U–Pb zircon chronostratigraphy of early-Pliocene ignimbrites from La Pacana, north Chile: implications for the formation of stratified magma chambers

High spatial resolution U–Pb dates of zircons from two consanguineous ignimbrites of contrasting composition, the high-silica rhyolitic Toconao and the overlying dacitic Atana ignimbrites, erupted from La Pacana caldera, north Chile, are presented in this study. Zircons from Atana and Toconao pumice clasts yield apparent ²³⁸U/²⁰⁶Pb ages of 4.11±0.20 Ma and 4.65±0.13 Ma (2σ), respectively. These data combined with previously published geochemical and stratigraphic data, reveal that the two ignimbrites were erupted from a stratified magma chamber. The Atana zircon U–Pb ages closely agree with the eruption age of Atana previously determined by K–Ar dating (4.0±0.1 Ma) and do not support long (>1 Ma) residence times. Xenocrystic zircons were found only in the Toconao bulk ignimbrite, which were probably entrained during eruption and transport. Apparent ²³⁸U/²⁰⁶Pb zircon ages of 13 Ma in these xenocrysts provide the first evidence that the onset of felsic magmatism within the Altiplano–Puna ignimbrite province occurred approximately 3 Myr earlier than previously documented.     

40Ar/39Ar Ages and stratigraphy of the Latera caldera,Italy

The Latera caldera is a well-exposed volcano where more than 8 km³ of mafic silica-undersaturated potassic lavas, scoria and felsic ignimbrites were emplaced between 380 and 150 ka. Isotopic ages obtained by ⁴⁰Ar/³⁹Ar analysis of single sanidine crystals indicate at least four periods of explosive eruptions from the caldera. The initial period of caldera eruptions began at 232 ka with emplacement of trachytic pumice fallout and ignimbrite. They were closely followed by eruption of evolved phonolitic magma. After roughly 25 ky, several phonolitic ignimbrites were deposited, and they were followed by phreatomagmatic eruptions that produced trachytic ignimbrites and several smaller ash-flow units at 191 ka. Compositionally zoned magma then erupted from the northern caldera rim to produce widespread phonolitic tuffs, tephriphonolitic spatter, and scoria-bearing ignimbrites. After 40 ky of mafic surge deposit and scoria cone development around the caldera rim, a compositionally zoned pumice sequence was emplaced around a vent immediately northwest of the Latera caldera. This activity marks the end of large-scale explosive eruptions from the Latera volcano at 156 ka.     

Ignimbrites of the Cerro Galan caldera, NW Argentina

The 35 × 20 km Cerro Galán resurgent caldera is the largest post-Miocene caldera so far identified in the Andes. The Cerro Galán complex developed on a late pre-Cambrian to late Palaeozoic basement of gneisses, amphibolites, mica schists and deformed phyllites and quartzites. The basement was uplifted in the early Miocene along large north-south reverse faults, producing a horst-and-graben topography. Volcanism began in the area prior to 15 Ma with the formation of several andesite to dacite composite volcanoes. The Cerro Galán complex developed along two prominent north-south regional faults about 20 km apart. Dacitic to rhyodacitic magma ascended along these faults and caused at least nine ignimbrite eruptions in the period 7-4 Ma (K-Ar determinations). These ignimbrites are named the Toconquis Ignimbrite Formation. They are characterised by the presence of basal plinian deposits, many individual flow units and proximal co-ignimbrite lag breccias. The ignimbrites also have moderate to high macroscopic pumice and lithic contents and moderate to low crystal contents. Compositionally banded pumice occurs near the top of some units. Many of the Toconquis eruptions occurred from vents along a north-south line on the western rim of the young caldera. However, two of the ignimbrites erupted from vents on the eastern margin. Lava extrusions occurred contemporaneously along these north-south lines. The total D.R.E. volume of Toconquis ignimbrite exceeds 500 km³.Following a 2-Ma dormant period a single major eruption of rhyodacitic magma formed the 1000-km³ Cerro Galán ignimbrite and the caldera. The ignimbrite (age 2.1 Ma on Rb-Sr determination) forms a 30–200-m-thick outflow sheet extending up to 100 km in all directions from the caldera rim. At least 1.4 km of welded intracaldera ignimbrite also accumulated. The ignimbrite is a pumice-poor, crystal-rich deposit which contains few lithic clasts. No basal plinian deposit has been identified and proximal lag breccias are absent. The composition of pumice clasts is a very uniform rhyodacite which has a higher SiO₂ content but a lower K₂O content than the Toconquis ignimbrites. Preliminary data indicate no evidence for compositional zonation in the magma chamber. The eruption is considered to have been caused by the catastrophic foundering of a cauldron block into the magma chamber.Post-caldera extrusions occurred shortly after eruption along both the northern extension of the eastern boundary fault and the western caldera margin. Resurgence also occurred, doming up the intracaldera ignimbrite and sedimentary fill to form the central mountain range. Resurgent doming was centred along the eastern fault and resulted in radial tilting of the ignimbrite and overlying lake sediments.     

