The NEAR‐Shoemaker x‐ray/gamma‐ray spectrometer experiment: Overview and lessons learned

Abstract— The near‐Earth asteroid rendezvous (NEAR)‐Shoemaker remote‐sensing x‐ray/gamma‐ray spectrometer (XGRS) completed more than a year of operation in orbit and on the surface of 433 Eros. Elemental compositions for a number of regions on the surface of Eros have been derived from analyses of the characteristic x‐ray and gamma‐ray emission spectra. The NEAR XGRS detection system was included as part of the interplanetary network (IPN) for the detection and localization of gamma‐ray bursts (GRBs). Preliminary results for both the elemental composition of the surface of Eros and the detection of GRBs have been obtained. In addition to the science results, the design and operation of the NEAR XGRS is considered. Significant information important for the design of future remote sensing XGRS systems has been obtained and evaluated. We focus on four factors that became particularly critical during NEAR: (1) overall spacecraft design, (2) selection of materials, (3) increase of the signal‐to‐noise ratio and (4) knowledge of the incident solar x‐ray spectrum.     

Primordial,thermal, and shock features of ordinary chondrites: Emulating bulk X‐ray diffraction using in‐plane rotation of polished thin sections

Using an X‐ray diffractometer, powder‐like diffraction patterns were acquired from in‐plane rotation of polished thin sections (PTSs) of 60 ordinary chondrites (23 H, 21 L, and 16 LL), in order to explore the thermal and shock metamorphism and its modifications of primordial features. The olivine (Ol) 130 peak position shown as Bragg indices clearly correlates with the chemical group for equilibrated ordinary chondrites (EOCs), while the peak is split or broad for unequilibrated ordinary chondrites (UOCs). The intensity ratio of kamacite may be useful for distinguishing the chemical group between H and L‐LL, but it is not definite because of heterogeneous terrestrial weathering of kamacite, especially in H chondrites. The summed intensities of the orthoenstatite (Oen) 511 and 421 peaks positively correlates with the metamorphic sequence from 3 to 6, while that of clinoenstatite (Cen) 22 is inversely correlated. The shock stage positively correlates with the summed full width of half maximum values of the Oen 511 and 421 peaks and the FWHM of Ol 130 peak for each class. Significant amount of Oen (Pbca) transformed through Cen (C2/c) finally to Cen (P2₁/c) is stable at high pressure for shock stage S6 (Tenham and NWA 4719). The shock melted LL chondrite is characterized by the occurrence of Cen and abundant homogeneous olivine. The effects of both thermal and shock metamorphism are thus incorporated into the bulk X‐ray diffraction (XRD) data. The bulk XRD method is useful for determining the bulk mineralogy, resulting in the classification of ordinary chondrites. The method is also applicable to samples other than PTS.     

The composition of 433 Eros: A mineralogical—chemical synthesis

Abstract— The near‐Earth asteroid rendezvous (NEAR) mission carried x‐ray/gamma‐ray spectrometers and multi‐spectral imager/near‐infrared spectrometer instrument packages which gave complementary information on the chemistry and mineralogy, respectively, of the target asteroid 433 Eros. Synthesis of these two data sets provides information not available from either alone, including the abundance of non‐mafic silicates, metal and sulfide minerals. We have utilized four techniques to synthesize these data sets. Venn diagrams, which examine overlapping features in two data sets, suggest that the best match for 433 Eros is an ordinary chondrite, altered at the surface of the asteroid, or perhaps a primitive achondrite derived from material mineralogically similar to these chondrites. Normalized element distributions preclude FeO‐rich pyroxenes and suggest that the x‐ray and gamma‐ray data can be reconciled with a common silicate mineralogy by inclusion of varying amounts of metal. Normative mineralogy cannot be applied to these data sets owing to uncertainties in oxygen abundance and lack of any constraints on the abundance of sodium. Matrix inversion for simultaneous solution of mineral abundances yields reasonable results for the x‐ray‐derived bulk composition, but seems to confirm the inconsistency between mineral compositions and orthopyroxene/clinopyroxene ratios. A unique solution does not seem possible in synthesizing these multiple data sets. Future missions including a lander to fully characterize regolith distribution and sample return would resolve the types of problems faced in synthesizing the NEAR data.     

