辽河流域太子河流域N、P和叶绿素a浓度空间分布及富营养化

通过对太子河流域46个采样点溶解性无机氮、溶解性无机磷、总氮、总磷、电导率、p H、溶解氧和叶绿素a浓度及相关环境因子的测定,分析氮、磷浓度与叶绿素a浓度的空间分布特征,利用回归分析判别氮、磷与叶绿素a浓度的相关性,冗余分析判别河流水质与环境因子的关系,并初步评价太子河流域水体富营养化状况.结果表明:太子河流域氮、磷浓度具有明显的空间异质性,表现为上游浓度较低且变化较平稳,辽阳段浓度逐渐上升且波动增大,鞍山段浓度最高.冗余分析显示氮、磷浓度的空间分布特征与土地利用方式、海拔、河岸缓冲带宽度、植被多样性密切相关.叶绿素a浓度与氨氮、硝态氮、溶解性无机氮、溶解性无机磷、总氮、总磷和电导率呈显著正相关,说明营养盐的增多在一定程度上会促进浮游藻类的增长.太子河流域水体富营养化评价综合指数显示,太子河流域"中"营养状态点位有27个,占58.7%,"富"营养状态点位有19个,占41.3%,没有"贫"、"重富"和"极富"营养状态.     

太湖流域望虞河西岸地区氮磷污染来源解析及控制对策

本文比较全面地调查了太湖流域望虞河西岸地区氮磷污染来源,结果表明:太湖流域望虞河西岸水体氮磷污染严重,氮磷污染物主要来源于生活污染,其氨氮、总氮、总磷排放量分别占总负荷量的60.2%、52.5%和52.9%.工业污染问题突出,纺织印染是污染物排放最大的工业行业.张家港市和江阴市为氮磷污染的主要贡献地.对区域环境容量进行了预测,并提出了氮磷污染削减目标,氨氮、总氮和总磷污染削减率分别达32.4%,51.8%和51.1%.最后,从加大污染综合治理力度、落实河道及生态修复工程、加强环境管理和监控等方面提出了望虞河西岸地区的氮磷污染控制对策.     

Water quality along a river continuum subject to point and diffuse sources

The water quality along the River Kennet, in the Thames basin of southern England, was examined in terms of the influence of point- and diffuse-nutrient inputs. The river is supplied mainly from a Cretaceous Chalk aquifer and hence the waters are of a calcium bicarbonate type. The nitrate largely comes from agricultural sources, with concentrations decreasing downstream due to plant uptake and probable denitrification. In contrast, soluble reactive phosphorus (SRP) is largely associated with sewage inputs and concentrations increase downstream in line with effluents from major towns such as Newbury and Reading. Adjacent to the river in the lower half of the catchment is the Kennet and Avon Canal and the two are in places hydrologically connected. The canal inputs may influence calcium carbonate (calcite) precipitation and increase suspended sediment and particulate phosphorus concentrations in the river. Monitoring upstream and downstream of Marlborough sewage treatment works (STW) showed that SRP concentrations in the effluent were highly variable due to variable efficiency of P stripping and still sufficiently concentrated to dominate downstream river SRP with potential impacts on stream ecology. Biological recovery in this river following P stripping at STWs is complex and controlling those spikes in SRP that are above a threshold of 100 μg l⁻¹ may be a critical requirement. More stringent effluent targets than are currently recommended may be needed (less than 800 μg RP l⁻¹) to achieve good ecological status in this river depending on SRP concentrations upstream.     