Effusive eruptions from a large silicic magma chamber: the Bearhead Rhyolite,Jemez volcanic field,NM

Large continental silicic magma systems commonly produce voluminous ignimbrites and associated caldera collapse events. Less conspicuous and relatively poorly documented are cases in which silicic magma chambers of similar size to those associated with caldera-forming events produce dominantly effusive eruptions of small-volume rhyolite domes and flows. The Bearhead Rhyolite and associated Peralta Tuff Member in the Jemez volcanic field, New Mexico, represent small-volume eruptions from a large silicic magma system in which no caldera-forming event occurred, and thus may have implications for the genesis and eruption of large volumes of silicic magma and the long-term evolution of continental silicic magma systems.⁴⁰Ar/³⁹Ar dating reveals that most units mapped as Bearhead Rhyolite and Peralta Tuff (the Main Group) were erupted during an ∼540 ka interval between 7.06 and 6.52 Ma. These rocks define a chemically coherent group of high-silica rhyolites that can be related by simple fractional crystallization models. Preceding the Main Group, minor amounts of unrelated trachydacite and low silica rhyolite were erupted at ∼11–9 and ∼8 Ma, respectively, whereas subsequent to the Main Group minor amounts of unrelated rhyolites were erupted at ∼6.1 and ∼1.5 Ma.The chemical coherency, apparent fractional crystallization-derived geochemical trends, large areal distribution of rhyolite domes (∼200 km²), and presence of a major hydrothermal system support the hypothesis that Main Group magmas were derived from a single, large, shallow magma chamber. The ∼540 ka eruptive interval demands input of heat into the system by replenishment with silicic melts, or basaltic underplating to maintain the Bearhead Rhyolite magma chamber.Although the volatile content of Main Group magmas was within the range of rhyolites from major caldera-forming eruptions such as the Bandelier and Bishop Tuffs, eruptions were smaller volume and dominantly effusive. Bearhead Rhyolite domes occur at the intersection of faults, and are cut by faults, suggesting that the magma chamber was structurally vented preventing volatiles from accumulating to levels high enough to trigger a caldera-forming eruption.     

Large-volume silicic volcanism in Kamchatka: Ar–Ar and U–Pb ages,isotopic, and geochemical characteristics of major pre-Holocene caldera-forming eruptions

The Kamchatka Peninsula in far eastern Russia represents the most volcanically active arc in the world in terms of magma production and the number of explosive eruptions. We investigate large-scale silicic volcanism in the past several million years and present new geochronologic results from major ignimbrite sheets exposed in Kamchatka. These ignimbrites are found in the vicinity of morphologically-preserved rims of partially eroded source calderas with diameters from ～ 2 to ～ 30 km and with estimated volumes of eruptions ranging from 10 to several hundred cubic kilometers of magma. We also identify and date two of the largest ignimbrites: Golygin Ignimbrite in southern Kamchatka (0.45 Ma), and Karymshina River Ignimbrites (1.78 Ma) in south-central Kamchatka. We present whole-rock geochemical analyses that can be used to correlate ignimbrites laterally. These large-volume ignimbrites sample a significant proportion of remelted Kamchatkan crust as constrained by the oxygen isotopes. Oxygen isotope analyses of minerals and matrix span a 3‰ range with a significant proportion of moderately low-δ¹⁸O values. This suggests that the source for these ignimbrites involved a hydrothermally-altered shallow crust, while participation of the Cretaceous siliceous basement is also evidenced by moderately elevated δ¹⁸O and Sr isotopes and xenocryst contamination in two volcanoes. The majority of dates obtained for caldera-forming eruptions coincide with glacial stages in accordance with the sediment record in the NW Pacific, suggesting an increase in explosive volcanic activity since the onset of the last glaciation 2.6 Ma. Rapid changes in ice volume during glacial times and the resulting fluctuation of glacial loading/unloading could have caused volatile saturation in shallow magma chambers and, in combination with availability of low-δ¹⁸O glacial meltwaters, increased the proportion of explosive vs effusive eruptions. The presented results provide new constraints on Pliocene–Pleistocene volcanic activity in Kamchatka, and thus constrain an important component of the Pacific Ring of Fire.     

