Groundwater quality assessment using the Water Quality Index and GIS in Saveh-Nobaran aquifer,Iran

Groundwater is the most important natural resource used for drinking by many people around the world, especially in arid and semi-arid areas. The resource cannot be optimally used and sustained unless the quality of groundwater is assessed. Saveh-Nobaran aquifer in Iran is the most important groundwater aquiferous system in the region which is considered a major source for drinking and irrigation. The main objective of this study is to understand the groundwater quality status of Saveh-Nobaran aquifer, followed by attempts to investigate the spatial distribution of groundwater quality parameters to identify places with the best quality for drinking consume within the study area. For this purpose, a set of original data, as yet unpublished, is presented. This paper provides an important contribution for understanding relationship between land use and groundwater quality, and also groundwater depth and groundwater quality. This goal has been achieved with the combined use of the Water Quality Index (WQI) and a geographical information system (GIS). A total of 58 groundwater samples were collected and analyzed for major cations and anions. Spatial distribution maps of pH, TDS, EC, TH, Cl, HCO, SO₄, Ca, Mg, Na and K have been created using the kriging method in a GIS environment. From the WQI assessment, over 65 % of the water samples fall within the ‘‘Poor’’, ‘‘Very poor’’ and “unsuitable for drinking” categories, suggesting that groundwater from the center and north-east of the Saveh-Nobaran aquifer is unsuitable for drinking purposes. This research and its results have shown the great combination use of GIS and WQI in assessing groundwater quality. Having a clear view of the geographic areas of groundwater quality, decision makers can plan better for the operation and maintenance of groundwater resources.     

Use of geographical information system and water quality index to assess groundwater quality in El Khairat deep aquifer (Enfidha, Central East Tunisia)

Groundwater is the most important natural resource used for drinking by many people around the world, especially in rural areas. In Tunisia, since the quantity and the quality of water available for different uses is variable from one place to another, groundwater quality in El Khairat deep aquifer was evaluated for its suitability for drinking purposes. To this end, an attempt has been made for the first time in order to determine spatial distribution of groundwater quality parameters and to identify places with the best quality for drinking within the study area based on: (1) an integrated analysis of physical?Cchemical parameters, (2) use of Geographical Information System, and (3) Water Quality Index (WQI) calculation. The physical?Cchemical results were compared with the World Health Organization (WHO) standards for drinking and public health, in order to have an overview of the present groundwater quality. According to the overall assessment of the basin, almost all the parameters analyzed are above the desirable limits of WHO. Using GIS contouring methods with Arcview 3.2a, spatial distribution maps of pH, TDS, EC, TH, Cl, HCO₃, SO₄, NO₃, Ca, Mg, Na, and K have been created. The spatial analysis of groundwater quality patterns of the study area shows that the TDS value increases from north-west to south-east following the general trend of the Khairat aquifer flow direction. The spatial distribution map of TH shows that a majority of the groundwater samples falls in the very hard category. WQI was used to assess the suitability of groundwater from the study area for human consumption. From the WQI assessment, over 82% of the water samples fall within the ??Poor?? and ??Very poor?? categories, suggesting that groundwater from the south-eastern of the El Khairat deep aquifer is unsuitable for drinking purposes.     

Development of Water Quality Index (WQI) model for the groundwater in Tirupur district, South India

Groundwater quality of the Tiruppur district in Tamil Nadu was investigated in this study to develop a Water Quality Index (WQI) model. Hydrochemical parameters showed tremendous variation in certain location over the seasons. Ionic chemistry of groundwater suggested that textile industries and rock-water interaction are major threats to the water quality. Analysis of Na and Ca concentration indicates that direct as well as the inverse cation exchange controls the natural cation chemistry. NO3 concentration shows that the pre-monsoon samples were affected by the fertilizer usage in agricultural fields. Na-Cl type of the water was dominant throughout the study area except few locations. WQI showed that 55% of the pre-monsoon samples and the 47% of the post monsoon samples were classified as poor/very poor/unsuitable for drinking category. Leaching of the textile waste and their transport to the downstream was well observed during the post-monsoon season. The specific contribution of river Noyyal in the transport of the solutes to the discharge zones was proved by the hydrochemistry of the samples.     

