Experimental constraints on the solidification of a hydrous lunar magma ocean

The identification of hydrogen in a range of lunar samples and the similarity of its abundance and isotopic composition with terrestrial values suggest that water could have been present in the Moon since its formation. To quantify the effect of water on early lunar differentiation, we present new analyses of a high‐pressure, high‐temperature experimental study designed to model the mineralogical and geochemical evolution of the solidification material equivalent to 700 km deep lunar magma oceans first reported in Lin et al. (2017a). We also performed additional experiments to better quantify water contents in the run products. Water contents in the melt phases in hydrous run products spanning a range of crystallization steps were quantified directly using a secondary ion mass spectrometry (SIMS). Results suggest that a significant but constant proportion (68 ± 5%) of the hydrogen originally added to the experiments was lost from the starting material independent of run conditions and run duration. The volume of plagioclase formed during our crystallization experiments can be combined with the measured water contents and the observed crustal thickness on the Moon to provide an updated lunar interior hygrometer. Our data suggest that at least 45–354 ppm H₂O equivalent was present in the Moon at the time of crust formation. These estimates confirm the inference of Lin et al. (2017a) that the Moon was wet during its magma ocean stage, with corrected absolute water contents now comparable to estimates derived from the water content in a range of lunar samples.     

The global distribution of pyroclastic deposits on Mercury: The view from MESSENGER flybys 1–3

We present a global survey of candidate pyroclastic deposits on Mercury, derived from images obtained during MESSENGER flybys 1–3 that provided near-global coverage at resolutions between 5 and 0.5 km/pixel. Thirty-five deposits were identified and characterized and are located principally on the floors of craters, along rims of craters, and along the edge of the Caloris basin. Deposits are commonly centered on rimless, often irregularly shaped pits, mostly between 5 and 45 km in diameter. The deposits identified are generally similar in morphology and absolute reflectance to lunar pyroclastic deposits. Spectrally the deposits appear brighter and redder than background Mercury terrain. On the basis of the available coverage, the candidate pyroclastic deposits appear to be essentially globally distributed. The diameters of the deposits, when mapped to lunar gravity conditions, are larger than their lunar counterparts, implying that more abundant volatiles were present during the typical eruptive process than on the Moon. These observations indicate that if these deposits resulted from hawaiian-style eruptions, the volatile contents required would be between ～1600 and 16,000 ppm CO or an equivalent value of H₂O, CO₂, SO₂, or H₂S (for a more oxidizing interior), or N₂, S₂, CS₂, S₂Cl, Cl, Cl₂, or COS (for a more reducing interior). These abundances are much greater than those predicted by existing models for Mercury's formation. An apparent lack of small deposits, compared with the Moon, may be due to resolution effects, a topic that can be further assessed during the orbital phase of the MESSENGER mission. These results provide a framework within which orbital observations by MESSENGER and the future BepiColombo mission can be analyzed.     

The lunar geochemistry of chromium and vanadium

Crystal/liquid partition coefficients for Cr, V, Mn, and Fe have been determined experimentally between olivine, orthopyroxene, clinopyroxene and silicate melt possesing the composition of a primitive lunar green glass, at oxygen fugacities appropriate to the lunar interior. These species all behave essentially as compatible elements and possess crystal/liquid partition coefficients mostly between 0.3 and 0.9. Partition coefficients for Cr, V, and Mn are generally similar to those of Fe. This implies that crystal/liquid fractionation processes in the lunar interior which do not involve the participation of spinels would not have been effective in fractionating MnO, CrO, and VO from FeO. The well-known constancy of FeO/MnO ratios in nearly all lunar rocks is a reflection of this behaviour. It is shown that comparably strong correlations between CrO-;FeO and VO-;FeO exist for lunar highland breccias and soils from all sites and that these correlations extend to primitive lunar volcanic glasses associated with mare volcanism, strongly suggesting that the CrO/FeO and VO/FeO ratios so derived are of global importance. The observed ratios characterizing differentiated regions of the Moon can be combined with the corresponding ratios for residual refractory portions of the Moon, using measured partition coefficients for Fe, Mg, Cr, V, and Mn between olivine, orthopyroxene and liquid. Bulk Moon abundances for Cr and V have been calculated for a range of reasonable assumptions concerning the petrogenetic relationships between differentiated portions of the Moon and complementary refractory residua consisting of olivine and orthopyroxene mineralogies. Because of the small differences in crystal liquid partition coefficients between FeO, CrO, and VO, these estimates are insensitive to large variations in the models. The bulk Moon is accordingly estimated to contain 2190–2463 ppm Cr and 79–95 ppm V. These values are very similar to the Cr and V contents of the Earth's mantle, estimated as 3010 ppm Cr and 81 ppm V by Sun (1982). The geochemical implications of these similarities are discussed.     