K-Ar geochronology of the late cenozoic volcanic rocks of the Cordillera Occidental, southernmost Peru

Twenty-four K-Ar radiometric ages are presented for late Cenozoic continental volcanic rocks of the Cordillera Occidental of southernmost Perú (lat. 16° 57′–17° 36′S). Rhyodacitic ignimbrite eruptions began in this transect during the Late Oligocene and continued episodically through the Miocene. The development of andesitic-dacitic strato volcanoes was initiated in the Pliocene and continues to the present.The earliest ignimbrite flows (25.3–22.7 Ma) are intercalated in the upper, coarsely-elastic member of the Moquegua Formation and demonstrate that this sedimentary unit accumulated in a trough, parallel to Andean tectonic trends, largely in the Oligocene. More voluminous ash-flow eruptions prevailed in the Early Miocene (22.8–17.6 Ma) and formed the extensively preserved Huaylillas Formation. This episode was coeval with a major phase of Andean uplift, and the pyroclastics overlie an erosional surface of regional extent incised into a Paleogene volcano-plutonic arc terrain. An age span of 14.2–8.9 Ma (mid-Late Miocene) is indicated for the younger Chuntacala Formation, which again comprises felsic ignimbrite flows, largely restricted to valleys incised into the pre-Huaylillas Formation lithologies, and, at lower altitudes, an extensive aggradational elastic facies. The youngest areally extensive ignimbrites, constituting the Sencca Formation, were extruded during the Late Miocene.In the earliest Pliocene, the ignimbrites were succeeded by more voluminous calcalkaline, intermediate flows which generated numerous large and small stratovolcanoes; these range in age from 5.3 to 1.6 Ma. Present-day, or Holocene, volcanism is restricted to several large stratovolcanoes which had begun their development during the Pleistocene (by 0.7 Ma).The late Oligocene/Early Miocene (ca. 22–23 Ma) reactivation of the volcanic arc coincided with a comparable increase in magmatic activity throughout much of the Cordilleras Occidental and Oriental of the Central Andes.     

Temporal dissection of the Huckleberry Ridge Tuff using the 40Ar/39Ar dating technique

New high-precision single crystal sanidine ⁴⁰Ar/³⁹Ar ages for the Huckleberry Ridge Tuff (HRT), Yellowstone volcanic field, show that the three HRT members (A, B, and C) represent at least two different eruptions. The new ⁴⁰Ar/³⁹Ar ages (all ages calculated relative to the optimisation model of Renne et al., 2011) are: 2.135 ± 0.006 Ma, 2.131 ± 0.008 Ma, and 2.113 ± 0.004 Ma (2σ, full uncertainty propagation), for members A, B and C, respectively. Members A and B are within uncertainty of one another and both are more precise than, but in agreement with, previously published ages. Member C was erupted later than members A and B. HRT members A and B were deposited during the Reunion Normal Polarity Subchron (C2r.1n). Member C was deposited during Subchron C2r.1r. Previously published radiogenic and stable isotope data show that member C was sourced from an isotopically discrete magma with a higher fraction of crustal material than members A and B. The volume of the first HRT eruption is reduced by c. 12% from previous estimates and explosive eruptions from the Yellowstone volcanic field occurred more frequently, producing more homogeneous magma than was previously believed. High-precision ⁴⁰Ar/³⁹Ar dating is key for resolving the eruptive history of Yellowstone, temporal dissection of voluminous ignimbrites, and rigorous investigation of what constitutes a ‘super-eruption’.     

High-precision 40Ar/39Ar sanidine geochronology of ignimbrites in the Mogollon-Datil volcanic field,southwestern New Mexico

⁴⁰Ar/³⁹Ar age spectra have been obtained from 85 sanidine separates from 36 ignimbrites and one rhyolitic lava in the latest Eocene-Oligocene Mogollon-Datil volcanic field of southwestern New Mexico. Of the 97 measured age spectra, 94 yield weighted-mean plateau ages each giving single-spectrum 1 precision of±0.25%–0.4% (±0.07–0.14 Ma). Replicate plateau age determinations for eight different samples show within-sample 1 precisions averaging ±0.25%. Plateau ages from multiple (n=3–8) samples of individual ignimbrites show 1 within-unit precision of ±0.1%–0.4% (±0.04–0.13 Ma). This within-unit precision represents a several-fold improvement over published K-Ar data for the same ignimbrites, and is similar to the range of precisions reported from single-crystal laser fusion studies. A further indication of the high precision of unit-mean ⁴⁰Ar/³⁰Ar ages is their close agreement with independently established stratigraphic order. Two samples failed to meet plateau criteria, apparently due to geologic contamination by older feldspars. Effects of minor contamination are shown by six other samples, which yielded slightly anomalous plateau ages. ⁴⁰Ar/³⁹Ar plateau ages permit resolution of units differing in age by 0.5% (0.15 Ma) or less. This high resolution, combined with paleomagnetic studies, has helped to correlate ignimbrites among isolated ranges and has allowed development of an integrated timestratigraphic framework for the volcanic field. Mogollon-Datil ignimbrites range in age from 36.2 to 24.3 Ma. Ignimbrite activity was strongly episodic, being confined to four brief (<2.6 m.y.) eruptive episodes separated by 1–3 m.y. gaps. Ignimbrite activity generally tended to migrate from the southeast toward the north and west.     

