H2释放扰动电离层的数值模拟

由于电离层中分子性离子与电子的复合要比氧离子与电子的复合快得多,因此H2在电离层高度释放可有效地引起电子的消耗.本文基于一个包括中性气体扩散方程和离子化学反应方程的二维动力学模型,对H2在电离层高度释放过程进行了数值模拟研究,并分析了不同释放条件下的电子扰动特性.结果表明:1)500 mol H2释放后,迅速向周围空间扩散,释放中心处的电子密度30 s内下降了近4％,F2层临界频率下降了1％左右;2)在不同高度处释放H2时,最大的电子密度相对变化率并不是在峰值高度附近处释放时出现的;3)释放化学物质的量越多,电子密度的扰动幅度也越大,但两者之间并不存在线性关系;4)相同量的H2在电离层峰值高度处释放,白天的电子密度扰动幅度要大于夜间的扰动幅度.     

电磁波在电离层的传播特性研究

研究了折射率n与电子数浓度N_e及高度h之间的关系,并通过数值模拟对电子数浓度的高度剖面和折射率随高度的变化规律进行了分析.将模拟和实际观测出的频高图进行对比,发现在高电离层模拟值与实际值较相近,在低电离层则由于非线性关系及E_s层存在的效应,模拟值与实际值有较大的误差.     

[Bmin][BF4]+AMP复合溶液捕集温室气体CO2

采用基于离子液体[Bmin][BF₄]+AMP作为捕集CO₂的复合溶液,在膜吸收-热再生循环装置上,研究了该复合溶液捕集CO₂的过程和传质性能;通过阻力层传质模型,比较了预测值与实验值.结果表明：在相同条件和较高负载下,复合溶液具有较高的传递推动力和更高的传质系数;模型预测值和实验值符合较好,平均误差为12.8%.实验证明复合溶液的传质性能优于单一溶液.     

东亚地区二氧化碳体积分数变化特征

利用2004年以来东亚地区10个本底观测站大气φ(CO₂)观测资料,分析了各站大气φ(CO₂)的变化特征及其各站之间的差异,讨论了下垫面特征、源汇作用等对φ(CO₂)变化的影响.结果表明:10个本底站大气月均φ(CO₂)有明显的季节变化,高值多出现在冬春等寒冷季节,而低值则多出现在6—9月,属于北半球的夏季;大气φ(CO₂)日变化趋势较为一致,15时(当地时间)前后达到全天最低,随后φ(CO₂)升高,并在日落后继续积累,至清晨7时(当地时间)前后达到全天最高,之后φ(CO₂)随着太阳辐射的增强而逐渐降低,且平均φ(CO₂)水平与下垫面植被量成反比,φ(CO₂)日变化的幅度与下垫面植被量成反比.作为全球基准站之一的瓦里关山站,2004—2008年φ(CO₂)年均值逐年增加,年增长率为2.28×10^-6/a.     

不确定奇异系统的时滞相关鲁棒H∞滤波器设计

为了设计出全阶的滤波器,同时使得滤波误差动态系统是正则的、无脉冲的,并且满足一定的H_∞性能指标,研究了连续奇异系统的全阶H_∞滤波器的设计问题.利用Lyapunov-Krasovskii泛函及二次型的积分不等式方法获得了滤波误差动态系统的H_∞性能时滞相关的判据,给出了奇异系统的鲁棒H_∞滤波器存在的时滞依赖的充分条件.最后的数值例子说明了该方法的有效性.     

西安市PM2.5城乡差异及与城市热岛的关联研究

依据一种基于建筑用地比例和土地利用信息熵的城乡站点划分方法,将西安市环境与气象站点划分为城区、郊区和两类乡村站,讨论其PM_2.5的城乡分布特征及与城市热岛效应强度(Urban Heat Island Intensity,UHII)间的相关关系。结果表明,不同季节西安市呈现不同的PM_2.5城乡分布特征和日变化特征,两类乡村站点PM_2.5差异明显且下风向乡村站点(乡村D)对应的UHII_D对城区和乡村的影响程度大于上风向乡村站点(乡村U)对应的UHII_U。在城区较多本地排放的影响下,乡村PM_2.5浓度与 UHII_U(或UHII_D)相关系数均大于城区。随着UHII_D的增加,城乡PM_2.5相对浓度差值(RUPII_D)整体呈下降趋势且UHII_D与RUPII_D在春夏秋季显著负相关。UHII_D增大,城区近地面PM_2.5的水平扩散能力减弱,但PM_2.5的垂直扩散能力较乡村更强,从而UHII_D通过影响PM_2.5的传输扩散特征,进一步影响西安市RUPII_D。     