Evidence for objects of lunar mass in the early solar system and for capture as a general process for the origin of satellites

The problem of the accumulation of the Moon is discussed on the assumption that the Moon is a captured object. If it is such, it is highly improbable that it is the only object of this kind present in the early solar system. Evidence indicating that other massive objects were present at that time is presented. Also, it is pointed out that the interior of the Moon must contain normal solar proportions of the elements of intermediate volatility in the lunar interior, if the Moon accumulated in a gas sphere.     

Evidence for objects of lunar mass in the early solar system

The problem of the accumulation of the Moon is discussed on the assumption that the Moon is a captured object. If it is such, it is highly improbable that it is the only object of this kind present in the early solar system. Evidence indicating that other massive objects were present at that time is presented. Also, it is pointed out that interior of the Moon must contain normal solar proportions of the elements of intermediate volatility in the lunar interior, if the Moon accumulated in a gas sphere.     

Thermal history and early magmatism in the Moon

Lunar heat-flow calculations are carried out for a model Moon in which (a) near-surface initial temperatures are very high (as the occurence of a surface anorthositic layer seems to require), and (b) heat-generating radionuclides are transported upward when melting occurs. Near-surface regions are found to cool and then experience a resurgence of high temperature, as radionuclide-rich magmas from the lunar interior accumulate near the surface. This peaking of near-surface temperature can be brought into correspondence with the episode of vulcanism (∼ 3.5 × 10⁹ years ago) that gave rise to the basalts represented in the Apollo samples, if we assume relatively high lunar temperatures in early times (due to high initial temperatures, or high content of radioactive elements, or both).     

Water and other volatiles on the moon: A review

This paper presents a review of research findings on the various forms of water on the Moon. First, this is the water of the Moon’s interior, which has been detected by sensitive mass spectrometric analysis of basaltic glasses delivered by the Apollo 15 and Apollo 17 missions. The previous concepts that lunar magmas are completely dehydrated have been disproved. Second, this is H₂O and/or OH in a thin layer (a few upper millimeters) of the lunar regolith, which is likely a result of bombardment of the oxygen contained in the lunar regolith with solar wind protons. This form of water is highly unstable and quite easily escapes from the surface, possibly being one of the sources of the water ice reservoirs at the Moon’s poles. Third, this is water ice associated with other frozen gases in cold traps at the lunar poles. Its possible sources are impacts of comets and meteorites, the release of gas from the Moon’s interior, and solar wind protons. The ice trapped at the lunar polars could be of practical interest for further exploration of the Moon.     

Compositional analyses of lunar pyroclastic deposits

The 5-band Clementine UVVIS data at ∼100 m/pixel were used to examine the compositions of 75 large and small lunar pyroclastic deposits (LPDs), and these were compared to representative lunar maria and highlands deposits. Results show that the albedo, spectral color, and inferred composition of most LPDs are similar to those of low-titanium, mature lunar maria. These LPDs may have consisted largely of fragmented basalt, with substantial components of iron-bearing mafic minerals (pyroxenes, olivine) and smaller amounts (if any) of volcanic glass. Several smaller LPDs also show substantial highland components. Three classes of very large deposits can be distinguished from most LPDs and from each other on the basis of crystallinity and possible titanium content of their pyroclastic components. One class has spectral properties that are dominated by high-titanium, crystallized “black beads” (e.g., Taurus-Littrow), a second consists of a mixture of high-titanium glasses and beads with a higher glass/bead ratio (Sulpicius Gallus) than that of Taurus-Littrow, and a third has a significant component of quenched iron-bearing volcanic glasses (Aristarchus) with possible moderate titanium contents. Although areally extensive, these three classes of very large pyroclastic deposits compose only 20 of the 75 deposits studied (∼27%), and eruption of such materials was thus likely to have been less frequent on the Moon.     