Determination of the equilibrium fO2 in bulk samples of H,L, and LL ordinary chondrites by solid‐state electrochemistry

High‐temperature solid‐state electrochemistry techniques (EMF method) were used to measure the oxygen fugacity (fO₂) of the ordinary chondrites Ochansk (H4), Savtschenskoje (LL4), Elenovka (L5), Vengerovo (H5), and Kharkov (L6). The fO₂ results are presented in the form of the following equations: It was found that fO₂ regularly increases from H chondrites to LL chondrites. Measured fO₂ are ~1.5 higher than those previously calculated from mineral assemblages. Kharkov (L6) is a little more oxidized than Elenovka (L5) in agreement with the progressive oxidation model. At the same time, Ochansk (H4) is more oxidized than Vengerovo (H5) and exhibits a slightly different slope compared to other chondrites and at T > 1200 K, becomes more reduced than Kharkov (L6) or Elenovka (L5). Measured oxygen fugacity values of meteorites fall within (0.1–1.0)·log fO₂ of one another. The possible explanation of discrepancies between measured and calculated values is discussed.     

Elemental composition from gamma‐ray spectroscopy of the NEAR‐Shoemaker landing site on 433 Eros

Abstract— Elemental composition and composition ratios derived from gamma‐ray measurements collected by the NEAR‐Shoemaker spacecraft while on the surface of 433 Eros are reported. Performance of the gamma‐ray spectrometer (GRS) during cruise and orbit is reviewed. The best gamma‐ray data were collected on the surface of Eros after the spacecraft's controlled descent on 2001 February 12. Methods used in spectral analysis, to convert peak areas to incident photons, and photons to elemental composition are described in some detail. The elemental abundance of K and the Mg/Si, Fe/Si, Si/O and Fe/O abundance ratios were determined. The Mg/Si and Si/O ratios and the K abundance are roughly chondritic, but the Fe/Si and Fe/O ratios are low compared to expected chondritic values. Three possible explanations for the apparent Fe depletion are considered.     

X‐ray fluorescence measurements of the surface elemental composition of asteroid 433 Eros

Abstract— We report major element ratios determined for the S‐class asteroid 433 Eros using remote‐sensing x‐ray fluorescence spectroscopy with the near‐Earth asteroid rendezvous Shoemaker x‐ray spectrometer (XRS). Data analysis techniques and systematic errors are described in detail. Data acquired during five solar flares and during two extended “quiet Sun” periods are presented; these results sample a representative portion of the asteroid's surface. Although systematic uncertainties are potentially large, the most internally consistent and plausible interpretation of the data is that Eros has primitive Mg/Si, Al/Si, Ca/Si and Fe/Si ratios, closely similar to H or R chondrites. Global differentiation of the asteroid is ruled out. The S/Si ratio is much lower than that of chondrites, probably reflecting impact‐induced volatilization and/or photo‐ or ion‐induced sputtering of sulfur at the surface of the asteroid. An alternative explanation for the low S/Si ratio is that it reflects a limited degree of melting with loss of an FeS‐rich partial melt. Size‐sorting processes could lead to segregation of Fe‐Ni metal from silicates within the regolith of Eros; this could indicate that the Fe/Si ratios determined by the x‐ray spectrometer are not representative of the bulk Eros composition.     

