Mineralogy,petrology, chronology,and exposure history of the Chelyabinsk meteorite and parent body

Three masses of the Chelyabinsk meteorite have been studied with a wide range of analytical techniques to understand the mineralogical variation and thermal history of the Chelyabinsk parent body. The samples exhibit little to no postentry oxidation via Mössbauer and Raman spectroscopy indicating their fresh character, but despite the rapid collection and care of handling some low levels of terrestrial contamination did nonetheless result. Detailed studies show three distinct lithologies, indicative of a genomict breccia. A light‐colored lithology is LL5 material that has experienced thermal metamorphism and subsequent shock at levels near S4. The second lithology is a shock‐darkened LL5 material in which the darkening is caused by melt and metal‐troilite veins along grain boundaries. The third lithology is an impact melt breccia that formed at high temperatures (~1600 °C), and it experienced rapid cooling and degassing of S₂ gas. Portions of light and dark lithologies from Chel‐101, and the impact melt breccias (Chel‐102 and Chel‐103) were prepared and analyzed for Rb‐Sr, Sm‐Nd, and Ar‐Ar dating. When combined with results from other studies and chronometers, at least eight impact events (e.g., ~4.53 Ga, ~4.45 Ga, ~3.73 Ga, ~2.81 Ga, ~1.46 Ga, ~852 Ma, ~312 Ma, and ~27 Ma) are clearly identified for Chelyabinsk, indicating a complex history of impacts and heating events. Finally, noble gases yield young cosmic ray exposure ages, near 1 Ma. These young ages, together with the absence of measurable cosmogenic derived Sm and Cr, indicate that Chelyabinsk may have been derived from a recent breakup event on an NEO of LL chondrite composition.     

Complex brecciation and shock effects in the Buck Mountain Wash (H3–5) chondrite

Abstract Buck Mountain Wash (BMW) is a new genomict breccia (H3‐5) found in the Franconia (H5) strewn field in Arizona that shows complex brecciation and shock effects. It contains three distinct chondritic lithologies in sharp contact: a) a main lithology that consists primarily of petrographic type 5 material but which has finely intermixed type 3 and 4 material, b) a shock‐blackened (shock stage S5) type 3 lithology (lithology A), and c) a shock‐blackened type 3/4 lithology (lithology B). Buck Mountain Wash was lithified after impact‐mixing and impact‐melting of weakly and strongly metamorphosed materials, possibly at depth in the regolith of the parent body. Shock effects included brecciation on a fine scale, localized impact‐melting of silicates, partial melting, and mobilization of metal‐sulfide, and chemical fractionations that produced non‐H‐group composition kamacite by two disequilibrium mechanisms. Shock heating did not cause significant thermal metamorphism in the shock‐blackened lithologies of BMW, except possibly in areas adjacent to whole‐rock shock melt. During lithification, cooling must have been rapid at high temperatures to preserve glass and inhomogeneous silicate compositions, but not so fast at lower temperatures as to produce dendritic metal‐sulfide globules or martensite.     

Shape,metal abundance,chemistry, and origin of chondrules in the Renazzo (CR) chondrite

Abstract— We used synchrotron X‐ray microtomography to image in 3‐dimensions (3D) eight whole chondrules in a ?1 cm³piece of the Renazzo (CR) chondrite at ?17 μm per volume element (voxel) edge. We report the first volumetric (3D) measurement of metal/silicate ratios in chondrules and quantify indices of chondrule sphericity. Volumetric metal abundances in whole chondrules range from 1 to 37 volume % in 8 measured chondrules and by inspection in tomography data. We show that metal abundances and metal grain locations in individual chondrules cannot be reliably obtained from single random 2D sections. Samples were physically cut to intersect representative chondrules multiple times and to verify 3D data. Detailed 2D chemical analysis combined with 3D data yield highly variable whole‐chondrule Mg/Si ratios with a supra‐chondritic mean value, yet the chemically diverse, independently formed chondrules are mutually complementary in preserving chondritic (solar) Fe/Si ratios in the aggregate CR chondrite. These results are consistent with localized chondrule formation and rapid accretion resulting in chondrule + matrix aggregates (meteorite parent bodies) that preserve the bulk chondritic composition of source regions.     

