低温酸性条件下白钨矿的不一致溶解动力学

在75℃和pH=1.04～2.46时采用间歇型实验方法测定了天然白钨矿在HCl溶液中的溶解速率,揭示了溶解反应的动力学机理。结果表明,Ca的释放速率随反应时间保持稳定,并随pH降低而增大。W的释放行为则更为复杂,在反应初期与Ca呈一致溶解,之后由于钨酸表面层(中间产物)的形成,W的释放量和释放速率明显下降。这说明白钨矿的溶解作用由早期的表面化学反应转变为化学反应-扩散控制过程,从而导致W、Ca呈不一致溶解。pH越小,不一致溶解出现的时间越早。酸性溶液中白钨矿的溶解速率方程为v=k[H+]n,以W和Ca计算的速率常数k分别为0.65×10-5mol/m2s和1.04×10-5mol/m2s,反应级数n则分别为1.20和1.26。结合他人研究结果,白钨矿的溶解反应相对于H+可能为一级反应。     

Dissolution Precipitation Wave Structure of Hydrothermal Ore Zoning

Ｄｉｓｓｏｌｕｔｉｏｎ　Ｐｒｅｃｉｐｉｔａｔｉｏｎ　Ｗａｖｅ　Ｓｔｒｕｃｔｕｒｅ　ｏｆＨｙｄｒｏｔｈｅｒｍａｌ　Ｏｒｅ　Ｚｏｎｉｎｇ￥ＹｕＣｈｏｎｇｗｅｎ（ＦａｃｕｌｔｙｏｆＥａｒｔｈＳｃｉｅｎｃｅｓ，ＣｈｉｎａＵｎｉｖｅｒｓｉｔｙｏｆＧｅｏｓｃｉｅ...     

紫硫镍矿交代镍黄铁矿的水热反应机理及动力学

本工作首次在实验室条件下对浅生区紫硫镍矿(Ni,Fe)3S4交代镍黄铁矿(Ni,Fe)9S8水热反应的机理及动力学进行了研究。起始反应矿物采用高纯自然镍黄铁矿,合成纯镍黄铁矿或合成镍黄铁矿-磁黄铁矿集合体。反应pH值采用0.2M醋酸-醋酸纳缓冲溶液控制在3～5的范围内。反应进程由X-射线衍射物相定量分析及扫描电镜观察进行跟踪。结果表明,当反应温度恒定在80℃时,交代20(4)%的镍黄铁矿需792h。相同条件下加入少量H2S可将反应速率提高一倍。当反应在125℃饱和蒸汽压水热环境下进行时,完全交代纯镍黄铁矿需约168h。此过程由于磁黄铁矿的存在而被催化,交代集合体中的镍黄铁矿仅需68h,进一步反应磁黄铁矿被交代成白铁矿。磁黄铁矿的催化作用可能源于溶解产生的微裂纹加速了流体的传质过程。当反应温度升高至145℃时,速率反而下降,不遵循Arrhenius经验规律。动力学分析得80℃速率常数介于5.8×10-8～3.0×10-7/s之间,125℃及145℃速率常数分别介于2.8×10-6～2.08×10-5/s及1×10-6～5.1×10-6/s之间,远高于同温度下固相扩散反应的速率常数,表明该反应在地质时标上为一快速反应。此外,用背散射电子显微技术对矿物表面形貌进行了分析,发现交代产物紫硫镍矿具有颗粒细小及存在微裂纹等特征,与自然界浅生矿床中的紫硫镍矿非常相似;电镜实验还表明该交代作用是一个典型的耦合溶解-再沉淀反应。其耦合机制的驱动力可能与反应界面处微空隙对流体饱和度的控制有关。     

Kinetics of Hydrothermal Reactions of Minerals in Near-critical and Supercritical Water

This work presents new experimental results on the kinetics of mineral dissolution in near-critical and supercritical water in a temperature range (T) from 25 to 400℃ and a constant pressure of 23 MPa. Kinetic experiments were carried out by using a flow reactor (packed bed reactor) of an open system. The dissolution rates of albite and magnetite were measured under these experimental conditions. Na, Al and Si release rates for albite dissolution in water were measured as a function of the temperature and flow velocity in the reaction system. The maximum release rates of Na, AI and Si of albite dissolution in the hydrothermal flow systems under different flow velocities were always obtained at 300℃, that is to say, the maximum albite dissolution rates in the flow systems, regardless of different flow rates, were repeatedly measured at 300℃. Results indicate a wide fluctuation in albite dissolution rates occurring close to the critical point of water. The dissolution rates increased when the temperatu     