Elemental composition of 433 Eros: New calibration of the NEAR-Shoemaker XRS data

We present a new calibration of the elemental-abundance data for Asteroid 433 Eros taken by the X-ray spectrometer (XRS) aboard the NEAR-Shoemaker spacecraft. (NEAR is an acronym for “Near-Earth Asteroid Rendezvous.”) Quantification of the asteroid surface elemental abundance ratios depends critically on accurate knowledge of the incident solar X-ray spectrum, which was monitored simultaneously with asteroid observations. Previously published results suffered from incompletely characterized systematic uncertainties due to an imperfect ground calibration of the NEAR gas solar monitor. The solar monitor response function and associated uncertainties have now been characterized by cross-calibration of a large sample of NEAR solar monitor flight data against contemporary broadband solar X-ray data from the Earth-orbiting GOES-8 (Geostationary Operational Environmental Satellite). The results have been used to analyze XRS spectra acquired from Eros during eight major solar flares (including three that have not previously been reported). The end product of this analysis is a revised set of Eros surface elemental abundance ratios with new error estimates that more accurately reflect the remaining uncertainties in the solar flare spectra: Mg/Si=0.753+0.078/−0.055, Al/Si=0.069±0.055, S/Si=0.005±0.008, Ca/Si=0.060+0.023/−0.024, and Fe/Si=1.678+0.338/−0.320. These revised abundance ratios are consistent within cited uncertainties with the results of Nittler et al. [Nittler, L.R., and 14 colleagues, 2001. Meteorit. Planet. Sci. 36, 1673-1695] and thus support the prior conclusions that 433 Eros has a major-element composition similar to ordinary chondrites with the exception of a strong depletion in sulfur, most likely caused by space weathering.     

Laboratory simulations of sulfur depletion at Eros

The X-ray spectrometer of the Near-Earth Asteroid Rendezvous (NEAR) mission discovered a low abundance of sulfur on the surface of asteroid Eros, which is seemingly inconsistent with the match of the overall surface composition to that of ordinary chondrites. Since troilite, FeS, is the primary sulfur-bearing mineral in ordinary chondrites, we investigated the hypothesis that sulfur loss from surface FeS could result from ‘space weathering’ by impact of solar wind ions and micrometeorites. We performed laboratory studies on the chemical alteration of FeS by 4 keV ions simulating exposure to the solar wind and by nanosecond laser pulses simulating pulsed heating by micrometeorite impact. We found that the combination of laser irradiation followed by ion impact lowers the S:Fe atomic ratio on the surface by a factor of up to 2.5, which is consistent with the value of at least 1.5 deduced from the NEAR measurements. Thus, our results support the hypothesis that the low abundance of sulfur at the surface of Eros is caused by space weathering.     

Ponded deposits on asteroid 433 Eros

Abstract— In late January 2001 the NEAR—Shoemaker spacecraft performed low‐altitude passes over the surface of 433 Eros. Coordinated observations of the asteroid surface were obtained at submeter resolution by the NEAR laser rangefinder and the multispectral imager. This paper presents three independent, coordinated observations of a 90 m pond adjacent to a granular debris flow, including the highest resolution altimetric measurements of ponded deposits on Eros. The ponded deposits appear to have been emplaced by fluid‐like motion of dry asteroidal regolith. A simple model of seismic agitation from impacts is developed to account for pond formation on Eros. The model predicts that ponds should form readily on Eros but not on the Moon, where ponds are not observed. The model also suggests that the absence of observable ponds in the largest craters of Eros, as well as on Phobos and Deimos, may be related to regolith depth.     

Crystallization temperature determination of Itokawa particles by plagioclase thermometry with X‐ray diffraction data obtained by a high‐resolution synchrotron Gandolfi camera

The crystallization temperatures of Itokawa surface particles recovered by the space probe Hayabusa were estimated by a plagioclase geothermometer using sodic plagioclase triclinicity. The Δ131‐index required for the thermometer, which is the difference in X‐ray diffraction peak positions between the 131 and 11 reflections of plagioclase, was obtained by a high‐resolution synchrotron Gandolfi camera developed for the third generation synchrotron radiation beamline, BL15XU at SPring‐8. Crystallization temperatures were successfully determined from the Δ131‐indices for four particles. The observed plagioclase crystallization temperatures were in a range from 655 to 660 °C. The temperatures indicate crystallization temperatures of plagioclases in the process of prograde metamorphism before the peak metamorphic stage.     

