Bedload tracing in a high‐sediment‐load mountain stream

This paper reports a radiofrequency identification (RFID) tracing experiment implemented in a high‐sediment‐load mountain stream typical of alpine gravel‐bed torrents. The study site is the Bouinenc Torrent, a tributary to the Bléone River in southeast France that drains a 38·9‐km² degraded catchment. In spring 2008, we deployed 451 tracers with b‐axis ranging from 23 to 520 mm. Tracers were seeded along eight cross‐sections located in the upstream part of the lowest 2·3 km of the stream. Three tracer inventories were implemented in July 2008, 2009 and 2010. Recovery rates calculated for mobile tracers declined from 78% in 2008 to 45% in 2009 and 25% in 2010. Observations of tracer displacement revealed very high sediment dispersion, with frontrunners having travelled more than 2 km only three months after their deployment. The declining recovery rate over time was interpreted as resulting from rapid dispersion rather than deep burial. We evaluated that 64% of the tracers deployed in the active channel were exported from the 2·3‐km study reach three years after the onset of the tracing experiment. Travel distances were characterized by right‐skewed and heavy‐tailed distributions, correctly fitted by a power‐law function. This supports the idea that in gravel‐bed rivers with abundant sediment supply relative to transport capacity, bedload transport can be viewed as a superdiffusive sediment dispersion process. It is also shown that tracers initially deployed in the low‐flow channel were characterized by a 15‐ to 30‐fold increase of mobility compared to tracers deployed in gravel bars. Copyright © 2011 John Wiley & Sons, Ltd.     

Multiple injected and natural conservative tracers quantify mixing in a stream confluence affected by acid mine drainage near Silverton,Colorado

The acidic discharge from Cement Creek, containing elevated concentrations of dissolved metals and sulphate, mixed with the circumneutral‐pH Animas River over a several hundred metre reach (mixing zone) near Silverton, CO, during this study. Differences in concentrations of Ca, Mg, Si, Sr, and SO₄^2? between the creek and the river were sufficiently large for these analytes to be used as natural tracers in the mixing zone. In addition, a sodium chloride (NaCl) tracer was injected into Cement Creek, which provided a Cl^? ‘reference’ tracer in the mixing zone. Conservative transport of the dissolved metals and sulphate through the mixing zone was verified by mass balances and by linear mixing plots relative to the injected reference tracer. At each of seven sites in the mixing zone, five samples were collected at evenly spaced increments of the observed across‐channel gradients, as determined by specific conductance. This created sets of samples that adequately covered the ranges of mixtures (mixing ratios, in terms of the fraction of Animas River water, %AR). Concentratis measured in each mixing zone sample and in the upstream Animas River and Cement Creek were used to compute %AR for the reference and natural tracers. Values of %AR from natural tracers generally showed good agreement with values from the reference tracer, but variability in discharge and end‐member concentrations and analytical errors contributed to unexpected outlier values for both injected and natural tracers. The median value (MV) %AR (calculated from all of the tracers) reduced scatter in the mixing plots for the dissolved metals, indicating that the MV estimate reduced the effects of various potential errors that could affect any tracer. Copyright © 2006 John Wiley & Sons, Ltd.     

Stream and bed temperature variability in a coastal headwater catchment: influences of surface‐subsurface interactions and partial‐retention forest harvesting

