四万大气压以下岩石的高压静水压缩试验

本文介绍了内径达20毫米的活塞圆筒式高压静水压缩试验装置,该装置可在0～4500兆帕压力范围内进行P-V关系试验;描述了用该裝置进行岩石高压静水压缩试验的方法及量测技术;详细地提供了大理岩、石英砂岩、花岗岩的高压P-V关系试验结果。试验中发现大理岩在1780兆帕时发生晶相变化。     

考虑温度效应的岩石损伤内时本构关系

本文根据岩石类材料受载时的损伤破坏机理,首次引入两个损伤变量 D_1和 D_0用以反映外载荷体量和偏量的作用,在内时理论的基础上建立起考虑温度效应的岩石损伤本构方程,并导出具有明确物理意义的本构方程增量型关系式。在不同温度下用大理岩试样进行了压缩实验和声发射实验。根据实验所得结果,确定了本构方程中材料的所有参数,得到了大理岩材料受温度影响其性质发生变化的一些有意义的结论。     

Experimental Study on Compressive Deformation of Marble Under Triaxial Stress States

This paper is presented to discuss emphatically the characteristics of compressive deformation of marble under the three-dimentional stress states and the researches of the influences on stress-strain relationship, strength , and failure mechanism by different loading paths. The tests that have been conducted included the constant confining pressure repeated loading, constant stresses, equal proportional loading or ynloading, the hydrostatic and uniaxial tests. The Model CBS-2 digital displacement apparatus manufacfured by our institute was used for measurement in these tests. The probes were directly fixed between the top and bottom fillers of specimen in a high pressure cylinder . It could be used to measure the deformation of specimen after failure, consequently there has a sufficient range for measuring deformation than that of electric strain gauge. The stress-strain relationships for different loading paths are given, and the author proposed some opinions to these problems.     

三向应力状态下大理岩压缩变形试验研究

本文着重讨论大理岩在三向应力状态下压缩变形特性试验研究.探讨了不同的加荷路径对应力-应变关系、强度及破坏机制等的影响.进行了恒侧压、反复加压、等比加压、应力常量,卸荷等试验研究,此外还进行了无侧向应变及静水压等试验.该试验采用了我所自制的 CBS-2型数字显示位移测量仪进行测量,探头直接固定在高压筒体内岩样上下垫块之间,可以测出岩样破裂后的变形,克服了过去采用电阻片量程不够的问题.     

温度周期作用下大理岩三轴蠕变试验与理论模型研究

为了解温度周期作用对大理岩蠕变力学特性的影响,采用温度-应力-渗流耦合的岩石力学三轴流变试验系统对大理岩进行了不同温度及温度周期变化下三轴压缩蠕变试验。基于试验结果,研究了大理岩试样在不同温度及温度周期变化下轴向应变随时间的变化规律,分析了不同温度及温度周期变化下蠕变的变形机制,掌握了温度对大理岩三轴蠕变影响的基本规律,并且建立了考虑温度及温度周期变化影响的改进的Burgers模型。理论值与试验结果非常接近,表明考虑温度及温度周期变化的改进Burgers模型适合描述大理岩的黏弹性蠕变特征。为长期暴露于外部环境下的岩质边坡的长期稳定性分析提供了重要的参考依据。     

大理岩常规三轴压缩下强度和变形特性的试验研究

通过在伺服试验机上对中、粗颗粒大理岩进行常规三轴试验,基于试验结果,研究了两种颗粒大理岩的强度和变形特性。结果表明,低围压时岩样内部材料并未均匀化,岩石表现为应变软化特性;而高围压时岩样内部材料强度由低到高逐渐屈服,变形趋于均匀,岩石出现塑性流动特性。岩石的峰值应变与围压显著成正线性关系;中颗粒和粗颗粒岩样之间确实存在差异,但内摩擦系数可以表征材料力学性质,与粒径没有关系;岩石残余强度对围压的敏感性显著高于峰值强度。     