Chondrules in Antarctic micrometeorites

Abstract— Previous studies of unmelted micrometeorites (>50 μm) recovered from Antarctic ice have concluded that chondrules, which are a major component of chondritic meteorites, are extremely rare among micrometeorites. We report the discovery of eight micrometeorites containing chondritic igneous objects, which strongly suggests that at least a portion of coarse‐grained crystalline micrometeorites represent chondrule fragments. Six of the particles are identified as composite micrometeorites that contain chondritic igneous objects and fine‐grained matrix. These particles suggest that at least some coarse‐grained micrometeorites (cgMMs) may be derived from the same parent bodies as fine‐grained micrometeorites. The new evidence indicates that, contrary to previous suggestions, the parent bodies of micrometeorites broadly resemble the parent asteroids of chondrulebearing carbonaceous chondrites.     

Stardust glass: Indigenous and modified comet Wild 2 particles

Abstract— Does comet 81P/Wild 2 have indigenous glass? Glass is used here to include all types of amorphous materials that could be either indigenous or modified comet Wild 2 grains, and all amorphous phases in chondritic aggregate interplanetary dust particles (IDPs). The answer is that it probably does, but very little is known of their compositions to allow a definitive answer to be given. There is no evidence among the collected comet dust for interstellar glass with embedded metals and sulfides. There is, however, ample evidence for melting of the smallest, sub‐micrometer comet particles of nanometer‐scale grains similar to those in the matrix of chondritic aggregate IDPs, including pyrrhotite. Massive patches of Mg‐SiO, Al‐SiO, or Ca‐Si‐O glass are incorporated in the familiar, vesicular Si‐rich glass are melted Wild 2 silicates. Magnesiosilica glass has a deep metastable eutectic smectite‐dehydroxylate composition. It indicates that very high temperatures well above the liquidus temperatures of forsterite were achieved very rapidly and were followed but ultra‐rapid quenching. This predictable and systematic response is not limited to Mg‐silicates, and recognizing this phenomenon among massive glass will provide a means to complete the reconstruction of this comet's original minerals, as well as constrain the physiochemical environment created during aerogel melting and evaporation.     

A new variant of saponite‐rich micrometeorites recovered from recent Antarctic snowfall

Abstract– Eight saponite‐rich micrometeorites with very similar mineralogy were found from the recent surface snow in Antarctica. They might have come to Earth as a larger meteoroid and broke up into pieces on Earth, because they were recovered from the same layer and the same location of the snow. Synchrotron X‐ray diffraction (XRD) analysis indicates that saponite, Mg‐Fe carbonate, and pyrrhotite are major phases and serpentine, magnetite, and pentlandite are minor phases. Anhydrous silicates are entirely absent from all micrometeorites, suggesting that their parental object has undergone heavy aqueous alteration. Saponite/serpentine ratios are higher than in the Orgueil CI chondrite and are similar to the Tagish Lake carbonaceous chondrite. Transmission electron microscope (TEM) observation indicates that serpentine occupies core regions of fine‐grained saponite, pyrrhotite has a low‐Ni concentration, and Mg‐Fe carbonate shows unique concentric ring structures and has a mean molar Mg/(Mg + Fe) ratio of 0.7. Comparison of the mineralogy to hydrated chondrites and interplanetary dust particles (IDPs) suggests that the micrometeorites are most similar to the carbonate‐poor lithology of the Tagish Lake carbonaceous chondrite and some hydrous IDPs, but they show a carbonate mineralogy dissimilar to any primitive chondritic materials. Therefore, they are a new variant of saponite‐rich micrometeorite extracted from a primitive hydrous asteroid and recently accreted to Antarctica.     