Stream temperature was recorded between 2002 and 2005 at four sites in a coastal headwater catchment in British Columbia, Canada. Shallow groundwater temperatures, along with bed temperature profiles at depths of 1 to 30 cm, were recorded at 10‐min intervals in two hydrologically distinct reaches beginning in 2003 or 2004, depending on the site. The lower reach had smaller discharge contributions via lateral inflow from the hillslopes and fewer areas with upwelling (UW) and/or neutral flow across the stream bed compared to the middle reach. Bed temperatures were greater than those of shallow groundwater during summer, with higher temperatures in areas of downwelling (DW) flow compared to areas of neutral and UW flow. A paired‐catchment analysis revealed that partial‐retention forest harvesting in autumn 2004 resulted in higher daily maximum stream and bed temperatures but smaller changes in daily minima. Changes in daily maximum stream temperature, averaged over July and August of the post‐harvest year, ranged from 1.6 to 3 °C at different locations within the cut block. Post‐harvest changes in bed temperature in the lower reach were smaller than the changes in stream temperature, greater at sites with DW flow, and decreased with depth at both UW and DW sites, dropping to about 1 °C at a depth of 30 cm. In the middle reach, changes in daily maximum bed temperature, averaged over July and August, were generally about 1 °C and did not vary significantly with depth. The pre‐harvest regression models for shallow groundwater were not suitable for applying the paired‐catchment analysis to estimate the effects of harvesting. However, shallow groundwater was warmer at the lower reach following harvesting, despite generally cooler weather compared to the pre‐harvest year. Copyright © 2012 John Wiley & Sons, Ltd.     

The effect of transient storage on nitrate uptake lengths in streams: an inter‐site comparison

Surface water–groundwater interaction in the hyporheic zone may enhance biogeochemical cycling in streams, and it has been hypothesized that streams exchanging more water with the hyporheic zone should have more rapid nitrate utilization. We used simultaneous conservative solute and nitrate addition tracer tests to measure transient storage (which includes hyporheic exchange and in‐stream storage) and the rate of nitrate uptake along three reaches within the Red Canyon Creek watershed, Wyoming. We calibrated a one‐dimensional transport model, incorporating transient storage (OTIS‐P), to the conservative solute breakthrough curves and used the results to determine the degree of transient storage in each reach. The nitrate uptake length was quantified from the exponential decrease in nitrate concentration with distance during the tracer tests. Nitrate uptake along the most downstream reach of Red Canyon Creek was rapid (turnover time K^?1_c = 32 min), compared with nitrate uptake reported in other studies (K^?1_c = 12 to 551 min), but other sites within the watershed showed little nitrate retention or loss. The uptake length S_w‐NO^?₃ for the most downstream reach was 500 m and the mass transfer coefficient V_f‐NO^?₃ was 6·3 m min^?1. Results from 15 other nitrate‐addition tracer tests were used to create a regression model relating transient storage and measures of stream flow to nitrate uptake length. The model, which includes specific discharge and transient storage area, explains almost half the variability in nitrate uptake length (adjusted R² = 0·44) and is most effective for comparing sites with very different stream characteristics. Although large differences in specific discharge and storage zone area explain inter‐site differences in nitrate uptake, other unmeasured variables, such as available organic carbon and microbial community composition, are likely important for predicting differences in nitrate uptake between sites with similar specific discharge rates and storage zone areas, such as when making intra‐site comparisons. Copyright © 2007 John Wiley & Sons, Ltd.     

Flow hydraulics and geomorphic effects of glacial‐lake outburst floods in the Mount Everest region,Nepal

Glacial‐lake outburst floods (GLOFs) on 3 September 1977 and 4 August 1985 dramatically modified channels and valleys in the Mount Everest region of Nepal by eroding, transporting, and depositing large quantities of sediment for tens of kilometres along the flood routes. The GLOF discharges were 7 to 60 times greater than normal floods derived from snowmelt runoff, glacier meltwater, and monsoonal precipitation (referred to as seasonal high flow floods, SHFFs). Specific stream power values ranged from as low as 1900 W m^?2 in wide, low‐gradient valley segments to as high as 51 700 W m^?2 in narrow, high‐gradient valley segments bounded by bedrock. Along the upper 16 km of the GLOF routes, the reach‐averaged specific stream power of the GLOFs was 3·2 to 8·0 times greater than the reach‐averaged specific stream power of the SHFFs. The greatest geomorphic change occurred along the upper 10 to 16 km of the GLOF routes, where the ratio between the GLOF specific stream power and the SHFF specific stream power was the greatest, there was an abundant supply of sediment, and channel/valley boundaries consisted primarily of unconsolidated sediment. Below 11 to 16 km from the source area, the geomorphic effects of the GLOFs were reduced because of the lower specific stream power ratio between the GLOFs and SHFFs, more resistant bedrock flow boundaries, reduced sediment supply, and the occurrence of past GLOFs. Copyright © 2003 John Wiley & Sons, Ltd.     

