Phase diagrams of the FeO-MgO-SiO2 system and the structure of the mantle discontinuities

Internally consistent thermodynamic computation of equilibria in the FeO-MgO-SiO₂ system up to 300 kbar is carried out and phase diagrams and profiles of the elastic properties and density are constructed at the depths of 300–800 km. Comparisons of calculated thermodynamic properties for different petrological models with seismic velocity profiles have been used to constrain the mineralogy of the mantle discontinuities. The 400-km discontinuity may represent the univariant or divariant transition in the olivine component of pyrolite as well as a chemical boundary. For the pyrolite composition at the depth of 650 km there are two different spinel + perovskite + stishovite (640 km) and magnesiowustite + spinel + perovskite (650 km) divariant loops (1–2 km wide) separated by a Invariant zone spinel + perovskite (4–6 km wide). The results indicate that phase changes in pyrolite do not explain the 650-km discontinuity. It is also shown that it is impossible to match the seismic properties observed at the depths of 600–800 km and through the discontinuity with any isochemical petrological model considered in the FMS system. However, increasing the iron content or silica and iron contents across the 650-km discontinuity can produce thermodynamic properties in the lower mantle that are more consistent with those inferred from seismic observations. Constraints on the SiO₂ and iron contents in the mantle are inferred from the comparison of thermodynamic and seismological data.     

Magmatic evolution of the material of the Earth’s lower mantle: Stishovite paradox and origin of superdeep diamonds (Experiments at 24–26 GPa)

The ultrabasic–basic magmatic evolution of the lower mantle material includes important physicochemical phenomena, such as the stishovite paradox and the genesis of superdeep diamonds. Stishovite SiO₂ and periclase–wüstite solid solutions, (MgO · FeO)_ss, associate paradoxically in primary inclusions of superdeep lower mantle diamonds. Under the conditions of the Earth’s crust and upper mantle, such oxide assemblages are chemically impossible (forbidden), because the oxides MgO and FeO and SiO₂ react to produce intermediate silicate compounds, enstatite and ferrosilite. Experimental and physicochemical investigations of melting phase relations in the MgO–FeO–SiO₂–CaSiO₃ system at 24 GPa revealed a peritectic mechanism of the stishovite paradox, (Mg, Fe)SiO₃ (bridgmanite) + L = SiO₂ + (Mg, Fe)O during the ultrabasic–basic magmatic evolution of the primitive oxide–silicate lower mantle material. Experiments at 26 GPa with oxide–silicate–carbonate–carbon melts, parental for diamonds and primary inclusions in them, demonstrated the equilibrium formation of superdeep diamonds in association with ultrabasic, (Mg, Fe)SiO₃ (bridgmanite) + (MgO · FeO)_ss (ferropericlase), and basic minerals, (FeO · MgO)_ss (magnesiowüstite) + SiO₂ (stishovite). This leads to the conclusion that a peritectic mechanism, similar to that responsible for the stishovite paradox in the pristine lower mantle material, operates also in the parental media of superdeep diamonds. Thus, this mechanism promotes both the ultrabasic–basic evolution of primitive oxide–silicate magmas in the lower mantle and oxide–silicate–carbonate melts parental for superdeep diamonds and their paradoxical primary inclusions.     

High-pressure phase transitions of anorthosite crust in the Earth's deep mantle

We investigated phase relations, mineral chemistry, and density of lunar highland anorthosite at conditions up to 125 GPa and 2000 K. We used a multi-anvil apparatus and a laser-heated diamond-anvil cell for this purpose. In-situ X-ray diffraction measurements at high pressures and composition analysis of recovered samples using an analytical transmission electron microscope showed that anorthosite consists of garnet, CaAl₄Si₂O₁₁-rich phase (CAS phase), and SiO₂ phases in the upper mantle and the mantle transition zone. Under lower mantle conditions, these minerals transform to the assemblage of bridgmanite, Ca-perovskite, corundum, stishovite, and calcium ferrite-type aluminous phase through the decomposition of garnet and CAS phase at around 700 km depth. Anorthosite has a higher density than PREM and pyrolite in the upper mantle, while its density becomes comparable or lower under lower mantle conditions. Our results suggest that ancient anorthosite crust subducted down to the deep mantle was likely to have accumulated at 660–720 km in depth without coming back to the Earth's surface. Some portions of the anorthosite crust might have circulated continuously in the Earth's deep interior by mantle convection and potentially subducted to the bottom of the lower mantle when carried within layers of dense basaltic rocks.     