Evidence for the insignificance of ordinary chondritic material in the asteroid belt

Abstract— We review the meteoritical and astronomical literature to answer the question: What is the evidence for the importance of ordinary chondritic material to the composition of the asteroid belt? From the meteoritical literature, we find that currently (1) our meteorite collections sample at least 135 different asteroids; (2) out of 25+ chondritic meteorite parent bodies, 3 are (by definition) ordinary chondritic; (3) out of 14 chondritic grouplets and unique chondrites, 11 are affiliated with a carbonaceous group/clan of chondrites; (4) out of 24 differentiated groups of meteorites, only the HE iron meteorites clearly formed from ordinary chondritic precursor material; (5) out of 12 differentiated grouplets and unique differentiated meteorites, 8 seem to have had carbonaceous chondritic precursors; (6) a high frequency of carbonaceous clasts in ordinary chondritic breccias suggests that ordinary chondrites have been embedded in a swarm of carbonaceous material. The rare occurrence (only one example) of ordinary chondritic clasts in carbonaceous chondritic breccias indicates that ordinary chondritic material has not been widespread in the asteroid belt; (7) cosmic spherules, micrometeorites, and stratospheric interplanetary dust particles—believed to represent a less biased sampling of asteroidal material—show that only a very small fraction (less than ～1%) of asteroidal dust has an ordinary chondritic composition. From the astronomical literature, we find that currently (8) spectroscopic surveys of the main asteroid belt are finding more and more nonordinary chondritic primitive material in the inner main belt; (9) the increase in spectroscopic data has increased the inferred mineralogical diversity of main belt asteroids; and (10) no ordinary chondritic asteroids have been directly observed in the main belt. These lines of evidence strongly suggest a scenario in which ordinary chondritic asteroids were never abundant in the main belt. The S-type asteroids may currently be primarily differentiated, but the precursor material is more likely to have been carbonaceous chondritic, not ordinary chondritic. Historically, carbonaceous material could have dominated the entire main belt. This could explain the presence in the inner main belt of asteroids linked to the primitive carbonaceous chondrites, and the absence of asteroids linked to the ordinary chondrites. The implications of this scenario for the asteroid heating mechanism(s) are briefly discussed.     

Niobium and tantalum in carbonaceous chondrites: Constraints on the solar system and primitive mantle niobium/tantalum,zirconium/niobium,and niobium/uranium ratio

Abstract— We have determined Nb, Y, and Zr abundances in the carbonaceous chondrites Orgueil (CI), Murray (CM2), Murchison (CM2), Allende (CV3), and Karoonda (CK4), and in the eucrites, Pasamonte and Juvinas, by a recently developed spark source mass spectrometric technique using multiple ion counting (MIC‐SSMS). The abundance of Ta was determined in the same meteorites by radiochemical neutron activation analysis (RNAA). Precision of the MIC‐SSMS and RNAA techniques is ～3% and ≤ 5%, respectively. The new abundances for CI chondrites are: Nb = 0.247, Ta = 0.0142, Zr = 3.86, Y = 1.56 μg/g; or 0.699, 0.0202, 11.2, and 4.64 atoms/10⁶ Si atoms, respectively. The values agree with earlier compilations, but they are a factor of 2 more precise than earlier analyses. Trace element concentrations in the CM, CV, and CK chondrites are higher than in the CI chondrite Orgueil by about 37, 86, and 120%, respectively, in agreement with the variable absolute contents of refractory lithophile elements in different groups of carbonaceous chondrites. Of particular interest are the chondritic Nb/Ta, Zr/Nb, and Nb/U ratios, because these ratios are important tools for interpreting the chemical evolution of planetary bodies. We obtained Nb/Ta = 17.4 ± 0.5 for the carbonaceous chondrites and the Juvinas‐type eucrites investigated. Though this value is similar to previous estimates, it is much more precise. The same is true for Zr/Nb (15.5 ± 0.2) and Zr/Y (2.32 ± 0.12). In combination with recently published MIC‐SSMS U data for carbonaceous chondrites, we obtained a chondritic Nb/U ratio of 29 ± 2. Because Nb, Ta, Zr, Y, and U are refractory lithophile elements and presumably partitioned into the silicate phase of the Earth during core formation, the elemental ratios may also be used to constrain evolution of the Earth's primitive mantle and, with the more precise determinations fractionation of Nb and Ta during magmatic processes and mantle‐crust interactions, can now be interpreted with greater confidence.     

