Synthesis of a spinifex‐textured basalt as an analog to Gusev crater basalts,Mars

Abstract– Analyses by the Mars Exploration Rover (MER), Spirit, of Martian basalts from Gusev crater show that they are chemically very different from terrestrial basalts, being characterized in particular by high Mg‐ and Fe‐contents. To provide suitable analog basalts for the International Space Analogue Rockstore (ISAR), a collection of analog rocks and minerals for preparing in situ space missions, especially, the upcoming Mars mission MSL‐2011 and the future international Mars‐2018 mission, it is necessary to synthesize Martian basalts. The aim of this study was therefore to synthesize Martian basalt analogs to the Gusev crater basalts, based on the geochemical data from the MER rover Spirit. We present the results of two experiments, one producing a quench‐cooled basalt (<1 h) and one producing a more slowly cooled basalt (1 day). Pyroxene and olivine textures produced in the more slowly cooled basalt were surprisingly similar to spinifex textures in komatiites, a volcanic rock type very common on the early Earth. These kinds of ultramafic rocks and their associated alteration products may have important astrobiological implications when associated with aqueous environments. Such rocks could provide habitats for chemolithotrophic microorganisms, while the glass and phyllosilicate derivatives can fix organic compounds.     

Phase equilibrium investigations of the Adirondack class basalts from the Gusev plains,Gusev crater,Mars

Abstract— Phase equilibrium experiments have been performed on a synthetic analog of the Gusev plains basalt composition from the Spirit landing site on Mars. Near‐liquidus phase relations were determined over the pressure range of 0.1 to 1.5 GPa and at temperatures from 1125 to 1390 °C in a piston cylinder apparatus and 1 atm gas mixing furnace. The composition is multiply saturated with olivine, orthopyroxene, and spinel near its liquidus at 1320 °C and 1.0 GPa, or 85 km depth on Mars, placing an upper limit constraint on the thickness of the Martian lithosphere at the time of eruption. Our experimental work suggests that the Gusev basalts are anhydrous batch melts of a primitive Martian mantle similar to the composition estimated by Dreibus and Wänke (1984). The temperature of multiple saturation indicates the persistence of high mantle potential temperatures on Mars, similar to those on the modern Earth, until at least the very latest Noachian (3.7 Ga). These high mantle temperatures would be responsible for persistent basaltic volcanism throughout the southern highlands during the first billion years of Mars's history. The source for Gusev basalts differs strongly from the source for shergottite meteorites, reinforcing the idea of the absence of global mantle convection and mixing on Mars. The existence of a relatively primitive mantle reservoir requires that at least part of the mantle underwent little modification during early planetary differentiation.     

Chemical compositions of martian basalts (shergottites): Some inferences on b; formation,mantle metasomatism,and differentiation in Mars

Abstract— Bulk chemical compositions of the shergottite basalts provide important constraints on magma genesis and mantle processes in Mars. Abundances of many major and trace elements in the shergottites covary in 2 distinct groups: Group 1 (Gl) includes mostly highly incompatible elements (e.g., La, Th), and Group 2 (G2) includes mostly moderately incompatible elements (e.g., Ti, Lu, Al, Hf). Covariations of G2 elements (not necessarily linear) are consistent with partitioning between basalt magma and orthopyroxene + olivine. This fractionation represents partial melting to form the shergottites and their crystallization; the restite minerals cannot include aluminous phase(s), phosphate, ilmenite, zircon, or sulfides. Overall, abundances of Gl elements are decoupled from those of G2. In graphing abundances of a Gl element against those of a G2 element, G1/G2 abundance ratios do not appear to be random but are restricted to 4 values. Shergottites with a given G1/G2 value need not have the same crystallization age and need not fall on a single fractionation trajectory involving compatible elements (e.g., Ti versus Fe*). These observations imply that the G1/G2 families were established before basalt formation and suggest metasomatic enrichment of their source region (major carrier of G2 elements) by a component rich in Gl elements. Group 1 elements were efficiently separated from G2 elements very early in Mars' history. Such efficient fractionation is not consistent with simple petrogenesis; it requires multiple fractionations, “complex” petrogenetic processes, or minerals with unusual geochemistry. The behavior of phosphorus in this early fractionation event is inexplicable by normal petrogenetic processes and minerals. Several explanations are possible, including significant compatibility of P in majoritic garnet and the presence of P‐bearing iron metal (or a phosphide phase) in the residual solid assemblage (carrier of G2 elements). If the latter, Mars' mantle is more oxidized now than during the ancient fractionation event.     