砂土充填大理岩节理的剪切强度经验公式

为研究砂土充填对节理抗剪强度的影响,利用GCTS（RDS?200型）岩石剪切测试系统对4种不同摩擦系数砂土充填的粉晶大理岩节理进行了直剪试验。结果表明：相同法向应力下,未充填节理的峰值剪切应力大于充填节理的峰值剪切应力,说明砂土的存在降低了节理的剪切强度;由节理面三维形貌参数最大谷深 表征节理面粗糙程度,得到了未充填节理的峰值剪切强度公式,公式预测值与试验值基本吻合;得到了用充填砂土摩擦系数表达的充填节理峰值剪切强度公式,公式预测值与试验值较为吻合。研究结论对充填节理岩体稳定性评价具有一定指导意义。     

水对岩石亚临界裂纹扩展及门槛值的影响研究

亚临界裂纹扩展是岩体工程时间相依性的主要原因之一。采用常位移松弛法,对饱水和干燥两种状态下的大理岩、花岗岩双扭试件进行了亚临界裂纹扩展试验研究,获得了两种岩石在两种状态下的亚临界裂纹扩展速率V与应力强度因子 的关系,分析了两种岩石在两种状态下亚临界裂纹扩展的规律,并确定了两种岩石在两种状态下的门槛值（干燥状态）：大理岩 为1.365,花岗岩 为2.305;（饱水状态）：大理岩 为1.118,花岗岩 为1.490。研究表明,两种岩石的 与 关系有较好的线性规律, 但由于岩石本身矿物成分等的不均匀性,同种岩石的 与 关系离散性较大,饱水状态下离散性更大;水能加速岩石亚临界裂纹的扩展,且对不同的岩石,其影响程度也不一样;水可以使岩石亚临界裂纹扩展的门槛值有较大幅度降低,不同岩石其降低的程度也不一样。     

X射线粉晶衍射仪在大理岩鉴定与分类中的应用

大理岩主要有方解石大理岩、白云石大理岩和菱镁矿大理岩三种。以往大理岩是依据偏光显微镜下观察岩石结构构造及矿物成分进行分类定名,由于方解石、白云石、菱镁矿都属于三方晶系,具有闪突起、高级白干涉色、一轴晶负光性和菱形解理等相同晶体光学特征,偏光显微镜下区分十分困难。为了准确鉴定大理岩中碳酸盐矿物种类及其相对含量,本文利用岩石薄片偏光显微镜和X射线粉晶衍射技术对32件大理岩岩石样品进行分析测试。岩石薄片鉴定结果表明:大理岩造岩矿物主要有方解石、白云石、菱镁矿、石英、斜长石、白云母、黑云母、绿泥石、黏土和金属矿物。根据岩石结构构造及矿物组分特征,可把32件大理岩样品划分为方解石大理岩、长英质方解石大理岩、石英绿泥白云石大理岩、白云石大理岩、云英质白云石大理岩和菱镁矿大理岩等15个类型。X射线粉晶衍射分析表明:大理岩造岩矿物主要有方解石、白云石、菱镁矿、石英、斜长石、钾长石、云母、绿泥石、滑石和蒙脱石。综合分析认为:岩石薄片偏光显微镜鉴定技术很难区分方解石、白云石和菱镁矿等碳酸盐矿物,以及细小的石英、钾长石和斜长石、滑石和白云母等鳞片状硅酸盐矿物;X射线粉晶衍射分析技术不仅能准确检测出大理岩中方解石、白云石和菱镁矿等碳酸盐矿物种类及相对含量(方解石、白云石和菱镁矿的X射线衍射主峰有明显差异,d值分别为0.303 nm、0.288 nm和0.274 nm),而且能够有效鉴别岩石中粉砂级斜长石、钾长石与石英(三种矿物的X射线衍射主峰d值分别为0.319 nm、0.324 nm、0.334 nm);且能区分蒙脱石、绿泥石、云母和滑石等层状硅酸盐矿物(四种硅酸盐矿物的X射线衍射主峰d值分别为1.400 nm、0.705 nm、0.989 nm、0.938 nm)。综合岩石薄片偏光显微镜鉴定和X射线粉晶衍射分析结果,最终确定32件大理岩样品划分为22个岩石类型。研究认为:仅根据岩石薄片偏光显微镜鉴定或X射线粉晶衍射技术其中一种方法不能准确鉴定大理岩岩石,应将大理岩岩石野外观察、岩石薄片鉴定和X射线粉晶衍射技术结合起来,才能准确确定大理岩岩石类型。     

