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1.
Figeh watershed spring is one of the important groundwater aquifer, which is considered a major source for drinking waters of Damascus city and countryside. The origin identification and recharge estimates of groundwater are significant components of sustainable groundwater development in this Mountain karst aquifer of Figeh spring. During the period 2001–2009, monthly groundwater and precipitation samples were taken and the isotopic compositions of δ18O, δ2H, and chloride contents were analyzed to identify groundwater origins and to estimate recharge rates. The δ18O, δ2H of the groundwater show that the groundwater recharge is of meteoric origin. The chloride mass balance (CMB) method was used to quantify recharge rates of groundwater in the Mountain karst aquifer of Figeh spring. The recharge rate varies from 192 to 826 mm/year, which corresponds to 43 and 67% of the total annual rainfall. Recharge rates estimated by CMB were compared with values obtained from other methods and were found to be in good agreement. This study can be used to develop effective programs for groundwater management and development.  相似文献   

2.
The hydrodynamic groundwater data and stable isotopes of water have been used jointly for better understanding of upward leakage and mixing processes in the Djerid aquifer system (southwestern Tunisia). The aquifer system is composed of the upper unconfined Plio-Quaternary (PQ) aquifer, the intermediate (semi-)confined Complex Terminal (CT) aquifer and the deeper confined Continental Intercalaire (CI) aquifer. A total of 41 groundwater samples from the CT and PQ aquifers were collected during June 2001. The stable isotope composition of waters establishes that the CT deep groundwater (depleted as compared to present Nefta local rainfall) is ancient water recharged during late Quaternary time. The relatively recent water in the shallow PQ aquifer is composed of mixed water resulting from upward leakage and sporadic meteoric recharge. In order to characterize the meteoric input signal for PQ in the study area, rainfall water samples were collected during 4 years (2000–2003) at the Nefta meteorological station. Weighted mean values of isotopic contents with respect to rainfall amounts have been computed. Despite the short collection period in the study area, results agree with those found in Beni Abbes (southwestern Algerian Sahara) by Fontes on 9 years of rainfall surveillance. Stable isotopic relationships provide clear evidence of shallow PQ aquifer replenishment by deep CT groundwater. The 18O/upward leakage rate allowed the identification of distinctive PQ waters related to CT aquifer configuration (confined in the western part of the study area, semi-permeable in the eastern part). These trends were confirmed by the relation 18O/TDS. The isotope balance model indicated a contribution of up to 75% of the deep CT groundwater to the upper PQ aquifer in the western study area, between Nefta and Hazoua.  相似文献   

3.
An overview is presented of existing groundwater-age data and their implications for assessing rates and timescales of recharge in selected unconfined aquifer systems of the United States. Apparent age distributions in aquifers determined from chlorofluorocarbon, sulfur hexafluoride, tritium/helium-3, and radiocarbon measurements from 565 wells in 45 networks were used to calculate groundwater recharge rates. Timescales of recharge were defined by 1,873 distributed tritium measurements and 102 radiocarbon measurements from 27 well networks. Recharge rates ranged from?<?10 to 1,200?mm/yr in selected aquifers on the basis of measured vertical age distributions and assuming exponential age gradients. On a regional basis, recharge rates based on tracers of young groundwater exhibited a significant inverse correlation with mean annual air temperature and a significant positive correlation with mean annual precipitation. Comparison of recharge derived from groundwater ages with recharge derived from stream base-flow evaluation showed similar overall patterns but substantial local differences. Results from this compilation demonstrate that age-based recharge estimates can provide useful insights into spatial and temporal variability in recharge at a national scale and factors controlling that variability. Local age-based recharge estimates provide empirical data and process information that are needed for testing and improving more spatially complete model-based methods.  相似文献   

4.
An approach combining the use of water dissolved chemical species and isotopic fingerprints has been used to understand the behavior of a phreatic aquifer and to determine the origin of its different water components. This aquifer is located in the large sedimentary basin of the Great Oriental Erg (Algeria) and overlies two deeper aquifers: the Complexe Terminal (CT) and the Continental Intercalaire (CI). Besides the deterioration of its groundwater quality, its water table has risen during the last 20 years. A water budget surplus between 950 and 2500 l s?1 was estimated. Down-gradient groundwater evolution (south-north) has shown that the mineralisation increases from 1.23 to 5.20 g l?1 due to evaporite minerals dissolution. Chemical and isotopic data demonstrated that in addition to rainfall there is a contribution from the CT and CI aquifers. The latter are tritium-free and less mineralized than the phreatic aquifer. Their radiocarbon contents are very low (<10 pmC, percent modern Carbon) (Pleistocene recharge) whereas quite the contrary is observed for the superficial aquifer which exhibits fairly high and variable C-14 activities (50–100 pmC), evidence of recent recharge. On the basis of tritium contents, two groundwater groups were identified for the phreatic aquifer.  相似文献   

