Aluminum incorporation in α-PbO2 type TiO2 at pressures up to 20 GPa

Aluminum incorporation into the high pressure polymorph of TiO₂ with the structure of α-PbO₂ has been studied from 10 to 20 GPa and 1300 °C by XRD, high-resolution ²⁷Al MAS-NMR and TEM. Al-doped α-PbO₂ type TiO₂ can be recovered at atmospheric pressure. Al₂O₃ solubility in α-PbO₂ type TiO₂ increases with increasing the synthesis pressure. The α-PbO₂ type TiO₂ polymorph is able to incorporate up to 35 wt.% Al₂O₃ at 13.6 GPa and 1300 °C, being the substitution of Ti⁴⁺ by Al³⁺ on normal octahedral sites the mechanism of solubility. The transition to the higher pressure TiO₂ polymorph with the ZrO₂ baddeleyite structure, Akaogiite, has not been observed in the quenched samples at room pressure. The microstructure of the recovered sample synthesized at 16 GPa and 1300 °C points to the existence of a non-quenchable aluminum titanium oxide phase at these conditions.     

A potential experiment for in-situ measurement of atmospheric temperature and atomic oxygen density in the 90–150 km altitude range by a Raman Lidar

The Raman backscatter cross sections for a 355 nm light source for the three fine-structure components are calculated. The signal-to-noise considerations show that the determination of the densities of the three fine-structure components separately is a feasible experiment. Since these fine-structure components are calculated to be in local thermodynamic equilibrium up to at least 350 km altitude, this experiment also gives atmospheric temperature. It is pointed out that this experiment does not suffer from the drawbacks of the previous efforts to determine atomic oxygen density and should yield reliable results for this density as well as temperature.     

A temperature-dependent multi-relaxation spectroscopic dielectric model for thawed and frozen organic soil at 0.05–15 GHz

A dielectric model for thawed and frozen Arctic organic-rich soil (50% organic matter) has been developed. The model is based on soil dielectric measurements that were collected over ranges of gravimetric moisture from 0.03 to 0.55 g/g, dry soil density from 0.72 to 0.87 g/cm³, and temperature from 25 to −30 °C (cooling run) in the frequency range of 0.05–15 GHz. The refractive mixing dielectric model was applied with the Debye multi-relaxation equations to fit the measurements of the soil’s complex dielectric constant as a function of soil moisture and wave frequency. The spectroscopic parameters of the dielectric relaxations for the bound, transient bound, and unbound soil water components were derived and were complimented by the thermodynamic parameters to obtain a complete set of parameters for the proposed temperature-dependent multi-relaxation spectroscopic dielectric model for moist soils. To calculate the complex dielectric constant of the soil, the following input variables must be assigned: (1) density of dry soil, (2) gravimetric moisture, (3) wave frequency, and (4) temperature. The error of the dielectric model was evaluated and yielded RMSE_ε′ values of 0.348 and 0.188 for the soil dielectric constant and the loss factor, respectively. These values are on the order of the dielectric measurement error itself. The proposed dielectric model can be applied in active and passive microwave remote sensing techniques to develop algorithms for retrieving the soil moisture and the freeze/thaw state of organic-rich topsoil in the Arctic regions.     

A 90,000–200,000 yrs marine tephra record of Italian volcanic activity in the Central Mediterranean Sea

A detailed tephrochronological study was undertaken in three deep-sea cores collected in the Tyrrhenian and Ionian Seas. The age and the origin of the marine tephra were inferred from oxygen isotope records of foraminifera and from major element compositions of glass-shards. Seventy-one eruptions were detected in the time interval 90,000–200,000 yrs during which the volcanoes of the Roman and Campanian regions and of the southern Italy were in activity. This is attested by the consistency of the geochemical compositions of both marine and terrestrial deposits. Most of the marine tephra consisted in trachytes and phonolites characterizing a Roman and Campanian origin. Several tephra were proposed as key-horizons for proximal and distal sediments. Among them, one tephra originating from Mount Etna (149,300 yrs) and five tephra from Pantelleria island (130,000 yrs, 163,600 yrs, 192,500 yrs, 197,400 yrs and 198,400 yrs) were northerly dispersed. Several other key horizons originated from the Campanian or Roman provinces were detected as far as 1000 km from the vents.     