Limits on the bulk composition of the Moon

Recent hypotheses of lunar evolution hold that the Moon was extensively or completely melted and differentiated about 4.6 b.y. ago, resulting in formation of the plagioclase-rich lunar highlands underlain by a great thickness of complementary ferromagnesian cumulates. Mare basalts are interpreted as being formed by subsequent remelting of these cumulates. These hypotheses are tested experimentally in the cases of several bulk compositions which have been proposed for the Moon—those of Taylor and Jakes, Ganapathy and Anders, Wänke and co-workers, and Anderson. An extensive experimental investigation of melting equilibria displayed by the Taylor-Jakes model at high pressures and temperatures is presented. This permits a quantitative evaluation of the manner in which a model Moon with this composition would crystallize and differentiate under conditions of (i) total melting throughout, and (ii) total melting only of an outer shell a few hundred kilometers thick. A detailed study is made of the capacity of the cumulates underlying the crust in these models to produce mare basalts by a second stage of partial melting. A wide range of experimentally based arguments is presented, showing that for both cases, partial melting of such cumulates would produce magmas with compositions quite unlike those of mare basalts. In order to minimize these difficulties, bulk lunar compositions containing substantially smaller abundances of involatile components (e.g. CaO, Al₂O₃, TiO₂) relative to major components of intermediate volatility (e.g. MgO, SiO₂, FeO) than are specified in the Taylor-Jakes model, appear to be required. Other bulk lunar composition models proposed by Ganapathy and Anders, Wänke and co-workers and Anderson, were similarly tested in the light of experimental data. All of these are far too rich in (Ca and Al) relative to (Mg + Si + Fe) to yield, after melting and differentiation, cumulates capable of being parental to mare basalts. Moreover these compositions, whdn melted and differentiated, appear incapable of matching the composition of the pyroxene component of the lunar highland crust.A brief discussion of the petrogenesis of mare basakts is presented. The most promising model is one in which only the outer few hundred kilometers of the Moon were melted and differentiated around 4.6 b.y. ago. Continued radioactive heating of the deep undifferentiated lunar interior provided a second generation of primitive magmas up to 1.5 b.y. after the early melting and differentiation. These primitive magmas participated in assimilative interactions with late-stage differentiates formed near the crust-mantle boundary during the 4.6 b.y. differentiation. These interactions might explain some trace element and isotopic characteristics of mare basalts. The model possesses some attractive characteristics relating to the thermal evolution of the Moon.     

Volatile retention from cometary impacts on the Moon

Impacts of comets and asteroids play an important role in volatile delivery on the Moon. We use a novel method for tracking vapor masses that reach escape velocity in hydrocode simulations of cometary impacts to explore the effects of volatile retention. We model impacts on the Moon to find the mass of vapor plume gravitationally trapped on the Moon as a function of impact velocity. We apply this result to the impactor velocity distribution and find that the total impactor mass retained on the Moon is approximately 6.5% of the impactor mass flux. Making reasonable assumptions about water content of comets and the comet size-frequency distribution, we derive a water flux for the Moon. After accounting for migration and stability of water ice at the poles, we estimate a total 1.3×10⁸-4.3×10⁹ metric tons of water is delivered to the Moon and remains stable at the poles over 1 Ga. A factor of 30 uncertainty in the estimated cometary impact flux is primarily responsible for this large range of values. The calculated mass of water is sufficient to account for the neutron fluxes poleward of 75° observed by Lunar Prospector. A similar analysis for water delivery to the Moon via asteroid impacts shows that asteroids provide six times more water mass via impacts than comets.     

Stress history of the Moon

The character of the lunar surface indicates that surface faulting has not been an important mechanism for the build-up of the lunar surface. If the radioactive content of the Moon is of the same order as that of chondritic meteorites, then the absence of major surface faults can be explained in a number of ways. A near-surface concentration of radioactivity will provide an equality of heat production and surface heat flow necessary for the maintenance of a constant lunar radius. Alternatively, the radioactivity could be deeply buried, with the radius still remaining constant over the past 2,000,000,000 years. Heat transported by mechanisms other than radiation and thermal conduction will also tend to keep the radius of the Moon at a constant value.

Even though the radius of the Moon remains constant, there is a major build-up of strain energy throughout the Moon. The rate is such that, on the average, something on the order of 10²⁴–10²⁵ ergs of distortional energy should be released per year throughout the Moon, provided the radioactivity is uniformly distributed. A near-surface concentration of the radioactivity might decrease this rate of energy release but certainly by no more than an order of magnitude. Under all circumstances it would appear that a Moon of chondritic composition would have strong Scismic activity.     

