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1.
沈敢富 《地球化学》1976,(4):279-284,312
An investigation has been conducted of the geological and geochemical characteristics of euxenitebearing granitic veins found for the first time in China. It is shown that these veins are late intrusives in an Yah Shah granitic complex at a geosyclinal folded zone and composed mainly of medium grained biotite granite in which the local enrichment of euxenite during the late period of magmatic activity is obvious. The mineral has been found to be metamiet and chemically represent a transitional member between euxenite and polyclase. This study has provided a typical example that gralitic melts with a lower initial content of rare elements would contribute significantly to the local enrichment of rare element minerals under special external conditions.  相似文献   

2.
Cu–Au mineralization is rare in the Jurassic–Early Tertiary batholiths related to the India–Asia collision. Geochemical analysis and U–Pb isotope chronology was carried out on Shuangbujiere biotite hornblende granodiorite from the Zedong area. Zircon grains of the biotite hornblende granodiorite show oscillatory growth zonation and have high Th/U ratios of 1.08–2.39, indicating a magmatic origin for the zircons. Geochrological test yielded a LA-ICP-MS U-Pb age of 51.5±1.0 Ma, suggesting that the emplacement age of the biotite hornblende granodiorite is Early Eocene. The Shuangbujiere biotite hornblende granodiorites have geochemical features characteristic of adakite and are associated with a calc–alkaline metaluminous I-type granite enriched in Sr, high in Mg~#(49.6–54.9) and Sr/Y, and depleted in Y and Yb. These results indicate that this intrusion formation may have been associated with crustal thickening caused by the early collision of the Indian and Eurasian Plates. As the process of crustal thickening continued, the heating of the underplated basaltic magma caused the thickened lower crust amphibolite to dehydrate the melt and form a high-K calc–alkaline adakitic melt at about 848°C. Meanwhile, magma mixing of the underplated basaltic melt and high-K calc–alkaline adakitic melt formed a high-Mg# adakite representative of the sys-collisional tectonic setting.  相似文献   

3.
The Erlangmiao granite intrusion is located in the eastern part of the East Qinling Orogen.The granite contains almost 99 vol.% felsic minerals with accessory garnet,muscovite,biotite,zircon,and Fe-Ti ...  相似文献   

4.
某钽铌钨铍矿化花岗岩岩石化学特征   总被引:1,自引:0,他引:1  
章崇真 《地球化学》1975,(2):135-146
During the magmatie evolution from biotite granite through two-mlca granite to mineralized muscovite granite it has been noted that Na^ , Mm^2 , Si^4 increase while K^ , Ca^2 , Mg^2 , Fe^2 , Fe^3 , Ti^4 , and P^5 decrease systematically in this district. Oreforming metals occur in higher abundance in biotite granite which is thought to be the representative of primary magma, and have been enriched rapidly with magmatic evolution R^ /R^2 Na^ /K^ , Rb/K, Mn/Fe and other petrochemical parameters increase whereas Ti^4 /Si^4 decreases in a sympathetic way with the enrichment of niobium and tantalum, providing good indicators of the degree of differentiation and metasematism of the magma ,Within the mineralized granite, there is a same trend of variation upward whioh is found closely related to the enrichment of tantalum. Fluorine is strongly concentrated in wall rocks above blind mineralized granite, and the eontente of tantalum and niobium in wolframite from quartz veins genetically related to the granite increase towards buried mineralization. The latter two phenomena are suggested by the author as clues to buried ore bodies.  相似文献   

5.
Coexisting quartz, feldspar and biotite vary widely in their δ18O values and display a remarkable 18O/16O disequilibrium relation; especially, a quartz-feldspar reversal (△ 18OQUartz_feldspar< 0) exsists in the Aral granite pluton of the Altay Mountains, northern Xinjiang. The 18O / 16O exchange reaction definitely occurred between granite and water. Initial δ18O values of the granite and exotic fluid are evaluated by the mass balance consideration. The conventional method of discrimination between various magma derivations simply with δ18O values of either whole rock or separate minerals is misleading and unreliable. Experiments carried out by the authors show that the 18O / 16O exchange reaction is not accompanied by what geologists describe as petrological and mineralogical alteration effect. This decoupling relation implies that exchange reaction occurs at a relatively high temperature during subsolidus-postmagmatic cooling of magmas. The exchange mechanism is mainly diffusion-controlled. It is  相似文献   

