Effective collision strengths for fine-structure forbidden transitions among the 2s22p3 levels of Ne iv

Effective collision strengths for electron-impact excitation of the N-like ion Ne  iv are calculated in the close-coupling approximation using the multichannel R-matrix method. Specific attention is given to the 10 astrophysically important fine-structure forbidden transitions among the ⁴S^o, ²D^o and ²P^o levels in the 2s²2p³ ground-state configuration. The expansion of the total wavefunction incorporates the lowest 11 LS eigenstates of Ne  iv , consisting of eight n  = 2 terms with configurations 2s²2p³, 2s2p⁴ and 2p⁵, together with three n  = 3 states of configuration 2s²2p²3s. We present in graphical form the effective collision strengths obtained by thermally averaging the collision strengths over a Maxwellian distribution of velocities, for all 10 fine-structure transitions, over the range of electron temperatures log T (K) = 3.6 to log T (K) = 6.1 (the range appropriate for astrophysical applications). Comparisons are made with the earlier, less sophisticated close-coupling calculation of Giles, and excellent agreement is found in the limited temperature region where a comparison is possible [log T (K) = 3.7 to log T (K) = 4.3]. At higher temperatures the present data are the only reliable results currently available.     

Effective collision strengths for forbidden transitions among the 3s23p3 fine-structure levels of Cl IIIIII

Effective collision strengths for the 10 astrophysically important fine-structure forbidden transitions among the ⁴S^o, ²D^o and ²P^o levels in the 3s²3p³ configuration of Cl  iii are presented. The calculation employs the multichannel R-matrix method to compute the electron-impact excitation collision strengths in a close-coupling expansion, which incorporates the lowest 23 LS target eigenstates of Cl  iii . These states are formed from the 3s²3p³, 3s3p⁴, 3s²3p²3d and 3s²3p²4s configurations. The Maxwellian-averaged effective collision strengths are presented graphically for all 10 fine-structure transitions over a wide range of electron temperatures appropriate for astrophysical applications [log  T (K)=3.3−log  T (K)=5.9]. Comparisons are made with the earlier seven-state close-coupling calculation of Butler & Zeippen, and in general excellent agreement is found in the low-temperature region where a comparison is possible [log  T (K)=3.3−log  T (K)=4.7]. However, discrepancies of up to 30 per cent are found to occur for the forbidden transitions which involve the ⁴S^o ground state level, particularly for the lowest temperatures considered. At the higher temperatures, the present data are the only reliable results currently available.     

Effective collision strengths for fine-structure forbidden transitions among the 3s23p4 levels of Cl ii

The ab initio R -matrix method is used to calculate effective collision strengths for electron-impact excitation of the sulphur-like ion Cl  ii in the close-coupling approximation. All 10 astrophysically important fine-structure forbidden transitions within the 3s²3p⁴     ,     ,     ground configuration levels are considered. The 12 lowest LS target states are included in the calculation. Effective collision strengths are obtained by averaging the electron collision strengths over a Maxwellian distribution of electron velocities. Results are presented for electron temperatures in the range  log  T (K)=3.3  to  log  T (K)=5.5  , appropriate for astrophysical applications. These are the only effective collision strength data that are currently available.     

Electron impact excitation of the ground-state 3P fine-structure levels in atomic oxygen

Fine-structure collision strengths are calculated for transitions between the ground-state levels of atomic oxygen. The R -matrix method is used in which the (2p⁴) ³P, ¹D and ¹S terms are included as well as three pseudo-states chosen to represent the dipole polarizability of the ³P ground state. Very sophisticated configuration–interaction wavefunctions are used for the target states and a recoupling transformation to pair coupling is applied to the inner-region Hamiltonian matrix, with the ³P fine-structure energy levels being adjusted to match the observed splitting prior to diagonalization. Effective collision strengths are obtained by integrating over a Maxwellian distribution and the rate coefficient of the cooling of electron gas is determined. The cooling rates are significantly lower than those currently available, in confirmation of the result deduced from measurements of the Earth's ionosphere electron gas.     

