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1.
Particulate matter concentration and assessment of its movement pattern is crucial in air pollution studies. However, no study has been conducted to determine the PM10 concentration using atmospheric correction of thermal band by temperature of nearest dark pixels group (TNDPG) of this band. For that purpose, 16 Landsat Enhanced Thematic Mapper plus ETM+ images for Sanandaj and Tehran in Iran were utilized to determine the amount of PM10 concentration in the air. Thermal infrared (band 6) of all images was also used to determine the ground station temperature (GST b6) and temperature of nearest dark pixels group. Based on atmospheric correction of images using temperature retrieval from Landsat ETM+, three empirical models were established. Non-linear correlation coefficient with polynomial equation was used to analyze the correlations between particulate matter concentration and the ground station temperature for the three models. Similar analyses were also undertaken for three stations in Klang Valley, Malaysia, using 11 Landsat ETM+ images to show the effectiveness of the model in different region. The data analysis indicated a good correlation coefficient R = 0.89 and R = 0.91 between the trend of the result of temperature of nearest dark pixels group b6 ? (GST b6 ? GST) model and the trend of PM10 concentration in Iran and Malaysia, respectively. This study reveals the applicability of the thermal band of Landsat TM and ETM+ to determine the PM10 concentration over large areas.  相似文献   

2.
The Kathmandu valley urban area is growing as a metropolis. Bishnumati corridor in Kathmandu valley is is a target of increased pollution. The unabated solid waste land-filling on either side of the river-bank and animal slaughter houses and biological waste arising from these activities, busy commercial and high residential density characterize the corridor. Six areas, namely Teku Dovan, Kalimati Bridge, Kankeswori, Shova Bhagwati, Balaju and New Bus Park areas, all areas falling within the Bishnumati corridor were selected to measure air quality representing corridor. The pollutants quantified were respirable particulate matter — PM10, sulphur dioxide and oxides of nitrogen. The air-borne microbial flora and fungi load quantification were also carried out. Teku Dovan (918.92 μg/m3) and Shovabhagavati areas (847.45 μg/m3) showed higher levels of particulates. Kankeswori area showed highest levels of aerial bacterial (3.7×107 cfu/m3) and fungal load (4.8×108 cfu/m3). The PM10 levels at all the sites are substantial and fall in the categories of ’Harmful’ and ’Hazardous’ quality of air suggesting that the corridor needing intervention to minimize the risk from air pollution. Non-judicious open-air combustion of the solid waste contributes to air pollution. Heavy traffic and few roads not clad with asphalt; perceivable mal-odor and persistent stench emanating from the indiscriminate disposal and consequent putrefaction processes, dense population and increased commercial activities are other principal contributing sources to the resulting pollution of the corridor. In view of this status, mitigating measures to minimize exposure to the toxicants in the corridor is a necessity.  相似文献   

3.
成都市近地表大气尘铅分布特征及源解析   总被引:7,自引:1,他引:7  
分析了成都市近地表大气尘样品铅及其同位素含量比的测定数据,铅含量变化范围为(119.76~1327.42)×10-6,均值为374.51×10-6,统计标准偏差为273.36,变异系数为0.73,说明成都市近地表大气尘铅含量变化大。燃煤飞灰的放射性成因铅明显高于汽油和柴油,可作为鉴别大气尘铅来源的证据。铅同位素含量数据表明成都市近地表大气尘的铅污染是复合污染源所致,其中,相对清洁区污染以建筑扬尘为主,中度污染区是汽车尾气和扬尘的叠加作用,重污染区是燃煤飞灰汽车尾气和工业污染源的综合表征。  相似文献   

4.
The main goal of this study is the derivation of Carlson’s Trophic State Index (TSI) through the remote sensing of four different Case-2 waters in the Mediterranean region such as Cyprus and Greece. TSI SD is derived through extensive field ground campaign of Secchi Disk Depth measurements for the Asprokremmos Dam, located in Paphos District in Cyprus; Alyki Salt Lake, located in Larnaca District in Cyprus; and in Karla Lake, located in Volos District in Greece; and finally to three coastal water areas in the Limassol coastal area. Several regression models have been applied in order to develop the best regression model between the TSI SD and in-band reflectance values for Landsat TM/ETM derived from spectroradiometric measurements using a GER-1500 field spectroradiometer over the main case study area in Asprokremmos Dam in Cyprus. Finally, we apply several regression models for Asprokremmos Dam for retrieving the suitable Landsat TM/ETM band or band combinations (obtained from field spectroradiometric measurements) in which TSI SD can be determined. Indeed, the best regression model has been obtained by correlating ‘TSI Versus Band2/Band3’, with R2=0.89. All field TSI SD and in-band reflectance values from the four different water bodies have been used to develop the best fitted model for the established TSI SD Versus Band2/Band3 model. We find that the exponential regression model provides the best fitted equation over the four different water bodies.  相似文献   