6.
某地钽铌钨铍矿化花岗岩   总被引:1,自引:0,他引:1  
章崇真 《地球化学》1974,(4):249-257
The tantalum-, niobium-, tungsten-, beryllium-mineralized granite described in this paper is identified as albitizied fine-grained muscovite granite and occurs as a small discordant taeolity with a bulging central part, dipping and finning out outwards.A crust of quartz-pegmatoid, several tens of centimeters thick, dsvelopes in its apices. Major rock-forming minerals are plagioclase, mierocline, albite, muscovite and quartz. Partsehinite, fluorite and topaz are characteristically abundant among accessory minerals. Rare element and base metal minerals include wolframite,scbeellte, microlite, raanganese-rich columbite, berly, phenacite, xenotirae, monazite,cassitcrite, raolybdenite, bisrauthinite, etc. Niobium and beryllium mineralizations are uniformly present throughout the rock body, but tantalum is feund richer in upper parts than in lower parts. It is tentatively suggested that this is a differentiationmctasomatic deposit of fracture-filling type originated during late magmatic stage.  相似文献   

7.
This study is concerned with the radioactivity and mineralogy of the younger granites and pegmatites in the Wadi Haleifiya area, southeastern Sinai Peninsula, Egypt. The area is occupied by metasediments, migmatites, older and younger granites. Most of these rocks, especially granites, are dissected by mafic and felsic dykes as well as pegmatites. The younger granites are represented by three main varieties: monzogranites, syenogranites and alkali feldspar granites. The monzogranite consists essentially of quartz, plagioclase, potash feldspar and biotite with minor musco-vite. Iron oxide, titanite, zircon and allanite are the main accessory minerals. Syenogranite is massive, medium- to coarse-grained and commonly exhibits equigranular and hypidiomorphic textures. It is made up essentially of potash feldspar, quartz, plagioclase and biotite. Iron oxides, allanite, epidote, titanite, and zircon are accessory minerals. The alkali feldspar granite consists mainly of perthite, quartz, alkali amphibole (arfvedsonite and riebekite), biotite, sub-ordinate plagioclase and aegirine. Iron oxide, zircon and apatite are accessory minerals, whereas chlorite and sas-surite are secondary minerals. The altered monzogranite and pegmatite recorded high radioelement contents. The eU reaches up to 120 (av.=82×10-6) in the altered monzogranite and up to 55 (av.=27×10-6) in the pegmatites. The high radioactivity in the altered monzogranite is due to the presence of thorite, uranothorite and metamict zircon. In the pegmatites, it is re-lated to the presence of uranophane, uranothorite, thorite, zircon, samarskite, monazite, xenotime, magnetite, ilmen-ite, hematite and rutile.  相似文献   

8.
周维全 《地球化学》1977,(3):227-234
Alkali amphibole asbestus is widely distributed in a Mesozoic terrestrial redbed.Preliminary mineralogical study shows that it belongs to magnesian riebeckite asbestus. The mineral contains higher Na, Mg and Fe^3 , lower Al, and is well comparable with that of typical magnesian riebeckite asbestus in chemical composition. A comparasion between the methods used for calculating the crystallochemical formula of amphibole indicatesthat the structural characteristics of amphibole can be best brought out if a total catian number of 15, i.e., x y z=15, is taken as the factor for magnesian riebeckite. The infrared spectra for fibrous magnesian riebeckite exhibit two definite absorption bands. The firat one is at 850--1250 cm^-1, involving several minor bands due to the valency vibration of Si--O, with maximum values of 975,1025, 1080cm^-1 respectively. The second absorption band which is attributable to the distortional vibration of Si--O--Si, is detected at 350--600cm^-1, with a maximum value of 440cm^-2. Optically, its refractien iadices bacrease with increasing transition elements, especiany the ratio of Mg/Mg Fe^2 Fe^3 Mn. A distinct exothermic effect is observed between 350--400℃, indicating the oxidation of Fe^3 to Fe^3 . A deep endothermic valley between 970--1020℃ can be attributed to the melting of magnesian riebeckite and the formation of new minerals. The auther oonsideres that fibrous magnesian riebeckite is crystallized in favorable accumulation strata from a Na-, Mg-, Fe-rich silicate colloidal solution that has been derived from country rocks by some alkline ground water duringg the process of sedimentation and diagenesis in terrestrial saline carbonate muds. Magnesian riebeckite formed at terrestrial carbonate saline formations promises to be a potentially important genesis type for alkali amphiboles.  相似文献   