Evaluating the performance of topobathymetric LiDAR to support multi-dimensional flow modelling in a gravel-bed mountain stream

Stream biophysical processes are commonly studied using multi-dimensional numerical modelling that quantifies flow hydraulics from which parameters such as habitat suitability, stream carrying capacity, and bed mobility are derived. These analyses would benefit from accurate high-resolution stream bathymetries spanning tens of kilometres of channel, especially in small streams or where navigation is difficult. Traditional ground-based survey methods are limited by survey time, dense vegetation and stream access, and are usually only feasible for short reaches. Conversely, airborne topobathymetric LiDAR surveys may overcome these limitations, although limited research is available on how errors in LiDAR-derived digital elevation models (DEMs) might propagate through flow models. This study investigated the performance of LiDAR-derived topobathymetry in support of multi-dimensional flow modelling and ecohydraulics calculations in two gravel-bedded reaches (approximately 200 m long), one morphologically complex and one morphologically simple, and at the segment scale (32 km-long stream segment) along a 15 m-wide river in central Idaho, USA. We compared metre and sub-metre-resolution DEMs generated from RTK-GPS ground and Experimental Advanced Airborne Research LiDAR-B (EAARL-B) surveys and water depths, velocities, shear stresses, habitat suitability, and bed mobility modelled with two-dimensional (2D) hydraulic models supported by LiDAR and ground-surveyed DEMs. Residual statistics, bias (B), and standard deviation (SD) of the residuals between depth and velocity predicted from the model supported by LiDAR and ground-survey topobathymetries were up to −0.04 (B) and 0.09 m (SD) for depth and −0.09 (B) and 0.20 m s⁻¹ (SD) for velocity. The accuracy (B = 0.05 m), precision (SD = 0.09 m), and point density (1 point m⁻²) of the LiDAR topobathymetric survey (regardless of reach complexity) were sufficient to support 2D hydrodynamic modelling and derivative stream habitat and process analyses, because these statistics were comparable to those of model calibration with B = 0 m and SD = 0.04 m for water surface elevation and B = 0.05 m s⁻¹ and SD = 0.22 m s⁻¹ for velocity in our investigation. © 2020 John Wiley & Sons, Ltd.     

Stream nitrate uptake and transient storage over a gradient of geomorphic complexity,north‐central Colorado,USA

The understanding of nutrient uptake in streams is impeded by a limited understanding of how geomorphic setting and flow regime interact with biogeochemical processing. This study investigated these interactions as they relate to transient storage and nitrate uptake in small agricultural and urban streams. Sites were selected across a gradient of channel conditions and management modifications and included three 180‐m long geomorphically distinct reaches on each of two streams in north‐central Colorado. The agricultural stream has been subject to historically variable cattle‐grazing practices, and the urban stream exhibits various levels of stabilisation and planform alteration. Reach‐scale geomorphic complexity was characterised using highly detailed surveys of channel morphology, substrate, hydraulics and habitat units. Breakthrough‐curve modelling of conservative bromide (Br^?) and nonconservative nitrate (NO₃^?) tracer injections characterised transient storage and nitrate uptake along each reach. Longitudinal roughness and flow depth were positively associated with transient storage, which was related to nitrate uptake, thus underscoring the importance of geomorphic influences on stream biogeochemical processes. In addition, changes in geomorphic characteristics due to temporal discharge variation led to complex responses in nitrate uptake. Copyright © 2011 John Wiley & Sons, Ltd.     