塔中地区奥陶系海相碳酸盐岩储层的溶解动力学特征

选取塔中地区奥陶系海相碳酸盐岩样品进行了模拟实验,以研究其在表生岩溶作用下的溶解动力学特征.实验分别在30,50℃下,用pH值为3～6的盐酸溶液,恒温水浴加热进行.结果表明:4种样品溶解速率的相对大小依次为:灰白色灰岩＞砂屑灰岩＞粗晶白云岩＞中粗-细晶白云岩,且溶解速率均随着温度的升高而增大,随着pH值的增大而减小.但随着外界环境的变化,溶解速率的变化略有差异.造成这种差异的原因可能是样品中的硅酸盐杂质、晶体颗粒的大小以及实验过程中产生的CO2的影响.由实验结果推测可知,对于塔中地区以表生岩溶作用为主形成的奥陶系海相碳酸盐岩储层,灰岩储层的储集性能可能优于白云岩储层;对于以埋藏岩溶作用为主形成的奥陶系海相碳酸盐岩储层,白云岩储层的储集性能可能优于灰岩储层.     

Dissolution and precipitation processes in deformed amphibolites: an example from the ductile shear zone of the Ryoke metamorphic belt, SW Japan

The granitic mylonite zone in the Cretaceous Ryoke metamorphic belt contains deformed amphibolites as thin layers. The amphibolite layers do not exhibit pinch‐and‐swell or boudinage structures, even when contained in a high‐strain granitic mylonite. This mode of occurrence suggests that they were deformed as much as the surrounding granite mylonite. In the highly deformed zone, strongly foliated amphibolites contain Ti‐rich brown amphibole porphyroclasts rimmed by Ti‐poor green amphibole, titanite and chlorite. These porphyroclasts are elongated, forming shear surfaces defined by preferential distribution of the chlorite and titanite. Porphyroclastic plagioclase in the strongly foliated amphibolites consists of two components: an anorthite‐rich core and an anorthite‐poor rim. Based on these observations, the mass‐balanced reaction occurring during deformation is defined as As the reaction products form a weak interconnected matrix, the strain rate of the amphibolites may be controlled by the rate of dissolution–precipitation through fluids. Weakly foliated amphibolites in the low‐strain zone exhibit cataclastic microstructures, whereas the strongly foliated amphibolites do not exhibit such features. These microstructural and chemical changes suggest that high‐strain amphibolites were initially deformed by cataclasis, followed by deformation through metamorphic reactions. During the metamorphism/deformation, old plagioclase grains with high X_an were not stable and dissolved, and new plagioclase grains with low X_an crystallized at the old plagioclase rim. Dissolution of old plagioclase and precipitation of new plagioclase occurred normal to and parallel to the foliation, respectively, reflecting incongruent pressure solution due to differential stress and changes in P–T–H₂O conditions. The development of incongruent pressure solution is attributed to increased fluid flux in the strongly foliated amphibolites, as evidenced by the greater abundance of hydration‐reaction products in the strongly foliated amphibolites than in the weakly foliated ones.     

Numerical Simulation of Hydrothermal Alteration Chemical Reactions During Ore-forming Process of the Jiaojia Gold Deposit,Jiaodong Peninsula,China;

