Precambrian crustal contribution to the Variscan accretionary prism of the Kaczawa Mountains (Sudetes,SW Poland): evidence from SHRIMP dating of detrital zircons

SHRIMP dating of detrital zircons from sandstones of the Gackowa Formation (Kaczawa Complex, Sudetes, SW Poland) indicates input from late (550–750 Ma) and early Proterozoic to Archaean sources (∼2.0–3.4 Ga, the latter being the oldest recorded age from the Sudetic region). These dates preclude within-terrane derivation from seemingly correlatory acid volcanic rocks of early Palaeozoic age. Rather, they indicate provenance from Cadomian and older rocks that currently form part of other, geographically distant terranes; the most likely source identified to date is the Lusatian Block in the Saxothuringian Zone. Hence, the Gackowa Formation may be late Proterozoic rather than early Palaeozoic in depositional age, possibly coeval with the late Proterozoic (pre-Cadomian) greywackes of Lusatia, being subsequently tectonically interleaved with early Palaeozoic volcanic rocks into the Kaczawa accretionary prism during the Variscan orogeny. However, correlation with the lithologically similar early Ordovician Dubrau Quartzite of Saxothuringia, and so assignation to the early Paleozoic (post-Cadomian) rift succession deposited at the northern margin of Gondwana, cannot yet be precluded.     

Evidence of glaucophane-schist facies metamorphism in the East Karkonosze complex,West Sudetes,Poland

In the East Karkonosze complex (Karkonosze = Riesengebirge), which occurs at the northern margin of the Bohemian massif, rocks of the glaucophane-schist facies and transitions between the glaucophane-schist facies, greenschist facies and epidote-amphibolite facies are present. They belong to the Leszczyniec Volcanic Formation (LVF) of Cambrian/Ordovician age and to the mainly metasedimentary Czarnów Schist Formation (CSF) of Ordovician/Silurian age. Similar high-pressure, low-temperature rocks occur in the southern Karkonosze and in the Kaczawa Mountains within metavolcanic formations of approximately the same age. Petrographic and electron probe studies show complex relationships between minerals including chemical zoning. In the East Karkonosze three stages of metamorphism pre-dating contact metamorphism by late Variscan (lowermost Upper Carboniferous) granite intrusion were distinguished [stage 1: ocean floor, amphibolite facies (observed only in part of the LVF); stage 2: high-pressure, low-temperature, variably glaucophane-schist facies, high-pressure greenschist facies and epidote-amphibolite facies; stage 3: medium-pressure greenschist facies accompanied by strong deformations]. Glaucophane-schist facies rocks formed in stage 2 survived the later stages of metamorphism only in the southern part of East Karkonosze, i. e. in Lasocki Range and Rýchory. Using the Maruyama et al. (1986) geobarometer the glaucophane-bearing rocks formed at 6.5–7 Kb, those with crossite at 5–6 Kb and rocks with magnesioriebeckite/riebeckite at 4–5 Kb. Other estimates for glaucophane-bearing rocks give somewhat higher values of pressure, i. e. 7–12 Kb at temperatures between 300 and 530°C. The highest temperatures are recorded in the glaucophane- and garnet-bearing rocks. Stilpnomelane may occur in all of these rocks. The subduction/obduction episode responsible for this high-pressure, low-temperature metamorphism is considered to have taken place in the early Variscan, although no geochronology is yet available to confirm this.     

High-pressure granulites from the Sudetes (south-west Poland): evidence of crustal subduction and collisional thickening in the Variscan Belt