复杂应力路径下大理岩三轴渗透试验研究

在隧道施工过程中,围岩的应力条件非常复杂,研究复杂应力路径下围岩渗透性能的变化规律对在高水压地区修建隧道具有重要意义。以锦屏水电枢纽二级电站交通辅助洞大理岩为研究对象,进行了常规三轴渗透试验与控制轴向应变（简称应变 ）、围压先升后降的三轴渗透试验,探讨了轴压与围压之差的绝对值 （简称应力差）与渗透率的关系。试验结果表明: (1)常规渗透试验大理岩渗透率的变化过程有3个重要的特征点：渗透率最低点、渗透率峰值点以及渗透率稳定点;(2)大理岩的渗透率随着应力差的增大而减小,两者呈负指数关系;(3)对某一固定的应力差,升围压阶段测得的渗透率大于降围压阶段测得的渗透率;(4)对任何试验岩样总存在一阈值,当应力差小于该值时,应力差的改变对渗透率有显著影响;(5)应力差减小过程中岩样渗透率的“恢复能力”随着岩样轴向应变的增大而逐渐减弱。     

高温后大理岩动态劈裂拉伸试验研究

为了研究高温处理后的岩石材料在冲击加载速率作用下的动态劈裂拉伸性能,利用大直径分离式霍普金森压杆试验设备对经历不同高温作用冷却后的“大理岩”平台巴西圆盘试样进行不同加载速率作用下的径向冲击试验。研究了高温后大理岩的动态劈裂拉伸强度及动态劈裂破坏形式随温度和冲击加载速率的变化规律。试验结果表明,与静态劈裂拉伸强度相比,经历不同高温作用冷却后,大理岩的动态劈裂拉伸强度有明显的提高,表现出显著的冲击加载速率强化效应,同一冲击加载速率作用下,随着温度的升高,动态劈裂拉伸强度表现出先增大后减小的变化趋势;高温后大理岩的动态劈裂破坏形式受到冲击加载速率和温度的共同影响。     

单轴压缩下两种脆性岩石强度及声发射特性的试验研究

脆性对岩石破裂机制及声发射特性具有重要影响。采用花岗岩及大理岩两种不同岩性的岩石,开展了单轴压缩及声发射测试试验,获取了两种岩石的强度及变形特性,并对其脆性大小进行定量评价,分析了单轴压缩过程中两种岩石声发射能量演化特性,结合声发射b值计算结果及其物理意义,对比了两种岩石破裂机制的差异性。结果表明:(1)试验所采用的两种岩石,花岗岩的σ_cd/σ_p之比介于0.676~0.745之间,平均为0.706,而大理岩的σ_cd/σ_p之比介于0.439~0.615,平均为0.52;(2)基于脆性评价指标,结合试样宏观破坏现象及形态,本次试验采用的花岗岩其脆性大于大理岩;(3)岩石脆性程度越大,在裂纹不稳定扩展阶段,在产生相同的轴向压缩变形的情况下,环向变形量越大;(4)强脆性的花岗岩在裂纹不稳定扩展阶段持续出现高能级的声发射信号,而弱脆性的大理岩则表现出能量持续降低的变化趋势,峰值强度后,弱脆性的大理岩其高能级能量的声发射信号更活跃;(5)单轴压缩下,与大理岩相比,花岗岩破坏过程中大尺度的破裂事件所占比例较大。     

Determination of the relative thermal conductivity of solid samples by X-ray diffraction device

The thermal conductivity (TC) of metal and rock samples was determined, under ambient conditions, using standard X-ray diffraction equipment in which only the diffractometer sample holder had been modified from the original. As the method is comparative, standard reference materials were used: a copper standard for the analysis of metals and marble for the rock specimens. The marble was analyzed beforehand using a quick thermal conductivity meter QTM. In experimental measurements of TC the mean reproducibility value appears to be about 4% while the accuracy is about 5% for the examined rocks, and better for metals.     