5.
The Velenje area (almost 200 km2 with over 31,000 inhabitants) is based on the Šalek Valley, which became a leading area of industrialisation and urbanisation after the Second World War, with consequent pollution problems. Various industrial plants polluted the river Paka while more serious hazards arose through the coal mine which is a still causing landscape subsidence and the thermal power station in the neighbourhood of Šoštanj which is a major source of sulphur dioxide and nitrogen oxide pollution. In 1987 there was an ecological protest which marked the beginning of a sustainable development strategy for the community. During the past decade programmes have dealt with the degradation of air, soil and water to achieve cleaner air, a transformation in landuse and enhancement the river's formerly weak self-purifying capabilities. This article examines the changes in the valley since the attention of the authorities was drawn to the deterioration of living conditions. Despite the pressures of transition which have seen unemployment rising to over ten percent, significant environmental improvements have been made and the area stands as a model for the rest of the country. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

6.
Through collected precipitation samples continuously to research the precipitation chemical characteristics and the water vapor source in Shiyang River Basin, Northwestern China, a total of 121 precipitation samples had been collected in the Shiyang River Basin from July 2013 to July 2014. The results showed that, during the period of sampling, the variation range of pH value of precipitation ranged from 6.62 to 8.53 in Shiyang River Basin and the average was 7.46. The EC values ranged from 17.28 to 787.00 μs/cm, with a mean 186.66 μs/cm. Ca2+ and Na+ dominated cations and accounted for 71.80% of total cations composition, while SO4 2? and NO3 ? dominated anions with a contribution of 82.18%. The main ionic sources are local dust aerosols and the dust from Central Asia and Northwestern China arid regions brought by the westerly, and the back trajectories also supported it. Back trajectories suggested that the air mass arrived in Shiyang River Basin mainly from the dust sources region in Central or West Asia or Northwestern China through westerly circulation in dry season, while from the Indian Ocean or the Pacific Ocean through monsoon circulation in wet season. The precipitation can be divided into three types based on the vector of water vapor transportation: the monsoon precipitation, the westerly precipitation, and the interaction precipitation (precipitation influenced both by monsoon and westerly). The type of interaction precipitation was major precipitation patterns in study area, and the westerly precipitation came next. The results are also helpful for further understanding the air pollution situation caused by dust events in study area and providing scientific basis for the effective prevention and control of atmospheric pollution.  相似文献   

7.
Air quality monitoring was performed at the measuring sites in the urban-industrial and suburban zone during the period 2005–2007 in Bor (Serbia). Arsenic, lead, cadmium, copper and sulphur dioxide are predominantly of industrial origin as a result of copper production in the study area. The smelter, which is a part of the Mining-Metallurgical Complex Bor, is the major pollution source. As and SO2 are the pollutants which pose the biggest threat for the inhabitants of the Bor area, since the measured concentrations exceed the proposed limit values. The obtained concentrations showed that the endangered areas are in close vicinity of the smelter, as well as in the directions of the prevailing winds. By grouping these pollutants into separate clusters, the results of cluster analysis confirmed high loads of As and SO2 in the air. The results of principal component analysis showed that copper production has major influence on air pollution.  相似文献   