Depletion of sulfur on the surface of asteroids and the moon

Abstract— Data from the X‐ray and γ‐ray spectrometers onboard the Near Earth Asteroid Rendezvous (NEAR) spacecraft were used to constrain the chemical and mineralogical composition of asteroid 433 Eros (McCoy et al. 2001). The bulk composition appears to be consistent with that of L to H chondrites (Nittler et al. 2001). However, there appeared to be a marked depletion relative to ordinary chondritic composition in the S/Si ratio (0.014 ± 0.017). We investigate space weathering mechanisms to determine the extent to which sulfur can be preferentially lost from the surface regolith. The two processes considered are impact vaporization by the interplanetary meteoroid population and ion sputtering by the solar wind. Using impact data for Al projectiles onto enstatite, we find that the vaporization rate for troilite (FeS) is nine times as fast as that for the bulk of the regolith. If 20% of the iron is in the form of troilite, then the net vaporization rate, normalized to bulk composition, is 2.8 times faster for sulfur than for iron. Sputtering is equally efficient at removing sulfur as impact vaporization.     

The geology of 433 Eros

Abstract— The global high‐resolution imaging of asteroid 433 Eros by the Near‐Earth Asteroid Rendezvous (NEAR) Shoemaker spacecraft has made it possible to develop the first comprehensive picture of the geology of a small S‐type asteroid. Eros displays a variety of surface features, and evidence of a substantial regolith. Large scale facets, grooves, and ridges indicate the presence of at least one global planar structure. Directional and superposition relations of smaller structural features suggest that fracturing has occurred throughout the object. As with other small objects, impact craters dominate the overall shape as well as the small‐scale topography of Eros. Depth/diameter ratios of craters on Eros average ～0.13, but the freshest craters approach lunar values of ～0.2. Ejecta block production from craters is highly variable; the majority of large blocks appear to have originated from one 7.6 km crater (Shoemaker). The interior morphology of craters does not reveal the influence of discrete mechanical boundaries at depth in the manner of craters formed on lunar mare regolith and on some parts of Phobos. This lack of mechanical boundaries, and the abundant evidence of regolith in nearly every high‐resolution image, suggests a gradation in the porosity and fracturing with depth. The density of small craters is deficient at sizes below ～200 m relative to predicted slopes of empirical saturation. This characteristic, which is also found on parts of Phobos and lunar highland areas, probably results from the efficient obliteration of small craters on a body with significant topographic slopes and a thick regolith. Eros displays a variety of regolith features, such as debris aprons, fine‐grained “ponded” deposits, talus cones, and bright and dark streamers on steep slopes indicative of efficient downslope movement of regolith. These processes serve to mix materials in the upper loose fragmental portion of the asteroid (regolith). In the instance of “ponded” materials and crater wall deposits, there is evidence of processes that segregate finer materials into discrete deposits. The NEAR observations have shown us that surface processes on small asteroids can be very complex and result in a wide variety of morphologic features and landforms that today seem exotic. Future missions to comets and asteroids will surely reveal still as yet unseen processes as well as give context to those discovered by the NEAR Shoemaker spacecraft.     