The Jiaojia gold deposit is featured by obvious alteration zonation, and is one of the typical altered-type gold deposits in the Jiaodong gold province. However, the formation conditions of hydrothermal alteration zonation and the spatial location of chemical reaction associated with gold precipitation are still unclear. To quantitatively discuss the hydrothermal process, we used the TOUGHREACT software to simulate the chemical reactions between ore-bearing fluids and wall rocks of the Jiaojia gold deposit. First, we constructed a conceptual mineralization model related to hydrothermal alteration by discussing the chemical reaction between ore-bearing fluids and wall rocks. Subsequently, we simulated the chemical equilibrium concentration of ore-forming fluids and pH changes under different temperature and pressure conditions, which was used to study the dissolution and precipitation mechanism of hydrothermal minerals during ore-forming processes. The simulation results show that the chemical equilibrium concentration of Au+ significantly decreased with temperature from 280 ℃ to 180 ℃, and the chemical equilibrium concentration of Fe2+ showed similar trend, indicating that the favorable gold metallogenic temperature range is 180 ℃ to 280 ℃, and Fe2+ in ore-forming fluids reacts with [Au(HS)2]− to promote gold precipitation. The temperature and pressure conditions influence the chemical equilibrium concentrations of ore elements, nevertheless, temperature is a more critical factor controlling gold precipitation, while the influence of pressure is relatively weak. The pH simulation results show that the pH values of ore-forming fluids increased during the hydrothermal alteration reaction, which means that the ore-forming environment changes from acidic to neutral and/or alkaline. The pH variation during the ore-forming process is consistent with conventional geological observations, and thus validated the simulation results. The above results indicate that the temperature driving lateral migration of ore-forming fluids along the fault resulted in the continuous overprinting alteration. The pyrite-sericite-quartz alteration in the footwall of the fault zone is conducive to gold precipitation and enrichment due to frequent overprinting of various alteration and changes of temperature and pH. © 2023 Science Press. All rights reserved.     

Geology and Hydrothermal Alteration of the Low Sulfidation

Abstract. The Pantingan Gold System (PGS) is a vein-type epithermal prospect exposed within the summit caldera of Mount Mariveles, Bagac, Bataan (Luzon), Philippines. It consists of nine major veins, eight of which trend NW-WNW and distributed in an en echelon array. The eastern tips of these veins appear to terminate near the NE-NNE trending Vein 1, which is located in the easternmost portion of the prospect. Metal assay results on vein and wall rock samples indicate concentrations of 0.01 to 1.1 g/ton Au, trace to 34 g/ton Ag and 0.003 to 0.02 % Cu. Andesite lava flow deposits host the PGS. Potassium-Argon isotopic dating of these andesites yields anarrow age range of 0.88± 0.13 to 1.13 ± 0.17 Ma. The surface exposures of the veins (up to 5 m wide) are encountered at different levels between 590–740 masl. These commonly display a massive texture although banding prominently occurs in Vein 1. The veins consist of gray to cream-colored crystalline and chalcedonic quartz and amorphous silica. Pyrite is the most ubiquitous sulfide mineral. It occurs either as fine-grained disseminations and aggregates in quartz or as infillings in vugs. Calcite, marcasite and bornite are also occasionally noted in the deposit. The prospect shows silicic, argillic, propylitic and advanced argillic alteration zones. Silicic and argillic alterations are confined in the immediate wall rocks of the quartz veins. Argillic alteration grades to a propylitic zone farther away from the veins. The advanced argillic alteration zone, indicated by a suite of acidic clay minerals that include kaolin-ite, dickite, pyrophyllite and alunite, might have been imprinted during the late stages of gold deposition. As a whole, the PGS displays geological and mineralogical features typical of gold mineralization in a low sulfidation, epithermal environment. It is also representative of a young, tectonically undisturbed gold deposit.     

内蒙古迪彦钦阿木钼矿区热液矿化蚀变分带建模-基于Surpac软件

本文应用了近红外光谱分析技术(BJKF-1型便携式近红外矿物分析仪)及Gemcom Surpac三维地质建模软件;通过近红外光谱分析技术,对迪彦钦阿木矿区Ⅲ号矿带勘查钻孔中提取的岩石样品进行测试,并结合野外编录情况,将钻孔中岩石的蚀变类型主要划分为青磐岩化、泥化和绢英岩化。结合该矿区以往地质工程勘查资料,应用加拿大Gemcom Surpac三维地质建模软件,通过距离幂次反比法,将蚀变信息转化为数字参数并取代传统的品位数据,建立了矿体的蚀变块体模型,划分出了斑岩型矿床特有的蚀变分带。根据在矿区划分的蚀变分带,表明斑岩型矿化的蚀变中心位于矿区东南和西南部,推断导致成矿的斑岩侵入体很可能位于矿区东南和西南方位的深部。迪彦钦阿木矿区的工作结果表明,基于Gemcom Surpac实现的矿区三维蚀变分带建模可以很好的圈定热液矿化蚀变分带,解释并找出指向斑岩型矿化-蚀变中心的指示标志,判断矿化中心,为确认矿床类型提供了直接证据,并对进一步的勘探具有重要参考意义。     