8.
为研究大规模综合机械化采煤氮污染来源及影响程度,选取宁东煤炭基地侏罗纪煤田鸳鸯湖矿区的梅花井井田为研究对象,通过调查取样分析,对梅花井井田地下水三氮污染分布、物源、水文地质条件进行研究。结果表明:(1)宁东煤炭基地鸳鸯湖矿区梅花井井田三氮NH4+、NO3-、NO2-含量范围分别为0.06~0.12mg/L、4.67~234mg/L、0.01~2.01mg/L,与国家地下水质量标准Ⅲ类水质限值对比,NO2-达到重度或极严重污染,主要分布在潜水含水层;NO3-污染级别为中度、轻度污染,超标样点占调查样点的75%,垂向上已延伸到承压含水层。水平空间上无论矿权范围还是矿权外,污染样点均有存在。(2)部分水样中NO3-毫克当量百分数超过25%,对水化学类型产生影响。(3)煤矿区NO3-、NO2-的污染首先与丰富的物源有关,还受煤矿开采扰动、地形地貌条件、垂向补给径流、水文地球化学条件等因素的影响。研究结果为风积沙大型机械化煤矿开采区地下水氮污染的防治提供了可参考依据。  相似文献   

9.
Pollution from urban centers and fossil fuel combustion can decrease forest growth and interfere with physiological processes. To evaluate whether tree growth and the carbon isotope ratio (δ13C) and nitrogen isotope ratio (δ15N) in tree rings can serve as proxies for air pollution, this study compared these indices for poplar (Populus cathayana) growing at urban and suburban locations in Lanzhou, in northwestern China. Basal area increment values were much lower at the urban site than in the suburbs from 1985 to 2009, were negatively correlated with NO2 (r = ?0.56, p < 0.01) and SO2 (r = ?0.52, p < 0.05) emissions from 1990 to 2009, and increased abruptly after the Lanzhou urban steel factory closed. Urban tree-ring δ13C values were not significantly correlated with NO2 and SO2 concentrations, and did not differ significantly between the two sites, indicating that other environmental effects (such as precipitation) masked the pollution effects. Tree-ring δ15N values in the urban samples were much higher than the suburban values. Such differences may be attributable to uptake of 15N-enriched compounds caused by a higher urban N deposition rate. Tree growth is a promising tool for detecting ecophysiological responses of trees to both diffuse and point-source air pollution, but δ13C and δ15N in poplar were not sensitive to point-source air pollution in a heavily polluted environment.  相似文献   

10.
利用1964年美国CORONA间谍卫星影像和1976-2010年的Landsat MSS/TM/ETM+遥感影像, 对青藏高原长江源各拉丹冬地区的冰川进行监测, 获得每10 a间隔的冰川面积数据, 并对冰川制图中的不确定性进行了评估.由于冰川表面比较洁净, 认为该地区冰川变化的不确定性主要由分辨率(Landsat)和人为操作差异造成, 误差可达1%~2%.通过对比发现: 1964-2010年间, 各拉丹冬地区冰川面积总体上减少了45.75 km2, 相对变化为6.80%, 冰川年平均变化速度约为0.99 km2·a-1, 相对变化速度为0.15%·a-1; 该地区冰川总体退缩较为缓慢, 但部分冰川变化显著, 在138条冰川中, 有14条大冰川存在较为明显的变化.在过去的近50 a中, 该地区的冰川并不是都呈退缩状态, 先后有9条冰川出现过前进的现象, 其中有1条冰川一直处于前进状态, 长江源头冰川(姜古迪如北支冰川)先后出现过两次前进, 分别发生在1964-1977年间和2000-2010年间.  相似文献   

11.
Remotely sensed thermal infrared (TIR) data have been widely used to retrieve land surface temperature (LST). LST is an important parameter in the studies of urban thermal environment and dynamics. In the study, an attempt has been made using LANDSAT 8 thermal imagery to compute LST and the associated land cover parameters viz; land surface emissivity (LSE), normalized difference vegetation index (NDVI), normalized difference built-up index (NDBI) and normalized difference water index (NDWI). Landsat 8 TIRS band 10 & 11 (thermal bands) during 21 Oct. 2016, 22 Nov.2016, 24 Dec. 2016 and 09 Jan. 2017 were processed for LST analysis. However, band 5 & band 4 of the imagery was processed for NDVI, band 6 & band 5 for NDBI and band 2 & band 5 for NDWI analysis. LST has been derived from both the bands 10 &11 and validated by in-situ observations on the date and time of satellite overpass from the study area. Band 10 derived LST have shown much temperature difference while comparing with the in-situ observations. However, LST derived from band 11 found similar & close to the in-situ measurements. Relationship between band 11 results and in-situ observed measurements were developed, which has showing a strong correlation with (r2 = 0.991). Land surface emissivity were also evaluated which shows variation in different land cover surfaces like vegetation, settlement, forest cover and water body. The study has proven that land surface temperature derived from satellite band 11 is the actual surface temperature of the study area.  相似文献   