Assessment of groundwater quality and its suitability for domestic and agricultural uses in Low-Isser plain,Boumedres, Algeria

The assessment of the suitability of groundwater for drinking and irrigation uses was carried out in the alluvial plain of Low-Isser in the north of Algeria. The plain covers an area of 533 km² and lies in a Mediterranean sub-humid climate. Groundwater is the main source for domestic uses and agricultural activities in this area. Groundwater samples were collected from 15 wells during dry and wet seasons in 2015, and they were analyzed for major cations and anions and compared with drinking and irrigation specification standards. The comparison of chemical concentration with WHO drinking water standards of 2006 shows that more than 30% of groundwater samples are unsuitable for drinking, and the majority of groundwater samples fell on the hard and very hard categories. Suitability of groundwater for drinking was also evaluated based on the water quality index (WQI). It shows more than 80% of samples have good or permissible water quality for dry and wet seasons. In terms of the irrigation usage, generally, groundwater in the study area is suitable for different uses in both seasons according to SAR, %Na, RSBC, and PI. However, water rock exchange processes and groundwater flow have been responsible for the dominated water type Ca–Mg–Cl.     

Visualizing the spatial water quality of Bentota,Sri Lanka in the presence of seawater intrusion

Seawater flows towards the inlands along with the rivers and canals, through the process of infiltration and leaks in the ground water characterized by high concentrations of soluble salts. High salinity concentrations can make groundwater unsuitable for public consumption and surface water unsuitable for irrigation and agricultural activities. This study envisages the fluctuations of ground and surface water quality of Bentota area in the presence of seawater intrusion. The temporal and spatial variations of eleven water parameters were monitored by collecting the water samples during one year period. Spatial distributions were assessed by applying the Inverse distance weighted (IDW) interpolation method in Arc GIS 10.5 software. Water quality is assessed on the integration of all parameters in terms of an index based on the World Health Organization (WHO) standards. The significant linear relationship between the considered parameters of surface water (SW) and groundwater (GW) were identified applying correlation analysis using SPSS software. All parameters of surface water were above the permissible limits of WHO standards. Surface water quality index values with respect to 60% of canals show very poor quality (>1 250) of surface water indicating their unsuitability for irrigation activities. Those surface water bodies indicated very highly saline conditions during dry months. The spatial distribution of ground water quality index with respect to the highest parameter values of each sampling location indicates that 52.2% of total land extent of Bentota Divisional Secretariat Division (DSD) has good quality of ground water which is suitable for drinking. Its 47.2% of total land extent has poor quality of ground water for drinking purpose and less than 0.5% of the area consists of excellent or very poor quality of ground water in each. This study helps to manage coastal aquifers by understanding the extreme water quality conditions and coastal salinity.     

Visualizing the spatial water quality of Bentota,Sri Lanka in the presence of seawater intrusion

Seawater flows towards the inlands along with the rivers and canals, through the process of infiltration and leaks in the ground water characterized by high concentrations of soluble salts. High salinity concentrations can make groundwater unsuitable for public consumption and surface water unsuitable for irrigation and agricultural activities. This study envisages the fluctuations of ground and surface water quality of Bentota area in the presence of seawater intrusion. The temporal and spatial variations of eleven water parameters were monitored by collecting the water samples during one year period. Spatial distributions were assessed by applying the Inverse distance weighted (IDW) interpolation method in Arc GIS 10.5 software. Water quality is assessed on the integration of all parameters in terms of an index based on the World Health Organization (WHO) standards. The significant linear relationship between the considered parameters of surface water (SW) and groundwater (GW) were identified applying correlation analysis using SPSS software. All parameters of surface water were above the permissible limits of WHO standards. Surface water quality index values with respect to 60% of canals show very poor quality (>1 250) of surface water indicating their unsuitability for irrigation activities. Those surface water bodies indicated very highly saline conditions during dry months. The spatial distribution of ground water quality index with respect to the highest parameter values of each sampling location indicates that 52.2% of total land extent of Bentota Divisional Secretariat Division (DSD) has good quality of ground water which is suitable for drinking. Its 47.2% of total land extent has poor quality of ground water for drinking purpose and less than 0.5% of the area consists of excellent or very poor quality of ground water in each. This study helps to manage coastal aquifers by understanding the extreme water quality conditions and coastal salinity.     

