Characteristics of Piezometric heads and determination of fresh water–salt water interface in the coastal zone near Beihai,China

Changes in hydraulic heads with space and time and evolution of the location of fresh water–salt water interface are important for groundwater development in coastal aquifers. Measurements of piezometric heads at 11 well clusters consisting of three piezometric wells of different depths with a 5-day interval for 15 months show that the piezometric heads at nearly all the wells near the northwestern coast in Beihai decrease with increasing depth and increase with increasing distance from the coast. Changes in piezometric heads at the wells during the measurement period were caused by seasonal precipitation and induced by the tide. The depth of the sharp interface between fresh water–salt water can be estimated based on measurements of piezometric heads at a piezometric well tapping at a point in the salt water zone below the interface and measurements of the water table at the same well. The calculations of the interface for well H5 range from 40 to 80 m below sea level in the measurement period, which are believed to be more reasonable than those estimated with the Ghyben–Herzberg relation. An erratum to this article can be found at     

Characteristics of natural low pH groundwater in the coastal aquifers near Beihai, China

Groundwater with low total dissolved solids （less than 200 mg/L） occurs in the unconfined and confined aquifers near Beihai in southern Guangxi, China. Under natural conditions the groundwater ranges in pH from 3,33 to 7,0 with an average value of 5.12. The pH in the unconfined aquifer varies from 3.67 to 7.0 with an average value of 5.17 and the pH in the confined aquifer is in the range 3.33-6.97 with an average value of 5.07. The pH in the groundwater does not show significantly increasing or decreasing trends with time. Fluctuations in pH exist at some of the monitoring wells and the pH in groundwater is a bit higher in the rainy season than in the dry season, Monitoring data show that the pH in rainwater is higher than in groundwater in the unconfined aquifer, whereas the pH in the latter is a bit higher than in the confined aquifer. A slightly decreasing trend in the pH was also found from the inland area to the coastal zone. The occurrence of weakly acidic groundwater in this area is attributed to the recharge from low pH precipitation and the multi-aquifer and leaky groundwater system.     

Determination of the distance of the fresh water–salt water interface extending into coastal confined aquifers

In a coastal zone an understanding of the distance of the fresh water–salt water interface and its extension inland is important for prevention of sea water intrusion. In this article estimating methods are described for calculating the distance of a fresh water–salt water interface in a coastal confined aquifer based on the submarine fresh groundwater discharge. This groundwater discharge is controlled not only by the aquifer properties and hydraulic head difference, but also by the position of the fresh water–salt water interface in the coastal zone. A homogeneous and isotropic coastal confined aquifer is considered and fresh groundwater flow in the confined aquifer is thought to be at a steady state. Two observation wells at different distances in a profile perpendicular to the coastline are required in calculation of the distance of the interface toe in the coastal zone. Four coastal confined aquifers with horizontal and sloping confining beds and with varying thickness are also considered. Reasonable results are obtained when examples are used to illustrate the application of the methods. The methods require hydraulic head data at the two wells and thickness of the confined aquifers, but the hydraulic conductivity and fresh groundwater flow rate of the confined aquifers are not needed.     

Modeling of water–rock interactions in an aquitard of sandy clay in the coastal area near Beihai,China

Unconsolidated sand, gravel and clay deposits near Beihai and in the Leizhou Peninsula in southern China form an unconfined aquifer, aquitard and a confined aquifer. Water and soil samples were collected from the two aquifers in the coastal Beihai area for the determination of chemical compositions, minerals and soluble ions. Hydrogeochemical modeling of three flow paths through the aquitard are carried out using PHREEQC to determine water–rock interactions along the flow paths. The results indicate that the dissolution of anorthite, fluorite, halite, rhodochrosite and CO₂, and precipitation of potash feldspar and kaolinite may be occurring when groundwater leaks through the aquitard from the unconfined aquifer to the confined aquifer. Cation exchanges between Na and Ca can also happen along the flow paths.     

Factors controlling the configuration of the fresh–saline water interface in the Dead Sea coastal aquifers: synthesis of TDEM surveys and numerical groundwater modeling