A Model for Alteration Zoning of Hydrothermal Mineralization Based on Surpae Software for the Diyanqinamu Mo Mine District, Inner Mongolia

本文应用了近红外光谱分析技术（BJKF一-型便携式近红外矿物分析仪）及GemcomSur—pac三维地质建模软件;通过近红外光谱分析技术,对迪彦钦阿木矿区Ⅲ号矿带勘查钻孔中提取的岩石样品进行测试,并结合野外编录情况,将钻孔中岩石的蚀变类型主要划分为青磐岩化、泥化和绢英岩化。结合该矿区以往地质工程勘查资料,应用加拿大GemcomSurpac三维地质建模软件,通过距离幂次反比法,将蚀变信息转化为数字参数并取代传统的品位数据,建立了矿体的蚀变块体模型,划分出了斑岩型矿床特有的蚀变分带。根据在矿区划分的蚀变分带,表明斑岩型矿化的蚀变中心位于矿区东南和西南部,推断导致成矿的斑岩侵入体很可能位于矿区东南和西南方位的深部。迪彦钦阿木矿区的工作结果表明,基于GemcomSurpac实现的矿区三维蚀变分带建模可以很好的圈定热液矿化蚀变分带,解释并找出指向斑岩型矿化一蚀变中心的指示标志,判断矿化中心,为确认矿床类型提供了直接证据,并对进一步的勘探具有重要参考意义。     

伊犁京希—伊尔曼德金矿床的热液蚀变及成矿流体演化特征

京希－伊尔曼德金矿床的热液蚀变在空间上有明显的分带性，中心蚀变带以强烈的硅化为主，典型的蚀变矿物组合为石英或玉髓和地开石，中间带为高级泥化带，以地开石－高岭石－石英或玉髓为特征；外带为以蒙脱石－高岭石－伊利石－其他粘土矿物等矿物组合为主的泥化带，蚀变强度和矿物组合的分带性是温度、压力和化学梯度的反映，是流体在不断的水或流体－岩石反应和成分交换的产物。该矿床成矿流体演化过程为：早期酸性（pH=2-3)含矿流体在沿断裂上升过程中，受围岩灰岩中的流体（pH为中性）缓冲，在其进入高渗透性的碎屑岩层时，流速和水－岩石或流休－岩石反应大大加快，并在与大气降水的混合作用下，pH值逐步升高（3－5），产生了流体的温度及成分梯度，在温度和压力迅速下降的条件下，金及蚀变矿物沉淀、结晶生长，形成了蚀变空间分带，中心带保存完好的多孔状石英和地开石等高级泥化矿物组合说明该矿床是高硫化热液体系作用下的产物。     

热液成矿作用的一般动力学方程

分析了热液成矿作用的基本特点和研究现状，推导出热液成矿作用动力学体系的一般方程，并着重讨论了方程中表征热液与围岩之间化学反应的速率项，除目前一般采用动力学实验实测反应速率常数外，作者根据局域平衡原理，认为成矿作用可视为体系内各点随着温度和压力的变化不断重建平衡的过程，可用温度和压力变化时成矿反应的平衡常数的变化速度表征成矿反应的动力学行为，成矿化学反应的速率还可用主要成矿物质的溶解的变化率来表征。     

滇东北矿集区昭通铅锌矿区蚀变岩分带及元素迁移特征

围岩蚀变是昭通铅锌矿床的重要找矿标志。通过对矿区760中段98勘探线剖面实测、蚀变岩分带研究、岩石地球化学迁移特征与参数计算,指出围岩蚀变与成矿的关系：热液蚀变分带明显,在蚀变中心,黄铁矿化最强,方解石化、白云石化次之,硅化较弱,黄铁矿化与矿化关系密切;远离矿体,黄铁矿化逐渐减弱,而方解石化、白云石化逐渐增强。强黄铁矿化和强黄铁矿化-强方解石化-强硅化粗晶白云岩蚀变组合是重要的找矿标志。从细晶白云岩带到强黄铁矿化带,元素整体呈迁入形式,主要为与Zn-Pb成矿作用有关的元素,如Ge、Ag、Cd等迁入;同时伴随成矿流体作用,亲铁元素及铁明显富集,显示不同蚀变岩相受热液改造作用影响。蚀变指数（I_A）的大小,与矿化强弱呈正相关关系,I_A大,则矿化强。     