Effect of bed surface roughness on longitudinal dispersion in artificial open channels

In several empirical and modelling studies on river hydraulics, dispersion was negatively correlated to surface roughness. In this study, it was aimed to investigate the influence of surface roughness on longitudinal dispersion under controlled conditions. In artificial flow channels with a length of 104 m, tracer experiments with variations in channel bed material were performed. By use of measured tracer breakthrough curves, average flow velocity, mean longitudinal dispersion, and mean longitudinal dispersivity were calculated. Longitudinal dispersion coefficients ranged from 0·018 m² s^?1 in channels with smooth bed surface up to 0·209 m² s^?1 in channels with coarse gravel as bed material. Longitudinal dispersion was linearly related to mean flow velocity. Accordingly, longitudinal dispersivities ranged between 0·152 ± 0·017 m in channels with smooth bed surface and 0·584 ± 0·015 m in identical channels with a coarse gravel substrate. Grain size and surface roughness of the channel bed were found to correlate positively to longitudinal dispersion. This finding contradicts several existing relations between surface roughness and dispersion. Future studies should include further variation in surface roughness to derive a better‐founded empirical equation forecasting longitudinal dispersion from surface roughness. Copyright © 2011 John Wiley & Sons, Ltd.     

Effects of overlying velocity,particle size,and biofilm growth on stream–subsurface exchange of particles

Stream–subsurface exchange strongly influences the transport of contaminants, fine particles, and other ecologically relevant substances in streams. We used a recirculating laboratory flume (220 cm long and 20 cm wide) to study the effects of particle size, overlying velocity, and biofilm formation on stream–subsurface exchange of particles. Sodium chloride was used as a non‐reactive dissolved tracer and 1‐ and 5‐µm fluorescent microspheres were used as particulate tracers. Surface–subsurface exchange was observed with a clean sand bed and a bed colonized by an autotrophic–heterotrophic biofilm under two different overlying velocities, 0·9 and 5 cm s^?1. Hydrodynamic interactions between the overlying flow and sand bed resulted in a reduction of solute and particle concentrations in the water column, and a corresponding accumulation of particles in both the sediments and in the biofilm. Increasing overlying velocity and particle size resulted in faster removal from the overlying water due to enhanced mass transfer to the bed. The presence of the biofilm did not affect solute exchange under any flow condition tested. The presence of the biofilm significantly increased the deposition of particles under an overlying velocity of 5 cm s^?1, and produced a small but statistically insignificant increase at 0·9 cm^?1. The particles preferentially deposited within the biofilm matrix relative to the underlying sand. These results demonstrate that hydrodynamic transport conditions, particle size, and biofilm formation play a key role in the transport of suspended particles, such as inorganic sediments, particulate organic matter, and pathogenic microorganisms in freshwater ecosystems, and should be taken into consideration when predicting the fate and transport of particles and contaminants in the environment. Copyright © 2009 John Wiley & Sons, Ltd.     

Flood dynamics of a concrete-lined,urban stream in Kansas City,Missouri

Brush Creek drains a 76·1 km² watershed within urban Kansas City, Missouri and eastern Kansas. A concrete-lined reach trending 6·1 km through the Plaza District of Kansas City, Missouri has been the focus for several major floods over the past ten years. Channel geometry, slope, and floodwater elevations were determined in the field for segments of the concrete-lined section of Brush Creek for a flood event that occurred on September 18, 1986. Discharge was computed by indirect methods and compared to a value determined from a rating curve established by the Water Resources Division of the U.S.G.S. Boundary shear stress, unit stream power, and average velocity were also computed in order to establish a quantitative relationship between sediment distribution, volume, and size fractions; and flow dynamics operating throughout the channel during this event. Boundary shear stress ranged from 91-96 Nm^?2, stream power was 528-557 Wm^?2, while average velocity was 5-8 ms^?1. These values were sufficient to displace concrete slabs as large as 5 m long by 4·6 m wide by 0·23 m thick weighing an estimated 12 245 kg. As the channel was sediment free and unsecured prior to the flood, the distribution of deposits and subsequent channel scour provide valuable evidence for potentially hazardous sections of this urban stream.     