浙江金华江支流白沙溪水质硅藻生物监测方法

以白沙溪为示范区,比较了硅藻生物指数评价与我国现阶段河流水质理化评价结果的异同性,同时对白沙溪进行水生态评估.水质理化评价显示白沙溪水质从Ⅰ类到劣Ⅴ类均有出现,而硅藻特定污染敏感指数和硅藻生物指数评价白沙溪水质为"优"到"差"均有出现.二者评价结果总体上相吻合,同时亦存在一定差异.硅藻生态类群组成显示前三个断面以耐低污染硅藻、自养硅藻和喜好很高氧饱和度硅藻为主,4#断面(除2010年11月)以耐中污染和强污染硅藻、异养硅藻、喜好低氧硅藻类群占优势.全年水体各断面均以喜中性和碱性的硅藻类群为主.特定污染敏感指数和硅藻生物指数均与电导率、总磷、氨氮、氯化物之间呈显著负相关,此外硅藻生物指数还与高锰酸盐指数、总氮、亚硝酸盐氮和可溶性磷酸盐之间呈显著负相关.本研究结果对开展我国河流水质生物监测具有一定的借鉴意义,但其在我国的适用性还需要开展进一步的研究.     

Spatial evolution of nitrogen and phosphorus loads along a small Mediterranean river: implication of bed sediments

This study addresses the spatial variations in water quality along the River Vène (France). The Vène drains a 67 km² rural basin, with a large karstic area, located in a Mediterranean context. A 1 day sampling campaign was conducted along the river, in winter low‐flow conditions (February 2003). Physico‐chemical parameters and water flow discharge were measured in situ during the sampling campaign. Water quality was evaluated by determining the concentrations of nitrogen and phosphorus in water and bed‐sediment samples. Nitrogen and phosphorus loads were evaluated taking into account the measured concentrations and discharge. The campaign included 18 sampling points and concerned the whole river from the spring to the outlet, plus the main inputs, i.e. sewage treatment works, main tributaries and karstic springs. The spatial evolution of nitrogen and phosphorus loads along the river allowed the significant role of point‐source inputs to be demonstrated. The decrease in nutrient loads along the river occurred mainly in specific reaches where fine sediments had accumulated. In these zones, phosphorus is trapped in the bed sediments in calcium‐bound phosphates due to precipitation processes. Copyright © 2005 John Wiley & Sons, Ltd.     

Partial recovery of Newark Bay,NJ, following pollution abatement

For the seven months terminating on 17 August 1980, primary sewage effluent was discharged into Newark Bay. From 22 July to 6 October 1980, we collected physical, chemical and biological data in the Newark Bay estuary from the lower Passaic River to New York Harbor. During the period of maximum discharge, the Passaic River and much of Newark Bay were anoxic or nearly so. Recovery of the Newark Bay water following sewage abatement took approximately 30 days. During most of the study period, a bloom of blue-green algae characterized the ‘Passaic River water’. This water was also characterized by chlorophyll-a values as high as 73 mg m^?3. Chlorophyll concentration almost always increased up the bay, along with decreasing salinity, increasing temperature, increasing phosphate-P and decreasing nitrate-N. The decrease in nitrate, however, was associated with an increase in ammonia-N and total N during the period of sewage discharge.     

Charakterisierung des chemischen Zustandes der Limmat zwischen Zürichsee und Wettingen (1974–1978)

In connection with the enlargement and updating of the Werdhölzli sewage treatment plant, research was undertaken on the chemistry of that part of the River Limmat lying between Lake Zürich and Wettingen from 1974 to 1978. The extensive amount of data involved was subjected to statistical analysis and the results are being interpreted. In general, the chemical condition of the water of the Limmat river upstream from the Werdhölzli sewage plant can be described as good. In order to attain the desired water quality criteria downstream of the waste-water outfall of the plant, pollution in therms of ammonium nitrogen and organic substances must be reduced. The performing of a chemical pre-precipitation process has brought about a sizable reduction in the phosphorus concentration of the Limmat river downstream of the plant; the values are now below the required water quality limits.     