Systematics of xenocrystic contamination: preservation of discrete feldspar populations at McCullough Pass Caldera revealed by Ar/Ar dating

Single crystal ⁴⁰Ar/³⁹Ar dating of K-feldspars from silicic volcanic rocks containing xenocrysts often yields a spectrum of ages slightly older than those of juvenile sanidine phenocrysts. In contrast, feldspars from thin, low-volume units of the Tertiary (14 Ma) McCullough Pass Tuff define discrete age populations at 14 Ma, 15 Ma, and 1.3 Ga, reflecting the time of eruption, xenocrysts from an older ignimbrite exposed in the caldera wall, and Proterozoic basement K-feldspars, respectively. Conductive cooling and diffusion modelling suggests preservation of such discrete populations is likely only when xenocrystic material is incorporated into the magma very near or at the surface, or is engulfed in thin, rapidly cooled pyroclastic flows during emplacement. Incorporation of xenocrysts into the subvolcanic magma chamber, into thick rhyolite domes or lava flows, or into large, welded ignimbrite sheets will result in partial or total resetting of the K/Ar isotopic system. Similarly, petrographic evidence such as exsolution lamellae may be homogenized under these conditions but not in thin ignimbrites. Extremely low diffusion rates for disordering of the Al–Si tetrahedral siting of basement feldspars suggests that they will retain their ordered structural state given rhyolitic magma temperatures. Thus, even when petrographic and K/Ar isotopic evidence for xenocrystic contamination is obscured, it may be preserved in the form of Al–Si ordering.     

Genesis of lavas of the Taupo Volcanic Zone, North Island, New Zealand

The Taupo Volcanic Zone forms part of the Taupo-Hikurangi subduction system, and comprises five volcanic centres: Tongariro, Taupo, Maroa, Okataina and Rotorua. Tongariro Volcanic Centre is formed almost entirely of andesite while the other four centres contain predominantly rhyolitic volcanics and later fissure eruptions of high-Al basalt. Estimated total volume of each lava type are as follows: 2 km³ of high-Al basalt (< 0.1%); 260 km³ of andesite (< 2.5%); 5 km³ of dacite (< 0.1%); > 10,000 km³ of rhyolite and ignimbrite (> 97.4%).The location of the andesites and vent alignments suggest a source from a subduction zone underlying the area. However, the lavas differ chemically from island-arc andesites such as those of Tonga; in particular by having higher contents of the alkali elements, light REE and Sr and Pb isotopes. This suggests some crustal contamination, and it is considered that this may occur beneath the wide accretionary prism of the subduction system. Amphibolite of the subduction zone will break down between 80 and 100 km and a partial melt will rise. A multi-stage process of magma genesis is then likely to occur. High-Al basalts are thought to be derived from partial melting of a garnet-free peridotite near the top of the mantle wedge overlying the subduction zone, locations of the vents controlled largely by faults within the crust. Rhyolites and ignimbrites were probably derived from partial melting of Mesozoic greywacke and argillite under the Taupo Volcanic Zone. Initial partial melting may have been due to hydration of the base of the crust; the “water” having come from dehydration of the downgoing slab. The partial melts would rise to form granodiorite plutons and final release of the magma to form rhyolites and ignimbrites was allowed because of extension within the Taupo graben.Dacites of the Bay of Plenty probably resulted from mixing of andesitic magma with small amounts of rhyolitic magma, but those on the eastern side of the Rotorua-Taupo area were more likely formed by a higher degree of partial melting of the Mesozoic greywacke-argillite basement. This may be due to intrusion of andesite magma on this side of the Taupo volcanic zone.     

Eruptive patterns for the volcano piton de la fournaise, Reunion Island

A study of the historic record of activity of Piton de la Fournaise has revealed a cyclic pattern of eruption involving effusion of oceanite lava from major-flank centers every 20–40 years. Calculated volumes of the recent lava flows and pyroclastic ejecta have established an effusion rate of 3.9 m³ s⁻¹ since 1931 and 6.2 m³ s⁻¹ since 1951. Flank eruptions outside the present caldera define a distribution maximum which is expected to correlate with the depth range of a high-level magma reservoir.A model has been constructed which requires replenishment of a high-level magma chamber at a constant rate and regular eruption from summit and minor-flank centers, acting as “safety valves” to the magma chamber; when the magma chamber reaches its maximum expansion, a major-flank outburst of oceanitic lava occurs.The fact that calculated effusion rates are not consistent with radiometric dates implies an increase in effusion volume with time for the volcano.     