5.
The present work studies the environmental isotopes assess groundwater characteristics of the different parts of the main aquifer in the northeast Missan Province in south of Iraq.Water samples of groundwater and surface water were collected for two dry and wet seasons during the water year of 2011–2012.The study shows that most of the groundwater in the aquifer falls above the global meteoric water line,and all the samples fall below the Mediterranean meteoric water line,indicating that these samples are a mixture of two water types.The tritium content of these samples supports this conclusion.The overall conclusion of this study indicates that there are two sources of groundwater recharge in the studied area:the ephemeral streams(Teeb and Dewerge) and major precipitation sources.According to the tritium levels at or below one tritium unit(TU) obtained from the water,supply wells are highly confined or "not vulnerable".Overall,the 3H results imply that recent recharge has taken place during the last four to five decades.In the recharge area,the high tritium content in the southern part of the Teeb area suggests that the recharge originates from rapid infiltration of surface runoff.Therefore,the groundwater resources in the study area should be protected from contamination,because it will influence the aquifer in a relatively short period of time if any contamination enters the recharge areas of the aquifer.  相似文献   

6.
The combined effects of low rainfall, groundwater withdrawal in excess of 300 GL/year and reduced recharge in areas covered by pine plantations has caused the water table in a sandy unconfined aquifer on the Gnangara Mound in Western Australia to drop by up to 5 m and aquifer storage to decline by about 500 GL over the last 20 years. Groundwater has become acidic in areas of high drawdown, with pH values typically being less than 5.0 at the water table, and elevated concentrations of SO4 2?, Al, Fe, Zn, Cu, Ni and Pb. Trends of increasing acidity and base cation concentrations in deep water supply wells in the Mirrabooka wellfield indicate that about 0.7 keq/ha/year of base cations are being leached from soil within cones of depression of pumping wells. These results indicate that the assessment of the sustainable yields of aquifers under conditions of low rainfall needs to consider geochemical interactions between groundwater, aquifer sediments, soils and vegetation, and not be just based on aquifer hydraulics and water-balance changes.  相似文献   

7.
The chemical and hydrodynamic characteristics of groundwater in deltaic regions are strongly influenced by the complex stratigraphy of these areas, caused by the continuously varying depositional environments associated with their recent hydrographic evolution. As a case study, the eastern sector of the Po River plain, northern Italy, has been investigated to understand the quality of the available groundwater resources. Based on the analysis of hydrochemical and isotopic data, the recharge characteristics, the groundwater residence time and the aquifer vulnerability are defined. The results show significant qualitative degradation of the unconfined aquifer due to the shallow depth to water, while in the underlying confined aquifer, a hydrochemical facies of Ca–HCO3 type prevails. The spatial variation and relationship between oxygen-18 and deuterium determine: firstly, hydraulic separation of the two hydrogeological units; secondly, direct infiltration of local precipitation to the unconfined aquifer; thirdly, the occurrence of waters originating in the Alps and locally from the Apennines, pervading the confined aquifer. The tritium results suggest local mixing between the superficial waters and the confined aquifer, occurring along the palaeo-river channels. This increases the pollution vulnerability of the confined hydrogeological unit within the plain, which is the only natural groundwater resource exploited for water supply.  相似文献   

8.
Whether groundwater resources can be sustainably utilized is largely determined and characterized by hydrogeological parameters.Estimating the groundwater recharge is one of the essential parameters for managing water resources and protecting water resources from contamination.This study researched the spatial and temporal variation of groundwater recharge in the Thepkasattri sub-district through integrating chloride mass balance(CMB)and water table fluctuation(WTF)methods.The chloride content of representative rainfall and groundwater samples was analyzed.Besides,WTF method was adopted from groundwater level data from 2012 to 2015.According to the CMB method,the mean recharge was estimated to be 1172 mm per year,accounting for 47%of the annual rainfall.Moreover,the estimated recharge from the WTF method took 26%of annual rainfall in 2015.The recharge was underestimated according to the WTF method,because of the uncertainty in specific yield estimates and the number of representative wells in the study area.Moreover,the correlation between rainfall and water table fluctuation data indicated the positive linear relationship between two parameters.The spatial recharge prediction indicated that recharge was higher(1200-1400 mm/yr)in the eastern and western catchment,while that in the central floodplains was between 800 mm/yr and 1100 mm/yr.In addition,low recharge value between 450 mm/yr and 800 mm/yr was observed in the south-west part of Thepkasattri.The spatial variation of recharge partly reflects the influences of land use and land cover of the study area.  相似文献   

9.