9.
To the north of the Qinling-Dabie orogen there exists a Mesozoic (K1) granite-syenite belt called the Beihuaiyang granite-syenite belt, in which the Xianghongdian alkaline complex outcrops in the Devonian Foziling schist and also intruded into the slightly earlier volcanic rocks. This alkaline complex is composed of syenite, alkaline syenite and nepheline syenite, but the nepheline syenite occurs inside the alkaline syenite in the pod-like, irregular, lenticular or layered shape. Researches on the petrogenesis of the alkaline complex and the relationship between the alkaline syenite and the nepheline syenite must rely on precise isotopic ages. Previous researches have reported iso-topic dating results merely by the 40Ar/39Ar method on hornblende and biotite separated from the alkaline syenite and nepheline syenite. In view of this, the authors have made fairly detailed isotopic geochronological studies of the alkaline syenite and nepheline syenite by using Rb-Sr isochron for the whole rock and minerals,  相似文献   

10.
Rare metal mineralization of Sn, Nb-Ta and W is encountered in the Gebel Dihmit area (GDA), southeastern Aswan, Egypt. The mineralization is related to muscovite granites and their pegmatite derivatives. The pegmatites are divided into three types according to their main mineral assemblages: K-feldspar-muscovite-tourmaline, K-feldspar-albite-muscovite and albite-K-feldspar-lepidolite veins. Petrogenetic studies indicate that Sn and Nb-Ta mineralization extends from the late-magmatic stage to the pegmatite and hydrothermal stages of the (GDA) suite. The albite-K-feldspar-lepidolite granite is composed dominantly of albite, lepidolote, and quartz, with topaz, K-feldspar and amblygonite. The accessory minerals are zircon, monazite, pollucite, columbite-tantalite, microlite and Ta-rich cassiterite. Phenocrysts of quartz, topaz and K-feldspar contain abundant inclusions of albite laths and occasional lepidolite crystals along growth zones (snowball texture), indicating simultaneous crystallization from a subsolvus, residual magma. The origin of the pegmatites is attributed to extreme differentiation by fractional crystallization of a granitic magma. The economic potential for rare metals was evaluated in the geochemical discrimination diagrams. Accordingly, some of the pegmatites are not only highly differentiated in terms of alkalis, but also the promising targets for small-scale Ta and, to a less extent, Sn. The pegmatites also provide the first example of Fe-Mn and Nb-Ta fractionation in successive generations of granites to cassiterite-bearing pegmatites, which perfectly ex- hibit similar fractionation trends established for primary columbite-tantalite in the corresponding categories of pegmatites. Uranium and Th of magmatic origin are indicated by the presence of thorite and allanite, whereas evidence of hydrothermal mineralization is the alteration of rock- foring minerals such as feldspar and the formation of secondary minerals such as uranophane..  相似文献   

11.
The Madi rare metal granite is a complex massif, which contains a variety of rare metals, such as Nb, Ta, Li, and Be. In this paper, the geochemical characteristics of the granite were obtained by multi-collector inductively coupled mass spectrometry (MC-ICP-MS). The precise crystalline age of the granite was obtained from monazite U-Pb dating, and the source of the granite was determined using Li-Nd isotopes. The Madi rare metal granite is a high-K (calc-alkaline), peraluminous, S-type granite. The U-Pb monazite age indicates that the crystalline age of the granite is 175.6 Ma, which is Early Jurassic. The granite is characterized by a relatively wide range of δ7Li values (+2.99‰ to +5.83‰) and high lithium concentrations (181 ppm to 1022 ppm). The lithium isotopic composition of the granite does not significantly correlate with the degree of magmatic differentiation. An insignificant amount of lithium isotope fractionation occurred during the granitic differentiation. The lithium isotopic composition of the granite significantly differs from that of the wall rock, but it is very similar to that of a primitive mantle peridotite xenolith (mean δ7Li value +3.5‰). The plot of Li concentration versus δ7Li indicates that the Li isotopic composition of the granite is similar to that of island arc lavas. Based on the above-described evidence, the granite was mainly derived from the crust, but it was contaminated by a deep granitic magma.  相似文献   