Phase transformation studies on a synthetic hedenbergite up to 26 GPa at 1200° C

Phase transformations in a synthetic hedenbergite (CaFeSi₂O₆) have been observed with X-ray diffraction up to 26 GPa at 1200° C in a diamond anvil cell with a YAG laser heating system. Hedenbergite first decomposes into spinel, stishovite, and cubic perovskite phases at 16 GPa, and spinel further decomposes into wüstite and stishovite at 19 GPa. Between 19 GPa and 26 GPa, the phase assemblage is wüstite + stishovite+ perovskite. On decompression to 0.1 MPa, all the highpressure phases are retained except the cubic perovskite, which reverts to a retrogressive phase of CaSiO₃. A comparison of the results of this study with those from a previous study on a natural hedenbergite suggests that the garnet phase formed from natural hedenbergite is stabilized by manganese.     

Calculations of pressure-induced phase transitions in mantle minerals

The crystal structures and energies of SiO₂ stishovite, MgO periclase, Mg₂SiO₄ spinel, and MgSiO₃ perovskite were calculated as a function of pressure with the polarization-included electron gas (PEG) model. The calculated pressures of the spinel to perovskite phase transitions in the Mg₂SiO₄ and MgSiO₃ systems are 26.0 GPa and 27.0 GPa, respectively, compared to the experimental zero temperature extrapolations of 27.4 GPa and 27.7 GPa. The two oxide phases are found to be the most stable form in the pressure range 24.5 GPa to 31.5 GPa, compared to the experimental zero temperature extrapolation of 26.7 GPa to 28.0 GPa. The volume changes associated with the phase transitions are in good agreement with experiment. The transition pressures calculated with the PEG model, which allows the ions to distort from spherical symmetry, are in much better agreement with experiment than those calculated with the modified electron gas (MEG) model, which constrains the ions to be spherical.     

The stishovite paradox in the evolution of lower mantle magmas and diamond-forming melts (experiment at 24 and 26 GPa)

Experimental studies of phase relations in the oxide–silicate system MgO–FeO–SiO₂ at 24 GPa show that the peritectic reaction of bridgmanite controls the formation of stishovite as a primary in situ mineral of the lower mantle and as an effect of the stishovite paradox. The stishovite paradox is registered in the diamond-forming system MgO–FeO–SiO₂–(Mg–Fe–Ca–Na carbonate)–carbon in experiments at 26 GPa as well. The physicochemical mechanisms of the ultrabasic–basic evolution of deep magmas and diamondforming media, as well as their role in the origin of the lower mantle minerals and genesis of ultradeep diamonds, are studied.     

Spinel-anthophyllite rocks of the Kokchetav massif (northern Kazakhstan)

Spinel-anthophyllite rocks that may be classified as ultrabasic low-Ca spinel amphibolites have been first discovered in the Kokchetav collision zone (northern Kazakhstan). They outcrop 2 km west of Enbek-Berlyk Village among schists and quartzites and are closely associated with spinel harzburgites and garnet pyroxenites. The main hosted minerals are spinel (hercynite) and anthophyllite. The rocks bear magnetite-hornblende-spinel-anthophyllite pseudomorphs with rounded and polygonal sections, which might have been resulted from the replacement of garnet grains. The prismatic anthophyllite crystals and scarce olivine relics contain elongate parallel spinel inclusions resembling spinel-olivine syntactic intergrowths in the Enbek-Berlyk spinel harzburgites. The spinel-anthophyllite rocks are similar to the associated spinel harzburgites in CaO, MnO, SiO₂, and Al₂O₃ contents but are richer in FeO and poorer in MgO (F = FeO/(FeO + MgO) = 57% against 35% in the harzburgites). Geological, mineralogical, and geochemical data suggest that the spinel-anthophyllite rocks formed during the isochemical contact metamorphism of garnet-bearing spinel harzburgites, which contained more FeO and less MgO than garnet-free harzburgites of the same area. Variations in FeO and MgO contents in both types of harzburgites seem to be due to different chemical compositions of the chlorite protoliths of these rocks.     