A new electrical and mechanically detonatable shear wave source for near surface (0–30 m) seismic acquisition

We present a new, impulsive, horizontal shear source capable of performing long shot profiles in a time-efficient and repeatable manner. The new shear source is ground-coupled by eight 1/2″ (1.27 cm) × 2″ (5.08 cm) steel spikes. Blank shotshells (12-gauge) used as energy sources can be either mechanically or electrically detonated. Electrical fuses have a start time repeatability of < 50 μs. This source can be operated by a single individual, and takes only ~ 10 s between shots as opposed to ~ 30 s for six stacked hammer blows. To ensure complete safety, the shotshell holder is surrounded by a protective 6″ (15.24 cm)-thick barrel, a push-and-twist-locked breach, and a safety pin.We conducted field tests at the 17th Street Canal levee breach site in New Orleans, Louisiana (30.017° N 90.121° W) and at an instrumented test borehole at Millsaps College in Jackson, Mississippi (32.325° N 93.182° W) to compare our new source and a traditional hammer impact source. The new shear source produces a broader-band of frequencies (30–100 Hz cf. 30–60 Hz). Signal generated by the new shear source has signal-to-noise ratios equivalent to ~ 3 stacked hammer blows to the hammer impact source. Ideal source signals must be broadband in frequency, have a high SNR, be consistent, and have precise start times; all traits of the new shear source.     

The 4-emission-core structure of dayside aurora oval observed by all-sky imager at 557.7 nm in Ny-Ålesund,Svalbard

A survey of dayside aurora excitation at 557.7 nm, which was acquired from an all-sky imager at Yellow River Station in Ny-Ålesund, Svalbard, shows that there are 4 intense emission maxima in the dayside oval, centered near 0630/76, 0830/76, 1400/75, and 1600/75 (unit: MLT/MLAT), respectively. Tracing the magnetospheric sources of these cores along geomagnetic field lines, the 0830- and 1400-MLT cores correspond with the prenoon and postnoon magnetospheric boundary layers (MBLs), and the 0630- and 1600-MLT cores are located at the dusk and dawn MBLs, respectively. The potential solar wind-magnetosphere dynamic processes resulting in these auroral features are discussed.     

A high-resolution quartz OSL chronology of the Talede loess over the past ∼30 ka and its implications for dust accumulation in the Ili Basin,Central Asia

Similar to the loess deposits on the Chinese Loess Plateau (CLP), a reliable chronology plays also an important role in revisiting past climate and environment changes recorded by the loess in Central Asia. Previously, a few luminescence and ¹⁴C ages, mainly covering the last glacial, were obtained for several loess sections in Central Asia, which are often controversial. Until now, there is still a lack of reliable high-resolution chronologies covering the late Pleistocene, especially the Holocene. Here, the fine-grained (4–11 μm) quartz single-aliquot regenerative-dose (SAR) optically stimulated luminescence (OSL) dating protocol is used to establish a detailed chronology of the uppermost part (∼5 m) of Talede loess in the Ili Basin Central Asia. Conventional tests of the SAR protocol and the general luminescence characteristics indicate that this protocol is suitable for dating the Talede loess. Finally, 15 closely-spaced quartz OSL ages, ranging from 0.72 ± 0.05 to 28.9 ± 2.12 ka and with no reversals, were obtained. Consistent with previous studies in the Ili Basin, two of the three ¹⁴C ages show discrepancy when compared with quartz OSL ages for the Talede loess section. The constructed OSL chronology of the Talede loess reveals that the dust accumulation is rapid during marine isotope stage (MIS) 2, especially during the Last Glacial Maximum (LGM), and is also continuous during the Holocene, with the dust accumulation rate exhibiting a relatively low level and an increasing trend. Comparison of the dust accumulation at Talede with that at other sites in the Ili Basin indicates that the rapid dust accumulation during the LGM is not universal, and the slow dust accumulation during the Holocene is probably true for the entire Ili Basin. Comparison of different grain sized quartz OSL ages from Central Asian loess show characteristics of both consistency and inconsistency, which needs to be further investigated.     