Anomalous mixing of the w2Po3/2 and x6Po3/2 levels in Fe ii

The neighbouring lines a ⁶D_5/2– x ⁶P^o_3/2 (1272.617 Å) and a ⁶D_5/2– w ²P^o_3/2 (1272.657 Å) have been observed in the UV spectrum of χ Lupi to be of comparable intensity. The latter, Δ S  = 2, transition would be expected to be very weak. The two upper states should display negligible mixing. We give a detailed, quantitative discussion of how the two upper states are in fact strongly mixed through their mixing with 3d⁶(³D)4p ⁴P^o_3/2, and hence we explain the relative strengths of the two UV lines.     

Calculated spectra for HeH+ and its effect on the opacity of cool metal-poor stars

The wavelength and Einstein A coefficient are calculated for all rotation–vibration transitions of  ⁴He¹H⁺, ³He¹H⁺, ⁴He²H⁺  and  ³ He²H⁺  , giving a complete line list and the partition function for  ⁴HeH⁺  and its isotopologues. This opacity is included in the calculation of the total opacity of low-metallicity stars and its effect is analysed for different conditions of temperature, density and hydrogen number fraction. For a low helium number fraction (as in the Sun), it is found that HeH⁺ has a visible but small effect for very low densities  (ρ≤ 10⁻¹⁰ g cm⁻³)  , at temperatures around 3500 K. However, for high helium number fraction, the effect of HeH⁺ becomes important for higher densities  (ρ≤ 10⁻⁶ g cm⁻³)  , its effect being most important for a temperature around 3500 K. Synthetic spectra for a variety of different conditions are presented.     

H3+ in diffuse interstellar gas

A model is constructed of the material in front of the star Cygnus OB2 no. 12 in which dense cores are embedded in diffuse clumps of gas. The model reproduces the measured abundances of C₂ and CO, and predicts a column density of 910¹⁰ cm² for HCO⁺.     

3s23p–3s3p2 transitions in S iv

We use both the civ3 and mchf codes to calculate oscillator strengths of allowed and intercombination lines in the  3s²3p–3s3p²  multiplets. Valence, core–valence and some core–core correlation effects are included. The two approaches give results in excellent agreement. Core effects are particularly important for the intercombination lines, though relatively minor for allowed transitions.
We obtain a branching ratio of 1.42 with an estimated accuracy of 0.02 for the     transitions, compared with an experimental value of  1.12±0.1  . The A -values of the     intercombination lines are substantially different from those of previous calculations.     

State-to-state rotational transition rates of the HCO+ ion by collisions with helium

The rates of rotational transitions for HCO⁺, the most abundant ion in interstellar space, induced by collision with helium are obtained for temperatures ranging from 10 to 80 K. The calculations are based on a new potential energy surface for the He–HCO⁺ interaction and on a scattering matrix whose accuracy was checked by pressure broadening and shift measurements. The rates     decrease for increasing values of j and  Δ j   , with a temperature trend depending on the energy involved in the transitions: if it is small, the rates are almost constant, while an increase with T is found for other cases. Comparison with previous and less accurate results shows an agreement within 50 per cent. Comparison between state-to-state and pressure broadening cross-sections allows us to discuss importance and influence of elastic and inelastic collisions.     

Effective collision strengths for fine-structure forbidden transitions among the 3s23p3 levels of K v

In wind-fed X-ray binaries the accreting matter is Compton-cooled and falls freely on to the compact object. The matter has a modest angular momentum l and accretion is quasi-spherical at large distances from the compact object. Initially small non-radial velocities grow in the converging supersonic flow and become substantial in the vicinity of the accretor. The streamlines with l >( GMR ∗)^1/2 (where M and R ∗ are the mass and radius of the compact object) intersect outside R ∗ and form a two-dimensional caustic which emits X-rays. The streamlines with low angular momentum, l <( GMR ∗)^1/2, run into the accretor. If the accretor is a neutron star, a large X-ray luminosity results. We show that the distribution of accretion rate/luminosity over the star surface is sensitive to the angular momentum distribution of the accreting matter. The apparent luminosity depends on the side from which the star is observed and can change periodically with the orbital phase of the binary. The accretor then appears as a 'Moon-like' X-ray source.     