12.
The medium- to coarse-grained and porphyritic granitoid of Dharmawaram, Karimnagar district, Andhra Pradesh, south India is a biotite-hornblende granite with notable contents of rare metal (Zr, Hf, Th) and rare earth (including Y) minerals like zircon, thorite, allanite, monazite and xenotime. Chemically, it is metaluminous (average A/ C+N+K = 0.95)-type, potassic (av. 5% K2O) granite, with dominantly sub-alkaline characters. It shows up to 8 times enrichment of rare metals (Zr, Hf, U, Th) and rare earths (including Y, Sc), with reference to their abundances in normal unevolved granite, and hence, fertile for some of these elements. Field, petrological, geochemical and isotopic data of potassic granite (PG) indicate involvement of silica-rich metasedimentary-basic crustal rocks (amphibole-quartzite, amphibolite, hornblende-biotite gneiss, etc.) in its genesis, at a depth range of 30 km. Further, chondrite-normalized REE patterns demonstrate that low-degree partial melting of source rocks is the major con  相似文献   

13.
The Jiangla'angzong granite in the northern part of the Central Lhasa Terrane is composed of syenogranite and adamellite. LA-ICP-MS zircon U-Pb analyses suggest that syenogranite has a weighted mean ~(206) Pb/~(238) U age of 86±1 Ma(mean square weighted deviation=0.37), which is in accordance with the muscovite Ar-Ar age(85±1 Ma) of Cu-Au ore-bearing skarns and the zircon U-Pb age(84±1 Ma) of adamellite. This suggests that the Jiangla'angzong magmatism and Cu–Au mineralization events took place during the Late Cretaceous. The granite contains hornblende, biotite, and pyroxene, and does not contain Al-bearing minerals, such as muscovite, cordierite, and garnet. It has high contents of SiO_2(65.10–70.91 wt%), K_2O(3.44–5.17 wt%), and total K_2O+Na_2O(7.13–8.15 wt%), and moderate contents of A_(12)O_3(14.14–16.45 wt%) and CaO(2.33–4.11 wt%), with a Reitman index(σ43) of 2.18 to 2.33, and A/CNK values of 0.88 to 1.02. The P_2O_5 contents show a negative correlation with SiO_2, whereas Pb contents show a positive correlation with SiO_2. Th and Y contents are relatively low and show a negative correlation with the Rb contents. These characteristics suggest that the Jiangla'angzong granite is a high K calc–alkaline metaluminous I–type granite. It is enriched in light rare earth elements(LREE) and large ion lithofile elements(LILE), and depleted in heavy rare earth elements(HREE) and high field strength elements(HFSE), with LREE/HREE ratios of 11.7 to 18.1. The granite has negative Eu anomalies of 0.58 to 0.94 without obvious Ce anomalies(δCe=1.00–1.04). The relatively low initial 87 Sr/86 Sr ratios of 0.7106 to 0.7179, positive εHf(t) values of 1.0 to 4.1, and two-stage Hf model ages(TDM2) ranging from 889 Ma to 1082 Ma, These geochemical features indicate that the granite derived from a juvenile crust. The(~(143) Nd/~(144) Nd)_t values from the Jiangla'angzong granite range from 0.5121 to 0.5123, its εNd(t) values range from-10.17 to-6.10, its(~(206) Pb/~(204) Pb)_t values range from 18.683 to 18.746, its(~(207) Pb/~(204) Pb)_t values range from 15.695 to 15.700, and its(~(208) Pb/~(204) Pb)_t values range from 39.012 to 39.071. These data indicate that the granite was formed by melting of the upper crust with the addition of some mantle materials. We propose that the Jiangla'angzong granite was formed during the postcollision extension of the Qiangtang and Lhasa terranes.  相似文献   