Induced Magnetization of Magnetite-titanomagnetite in Alternating Fields Ranging from 400 A/m to 80,000 A/m; Low-field Susceptibility (100 – 400 A/m) and Beyond

For remanence-bearing minerals (RBM) such as magnetite-titanomagnetite, susceptibility to induced magnetism (M) measured in alternating fields (H _AC ) is field-dependent. However, for fields ≤ 400 A/m, measured in an AC induction coil instrument (at 19,100 Hz), susceptibility k ₀ = M/H _AC is sufficiently linear to provide a reproducible rock (or mineral) magnetic characteristic and its anisotropy may be related to arrangements of minerals in rock, or for single mineral grains to their crystalline or shape anisotropy. For any remanence-bearing mineral at higher fields k _HF (= M/H _AC ) is not constant and the term susceptibility is not normally used. This study bridges the responses between traditional low-field susceptibility measurements and those due to high applied fields, for example when studying hysteresis or saturation magnetization of RBM. Where |k _HF | is measured in alternating fields that peak significantly above 400 A/m the M(H _AC ) relation is forced to follow a hysteresis loop in which |k _HF | > k ₀ for small |H _AC | and where |k _HF | decreases to zero for very large fields that achieve saturation magnetization. Hysteresis nonlinearity is due to remanence acquired with one field direction requiring a reverse field for its cancellation. We investigate the transition from initial, traditional “low-field” susceptibility (k ₀ ) measurements at 60 A/m, through 24 different fields from 400 A/m to 40,000 A/m (for very high k ₀ to 80,000 A/m). This reveals M(H _AC ) dependence beyond from conventional k ₀ through the range of hysteresis behavior in fields equal to and exceeding that required to achieve saturation magnetization (M _S ). We show k _HF increases with peak H _AC until the peak field is slightly less than saturation magnetization in natural rock samples rich in magnetite (TM₀ = Fe₃O₄) and TM₆₀ (Fe_2.4Ti_0.6O₄). All sample suites predominantly contain multidomain grains with subordinate pseudo-single domain and single-domain grains. k/k ₀ increases by ≤ 5% for fields up to 2 kA/m. Above 4 kA/m k/ k ₀ increases steeply and peaks, usually between 24 kA/m and 30 kA/m where all grains magnetic moments are activated by H _AC since this exceeds the coercive force of most grains. For higher peak H _AC , k/k ₀ declines sharply as increased H _AC values more effectively flip M with each field-direction switch, leading to the low gradient at distal portions of the hysteresis loop. For M₀-TM₆₀ bearing rocks, susceptibility peaks for fields ~12 kA/m and for magnetite rich rocks up to 24 kA/m. These values are approximately 10% of saturation magnetizations (M _S ) reported for the pure minerals from hysteresis DC field measurements. Both the field at peak k/k ₀ and the peak k/k ₀ value appear to be controlled by the dominant domain structure; multidomain behavior has larger k/k ₀ peaks at lower H _AC . Stacked k/k ₀ versus H _AC curves for each sample suite (n = 12 to n = 39) were successfully characterized at the 95% level by a polynomial fit that requires the cubic form k/k ₀ = a + bH + cH ² + dH ³. Thus, for most M-TM bearing rocks, susceptibility and anisotropy of susceptibility (AMS) measurements made on different instruments would be sufficiently precise for most geological applications, if peak alternating fields are ≤700 A/m.     