Over-exploited groundwater is expected to remain the predominant source of domestic water in suburban areas of Hanoi, Vietnam. In order to evaluate the effect on groundwater recharge, of decreasing surface-water bodies and land-use change caused by urbanization, the relevant groundwater systems and recharge pathways must be characterized in detail. To this end, water levels and water quality were monitored for 3 years regarding groundwater and adjacent surface-water bodies, at two typical suburban sites in Hanoi. Stable isotope (δ18O, δD of water) analysis and hydrochemical analysis showed that the water from both aquifers and aquitards, including the groundwater obtained from both the monitoring wells and the neighboring household tubewells, was largely derived from evaporation-affected surface-water bodies (e.g., ponds, irrigated farmlands) rather than from rivers. The water-level monitoring results suggested distinct local-scale flow systems for both a Holocene unconfined aquifer (HUA) and Pleistocene confined aquifer (PCA). That is, in the case of the HUA, lateral recharge through the aquifer from neighboring ponds and/or irrigated farmlands appeared to be dominant, rather than recharge by vertical rainwater infiltration. In the case of the PCA, recharge by the above-lying HUA, through areas where the aquitard separating the two aquifers was relatively thin or nonexistent, was suggested. As the decrease in the local surface-water bodies will likely reduce the groundwater recharge, maintaining and enhancing this recharge (through preservation of the surface-water bodies) is considered as essential for the sustainable use of groundwater in the area.

  相似文献   

10.
Process-based groundwater models are useful to understand complex aquifer systems and make predictions about their response to hydrological changes. A conceptual model for evaluating responses to environmental changes is presented, considering the hydrogeologic framework, flow processes, aquifer hydraulic properties, boundary conditions, and sources and sinks of the groundwater system. Based on this conceptual model, a quasi-three-dimensional transient groundwater flow model was designed using MODFLOW to simulate the groundwater system of Mahanadi River delta, eastern India. The model was constructed in the context of an upper unconfined aquifer and lower confined aquifer, separated by an aquitard. Hydraulic heads of 13 shallow wells and 11 deep wells were used to calibrate transient groundwater conditions during 1997–2006, followed by validation (2007–2011). The aquifer and aquitard hydraulic properties were obtained by pumping tests and were calibrated along with the rainfall recharge. The statistical and graphical performance indicators suggested a reasonably good simulation of groundwater flow over the study area. Sensitivity analysis revealed that groundwater level is most sensitive to the hydraulic conductivities of both the aquifers, followed by vertical hydraulic conductivity of the confining layer. The calibrated model was then employed to explore groundwater-flow dynamics in response to changes in pumping and recharge conditions. The simulation results indicate that pumping has a substantial effect on the confined aquifer flow regime as compared to the unconfined aquifer. The results and insights from this study have important implications for other regional groundwater modeling studies, especially in multi-layered aquifer systems.  相似文献   

11.
The groundwater extracted from the unconfined Quaternary aquifer is the main source of water supply in El-Tur area. The area is bounded from the east by the elevated basement complex of Southern Sinai and from the west by El-Qabaliyat Ridge. The wadis dissecting these highlands form effective watersheds of the Quaternary aquifer. These wadis form areas of focused recharge. Recharge also occurs directly via the Quaternary sediments covering El-Qaa Plain. Subsurface lateral groundwater flow from the fractured basement contributes significant recharge to the aquifer as well. The aquifer sediment facies affect the type and quality of groundwater. In the eastern part where the aquifer is composed mainly of gravel and coarse sand with fragments of weathered basement, the Na-Cl-SO4 water dominates. In the west where the facies change is rapid and complex, many water types arise. The base exchange index (BEX) is positive in this part reflecting the role of clay minerals in changing the water types via cation exchange. In the east where clays are insignificant in the aquifer, the BEX is negative. In the western part next to El-Qabaliyat Ridge, the wells discharging from the calcareous sand zone have low groundwater salinities compared to the wells discharging from the alluvium. In general, the groundwater salinity increases in the direction of groundwater flow from the northeast to the southwest which reflects the dissolution of aquifer sediments. The concentration relationships between the major ions on one hand and chloride on the other reflect the dissolution of calcium carbonates, precipitation of K- and Mg-bearing minerals, and cation exchange of Ca for Na on clay minerals. The hydrochemical models support these reactions. In addition, they show that the effect of evaporation on the recharge water in the western catchment is about four times its effect on the eastern recharge water which reflects the rapid recharge through the wadis draining the fractured basement. Moreover, the contribution from the eastern catchment in sample No. 23 is more than four-folds the contribution from the western recharge area. The stable isotopes (2H and 18O) show that the Quaternary aquifer is recharging from recent rainfall. However, upward leakage of Paleogene groundwater (depleted in 18O) also occurs. The groundwater level map shows strong overpumping impact especially in the areas close to El-Tur city.  相似文献   