12.
Karst groundwater is a vital resource for drinking, living and irrigation purposes in karst agricultural areas of the world. Due to the vulnerability of karst aquifers, surface pollutants are easily transferred to the subsurface and make karst groundwater be deteriorated, thereby restricting the rational exploitation of karst groundwater resource. In view of this, 49 karst groundwater samples were collected from spring (SW) and underground river (URW) sites in the suburban area of Chongqing City and analyzed for various hydrochemical components. Particularly, the karst groundwater quality was comprehensively uncovered by combining characteristics of hydrogeochemical evolution and health risks caused by nitrate and fluoride. The results revealed that the karst groundwater was slightly alkaline in nature and the water types were mainly characterized by Ca-HCO3 accounting for 93.88% of the total samples due to the heavy dissolution of carbonate rock. The relatively high concentrations of Na+, SO42? and NO3? up to 271.88 mg/L, 277.94 mg/L and 56.94 mg/L were over the corresponding maximum acceptable limits for drinking water, which can be predominately attributed to the emissions of industrial park, dissolution of gypsum and pyrite and excessive application of chemical fertilizers. Although agricultural activities were stopped and chemical fertilizers were no longer applied during the sampling period, long-term application of fertilizers have a persistent adverse effect on the karst groundwater NO3?. The pollution index of the karst groundwater (PIG) revealed that the low pollution and potential pollution zones were noticed in the northwestern parts of the study area. With respect of the SW, all the total hazard index (HI) values were below 1 suggesting no significant health risk. On the contrary, HI values of 0.11–1.16 for adults, 0.15–1.61 for children and 0.17–1.83 for infants in the URW indicated significant noncarcinogenic health risks. Particularly, infants and children were more vulnerable to karst groundwater NO3? than adults. Furthermore, the noncarcinogenic health risks of karst groundwater can be mainly attributed to NO3?, confirmed by the higher contribution ratio (66.55%) to the HI values. Therefore, special and targeted measures need to be taken to decrease the NO3? concentration in agricultural area.  相似文献   

13.
Hydrogeochemical investigations were carried out in the south-eastern part of the Ranga Reddy district, Hyderabad, India, to assess the quality of groundwater for its suitability for domestic and irrigation purposes. The area falls under a semi-arid type of climate and consists of granites and pegmatites of igneous origin of Archaean age. Forty-five representative groundwater samples were collected from bore wells to monitor the water chemistry of various ions, comprising Ca +2, Mg +2, Na +, K +, CO 3 -2, HCO 3 -, SO 4 -2, NO 3 -, Cl - and F -. The results showed that the concentrations of these ions are above the permissible limits for drinking and irrigation purposes. The pollution with respect to NO 3 -, Cl -, and F - is mainly attributed to the extensive use of fertilizers and large-scale discharge of municipal wastes into the open drainage system of the area.  相似文献   

14.
In this paper, the hydrochemical isotopic characteristics of samples collected from geothermal springs in the Ilica geothermal field, Eastern Anatolia of Turkey, are examined and described. Low-temperature geothermal system of Ilica (Erzurum, Turkey) located along the Eastern Anatolian fault zone was investigated for hydrogeochemical and isotopic characteristics. The study of ionic and isotopic contents shows that the thermal water of Ilica is mainly, locally fed by groundwater, which changes chemically and isotopically during its circulation within the major fault zone reaching depths. The thermal spring has a temperature of 29–39 °C, with electrical conductivity ranging from 4,000 to 7,510 µS/cm and the thermal water is of Na–HCO3–Cl water type. The chemical geothermometers applied in the Ilica geothermal waters yielded a maximum reservoir temperature of 142 °C according to the silica geothermometers. The thermal waters are undersaturated with respect to gypsum, anhydrite and halite, and oversaturated with respect to dolomite. The dolomite mineral possibly caused scaling when obtaining the thermal waters in the study area. According to the enthalpy chloride-mixing model, cold water to the thermal water-mixing ratio is changing between 69.8 and 75 %. The δ18O–δ2H compositions obviously indicate meteoric origin of the waters. Thermal water springs derived from continental precipitation falling on to higher elevations in the study area. The δ13C ratio for dissolved inorganic carbonate in the waters lies between 4.63 and 6.48 ‰. In low-temperature waters carbon is considered as originating from volcanic (mantle) CO2.  相似文献   