Evaluation of spatial variations in groundwater quality by WQI and GIS technique: a case study of Virudunagar District, Tamil Nadu, India

Groundwater plays a major life support to mankind. It is the major source to meet the domestic, irrigation and industrial water demands. The depletion of groundwater through excessive consumption and less recharge in the study area has detoriated the quality of groundwater. The present study has analyzed the pre- and post-monsoon physicochemical data of groundwater samples from 49 different bore wells in Virudunagar district. Spatial distribution maps were prepared for various physicochemical parameters using geographic information system. These maps are further classified according to highest desirable, maximum permissible and not permissible prescribed by the World Health Organization. Furthermore, a water quality index (WQI) map was also generated to understand the groundwater quality in the study area. It was observed that the groundwater in the area is hard and alkaline in nature and the WQI reveals that most part of the study area fall under fair water quality class. Also, the effect of recharge during monsoon period has diluted the geochemistry of the groundwater. The application of GIS and WQI in the study area is a promising tool to understand the spatial pattern of groundwater quality and its management.     

Assessment of hydrochemistry and groundwater quality in the coastal area of South Chennai,India

An attempt has been made to evaluate the water quality in the fast-growing coastal area of South Chennai. Groundwater samples were collected from selected locations and analyzed for major physico-chemical parameters. Experimental results show that the water has alkaline with pH varying from 7.2 to 8.2. Concentrations of Na and Cl were positively correlated with EC and elevated levels of these parameters near the coastal region, especially in the northern end of the study area, indicating the influence of seawater intrusion. Piper diagram identified Na–Cl as the dominant type of water in most of the samples. The presence of Ca–Cl facies in the groundwater suggests the possible ion exchange (Na with Ca) reaction in the aquifer. Molar ratios of Cl/HCO₃ and Mg/Ca showed a higher value (>1) in many samples, which confirmed the influence of seawater intrusion on water quality. The Water Quality Index (WQI) of the study area ranged between 8 and 116, the highest recorded being at Thiruvanmiyur and the lowest at Muttukkadu. However, total hardness values show that 64% of the samples were hard or very hard in nature. The results of SAR, Na%, and PI show that majority of the samples are suitable for irrigation purposes. A comparison of spatial distribution maps of water quality parameters with those of WQI shows that groundwater quality has highly deteriorated in the Thiruvanmiyur region, located on the northeast part of the study area. Good-quality water is found at the southeast part of the study area, namely, Muttukkadu. This study indicates that urbanization and seawater intrusion have heavily affected the groundwater quality of South Chennai coastal area.     

Assessing water quality using water quality index and multivariate analysis

Groundwater is increasingly gaining significance as the main solution to the water supply problems in Ghana, especially in the rural areas. This study was conducted to determine which factors play significant roles in the hydrochemistry of groundwater from the southern Voltaian formation. Conventional graphical and multivariate statistical methods were used. The study reveals three main factors controlling the hydrochemistry. Silicate mineral weathering and reverse cation exchange are the most important processes affecting the hydrochemistry of groundwater at this part of the formation. Interpolation maps created from factor scores suggest that these processes are the most pervasive, recording high scores almost everywhere in the study area. Carbonate mineral weathering is the second most important process in the hydrochemistry. This study finds that carbonate mineral weathering in the area is probably facilitated by carbonic acid rather than sulfuric acid. Chemicals from agricultural activities constitute the third most important process influencing groundwater quality in the area. Eighty samples were used to calculate water quality indices, WQI, which were in turn used to classify groundwater from the study area. Over 98% of the samples fall within the “Excellent” and “Good” categories, suggesting that groundwater from the southern Voltaian formation is generally acceptable for drinking purposes.     