遇水冷却的高温大理岩力学与波动特性分析

岩石经历高温作用冷却后工程特性的变化情况,直接影响着地下深部空间及资源的开发与利用、核废料的存储以及突发性高温灾害后地下工程的稳定性评价。以大理岩为研究对象,对遇水冷却和自然冷却后的高温岩样进行单轴压缩试验和声波测试,分析和比较岩样在不同状态下峰值强度、弹性模量、衰减系数、纵波波速和主频的变化情况。结果表明：随着温度的不断升高,遇水冷却高温大理岩的峰值强度、弹性模量和纵波波速总体上均呈现减小趋势;低于400 ℃时,随着温度的升高,衰减系数逐渐增大,主频逐渐减小;但高于400 ℃时,随着温度的升高,衰减系数和主频并未完全呈现单调递增或递减趋势,出现了高温拐点;在经历相同高温作用后,遇水冷却大理岩的峰值强度、弹性模量和主频均低于自然冷却,而纵波波速、衰减系数均高于自然冷却。研究结果可以为遇水冷却的高温岩石工程性状的检测和稳定性的评价提供参考,对经历高温作用的岩石冷却方式的选择具有指导意义。     

层状岩体单轴和双轴压缩蠕变特性的数值试验

以绿片岩和大理岩组成的层状岩体为研究对象,采用FLAC3D对互层状岩体进行了单轴和双轴压缩蠕变试验的数值分析,在数值分析中考虑荷载方向与层理之间的几何关系、大理岩夹层的体积分数、应力水平等的影响。研究结果表明:单轴和双轴压缩条件下,随着夹层倾角由0°增加至90°,轴向和夹层倾斜方向的应变绝对值均呈先增大后减小的变化规律;随着大理岩夹层体积分数的增加,轴向压缩变形和2个侧向方向的膨胀变形量均有所减小。单轴压缩条件下,当轴向荷载方向垂直于层理时,轴向压缩变形均大于轴向荷载方向平行于层理时的轴向压缩变形;双轴压缩条件下,当轴向荷载方向垂直于层理、侧向荷载方向平行于层理时,轴向压缩变形最大,当轴向荷载方向平行于层理、侧向荷载方向垂直于层理时,轴向压缩变形最小。     

Indirect tensile test assessments for rock materials using 3-D disc-type specimens

Indirect test methods are usually the preferred approach for determining the tensile strength of brittle and quasi-brittle materials such as ceramics, rocks, and concrete. In this paper, the tensile strength of a rock material (Iranian Harsin marble) was obtained indirectly by means of two disc type samples. The test samples were the well-known Brazilian disc and semi-disc specimen under three-point bend loading. Since the existing formula for determining the indirect tensile strength is based on 2-D stress assumption which ignores the effects of specimen thickness, a general 3-D tensile strength formulation was derived for each sample by employing finite element analysis. A series of tensile strength tests were conducted on Harsin white marble using disc and semi-disc specimens with different thicknesses in parallel to finite element analysis. The test results using 3-D formulation showed that the tensile strength of the tested marble depends on the thickness/diameter ratio of the specimen and generally decreases from 11.5 to 7 MPa on increasing the thickness of test samples. The average values of tensile strength were about 8.8 MPa for the Brazilian disc specimen and 9.8 MPa for the semi-disc specimen. The good agreement existing between the results of the two specimens suggests that the semi-disc specimen can also be used for determining the rock tensile strength in addition to using the conventional Brazilian test.     

The Market Gate of Miletus: damages, material characteristics and the development of a compatible mortar for restoration

The indoor exhibit of the Market Gate of Miletus is unique for an archaeological monument. The reconstruction of the gate was done in such a way that most marble fragments were removed leaving cored marble columns 3–4 cm in thickness. These cored columns were mounted on a steel construction and filled with different mortars or filled with specially shaped blocks of brick combined with mortar. All the missing marble elements were replaced by copies made of a Portland cement based concrete, which is compositionally similar to the original building materials. During the Second World War the monument was heavily damaged by aerial bombardment. For 2 years the Market Gate of Miletus was exposed to weathering, because a brick wall protecting the gate was also destroyed. The deterioration phenomena observed are microcracks, macroscopic fractures, flaking, sugaring, greying, salt efflorescence, calcitic-sinter layers and iron oxide formation etc. The rapid deterioration seems to be due to indoor atmospheric effects, and also by a combination of incompatible materials (e.g. marble, steel, mortar, concrete, bricks etc.). Compatible building materials like mortars or stone replacing materials have to be developed for the planned restoration. The requirements for restoration mortars are chemical-mineralogical and physical-mechanical compatibilities with the existing building materials. In detail this means that the mortar should ensure good bonding properties, adapted strength development and not stain the marble when in direct contact. The favoured mortar was developed with a hydraulic binder based on iron-free white cement and pozzolana based on activated clay. A special limestone and quartz sand mixture was used as an aggregate. The cement was adjusted using chemical additives. Specially designed tests were applied extensively to prove whether the developed mortar is suitable for the restoration of this precious monument.     