15.
Suquía River is a medium-sized hydrological system (basin area of ~7,700 km2) that supplies fresh water to Córdoba city, a town of ~1,500,000 inhabitants in central Argentina. This paper examines the present-day hydrochemistry of Suquía River urban catchment analyzing its major and minor dissolved components, and the nutrients variability by means of QUAL-2K modeling software. The Suquía River has bicarbonate-type waters upstream the city and sulfate-type waters right downstream, whereas they exhibit a mixed-to-alkali-type cationic composition. The seasonal analysis of its major dissolved constituents clearly showed a dilution process during the wet season (i.e. austral summer). In the last 20 years, the Suquía River has modified its anionic composition, now showing higher relative concentrations of SO4 2− as a consequence of urban activities. However, trace elements dissolved concentrations do not evidence a strong pollution effect. Nutrients [nitrogen species, total phosphorous (TP)] and related parameters, such as biochemical oxygen demand (BOD), and dissolved oxygen (DO), evidence a clear influence of human activities. The QUAL-2K model was used to evaluate the spatial behavior of selected nutrients and associated variables, (i.e. TP, N–NH4 +, N–NO3 , DO, BOD). Nutrient concentrations are affected by point sources of contaminants, particularly domestic waste and sewage, as well as by diffuse agricultural pollution. A calibrated QUAL-2K modeling exercise clearly shows the impact of the Córdoba city’s municipal wastewater treatment plant on the Suquía River water quality.  相似文献   

16.
We have used correlative analysis between mean December-January-February winter wind velocities, measured at the Xisha Meteorological Observatory (16°50′N, 112°20′E) in the middle of the South China Sea, and mean δ18O data for the corresponding month from Porites lutea coral, collected in Longwan waters (19°20′N, 110°39′E), to obtain a linear equation relating the two datasets. This winter wind velocity for the South China Sea (WMIIscs) can then be correlated to the coral δ18O by the equation WMIIscs = −1.213-1.351 δ18O (‰ PDB), r = −0.60, n = 40, P = 0.01. From this, the calculated WMIIscs-δ18O series from 1944 to 1997 tends to decrease during the 1940s to the 1960s; it increases slightly during the 1970s and then decreases again in the 1980s and 1990s. The calculated decadal mean WMIIscs-δ18O series had a obvious decrease from 5.92 to 4.63 m/s during the period of 1944-1997. The calculated yearly mean WMIIscs-δ18O value is 5.58 m/s from 1944 to 1976 and this decreases to 4.85 m/s from 1977 to 1998. That is the opposite trend to the observed yearly mean SST variation. The yearly mean SST anomaly is −0.27° from 1943 to 1976 and this increases to +0.16° from 1977 to 1998. Spectral analysis used on a 54-year-long calculated WMIIscs-δ18O series produces spectral peaks at 2.4-7 yr, which can be closely correlated with the quasibiennial oscillation band (QBO band, 2-2.4 yr) and the El Ñino southern oscillation band (ENSO band, 3-8 yr). Hence most of the variability of the winter monsoon intensity in the middle of the South China Sea is mainly constrained by changes in the thermal difference between the land and the adjoining sea area, perhaps due to global warming.  相似文献   

17.
Zinccopperite (tentatively named) is a rare native alloy mineral discovered in quartz monzonite-porphyry in the Xifanping area, Yanyuan County, Sichuan Province. It is a new variety of zinc-copper alloy mineral found for the first time in the porphyry-copper deposit in China. Its intergrown minerals are K-feldspar (mainly perthite), albite-oligoclase, quartz and biotite; and the associated minerals include pyrite and chalcopyrite. It is characterized by a golden reflection colour, being isotropic (isometric), with the grain size ranging from 10 to 50 μm, microhardness VHN10= 190 kg/mm2, and reflectance RVis= 67.97%. Electron microprobe (Model JXA-733) analysis shows Cu = 59.15%-62.55% and Zn= 36.32%-39.85%. The crystallochemical formula is Cu6.27-7.0Zn4.0, simplified as Cu7Zn4.  相似文献   

18.