Geochemistry of intermediate olivine‐phyric shergottite Northwest Africa 6234, with similarities to basaltic shergottite Northwest Africa 480 and olivine‐phyric shergottite Northwest Africa 2990

Abstract— The newly found meteorite Northwest Africa 6234 (NWA 6234) is an olivine (ol)‐phyric shergottite that is thought, based on texture and mineralogy, to be paired with Martian shergottite meteorites NWA 2990, 5960, and 6710. We report bulk‐rock major‐ and trace‐element abundances (including Li), abundances of highly siderophile elements, Re‐Os isotope systematics, oxygen isotope ratios, and the lithium isotope ratio for NWA 6234. NWA 6234 is classified as a Martian shergottite, based on its oxygen isotope ratios, bulk composition, and bulk element abundance ratios, Fe/Mn, Al/Ti, and Na/Al. The Li concentration and δ⁷Li value of NWA 6234 are similar to that of basaltic shergottites Zagami and Shergotty. The rare earth element (REE) pattern for NWA 6234 shows a depletion in the light REE (La‐Nd) compared with the heavy REE (Sm‐Lu), but not as extreme as the known “depleted” shergottites. Thus, NWA 6234 is suggested to belong to a new category of shergottite that is geochemically “intermediate” in incompatible elements. The only other basaltic or ol‐phyric shergottite with a similar “intermediate” character is the basaltic shergottite NWA 480. Rhenium‐osmium isotope systematics are consistent with this intermediate character, assuming a crystallization age of 180 Ma. We conclude that NWA 6234 represents an intermediate compositional group between enriched and depleted shergottites and offers new insights into the nature of mantle differentiation and mixing among mantle reservoirs in Mars.     

New observations of Warrego Valles, Mars: Evidence for precipitation and surface runoff

Most valley networks have been identified primarily in the heavily cratered uplands which are Noachian in age (>3.5 Gyr). A striking exception to this general observation is Warrego Valles located on the southeastern part of the Tharsis bulge. Recent data obtained by the Mars Orbiter Laser Altimeter, the Thermal Emission Imaging System (THEMIS) spectrometer and the Mars Orbiter Camera give new insight into the formation of valley networks and the early Mars climate. We focus our study on the southern Thaumasia region especially on Warrego Valles and determine the organisation of valleys in relation to regional topography and structural geology. Warrego Valles is the most mature valley network that incised the southern side of Thaumasia highlands. It developed in a rectangular-shaped, concave-up drainage basin. Four times more valleys are identified in THEMIS infrared images than in Viking images. Valleys exist on both sides of the main tributary contrary to what was visible in Viking images. Their distribution is highly controlled by topographic slope, e.g. there is a parallel pattern on the sides and dendritic pattern on the central part of Warrego Valles. We quantitatively analyse valley morphology and morphometry to determine the processes responsible for valley network formation. Warrego Valles displays morphometric properties similar to those of a terrestrial fluvial valley network. This valley network is characterised by seven Strahler's orders, a bifurcation ratio of 3, a length ratio of 1.7, a drainage density of 0.53 km⁻¹ and a ruggedness number of 3.3. The hypsometric curve and integral (0.46) indicate that Warrego Valles reached the mature Davis’ stage. Valleys have undergone external degradation since their incision, which masks their main morphological characteristics. Our study supports the assertion that valley networks formed by fluvial processes controlled by an atmospheric water cycle. Further, they seem to develop by successive stages of erosion that occurred during Noachian through the late Hesperian.     

Polygonal terrains on Mars: A contribution to their geometric and topological characterization

Detailed examination of large extensions of polygonal terrains on the surface of Mars and extraction of some characteristic geometric and topological parameters is made possible by the application of image analysis methods to scenes of the Martian surface acquired from orbit. This is illustrated by the analysis of a set of diverse Martian networks, clearly visible in MOC/MGS images with high spatial resolution. It is shown that these networks present, in average, a hexagonal habit, and that they verify two classic laws relative to 2D random networks (those of Lewis and Aboav-Weaire). This research can, through the quantified analysis of the differences and similarities between networks, lead into a much better understanding of the origin and dynamics of this type of features.     