H2 emission from shocks in molecular outflows: the significance of departures from a stationary state

We have computed the time dependence of the H₂ rovibrational emission spectrum from molecular outflows. This emission arises in shock waves generated by the impact of jets, associated with low-mass star formation, on molecular gas. The shocks are unlikely to have attained a state of equilibrium, and so their structure will exhibit both C- and J-type characteristics. The rotational excitation diagram is found to provide a measure of the age of the shock; in the case of the outflow observed in Cepheus A West by the ISO satellite, the shock age is found to be approximately 1.5×10³ yr. Emission by other species, such as NH₃ and SiO, is also considered, as are the intensities of the fine-structure transitions of atoms and ions.     

SN 1988Z: spectro-photometric catalogue and energy estimates★

We present a spectro-photometric catalogue of the evolution of supernova 1988Z, which combines new and published observations in the radio, optical and X-ray bands, with the aim of offering a comprehensive view of the evolution of this object and deriving the total energy radiated since its discovery. The major contribution to the total radiated energy comes at optical to X-ray frequencies, with a total emission of at least 2×10⁵¹ erg (for H₀=50 km s⁻¹ Mpc⁻¹) in 8.5 yr. A model-dependent extrapolation of this value indicates that the total radiated energy may be as high as 10⁵² erg. The high value of the radiated energy supports a scenario in which most of the kinetic energy of the ejecta is thermalized and radiated in a short interaction with a dense circumstellar medium of nearly constant density. In this sense, 1988Z is not a supernova but a young and compact supernova remnant.     

Ultra-high-resolution observations of circumstellar K i and C2 around the post-AGB star HD 56126

We have used the Ultra-High-Resolution Facility (UHRF) at the AAT, operating at a resolution of 0.35 km s⁻¹ (FWHM), to observe K  i and C₂ absorption lines arising in the circumstellar environment of the post-AGB star HD 56126. We find three narrow circumstellar absorption components in K  i , two of which are also present in C₂. We attribute this velocity structure to discrete shells resulting from multiple mass-loss events from the star. The very high spectral resolution has enabled us to resolve the intrinsic linewidths of these narrow lines for the first time, and we obtain velocity dispersions ( b -values) of 0.2–0.3 km s⁻¹ for the K  i components, and 0.54±0.03 km s⁻¹ for the strongest (and best defined) C₂ component. These correspond to rigorous kinetic temperature upper limits of 211 K for K  i and 420 K for C₂, although the b -value ratio implies that these two species do not co-exist spatially. The observed degree of rotational excitation of C₂ implies low kinetic temperatures ( T _k≈10 K) and high densities ( n ≈10⁶ to 10⁷ cm⁻³) within the shell responsible for the main C₂ component. Given this low temperature, the line profiles then imply either mildly supersonic turbulence or an unresolved velocity gradient through the shell.     

Stability of C60 and C70 fullerenes toward corpuscular and γ radiation

The stability of C₆₀ and C₇₀ fullerenes in the interstellar medium deposited on dust surface or embedded in meteorites and comets has been simulated with γ irradiation and with He⁺ ion bombardment. It is shown by vibrational spectroscopy that a γ radiation dose of 2.6 MGy (1 Gy = 1 joule absorbed energy per kilogram) causes partial oligomerization of both C₆₀ and C₇₀ fullerenes. Oligomers are made by fullerene cages chemically connected each other which can yield back free fullerenes by a thermal treatment. The amount of irreversibly polymerized fullerenes caused by 2.6 MGy as deduced as the toluene insoluble fraction has been determined as 1.7 and 15 per cent by weight, respectively, for C₆₀ and C₇₀ fullerene. The radiation dose generated by radionuclides decay and expected to be delivered to fullerenes buried at a depth of more than 20 m in comets and meteorites is about 3 MGy per 10⁹ yr. Since fullerenes are by far resistant to such radiation dose they can survive for at least some billion years inside comets and meteorites and in fact have been detected inside certain carbonaceous chondrites. On the other hand, the direct exposure of fullerenes to cosmic rays for instance when they are adsorbed or deposited on the surface of carbon dust corresponds to the delivery of a radiation dose comprised between 30 and 65 MGy per 10⁹ yr. Experimental bombardment of both C₆₀ and C₇₀ fullerenes for instance with He⁺ ions has shown that the complete amorphization occurs at about 250 MGy. Thus in ∼4 Gyr exposure to cosmic rays it is expected a complete amorphization.     