Investigation of runoff generation in a pristine,poorly gauged catchment in the Chilean Andes II: Qualitative and quantitative use of tracers at three spatial scales

Understanding runoff generation processes is important for flood prediction, water management, erosion control, water quality, contaminant transport and the evaluation of impacts of land use change. However, little process research has been carried out in southern Chile. In particular the young volcanic ash soils, which are typical for this area, are not well understood in their hydrologic behaviour. To establish a ‘reference study’ which can then be used for comparison with other (disturbed) sites, this study focuses on the investigation of runoff generation processes in an undisturbed, forested catchment in the Chilean Andes. The paper reports on an investigation of these processes with different tracer methods at different spatial scales. Hydrograph separation with environmental isotopes and geochemical constituents was used on the catchment scale. Thermal energy was used as a tracer to investigate groundwater–surface water interactions at the local stream reach scale and dye tracers were used to study infiltration and percolation characteristics at the plot scale. It was found that pre‐event water dominates the storm hydrograph. In the lower reaches, however, water usually exfiltrates from the stream into the adjacent aquifer. The dye tracer experiments showed that while preferential vertical flow dominates under forest, water infiltrates as a straight horizontal front in the bare volcanic ashes (no vegetation) on the catchment rim. Subsurface flow patterns in the forest differ significantly from summer to winter. All three approaches used in this study suggest an important shift in dominant processes from dry to wet season. Copyright © 2008 John Wiley & Sons, Ltd.     

Interstitial flow through preferential flow paths in the hyporheic zone of the Oberer Seebach,Austria

We investigated interstitial flow velocities in the Oberer Seebach, Austria, with NaCl tracer injections at a sediment depth of 30 cm to estimate the hydraulic conditions experienced by invertebrates inhabiting the hyporheic zone. Flow velocity measured with tracers is taken as travel time of the water along a straight line between injection and sampling points, although the water flows around sediment particles, and thus travels a somewhat longer distance. From sections of stream sediment in which the interstitial spaces were replaced by concrete, we estimated that this difference amounts, on average, to 27% and used this factor to correct the results of our velocity measurements. Corrected interstitial water velocities ranged from 0.01 to 1.32 cm s^-1 and were independent of surface discharge. We also studied spatial flow patterns in the bed sediments with long-term tracer injections. The three-dimensional distribution of tracer concentrations 24 hours after the start of the injection indicated that interstitial water preferentially flows in a complex network of areas of high hydraulic connectivity. Reynolds numbers for flow in the hyporheic pore space ranged from 0.1 to 489, implying that the flow environment varies from laminar up to the zone of transition to turbulent flow. Therefore, invertebrates may have a size-related active choice of areas where either friction drag or pressure drag predominates. The consequence of flow patterns, such as those observed in our study, is that small-scale variability of hydraulic conditions may be an important determinant of the patchy invertebrate distribution in bed sediments.     

The role of channel morphology on the mobility and dispersion of bed sediment in a small gravel‐bed stream

This study uses a unique 10‐year tracer dataset from a small gravel‐bed stream to examine bed mobility and sediment dispersion over long timescales and at a range of spatial scales. Seasonal tracer data that captured multiple mobilizing events was examined, while the effects of morphology on bed mobility and sediment dispersion were captured at three spatial scales: within morphological units (unit scale), between morphological units (reach scale) and between reaches with different channel morphologies (channel scale). This was achieved by analyzing both reach‐average mobility and travel distance data, as well as the development of ‘mobility maps’ that capture the spatial variability in tracer mobility within the channel. The tracer data suggest that sediment transport in East Creek remains near critical the majority of the time, with only rare large events resulting in high mobility rates and grain travel distances large enough to move sediment past dominant bedforms. While a variable capturing both the magnitude and frequency of flow events within a season yielded a better predictor to sediment mobility and dispersion than peak discharge alone, the distribution of events of different magnitude within the season played a large role in determining tracer mobility rates and travel distances. The effects of morphology differed depending on the analysis scale, demonstrating the importance of scale, and therefore study design, when examining the effect of morphology on sediment transport. Copyright © 2016 John Wiley & Sons, Ltd.     