Mineralogy and evolution of the surface of Mars: A review

We review the mineralogy of the surface of Mars, using data from various sources, including in situ characterisations performed by landers, remote observations from orbit, and studies of the SNC meteorites. We also discuss the possible alteration processes and the factor controlling them, and try to relate the mineralogical observations to the chemical evolution of the surface materials on Mars in order to identify the dominant process(es). Then we try to describe a possible chemical and mineralogical evolution of the surface materials, resulting from weathering driven by the abundance and activity of water. Even if weathering is the dominant process responsible for the surface evolution, all observations suggest that it is strongly affected locally in time and space by various other processes including hydrothermalism, volcanism, evaporites, meteoritic impacts and aeolian erosion. Nevertheless, the observed phases on the surface of Mars globally depend on the evolution of the weathering conditions. This hypothesis, if confirmed, could give a new view of the evolution of the martian surface, roughly in three steps. The first would correspond to clay-type weathering process in the Noachian, under a probable thick H₂O/CO₂-rich atmosphere. Then, during the Hesperian when water became scarcer and its activity sporadic, linked to volcanic activity, sulfate-type acidic weathering process would have been predominant. The third period would be like today, a very slow weathering by strongly oxidising agents (H₂O₂, O₂) in cold and dry conditions, through solid-gas or solid-films of water resulting frost-thaw and/or acid fog. This would favour poorly crystalline phases, mainly iron (oxy) hydroxides. But in this scenario many questions remain about the transition between these processes, and about the factors affecting the evolution of the weathering process.     

Erosive flood events on the surface of Mars: Application to Mangala and Athabasca Valles

We address key factors involved in determining water flow conditions in outflow channels on Mars, including the temperature of the sub-surface water being released and the environmental conditions of low temperature, low atmospheric pressure, and low acceleration due to gravity. We suggest how some of the assumptions made in previous work may be improved. Our model considers the thermodynamic effects of simultaneous evaporation and freezing of water, and fluid dynamical processes including changes in flow rheology caused by assimilation of cold rock and ice eroded at the channel bed, and ice crystal growth due to water freezing. We model how far initially turbulent water could flow in a channel before it erodes and entrains enough material to become laminar, and subsequently ceases to erode the bed. An ice raft will begin to form on the flood while transition occurs between turbulent and laminar flow. Estimates are given for water transit times, ～17–19 h, initial water depths, 50–62 m, and average flow speeds, 5–12 m s^?1, in the Mangala and Athabasca Valles. We show that these two outflow channels, and by implication others like them, could plausibly have been formed in single water release events. Resulting mean erosion rates are approximately 0.7 mm s^?1, a factor of three greater than previous estimates based on combinations of estimates of flood duration and required water volumes. This is explained by the consideration of the effects of eroded ice and the physics of thermal erosion in the present study.     

Spectral reflectance properties of minerals exposed to simulated Mars surface conditions

A number of mineral species were exposed to martian surface conditions of atmospheric pressure and composition, temperature, and UV light regime, and their evolution was monitored using reflectance spectroscopy. The stabilities for different groups varied widely. Phyllosilicate spectra all showed measurable losses of interlayer H₂O, with some structural groups showing more rapid H₂O loss than others. Loss of OH from the phyllosilicates is not always accompanied by a change in metal-OH overtone absorption bands. OH-bearing sulfates, such as jarosite and alunite, show no measurable change in spectral properties, suggesting that they should be spectrally detectable on Mars on the basis of diagnostic absorption bands in the 0.4-2.5 μm region. Fe³⁺- and H₂O-bearing sulfates all showed changes in the appearance and/or reduction in depths of hydroxo-bridged Fe³⁺ absorption bands, particularly at 0.43 μm. The spectral changes were often accompanied by visible color changes, suggesting that subsurface sulfates exposed to the martian surface environment may undergo measurable changes in reflectance spectra and color over short periods of time (days to weeks). Organic-bearing geological materials showed no measurable change in CH related absorption bands, while carbonates and hydroxides also showed no systematic changes in spectral properties. The addition of ultraviolet irradiation did not seem to affect mineral stability or rate of spectral change, with one exception (hexahydrite). In some cases, spectral changes could be related to the formation of specific new phases. The data also suggest that hydrated minerals detected on Mars to date retain their diagnostic spectral properties that allow their unique identification.     