天津中心城区河网氮磷污染与富营养化特征

2013年底天津中心城区河道全部连通,形成中心城区河网.为了掌握河网形成后的水质状况,于2014年3月-2015年2月进行了为期1年的定点水质监测,并对其水体氮、磷时空分布及富营养化特征进行分析.结果表明,河网水体氮污染严重,以铵态氮(NH+4-N)为主;磷污染程度较轻,主要形态为磷酸盐(PO3-4-P);河网水体中氮、磷浓度顺水流方向均呈上游高、下游低的空间分布特征;氮、磷各项指标浓度时间变化趋势基本一致,3月均最高,10月均最低,冬季处于相对较低水平;与河网形成前相比,海河干流NH+4-N、总磷(TP)和PO3-4-P浓度年平均值分别下降6.5%、14.7%和16.4%,津河总氮、NH+4-N、硝态氮、TP和PO3-4-P浓度年平均值分别降低18.6%、34.5%、12.9%、31.6%和32.5%,表明河网形成后氮、磷污染程度较之前有所改善,其中津河改善较为明显;河网水体全年处于中度富营养状态,主要为磷限制性状态;河网富营养化防治应遵循以控制营养盐为主的控源、截污、水环境增容和生态补水策略.     

Semicontinuous Outdoor Cultivation of Scenedesmus acutus in Waste Water

The algae were cultivated in an outdoor cultivation unit in waste water from sewage treatment plant processing city sewage and largescale hoggery effluent. The cultivation area (2m²) had a slant of 3% and the suspension layer thickness was about 5 cm. The total suspension volume in the cultivation device was 150 I. Mass balance served us for derivation of formulas for the average rate of algal biomass production and for the extent of nutrient removal from waste water. Experiments showed a considerable effect of dilution rate on individual parameters in these formulas. The removal of nitrogen and phosphorus is optimal at a dilution rate of 0.3 day^?1 whereas optimum biomass production lies at about 0.1 day^?1. The nitrogen and phosphorus yield coefficient Y (g biomass/g element) are practically identical, both of them depending on dilution rate. The effect of the dilution rate on other characteristics of the effluent water has not yet been unambiguously proved. The results are shown of bacteriological and mycological examinations, in addition, of the chemical analysis of resulting algal biomass.     

Effect of sewage nutrients on algal production,biomass and pigments in tropical tidal creeks

Microalgal blooms can result from anthropogenic nutrient loadings in coastal ecosystems. However, differentiating sources of nutrients remains a challenge. The response of phytoplankton and benthic microalgae (BMA) to nutrient loads was compared across tropical tidal creeks with and without secondary treated sewage. Primary productivity in the water column was limited by nitrogen availability in absence of sewage, with nitrogen saturation in the presence of sewage. Phytoplankton primary productivity rates and chlorophyll a concentrations increased in response to sewage, and there was a greater response than for BMA. There was no change in algal pigment proportions within the phytoplankton or BMA communities. Concentrations of the sewage marker, coprostanol, were higher near sewage discharge points decreasing downstream, correlating with a decline in nutrient concentrations. This suggests that sewage was the main source of nitrogen and phosphorus. This study highlights the scale and type of response of algal communities to sewage nutrients.     

Stable carbon and nitrogen isotope signatures indicate recovery of marine biota from sewage pollution at Moa Point,New Zealand

Stable carbon and nitrogen isotopes have been used to assess sewage contamination of a sewage outfall, discharging milli-screened effluent into Moa Point Bay, New Zealand, and monitor the recovery of flora and fauna after the outfall's closure. An initial study characterising the extent of the discharge and the effects on seaweed (Ulva lactuca L.), blue mussels (Mytilus galloprovincialis) and limpets (Cellana denticulata) from the area, showed effects of the sewage discharge on flora and fauna were localised within in the bay. The immediate area surrounding the discharge area was found to contain limited biodiversity, with an abundance of Ulva lactuca, a bright green lettuce-like seaweed, typically found in areas with high nutrient input, limpets and small blue mussels. The nitrogen isotopic signature (delta15N) is shown to be a good tracer of sewage pollution in seaweed and associated grazers (i.e. limpets) as a result of the increased contribution of urea and ammonia to seawater nitrogen derived from the effluent. The carbon isotopic signature (delta13C) is suggested as a more appropriate sewage tracer for mussels, which filter feed the effluent's particulate organic matter from the water. Lower carbon:nitrogen ratios were found in Ulva lactuca sampled from around the outfall region compared to uncontaminated control sites. However carbon:nitrogen ratios do not vary significantly amongst shellfish species.After closure, monitoring continued for 9 months and showed that the carbon and nitrogen isotopic signatures of algae (Ulva lactuca L.) returned to similar control site levels within 3 months. Limpet and blue mussels (Cellana denticulata and Mytilus galloprovincialis) showed slower recovery times than the Ulva lactuca, with detectable levels of the sewage-derived carbon and nitrogen remaining in the animal's tissue for up to 9 months.     