Geology and eruptive history of the Rabaul Caldera area, Papua New Guinea

Rabaul Caldera is the most recently active (1937–1943) of four adjoining volcanic centres aligned north-south through the northern extremity of eastern New Britain. Geological mapping after the 1983–1985 Rabaul seismic and deformation crisis has partially revealed a long and complex eruption history dominated by numerous explosive eruptions, the largest accompanied by caldera collapse. The oldest exposed eruptives are the basaltic pre-caldera cone Tovanumbatir Lavas K/Ar dated at 0.5 Ma. The dacitic Rabaul Quarry Lavas exposed in the caldera wall and K/Ar dated at 0.19 Ma, are overlain by a sequence of dacitic and andesitic pyroclastic flow and fall deposits. Uplifted coral reef limestones, interbedded within the pyroclastic sequence on the northeast coast, suggest that explosive eruptions in the Rabaul area had commenced prior to the 0.125 Ma last interglacial high sea level stand. The pyroclastic sequence includes the large Boroi Ignimbrites and Malaguna Pyroclastics both ⁴⁰Ar/³⁹Ar dated at about 0.1 Ma, and the Barge Tunnel Ignimbrite ⁴⁰Ar/³⁹Ar dated at around 0.04 Ma. Few reliable ages exist for the many younger eruptives. These include Holocene ignimbrites of the latest caldera-forming eruptions—the Raluan Pyroclastics variously dated (¹⁴C) at either about 3500 or 7000 yr B.P., and the ca. 1400 yr B.P. Rabaul Pyroclastics. At least eight intracaldera eruptions have occurred since the 1400 yr B.P. collapse, building small pyroclastic and lava cones within the caldera.A major erosional episode is evident as a widespread unconformity in the upper pyroclastic stratigraphy at Rabaul. Lacking relevant radiometric ages, this episode is assumed to have occurred during last glaciation low sea levels and is here arbitarily dated at ca. ?20 ka. At least five, possibly nine, significant ignimbrite eruptions have occurred at Rabaul during the last ?20 ka. The new eruptive history differs considerably from that previously published, which considered ignimbrite eruption and caldera collapse to have first occurred at 3500 yr B.P.Rabaul volcanism has been dominated by two main types: (a) basaltic and basaltic andesite cone building eruptions; and (b) dacitic, and rarely andesitic or rhyolitic, plinian/ignimbrite eruptions of both high- and low-aspect ratio types. The 1400 yr B.P. Rabaul Ignimbrite is a type example of a low-aspect ratio, high-energy, and potentially very damaging eruption. Fine vitric ash deposits, common in the Rabaul pyroclastic sequence, demonstrate the frequent modification of eruptions by external water probably related to early caldera lakes or bays. Interbedding of these fine ashes with plinian pumice lapilli beds suggests that many early eruptions occurred from multiple vents, located in both wet and dry areas.     

Chronological and palaeomagnetic constraints on widespread welded ignimbrites of the Taupo volcanic zone,New Zealand

 Large volume (100–1000 km³), widespread rhyolitic ignimbrites are the main products of the Taupo volcanic zone (TVZ) of New Zealand, one of the most active silicic volcanic regions on Earth. Several factors have made correlation and the eruptive history of the ignimbrites difficult to resolve, including limited exposure and chronological data, broadly similar lithologies and the lack of stratigraphic successions visible in the field. We have used the isothermal plateau fission track (ITPFT) method on glass shards from the non-welded basal zones to obtain new eruption ages for the widespread units: Ongatiti (1.25±0.12 Ma), Whakamaru group (0.34±0.03 Ma), Matahina (0.34±0.02 Ma), Chimp (0.33±0.02 Ma), Kaingaroa (0.31±0.01 Ma) and Mamaku (0.23±0.01 Ma) ignimbrites. These glasses show little evidence of geochemical alteration and allow the units to be fingerprinted for correlation. The glass ages we have obtained for the late Quaternary units provide an independent check on chronological data obtained from phenocryst phases. The ITPFT method is a useful dating approach for sanidine-poor eruptives which limit the application of ⁴⁰Ar/³⁹Ar. Errors as limited as 10–30 ka can be obtained from the weighted mean of several age determinations. The thermoremanent magnetic (TRM) direction recorded in the units provides a means of correlation over a wide area of the TVZ, because each ignimbrite can be distinguished by its unique record of palaeosecular variation. These data indicate that the four separately mapped members of the Whakamaru group represent the same phase of activity, occurring within a period of 100 years. The TRM data indicate that the widespread Ahuroa ignimbrite erupted during an excursion in Earth's magnetic field, perhaps associated with the Cobb Mountain subchron (ca. 1.2 Ma). The youngest widespread welded unit, Mamaku ignimbrite (ca. 0.23 Ma), also erupted during an excursion and may represent a southern hemisphere record of the Pringle Falls geomagnetic episode found in the western United States. The palaeomagnetic and ITPFT data for the widespread late Quaternary ignimbrites suggest a major period of caldera formation at 0.34–0.30 Ma. This interval represents the eruption of multiple units from the Whakamaru caldera, followed by the formation of the Okataina and Reporoa calderas in rapid succession. Received: 20 November 1995 / Accepted: 8 May 1996     