Geomorphic knobs of Candor Chasma, Mars: New Mars Reconnaissance Orbiter data and comparisons to terrestrial analogs

High Resolution Imaging Science Experiment (HiRISE) imagery and digital elevation models of the Candor Chasma region of Valles Marineris, Mars, reveal prominent and distinctive positive-relief knobs amidst light-toned layers. Three classifications of knobs, Types 1, 2, and 3, are distinguished from a combination of HiRISE and Thermal Emission Imaging System (THEMIS) images based on physical expressions (geometries, spatial relationships), and spectral data from Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). Type 1 knobs are abundant, concentrated, topographically resistant features with their highest frequency in West Candor, which have consistent stratigraphic correlations of the peak altitude (height). These Type 1 knobs could be erosional remnants of a simple dissected terrain, possibly derived from a more continuous, resistant, capping layer of pre-existing material diagenetically altered through recrystallization or cementation. Types 2 and 3 knobs are not linked to a single stratigraphic layer and are generally solitary to isolated, with variable heights. Type 3 are the largest knobs at nearly an order of magnitude larger than Type 1 knobs. The variable sizes and occasional pits on the tops of Type 2 and 3 knobs suggest a different origin, possibly related to more developed erosion, preferential cementation, or textural differences from sediment/water injection or intrusion, or from a buried impact crater. Enhanced color HiRISE images show a brown coloration of the knob peak crests that is attributable to processing and photometric effects; CRISM data do not show any detectable spectral differences between the knobs and the host rock layers, other than albedo. These intriguing knobs hold important clues to deducing relative rock properties, timing of events, and weathering conditions of Mars history.     

On the smooth surface of the northern bow shock of Mars,based on Mars Global Surveyor's measurements

A very smooth and time-invariable bow shock of Mars is revealed using Mars Global Surveyor's data. The bow-shock position has been identified using magnetic and electron flux data obtained by the Magnetometer and Electron Reflectometer (MAG/ER) experiment aboard Mars Global Surveyor, in the time period between days 87 and 255 of 1998. From the magnetic field and the electron flux measurements, 148 bow-shock crossings were detected, concentrated mostly on the northern hemisphere of the planet. With these results, a 3D configuration of the bow shock is constructed and presented. The results show that part of the observed bow shock is a surprisingly smooth surface. It is possible that the bow shock is smooth only in the northern hemisphere, since the southern surface is characterized by local magnetic anomalies. Its real shape can only be revealed in a 3D representation in the planetary centered solar ecliptic coordinate system and questions the theoretically expected variation of the bow shock.     

Saltation threshold on Mars: The effect of interparticle force,surface roughness,and low atmospheric density

The effect of interparticle forces, as well as changes in surface roughness, particle diameter and density, and atmospheric density and viscosity are considered in new estimates of saltation thershold on Mars. These estimates result in somewhat lower minimum values of predicted threshold speed than by use of the “universal” A-B curve, with the minimum threshold speed occuring at smaller values of particle diameter. It is shown that the new predictions are much closer to the limited low atmospheric density data available than if the older method of estimation is used.     

Tidally induced surface displacements, external potential variations, and gravity variations on Mars

We have used and extended Roosbeek’s tidal potential for Mars to calculate tidal displacements, gravity variations, and external gravitational potential variations. The tides on Mars are caused by the Sun, and to a lesser degree by the natural satellites Phobos (8%, relative to the Sun) and Deimos (0.08%, relative to the Sun). To determine the reaction of Mars to the tidal forcing, the Love numbers h, l, and k and the gravimetric factor δ were calculated for interior models of Mars with different state, density, and radius of the core and for models which include mantle anelasticity. The latitude dependence and frequency dependence of the Love numbers have been taken explicitly into account. The Love numbers are about three times smaller than those for the Earth and are very sensitive to core changes; e.g., a difference of about 30% is found between a model with a liquid core and an otherwise similar model with a solid core. Tidal displacements on Mars are much smaller than on Earth due to the smaller tidal potential, but also due to the smaller reaction of Mars (smaller Love numbers). For both the tidal diplacement and the tidal external potential perturbations, the tidal signal is at the limit of detection and is too small to permit properties of Mars’s interior to be inferred. On the other hand, the Phobos tidally induced gravity changes, which are subdiurnal with typical periods shorter than 12 h, can be measured very precisely by the very broad band seismometer with thermal control of the seismological experiment SEIS of the upcoming NetLander mission. It is shown that the Phobos-induced gravity tides could be used to study the Martian core.     