Two high-grade gneissic complexes of the Western Sudetes, the Góry Sowie Block and the Śnieżnik area complex, contain small, predominantly felsic granulitic inliers with minor Cpx-bearing intercalations. The P–T  conditions of the granulite facies events and of the subsequent re-equilibration are estimated using the ternary feldspar thermometer and the Geo-Calc computer program (version TWQ, Jan 92).
In the Góry Sowie granulites, the peak granulitic event occurred at c . 18–20 kbar and 900 °C, and the late decompressive re-equilibration within a range of 4–10 kbar and temperatures decreasing to 600–700 °C. The latter event is thought to have coincided with the main metamorphic phase in the surrounding gneisses.
The P–T  estimates are more scattered in the Śnieżnik granulites, but the peak conditions for the granulitic event are estimated at pressure over 22 kbar (possibly around 30 kbar) and temperature exceeding 900 °C. The analysed samples from the Śnieżnik area bear no significant evidence of lower-pressure re-equilibration.
Integrating the thermobarometric data and some age constraints indicates that the Góry Sowie granulites belong to the early stage 'type I' granulites of the Variscan Belt ( c . 400 Ma old), which are interpreted as fragments of continental crustal materials subducted to mantle depths in the earliest stages of the Variscan orogeny. The Śnieżnik granulites are more problematic; they may belong to a 'younger high- P suite' ( c . 350 Ma old), widespread in the southern and eastern parts of the Bohemian Massif, and possibly related to the climax of the Variscan continent–continent collision.     

Early Carboniferous blueschist facies metamorphism in metapelites of the West Sudetes (Northern Saxothuringian Domain,Bohemian Massif)

The metamorphic evolution of micaschists in the north‐eastern part of the Saxothuringian Domain in the Central European Variscides is characterized by the early high‐pressure M1 assemblage with chloritoid in cores of large garnet porphyroblasts and a Grt–Chl–Phe–Qtz ± Pg M2 assemblage in the matrix. Minerals of the M1–M2 stage were overprinted by the low‐pressure M3 assemblage Ab–Chl–Ms–Qtz ± Ep. Samples with the best‐preserved M1–M2 mineralogy mostly appear in domains dominated by the earlier D1 deformation phase and are only weakly affected by subsequent D2 overprint. Thermodynamic modelling suggests that mineral assemblages record peak‐pressure conditions of ≥18–19 kbar at 460–520 °C (M1) followed by isothermal decompression 10.5–13.5 kbar (M2) and final decompression to <8.5 kbar and <480 °C (M3). The calculated peak P–T conditions indicate a high‐pressure/low‐temperature apparent thermal gradient of ～7–7.5 °C km^?1. Laser ablation inductively coupled plasma mass spectrometry isotopic dating and electron microprobe chemical dating of monazite from the M1–M2 mineral assemblages give ages of 330 ± 10 and 328 ± 6 Ma, respectively, which are interpreted as the timing of a peak pressure to early decompression stage. The observed metamorphic record and timing of metamorphism in the studied metapelites show striking similarities with the evolution of the central and south‐western parts of the Saxothuringian Domain and suggest a common tectonic evolution along the entire eastern flank of the Saxothuringian Domain during the Devonian–Carboniferous periods.     

Paleomagnetism of Carboniferous sediments from the West Sudetes (SW Poland)

The studied Carboniferous flysch and molasse sediments from the Intra-Sudetic Basin correspond to the period from Middle Visean to Early Autunian. Main magnetic minerals carrying the natural remanent magnetization (NRM) are goethite, magnetite, maghemite and hematite, all usually secondarily formed and/or remagnetized due to several tectonometamorphic events. In most samples several NRM components were isolated. One of them is usually a Jurassic-Triassic overprint. Some others define the Westphalian-Early Permian segment of the declination and inclination trajectory for the Sudetes calculated according to the reference apparent polar wander path for the Baltica plate. The Sudetic path is slightly shifted to the east compared to the reference path, suggesting the possibility of independent movements of the Sudetes during this time. The majority of isolated NRM components are secondary and related to the Sudetic orogenic phase and later tectonometamorphic activity.     

Enigmatic sedimentary–volcanic successions in the central European Variscides: a Cambrian/Early Ordovician age for the Wojcieszów Limestone (Kaczawa Mountains,SW Poland) indicated by SHRIMP dating of volcanic zircons