青西凹陷下白垩统湖相喷流岩成因探讨及其意义

青西凹陷下白垩统泥云岩 (泥质白云岩、白云质泥岩、白云岩,统称“泥云岩”)以其富含泥级钠长石、石英、铁白云石和重晶石等特殊矿物成分为特点。从构造、沉积、岩石学等方面对青西凹陷下白垩统泥云岩进行了地质分析,指出泥云岩的成因与湖底热水喷流有关。     

鲕粒灰岩的溶解动力学特征和微观形貌的发育演化

鲕粒灰岩是重要的碳酸盐岩油气储层。通过常温常压下,北京西山鲕粒灰岩的溶解动力学实验发现,鲕粒灰岩的溶解主要受岩石和矿物的结构和化学成分控制。结构上表现为构造裂缝、鲕粒结合纹、颗粒晶体结合带等结构薄弱带优先发生溶蚀。成分上表现为白云岩化组分不仅自身较易溶蚀,而且能促进鲕粒灰岩的整体溶解;粘土矿物、石英等杂质组分常与鲕粒和白云岩化颗粒伴生,其对两者的阻溶效应更大。溶解过程中,鲕粒灰岩的构造裂隙、鲕粒放射结合纹和同心圈层等首先发生溶蚀,产生溶隙、粒内溶孔和粒间溶孔;其次为白云质组分以及白云质组分与方解石结合处而产生晶间溶孔、粒内溶孔;随着溶蚀强度的加强,围绕鲕粒形成环状溶蚀沟,在鲕粒溶蚀脱落后而形成鲕模孔。     

Geological and Geochemical Characteristics of the Hydrothermal Clay Alteration in South Korea

Abstract: Hydrothermally altered areas forming pyrophyllite‐kaolin‐sericite‐alunite deposits are distributed in Chonnam and Kyongsang areas, Cretaceous volcanic field of the Yuchon Group. The Chonnam alteration area is located within depression zone which is composed of volcanic and granitic rocks of late Cretaceous age. The clay deposits of this area show the genetic relationship with silicic lava domes. The Kyongsang alteration area is mainly distributed within Kyongsang Basin comprising volcanic, sedimentary and granitic rocks of Cretaceous and Tertiary age. Most of the clay deposits of this area are closely related to cauldrons. Paleozoic clay deposit occurs in the contact zone between Precambrian Hongjesa granite gneiss and Paleozoic Jangsan quartzite of Choson Supergroup. Cretaceous igneous rocks of the both alteration areas belong to high K calc‐alkaline series formed in the volcanic arc of continental margin by subduction‐related magmatism. Chonnam igneous rocks show more enrichment of crustal components such as K, La, Ce, Sm, Nd and Ba, higher (La/Yb)cn ratio, and higher initial ⁸⁷Sr/⁸⁶Sr ratio (0. 708 to 0. 712) than those of Kyongsang igneous rocks. This might be due to the difference of degree of crustal contamination during Cretaceous magmatism. The most characteristic alteration minerals of Chonnam clay deposits are alunite, kaolin, quartz, pyrophyllite and diaspore which were formed by acidic solution. Those of Kyongsang clay deposits are sericite, quartz and pyrophyllite which were formed by weak acid and neutral solution. The formation ages of the clay deposits of two alteration areas range from 70. 1 to 81. 4 Ma and 39. 7 to 79. 4 Ma, respectively. The Daehyun clay deposit in Ponghwa area of Kyongsang province shows the alteration age range from 290 to 336 Ma. This result shows the different alteration episode from the hydrothermal alteration of Cretaceous to early Tertiary in the Kyongsang and Chonnam alteration areas. These data indicate, at least, three hydrothermal activities of Tertiary (middle to late Eocene), late Cretaceous (Santonian to Maastrichtian) and Paleozoic Carboniferous Periods in South Korea.     