Paleolakes, paleofloods, and depressions in Aurorae and Ophir Plana, Mars: Connectivity of surface and subsurface hydrological systems

The plains of Aurorae and Ophir in the equatorial region of Mars display geomorphic evidence indicative of extensive but generally short-lived paleohydrological processes. Elaver Vallis in Aurorae Planum south of Ganges Chasma is an outflow channel system >180 km long, and here inferred to have formed by cataclysmic spillover flooding from a paleolake(s) contained in the Morella crater basin. Ganges Cavus is an enormous 5-km-deep depression of probable collapse origin located in the Morella basin. The fluid responsible for the infilling of the Morella basin likely emerged at least partially through Ganges Cavus or its incipient depression, and it may have been supplied also from small-scale springs in the basin. Similar paleohydrological processes are inferred also in Ophir Planum. It is reasonable to assume that water, sometimes sediment-laden and/or mixed with gases, was the responsible fluid for these phenomena although some of the observed features could be explained by non-aqueous processes such as volcanism. Water emergence may have occurred as consequences of ground ice melting or breaching of cryosphere to release water from the underlying hydrosphere. Dike intrusion is considered to be an important cause of formation for the cavi and smaller depressions in Aurorae and Ophir Plana, explaining also melting of ground ice or breaching of cryosphere. Alternatively, the depressions and crater basins may have been filled by regional groundwater table rising during the period(s) when cryosphere was absent or considerably thin. The large quantities of water necessary for explaining the paleohydrological processes in Aurorae and Ophir Plana could have been derived through crustal migration from the crust of higher plains in western Ophir Planum where water existed in confined aquifers or was produced by melting of ground ice due to magmatic heating or climatic shift, or from a paleolake in Candor Chasma further west.     

Mass fractionation during transonic escape and implications for loss of water from Mars and Venus

Hydrodynamic escape of hydrogen from a planetary atmosphere can remove heavier gases as well as hydrogen, provided that the escape rate is sufficiently large. Here, analytic approximations for the degree of mass fractionation of a trace species during hydrodynamic escape are compared with accurate numerical solutions for the case of transonic outflow. Even the simplest analytic approximation is found to be surprisingly good, despite numerous assumptions made in the course of its derivation. The analytic approximations are most accurate when the ratio of molecular weights of the heavier and lighter constituents is large so that nonlinear terms in the momentum equation for the heavy constituent become small. The simplest analytic formula is readily generalized to the case where a heavy constituent is also a major species. Application of the generalized formula to hypothetical episodes of hydrodynamic escape from Venus and Mars suggests that both hydrogen and oxygen could have escaped; thus, substantial quantities of water may have been lost without the need to oxidize large amounts of the crust. Mars could have lost large amounts of rare gases in this manner, but if so it may also have lost significant quantities of carbon dioxide and nitrogen. Venusian argon and neon isotope ratios indicate that Venus lost little or no argon and 50% or less of its original complement of neon. Terrestrial noble gas patterns resemble those that would have resulted had an initially Venus-like Earth undergone a short-lived but locally very energetic escape event.     

Apparent thermal inertia and the surface heterogeneity of Mars

Thermal inertia derivation techniques generally assume that surface properties are uniform at horizontal scales below the footprint of the observing instrument and to depths of several decimeters. Consequently, surfaces with horizontal or vertical heterogeneity may yield apparent thermal inertia which varies with time of day and season. To investigate these temporal variations, we processed three Mars years of Mars Global Surveyor Thermal Emission Spectrometer observations and produced global nightside and dayside seasonal maps of apparent thermal inertia. These maps show broad regions with diurnal and seasonal differences up to 200 J m⁻² K⁻¹s^−1/2 at mid-latitudes (60° S to 60° N) and 600 J m⁻² K⁻¹s^−1/2 or greater in the polar regions. We compared the seasonal mapping results with modeled apparent thermal inertia and created new maps of surface heterogeneity at 5° resolution, delineating regions that have thermal characteristics consistent with horizontal mixtures or layers of two materials. The thermal behavior of most regions on Mars appears to be dominated by layering, with upper layers of higher thermal inertia (e.g., duricrusts or desert pavements over fines) prevailing in mid-latitudes and upper layers of lower thermal inertia (e.g., dust-covered rock, soils with an ice table at shallow depths) prevailing in polar regions. Less common are regions dominated by horizontal mixtures, such as those containing differing proportions of rocks, sand, dust, and duricrust or surfaces with divergent local slopes. Other regions show thermal behavior that is more complex and not well-represented by two-component surface models. These results have important implications for Mars surface geology, climate modeling, landing-site selection, and other endeavors that employ thermal inertia as a tool for characterizing surface properties.     