Assessment of spatial relationship between groundwater pollution vulnerability and quality indices in Kano,Nigeria

Safeguarding groundwater from pollution is largely a global political decision. These decisions are basically supported by DRASTIC (D=Depth to water, R=Recharge, A=Aquifer media, S=Soil media, T=Topography, I=Impact of vadose zone, C=Hydraulic conductivity) analysis. Furthermore, water quality index (WQI) is an effective tool for groundwater quality evaluation and management. This study identifies the relationship between these two indices [i.e., pollution vulnerability index (PVI) and WQI]. The DRASTIC index of the study area was found to be from 60.4 to 178 characterized by very low, low, medium high, and very high vulnerability constituting of 12.88, 24.38, 34.11, 21.99, and 6.63% of the study area, respectively. In addition, the WQI of the area according to the analyzed parameters is between 10.19 and 55.63. It was established that a good correlation (61%) was found to exist between the two indices; which may be an indication that most pollutants present in the groundwater are likely due to anthropogenic activities on the land surface.     

GIS-based Evaluation of Water Quality Index of groundwater resources around Tuticorin coastal city,south India

Groundwater is a vital source of water for industrial, domestic and agricultural activities in Tuticorin city due to lack of surface water resources; groundwater quality and its suitability for drinking usage were evaluated. A total of 72 groundwater samples were collected from open wells and boreholes during pre and post-monsoon period. Samples were analyzed for physico-chemical properties, major cation and major anions in the laboratory using the standard methods given by the American Public Health Association. The geographic information system-based spatial distribution map of different major elements has been prepared using ArcGIS 9.2. These maps are classified as desirable, maximum permissible and the values that exceed maximum permissible limit are termed as not permissible prescribed by the WHO (2004). From the Piper plot, which gives the cation chemistry, the concentration of the alkalies (Na⁺ and K⁺) exceeds the alkaline earths (Ca²⁺ and Mg²⁺) and those of strong acids exceeds weak acids. In the case of anions, during the two periods strong acid shows dominance over weak acid and HCO₃ ^? and Cl^? have influences almost equal to Na⁺, which indicate the saltwater intrusion into the freshwater aquifer of the study area. A Canadian Council of Ministers for the Environment Water Quality Index (CCME WQI) map was also generated with the GIS technique to better understand the water portability over space. The categories of water quality evaluated by CCME WQI values of major part of the study area fall under fair category during PRM and good category during the POM period. The CCME WQI is a very useful and an efficient tool to summarize and to report on the monitoring data to the decision makers in order to understand the status of the groundwater quality. Finally, the study concludes that the groundwater quality is impaired by man-made activities, and proper management plan is necessary to protect valuable groundwater resources in Tuticorin city.     

Analysis of groundwater quality using water quality index and conventional graphical methods: the Volta region,Ghana

Conventional graphical and statistical methods were used with water quality indices to characterize the hydrochemistry of groundwater from the northern part of the Volta region of Ghana. The objective was to determine the processes that affect the hydrochemistry and the variation of these processes in space among the three main geological terrains: the Buem formation, Voltaian System and the Togo series that underlie the area, and to determine the suitability of groundwater from the area for drinking purposes. The Q-mode cluster analysis reveals three main water groups. The groups established from the Q-mode HCA appear to indicate different degrees of weathering which could further indicate varying levels of fracturing aquifer hydraulic properties. R-mode HCA and factor analysis (using varimax rotation and Kaiser Criterion) were then applied to determine the significant sources of variation in the hydrochemistry. This study finds that groundwater hydrochemistry in the area is controlled by the weathering of silicate and carbonate minerals, as well as the chemistry of infiltrating precipitation. Mineral activity diagrams for the CaO–Na₂O–Al₂O₃–SiO₂–H₂O and CaO–MgO–Al₂O₃–SiO₂–H₂O systems plotted for the area indicate stability in the smectite field and attribute hydrochemistry to the weathering of silicate minerals. Silicate mineral weathering and the effects of precipitation appear to be pervasive among all the three main geological terrains, whereas carbonate weathering is localized among the Voltaian aquifers. Cation exchange does not appear to play a significant role in the hydrochemistry but mild Water quality indices (WQI) were calculated for the samples using the concentrations of Na⁺, Ca²⁺, Mg²⁺, Cl⁻, NO₃ ⁻, F⁻, and EC at the various sample locations. The WQI values indicate that groundwater from the study area is of excellent quality for drinking purposes. WQI values from groundwater samples are averagely higher than samples taken from surface water sources in the area. This implies that geology has had an impact on the WQI of groundwater in the area.     