福建三明市春季PM2.5中有机碳、元素碳和水溶性离子特征分析

2014年3月13日至4月20日在福建三明市利用PM_2.5中流量采样器采集大气中PM_2.5膜样品,测定了PM_2.5的质量浓度,并用热/光碳分析仪和离子色谱分析了其组分变化特征.结果表明,三明市观测期间PM_2.5的平均质量浓度为73.61±0.73 μg/m³,有机碳(OC)和元素碳(EC)的平均质量浓度分别为7.26±1.00和5.63±0.27 μg/m³,水溶性离子中SO₄^2-、NH₄⁺、NO₃^-和Na⁺的质量浓度分别为18.08±12.19、4.18±3.56、2.77±1.16和2.73±0.23 μg/m³,总和占总水溶性离子的87.76%.结合后向轨迹分析了福建三明市的污染物来源特征.该地区OC/EC的平均比值小于2,SOC(二次有机碳)生成量很少,主要以一次有机污染物为主,OC、EC与K⁺的相关性分析表明OC、EC与K⁺的来源相近,可以判断OC、EC绝大部分来源是生物质燃烧产生的污染物.在水溶性离子分析中,观测期间NO₃^-/SO₄^2-为0.159±0.02,表明三明市主要以固定源为主,机动车辆等移动源贡献较少.     

武汉市冬季灰霾期PM2.5中水溶性无机离子的特征

2018年1月,利用颗粒物采样器采集武汉市大气PM_2.5样品并进行水溶性无机离子（F^-、Cl^-、NO₃^-、SO₄^2-、Na⁺、NH₄⁺、K⁺、Mg²⁺、Ca²⁺）的分析.结果表明,NO₃^-、SO₄^2-、NH₄⁺是PM_2.5中最主要的3种水溶性无机离子,除Mg²⁺与Ca²⁺外,PM_2.5与WSⅡs （水溶性无机离子）之间的相关性显著,且移动源贡献占主导地位.阴阳离子平衡表明武汉市冬季灰霾期PM_2.5呈中性或弱酸性.通过混合单粒子拉格朗日综合轨迹模式模拟并采用分层聚类得出了4种主要的后向气流轨迹及相应的PM_2.5和水溶性离子浓度,结果表明区域传输对此次灰霾期影响较大.     

雷暴闪电放电活动对电离层影响的研究进展

雷暴中的闪电放电能够产生强静电场以及电磁辐射场,从而对空间电离层产生重要影响,引起电离层电子密度分布的扰动。研究表明:闪电放电引起电离层扰动的方式有两种:直接耦合和间接耦合。其中,直接耦合主要来自于闪电产生的准静电场及电磁场的作用,在甚低频 (VLF) 反射信号上表现出快VLF事件, 而间接耦合主要是闪电低频电磁波在传播过程中与磁层相互作用,在辐射带产生闪电诱导电子沉降 (LEP) 现象。雷暴闪电活动能够改变电离层从D层到F层的电子密度分布,影响对流层大气和电离层之间的场,导致中高层瞬态放电淘气精灵 (elves) 及红闪 (sprite) 等现象的激发。闪电VLF传输反射信号可用于反演电离层密度的变化,目前已成为一种探测电离层扰动的常用方法,而引起电离层扰动的强度不但和闪电放电参量密切相关,也和闪电放电过程、类型有关。该文重点阐述了闪电放电与电离层直接耦合和间接耦合作用以及导致的相关现象。     

H2O/CO2污染对煤油燃料超声速燃烧影响数值研究

在纯净空气与H₂O/ CO₂污染空气来流对比试验结果基础上,采用数值计算方法和化学动力学方法,研究了H₂O和CO₂污染组分对煤油燃料超声速燃烧的影响,获得了试验手段难以得到的燃烧室流场参数和性能数据。完成了相应的煤油燃料超声速燃烧室二维数值计算,其中匹配了进口总温、总压、马赫数、氧气摩尔分数和工作当量油气比。将数值计算结果与相应试验测量值进行了对比分析,并结合燃烧室流场数据、性能参数分析了H₂O和CO₂污染的动力学影响、以及对燃烧室性能的影响。研究表明:(1)数值计算结果与实验测量值总体上吻合,两种手段均体现了纯净空气来流时不同煤油当量油气比的燃烧室性能,并反映了一致的“污染效应”影响趋势;(2) H₂O污染、H₂O+ CO₂污染的存在降低了煤油燃料超声速燃烧室性能,体现在燃烧诱导压升、燃烧效率、流向冲量增量的下降,而且随着污染组分含量的增加,燃烧室性能下降越加显著。      