Influences of sudden changes in discharge and physical stream characteristics on transient storage and nitrate uptake in an urban stream

Changes in the physical structure of urban streams can occur abruptly due to flashy high‐flow events and subsequently alter stream processes, including transient storage and nitrate uptake. We examined temporal variability in transient storage and nitrate uptake by exploring the effects of altered physical characteristics resulting from a single high‐flow event in three reaches of Spring Creek, an urban stream in Fort Collins, Colorado, USA. Study reaches of varying geomorphic and hydraulic characteristics were chosen to represent distinct geomorphic settings in terms of substrate size, sinuosity, bed slope, and degree of rehabilitation and structural controls. We performed detailed physical characterizations and multiple nutrient injections of Br^? and NO₃^? to estimate transient storage and nitrate uptake in each reach. A comparison of pre‐flood and post‐flood data indicates that transient storage and nitrate uptake are highly context specific and mediated by interactions between geomorphic setting and flood discharge. In the two reaches that showed significant post‐flood increases in transient storage (250% to 350% increases in F_med²⁰⁰), the pool‐riffle reach exhibited a significant increase in uptake velocity, while the channelized reach did not. In contrast, transient storage decreased post‐flood in the third reach containing hydraulic structures. These complex responses likely reflect reach‐specific differences in hyporheic versus in‐channel storage. This study shows that repeat injections are necessary to describe nutrient dynamics because transient storage and nitrate uptake can be highly variable over time (showing changes on the order of 100%) due to variation in discharge and geomorphically influential flow events. Copyright © 2014 John Wiley & Sons, Ltd.     

Using fluorescein and bromide tracers to investigate the role of baseflow in a small suburban watershed in Iowa,USA

Fluorescein and bromide tracers were used to study baseflow mechanisms of a small suburban watershed in northeast Iowa, USA. The tracers were applied to ten injection holes ranging from 1.3 to 3.0 ft in depth in two phases. Separately, two PVC wells (15 and 16 ft deep) were used to investigate tracer movement in a deeper flow system. Over 30 days of phase 1, none of the tracers was detected in the creek water. In phase 2, fluorescein was irregularly detected in the creek at two sites, whereas bromide was detected at one site only. Meanwhile, soil analysis detected measurable diffusion of bromide and fluorescein at four sites. At each of these sites, the tracer was found to be diffusing toward the creek. None of the tracers applied to the deeper PVC wells showed any movement toward the creek over 1 month of continuous sampling. Isotopic composition of water samples varied spatially as well as temporally going from the deep well (δ¹⁸O = ?8.89‰) to the injection holes (average δ¹⁸O = ?8.42‰), to the creek (average δ¹⁸O = ?7.86‰), and further to the rain samples (average δ¹⁸O = ?4.68‰). The analytical error margin is ±0.09‰. Samples from the injection holes were generally heavier than the deep well sample and lighter than the creek samples, indicating that there was no significant connection between the surface and the subsurface systems. Furthermore, the sporadic appearance of bromide and fluorescein both spatially and temporally points to the fact that baseflow does not constitute a significant part of the area's stream discharge. Copyright © 2014 John Wiley & Sons, Ltd.     

Response to the slug injection of a tracer—a large-scale experiment in a natural river / Réponse à l'injection impulsionnelle d'un traceur—expérience à grande échelle en rivière naturelle

Abstract

A unique, large-scale tracer test performed along a 90-km reach of a natural river is presented. This method was crucial for evaluating the impact of a retention reservoir on protected areas of the river downstream, and to assess the threats due to potentially catastrophic releases of toxic substances into that river. The response to the slug injection of a soluble tracer is assumed to imitate the characteristics of a soluble pollutant, so an understanding of how tracers mix and disperse in a stream is essential to understanding the processes of pollution transport. The procedure applied during this experiment consisted of the instantaneous injection of a known quantity of Rhodamine WT into the stream and the determination of the temporal variation in concentration of the tracer at sites as it moved downstream. The results were analysed from the perspective of a transient storage model. Relevant model parameters were evaluated by fitting the computed breakthrough curves to the observed ones on a reach-by-reach basis.     