Changes in phytoplankton production and upwelling intensity off A Coruña (NW Spain) for the last 28 years

Ocean Dynamics - The analysis of a 28-year-long (1989–2016) series of monthly measurements of chlorophyll concentrations and primary production rates at a shelf station off A Coruña (NW...     

A collaborative study on temperature diurnal tide in the midlatitude mesopause region (41°N, 105°W) with Na lidar and TIMED/SABER observations

The na lidar-observed temperature diurnal tidal perturbations, based on full-diurnal-cycle observations from 2002 to 2008, are compared with tidal wave measurements by the TIMED/SABER instrument to elucidate the nature of diurnal tidal-period perturbations observed locally. The diurnal amplitude and phase profiles deduced by the two instruments are in very good agreement most of the year. However, the lidar-observed diurnal amplitudes during winter months and early spring are considerably larger than SABER observations, leading to the existence of a significant amplitude maximum of 12 K near 90 km in February and a different seasonal structure of temperature diurnal amplitude from the two instruments. The lidar-observed diurnal phase shows propagating wave characteristics during equinoctial months, but exhibit “evanescent wave” behavior in winter months, whereas SABER diurnal tidal phase exhibits propagating diurnal tidal character all year long with small seasonal variation. This anomalous tidal characteristic from the lidar observations repeats almost every winter. The exact mechanism behind this tidal feature is not fully understood, therefore further investigation and more experimental observations are necessary.     

Equatorial electrojet plasma irregularities observed during late afternoon by the 30 MHz coherent scatter radar in São Luís,Brazil

Coherent scatter radar observations conducted right before twilight by the 30 MHz radar in São Luís (Brazil) during both quiet (December 10, 2001) and disturbed (December 12, 2001) conditions detected type I echoes on the shoulders of broad type II spectra (near zero Doppler velocity). Zonal electric fields inferred from the São Luís ionosonde have a larger magnitude during the period where these spectral observations were made than on December 18, 2001 when type I echoes were not observed during late afternoon. The IMF B_z and AE index indicate that the extended geomagnetic disturbance in the afternoon of December 12, 2001 has allowed the interaction between disturbance dynamo and prompt penetration electric fields. The latter electric field component could have exceeded the former to give rise to the observed electric fields, and make possible observation of type I echoes.     

A 20 ka sediment record from the Hajar Mountain range in N-Oman,and its implication for detecting arid–humid periods on the southeastern Arabian Peninsula

Playa-like sediments from the Hajar Mountain range in northern Oman (22.83°N, 59.00°E; 1050 m asl) document variations of the paleoenvironmental and paleoclimate conditions over the last 20 ka. Based on high-resolution sediment sampling and their OSL dating, sedimentation rates were calculated and used as a proxy for paleorainfall. The results show that the Glacial to Lateglacial was characterized by arid conditions with a following transitional period of even less rainfall. At 10.5 ka, sedimentation rates increases abruptly, indicating the onset of the early Holocene humid period (EHHP). Rainfall reaches its maximum at 9–8 ka (EHHP-2) and a decreasing sedimentation rate after 8 ka characterizes the arid period of the middle to late Holocene. Variations of the hydrological regime are associated with the intensity of the boreal summer Indian monsoon and its related position of the ITCZ. For the onset of the EHHP, a northerly shift of the ITCZ is postulated, thus confirming earlier results from the southern Arabian Peninsula.     

Experimental studies of melt-peridotite reactions at 1–2 GPa and 1250–1400°C and their implications for transforming the nature of lithospheric mantle and for high-Mg signatures in adakitic rocks