Metamorphosed volcanic and sedimentary successions in the central European Variscides are, in many areas, poorly biostratigraphically constrained, making palaeotectonic interpretations uncertain. In such instances, geochronological data are crucial. Sensitive high resolution ion microprobe (SHRIMP) dating of volcanic zircons from a quartz–white mica schist (interpreted as deformed metavolcaniclastic/epiclastic rock) within the stratigraphically controversial Wojcieszów Limestone of the Kaczawa Mountains (Sudetes, SW Poland), near to the eastern termination of the European Variscides, has yielded an age of 498 ± 5 Ma (2σ error), corresponding to late Cambrian to early Ordovician magmatism in that area and constraining the depositional age of the limestones. The new SHRIMP data are not consistent with the recent revision of the age of the Wojcieszów Limestone based on Foraminifera findings that ascribed them to a Late Ordovician—Silurian or even younger interval. They are though, consistent with sparse macrofossil data and strongly support earlier interpretations of the lower part of the Kaczawa Mountains succession as a Cambrian–Early Ordovician extensional basin‐fill with associated initial rift volcanic rocks, likely emplaced during the breakup of Gondwana. Copyright © 2008 John Wiley & Sons, Ltd.     

Accretion and post-accretion metamorphism in subduction complex terranes of the New England Fold Belt, eastern Australia

Abstract Regional metamorphic rocks that form Late Palaeozoic subduction complexes in central Queensland, Australia, are products of two metamorphic episodes. Synaccretion metamorphism (M1) gave rise to prehnite-pumpellyite and greenschist facies rocks, whereas a subsequent episode (M2) at about 250 Ma formed upper greenschist to upper amphibolite facies rocks of both intermediate- and low-pressure type, probably in a compressive arc or back-arc setting. A similar pattern can be recognized for 1000 km along the New England Fold Belt, although at several localities, where higher grade rocks are exposed, metamorphism was essentially continuous over the M1-M2 interval, with a rapid rise in geothermal gradient at the end of accretion. Where out-stepping of tectonic elements has occurred at long-lived convergent margins elsewhere, similar overprinting of high- by lower-pressure facies series is anticipated, complicating the tectonic interpretation of metamorphism. The discrete character of metamorphic events may be blurred where conditions giving rise to a major episode of accretion and out-stepping are followed by the subduction of a major heat source.     

An example of high-pressure low-temperature metamorphic rocks from an island-arc: the Paikon Series (Innermost Hellenides, Greece)

Abstract The Paikon Series is considered to be a volcanic arc sequence with a mainly neritic sedimentary sequence and bimodal tholeiitic volcanism of early Mesozoic age. The metamorphic assemblages are syn- to post-kinematic with respect to a pre-Tithonian tectonic phase and range from the lawsonite-chlorite-albite facies through transitional Na-amphibole-greenschist facies to the chlorite sub-zone of the greenschist facies. The metamorphic imprint of the Paikon Series corresponds to a temperature range from less than 330° C to ± 450° C under a total pressure from 3 kbar to 6–7 kbar. The overprinting of these facies on an earlier blueschist assemblage, related either to a subduction zone or to a tectonic overpressure caused by thrusting, is suspected.     

吉林延边开山屯地区蓝片岩相变质作用——来自硬绿泥石＋纤锰柱石＋多硅白云母组合的证据

吉林延边开山屯低级变质作用发育于兴凯地块西南晚古生代活动大陆边缘,这里产出二叠纪末的消减增生杂岩。低级变质作用矿物除冻蓝闪石、阳起石、玉髓、黝帘石、多硅白云母、绿泥石、钠长石外,还在灰黑色变泥质岩中发现硬绿泥石 纤锰柱石 多硅白云母组合。这是国内首次报道的以泥质岩为原岩并具有硬绿泥石 纤锰柱石标志矿物组合的蓝片岩相岩石。研究表明,该组合的形成温度290．14(或370．8)℃,具明显的低温特征。     

High-pressure-low-temperature metamorphism of granitic orthogneiss in the Brooks Range, northern Alaska