Hydrothermal Alteration and Fluid Geochemistry of the Tongonan Geothermal Field, Philippines

Abstract: The alteration mineralogy, the present-day fluid chemistry, and some fluid inclusion data are used to make inferences on the chemical changes that have occurred in the fluids during the history of the Tongonan Geothermal Field. Thermal activity in the Tongonan area began in the Miocene when emplacement of many plutons forming a batholith contact metamorphosed the overlying volcanics to hornblende hornfels assemblages. In the early Pliocene, when tectonic uplift occurred along the Philippine Fault, about 2 mole % of mainly carbon dioxide and sulfur gas was released to a geothermal fluid and condensed in groundwater with geothermal steam. The condensate intensely altered the reservoir rock and formed an acid mineral assemblage, which was overprinted by a later, lower temperature, neutral-pH assemblage. Some chlorite, epidote and illite in the reservoir rock formed at temperatures up to 100°C lower than present-day temperatures possibly during the Plio-Pleistocene uplift period, i.e., the system was heating up. The assemblage garnet-anhydrite formed in fractures from a condensate after the gas had nearly completely separated from the deep, CO₂-rich fluid during vigorous boiling possibly during hydrothermal eruptions. The output of gas to the geothermal fluid decreased, while the salinity (10,000 mg/kg or - 2 wt% NaCl) and the temperature of the geothermal fluid remained nearly constant throughout the Quaternary. When this neutral-pH, alkali chloride fluid boiled, it initially precipitated albite or epidote on the rims then anhydrite at the center of fractures at high temperatures (-250–300°C). At lower temperatures (-150–250°C), adularia or wairakite and later calcite were deposited as the proportion of gas in the steam condensate increased. The origin of solutes is also discussed.     

Geology and Hydrothermal Alteration of the Milyang Pyrophyllite Deposit, Southeast Korea

Abstract: The Milyang pyrophyllite deposit, which is embedded in the Late Cretaceous Yuchon Group of the Kyongsang Supergroup, is one of the largest hydrothermal clay deposits in the Kyongsang basin, southeast Korea. Host rocks of the deposit are porphyritic andesite lava and minor andesitic lapilli tuff. In the Milyang district, a hydrothermally altered zone is about 2 × 3 km in extent; we can recognize the concentric arrangement of advanced argillic, propylitic, and sericitic alteration zones from the central to peripheral parts of the zone. The Milyang pyrophyllite deposit forms a part of the advanced argillic alteration zone. The Milyang pyrophyllite deposit is subdivided into the following four zones based on mineral assemblages: the pyrophyllite zones 1, 2, 3, and the silicified zone. The pyrophyllite zone 1, which occupies the central part of the deposit, comprises mainly pyrophyllite, kaolinite, and diaspore without quartz. Diaspore nodules often concentrate in beds 40–50 cm thick. Andalusite, dumortierite, and tourmaline locally occur as network veins, crack‐filler, or small spherulitic spots. The Al₂O₃ content of the ore ranges from 27 to 36 wt%. The pyrophyllite zone 2, which constitutes a major part of the deposit, comprises mainly pyrophyllite, kaolinite, and quartz. The Al₂O₃ content of the ore ranges from 15 to 24 wt%. The pyro‐phyllite zone 3 is the hematite‐rich marginal facies of the deposit. The silicified zone, which occurs as beds and septa, is mostly composed of quartz with minor pyrophyllite and kaolinite; the SiO₂ contents range from 79 to 90 wt%. Comparing chemical compositions of the high‐Al ores with those of unaltered host andesite, the Fe, Ca, alkalis, HFSE, and HREE contents are significantly depleted, whereas S, B, As, Sr, and LREE are enriched. The hydrothermal alteration of the Milyang pyrophyllite deposit can be classified into the following four stages: 1) extensive sericitic and propylitic alteration, 2) medium‐temperature (200–250°C) advanced argillic alteration, 3) high‐temperature (250–350°C or more) advanced argillic alteration, and 4) retrograde low‐temperature alteration. The heat and some volatile components such as B and S would be derived from the Pulguksa Granite intruded underneath the deposit.     

25～75℃酸性NaCl溶液中方铅矿的溶解动力学

在25～75℃、pH=0.43～2.45的1mol/LNaCl溶液中进行了方铅矿的溶解动力学实验。发现在远平衡条件下,方铅矿的溶解速率r与氢离子活度犤H+犦呈线性关系,溶解速率方程(速率定律)为:r=k犤H+犦,即对H+而言,溶解反应为一级。其中速率常数k为2.344×10-7mol/m2·s(25℃)、1.380×10-6mol/m2·s(50℃)、7.079×10-6mol/m2·s(75℃)。溶解反应的活化能为43.54kJ/mol,方铅矿的溶解机理为表面化学反应,速率决定步骤为表面配合物的离解。