Experiments of the melt-peridotite reaction at pressures of 1 and 2 GPa and temperatures of 1250–1400°C have been carried out to understand the nature of the peridotite xenoliths in the Mesozoic high-Mg diorites and basalts of the North China Craton,and further to elucidate the processes in which the Mesozoic lithospheric mantle in this region was transformed.We used Fuxin alkali basalt,Feixian alkali basalt,and Xu-Huai hornblende-garnet pyroxenite as starting materials for the reacting melts,and lherzolite xenoliths and synthesized harzburgite as starting materials for the lithospheric mantle.The experimental results indicate that:(1)the reactions between basaltic melts and lherzolite and harzburgite at 1–2 GPa and 1300–1400°C tended to dissolve pyroxene and precipitate low-Mg#olivine(Mg#=83.6–89.3),forming sequences of dunite-lherzolite(D-L)and duniteharzburgite(D-H),respectively;(2)reactions between hornblende-garnet pyroxenite and lherzolite at 1 GPa and 1250°C formed a D-H sequence,whereas reactions at 2 GPa and 1350°C formed orthopyroxenite layers and lherzolite;and(3)the reaction between a partial melt of hornblende-garnet pyroxenite and harzburgite resulted in a layer of orthopyroxenite at the boundary of the pyroxenite and harzburgite.The reacted melts have higher MgO abundances than the starting melts,demonstrating that the melt-peridotite reactions are responsible for the high-Mg#signatures of andesites or adakitic rocks.Our experimental results support the proposition that the abundant peridotite and pyroxenite xenoliths in western Shandong and the southern Taihang Mountains might have experienced multiple modifications in reaction to a variety of melts.We suggest that melt-peridotite reactions played important roles in transforming the nature of the Mesozoic lithospheric mantle in the region of the North China Craton.     

Temporal variations of C,N, δC,and δN in organic matter collected by a sediment trap at Cuenca Alfonso,Bahía de La Paz,SW Gulf of California

To monitor the composition and the vertical flux of particulate matter from the sea surface, a sediment trap was moored in Cuenca Alfonso, Bahía de La Paz, a zone of high productivity in the southwestern Gulf of California. Carbonate-free samples from 2002 to 2005 were analyzed for C_org, N, δ¹³C, and δ¹⁵N. The results show seasonal and interannual variability, with the δ¹³C and δ¹⁵N values larger in spring and summer than in fall and winter. The C:N ratio and δ¹³C increased by 1.5 units from 2002 to 2003–2005, suggesting a change in the supply of organic matter and-or the use or preferential degradation of N_org. There was no interannual variation in δ¹⁵N. The occasional high δ¹⁵N values suggest that physical mechanisms, such as the shoaling and advection into the bay of ¹⁵N-rich subsurface equatorial water, occur over short time periods. The latter is presumed to be related to the periodic development of a significant cyclonic gyre in the southern Gulf.     

Changes of the 0°C isotherm and the equilibrium line altitude in central Chile during the last quarter of the 20th century / Changements de l'isotherme 0°C et de la ligne d'équilibre des neiges dans le Chili central durant le dernier quart du 20ème siècle

Abstract

An overall retreat of glaciers has been observed in the Andes of central Chile during the last ~100 years. Precipitation is mainly of frontal origin and concentrates in winter months. Analysis of precipitation data shows a decrease until 1976, an increase thereafter north of 34°S and a decrease south of 34°S, but overall no significant trends during the last quarter of the 20th century. Analysis of radiosonde data of central Chile shows mid-tropospheric warming with an elevation increase of the 0°C isotherm of 122 ± 8 m and 200 ± 6 m in winter and summer, respectively, during the 27-year period between 1975 and 2001. The results point to a snowline elevation increase in the region during the last quarter of the 20th century and a concurrent rise of the equilibrium line altitude (ELA) and suggest that mid-troposphere warming is the main cause for glacier retreat in central Chile.     

Multiple interpretive errors? Indeed. Reply to: Climate effects of the 74 ka Toba super-eruption: Multiple interpretive errors in ‘A high-precision 40Ar/39Ar age for the Young Toba Tuff and dating of ultra-distal tephra’ by Michael Haslam

We would like to thank Michael Haslam (Haslam et al., 2013) for his interest in our recent contribution on the dating of the Young Toba Tuff/Tephra (YTT) (Mark et al., 2013). However, we point out errors made by Haslam, using this opportunity to clarify and expand on our discussion while also re-emphasising the important points from our study that have been overlooked.