Decarbonation reaction of magnesite in subducting slabs at the lower mantle

High-pressure and temperature experiments (28–62 GPa, and 1,490–2,000 K, corresponding to approximately 770–1,500 km depth in the mantle) have been conducted on a MgCO₃ + SiO₂ mixture using a laser-heated diamond anvil cell combined with analytical transmission electron microscope observation of the product phases to constrain the fate of carbonates carried on the subducting basalt into the lower mantle. At these conditions, the decarbonation reaction MgCO₃ (magnesite) + SiO₂ (stishovite) → MgSiO₃ (perovskite) + CO₂ (solid) has been recognized. This indicates that above reaction takes place as a candidate for decarbonation of the carbonated subducting mid ocean ridge basalts in the Earth’s lower mantle.     

陆壳超深俯冲到斯石英稳定域地幔深度(~300 km)的新证据

南阿尔金高压-超高压变质岩带泥质片麻岩中发现先存斯石英出溶蓝晶石+尖晶石的显微结构证据,将陆壳深俯冲的深度推进到了斯石英稳定域的地幔深度（≥ 300 km）.然而,该类岩石是局部出现的还是具有一定的普遍性以及又是如何折返出露地表的?十多年来一直困惑着地球科学界.针对这一科学问题,通过系统的岩石学研究,在南阿尔金榴辉岩中首次发现了斯石英副象,重新厘定南阿尔金英格利萨依石榴辉石岩中石榴子石出溶单斜辉石和北秦岭松树沟长英质片麻岩中石榴石出溶石英棒状体岩石的峰期变质压力为9~10 GPa的斯石英稳定域,结合先期南阿尔金泥质片麻岩中发现先存斯石英出溶显微结构的研究成果,论证提出陆壳俯冲到斯石英稳定域的地幔深度（~300 km）,然后再折返回地表的地质现象可能更为普遍,其岩石类型也可能具有多样性.通过高温高压实验研究,明确SiO₂饱和岩石体系中石榴子石超硅的最小稳定条件为≥ 9~10 GPa斯石英稳定域,为识别辨认陆壳岩石俯冲到斯石英稳定域地幔深度的研究提供了新的借鉴和思路.      

A study of phase transformation in hedenbergite to 40 GPa at ∼1200° C

Phase transformations in a natural sample of hedenbergite ((Ca_0.93Fe_0.61Mn_0.34Mg_0.08Na_0.01Zn_0.02Al_0.003)Si₂O₆) have been studied by X-ray diffraction up to 40 GPa at ∼ 1200°C in a diamond anvil cell interfaced with a laser heating system. The starting hedenbergite phase decomposed into a garnet plus γ-spinel and stishovite at ∼ 14 GPa; then into garnet plus stishovite and wüstite at ∼ 18 GPa; and finally into perovskite plus stishovite and wüstite at pressures higher than ∼ 24 GPa. On decompression to 0.1 MPa, all the high pressure phases are retained except for the cubic perovskite, which reverts back into the ɛ-CaSiO₃ phase, in accordance with previous reports. Energy-dispersive SEM analyses show that the garnet is present as a calcium-rich ABO ₃-type phase. As no garnet phase has been previously observed either in pure CaSiO₃ or in pure CaMgSi₂O₆, it appears that the observed calcium-rich garnet phase has been stabilized by the presence of other cations such as the Na⁺, Zn²⁺, Mn²⁺, Fe²⁺, Mn³⁺, Fe³⁺ and Al³⁺.     

Internally consistent gahnitic spinel-cordierite-garnet equilibria in the FMASHZn system: geothermobarometry and applications

The equilibrium (Mg, Fe, Zn)₃Al₂Si₃O₁₂+2Al₂SiO₅=3(Mg, Fe, Zn)Al₂O₄+5SiO₂ garnet + sillimanite/kyanitc = spinel + quartz was calibrated in the piston-cylinder apparatus between 11 and 30 kbar, and over the temperature range of 950 to 1200°C. Three experimental mixes of Mg no. [100^*MgO/(MgO+FeO)] 40, 47 and 60, in the FeO –MgO–Al₂O₃–SiO₂–ZnO (FMASZn) system were used under low oxygen fugacities and anhydrous conditions. We derive a ternary Fe–Mg–Zn symmetric mixing model for aluminous spinels in equilibrium with garnet, to quantify the increase in gahnitic end-member of spinel with increasing pressure and descreasing temperature. Further experiments in the spinel-cordieritequartz-sillimanite field were combined with garnet-cordierite data from the literature to produce a consistent set of equations describing the exchange reactions in FMASHZn relevant to quartz-sillimanite bearing rocks at granulite facies conditions. As spinel is an important mineral participating in many rocks of aluminous composition at granulite-facies conditions, and as zinc contributes to an enlargement of spinel's stability field towards higher pressures and lower temperatures, the thermobarometric calibrations presented here will be most significant in delineating the prograde and retrograde trajectory of P-T paths.     