Water contents, temperatures and diversity of the magmas of the catastrophic eruption of Nevado del Ruiz, Colombia, November 13, 1985

The petrology of the highly phyric two-pyroxene andesitic to dacitic pyroclastic rocks of the November 13, 1985 eruption of Nevado del Ruiz, Colombia, reveals evidence of: (1) increasingly fractionated bulk compositions with time; (2) tapping of a small magma chamber marginally zoned in regard to H₂O contents (1 to 4%), temperature (960–1090°C), and amount of residual melt (35 to 65%); (3) partial melting and assimilation of degassed zones in the hotter less dense interior of the magma chamber; (4) probable heating, thermal disruption and mineralogic and compositional contamination of the magma body by basaltic magma “underplating”; and (5) crustal contamination of the magmas during ascent and within the magma chamber. Near-crater fall-back or “spill-over” emitted in the middle of the eruptive sequence produced a small pyroclastic flow that became welded in its central and basal portions because of ponding and thus heat conservation on the flat glaciated summit near the Arenas crater. The heterogeneity of Ruiz magmas may be related to the comparatively small volume (0.03 km³) of the eruption, nearly ten times less than the 0.2 km³ of the Plinian phase of Mount St. Helens, and probable steep thermal and P_H2O gradients of a small source magma chamber, estimated at 300 m long and 100 m wide for an assumed ellipsoidal shape.     

Reconstruction of a major caldera-forming eruption from pyroclastic deposit characteristics: Kos Plateau Tuff, eastern Aegean Sea

The 161 ka explosive eruption of the Kos Plateau Tuff (KPT) ejected a minimum of 60 km³ of rhyolitic magma, a minor amount of andesitic magma and incorporated more than 3 km³ of vent- and conduit-derived lithic debris. The source formed a caldera south of Kos, in the Aegean Sea, Greece. Textural and lithofacies characteristics of the KPT units are used to infer eruption dynamics and magma chamber processes, including the timing for the onset of catastrophic caldera collapse.The KPT consists of six units: (A) phreatoplinian fallout at the base; (B, C) stratified pyroclastic-density-current deposits; (D, E) volumetrically dominant, massive, non-welded ignimbrites; and (F) stratified pyroclastic-density-current deposits and ash fallout at the top. The ignimbrite units show increases in mass, grain size, abundance of vent- and conduit-derived lithic clasts, and runout of the pyroclastic density currents from source. Ignimbrite formation also corresponds to a change from phreatomagmatic to dry explosive activity. Textural and lithofacies characteristics of the KPT imply that the mass flux (i.e. eruption intensity) increased to the climax when major caldera collapse was initiated and the most voluminous, widespread, lithic-rich and coarsest ignimbrite was produced, followed by a waning period. During the eruption climax, deep basement lithic clasts were ejected, along with andesitic pumice and variably melted and vesiculated co-magmatic granitoid clasts from the magma chamber. Stratigraphic variations in pumice vesicularity and crystal content, provide evidence for variations in the distribution of crystal components and a subsidiary andesitic magma within the KPT magma chamber. The eruption climax culminated in tapping more coarsely crystal-rich magma. Increases in mass flux during the waxing phase is consistent with theoretical models for moderate-volume explosive eruptions that lead to caldera collapse.     

Correlation of welded ignimbrites on Pantelleria (Strait of Sicily) using paleomagnetism

Although the oldest volcanic rocks exposed at Pantelleria (Strait of Sicily) are older than 300 ka, most of the island is covered by the 45–50 ka Green Tuff ignimbrite, thought to be related to the Cinque Denti caldera, and younger lavas and scoria cones. Pre-50 ka rocks (predominantly rheomorphic ignimbrites) are exposed at isolated sea cliffs, and their stratigraphy and chronology are not completely resolved. Based on volcanic stratigraphy and K/Ar dating, it has been proposed that the older La Vecchia caldera is related to ignimbrite Q (114 ka), and that ignimbrites F, D, and Z (106, 94, and 79 ka, respectively) were erupted after caldera formation. We report here the paleomagnetic directions obtained from 23 sites in ignimbrite P (133 ka) and four younger ignimbrites, and from an uncorrelated (and loosely dated) welded lithic breccia thought to record a caldera-forming eruption. The paleosecular variation of the geomagnetic field recorded by ignimbrites is used as correlative tool, with an estimated time resolution in the order of 100 years. We find that ignimbrites D and Z correspond, in good agreement with recent Ar/Ar ages constraining the D/Z eruption to 87 ka. The welded lithic breccia correlates with a thinner breccia lying just below ignimbrite P at another locality, implying that collapse of the La Vecchia caldera took place at ~130–160 ka. This caldera was subsequently buried by ignimbrites P, Q, F, and D/Z. Paleomagnetic data also show that the northern caldera margin underwent a ~10° west–northwest (outwards) tilting after emplacement of ignimbrite P, possibly recording magma resurgence in the crust.     