Long‐term assessment of nutrient flow pathway dynamics and in‐stream fate in a temperate karst agroecosystem watershed

Nutrient dynamics in karst agroecosystems remain poorly understood, in part due to limited long‐term nested datasets that can discriminate upland and in‐stream processes. We present a 10‐year dataset from a karst watershed in the Inner‐Bluegrass Region of central Kentucky, consisting of nitrate (nitrate‐N [NO₃^?]), dissolved reactive phosphorus (DRP), total organic carbon (TOC), and total ammoniacal‐N (TAN) measurements at nested spring and stream sites as well as flowrate at the watershed outlet. Hydrograph separation techniques were coupled with multiple linear regression and Empirical Mode Decomposition time‐series analysis to determine significance of seasonal processes and to generate continuous estimates of nutrient pathway loadings. Further, we used model results of benthic algae growth and decomposition dynamics from a nearby watershed to assess if transient storage in algal biomass could explain differences in spring and downstream watershed nutrient loading. Results highlight statistically significant seasonality for all nutrients at stream sites, but only for NO₃^? at springs with longitudinal variability showing significant decreases occurring from spring to stream sites for NO₃^? and DRP, and significant increases for TOC and TAN. Pathway loading analysis highlighted the importance of slow flow pathways to source approximately 70% of DRP and 80% of NO₃^?. Results for in‐stream dynamics suggest that benthic autotroph dynamics can explain summer deviations for TOC, TAN, and DRP but not NO₃^?. Regarding upland dynamics, our findings agree well with existing perceptions in karst for N pathways and upland source seasonality but deviate from perceptions that karst conduits are retentive of P, reflecting the limited buffering capacity of the soil profile and conduit sediments in the Inner‐Bluegrass. Regarding in‐stream fate, our findings highlighted the significance of seasonally driven nutrient processing in the bedrock‐controlled streambed to influence nutrient fluxes at the watershed outlet. Contrary to existing perceptions, we found high N attenuation and an unexplained NO₃^? sink in the bedrock stream, leading us to postulate that floating macrophytes facilitate high rates of denitrification.     

Seasonal dynamics and exports of elements from a first‐order stream to a large inland lake in Michigan

Headwater streams are critical components of drainage systems, directly connecting terrestrial and downstream aquatic ecosystems. The amount of water in a stream can alter hydrologic connectivity between the stream and surrounding landscape and is ultimately an important driver of what constituents headwater streams transport. There is a shortage of studies that explore concentration–discharge (C‐Q) relationships in headwater systems, especially forested watersheds, where the hydrological and ecological processes that control the processing and export of solutes can be directly investigated. We sought to identify the temporal dynamics and spatial patterns of stream chemistry at three points along a forested headwater stream in Northern Michigan and utilize C‐Q relationships to explore transport dynamics and potential sources of solutes in the stream. Along the stream, surface flow was seasonal in the main stem, and perennial flow was spatially discontinuous for all but the lowest reaches. Spring snowmelt was the dominant hydrological event in the year with peak flows an order of magnitude larger at the mouth and upper reaches than annual mean discharge. All three C‐Q shapes (positive, negative, and flat) were observed at all locations along the stream, with a higher proportion of the analytes showing significant relationships at the mouth than at the mid or upper flumes. At the mouth, positive (flushing) C‐Q shapes were observed for dissolved organic carbon and total suspended solids, whereas negative (dilution) C‐Q shapes were observed for most cations (Na⁺, Mg²⁺, Ca²⁺) and biologically cycled anions (NO₃^?, PO₄^3?, SO₄^2?). Most analytes displayed significant C‐Q relationships at the mouth, indicating that discharge is a significant driving factor controlling stream chemistry. However, the importance of discharge appeared to decrease moving upstream to the headwaters where more localized or temporally dynamic factors may become more important controls on stream solute patterns.     

