthropogenic activities give rise to environmental pollution.