Fluids on differentiated asteroids: Evidence from phosphates in differentiated meteorites GRA 06128 and GRA 06129

Abstract– Paired meteorites Graves Nunatak 06128 and 06129 (GRA) represent an ancient cumulate lithology (4565.9 Ma ± 0.3) containing high abundances of sodic plagioclase. Textures and stable isotope compositions of GRA indicate that superimposed on the igneous lithology is a complex history of subsolidus reequilibration and low‐temperature alteration that may have extended over a period of 150 Myr. In GRA, apatite is halogen‐rich with Cl between 4.5 and 5.5 wt% and F between 0.3 and 0.9 wt%. The Cl/(Cl+F+OH) ratio of the apatite is between 0.65 and 0.82. The Cl and F are negatively correlated and are heterogeneously distributed in the apatite. Merrillite is low in halogens with substantial Na in the 6‐fold coordinated Na‐site (≈2.5%) and Mg in the smaller octahedral site. The merrillite has a negative Eu anomaly, whereas the apatite has a positive Eu anomaly. The chlorine isotope composition of the bulk GRA leachate is +1.2‰ relative to standard mean ocean chloride (SMOC). Ion microprobe chlorine isotope analyses of the apatite range between ?0.5 and +1.2‰. Textural relationships between the merrillite and apatite, and the high‐Cl content of the apatite, suggest that the merrillite is magmatic in origin, whereas the apatite is a product of the interaction between merrillite and a Cl‐rich fluid. If the replacement of merrillite by apatite occurred at approximately 800 °C, the fluid composition is f(HCl)/f(H₂O) = 0.0383 and a HCl molality of 2.13 and f(HCl)/f(HF) = 50–100. It is anticipated that the calculated f(HCl)/f(H₂O) and a HCl molality are minimum values due to assumptions made on the OH component in apatite and basing the calculations on the apatite with the lowest X_Cl. The bulk δ³⁷Cl of GRA is a >2σ outlier from chondritic meteorites and suggests that parent body processes resulted in fractionation of the Cl isotopes.     

Characterization of the lithological contact in the shergottite EETA79001—A record of igneous differentiation processes on Mars

Abstract— Elephant Moraine (EET) A79001 is the only Martian meteorite that consists of both an olivine‐phyric shergottite (lithology A) and a basaltic shergottite (lithology B). The presence of these lithologies in one rock has previously been ascribed to mixing processes (either magmatic or impact‐induced). Here we present data regarding phase changes across the contact between the lithologies. These data show that the contact is gradational and suggest that it is a primary igneous feature consistent with crystallization of a single cooling magma. We present a model to establish a petrogenetic connection between an olivine‐phyric and a basaltic shergottite through differentiation. The model involves the shallow or surface emplacement of a magma that contained pre‐eruptive solids (phenocrysts and minor xenocrysts). Subsequent differentiation via crystal settling and in situ crystallization (Langmuir 1989) resulted in a layered sequence of lithology A overlain by lithology B, with gradations in modal abundance of maskelynite (increasing from A to B) and pigeonite/maskelynite (decreasing from A to B), and a gradational change in pattern of pyroxene zonation (zones of magnesian augite separating magnesian and ferroan pigeonite appear and thicken into B) across the contact. A pigeonite phenocryst‐bearing zone near the contact in lithology B appears to be intermediate between lithology A and the bulk of lithology B (which resembles basaltic shergottite Queen Alexandra Range [QUE] 94201). Re‐examination of Sr isotopic compositions in lithology A and across the contact is required to test and constrain the model.     

Eutectic metal + troilite + Fe‐Mn‐Na phosphate + Al‐free chromite assemblage in shock‐produced chondritic melt of the Yanzhuang chondrite

An assemblage with FeNi metal, troilite, Fe‐Mn‐Na phosphate, and Al‐free chromite was identified in the metal‐troilite eutectic nodules in the shock‐produced chondritic melt of the Yanzhuang H6 meteorite. Electron microprobe and Raman spectroscopic analyses show that a few phosphate globules have the composition of Na‐bearing graftonite (Fe_,Mn,Na)₃(PO₄)₂, whereas most others correspond to Mn‐bearing galileiite Na(Fe,Mn)₄(PO₄)₃ and a possible new phosphate phase of Na₂(Fe,Mn)₁₇(PO₄)₁₂ composition. The Yanzhuang meteorite was shocked to a peak pressure of 50 GPa and a peak temperature of approximately 2000 °C. All minerals were melted after pressure release to form a chondritic melt due to very high postshock heat that brought the chondrite material above its liquidus. The volatile elements P and Na released from whitlockite and plagioclase along with elements Cr and Mn released from chromite are concentrated into the shock‐produced Fe‐Ni‐S‐O melt at high temperatures. During cooling, microcrystalline olivine and pyroxene first crystallized from the chondritic melt, metal‐troilite eutectic intergrowths, and silicate melt glass finally solidified at about 950–1000 °C. On the other hand, P, Mn, and Na in the Fe‐Ni‐S‐O melt combined with Fe and crystallized as Fe‐Mn‐Na phosphates within troilite, while Cr combined with Fe and crystallized as Al‐free chromite also within troilite.     