14.
The Boziguoer A-type granitoids in Baicheng County,Xinjiang,belong to the northern margin of the Tarim platform as well as the neighboring EW-oriented alkaline intrusive rocks.The rocks comprise an aegirine or arfvedsonite quartz alkali feldspar syenite,an aegirine or arfvedsonite alkali feldspar granite,and a biotite alkali feldspar syenite.The major rock-forming minerals are albite,K-feldspar,quartz,arfvedsonite,aegirine,and siderophyllite.The accessory minerals are mainly zircon,pyrochlore,thorite,fluorite,monazite,bastnaesite,xenotime,and astrophyllite.The chemical composition of the alkaline granitoids show that SiO2 varies from 64.55% to 72.29% with a mean value of 67.32%,Na2O+K2O is high (9.85%-11.87%) with a mean of 11.14%,K2O is 2.39%-5.47% (mean =4.73%),the K2O/Na2O ratios are 0.31-0.96,Al2O3 ranges from 12.58% to 15.44%,and total FeOT is between 2.35% and 5.65%.CaO,MgO,MnO,and TiO2 are low.The REE content is high and the total SREE is (263-1219) ppm (mean =776 ppm),showing LREE enrichment and HREE depletion with strong negative Eu anomalies.In addition,the chondrite-normalized REE patterns of the alkaline granitoids belong to the "seagull" pattern of the right-type.The Zr content is (113-1246) ppm (mean =594 ppm),Zr+Nb+Ce+Y is between (478-2203) ppm with a mean of 1362 ppm.Furthermore,the alkaline granitoids have high HFSE (Ga,Nb,Ta,Zr,and Hf) content and low LILE (Ba,K,and Sr) content.The Nb/Ta ratio varies from 7.23 to 32.59 (mean =16.59) and the Zr/Hf ratio is 16.69-58.04 (mean =36.80).The zircons are depleted in LREE and enriched in HREE.The chondrite-normalized REE patterns of the zircons are of the "seagull" pattern of the left-inclined type with strong negative Eu anomaly and without a Ce anomaly.The Boziguoer A-type granitoids share similar features with A1-type granites.The average temperature of the granitic magma was estimated at 832-839℃.The Boziguoer A-type granitoids show crust-mantle mixing and may have formed in an anorogenic intraplate tectonic setting under high-temperature,anhydrous,and low oxygen fugacity conditions.  相似文献   

15.
Zinccopperite (tentatively named) is a rare native alloy mineral discovered in quartz monzonite-porphyry in the Xifanping area, Yanyuan County, Sichuan Province. It is a new variety of zinc-copper alloy mineral found for the first time in the porphyry-copper deposit in China. Its intergrown minerals are K-feldspar (mainly perthite), albite-oligoclase, quartz and biotite; and the associated minerals include pyrite and chalcopyrite. It is characterized by a golden reflection colour, being isotropic (isometric), with the grain size ranging from 10 to 50 μm, microhardness VHN10= 190 kg/mm2, and reflectance RVis= 67.97%. Electron microprobe (Model JXA-733) analysis shows Cu = 59.15%-62.55% and Zn= 36.32%-39.85%. The crystallochemical formula is Cu6.27-7.0Zn4.0, simplified as Cu7Zn4.  相似文献   

16.
The Burpala alkaline massif contains rocks with more than 50 minerals rich in Zr,Nb,Ti,Th,Be and rare earth elements(REE).The rocks vary in composition from shonkinite,melanocratic syenite,nepheline and alkali syenites to alaskite and alkali granite and contain up to 10%LILE and HSFE,3.6%of REE and varying amounts of other trace elements(4%Zr,0.5%Y,0.5%Nb,0.5%Th and 0.1%U).Geological and geochemical data suggest that all the rocks in the Burpala massif were derived from alkaline magma enriched in rare earth elements.The extreme products of magma fractionation are REE rich pegmatites,apatite-fiuorite bearing rocks and carbonatites.The Sr and Nd isotope data suggest that the source of primary melt is enriched mantle(EM-Ⅱ).We correlate the massif to mantle plume impact on the active margin of the Siberian continent.  相似文献   