Analysis of stream water quality and estimation of nutrient load with the aid of Quick Bird remote sensing imagery

Abstract

Human activities have created high nutrient surpluses in agricultural lands due to the increasing rate of chemical fertilizer application and the increase in livestock production. To analyse the nutrient characteristics and estimate the nutrient load in streams, we conducted extensive field survey and water quality experiments from 2007 to 2008 in Koise River, a major river of the Lake Kasumigaura watershed, Japan. Water quality indicators of total nitrogen (TN), total phosphorus (TP) and total organic carbon (TOC) were investigated. The nutrient loads of TN, TP and TOC, as well as dissolved total nitrogen, dissolved inorganic nitrogen, dissolved organic nitrogen, particle organic nitrogen, dissolved total phosphorus, dissolved organic carbon and particle organic carbon were also estimated for the Koise River. Seasonal variation of the nutrient concentration from 2007 to 2008 was analysed considering the river discharge variation and agricultural activities. The results showed that the irrigation water from Lake Kasumigaura has the potential ability to decrease the TN concentration and increase the TOC concentration in the Koise River. Significant correlation coefficients between nutrient load and river discharge were found. The monthly pollution loads from different sources were then evaluated based on land cover classification generated from high-resolution Quick Bird remote sensing imagery. This study presents a useful interpretation of water quality data sets with a view to obtaining better information about water quality for more effective management of water resources in river basins.

Editor Z.W. Kundzewicz

Citation He, B., Oki, K., Wang, Y., Oki, T., Yamashiki, Y., Takara, K., Miura, S., Imai, A., Komatsu, K. and Kawasaki, N., 2012. Analysis of stream water quality and estimation of nutrient load with the aid of Quick Bird remote sensing imagery. Hydrological Sciences Journal, 57 (5), 850–860.     

人类活动对乌梁素海湿地环境演变的影响分析

乌梁素海是我国半荒漠地区具有很高生态价值和社会效益的大型多功能湖泊湿地[1],是黄河流域最大的淡水湖泊,也是内蒙古河套灌区唯一的承泄途径.乌梁素海的补给水源主要包括含高N,P的农田退水,工业废水以及生活污水,这些退水及废污水的排入使得湿地环境发生着重大的变化.本文在收集1986-2004年19年间Landsat TM/ETM遥感影像数据的基础上,结合乌梁素海历史资料,分析了80年代以来人类活动对湿地环境的影响,这种影响主要体现在人工芦苇面积不断扩大,富营养化程度逐年增高,水生资源迅速减少等方面,尽管2003年以来"引黄入海"工程的实施某种程度上缓解了湿地环境恶化的进程,但湿地环境仍然面临严重的威胁.     

Influence of the Pearl River estuary and vertical mixing in Victoria Harbor on water quality in relation to eutrophication impacts in Hong Kong waters