12.
韩家哨村位于河北滦县李家屿灰场北部谷地,地势低于灰场,距离约800m。灰场运行期间,该区地下水出现水位升高及水质变差等问题。本文从水文地质条件角度,详细研究灰水的运移途径及其对该区地下水的影响。韩家哨村区域地下水系统分为上层滞水和孔隙一裂隙(溶隙)潜水含水层系统。潜水含水层系统水力传导系数为172.6~203.4m^2/d。地下水补给主要来源于韩家哨村以南坝后地形较高区域及灰水。灰水渗漏优势区韩家哨村南部宽约200m的带状区域。灰场堆灰形成新的地下水分水岭致使灰水在20副坝坝前垂直下渗进入风化带,沿白云岩裂隙(溶隙)补给潜水含水层,并向韩家哨村区域流动补给孔隙含水层,改变后的潜水部分通过民井向外排泄。  相似文献   

13.
The Quaternary coastal plain aquifer down gradient of the Wadi Watir catchment is the main source of potable groundwater in the arid region of south Sinai, Egypt. The scarcity of rainfall over the last decade, combined with high groundwater pumping rates, have resulted in water-quality degradation in the main well field and in wells along the coast. Understanding the sources of groundwater salinization and amount of average annual recharge is critical for developing sustainable groundwater management strategies for the long-term prevention of groundwater quality deterioration. A combination of geochemistry, conservative ions (Cl and Br), and isotopic tracers (87/86Sr, δ81Br, δ37Cl), in conjunction with groundwater modeling, is an effective method to assess and manage groundwater resources in the Wadi Watir delta aquifers. High groundwater salinity, including high Cl and Br concentrations, is recorded inland in the deep drilled wells located in the main well field and in wells along the coast. The range of Cl/Br ratios for shallow and deep groundwaters in the delta (∼50–97) fall between the end member values of the recharge water that comes from the up gradient watershed, and evaporated seawater of marine origin, which is significantly different than the ratio in modern seawater (228). The 87/86Sr and δ81Br isotopic values were higher in the recharge water (0.70,723 < 87/86Sr < 0.70,894, +0.94 < δ81Br < +1.28‰), and lower in the deep groundwater (0.70,698 < 87/86Sr < 0.70,705, +0.22‰ < δ81Br < +0.41‰). The δ37Cl isotopic values were lower in the recharge water (−0.48 < δ37Cl < −0.06‰) and higher in the deep groundwater (−0.01 < δ37Cl < +0.22‰). The isotopic values of strontium, chloride, and bromide in groundwater from the Wadi Watir delta aquifers indicate that the main groundwater recharge source comes from the up gradient catchment along the main stream channel entering the delta. The solute-weighted mass balance mixing models show that groundwater in the main well field contains 4–10% deep saline groundwater, and groundwater in some wells along the coast contain 2–6% seawater and 18–29% deep saline groundwater.A three-dimensional, variable-density, flow-and-transport SEAWAT model was developed using groundwater isotopes (87Sr/86Sr, δ37Cl and δ81Br) and calibrated using historical records of groundwater level and salinity. δ18O was used to normalize the evaporative effect on shallow groundwater salinity for model calibration. The model shows how groundwater salinity and hydrologic data can be used in SEAWAT to understand recharge mechanisms, estimate groundwater recharge rates, and simulate the upwelling of deep saline groundwater and seawater intrusion. The model indicates that most of the groundwater recharge occurs near the outlet of the main channel. Average annual recharge to delta alluvial aquifers for 1982 to 2009 is estimated to be 2.16 × 106 m3/yr. The main factors that control groundwater salinity are overpumping and recharge availability.  相似文献   