A quantum-mechanical study of the relative stability under pressure of MgSiO3-ilmenite,MgSiO3-perovskite,and MgO-periclase+SiO2-stishovite assemblage

The relative stability of MgSiO₃-ilmenite, MgSiO₃-perovskite and (periclase+stishovite) assemblage phases as a function of the pressure is investigated with the periodic quantum mechanical ab initio HartreeFock program CRYSTAL. For the first time, the structure of MgSiO₃-ilmenite is fully optimized. Basis set effects are explored. It turns out that relatively small basis sets reproduce correctly experimental geometries. However, larger basis sets (triple zeta quality, plus polarization d functions) are needed to yield significant thermochemical results. All contributions to the 0 K enthalpy are discussed. On the basis of the present highest level calculations, it appears that in the explored range of pressure (0P< 60=" gpa)=" the=" mineralogical=" assemblage=" periclase+stishovite=" has=" higher=" enthalpy=" than=">₃-ilmenite or perovskite, and that ilmenite transforms to orthorhombic perovskite around to 29.4 GPa in good agreement with experimental data extrapolated down to 0 K.     

蛇绿岩地幔岩中自由SiO2的发现及其地质意义

自由SiO_2系指石英及其同质多型物(polymorphs)柯石英、斯石英等。石英广泛分布于地壳中的各种岩石中,柯石英和斯石英只存在于超高压岩石和陨石坑中。由于石英和非饱和SiO_2的橄榄石不能共生,因此在地幔橄榄岩和超镁铁岩中不存在原生石英。最近笔者在西藏罗布莎蛇绿岩的地幔岩(方辉橄榄岩)的豆荚状铬铁矿中发现了自由SiO_2和柯石英相。根据高温高压相平衡实验资料,橄榄石、辉石这样的硅酸盐矿物在地幔深部的压力条件下可以分解成简单氧化物,如FeO(方铁矿)、MgO(方镁石)以及SiO_2(斯石英)等。由此推测,西藏蛇绿岩地幔岩中自由SiO_2可能是来自于下地幔的矿物,是地幔柱作用将其搬运到上地幔浅部。     

Diopside-jadeite join at 16–22 GPa

Phase relations on the diopside-jadeite join were experimentally determined at 16–22 GPa pressures and temperatures in the vicinity of 1500 °C under hydrous and 2100 °C under anhydrous conditions, using a split-sphere anvil apparatus (USSA-2000). Starting compositions on the diopside-jadeite join produced assemblages containing CaSiO₃ perovskite. This assured that the coexisting garnet with compositions in the ternary system Mg₂Si₂O₆(En)-CaMgSi₂O₆(Di)-NaAlSi₂ O₆(Jd) had the maximum Ca content possible under the given conditions. Garnet reached its maximum Ca content at 17 GPa, and exsolved CaSiO₃ perovskite at higher pressures. The garnet composition closest to the join, En₅Di_47.5Jd_47.5 (mol%), was reached at 18–19 GPa and 2100 °C. The maximum Na content of garnet limited by the coexisting pyroxene did not exceed 51 mol% jadeite at 22 GPa and 2100 °C. At 22 GPa, pyroxene was replaced with NaAlSiO₄ (calcium ferrite structure) and stishovite under anhydrous conditions, while in the presence of H₂O a new hydrous Na-bearing phase with the ideal composition Na₇(Ca, Mg)₃AlSi₅O₉(OH)₁₈ was synthesized instead. Garnet coexisting with CaSiO₃ perovskite and MgSiO₃ ilmenite at 22 GPa and 1400 °C was En₅₁Di₉Jd₄₀, coincidentally identical to the first garnet forming in the ternary system at 13 GPa. The new data are applicable to the Earth's transition zone (400–670 km depths) and suggest that the transformation from eclogite to garnetite would occur primarily over a limited depth interval from 400 to 500 km. Gaps in the observed garnet compositions suggest immiscibility, which could potentially cause a sharp 400 km discontinuity in an eclogitic mantle.     