Geochemical,isotopic and single crystal <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar age constraints on the evolution of the Cerro Galán ignimbrites

The giant ignimbrites that erupted from the Cerro Galán caldera complex in the southern Puna of the high Andean plateau are considered to be linked to crustal and mantle melting as a consequence of delamination of gravitationally unstable thickened crust and mantle lithosphere over a steepening subduction zone. Major and trace element analyses of Cerro Galán ignimbrites (68–71% SiO₂) that include 75 new analyses can be interpreted as reflecting evolution at three crustal levels. AFC modeling and new fractionation corrected δ¹⁸O values from quartz (+7.63–8.85‰) are consistent with the ignimbrite magmas being near 50:50 mixtures of enriched mantle (⁸⁷Sr/⁸⁶Sr ~ 0.7055) and crustal melts (⁸⁷Sr/⁸⁶Sr near 0.715–0.735). Processes at lower crustal levels are predicated on steep heavy REE patterns (Sm/Yb = 4–7), high Sr contents (>250 ppm) and very low Nb/Ta (9-5) ratios, which are attributed to amphibolite partial melts mixing with fractionating mantle basalts to produce hybrid melts that rise leaving a gravitationally unstable garnet-bearing residue. Processes at mid crustal levels create large negative Eu anomalies (Eu/Eu* = 0.45–0.70) and variable trace element enrichment in a crystallizing mush zone with a temperature near 800–850°C. The mush zone is repeatedly recharged from depth and partially evacuated into upper crustal magma chambers at times of regional contraction. Crystallinity differences in the ignimbrites are attributed to biotite, zoned plagioclase and other antecrysts entering higher level chambers where variable amounts of near-eutectic crystallization occurs at temperatures as low as 680°C just preceding eruption. ⁴⁰Ar/³⁹Ar single crystal sanidine weighted mean plateau and isochron ages combined with trace element patterns show that the Galán ignimbrite erupted in more than one batch including a ~ 2.13 Ma intracaldera flow and outflows to the west and north at near 2.09 and 2.06 Ma. Episodic delamination of gravitationally unstable lower crust and mantle lithosphere and injection of basaltic magmas, whose changing chemistry reflects their evolution over a steepening subduction zone, could trigger the eruptions of the Cerro Galán ignimbrites.     

Ar–Ar geochronology of Santo Antão, Cape Verde Islands

Santo Antão, the northernmost island of the Cape Verde Archipelago, consists entirely of silica-undersaturated volcanic products and minor intrusions. ⁴⁰Ar–³⁹Ar incremental heating experiments have been carried out on 24 samples that cover the entire exposed chronological sequence. The oldest lavas (7.57±0.56 Ma), representing an older volcanic basement, are exposed about 620 m above mean sea level. After an interval of quiescence of up to 4.3 Ma the volcanic activity resumed and continued at low eruption rates. The older basement is unconformably overlain by a ca. 810-m-thick lava sequence that spans an age range from 2.93±0.03 to 1.18±0.01 Ma. This sequence is cut by many dykes and sills. Simultaneous volcanic activity occurred in the northeastern, central and eastern part of the island. A phonolitic pumice deposit that forms a noteworthy feature over most of the island has an estimated age of 0.20 Ma. This predates volcanic activity that formed the highest point of the island (Tope de Coroa) which has an age of 0.17±0.02 Ma. The most recent eruption on the island formed nephelinitic lavas in the Porto Novo region at 0.09±0.03 Ma. The oldest volcanism exposed on Santo Antão, which took place about 7.6 Ma ago, was simultaneous with waning activity on Maio at the eastern end of the Cape Verde Archipelago.     

Glass-bearing plutonic fragments from ignimbrites of the Okataina caldera complex, Taupo Volcanic Zone, New Zealand: remnants of a partially molten intrusion associated with preceding eruptions