14.
Groundwater is the most important source of water supply in Sidi Bouzid plain located in central Tunisia. Proper understanding of the geochemical evolution of groundwater is important for sustainable development of water resources in this region. A hydrogeochemical survey was conducted on the Mio–Plio–Quaternary aquifer system using stable isotopes, radiocarbon, tritium and major elements, in order to evaluate the groundwater chemistry patterns and the main mineralization processes occurring in this system. The chemical data indicate that dissolution of evaporate minerals and evaporation are the main processes controlling groundwater mineralization. The isotopic data show that groundwater in the study area is a mixture of recent shallow waters located upstream and along Wadi Al Fakka bed and paleowaters located towards plain limits and discharge areas. Low 3H and 14C contents are observed in major part of the plain indicating that recharge of the aquifer occurs mainly through direct infiltration at Wadi Al Fakka while there is no evidence of significant recharge in major part of the plain and mountains piedmonts.  相似文献   

15.
 The Hadejia–Nguru Wetlands are annually inundated flood plains in semi-arid northeastern Nigeria. The area has a unique ecosystem that forms a natural barrier against the encroachment of the Sahara desert. Both the rich wetland vegetation and local farmers using shallow tube wells depend on a groundwater mound (with a water table less than 6 m below the surface) that is present in the unconfined aquifer under the flood-plain area. Using well records (1991–97) and a hydrogeologic profile based on piezometers that were monitored for two years, it is shown that recharge through the annually inundated flood plains is the source of the groundwater mound. Maintenance of the groundwater-recharge function of the flood plains depends on wet-season releases from two large upstream dams. On the basis of a water-budget method, the mean (1991–97) wet-season unconfined groundwater recharge in the flood-plain area between Hadejia and Nguru and in the immediate vicinity (1250 km2) is estimated to be 132 mm (range, 73–197 mm). Outflow from the unconfined flood-plain aquifer to the unconfined upland aquifer is approximately 10% of the wet-season flood-plain recharge. The unconfined groundwater outflow from the flood-plain area can provide a significant contribution to the present-day rural water supply in the surrounding uplands, but it does not offer much potential for additional groundwater abstraction. In addition to outflow to the upland aquifer (∼14 mm), the distribution of the annually recharged water volume of the shallow flood-plain aquifer is (1) domestic uses (3 mm), (2) small-scale irrigation (∼15 mm), and (3) evapotranspiration ( 1 100 mm). Along the hydrogeologic profile, the recharge in the upland (i.e., outflow from the unconfined flood-plain aquifer and possibly diffuse rain-fed recharge) is in balance with the water uses (i.e., domestic uses, groundwater outflow, and evapotranspiration). The absence of a seasonal water-level trend in the two piezometers in the upland indicates that no rain-fed recharge occurs through preferential path-way (macropore) flow. Received, June 1998 / Revised, November 1998, January 1999 / Accepted, January 1999  相似文献   

16.
《Applied Geochemistry》2006,21(1):83-97
Groundwater in the Gwelup groundwater management area in Perth, Western Australia has been enriched in As due to the exposure of pyritic sediments caused by reduced rainfall, increased groundwater abstraction for irrigation and water supply, and prolonged dewatering carried out during urban construction activities. Groundwater near the watertable in a 25–60 m thick unconfined sandy aquifer has become acidic and has affected shallow wells used for garden irrigation. Arsenic concentrations up to 7000 μg/L were measured in shallow groundwater, triggering concerns about possible health effects if residents were to use water from household wells as a drinking water source. Deep production wells used for public water supply are not affected by acidity, but trends of progressively increasing concentrations of Fe, SO4 and Ca over a 30-a period indicate that pyrite oxidation products extend to the base of the unconfined aquifer. Falling Eh values are triggering the release of As from the reduction of Fe(III) oxyhydroxide minerals near the base of the unconfined aquifer, increasing the risk that groundwater used as a drinking water source will also become contaminated with high concentrations of As.  相似文献   

17.
Groundwater is a valuable resource in the semiarid Ordos Plateau region where abundant mineral resources, such as coal, natural gas, and halite, are present. With resources development, groundwater demand will increase dramatically. The origin identification and recharge estimates of groundwater are significant components of sustainable groundwater development in the Ordos Plateau. Groundwater and precipitation samples were taken and the isotopic compositions δ2H, δ18O, and chloride were analyzed to identify groundwater origins and to estimate recharge rates. The δ2H and δ18O of the groundwater show that the groundwater recharge is of meteoric origin. The chloride mass balance (CMB) method was used to quantify recharge rates of groundwater in the Ordos Plateau, which varies from 2.93 to 22.11% of the effective annual rainfall. Recharge rates estimated by CMB were compared with values obtained from other methods and were found to be in good agreement. This study can be used to develop effective programs for groundwater management and development.  相似文献   