Ultrarapid chondrite formation by hot chondrule accretion? Evidence from unequilibrated ordinary chondrites

Abstract– Unequilibrated ordinary chondrites (UOCs) of all groups (H, L, LL) contain unique chondrite clasts, which are characterized by a close‐fit texture of deformed and indented chondrules. These clasts, termed “cluster chondrites,” occur in 41% of the investigated samples with modal abundances between 5 and 90 vol% and size variations between <1 mm and 10 cm. They show the highest chondrule abundances compared with all chondrite classes (82–92 vol%) and only low amounts of fine‐grained interchondrule matrix and rims (3–9 vol%). The mean degree of chondrule deformation varies between 11% and 17%, compared to 5% in the clastic portions of their host breccias and to values of 3–5% found in UOC literature, respectively. The maximum deformation of individual chondrules is about 50%, a value which seemingly cannot be exceeded due to geometric limitations. Both viscous and brittle chondrule deformation is observed. A model for cluster chondrite formation is proposed where hot and deformable chondrules together with only small amounts of co‐accreting matrix formed a planetesimal or reached the surface of an already existing body within hours to a few days after chondrule formation. They deformed in a hot stage, possibly due to collisional compression by accreting material. Later, the resulting rocks were brecciated by impact processes. Thus, cluster chondrite clasts are interpreted as relicts of primary accretionary rocks of unknown original dimensions. If correct, this places a severe constraint on chondrule‐forming conditions. Cluster chondrites would document local chondrule formation, where chondrule‐forming heating events and the accretion of chondritic bodies were closely linked in time and space.     

Mineralogy of Tagish Lake: An ungrouped type 2 carbonaceous chondrite

Abstract— In this paper we describe the recovery, handling and preliminary mineralogical investigation of the Tagish Lake meteorite. Tagish Lake is a type 2 carbonaceous chondrite which bears similarities to CI1 and CM chondrite groups, but is distinct from both. Abundant phyllosilicates as well as chondrules (however sparse) and common olivine grains in the matrix preclude any other classification. The bulk density of Tagish Lake (1.67 g/cc) is far lower than CI or CM chondrites (2.2‐2.3 and 2.6‐2.9 g/cc, respectively), or any other meteorite for that matter. We have identified two lithologies: a dominant carbonate‐poor lithology and a less‐abundant carbonate‐rich lithology. The meteorite is a breccia at all scales. We have noted similarities between Tagish Lake and some clasts within the enigmatic meteorite Kaidun; possibly there are genetic relationships here worth exploring. In the paper we describe a clast of CM1 material within Tagish Lake which is very similar to a major lithology in Kaidun.     

A petrologic study of the IAB iron meteorites: Constraints on the formation of the IAB‐Winonaite parent body