Abstract Granitic orthogneiss is widespread throughout the metamorphic core of the Brooks Range in both the ductilely deformed blueschist/greenschist facies Schist Belt and the lower grade Central Belt (= Skajit allochthon) to the north. Orthogneiss occurs as large metaplutonic massifs and in small bodies enclosed within metasedimentary rocks. Crystallization ages for the granitic protoliths range from Proterozoic through Devonian (U-Pb zircon); the K-Ar system was reset during Cretaceous metamorphism. Mineral assemblages of the orthogneisses reflect nearly complete re-equilibration during Jurassic-Cretaceous collisional orogenesis in northern Alaska. The most common metamorphic paragenesis in orthogneiss is: Qtz + Kfs + Ab + Phe + Bt ± Ep, Ttn, Rt, Ap, Chl, Cal. Constituent minerals from 16 Brooks Range orthogneiss samples were analysed with the electron microprobe. Phengite from the Schist Belt samples is highly enriched in Al-celadonite, with Si values up to 3.50 per formula unit (on an 11-oxygen basis). Central Belt samples contain phengite with lower Si content (±3.38 p.f.u.). In nearly all samples, Si content of phengite varies considerably, reflecting partial re-equilibration to lower pressure and/or higher temperature conditions. Metamorphic conditions were estimated using the Phe-Bt-Kfs-Qtz barometer and the two-feldspar solvus thermometer. The results indicate that the Schist belt underwent high-pressure/low-temperature metamorphism (generally 9-12 kbar at 375-430° C), consistent with the widespread development of glaucophane + epidote/clinozoisite and lawsonite pseudomorphs in other rock types. The Central Belt also experienced a relatively high P-T metamorphism, with most samples yielding pressure estimates in the range 5-8 kbar (at 325-415° C). These results confirm the existence of two metamorphic belts in the core of the Brooks Range that differ in metamorphic conditions by up to 5 kbar. The range in Si content in phengite from Schist Belt samples is consistent with isothermal decompression of up to 5 kbar.     

Petrological constraints on the eclogite- and blueschistfacies metamorphism and P-T-t paths in the Western Alps*

Phase relationships in the model mafic system and geothermobarometry allow discrimination of four main groups of high-P rocks in the nappes of the Western Alps: very high-P eclogite-facies (including kyanite eclogites and coesite-pyrope assemblages), eclogite-facies (paragonite-zoisite eclogites), high-T blueschist-facies (glaucophane-garnet ± lawsonite assemblages) and low-T blueschist-facies (glaucophane-lawsonite ± pumpellyite assemblages). The blueschist-facies-eclogite-facies transition is promoted chiefly by increasing T, low bulk X_Mg and relatively low μ_H2O. The variety of assemblages and the heterogeneous approach to equilibrium observed in the Alpine rocks are not only constrained by the intersection of the reaction surfaces in P-T-X space, but also by the effect and timing of the processes which control kinetics (i.e. pervasive deformation and fluid infiltration). The faster rate of dehydration reactions relative to hydration reactions along with the fact that different bulk compositions crossed the reaction curves at different temperatures (and times), all may have induced μ_H2O gradients and contributed to the heterogeneous distribution of deformation through a process of reaction-enhanced ductility. Also mass-transfer may have been an effective process in determining the type of high-P assemblage in particular rock volumes. As regards the P-T-t paths, only the post-climax histories are recorded well in the Alpine nappes. Post-eclogitic exhumation paths at decreasing temperatures characterize structurally higher nappes which were first subducted during the early-Alpine (Cretaceous) event. In contrast, more or less isothermal decompression paths characterize structurally deeper nappes formed by westward propagation of the underthrust surfaces during the early-Alpine event and the subsequent meso-Alpine (Palaeogene) collision between the ‘European’and ‘African’plates. In the Western Alps, prevalent eclogite-facies conditions were attained during the metamorphic climax of the early-Alpine subduction, while blueschist-facies recrystallization characterizes the early-Alpine exhumation of the eclogitized units and the subsequent intracontinental underthrusts linked to the meso-Alpine continental collision.     

Environmental problems in the Sudetes, Poland

Due to the abundance of mineral deposits associated with the metamorphic rocks of the Sudetes, the area was intensively settled and developed by the end of the Middle Ages. Several centuries later, the first attempts were made to rehabilitate the devastated natural environment. The advent of capitalism brought further damage to the environment, which has remained almost unchanged to this day. Improvements in the context of transfrontier cooperation have arisen out of the economic crisis and the disintegration of the Soviet bloc. However, the Sudetes are still a problem area, and various industries are competing for local resources. The main problem facing the region is the need to rehabilitate its natural environment and create a more balanced local economy. Tourism, forestry, agriculture and ‘clean’ industrial technologies have the greatest potential. This revised version was published online in July 2006 with corrections to the Cover Date.     