Valley network-fed, open-basin lakes on Mars: Distribution and implications for Noachian surface and subsurface hydrology

A new catalog of 210 open-basin lakes (lakes with outlet valleys) fed by valley networks shows that they are widely distributed in the Noachian uplands of Mars. In order for an outlet valley to form, water must have ponded in the basin to at least the level of the outlet. We use this relationship and the present topography to directly estimate the minimum amount of water necessary to flood these basins in the past. The volumes derived for the largest lakes (∼3×¹⁰⁴ to ∼2×¹⁰⁵ km³) are comparable to the largest lakes and small seas on modern Earth, such as the Caspian Sea, Black Sea, and Lake Baikal. We determine a variety of other morphometric properties of these lakes and their catchments (lake area, mean depth, volume, shoreline development, outlet elevation, and watershed area). Most candidate lakes have volumes proportional to and commensurate with their watershed area, consistent with precipitation as their primary source. However, other lakes have volumes that are anomalously large relative to their watershed areas, implying that groundwater may have been important in their filling. Candidate groundwater-sourced lakes are generally concentrated in the Arabia Terra region but also include the Eridania basin [Irwin, R.P., Howard, A.D., Maxwell, T.A., 2004a. J. Geophys. Res. 109, doi: 10.1029/2004JE002287. E12009; Irwin, R.P., Watters, T.R., Howard, A.D. Zimbelman, J.R., 2004b. J. Geophys. Res. 109, doi: 10.1029/2004JE002248. E09011] and several lakes near the dichotomy boundary. This areal distribution is broadly consistent with where groundwater should have reached the surface as predicted by current models. Both surface runoff and groundwater flow appear to have been important sources for lakes and lake chains, suggesting a vertically integrated hydrological system, the absence of a global cryosphere, and direct communication between the surface and subsurface hydrosphere of early Mars.     

Characterization of hydrated silicate-bearing outcrops in Tyrrhena Terra,Mars: Implications to the alteration history of Mars

The Tyrrhena Terra region of Mars is studied with the imaging spectrometers OMEGA (Observatoire pour la Minéralogie, l’Eau, les Glaces et l’Activité) onboard Mars Express and CRISM (Compact Reconnaissance Infrared Spectrometer for Mars) onboard Mars Reconnaissance Orbiter, through the observation of tens of craters that impacted into this part of the martian highlands. The 175 detections of hydrated silicates are reported, mainly associated with ejecta blankets, crater walls and rims, and central up-lifts. Sizes of craters where hydrated silicates are detected are highly variable, diameters range from less than 1 km to 42 km. We report the presence of zeolites and phyllosilicates like prehnite, Mg-chlorite, Mg-rich smectites and mixed-layer chlorites–smectites and chlorite–vermiculite from comparison of hyperspectral infrared observations with laboratory spectra. These minerals are associated with fresh craters post-dating any aqueous activity. They likely represent ancient hydrated terrains excavated by the crater-forming impacts, and hence reveal the composition of the altered Noachian crust, although crater-related hydrothermal activity may have played a minor role for the largest craters (>20 km in diameter). Most detected minerals formed over relatively high temperatures (100–300 °C), likely due to aqueous alteration of the Noachian crust by regional low grade metamorphism from the Noachian thermal gradient and/or by extended hydrothermal systems associated with Noachian volcanism and ancient large impact craters. This is in contrast with some other phyllosilicate-bearing regions like Mawrth Vallis where smectites, kaolinites and hydrated silica were mainly identified, pointing to a predominance of surface/shallow sub-surface alteration; and where excavation by impacts played only a minor role. Smooth plains containing hydrated silicates are observed at the boundary between the Noachian altered crust, dissected by fluvial valleys, and the Hesperian unaltered volcanic plains. These plains may correspond to alluvial deposition of eroded material. The highlands of Tyrrhena Terra are therefore particularly well suited for investigating the diversity of hydrated minerals in ancient martian terrains.     

A survey of shergottite,nakhlite and chassigny meteorites whole-rock compositions

Abstract— Literature data on major and trace elemental abundances and water contents of the shergottite, nakhlite, and chassigny (SNC) meteorites are compiled and evaluated. The individual members of the SNC group are relatively homogeneous, and representative average compositions for each meteorite can be computed from multiple data reported in the literature. Major element abundances are used to calculate normative compositions and densities. The data survey shows that our knowledge of whole rock abundances in SNC meteorites is very limited for many elements and that more basic analytical work is needed.