Abstract— We studied 26 IAB iron meteorites containing silicate‐bearing inclusions to better constrain the many diverse hypotheses for the formation of this complex group. These meteorites contain inclusions that fall broadly into five types: (1) sulfide‐rich, composed primarily of troilite and containing abundant embedded silicates; (2) nonchondritic, silicate‐rich, comprised of basaltic, troctolitic, and peridotitic mineralogies; (3) angular, chondritic silicate‐rich, the most common type, with approximately chondritic mineralogy and most closely resembling the winonaites in composition and texture; (4) rounded, often graphite‐rich assemblages that sometimes contain silicates; and (5) phosphate‐bearing inclusions with phosphates generally found in contact with the metallic host. Similarities in mineralogy and mineral and O‐isotopic compositions suggest that IAB iron and winonaite meteorites are from the same parent body. We propose a hypothesis for the origin of IAB iron meteorites that combines some aspects of previous formation models for these meteorites. We suggest that the precursor parent body was chondritic, although unlike any known chondrite group. Metamorphism, partial melting, and incomplete differentiation (i.e., incomplete separation of melt from residue) produced metallic, sulfide‐rich and silicate partial melts (portions of which may have crystallized prior to the mixing event), as well as metamorphosed chondritic materials and residues. Catastrophic impact breakup and reassembly of the debris while near the peak temperature mixed materials from various depths into the re‐accreted parent body. Thus, molten metal from depth was mixed with near‐surface silicate rock, resulting in the formation of silicate‐rich IAB iron and winonaite meteorites. Results of smoothed particle hydrodynamic model calculations support the feasibility of such a mixing mechanism. Not all of the metal melt bodies were mixed with silicate materials during this impact and reaccretion event, and these are now represented by silicate‐free IAB iron meteorites. Ages of silicate inclusions and winonaites of 4.40‐4.54 Ga indicate this entire process occurred early in solar system history.     

Sampling interplanetary dust from Antarctic air

We built a collector to filter interplanetary dust particles (IDPs) larger than 5 μm from the clean air at the Amundsen Scott South Pole station. Our sampling strategy used long duration, continuous dry filtering of near‐surface air in place of short duration, high‐speed impact collection on flags flown in the stratosphere. We filtered ~10⁷ m³ of clean Antarctic air through 20 cm diameter, 3 µm filters coupled to a suction blower of modest power consumption (5–6 kW). Our collector ran continuously for 2 years and yielded 41 filters for analyses. Based on stratospheric concentrations, we predicted that each month’s collection would provide 300–900 IDPs for analysis. We identified 19 extraterrestrial (ET) particles on the 66 cm² of filter examined, which represented ~0.5% of the exposed filter surfaces. The 11 ET particles larger than 5 µm yield about a fifth of the expected flux based on >5 µm stratospheric ET particle flux. Of the 19 ET particles identified, four were chondritic porous IDPs, seven were FeNiS beads, two were FeNi grains, and six were chondritic material with FeNiS components. Most were <10 µm in diameter and none were cluster particles. Additionally, a carbon‐rich candidate particle was found to have a small ¹⁵N isotopic enrichment, supporting an ET origin. Many other candidate grains, including chondritic glasses and C‐rich particles with Mg and Si and FeS grains, require further analysis to determine if they are ET. The vast majority of exposed filter surfaces remain to be examined.     

Petrology and mineralogy of the Ningqiang carbonaceous chondrite

Abstract— We report detailed chemical, petrological, and mineralogical studies on the Ningqiang carbonaceous chondrite. Ningqiang is a unique ungrouped type 3 carbonaceous chondrite. Its bulk composition is similar to that of CV and CK chondrites, but refractory lithophile elements (1.01 × CI) are distinctly depleted relative to CV (1.29 × CI) and CK (1.20 × CI) chondrites. Ningqiang consists of 47.5 vol% chondrules, 2.0 vol% Ca,Al‐rich inclusions (CAIs), 4.5 vol% amoeboid olivine aggregates (AOAs), and 46.0 vol% matrix. Most chondrules (95%) in Ningqiang are Mg‐rich. The abundances of Fe‐rich and Al‐rich chondrules are very low. Al‐rich chondrules (ARCs) in Ningqiang are composed mainly of olivine, plagioclase, spinel, and pyroxenes. In ARCs, spinel and plagioclase are enriched in moderately volatile elements (Cr, Mn, and Na), and low‐Ca pyroxenes are enriched in refractory elements (Al and Ti). The petrology and mineralogy of ARCs in Ningqiang indicate that they were formed from hybrid precursors of ferromagnesian chondrules mixed with refractory materials during chondrule formation processes. We found 294 CAIs (55.0% type A, 39.5% spinel‐pyroxene‐rich, 4.4% hibonite‐rich, and several type C and anorthite‐spinel‐rich inclusions) and 73 AOAs in 15 Ningqiang sections (equivalent to 20 cm²surface area). This is the first report of hibonite‐rich inclusions in Ningqiang. They are texturally similar to those in CM, CH, and CB chondrites, and exhibit three textural forms: aggregates of euhedral hibonite single crystals, fine‐grained aggregates of subhedral hibonite with minor spinel, and hibonite ± Al,Ti‐diopside ± spinel spherules. Evidence of secondary alteration is ubiquitous in Ningqiang. Opaque assemblages, formed by secondary alteration of pre‐existing alloys on the parent body, are widespread in chondrules and matrix. On the other hand, nepheline and sodalite, existing in all chondritic components, formed by alkali‐halogen metasomatism in the solar nebula.     