Settlement and sustainability in the Polish Sudetes

The paper summarises the history of human settlement in the Sudetes from the Bronze Age. A more intensive stage was reached in the Middle Ages when settlers from the west established new villages deep in the mountain valleys. By the beginning of the 20th century the Sudetes were already overpopulated but after a near-complete ethnic replacement from a German to a Polish population in 1945–8, population continued to grow until the 1980s. However, the economic system was hardly sustainable by this time. There were many polluting industries in the region and massive transboundary pollution from adjacent areas of Czechoslovakia and Germany had a devastating effect on the forests. Moreover, subsidised state agriculture placed heavy pressure on vulnerable mountain grazings. Since 1989 there has been a process of deindustrialisation in the Sudetes and surrounding areas and, with the disappearance of the state farms and the reduction in subsidies, agriculture is now better adjusted to the natural potential and is complemented by a promising start with agrotourism. The population of the region is growing relatively slowly (0.8% per annum 1956–1999), with the rural areas now in decline. A sustainable future for the region is now a possibility, but while there is a consensus for continued environmental reconstruction, supported by alternative economies, this will have to be carefully managed in the years ahead when EU accession may bring heavier development pressures than those evident at the moment. This revised version was published online in July 2006 with corrections to the Cover Date.     

The greenschist metamorphism of Archaean synvolcanic stocks near Wawa, Ontario, Canada

Abstract Two Archaean synvolcanic stocks with contact aureoles occur in the Wawa greenstone belt near Wawa, Ontario, Canada. The Gutcher Lake and Jubilee stocks consist mainly of granitoid trondhjemite with feldspar laths mottled by white mica + calcite + epidote and rimmed by clear albite. Biotite is partly or wholly pseudomorphosed by chlorite + sphene; some epidote is partly altered to calcite + chlorite. The granitoid phase grades into a foliated phase of quartz + albite + white mica + calcite + chlorite near fracture zones traversing the stocks.
The alteration of the Gutcher Lake stock along its foliated margin involved addition of K₂O, H₂O + CO₂, MnO, plus Rb; loss of CaO plus Sr; and a shift in Fe⁺²/Fe_t from 0.66 to 0.81. The alteration of the Jubilee stock along the Darwin Shear involved addition of H₂O + CO₂; loss of Sr; and no significant shift in Fe⁺²/Fe_t. The greenschist alteration also modified the contact aureoles bordering both stocks.
One interpretation is that regional metamorphism in the Archaean overprinted a greenschist assemblage on both stocks. The alteration was intense near fracture zones and sporadic remote from fractures. Lower integrated water to rock ratios along the Darwin Shear compared to the margin of the Gutcher Lake stock may explain the comparatively lower perturbation of the element abundances and redox state of iron.     

A Lower Palaeozoic shallow water sequence in the eastern European Variscides (SW Poland): provenance and depositional history

The Gackowa Formation of inferred Cambrian —Ordovician age is part of the metamorphosed pre-Variscan basement of the southern Kaczawa Mountains of the Sudetes region, south-west Poland. Previously variously interpreted as lavas, tuffs and sandstones, it is shown to consist of about 200 m of originally well-sorted siliclastic sedimentary rocks within a sequence of predominantly mafic volcanic rocks. Four facies have been distinguished based on relict sedimentary structures and textures and these suggest that deposition took place on a storm-dominated shelf, mostly above the wave base. The petrography, detrital zircon morphologies and geochemistry suggest affinity with, and derivation in large part from, acid volcanic rocks at a comparable stratigraphic position in a separate tectonostratigraphic unit to the south. The Gackowa Formation and its acid volcanic source rocks have a clear continental geochemical signature, in contrast with the mantle-derived basic/bimodal volcanic rocks below and above; it is suggested that the parent acid magma originated by crustal melting during the ascent of these mantle-derived magmas. A continental crust setting is inferred for the deposition of the Gackowa Formation sandstones, thus suggesting a continental setting for the associated within-plate basalts. The entire volcanic/sedimentary succession resembles elements of the Lower Palaeozoic of Germany, and all may have formed in an initial rift setting during Late Precambrian to Ordovician times.     