Transformations of runoff chemistry in the Arctic tundra,Northwest Territories,Canada

The transformation of snowmelt water chemical composition during melt, elution and runoff in an Arctic tundra basin is investigated. The chemistry of the water flowing along pathways from the surface of melting snow to the 95·5 ha basin outlet is related to relevant hydrological processes. In so doing, this paper offers physically based explanations for the transformation of major ion concentrations and loads of runoff water associated with snowmelt and rainfall along hydrological pathways to the stream outlet. Late‐lying snowdrifts were found to influence the ion chemistry in adjacent reaches of the stream channel greatly. As the initial pulse of ion‐rich melt water drained from the snowdrift and was conveyed through hillslope flowpaths, the concentrations of most ions increased, and the duration of the peak ionic pulse lengthened. Over the first 3 m of overland flow, the concentrations of all ions except for NO increased by one to two orders of magnitude, with the largest increase for K⁺, Ca²⁺ and Mg²⁺. This was roughly equivalent to the concentration increase that resulted from percolation of relatively dilute water through 0·25 m of unsaturated soil. The Na⁺ and Cl^? were the dominant ions in snowmelt water, whereas Ca²⁺ and Mg²⁺ dominated the hillslope runoff. On slopes below a large melting snowdrift, ion concentrations of melt water flowing in the saturated layer of the soil were very similar to the relatively dilute concentrations found in surface runoff. However, once the snowdrift ablated, ion concentrations of subsurface flow increased above parent melt‐water concentrations. Three seasonally characteristic hydrochemical regimes were identified in a stream reach adjacent to late‐lying snowdrifts. In the first two stages, the water chemistry in the stream channel strongly resembled the hillslope drainage water. In the third stage, in‐stream geochemical processes, including the weathering/ion exchange of Ca²⁺ and Mg²⁺, were the main control of streamwater chemistry. Copyright © 2006 John Wiley & Sons, Ltd.     

A stream tracer technique employing ionic tracers and specific conductance data applied to the Maimai catchment,New Zealand

The stream tracer technique and transient storage models (TSMs) have become common tools in stream solute and hyporheic exchange studies. The expense and logistics associated with water sample collection and analysis often results in limited temporal resolution of stream tracer breakthrough curves (BTCs). Samples are often collected without a priori or real‐time knowledge of BTC information, which can result in poor sample coverage of the critical shoulder (initial rise) and tail (post‐steady state fall) of the BTC. We illustrate the use of specific conductance (SC) measurements as a surrogate for conservative dissolved tracer (Br⁻) samples. The advantages of collecting SC data for use in the TSM are (1) cost, (2) ease of data collection, and (3) well‐defined breakthrough curves, which strengthen TSM parameter optimization. This method is based on developing an ion concentration (IC)–SC relationship from limited discrete tracer solute samples. SC data can be collected on a more frequent basis at no additional analysis cost. TSM simulations can then be run for the conservative tracer data derived from SC breakthrough curves and the IC–SC relationship. This technique was tested in a 120 m reach of stream (2–60 m subreaches) in the Maimai M15 catchment, New Zealand during baseflow recession. Dissolved LiBr was injected for 12·92 h, with Br⁻ as the conservative ion of interest. Four TSM simulations using the OTIS model are optimized using UCODE to fit (1) Br⁻ data derived from the Br⁻–SC relationship (n = 1307 observations at each of two stream sampling sites), (2) all stream Br⁻ data collected (n = 58 in upper reach, n = 60 in lower reach), (3) half of the stream Br⁻ data collected, and (4) 20 stream Br⁻ samples from each site. No two simulations resulted in the same optimal parameter values. Results suggest that the greater the frequency of observations, the greater the confidence in estimated parameter values. Br⁻–SC simulations resulted in the best overall model fits to the data, with the lowest calculated error variance of 6·37, narrowest 95% parameter estimate confidence intervals, and the highest correlation coefficient of 0·99 942, among the four simulations. This is largely due to the improved representation of the shoulder and tail of the BTC with this method. The IC–SC correlation method is robust in situations in which (1) changes in background SC data can be accounted for, and (2) the data used to define the IC–SC relationship are representative of the range of data collected. This method provides more efficient sample analysis, improved data resolution, and improved model results compared to the alternative stream tracer data gathering methods presented. Additionally, we describe a new parameterization of the cross‐sectional area of the stream during flow recession, as a function of discharge, based on a stream hydraulic geometry relationship. This variant of the OTIS model provides a more realistic representation of stream dynamics during unsteady discharge. Copyright © 2005 John Wiley & Sons, Ltd.