Glass-bearing plutonic fragments occur as rare accessory lithics within the ca. 64 ka Rotoiti and Earthquake Flat ignimbrites that were erupted from Okataina caldera complex, Taupo Volcanic Zone, New Zealand. Granitoid lithic fragments are only found in the Rotoiti ignimbrite and fall into two groups. Group 1 granitoids have textures consistent with a period of slow cooling followed by rapid quenching, and were excavated by the Rotoiti eruption from a single incompletely solidified magma body. Although isotopic ratios for the Group 1 granitoids are similar to the host ignimbrite, they are not cognate, having different chemistry, mineralogy, mineral chemistry and crystallisation history. It is more likely that they represent fragments of a separate incompletely solidified magma chamber that was intercepted by the erupting Rotoiti ignimbrite magma. Low LILE and high HFSE abundances favour a comagmatic link with the ca. 0.28 Ma Matahina ignimbrite and it is suggested they are derived from an isolated cupola of the Matahina magma chamber that remained at depth (between 3.5 and 5 kbar pressure) after eruption of the Matahina ignimbrite. Migration toward the surface probably accompanied development of the Rotoiti magma system in the upper crust. Most geochemical variation in Group 1 granitoids is related to the abundance of biotite, the concentration of which is controlled by differential shear. REE abundance is controlled by light REE-enriched accessory minerals preferentially included within biotite. Although Eu_n remains constant in the Group 1 granitoids, Eu/Eu^* varies systematically with (La/Yb)_n and is controlled by variations in Sm and Gd rather than in Eu. Group 2 granitoid fragments have a wide range of composition, comparable to many Okataina rhyolites, including those found as lithic fragments in the Rotoiti ignimbrite. Rare microdiorite fragments occur in both Rotoiti and Earthquake Flat ignimbrites and typically contain vesicular interstitial glass indicating that they were incompletely solidified prior to eruption. Those from the Rotoiti ignimbrite are comparable to the (>64 ka) Matahi basaltic tephra and probably represent part of the same magmatic event which generated the Matahi tephra.     

Geochemical homogeneity of a long-lived,large silicic system; evidence from the Cerro Galán caldera,NW Argentina

By applying a number of analytical techniques across a spectrum of spatial scales (centimeter to micrometer) in juvenile components, we show that the Cerro Galán volcanic system has repeatedly erupted magmas with nearly identical geochemistries over >3.5 Myr. The Cerro Galán system produced nine ignimbrites (∼5.6 to 2 Ma) with a cumulative volume of >1,200 km³ (DRE; dense rock equivalent) of calc-alkaline, high-K rhyodacitic magmas (68–71 wt.% SiO₂). The mineralogy is broadly constant throughout the eruptive sequence, comprising plagioclase, quartz, biotite, Fe–Ti oxides, apatite, and titanite. Early ignimbrite magmas also contained amphibole, while the final eruption, the most voluminous Cerro Galán ignimbrite (CGI; 2.08 ± 0.02 Ma) erupted a magma containing rare amphibole, but significant sanidine. Each ignimbrite contains two main juvenile clast types; dominant “white” pumice and ubiquitous but subordinate “grey” pumice. Fe–Ti oxide and amphibole-plagioclase thermometry coupled with amphibole barometry suggest that the grey pumice originated from potentially hotter and deeper magmas (800–840°C, 3–5 kbar) than the more voluminous white pumice (770–810°C, 1.5–2.5 kbar). The grey pumice is interpreted to represent the parental magmas to the Galán system emplaced into the upper crust from a deeper storage zone. Most inter-ignimbrite variations can be accounted for by differences in modal mineralogy and crystal contents that vary from 40 to 55 vol.% on a vesicle-free basis. Geochemical modeling shows that subtle bulk-rock variations in Ta, Y, Nb, Dy, and Yb between the Galán ignimbrites can be reconciled with differences in amounts of crystal fractionation from the “grey” parent magma. The amount of fractionation is inversely correlated with volume; the CGI (∼630 km³) and Real Grande Ignimbrite (∼390 km³) return higher F values (proportion of liquid remaining) than the older Toconquis Group ignimbrites (<50 km³), implying less crystal fractionation took place during the upper-crustal evolution of these larger volume magmas. We attribute this relationship to variations in magma chamber geometry; the younger, largest volume ignimbrites came from flat sill-like magma chambers, reducing the relative proportion of sidewall crystallization and fractionation compared to the older, smaller-volume ignimbrite eruptions. The grey pumice clasts also show evidence of silicic recharge throughout the history of the Cerro Galán system, and recharge days prior to eruption has previously been suggested based on reversely zoned (OH and Cl) apatite phenocrysts. A rare population of plagioclase phenocrysts with thin An-rich rims in juvenile clasts in many ignimbrites supports the importance of recharge in the evolution and potential triggering of eruptions. This study extends the notion that large volumes of nearly identical silicic magmas can be generated repeatedly, producing prolonged geochemical homogeneity from a long-lived magma source in a subduction zone volcanic setting. At Cerro Galán, we propose that there is a zone between mantle magma input and upper crustal chambers, where magmas are geochemically “buffered”, producing the underlying geochemical and isotopic signatures. This produces the same parental magmas that are delivered repeatedly to the upper crust. A lower-crustal MASH (melting, assimilation, storage, and homogenization) zone is proposed to act as this buffer zone. Subsequent upper crustal magmatic processes serve only to slightly modify the geochemistry of the magmas.