电离层时空变化效应对星载及月基SAR成像影响:现状与展望

合成孔径雷达（SAR）作为一种主动传感器,具备全天时、全天候的观测能力,已广泛应用于对地观测中.然而,无线电信号在空间传播过程中会不可避免地受到电离层效应的影响,导致信号的相位、幅度发生变化,使得工作在电离层之上的SAR系统的成像性能受到干扰.本文分别从法拉第旋转、背景电离层和电离层不规则体三个方面介绍了电离层效应对不同轨道SAR系统成像性能的影响,并总结了电离层效应的补偿修正方案.最后,给出了电离层效应对星载和月基SAR成像影响的一些亟待解决的问题,以促进星载和月基SAR成像的发展及应用.     

Measurements of Trace Substances in the Arctic Troposphere as Potential Precursors and Constituents of Arctic Haze

During two measuring campaigns in early spring 1994 and 1995 (March/April) and one campaign in summer 1994, measurements of ozone, PAN, sulfur dioxide, nitric acid, and particulate nitrate, sulfate, and ammonium (only 1995) were recorded in the Arctic. Observations were made by aircraft at various sites in the eastern and western Arctic. Ozone concentrations showed a steady increase with altitude both in spring and summer. During five flights in springtime, low ozone events (LOEs) could be observed near the surface and up to altitudes of 2000 m. SO₂ background concentrations, ranging from detection limit (0.5 nmol/m³) to 5 nmol/m³, were observed during both spring and summer. Distinct maxima up to 55 nmol/m³ in lower altitudes were only obtained in springtime. Concentrations of the organic nitrate PAN were within a similar range as those of the inorganic nitrate HNO₃ during spring campaigns. In contrast, concentrations of particulate nitrate were one half an order of magnitude lower. HNO₃ concentrations increased significantly with altitude. Evidently, HNO₃ was intruded from the stratosphere into the troposphere. Sulfate concentrations ranged between 5 and 30 nmol/m³; ammonium concentrations were obtained within a range from 10 to 50 nmol/m³.     

Measurements of stratospheric HO2 and NO2 by matrix isolation and ESR spectroscopy

Vertical profiles of stratospheric HO₂ and NO₂ concentrations were determined using matrix isolation and ESR. Up to 10 different samples per flight were collected in situ by a balloon borne cryosampler. Free radicals and trace constituents which are condensable at 68 K are trapped in a polycristalline H₂O or D₂O matrix. After collection, the samples are stored at a temperature below 83 K until they are analysed in the laboratory by X-band ESR spectroscopy at 4 K. The HO₂ and NO₂ were identified and calibrated by comparison with standard samples collected in the laboratory under typical stratospheric sampling conditions. From several flights over Southern France (44°N) we obtained two profiles of the stratospheric NO₂ mixing ratio. One, from 21 October 1982, agrees well with previous measurements. The other, from 8 October 1981, is lower by one order of magnitude. The few HO₂ data obtained around 35 km altitude agree with previous measurements. An isolated measurement at 17 km altitude is one order of magnitude higher than the model predicted HO₂ concentration.     

Ballon-borne and aircraft infrared measurements of ethane (C2H6) in the upper troposphere and lower stratosphere

Quantitative infrared measurements of ethane (C₂H₆) in the upper troposphere and lower stratosphere are reported. The results have been obtained from the analysis of absorption features of the ₉ band at 12.2 m, which have been identified in high-resolution ballon-borne and aircraft solar absorption spectra. The ballon-borne spectral data were recorded at sunset with the 0.02 cm^-1 resolution University of Denver interferometer system from a float altitude of 33.5 km near Alamogordo, New Mexico, on 23 March 1981. The aircraft spectra were recorded at sunset in July 1978 with a 0.06 cm^-1 resolution interferometer aboard a jet aircraft at 12 km altitude, near 35°N, 96°W. The balloon analysis indicates the C₂H₆ mixing ratio decreased from 3.5 ppbv near 8.8 km to 0.91 ppbv near 12.1 km. The results are consistent with the colum value obtained from the aircraft data.     