Preferential dissolution of SiO<Subscript>2</Subscript> from enstatite to H<Subscript>2</Subscript> fluid under high pressure and temperature

Stability and phase relations of coexisting enstatite and H₂ fluid were investigated in the pressure and temperature regions of 3.1–13.9 GPa and 1500–2000 K using laser-heated diamond-anvil cells. XRD measurements showed decomposition of enstatite upon heating to form forsterite, periclase, and coesite/stishovite. In the recovered samples, SiO₂ grains were found at the margin of the heating hot spot, suggesting that the SiO₂ component dissolved in the H₂ fluid during heating, then precipitated when its solubility decreased with decreasing temperature. Raman and infrared spectra of the coexisting fluid phase revealed that SiH₄ and H₂O molecules formed through the reaction between dissolved SiO₂ and H₂. In contrast, forsterite and periclase crystals were found within the hot spot, which were assumed to have replaced the initial orthoenstatite crystals without dissolution. Preferential dissolution of SiO₂ components of enstatite in H₂ fluid, as well as that observed in the forsterite H₂ system and the quartz H₂ system, implies that H₂-rich fluid enhances Mg/Si fractionation between the fluid and solid phases of mantle minerals.     

Enstatite-jadeite join and its role in the Earth's mantle

Phase relations on the enstatite-jadeite join were experimentally determined at solidus temperatures and 90–152 kb, and at 1400–2050°C/175–219 kb, with a split-sphere anvil apparatus (USSA-2000). New findings include immiscibility in garnet and determination of the stability of NaAlSiO₄ (calcium ferrite structure) with stishovite. A thermodynamic model for the enstatite-jadeite join was developed to calculate a complete phase diagram for the join at 500–2500°C and 0–270 kb. The results indicate that the two major discontinuities in the Earth's mantle at 400 and 670 km depths could correspond respectively to the formation and the breakdown of garnet with a pyroxene composition. A model for a chondritic upper mantle is proposed in which large-scale chemical and mineral layering was produced by fractionation of liquidus phases in a magma ocean. Solidification was completed at 400 km depth by crystallization of sodium-enriched residual melts, which produced a pyroxene layer at 300–400 km depths.     

Garnet and spinel lherzolite assemblages in MgO–Al2O3–SiO2 and CaO–MgO–Al2O3–SiO2: thermodynamic models and an experimental conflict

The recent publication of an updated thermodynamic dataset for petrological calculations provides an opportunity to illustrate the relationship between experimental data and the dataset, in the context of a new set of activity–composition models for several key minerals. These models represent orthopyroxene, clinopyroxene and garnet in the system CaO–MgO–Al₂O₃–SiO₂ (CMAS), and are valid up to 50 kbar and at least 1800 °C; they are the first high‐temperature models for these phases to be developed for the Holland & Powell dataset. The models are calibrated with reference to phase‐relation data in the subsystems CaO–MgO–SiO₂ (CMS) and MgO–Al₂O₃–SiO₂ (MAS), and will themselves form the basis of models in larger systems, suitable for calculating phase equilibria in the crust and mantle. In the course of calibrating the models, it was necessary to consider the reaction orthopyroxene + clinopyroxene + spinel = garnet + forsterite in CMAS, representing a univariant transition between simple spinel and garnet lherzolite assemblages. The high‐temperature segment of this reaction has been much disputed. We offer a powerful thermodynamic argument relating this reaction to the equivalent reaction in MAS, that forces us to choose between good model fits to the data in MAS or to the more recent data in CMAS. We favour the fit to the MAS data, preserving conformity with a large body of experimental and thermodynamic data that are incorporated as constraints on the activity–composition modelling via the internally consistent thermodynamic dataset.     