This study presents water quality parameters such as nutrients, phytoplankton biomass and dissolved oxygen based on 11 years of water quality data in Victoria Harbor and examined how the Pearl River estuary discharge in summer and year round sewage discharge influenced these parameters. Nutrients in Victoria Harbor were strongly influenced by both the Pearl River and sewage effluent, as indicated by the high NO(3) inputs from the Pearl River in summer and higher NH(4) and PO(4) in Victoria Harbor than both its sides. N:P ratios were low in the dry season, but increased to >16:1 in the wet season, suggesting that P is potentially the most limiting nutrient in this area during the critical period in the summer. Although there were generally high nutrients, the phytoplankton biomass was not as high as one would expect in Victoria Harbor. In fact, there were high concentrations of chl near the bottom well below the photic zone. Salinity near the bottom was lower in Victoria Harbor than at the two entrances to Victoria Harbor, suggesting strong vertical mixing within Victoria Harbor. Therefore, strong vertical mixing and horizontal advection appear to play an important role in significantly reducing eutrophication impacts in Victoria Harbor. Consequently, dissolved oxygen near the bottom was low in summer, but only occasionally dipped to 2 mgL(-1) despite the high organic loading from sewage effluent.     

Phosphorus and dissolved silicon dynamics in the River Swale catchment,UK: a mass‐balance approach

The internal riverine processes acting upon phosphorus and dissolved silicon were investigated along a 55 km stretch of the River Swale during four monitoring campaigns. Samples of river water were taken at 3 h intervals at sites on the main river and the three major tributaries. Samples were analysed for soluble reactive phosphorus, total dissolved phosphorus, total phosphorus, dissolved silicon and suspended solid concentration. Mass‐balances for each determinand were calculated by comparing the total load entering the river with the total load measured at the downstream site. The difference, i.e. the residual load, showed that there was a large retention of phosphorus and silicon within the system during the March 1998 flood event, but the other three campaigns produced net‐exports. Cumulative residual loads were calculated for each determinand at 6 h intervals throughout each campaign. This incremental approach showed that the mass‐balance residuals followed relatively consistent patterns under various river discharges. During stable low‐flow, there was a retention of particulate phosphorus within the system and also a retention of total dissolved phosphorus and soluble reactive phosphorus, most likely caused by the sorption of soluble phosphorus by bed‐sediments. In times of high river‐discharge, there was a mobilization and export of stored bed‐sediment phosphorus. During overbank flooding, there was a large retention (58% of total input) of particulate phosphorus within the system, due to the mass deposition of phosphorus‐rich sediment onto the floodplain. Soluble phosphorus was also retained within the system by sequestration from the water column by the high concentration of suspended solids. The dissolved silicon mass‐balance residuals had a less consistent pattern in relation to river discharge. There was a large retention of dissolved silicon during overbank flooding, possibly due to sorption onto floodplain soil, and net‐exports during periods of both stable low‐flow and rising limbs of hydrographs, due to release of dissolved silicon from pore‐waters. Copyright © 2001 John Wiley & Sons, Ltd.     

太湖北部梅梁湾水域水质因子聚类

计算了沿梁溪河河口到太湖湖心断面上１０个监测点１７个水质因子９３组数据的Ｐｅａｒｓｏｎ相关系数和Ｋｅｎｄａｌｌ秩相关系数,进而运用最小距离法进行了因子聚类,正态分布检验和聚类结果表明,采用Ｋｅｎｄａｌｌ秩相关进行了聚类为宜,结果将诸因子聚为五大类：ＴＤＮ,ＴＮ,ＣＯＮ,ＮＯ２－Ｎ,ＮＨ４－Ｎ,ＯＨ和ＣＯＤＭｎ归为一类,ＴＤＰ,ＴＰ,ＰＯ＾３＋４和ｐＨ值归为一类;ＳＳ和ＳＤ归为一类,反映了该水域环境     

Spatial and temporal patterns of the water quality in the Danjiangkou Reservoir,China

Abstract

The three-route South-to-North Water Diversion Project (SNWDP), transferring water from the water-rich Yangtze River and its tributaries to the much drier area of North China for irrigation, industrial and domestic use, has been implemented in China since 2002. Thus, water quality in the Danjiangkou Reservoir, the water source area of the SNWDP's Middle Route, is of great concern. We investigate its water quality from 2004 to 2006 by monitoring some important physical (T, turbidity and SPM) and chemical (DO, pH, alkalinity, TDS, SpCond, ORP, COD_Mn and BOD) parameters and nutrient (nitrogen and phosphorus) contents. Consequently, their spatial and temporal patterns in the reservoir were examined. The results indicate that the water of the reservoir is of a Ca and HCO₃ type, and the major pollutants are nitrogen and COD_Mn. Comparisons among the sampling sites show that water quality increases downstream, implying the self-purification capacity of the reservoir. The reservoir in general has better water quality in the dry season than in the wet season. Integrated basin management would be critical of the water quality in the Danjingkou Reservoir for the interbasin water transfer project.     