443 Eros: Problems with the meteorite magnetism record in attempting an asteroid match

Abstract— The magnetometer experiment (MAG) onboard the Near‐Earth Asteroid Rendezvous (NEAR)‐Shoemaker spacecraft detected no global scale magnetization and established a maximum magnetization of 2.1 times 10^?6 Am² kg^?1 for asteroid 433 Eros. This is in sharp contrast with the estimated magnetization of other S‐class asteroids (Gaspra, ?2.4 times 10^?2 Am² kg^?1; Braille, ?2.8 times 10^?2 Am² kg^?1) and is below published values for all types of ordinary chondrites. This includes the L/LL types considered to most closely match 433 Eros based on preliminary interpretations of NEAR remote geochemical experiments. The ordinary chondrite meteorite magnetization intensity data was reviewed in order to assess the reasonableness of an asteroid‐meteorite match based on magnetic property measurements. Natural remanent magnetization (NRM) intensities for the ordinary chondrite meteorites show at least a 2 order of magnitude range within each of the H, L, and LL groups, all well above the 2.1 times 10^?6 Am² kg^?1 level for 433 Eros. The REM values (ratio of the NRM to the SIRM (saturation remanent magnetization)) range over 3 orders of magnitude for all chondrite groups indicating no clear relationship between NRM and the amount of magnetic material. Levels of magnetic noise in chondrite meteorites can be as much as 70% or more of the NRM. Consequently, published values of the NRM should be considered suspect unless careful evaluation of the noise sources is done. NASA Goddard SFC studies of per unit mass intensities in large (>10 000 g) and small (down to <1 g) samples from the same meteorite demonstrate magnetic intensity decreases as size increases. This would appear to be explained by demagnetization due to magnetic vector randomness at unknown scale sizes in the larger samples. This would then argue for some level of demagnetization of large objects such as an asteroid. The possibility that 433 Eros is an LL chondrite cannot be discounted.     

Minor element evidence that Asteroid 433 Eros is a space-weathered ordinary chondrite parent body

The NEAR mission to 433 Eros provided detailed data on the geology, mineralogy, and chemistry of this S-class asteroid [McCoy, T.J., Robinson, M.S., Nittler, L.R., Burbine, T.H., 2002. Chem. Erde 62, 89-121; Cheng, A.F., 1997. Space Sci. Rev. 82, 3-29] with a key science goal of understanding the relationship between asteroids and meteorites [Cheng, A.F., 1997. Space Sci. Rev. 82, 3-29; Gaffey, M.J., Burbine, T.H., Piatek, J.L., Reed, K.L., Chaky, D.A., Bell, J.F., Brown, R.H., 1993a. Icarus 106, 573-602]. Previously reported major element data revealed a bulk surface similar to that of ordinary chondrites, with the notable exception of sulfur, which was highly depleted [Trombka, J.I., and 23 colleagues, 2000. Science 289, 2101-2105; Nittler, L.R., and 14 colleagues, 2001. Meteorit. Planet. Sci. 36, 1673-1695]. The origin of this sulfur deficiency, and hence the fundamental nature of the asteroid's surface, has remained controversial. We report a new analysis of NEAR X-ray spectrometer data, indicating that Eros has Cr/Fe, Mn/Fe, and Ni/Fe ratios similar to ordinary chondrite meteorites of type LL or L. Chondritic levels of Cr, Mn, and Ni argue strongly against a partial melting explanation for the sulfur depletion. Instead, our results provide definitive evidence that Eros is a primitive body with composition and mineralogy similar to ordinary chondrites, but with a surface heavily modified by interactions with the solar wind and micrometeorites, processes collectively termed space weathering.     

An Estimate of Eros's Porosity and Implications for Internal Structure

Earth-based spectral measurements and NEAR Shoemaker magnetometer, X-ray, and near-infrared spectrometer data are all consistent with Eros having a bulk composition and mineralogy similar to ordinary chondrite meteorites (OC). By comparing the bulk density of 433 Eros (2.67±0.03 g/cm³) with that of OCs (3.40 g/cm³), we estimate the total porosity of the asteroid to be 21-33%. Macro (or structural) porosity, best estimated to be ∼20%, is constrained to be between 6 and 33%. We conclude that Eros is a heavily fractured body, but we find no evidence that it was ever catastrophically disrupted and reaccumulated into a rubble pile.     