18.
High water demand for domestic use in Douala with over 3 million inhabitants is met mainly by shallow groundwater. Field measurements and water sampling in January 2015 were carried out to examine the major controls on the groundwater composition and spatial view of ions in the water, timing of recharge and link between the recharge process and quality of the water. Fifty-two water samples were analysed for major ions and stable hydrogen and oxygen isotopes. Low pH values (3.61–6.92) in the groundwater indicated an acidic aquifer; thus, prone to acidification. The dominant water type was Na–Cl. Nitrate, which exceeded the WHO guide value of 50 mg/l in 22% of the groundwater, poses a health problem. Mass ratios of Cl?/Br? in the water ranged from 54 to 3249 and scattered mostly along the mixing lines between dilute waters, septic-tank effluent and domestic sewage. A majority of the samples, especially the high NO3 ? shallow wells, clustered around the septic-tank effluent-end-member indicating high contamination by seepage from pit latrines; hence, vulnerable to pollution. Stable isotopes in the groundwater indicated its meteoric origin and rapid infiltration after rainfall. The δ18O values showed narrow ranges and overlaps in rivers, springs, open wells and boreholes. These observations depict hydraulic connectivity, good water mixing and a homogeneous aquifer system mainly receiving local direct uniform areal recharge from rainfall. The rapid and diffused recharge favours the leaching of effluent from the pit toilets into the aquifer; hence, the high NO3 ? and Cl? in shallow wells. Silicate weathering, ion exchange and leaching of waste from pit toilets are the dominant controls on the groundwater chemistry. Drilling of deep boreholes is highly recommended for good-quality water supply. However, due the hydraulic connection to the shallow aquifer, geochemical modelling of future effects of such an exploitation of the deeper aquifer should support groundwater management and be ahead of the field actions.  相似文献   

19.
Groundwater depletion and seawater intrusion constitute major challenges along coastal aquifers in arid areas. This paper assesses the role of groundwater recharge dams constructed to replenish aquifers and fight seawater intrusion with reference to AlKhod dam, Oman, sited 7 km from the coast on a gravely unconfined aquifer. Water table rise in piezometers located downstream from the dam shows regular patterns correlating with magnitude of wadi flow, whereas upstream piezometers show irregular patterns. Controlled release of water captured by the dam optimizes water percolation and enhances artificial recharge which was estimated in the wet years 1997, 2003 and 2005 as 15, 22 and 27 Mm3, respectively, using water table fluctuation method. Recharge contributed 40–60 % of the total annual abstraction. Groundwater salinity increased in the 1980s and 1990s and the saline/freshwater interface advanced inland, but has receded partially after 1997 (highest rainfall) and completely after 2005 indicated by reduction in electrical conductivity and thickening of freshwater lens. The recession is attributed to the dam’s induced recharge and reduction of pumping in 2004 following the commissioning of Barka desalination plant. Integrating artificial recharge with groundwater resources management is therefore an effective measure to replenish aquifers in arid areas and mitigate seawater intrusion along the coasts.  相似文献   

20.
Passive multi-level sampling using dialysis membrane diffusion cells is applied to the Chalk aquifer in order to estimate and monitor vertical contaminant distribution. This technique is associated with in situ profiles of field parameters which allow zones of groundwater flow to be established. Through three study cases (confined, semi-confined and unconfined aquifer conditions), the technique shows that vertical chemical heterogeneities are the particular result of flow zonation, or the renewal of water in the upper parts of the aquifer. The aquifer appears stratified or homogeneous according to depth depending on the chemical element being analysed, the sampling period (recharge period or not) and the hydrological situation (unconfined/confined zone). The high vertical resolution of this multi-level sampling also shows the influence of the Chalk lithology on hydrochemical variations, in particular for silica, iron and aluminium, in hardground and marly zones. By using these sampling techniques, the study emphasizes the importance of accurately measuring according to depth certain parameters such as temperature, electrical conductivity and the ratios of the major elements, in particular, Na/K, Mg/Ca and Sr/Ca. Interpretation of these measurements leads to an understanding of the local hydrodynamic and hydrochemical behaviour of an aquifer, and also allows geological heterogeneities to be located.  相似文献   

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