The impact of high altitude aircraft on the ozone layer in the stratosphere

The paper discusses the potential effects on the ozone layer of gases released by the engines of proposed high altitude supersonic aircraft. The major problem arises from the emissions of nitrogen oxides which have the potential to destroy significant quantities of ozone in the stratosphere. The magnitude of the perturbation is highly dependent on the cruise altitude of the aircraft. Furthermore, the depletion of ozone is substantially reduced when heterogeneous conversion of nitrogen oxides into nitric acid on sulfate aerosol particles is taken into account in the calculation. The sensitivity of the aerosol load on stratospheric ozone is investigated. First, the model indicates that the aerosol load induced by the SO₂ released by aircraft is increased by about 10–20% above the background aerosols at mid-high latitude of the Northern Hemisphere at 15 km for the NASA emission scenario A (the NASA emission scenarios are explained in Tables I to III). This increase in aerosol has small effects on stratospheric ozone. Second, when the aerosol load is increased following a volcanic eruption similar to the eruption of El Chichon (Mexico, April 1982), the ozone column in spring increases by as much as 9% in response to the injection of NO _x from the aircraft with the NASA emission scenario A. Finally, the modeled suggests that significant ozone depletion could result from the formation of additional polar stratospheric clouds produced by the injection of H₂O and HNO₃ by the aircraft engines.     

Mean flux estimation and cospectra of airborne carbon dioxide and water vapour eddy flux measurements in the planetary surface layer

CO₂ and H₂O eddy-flux measurements derived from airborne vertical wind and concentration data are examined to determine the accuracy of the eddy-flux estimate in moderately unstable conditions within the surface layer. Integral scale estimation is used to determine the minimum length of a sample required to achieve a given accuracy. Cospectral analysis is used to examine the scales responsible for the transport of water vapour and carbon dioxide in the surface layer. Cospectra are found to broaden as the sampling altitude increases, a well known result. At low altitudes, the cospectrum is found to become negative for large scales. A significant fraction of the flux is carried by this range of scales, which suggests that scales larger than the boundary-layer height may play an important role in the transport at low altitudes.     

Magnetic and ionospheric storms

Summary The characteristic ionospheric storm variation of F₂ Layer ionisation at a temperate latitude station is described and compared with corresponding effects at other latitudes. The well known marked variability of the F₂ Layer critical frequency is attributed, in part, to the operation of the ionospheric storm mechanism. The lack of correlation between variations of F₂ ionisation at two sites, at a considerable distance apart, is due to the fact that ionospheric storm manifestation is found to vary, in sign and magnitude, with geomagnetic latitude, and is also subject to a diurnal control determined by local time.

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Zusammenfassung Die charakteristische Ionosphärensturmvariation der Ionisation der F₂-Schicht an einer Station der gemäßigten Breite wird beschrieben und mit entsprechenden Vorgängen in anderen Breiten verglichen. Die bekannte eindeutige Veränderlichkeit der kritischen Frequenz der F₂-Schicht wird teilweise der Wirkung des Mechanismus der Ionosphärenstürme zugeschrieben. Das Fehlen einer Korrelation zwischen den Variationen der F₂-Schicht an zwei in beträchtlicher Entfernung voneinander gelegenen Orten erklärt sich aus der Tatsache, daß das Auftreten der Ionosphärenstürme nach Vorzeichen und Ausmaß mit der geomagnetischen Breite variiert und außerdem einem ortszeitlich bedingten Tageseinfluß unterliegt.

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Résumé On décrit la variation la variation caractéristique d'ionisation de la couche F₂ lors des tempêtes ionosphériques observées à une station de latitude moyenne et on la compare aux phénomènes analogues à d'autres latitudes. La variabilité marquée et bien connue de la fréquence critique de la couche F₂ est partiellement attribuée au mécanisme des tempêtes ionosphériques. L'absence de corrélation entre les variations de la couche F₂ en deux endroits considérablement éloignés l'un de l'autre s'explique par le fait que l'apparition des tempêtes ionosphériques varie en signe et en intensité avec la latitude

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With 4 figures.

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Dedicated to Professor Dr.H. Benndorf on the occasion of his eightieth birthday.