Restriction of parent body heating by metal‐troilite melting: Thermal models for the ordinary chondrites

Ordinary chondrite meteorites contain silicates, Fe,Ni‐metal grains, and troilite (FeS). Conjoined metal‐troilite grains would be the first phase to melt during radiogenic heating in the parent body, if temperatures reached over approximately 910–960 °C (the Fe,Ni‐FeS eutectic). On the basis of two‐pyroxene thermometry of 13 ordinary chondrites, we argue that peak temperatures in some type 6 chondrites exceeded the Fe,Ni‐FeS eutectic and thus conjoined metal‐troilite grains would have begun to melt. Melting reactions consume energy, so thermal models were constructed to investigate the effect of melting on the thermal history of the H, L, and LL parent asteroids. We constrained the models by finding the proportions of conjoined metal‐troilite grains in ordinary chondrites using high‐resolution X‐ray computed tomography. The models show that metal‐troilite melting causes thermal buffering and inhibits the onset of silicate melting. Compared with models that ignore the effect of melting, our models predict longer cooling histories for the asteroids and accretion times that are earlier by 61, 124, or 113 kyr for the H, L, and LL asteroids, respectively. Because the Ni/Fe ratio of the metal and the bulk troilite/metal ratio is higher in L and LL chondrites than H chondrites, thermal buffering has the greatest effect in models for the L and LL chondrite parent bodies, and least effect for the H chondrite parent. Metal‐troilite melting is also relevant to models of primitive achondrite parent bodies, particularly those that underwent only low degrees of silicate partial melting. Thermal models can predict proportions of petrologic types formed within an asteroid, but are systematically different from the statistics of meteorite collections. A sampling bias is interpreted to explain these differences.     

Photometric analysis of Eros from NEAR data

A photometric model of (433) Eros at wavelengths from 450 to 1050 nm is constructed using the combination of the images from the multispectral imager (MSI) obtained during the one-year long orbital phase of the NEAR mission, ground-based lightcurves from earlier observations, and our theoretical forward modeling simulations coupled with the NEAR shape model. The single scattering albedo is found to be 0.33±0.03 at 550 nm, which is smaller than past findings by 30%. The amplitude and width of the opposition effect are 1.4±0.1 and 0.010±0.004 from ground based lightcurves. It is confirmed that the asymmetry factor of the single-particle phase function and the surface roughness parameter do not depend on wavelength from 450 to 1050 nm, and their values are estimated to be −0.25±0.02 and 28°±3°, respectively, comparable with the earlier measurements from the NEAR NIS data. The geometric albedo and the Bond albedo at 550 nm are calculated to be 0.23 and 0.093, respectively, which make Eros less reflective than previous models, but still slightly more reflective than average S-type asteroids. The lower albedos of Eros are more consistent with our forward modeling simulations, as well as with its spectrum. Eros is a typical S-type asteroid like (951) Gaspra and (243) Ida, and has similar surface regolith properties. Combining the single-scattering albedo with the olivine composition of ordinary chondrites, taking into account space weathering darkening, we constrain the grain size of the regolith particles on Eros to a range of 50 to 100 μm.     

Chemical and mineralogical compositions of two grains recovered from asteroid Itokawa

Two silicate grains (RB‐QD04‐0049 and RA‐QD02‐0064, whose estimated masses are 0.050 μg and 0.048 μg, respectively) recovered from the asteroid Itokawa by the Hayabusa spacecraft were studied for their mineralogical characteristics by synchrotron X‐ray diffraction and synchrotron X‐ray microtomography and further analyzed for their bulk chemical compositions by instrumental neutron activation analysis (INAA). According to X‐ray tomography, RB‐QD004‐0049 is composed of olivine, high‐Ca pyroxene, plagioclase, Ca‐phosphate, and troilite, whereas RA‐QD002‐0064 entirely consists of olivine. INAA data are consistent with these mineral compositions except for rare earth elements (REEs). Although the grain RB‐QD004‐0049 contains measurable REEs, which seems to be consistent with the presence of Ca‐phosphate, their abundances are anomalously high. Very low abundance of Co implies less than 0.1 mass% of metals in these two grains by calculation, which is in contrast to the result for the previously analyzed grain RA‐QD02‐0049 (Ebihara et al., 2011). FeO/Sc ratios of the grains fall within the range of those for ordinary chondrite olivines, implying that these grains are extraterrestrial in origin. FeO/MnO ratios also confirm this conclusion and further suggest that the Hayabusa grains analyzed in this study are similar to material found in LL chondrites rather than CK chondrites although olivines from LL and CK chondrites have similar Fa# (molar% of Fe relative to [Fe+Mg] in olivine) (~30) to those of the Hayabusa grains including the two grains analyzed in this study.     