The chemical composition and structure of the moon

Three types of igneous rocks, all ultimately related to basaltic liquids, appear to be common on the lunar surface. They are: (1) iron-rich mare basalts, (2) U-, REE-, and Al-rich basalts (KREEP), and (3) plagioclase-rich or anorthositic rocks. All three rock types are depleted in elements more volatile than sodium and in the siderophile elements when relative element abundances are compared with those of carbonaceous chondrites. The chemistry and age relationships of these rocks suggest that they are derived from a feldspathic, refractory element-rich interior that becomes more pyroxenitic; that is, iron/magnesium-rich; with depth.It is suggested that the deeper parts of the lunar interior tend toward chondritic element abundances. The radial variation in mineralogy and bulk chemical composition inferred from the surface chemistry is probably a primitive feature of the Moon that reflects the accretion of refractory elementenriched materials late in the formation of the body.     

Volatiles in lunar regolith samples: A survey

A summary is given of the literature data on the content of volatiles in the lunar regolith, the characterization of the likely sources of the volatiles, and the possible processes of their migration and burial. The main sources of volatiles in the regolith are the solar wind, small Solar System bodies (comets and meteorites), and the lunar interior. Different sources are the leading ones for different volatiles. Water and other volatiles can accumulate on the surface and in the near-surface layers of the Moon only in the so-called cold traps in polar basins, where other volatiles, as well as water ice, including highly toxic elements such as mercury and cadmium must be accumulated. The content of volatiles in the lunar interior is comparable to that in terrestrial rocks. Water could have played an important role in the early stages of the Moon’s history, e.g., in the formation of mare basalts. The isotopic composition of the lunar juvenile water is similar to that on the Earth, which suggests a common origin of the terrestrial and lunar water.     

The early geological history of the Moon inferred from ancient lunar meteorite Miller Range 13317

Miller Range (MIL) 13317 is a heterogeneous basalt‐bearing lunar regolith breccia that provides insights into the early magmatic history of the Moon. MIL 13317 is formed from a mixture of material with clasts having an affinity to Apollo ferroan anorthosites and basaltic volcanic rocks. Noble gas data indicate that MIL 13317 was consolidated into a breccia between 2610 ± 780 Ma and 1570 ± 470 Ma where it experienced a complex near‐surface irradiation history for ~835 ± 84 Myr, at an average depth of ~30 cm. The fusion crust has an intermediate composition (Al₂O₃ 15.9 wt%; FeO 12.3 wt%) with an added incompatible trace element (Th 5.4 ppm) chemical component. Taking the fusion crust to be indicative of the bulk sample composition, this implies that MIL 13317 originated from a regolith that is associated with a mare‐highland boundary that is KREEP‐rich (i.e., K, rare earth elements, and P). A comparison of bulk chemical data from MIL 13317 with remote sensing data from the Lunar Prospector orbiter suggests that MIL 13317 likely originated from the northwest region of Oceanus Procellarum, east of Mare Nubium, or at the eastern edge of Mare Frigoris. All these potential source areas are on the near side of the Moon, indicating a close association with the Procellarum KREEP Terrane. Basalt clasts in MIL 13317 are from a very low‐Ti to low‐Ti (between 0.14 and 0.32 wt%) source region. The similar mineral fractionation trends of the different basalt clasts in the sample suggest they are comagmatic in origin. Zircon‐bearing phases and Ca‐phosphate grains in basalt clasts and matrix grains yield ²⁰⁷Pb/²⁰⁶Pb ages between 4344 ± 4 and 4333 ± 5 Ma. These ancient ²⁰⁷Pb/²⁰⁶Pb ages indicate that the meteorite has sampled a range of Pre‐Nectarian volcanic rocks that are poorly represented in the Apollo, Luna, and lunar meteorite collections. As such, MIL 13317 adds to the growing evidence that basaltic volcanic activity on the Moon started as early as ~4340 Ma, before the main period of lunar mare basalt volcanism at ~3850 Ma.     

Distribution, ,movement,and evolution of the volatile elements in the lunar regolith

The abundances and distributions of carbon, nitrogen, and sulfur in lunar soils are reviewed. Carbon and nitrogen have a predominantly extra-lunar origin in lunar soils and breccias, while sulfur is mostly indigeneous to the Moon. The lunar processes which effect the movement, distribution, and evolution of carbon, nitrogen, and sulfur, along with the volatile alkali elements sodium, potassium, and rubidium during regolith processes are discussed. Possible mechanisms which may result in the addition to or loss from the Moon of these volatile elements are considered.     