Identification of groundwater contamination sources in Dindugal district of Tamil Nadu,India using GIS and multivariate statistical analyses

The purpose of this research is to evaluate the groundwater quality in Dindugal district of Tamil Nadu based on the water quality index by geographic information system (GIS) and statistical analysis. This area consists of 80 functional tanneries around Dindigul town with a capacity to process about 200 Mt of hides and skins as leather. In 13 villages, as many as 1090 houses were damaged by tannery contamination. A total of 66 groundwater samples were collected to identify the geochemical sources and contamination. The order of major cations is Na > Ca > Mg > K, while that of anions is Cl > SO₄ > HCO₃ > F > PO₄. CaCl₂, MgCl₂, and (CaHCO₃)₂ types suggested that the mixing of high-salinity water was caused by irrigation return flow, domestic wastewater, and septic tank effluents, with existing water followed by ion exchange reactions. Moreover, Gibbs plots indicated that groundwater contamination was derived from the weathering of granitic gneisses as well as the leaching of evaporated and crystallized ions from agricultural and industrial effluents. The water quality index (WQI) exhibited 8 % of the groundwater samples were not suitable for drinking purpose. The GIS maps showed that the poor water quality decreased toward the southern part of the study area. WQI of TDS, fluoride, sodium, potassium, and bicarbonate were high in groundwater. Multivariate statistical analyses (principal component analysis (PCA), factor analysis (FA)) suggested that the groundwater chemistry was changed by the weathering of source rocks ion exchange and leaching of inorganic components and addition from anthropogenic effluents. Finally, it is thought that the monitoring and assessment works are very useful to understand the degree and sources of groundwater contamination.     

Hydrogeochemistry and water quality assessment of shallow aquifers in the western flanks of Southern Western Ghats,SW India

The present study deals with the hydrogeochemistry and water quality of shallow aquifers in two important river basins—the Ithikkara and Kallada river basins—draining the south western flanks of Western Ghats in Kerala, South West India. Well water samples were collected from 20 dug wells with a depth range of 1 m below ground level (mbgl) to 18.2 mbgl during pre-monsoon, monsoon, and post-monsoon seasons of the year 2011–2012. These samples were analyzed for various physico-chemical parameters following standard methods and were evaluated for their interrelations and drinking water suitability. The pH of the water samples shows wide variation from highly acidic to highly alkaline water. About 80% of pre-monsoon samples recorded Fe²⁺ concentration above the permissible limit of drinking water standard. Water Quality Index (WQI) shows that majority of the well water samples fall in the category of excellent–good for drinking purpose. The results of the irrigation suitability assessment using the procedures like Percent Sodium, Sodium Absorption Ratio, Residual Sodium Carbonate, Kelly Index, Permeability Index, and Magnesium Hazard reveal that the well waters of the study area are fit for irrigation purpose. Na⁺/Cl^? ratio reflects the release of sodium to water due to silicate weathering. The samples have a Ca²⁺/Mg²⁺ ratio equal or greater than 2 indicating the effect of silicate minerals in contributing Ca²⁺ and Mg²⁺ ions to the well water. The saturation indices reveal that groundwater is supersaturated with SiO₂. Among the causative factors that determine the hydrochemical quality of well water samples, silicate weathering plays a pivotal role with significant input of ions from anthropogenic sources.     