17.
<正>Jinshan gold deposit is located in northeastern Jiangxi,South China,which is related to the ductile shear zone.It has a gold reserve of more than 200 tons,with 80%of gold occurring in pyrite. The LREE of gold-bearing pyrite is as higher as 171.664 ppm on average,with relatively higher light rare earth elements(LREE;159.556 ppm) and lower HREE(12.108 ppm).TheΣLREE/ΣHREE ratio is 12.612 and(La/Yb)_N is 11.765.These indicate that pyrite is rich in LREE.The(La/Sm)_N ratio is 3.758 and that of(Gd/Yb)_N is 1.695.These are obvious LREE fractionations.The rare earth element(REE) distribution patterns show obvious Eu anomaly with averageδEu values of 0.664,andδCe anomalies of 1.044.REE characteristics are similar to those of wall rocks(regional metamorphic rocks),but different from those of the Dexing granodiorite porphyry and Damaoshan biotite granite.These features indicate that the ore-forming materials in the Jinshan gold deposit derived from the wall rocks, and the ore-forming fluids derived from metamorphic water.The Co/Ni ratio(average value 0.38) of pyrite suggests that the Jinshan gold deposit formed under a medium-low temperature.It is inferred from the values of high-field strength elements,LREE,Hf/Sm,Nb/La,and Th/La of the pyrite that the ore-forming fluids of the Jinshan gold deposit derived from metamorphic water with ClF.  相似文献   

18.
The accessory minerals apatite and sphene are the main carriers of REE in alkaline rocks.Their chondrite-normalized REE patterns decline sharply to the right as those of the host rocks,In the patterns an obvious negative Eu anomaly and a positive Ce anomaly can be seen in apatite and sphene,respectively.Zircon from alkaline rocks is different in REE pattern,I,e,. a nearly symmetric“V“-shaped pattern with a maximum negative Eu anomaly.Compared with the equivalents from granites,apatite,sphene and zircon from alkaline rocks are all characterized by higher (La/Yb)N ratio and less Eu depletion,As to the relative contents of REE in minerals,apatite,sphene and zircon are enriched in LREE,MREE and HREE respectively,depending on their crystallochemical properties.  相似文献   

19.
Enclaves in intermediate-acid plutons from Tongling can be divided into three types: xenoliths, relics and magmatogenic enclaves. The magmatogenic enclaves consist of cumulates, micrograined dioritite mixtite and dioritic chilled border enclaves. Petrologically, relics with eyed and meta-poikilitic texture are characterized by high content of biotite (>80%) and low content of cordierite and grossular. The cumulates with accumulate texture consist of a great amount of pyroxene, hornblende and minor spinel and phlogopite. The micrograined dioritic mixtite is composed of more hornblendes and feldspar and less needle apatites and an ellipsoid basic core included in plagio-clase. The chilled border enclaves have the same mineral association, but more dark minerals than the host rocks consisting of plagioclase, quartz, alkaline feldspar, hornblende and biotite. Geochemically, the relics exhibit high REE content (455.8×10-6) and high ratio of LREE/HREE, more obvious Eu negative anomaly and are rich in Cr and  相似文献   

20.
西藏南部花岗岩类中重结晶的黑云母与板块碰撞的关系   总被引:2,自引:0,他引:2  
Recrystallized biotite occurs in granitoid rocks from some plutens in the Lhagoi Kangri and Kangdese belts in southern Xizang. These plutons are characterized by well-developed micro-fractures, orientational arrangement of dark minerals showing gneissose structures to varing extents. This is consistent with the fact that K-Ar ages of crystallized biotite (30--17 my) are much younger as compared with the host rooks. Recrystallized biotites are mostly recognized along the tectonic suture line between the Indian plate and the Eurasian continental plate, i.e., in the neighborhood of the Yarlung Zangbo River and its north bank as well as in the Lhagoi Kangri Ranges.The authors postulate that when drifting north-northeastward, the Indian sub-continental plate was conteracted by the Kangdese belt as a result of the subduction of the Indian plate underneath the Eurasian Continental plate, causing a dramatic increase instress on the southern side, i.e., near the tectanic suture line, of the rock belt followed by the rising of temperature which resulted in the recrystallization of biotite in some plutons.  相似文献   

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