Regional and local patterns of low-grade metamorphism in the North Shore Volcanic Group, Minnesota, USA

Abstract The North Shore Volcanic Group in northern Minnesota is part of the Middle Proterozoic Keweenawan sequence, one of the largest plateau lava provinces in the world. The primary geochemistry of the basalts suggests that volcanism occurred in an intracontinental rift environment. The subaerial lava flows, mainly amygdaloidal olivine tholeiites and tholeiites, have undergone low-grade metamorphism from zeolite to lower greenschist facies. On the basis of alteration phases replacing the primary magmatic minerals, infilling amygdales and veins, and replacing secondary minerals, the following zones have been distinguished: (1) thomsonite-scolecite-smectite, (2) heulandite-stilbite-smectite, (3) laumontitechlorite-albite, (4) laumontite-chlorite-albite ± prehnite ± pumpellyite and (5) epidote-chlorite-albite ± actinolite zone. In addition to the overall zonation based on mineral parageneses, zonations in the composition of the Ab content of the newly formed albite replacing primary Ca-rich plagioclase and of the newly formed mafic phyllosilicates are observed within the sequence and within single flows. Mafic phyllosilicates in the upper part of the sequence (mainly smectites and mixed-layer smectite/chlorites) display high Si and Ca + Na + K contents, whereas in the lower part of the sequence the amounts of Si and Ca + Na + K are markedly lower (mainly chlorites and mixed-layer chlorite/smectites). Similar zonations are observed within the individual flows. The albite content of the newly formed plagioclase is highest, and the Si and Ca + Na + K content of the phyllosilicates lowest in the amygdaloidal flow top while the opposite is true for the massive flow interior. The above features suggest that the overall pattern is one of burial-type metamorphism associated with extension in the rift setting. In detail, the mineral assemblages are controlled not only by the stratigraphic position but also by the flow morphology controlling permeability whose effect on the assemblages is most pronounced in the stratigraphically upper parts. This suggests that at the first stages of alteration (lowest grade) the patterns of fluid flow were important effects in controlling the assemblages. At greater burial depth, assemblages are more homogeneous, perhaps representative of a more even and pervasive flow pattern. Using the observed assemblages at face value to define grade and/or facies, different conditions would be assigned within the different morphological flow portions. Thus at low-grade metamorphic conditions it is essential to integrate assemblages from different morphological flow portions in order to define satisfactorily the overall metamorphic conditions.     

Regional progressive high-pressure metamorphism, Seward Peninsula, Alaska

Abstract Blueschist-facies rocks on the Seward Peninsula constitute a structurally coherent terrane measuring at least 100 × 150 km. Radiometric age data indicate that high-pressure metamorphism probably occurred in Jurassic rather than in Palaeozoic or Precambrian time, as previously suggested. Protolith sediments (Nome Group) are of intracontinental basin or continental margin type, and of lower Palaeozoic and possibly late Precambrian age, thus predating the high pressure metamorphism by more than 200 m.y. Blueschist-facies mineral assemblages were developed in almost all lithologies of the Nome Group, and are best preserved in FeTi-rich metabasites (glaucophane + almandine + epidote) and pelites (glaucophane + chloritoid + phengite). A lawsonite–crossite subfacies was developed in possible Nome Group rocks on the east flank of the Darby Mountains. Albite–epidote–amphibolite facies assemblages characterize Nome Group rocks in the southwestern part of the Peninsula. Metamorphism in the central zone of the terrane passed from early lawsonitic to subsequent epidote–almandine–glaucophane schist subfacies with the local development (east of the Nome River) of eclogitic assemblages. The high pressure metamorphic minerals were synkinematic with the development of mesoscopic-scale intrafolial isoclinal folds and a flattening foliation of consistent orientation. Initiation of uplift probably corresponded to the growth of barroisite rims on earlier sodic and actinolitic amphiboles, and partial post-kinematic greenschist facies replacements record later stages of decompression. Ophiolites and melange are not associated with the Seward Peninsula blueschists. The high-pressure metamorphism was caused by tectonic loading of a continental plate by an allochthon of indeterminate origin. The PT conditions of high pressure metamorphism were approximately 9–11 kbar, 400–450°C, thus falling between the PT paths of the Shuksan and Franciscan terranes.     