Class II maser candidates in substituted methanol: CH3OD, 13CH3OH, CH318OH and CH3SH

We investigate the possibility of interstellar masers in transitions of the methanol isotopomers CH₃OD, ¹³CH₃OH and CH₃¹⁸OH, and of CH₃SH. The model used, in which masers are pumped through the first and second torsionally excited states by IR radiation, has accounted successfully for the Class II masers in main species methanol, ¹²CH₃¹⁶OH. Several potential maser candidates are identified for CH₃OD, their detectability depending on the enrichment of this species in star-forming regions. In ¹³CH₃OH and CH₃¹⁸OH the best maser candidates are direct counterparts of the well-known 6.7- and 12.2-GHz methanol masers, but the lower interstellar abundance of these substituted species means that the expected brightness is greatly reduced. The maser candidates in CH₃SH are also weak. By comparing these species we find that the large b -component of the dipole moment in methanol plays a significant role in its propensity to form masers, as does the strong torsion–rotation interaction due to the light hydroxyl frame. Thus the exceptional brightness of interstellar methanol masers is due to a favourable combination of molecular properties as well as high interstellar abundance.     

C-type shocks in the interstellar medium: profiles of CH+ and CH absorption lines

We have computed optical absorption-line profiles of CH⁺ and CH, as predicted by a model of a C-type shock propagating in a diffuse interstellar cloud. Both these species are produced in the shock wave in the reaction sequence that is initiated by C⁺(H₂, H)CH⁺. Whilst CH⁺ flows at the ion speed, CH, which forms in the dissociative recombination reaction CH⁺₃(e⁻, H₂)CH, flows at a speed which is intermediate between those of the ions and the neutrals. The predicted velocity shift between the CH⁺ and CH line profiles is found to be no more than approximately 2 km s⁻¹, which is smaller than has previously been assumed. We also investigate OH and HCO⁺, finding that the correlation between their column densities, recently observed in the diffuse interstellar medium, can be reproduced by the model.     

Carbon abundances and 12C/13C from globular cluster giants

The behaviour of the  Δν= 2 CO  bands around 2.3 μm was examined by comparing observed and synthetic spectra in stars in globular clusters of different metallicity. Changes in the ¹²C/¹³C isotopic ratio and the carbon abundances were investigated in stars from 3500–4900 K in the galactic globular clusters M71, M5, M3 and M13, covering the metallicity range from −0.7 to −1.6. We found relatively low carbon abundances that are not affected by the value of oxygen abundance. For most giants, the ¹²C/¹³C ratios determined are consistent with the equilibrium value for the CN cycle. This suggests complete mixing on the ascent of the red giant branch, in contrast to the substantially higher values predicted across this range of parameters by the current generation of models. We found some evidence for a larger dispersion of ¹²C/¹³C in giants of M71 of metallicity  [μ]=[M/H]=−0.7  in comparison with the giants of M3, M5 and M13, which are more metal deficient. Finally, we show evidence for lower ¹²C/¹³C in giants of globular clusters with lower metallicities, as predicted by theory.     

A search for CO+ in planetary nebulae

We have carried out a systematic search for the molecular ion CO⁺ in a sample of eight protoplanetary and planetary nebulae in order to determine the origin of the unexpectedly strong HCO⁺ emission previously detected in these sources. An understanding of the HCO⁺ chemistry may provide direct clues for the physical and chemical evolution of planetary nebulae. We find that the integrated intensity of the CO⁺ line may be correlated with that of HCO⁺, suggesting that the reaction of CO⁺ with molecular hydrogen may be an important formation route for HCO⁺ in these planetary nebulae.     

Radiative transitions of the helium atom in highly magnetized neutron star atmospheres

Recent observations of thermally emitting isolated neutron stars revealed spectral features that could be interpreted as radiative transitions of He in a magnetized neutron star atmosphere. We present Hartree–Fock calculations of the polarization-dependent photoionization cross-sections of the He atom in strong magnetic fields ranging from 10¹² to 10¹⁴ G. Convenient fitting formulae for the cross-sections are given along with the related oscillator strengths for various bound–bound transitions. The effects of finite nucleus mass on the radiative absorption cross-sections are examined using perturbation theory.