Basaltic magmatism and the bulk composition of the moon

The lunar interior is comprised of two major petrological provinces: (1) an outer zone several hundred km thick which experienced partial melting and crystallization differentiation 4.4–4.6 b.y. ago to form the lunar crust together with an underlying complementary zone of ultramafic cumulates and residua, and (2) the primordial deep interior which was the source region for mare basalts (3.2–3.8 b.y.) and had previously been contaminated to varying degrees with highly fractionated material derived from the 4.4–4.6 b.y. differentiation event. In both major petrologic provinces, basaltic magmas have been produced by partial melting. The chemical characteristics and high-pressure phase relationships of these magmas can be used to constrain the bulk compositions of their respective source regions.Primitive low-Ti mare basalts (e.g., 12009, 12002, 15555 and Green Glass) possessing high normative olivine and high Mg and Cr contents, provide the most direct evidence upon the composition of the primordial deep lunar interior. This composition, as estimated on the basis of high pressure equilibria displayed by the above basalts, combined with other geochemical criteria, is found to consist of orthopyroxene + clinopyroxene + olivine with total pyroxenes > olivine, 100 MgO/(MgO + FeO) = 75–80, about 4% of CaO and Al₂O₃ and 2× chondritic abundances of REE, U and Th. This composition is similar to that of the earth's mantle except for a higher pyroxene/olivine ratio and lower 100 MgO/(MgO + FeO).The lunar crust is believed to have formed by plagioclase elutriation within a vast ocean of parental basaltic magma. The composition of the latter is found experimentally by removing liquidus plagioclase from the observed mean upper crust (gabbroic anorthosite) composition, until the resulting composition becomes multiply saturated with plagioclase and a ferromagnesian phase (olivine). This parental basaltic composition is almost identical with terrestrial oceanic tholeiites, except for partial depletion in the two most volatile components, Na₂ and SiO₂. Similarity between these two most abundant classes of lunar and terrestrial basaltic magmas strongly implies corresponding similarities between their source regions. The bulk composition of the outer 400 km of the Moon as constrained by the 4.6-4.4 b.y. parental basaltic magma is found to be peridotitic, with olivine > pyroxene, 100 MgO/ (MgO + FeO) 86, and about 2× chondritic abundances of Ca, Al and REE. The Moon thus appears to have a zoned structure, with the deep interior (below 400 km) possessing somewhat higher contents of FeO and SiO₂ than the outer 400 km. This zoned model, derived exclusively on petrological grounds, provides a quantitative explanation of the Moon's mean density, moment of inertia and seismic velocity profile.The bulk composition of the entire Moon, thus obtained, is very similar to the pyrolite model composition for the Earth's mantle, except that the Moon is depleted in Na (and other volatile elements) and somewhat enriched in iron. The similarity in major element composition extends also to the abundances of REE, U and Th. These compositional similarities, combined with the identity in oxygen isotope ratios between the Moon and the Earth's mantle, are strongly suggestive of a common genetic relationship.     

Paleocratering of the Moon: Review of post-Apollo data

As a result of the dating of lunar samples, we are in a position to utilize the lunar surface as a recorder of environmental conditions in the Earth-Moon neighborhood in the past. Plots of crater density vs rock age at different lunar landing sites can be used to date unexplored lunar provinces. These plots also demonstrate evolution in the population of planetesimals that struck the Moon. Prior to 4.1 aeons ago, the cratering rate on the Moon was at least 10³ times the present rate, and the rate declined with a half-life less than 8×10⁷ yr. During the interval from 4.1 to 3.2 aeons ago, the number of planetesimals showed an exponential decay with a half-life about 3×10⁸ yr, corresponding to sweep-up of particles from solar orbits somewhat similar to those of Apollo asteroids. A more nearly constant cratering rate applied in the last three aeons. These data indicate that the Moon displays at least the final stages of an ancient accretion process; they also set certain conditions on possible capture processes relating to the Moon's origin. Pre-Apollo expectations that the Moon would provide a Rosetta Stone for interpreting solar system history and planet formation thus appear justified.Paper given at Philadelphia meeting of American Association for Advancement of Science, December, 1971.     