Compositional variation of phlogopite in a marble sample: implications for geological thermobarometry

Abstract The textural and compositional features of phlogopites in a contact-metamorphic dolomite marble inclusion in the Bergell intrusion (central Alps) and in a metasomatic reaction vein cutting through this marble suggest different origins for vein phlogopites:
(a) High-Al vein phlogopite represents former marble phlogopite which has been compositionally modified by reaction with the vein forming fluid.
(b) Low-Al vein phlogopite represents phlogopite precipitated from the vein forming fluid.
As both types of vein phlogopite were in contact with the same vein forming fluid at the same time, low-Al phlogopite most likely represents an equilibrium phlogopite composition, whereas high-Al phlogopite does not. High-Al vein phlogopite retained its Al-content from the contact-metamorphic marble parent phlogopite and only underwent Fe-Mg exchange with the metasomatic fluid.
All the vein phlogopites studied are strongly enriched in Fe relative to marble phlogopite. The data may suggest in general that phlogopite Al/Si ratios may be retained from the conditions under which the phlogopites first formed, whereas the Mg/Fe-ratios may be substantially modified by exchange with other ferromagnesian solid phases and/or a metamorphic fluid at later stages in their metamorphic history. This may have significant effects on calculated pressures and temperatures from thermobarometers involving biotite.     

岩石受热后的强度,变形破坏特性的微观研究

本文对砂岩、灰岩、大理岩在不同温度条件下的单轴抗压强度进行了实验研究,并对岩石在各种温度下结构变化进行了镜下分析,探讨了岩石受热后的破裂机理,定性定量地分析了岩石裂纹随温度变化而发展的规律。研究和分析结果表明:在热应力和外应力的作用下,随着温度增加,砂岩单轴抗压强度有增加的趋势,而灰岩、大理石的强度则有所降低。温度对这几种岩石的变形和破坏特性也有很大影响。     

Microcracking in calcite and dolomite marble: microstructural influences and effects on properties

Microstructure‐based finite-element analysis with a microcracking algorithm was used to simulate an actual degradation phenomenon of marble structures, i.e., microcracking. Both microcrack initiation and crack propagation were characterized, as were their dependence on lattice preferred orientation (LPO), grain shape preferred orientation (SPO), grain size, marble composition (calcite and dolomite) and grain‐boundary fracture toughness. Two LPOs were analyzed: a random orientation distribution function and an orientation distribution function with strong directional crystalline texture generated from a March–Dollase distribution. Three SPOs were considered: equiaxed grains; elongated grains and a mixture of equiaxed and elongated grains. Three different grain sizes were considered: fine grains of order 200 μm (only calcitic marble); medium size grains of order 1 mm (calcitic and dolomitic marbles); and large grains of order 2 mm (only dolomitic marble). The fracture surface energy for the grain boundaries, γ_ig, was chosen to be 20 and 40 % of the fracture surface energy of a grain, γ_xtal, so that both intergranular and transgranular fracture were possible. Studies were performed on these idealized marble microstructures to elucidate the range of microcracking responses. Simulations were performed for both heating and cooling by 50 °C in steps of 1 °C. Microcracking results were correlated with the thermoelastic responses, which are indicators related to degradation. The results indicate that certain combinations of LPO, SPO, grain size, grain‐boundary fracture toughness and marble composition have a significant influence on the thermal-elastic response of marble. Microstructure with the smallest grain size and the highest degree of SPO and LPO had less of a tendency to microcrack. Additionally, with increasing SPO and LPO microcracking becomes more spatially anisotropic. A significant observation for all microstructures was an asymmetry in microcracking upon heating and cooling: more microcracking was observed upon cooling than upon heating. Given an identical microstructure and crystallographic texture, calcite showed larger thermal stresses than dolomite, had an earlier onset of microcracking upon heating and cooling, and a greater microcracked area at a given temperature differential. Thermal expansion coefficients with and without microcracking were also determined.