2007-2008年千岛湖营养盐时空分布及其影响因素

2007-2008年对千岛湖水体中5个采样点(S1,S3,S4,S8,S9)的总氮、总磷、三态氮、溶解性总磷和可溶性活性磷等进行了不同深度的逐月监测,以研究探讨千岛湖营养盐的时空分布格局.结果表明,两年间总磷、总氮和硝酸盐氮浓度都呈现从上游(S1)至下游(S9)逐渐下降的趋势;2007-2008年汛期(3-7月)位于千岛湖上游新安江干流段的样点S1各种营养盐均为全年最高.但是2007年与2008年营养盐时空分布差异显著.2008年汛期(3-7月),S1的总磷和总氮浓度分别极显著低于和高于2007年同期.相对于2007年,虽然2008年具有更高的温度,但没有增强水体热稳定性.2008年强对流天气一方面通过打破水体热分层和促进水体混合,另一方面通过雨水带来大量的地表营养盐来影响营养盐的分布.汛期高浓度的总磷在1-2个月内平均降低64.4%,最大降低88.6%,显示千岛湖生态系统具有较强的净化能力.分析结果显示千岛湖营养盐时空分布总体格局是由水文、生物以及人类活动等各种因素之间的相互作用所产生的综合效应而形成的,而极端天气能够改变这一格局.     

梯级筑坝下小型山区河流水体碳氮磷的时空特征及富营养化风险

梯级筑坝对河流水环境演化的影响是国内外关注的热点.小型山区河流高密度梯级开发对水体生源要素的空间格局以及水环境演化的累积影响特征尚不清楚.以重庆市五布河为研究对象,对流域内8个“河流—水库—下泄水”交替系统中表层水体理化因子及碳(C)、氮(N)、磷(P)形态组成进行季节性监测,探讨了梯级筑坝对小型河流生源要素空间格局及水体富营养化风险影响的累积特征及驱动机制.结果表明：梯级水电开发对五布河流域水生生境和生源要素空间分配的影响具有潜在的累积效应,各库区水体碳氮磷浓度均呈逐级增加的空间规律;水库段的有机碳及不同形态的氮、磷浓度均高于入库河流,因此水体养分浓度呈现出河段尺度(即单个河流—水库—下泄水系统)和流域尺度(即上游至下游)耦合的空间变异模式.上游水库中溶解性氮、磷的再释放及下泄输移能够补给下游库区,加之下游水库泥沙对氮、磷的吸附—沉积作用的减弱,导致水体氮、磷总量及溶解性氮、磷的占比沿程增加,呈现梯级筑坝对水环境演化的累积影响.梯级筑坝影响下河流碳氮磷总量的相关性减弱,而溶解性养分间的相关性增强,形成了特殊的养分协同演化;水库群之间水力滞留时间的差异与水体碳氮磷浓度具有较好的线性关系...     

鄱阳湖区水体氮、磷污染状况分析

通过系统测定鄱阳湖湖水、主要入湖口河水及部分农田水、地下水及城市污水氮磷含量,对其氮、磷污染状况进行了分析,同时对湖水及河水的氮、磷来源进行了初步讨论.结果表明,鄱阳湖区水体已达到一定程度的氮、磷污染,特别是饶河段氮含量较高(0.89-3.15mg/L),信江磷含量较高(0.098-0.22mg/L),而湖体的总氮、总磷含量也分别达到1.06±0.28mg/L和0.067±0.042mg/L,已具备富营养化的条件.