Mineral chemistry of MUSES‐C Regio inferred from analysis of dust particles collected from the first‐ and second‐touchdown sites on asteroid Itokawa

The mineralogy and mineral chemistry of Itokawa dust particles captured during the first and second touchdowns on the MUSES‐C Regio were characterized by synchrotron‐radiation X‐ray diffraction and field‐emission electron microprobe analysis. Olivine and low‐ and high‐Ca pyroxene, plagioclase, and merrillite compositions of the first‐touchdown particles are similar to those of the second‐touchdown particles. The two touchdown sites are separated by approximately 100 meters and therefore the similarity suggests that MUSES‐C Regio is covered with dust particles of uniform mineral chemistry of LL chondrites. Quantitative compositional properties of 48 dust particles, including both first‐ and second‐touchdown samples, indicate that dust particles of MUSES‐C Regio have experienced prolonged thermal metamorphism, but they are not fully equilibrated in terms of chemical composition. This suggests that MUSES‐C particles were heated in a single asteroid at different temperatures. During slow cooling from a peak temperature of approximately 800 °C, chemical compositions of plagioclase and K‐feldspar seem to have been modified: Ab and Or contents changed during cooling, but An did not. This compositional modification is reproduced by a numerical simulation that modeled the cooling process of a 50 km sized Itokawa parent asteroid. After cooling, some particles have been heavily impacted and heated, which resulted in heterogeneous distributions of Na and K within plagioclase crystals. Impact‐induced chemical modification of plagioclase was verified by a comparison to a shock vein in the Kilabo LL6 ordinary chondrite where Na‐K distributions of plagioclase have been disturbed.     

Size‐frequency distributions of chondrules and chondrule fragments in LL3 chondrites: Implications for parent‐body fragmentation of chondrules

Abstract— We measured the sizes and textural types of 719 intact chondrules and 1322 chondrule fragments in thin sections of Semarkona (LL3.0), Bishunpur (LL3.1), Krymka (LL3.1), Piancaldoli (LL3.4) and Lewis Cliff 88175 (LL3.8). The mean apparent diameter of chondrules in these LL3 chondrites is 0.80 φ units or 570 μm, much smaller than the previous rough estimate of ～900 μm. Chondrule fragments in the five LL3 chondrites have a mean apparent cross‐section of 1.60 φ units or 330 μm. The smallest fragments are isolated olivine and pyroxene grains; these are probably phenocrysts liberated from disrupted porphyritic chondrules. All five LL3 chondrites have fragment/ chondrule number ratios exceeding unity, suggesting that substantial numbers of the chondrules in these rocks were shattered. Most fragmentation probably occurred on the parent asteroid. Porphyritic chondrules (porphyritic olivine + porphyritic pyroxene + porphyritic olivine‐pyroxene) are more readily broken than droplet chondrules (barred olivine + radial pyroxene + cryptocrystalline). The porphyritic fragment/chondrule number ratio (2.0) appreciably exceeds that of droplet‐textured objects (0.9). Intact droplet chondrules have a larger mean size than intact porphyritic chondrules, implying that large porphyritic chondrules are fragmented preferentially. This is consistent with the relatively low percentage of porphyritic chondrules within the set of the largest chondrules (57%) compared to that within the set of the smallest chondrules (81%). Differences in mean size among chondrule textural types may be due mainly to parent‐body chondrule‐fragmentation events and not to chondrule‐formation processes in the solar nebula.