An Analysis of Groundwater in Sinjar Plain (Northwest of Iraq) Using WQI Model

INTRODUCTlONGroundwater is very important in arid and semi--arid areasand in areas located far away from sources of surface water. Itdoes not contain suspended materials, organic materials andbacteria (as long as it does not get polluted from othersources), but it mostIy contains mineraI and chemicaI com-pounds with identified quantities, depending on the type ofrocks presented in the area.The importance of groundwater relies on its quantity,avai1ability and how to substitute its used amo…     

Assessment of water quality index for the groundwater in the upper Cheliff plain,Algeria

Assessment of groundwater suitability for drinking and agricultural purposes was carried out in the plain of upper Cheliff. The study area covers an area of 375 km² and lies in a semiarid climate. Groundwater is the major source for domestic and agricultural activity in this area. Groundwater samples were collected from 19 wells during dry and wet periods in 2012, and they were analyzed for major cations and anions and compared with drinking and irrigation specification standards. The concentration of the majority of chemical constituents exceeds the standards of WHO as a result of various sources of pollution. It indicates the dominance of groundwater types: Ca-Mg-Cl, and Ca-Mg-HCO₃. Suitability of groundwater for drinking was evaluated based on the water quality index; it shows more than 60% of samples have very poor quality for dry and wet periods, which means water is severely contaminated and unsuitable for drinking purpose. In terms of the irrigation usage, generally groundwater is suitable for both periods in the major part of the plain. The Mineralization processes in this area is determined by the lithology of the aquifer (exchange water-rock), by anthropogenic factors (discharges of urban sewage, use of fertilizers) and also by evaporation (semi-arid climate).     

Hydrogeochemical characterization and groundwater quality assessment in Al-Hasa,Saudi Arabia

Fifty groundwater samples were collected from Al-Hasa to analyze the pH, electrical conductivity (EC, dS m^?1), total dissolved solids (TDS), major anions (HCO₃^?, CO₃^2?, Cl^?, SO₄^2?, and NO₃^?), major cations (Ca²⁺, Mg²⁺, Na⁺, and K⁺), and total hardness. The analyzed data plotted in the Piper, Gibbs, and Durov diagrams, and water quality index (WQI) were calculated to evaluate the groundwater geochemistry and its water quality. The results reveal that most of the investigated samples are Ca²⁺, Mg²⁺, SO₄^2?, Cl^? and Na⁺, and HCO₃^? water types using the Piper diagram. Na⁺?>?Ca²⁺?>?Mg²⁺ are the dominant cations, while Cl^??>?HCO₃^??>?SO₄^2??>?CO₃^2? are the dominant anions. Sodium adsorption ratio (SAR) values varied from 0.79 to 10; however, the Kelly ratio (KR) ranged between 0.1 and 2.2. The permeability index (PI) showed that well water is suitable for irrigation purposes with 75% or more of maximum permeability. The US salinity diagram revealed that the water quality classes of studied waters were CIII-SI, CIII-SII, and CIV-SII, representing height hazards of salinity and medium- to low-sodium hazard. The water quality index (WQI) results indicated that total dissolved solids are out of the drinking water standard limits in Saudi Arabia. The WQI revealed that 38% of the studied wells were considered as poor water (class III), 52% are found as very poor water class (IV), and 10% are unsuitable water for drinking class (V).     

Evaluation of groundwater quality for irrigation and drinking using GIS and geostatistics in a peri-urban area of Delhi, India

Intensive agriculture by indiscriminate use of agrochemicals, sewage water, and polluted drain water has posed a serious threat to groundwater quality in some peri-urban areas of Delhi like Najafgarh block. The objective of the study was to determine the groundwater quality and to map their spatial variation in terms of suitability for irrigation and drinking purpose. Ordinary kriging method was used for preparation of thematic maps of groundwater quality parameters such as electrical conductivity, sodium adsorption ratio, bicarbonate, magnesium/calcium ratio, total dissolved solids, chloride, nitrate and hardness. Exponential semivariogram model was best fitted for all quality parameters except chloride and hardness, where spherical model fitted best. Pollution level was highest at south and south-eastern part of the study area. Better quality groundwater may be expected at the northern and western part. High salinity was due to high chloride concentration in the groundwater. Nitrate pollution level was found to be very alarming and need immediate interventions. High dissolved solids and hardness made the groundwater unsuitable for drinking. There were negligible sodium and bicarbonate hazard in the study area. The groundwater quality index was devised to analyse the combined impact of different quality parameters on irrigation and drinking purposes. The irrigation water quality index and drinking water quality index distribution maps delineated an area of 47.29 and 6.54 km² suitable for irrigation and drinking, respectively. These safe zones were found as a small strip along the northern boundary and a very small pocket at the western side of the study area.     