A redox profile of the Slave mantle and oxygen fugacity control in the cratonic mantle

The authors report a redox profile based on Mössbauer data of spinel and garnet to a depth of 210 km from mantle xenoliths of the northern (N) and southeastern (SE) Slave craton (northern Canada). The profile transects three depth facies of peridotites that form segments of different bulk composition, represented by spinel peridotite, spinel–garnet peridotite, low-temperature garnet peridotite, high-temperature garnet peridotite, and pyroxenite. The shallow, more depleted N Slave spinel peridotite records lower oxygen fugacities compared to the deeper, less depleted N Slave spinel–garnet peridotite, consistent with their different spinel Fe³⁺ concentrations. Garnet peridotites show a general reduction in log fO₂ (FMQ)s with depth, where values for garnet peridotites are lower than those for spinel–garnet peridotites. There is a strong correlation between depletion and oxygen fugacity in the spinel peridotite facies, but little correlation in the garnet peridotite facies. The strong decrease in log fO₂ (FMQ) with depth that arises from the smaller partial molar volume of Fe³⁺ in garnet, and the observation of distinct slopes of log fO₂ (FMQ) with depth for spinel peridotite compared to spinel–garnet peridotite strongly suggest that oxygen fugacity in the cratonic peridotitic mantle is intrinsically controlled by iron equilibria involving garnet and spinel.

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Alteration of Al-rich inclusions inside amoeboid olivine aggregates in the Allende meteorite

Lightly altered Al-rich inclusions in amoeboid olivine aggregates have cores containing primary melilite + fassaite + spinel + perovskite and no secondary alteration products. In moderately altered inclusions, whose cores now contain only fassaite + spinel + perovskite, melilite was replaced by a fine-grained mixture of grossular + anorthite + feldspathoids and perovskite was partially replaced by ilmenite. In heavily altered inclusions, fassaite has been replaced by a mixture of phyllosilicates + ilmenite and the remaining primary phases are spinel ± perovskite. In very heavily altered inclusions, no primary phases remain, the spinel having reacted to form either phyllosilicates or a mixture of olivine + feldspathoids. This sequence of alteration reactions may reflect successively lower solar nebular equilibration temperatures. During alteration, SiO₂, Na₂O, K₂O, FeO, Cr₂O₃, H₂O and Cl were introduced into the inclusions and CaO was lost. MgO may have been lost during the melilite reaction and added during formation of phyllosilicates. Electron microprobe analyses indicate that the phyllosilicates are a mixture of Na-rich phlogopite and chlorite or Alrich serpentine. Thermodynamic calculations suggest that, at a solar nebular water fugacity of 10⁻⁶, Na-rich phlogopite could have formed from fassaite at ~470 K and chlorite from Na-rich phlogopite at ~328 K. Olivine mantling Al-rich inclusions is not serpentinized, suggesting that these objects stopped equilibrating with the nebular gas above 274 K.     

Sodium-rich metasomatism in the upper mantle: Implications of experiments on the pyrolite-Na2O-rich fluid system at 950°C, 20 kbar

Sodium-rich metasomatism in the upper levels of the mantle has been modelled by reacting pyrolite with alkali-bearing H₂O fluids containing minor CO₂ and concentrations of Na₂O and Na₂O + K₂O (K/K + Na = 0.1 ) up to 4.0 g alkalies/10 g H₂O at 20 kbar and 950°C. With increasing alkali concentration, the amounts of amphibole (pargasite-edenite) and olivine increase as orthopyroxene and clinopyroxene decrease. Amphiboles show progressive increases in Na (and K) and Si concentrations and decreases in Al and Ca concentrations suggesting the dominant substitution mechanism is (Na, K) + SiAl + Ca. These results and least squares mass balance calculations suggest the reaction of clinopyroxene + orthopyroxene + spinel produces amphibole + olivine.In nature, upper mantle spinel lherzolite is commonly veined by a variety of rock types which may contain Ti-pargasite as a magmatic crystallization product. Pargasite-edenite occurs interstitially in spinel Iherzolite, often spatially related to Ti-pargasite and may be produced by hydrous fluids evolved during late stage crystallization of the veined rocks. This is supported by the close compositional correlation between the natural pargasite-edenite amphiboles and those produced in this study.The present study suggests that up to 43 wt.% amphibole may be accommodated in pyrolite in the presence of Na₂O-rich H₂O-CO₂ fluids. This represents 0.8 wt.% H₂O and 1.7 wt.% Na₂O in the hydrated pyrolite composition and indicates the importance of sodium in determining the extent of metasomatism. Sodium also lowers the solidus temperature of pyrolite by more than 50°C over the H₂O-saturated pyrolite system at 20 kbar.