A study of thirteen geothermal springs located in the geothermal field of Guelma, northeastern Algeria, was conducted. Samples were collected during the period between January 2014 and February 2016. Geochemical processes responsible for the chemical composition of thermal and mineralized water were evaluated. The hydrochemical analysis shows that the thermal waters are characterized by the presence of two different chemical facies, the first type SO4–Ca in the east, west and south of Guelma, the second type HCO3–Ca in the south. This analysis also attributed to sodium, chlorides, and sulfates to an evaporitic terrigenous origin by the molar ratio Sr2+/Ca2+. The thermal spring waters from Guelma geothermal system have a meteoric origin, and all samples are immature with strong mixing between hot and shallow waters with 19–38.5% rate of mixing. The silica geothermometer shows that these thermal waters have a temperature varying from 84 to 122 °C and that the water came from a depth of 2100–3000 m through a fault system that limits the pull-apart basin of Guelma. Potential environmental effluent from thermal spas could pollute in both the irrigation and drinking waters, and which imposes danger on the health of the inhabitants of the region.

  相似文献   

19.
《Applied Geochemistry》1986,1(1):153-160
The biaxial absorption bands in amethyst quartz, with peaks at 2.28 eV and 3.54 eV related to Fe4+ and a peak at 3.02 eV—which is the A3 band related to the [AlO4]° trapped hole center, have orientations of maximum light absorption in the basal plane of Brazil-twinnedr-growth sectors paralleling the planes of Brazil optical twinning. Absorption minima are at 90° to the maxima in all cases. The Brazil twinning planes always parallel thea-axes(1210,etc) of quartz and in many cases also parallel planes perpendicular to ther-faces(1011,etc.). These are directions of channels in the quartz structure. The anisotropy ratio,σmaxmin, of the Fe4+ band is that of the A2 absorption band in smoky quartz as would be expected if Fe3+ furnishes electrons to quench the trapped holes causing this absorption band. In the absence of the A1 and A2 absorption bands, the A3 absorption band width at half-maximum decreases from 1.43 to 0.36 eV indicating decreased charge-transfer character of the [AlO4]° center in the absence of the other types of Al trapped-hole centers in quartz. The key to the Brazil twinning in α-quartz are the channels which fill with large Fe3+ ions that force twinning to relieve strain in the structure. Amethyst color results only if aluminum is present substitutionally in the quartz as well as the interstitial iron plus ionizing radiation.  相似文献   

20.
研究目的】安徽长江经济带地热资源储量丰富,未来开发利用前景好,对该区域进行地热资源评价可为安徽省能源结构优化及地热资源可持续开发利用提供科学依据。【研究方法】在分析研究区地质构造、地层岩性、地热流体水化学类型等地质与水文地质条件的基础上,揭示了安徽长江经济带地热资源概况及分布特征,探讨了隆起山地对流型和沉积盆地传导型地热资源的赋存特征,并对其储量及开发利用潜力进行评价。【研究结果】安徽长江经济带地热资源热储主要赋存在巢湖—和县基岩隆起区、大别山隆起区、沿江基岩隆起区、江南隆起等隆起山地及定远断陷盆地、肥东断陷盆地、霍山—九井盆地、庐枞断陷盆地、安庆断陷盆地、宣城断陷盆地等沉积盆地。前者隆起区热储类型为带状,岩性以断裂破碎带中花岗岩为主,后者断陷盆地热储类型为层状及层状兼带状,岩性以砂岩和碳酸盐岩为主。带内热储主要为偏硅酸·氟热矿水,隆起山地型地热流体水化学类型主要为SO4、HCO3型水,沉积盆地型地热流体水化学类型主要为HCO3型水。通过潜力评价可知,隆起山地型地热资源潜力较小,且处于开发利用状态的地热田基本处于超采状态;沉积盆地型地热资源潜力相对较大,其中潜力大、中和小的盆地分别有4处、6处和10处。【结论】安徽长江经济带区域内地热资源潜力分布不均,地热资源需要分区规划利用,并且需要考虑高氟、高矿化度热矿水利用造成的地表水环境污染。  相似文献   

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