Groundwater quality assessment in urban environment

The assessment of environmental effects generated by urban areas (with various activities as agriculture, industry, human activities) on groundwater quality became essential for the use and conservation of the water resources. The main objective was to apply a water quality index to the groundwater sources using the specific methodology, establishing the suitability for drinking for groundwater. Water resources were monitored in October 2011, the samples were collected from 22 points for groundwater, and more parameters were analyzed: pH, electrical conductivity, turbidity, oxygen regime, hardness, alkalinity, nutrients regime (nitrates, ammonium, phosphates) which were considered important and utilized for water quality index computation that reveal poor quality for groundwater. The oxidability should be included in computation formula and the final results used for water management, taking into consideration the limits of the current model. Multivariate statistical analysis was used to indicate the influence of urban area on the quality of groundwater resources. Results of the analysis highlight an influence of geology and a contamination of agricultural origin.     

Precipitation controlled spatial variations in groundwater quality indices-suitability for drinking and irrigation purposes in the basalts of South India

Regional study on the impact of variations in input rainfall over groundwater quality and its suitability for utilitarian purposes is essential for its extraction and management. Water chemistry from 456 observations wells for 2007–2011 period in hard rock Basaltic terrain of Upper Godavari basin is supported with 8 field samples (in 2014) in this analysis. Based on mean annual rainfall (MAR), four narrow climatic zones are identified in the basin, defined as “humid” (MAR > 1600 mm), “sub-humid” (1600–1000 mm), “semi-arid” (1000–600 mm), and “arid” (MAR < 600 mm). NICB ratio (<±10%), and anionic percentages demarcated the polluted areas from rest “good data”, composing of 1818 samples. Hydrochemical facies are studied using Piper diagram, secondary alkalinity exceeded 50% and not one cation–anion pair exceeded 50%, and silicate–carbonate plot, arid zone nearer to silicate pole indicated the dominance of SiO₂ in Ca/Na vs Mg/Na plot. These geochemical variations emphasize a detailed study on role of climatic gradient on groundwater suitability for different purposes, for groundwater extraction, and its management. Suitability of groundwater for drinking based on water quality indices (WQI) indicated 98% of the samples as suitable (WQI < 50%). TDS in humid zone is 150–500 and 500–1000 mg/L in rest of the zones with ～68% in permissible range, 15% as hard water (TDS > 600 mg/L) and not acceptable for drinking. Suitability of groundwater for irrigation is studied using sodium percentage (Na %), Wilcox diagram, sodium absorption ratio (SAR), US salinity diagram, residual sodium carbonate (RSC), permeability index (PI), Kelly’s ratio (KR), ancd magnesium absorption ratio (MgAR). Na % in four zones is < 60% and permissible for irrigation. Very few water samples fall in “doubtful to unsuitable” and “unsuitable” category of Wilcox diagram. Region is observed to have SAR < 6, indicating that water would not cause any problem to the soil and crop. Humid and sub-humid zones belonged to C1S1 and C2S1 categories (low and medium sodium), while semi-arid extended to C3S1 category (salinity hazard zone) in US salinity plot. RSC for all the three zones ranged from 1 to 1.5 meq/L, with 90–95% of the area safe for irrigation. Out of 1818 samples, 1129 belonged to class 2 of PI classification (PI ranging from 25 to 75%) while rest 689 samples had PI >75% (class 1). KR varied from 0.05 to 12.81, with 70–80% of the area having KR < 1. MgAR ratio ranged from 67% to 96%, with sub-humid, humid zones having higher Mg concentrations (increased salinity). Thus, 90% of the samples indicated non-alkaline water with 1% of normal alkalinity. Hence, the current study systematically analyzed the effect of precipitation and geology on groundwater quality and on its usability for various purposes. This stepwise procedure categorized the regions, and the same can be adopted for any regional hydrogeochemical studies.