Lunar Water: A Brief Review

One of the most exciting recent developments in the field of lunar science has been the unambiguous detection of water (either as OH or H₂O) or water ice on the Moon through instruments flown on a number of orbiting spacecraft missions. At the same time, continued laboratory-based investigations of returned lunar samples by Apollo missions using high-precision, low-detection, analytical instruments have for the first time, provided the absolute abundance of water (present mostly as structurally bound OH⁻ in mineral phases) in lunar samples. These new results suggest that the Moon is not an anhydrous body, questioning conventional wisdom, and indicating the possibility of a wet lunar interior and the presence of distinct reservoirs of water on the lunar surface. However, not all recent results point to a wet Moon and it appears that the distribution of water on the Moon may be highly heterogeneous. Additionally, a number of sources are likely to have contributed to the water inventory of the Moon ranging from primordial water to meteorite-derived water ice through to the water formed during the reaction of solar-wind hydrogen with the lunar soil. Water on the Moon has implications for future astrobiological investigations as well as for generating resources in situ during future exploration of the Moon and other airless bodies in the Solar System.     

An integrated approach to understanding Apollo 16 impact glasses: Chemistry,isotopes, and shape

Abstract The major‐ and minor‐element abundances were determined by electron microprobe in 1039 glasses from regoliths and regolith breccias to define the compositional topology of lunar glasses at the Apollo 16 landing site in the central highlands of the Moon. While impact glasses with chemical compositions similar to local materials (i.e., Apollo 16 rocks and regoliths) are abundant, glasses with exotic compositions (i.e., transported from other areas of the Moon) account for up to ?30% of the population. A higher proportion of compositionally exotic, angular glass fragments exists when compared to compositionally exotic glass spherules. Ratios of non‐volatile lithophile elements (i.e., Al, Ti, Mg) have been used to constrain the original source materials of the impact glasses. This approach is immune to the effects of open‐system losses of volatile elements (e.g., Si, Na, K). Four impact glasses from one compositionally exotic group (low‐Mg high‐K Fra Mauro; lmHKFM) were selected for ⁴⁰Ar/³⁹ Ar dating. The individual fragments of lmHKFM glass all yielded ages of ?3750 ± 50 Ma for the time of the impact event. Based on the petrography of these individual glasses, we conclude that the likely age of the impact event that formed these 4 glasses, as well as the possible time of their ballistic arrival at the Apollo 16 site from a large and distant cratering event (perhaps in the Procellarum KREEP terrain) (Zeigler et al. 2004), is 3730 ± 40 Ma, close to the accepted age for Imbrium.     

Fission and geosynchronous release of the Moon

The problem of the origin of the Moon has led to various hypotheses: simultaneous accretion, fission, capture, etc. These theories were based primarily on global mechanical considerations. New geological data (Turcotteet al., 1974; Kahn and Pompea, 1978) have led to fresh approaches and new versions of these theories.As suggested by Wise (1969) and O'Keefe (1972), the initial Earth may have taken unstable forms when radial segregation sped up the rotation. The Moon may have been created as the small part of the pyroid of Poincaré.Fission theory was mainly discarded, in the past, on the basis of energy considerations. We are now arriving at the conclusion that these considerations are void if the fission was followed by a very long period of geostationary rotation of the Moon at a distance of about 3 Earth radius (i.e., out of the Roche limit). Indeed the large amount of energy of the initial system could have been released slowly and therefore evacuated by losses of material and radiation.The accretion of the Earth and the radial segregation of heavy chemicals toward the center has led to a differential rotation of the different layers with a faster rotation at the center. During the geostationary period the Moon was synchronous with respect to the surface layer. That Earth-Moon system has both a correct angular momentum and a large stability provided that the viscosity of intermediate layers was small enough, which is in concordance with its high temperature.Even with a very hot system, a superficial cold layer appears because of its low conductivity and the radiation equilibrium with outer space. This implies a slow loss of energy: the geosynchronous Moon receded extremely slowly.During the geostationary period lithophile elements were extracted with water by the radial segregation and were deposited in the area facing the Moon. One massive continent was formed, as suggested by Grjebine (1978).As the continent became thicker and sank into the mantle, convection currents appeared and speeded up the cooling of the Earth. The viscosity increased and the synchronization between the Moon and the surface of the Earth became more difficult to maintain. When synchronism was broken important lunar tides transferred energy and momentum from the Earth to the Moon which receded toward its present position and the modification of its equilibrium shape explains the formation of lunar maria in the near side.Paper presented at the European Workshop on Planetary Sciences, organised by the Laboratorio di Astrofisica Spaziale di Frascati, and held between April 23–27, 1979, at the Accademia Nazionale del Lincei in Rome, Italy.