The first samples from Almahata Sitta showing contacts between ureilitic and chondritic lithologies: Implications for the structure and composition of asteroid 2008 TC3

Almahata Sitta (AhS), an anomalous polymict ureilite, is the first meteorite observed to originate from a spectrally classified asteroid (2008 TC₃). However, correlating properties of the meteorite with those of the asteroid is not straightforward because the AhS stones are diverse types. Of those studied prior to this work, 70–80% are ureilites (achondrites) and 20–30% are various types of chondrites. Asteroid 2008 TC₃ was a heterogeneous breccia that disintegrated in the atmosphere, with its clasts landing on Earth as individual stones and most of its mass lost. We describe AhS 91A and AhS 671, which are the first AhS stones to show contacts between ureilitic and chondritic materials and provide direct information about the structure and composition of asteroid 2008 TC₃. AhS 91A and AhS 671 are friable breccias, consisting of a C1 lithology that encloses rounded to angular clasts (<10 μm to 3 mm) of olivine, pyroxenes, plagioclase, graphite, and metal‐sulfide, as well as chondrules (~130–600 μm) and chondrule fragments. The C1 material consists of fine‐grained phyllosilicates (serpentine and saponite) and amorphous material, magnetite, breunnerite, dolomite, fayalitic olivine (Fo 28‐42), an unidentified Ca‐rich silicate phase, Fe,Ni sulfides, and minor Ca‐phosphate and ilmenite. It has similarities to CI1 but shows evidence of heterogeneous thermal metamorphism. Its bulk oxygen isotope composition (δ¹⁸O = 13.53‰, δ¹⁷O = 8.93‰) is unlike that of any known chondrite, but similar to compositions of several CC‐like clasts in typical polymict ureilites. Its Cr isotope composition is unlike that of any known meteorite. The enclosed clasts and chondrules do not belong to the C1 lithology. The olivine (Fo 75‐88), pyroxenes (pigeonite of Wo ~10 and orthopyroxene of Wo ~4.6), plagioclase, graphite, and some metal‐sulfide are ureilitic, based on mineral compositions, textures, and oxygen isotope compositions, and represent at least six distinct ureilitic lithologies. The chondrules are probably derived from type 3 OC and/or CC, based on mineral and oxygen isotope compositions. Some of the metal‐sulfide clasts are derived from EC. AhS 91A and AhS 671 are plausible representatives of the bulk of the asteroid that was lost. Reflectance spectra of AhS 91A are dark (reflectance ~0.04–0.05) and relatively featureless in VNIR, and have an ~2.7 μm absorption band due to OH^? in phyllosilicates. Spectral modeling, using mixtures of laboratory VNIR reflectance spectra of AhS stones to fit the F‐type spectrum of the asteroid, suggests that 2008 TC₃ consisted mainly of ureilitic and AhS 91A‐like materials, with as much as 40–70% of the latter, and <10% of OC, EC, and other meteorite types. The bulk density of AhS 91A (2.35 ± 0.05 g cm^?3) is lower than bulk densities of other AhS stones, and closer to estimates for the asteroid (~1.7–2.2 g cm^?3). Its porosity (36%) is near the low end of estimates for the asteroid (33–50%), suggesting significant macroporosity. The textures of AhS 91A and AhS 671 (finely comminuted clasts of disparate materials intimately mixed) support formation of 2008 TC₃ in a regolith environment. AhS 91A and AhS 671 could represent a volume of regolith formed when a CC‐like body impacted into already well‐gardened ureilitic + impactor‐derived debris. AhS 91A bulk samples do not show a solar wind component, so they represent subsurface layers. AhS 91A has a lower cosmic ray exposure (CRE) age (~5–9 Ma) than previously studied AhS stones (11–22 Ma). The spread in CRE ages argues for irradiation in a regolith environment. AhS 91A and AhS 671 show that ureilitic asteroids could have detectable ~2.7 μm absorption bands.     