Metamorphism of the Bikou Group in the Shanxi-Gausu-Sichuan Border Region

The Blkou Group on the Shaanxi-Gansu-Sichuan border is composed of Mid-Late Proterozoic metamorphosed bimodal volcanic rocks and flysch sediments. Its metamorphism may be divided into the blueschist and greenschist facies. Three metamorphlc zones, i.e. zones A, B, and C, may be distinguished on the basis of the field distribution of metamorphlc rocks and the variation of b0 values of muscovite. Blueschists are characterized by coexistence of sodic amphiboles and epidote and occur as stripes or relict patches in extensive greenschists of zone A. Studies of metamorphic minerals such as amphiboles, chlorite, epidote and muscovite and their textural relationships indicate that blueschists and greenschists were not formed under the same metamorphic physico-chemical conditions. The blueschist facies was formed at temperatures of 300-400℃ and pressures of 0.5-0.6 GPa. The greenschist facies in zones A and B has similar temperatures but its pressure is only 0.4 GPa or so. The transition from the blueschist to     

Deep‐burial alteration of early‐diagenetic carbonate concretions formed in Palaeozoic deep‐marine greywackes and mudstones (Bardo Unit,Sudetes Mountains,Poland)

Carbonate concretions formed in bathyal and deeper settings have been studied less frequently than those formed in shallow‐marine deposits. Similarly, concretions affected by catagenetic conditions have rarely been reported. Calcite concretions in deep‐marine mudstones and greywackes of the Bardo Unit (Sudetes Mountains, Poland) formed during early diagenesis and were buried to significant depths. Petrographic and geochemical (elemental and stable C and O isotopic) analyses document their formation close to the sediment–water interface, prior to mechanical compaction within the sulphate reduction zone and their later burial below the oil window. Although the concretions were fully formed during early diagenesis, the effects of increased temperature and interaction with late‐diagenetic interstitial fluids can be discerned. During maximum burial, the concretions underwent thorough recrystallization that caused alteration of fabric and elemental and O isotope composition. The initial finely crystalline cement was replaced by more coarsely crystalline, sheaf‐like, poikilotopic calcite in the concretions. These large calcite crystals engulf and partially replace unstable detrital constituents. The extremely low δ¹⁸O values (down to ?21·2‰ Vienna Pee Dee Belemnite) in the concretions are the result of the increased temperature in combination with alteration of volcanic glass, both causing a significant ¹⁸O‐depletion of bicarbonate dissolved in the interstitial fluids. Recrystallization led to uniform O isotope ratios in the concretions, but did not affect the C isotope signature. The δ¹³C values of the late‐diagenetic cements precipitated in the greywacke and in cracks cutting through concretions imply crystallization in the catagenetic zone and decarboxylation as a source of the bicarbonate. These late‐diagenetic processes took place in a supposedly overpressured setting, as suggested by clastic dykes and hydrofractures that cut through both concretions and host rock. All of these features show how the effects of early and late diagenesis can be distinguished in such rocks.     

Metamorphism of the Bikou Group in the Shanxi-Gausu-Sichuan Border Region1

Abstract The Bikou Group on the Shaanxi-Gansu-Sichuan border is composed of Mid-Late Proterozoic metamorphosed bimodal volcanic rocks and flysch sediments. Its metamorphism may be divided into the blueschist and greenschist facies. Three metamorphic zones, i.e. zones A, B, and C, may be distinguished on the basis of the field distribution of metamorphic rocks and the variation of b₀ values of muscovite. Blueschists are characterized by coexistence of sodic amphiboles and epidote and occur as stripes or relict patches in extensive greenschists of zone A. Studies of metamorphic minerals such as amphiboles, chlorite, epidote and muscovite and their textural relationships indicate that blueschists and greenschists were not formed under the same metamorphic physico-chemical conditions. The blueschist facies was formed at temperatures of 300-400°C and pressures of 0.5–0.6 GPa. The greenschist facies in zones A and B has similar temperatures but its pressure is only 0.4 GPa or so. The transition from the blueschist to greenschist facies is a nearly isothermal uplift process. The rock and mineral assemblages of the Bikou Group indicate that the blueschist facies metamorphism of the group might be related to crustal thickening or A-subduction accompanying the closure of an intracontinental small ocean basin.