The fall,recovery, and classification of the Park Forest meteorite

Abstract— On the night of March 26, 2003, a large meteorite broke up and fell upon the south suburbs of Chicago. The name Park Forest, for the village that is at the center of the strewnfield, has been approved by the nomenclature committee of the Meteoritical Society. Satellite data indicate that the bolide traveled from the southwest toward the northeast. The strewnfield has a southeast‐northwest trend; however, this is probably due to the effects of strong westerly winds at high altitudes. Its very low ⁵⁶Co and very high ⁶⁰Co activities indicate that Park Forest had a preatmospheric mass that was at least ～900 kg and could have been as large as ～7 times 10³ kg, of which only ～30 kg have been recovered. The average compositions of olivine and low‐Ca pyroxene, Fa_{24.7 ± 1.1} and Fs_{20.8 ± 0.7}, respectively, and its bulk oxygen isotopic composition, δ¹⁸O = +4.68%o, δ¹⁷O = +3.44%o, show that Park Forest is an L chondrite. The ferromagnesian minerals are well equilibrated, chondrules are easily recognized, and maskelynite is mostly ≤50 μm across. Based on these observations, we classify Park Forest as type 5. The meteorite has been strongly shocked, and based on the presence of maskelynite, mosaicism and planar deformation features in olivine, undulatory extinction in pyroxene, and glassy veins, the shock stage is S5. The meteorite is a monomict breccia, consisting of light‐colored, angular to rounded clasts in a very dark host. The light and dark lithologies have essentially identical mineral and oxygen isotopic compositions. Their striking difference in appearance is due to the presence of a fine, pervasive network of sulfide veins in the dark lithology, resulting in very short optical path lengths. The dark lithology probably formed from the light lithology in an impact that formed a sulfide‐rich melt and injected it into cracks.     

Origin of a late Eocene to pre‐Miocene buried crater and breccia lens at Fohn‐1, North Bonaparte Basin,Timor Sea: A probable extraterrestrial connection

Abstract— Seismic reflection data and an at least 350 m thick, PGE‐rich carbonate breccia lens intersected by the Fohn‐1 exploration well in the Timor Sea off northern Australia, are interpreted in terms of a buried 4.8 km‐diameter impact crater of late Eocene to pre‐Miocene age. The crater displays the classic elements of impact structures, including a central uplift, ring syncline, and upraised rims. The presence in the breccia of redeposited Campanian and Maastrichtian microfossils suggests rebound of strata from levels deeper than 1250 m below the pre‐Miocene unconformity. Morphometric modelling suggests an original crater at least 1400 m deep, which is consistent with the excavation of Cretaceous strata. Stratigraphic and palaeontological evidence suggests that the impact occurred between 36 and 24.6 Ma. The breccia contains a pseudotachylite component enriched in the inert Pt group elements (PGE) (Ir, Ru) by factors of 5–12 above the values of common sediments. The more mobile PGE (Os, Pt, Pd) show a wide scatter and terrestrial‐type values. Opposite geochemical/stratigraphic trends pertain to different PGE species—the relatively inert Ir‐Ru group shows an overall concentration at the base of the section, whereas the more mobile Os shows peaks at median levels of the section—suggesting upward diagenetic leaching. The near‐chondritic PGE patterns at the base of the breccia pile are accompanied by near‐chondritic Ni/Cr, Co/Cr, Ni/Ir, Ni/Pt, and Cu/Pd ratios. Departure from these values related to alteration at higher levels in the breccia pile is accompanied with high S levels (～1%).     

THE WILLOWBAR METEORITE*

The Willowbar, Oklahoma meteorite was found by Kendall Rhoton in December, 1971, lat 36° 44′ N.; long 102° 12′ W. It is a shocked brecciated L6 chondrite (Fa-24.3) with large black veins cutting areas of normal chondritic texture. It weighed 2.07 kg.