TDEM (time domain electromagnetic) traverses in the Dead Sea (DS) coastal aquifer help to delineate the configuration of the interrelated fresh-water and brine bodies and the interface in between. A good linear correlation exists between the logarithm of TDEM resistivity and the chloride concentration of groundwater, mostly in the higher salinity range, close to that of the DS brine. In this range, salinity is the most important factor controlling resistivity. The configuration of the fresh–saline water interface is dictated by the hydraulic gradient, which is controlled by a number of hydrological factors. Three types of irregularities in the configuration of fresh-water and saline-water bodies were observed in the study area: 1. Fresh-water aquifers underlying more saline ones ("Reversal") in a multi-aquifer system. 2. "Reversal" and irregular residual saline-water bodies related to historical, frequently fluctuating DS base level and respective interfaces, which have not undergone complete flushing. A rough estimate of flushing rates may be obtained based on knowledge of the above fluctuations. The occurrence of salt beds is also a factor affecting the interface configuration. 3. The interface steepens towards and adjacent to the DS Rift fault zone. Simulation analysis with a numerical, variable-density flow model, using the US Geological Survey's SUTRA code, indicates that interface steepening may result from a steep water-level gradient across the zone, possibly due to a low hydraulic conductivity in the immediate vicinity of the fault. Electronic Publication     

Dynamic freshwater–saline water interaction in the coastal zone of Jeju Island, South Korea

Freshwater–saline water interactions were evaluated in a coastal region influenced by external forces including tidal fluctuations and seasonal rainfall variations. Five different coastal zones were considered on Jeju Island, South Korea, and electrical conductivity (EC) profiles from the monitoring wells were examined to identify the configuration of the freshwater–saline water interface. There appeared to be discrepancies among EC profiles measured at different points in time. To analyze the dynamic behavior of freshwater–saline water interactions, groundwater level measurements and multi-depth EC and temperature probes were used to obtain time-series data; the data showed that water level, EC and temperature were influenced by both tidal fluctuations and heavy rainfall. The effects of oceanic tide on EC and temperature differed with depth due to hydraulic properties of geologic formations. A spectral filter was used to eliminate the effects of tidal forces and provide information on the influence of heavy rainfall on water level, EC and temperature. Heavy rainfall events caused different patterns and degrees of variation in EC and temperature with depth. The time-series data of EC and temperature in the subsurface at various depths enable greater understanding of the interaction processes between fresh and saline water.     

Characteristics of distribution and migration of mercury in the sediment-water interface of Poyang Lake, China

Environmental pollution is one of several essential problems of concern global. Although total mercury concentration in the lake is at trace or even ultra-trace level, it is greatly harmful to human health through food chain by the enrichment in fish, etc…     

Variability of TOC and TN along the coastal salt marshes, Quanzhou Bay, China

Coastal salt marshes contain rich ecosystems and are habitats for many birds and unique halophyte flora; they have high conservation and resource values, sustaining the productivity of estuarine and tidal flat ecosystems and representing important nutrien…     

Three-dimensional configuration and dynamics of the fresh–saline water interface near two saline lakes with different levels (Middle East)

A typical fresh–saline water interface in a coastal aquifer is characterized by saline-water circulation below the interface and freshwater flow above. Both flows are perpendicular to the shoreline. The flow pattern near two separated saline lakes is more complicated. For example, in the Middle East, the Dead Sea northern basin and the evaporation ponds of the Dead Sea Works are adjacent to each other but separated. The northern basin level is dropping by 1.1 m/year and the evaporation ponds’ levels are increasing by 0.2 m/year. The fresh–saline water interface in such situation is numerically simulated. Streamlines parallel or semiparallel to the shoreline are significant. Moreover, the fresh–saline water interface intrudes landward adjacent to the higher saline lake and is pushed lakeward adjacent to the lower saline lake. The simulation results support field observations showing that the interface migrates vertically at a faster rate relative to the changes in the water table and the lake levels.

     

Characteristics of isotope in precipitation,river water and lake water in the Manasarovar basin of Qinghai–Tibet Plateau

The stable hydrogen and oxygen of lake, river, rain and snow waters were investigated to understand the water cycle characteristics of the drainage basin of Manasarovar Lake in Tibet. Both δD and δ ¹⁸O of river water are larger than those of lake water and the effect of altitude on both δD and δ ¹⁸O is not very significant. This phenomenon was suggested to occur because Manasarovar basin is located in Qinghai–Tibet Plateau which has low latitude, high altitude, abundant glaciers, thin air and intensive solar radiation, resulting in higher evaporation in lake water.     

Seasonal variations of arsenic at the sediment–water interface of Poyang Lake,China

Arsenic species including arsenite, arsenate, and organic arsenic were measured in the porewaters collected from Poyang Lake, the largest freshwater lake of China. The vertical distributions of dissolved arsenic species and some diagenetic constituents [Fe(II), Mn(II), S(−II)] were also obtained in the same porewater samples in summer and winter. In sediments the concentration profiles of total As and As species bound to Fe–Mn oxyhydroxides and to organic matter were also determined along with the concentrations of Fe, Mn and S in different extractable fractions. Results indicate that, in the summer season, the concentrations of total dissolved As varying from 3.9 to 55.8 μg/L in sediments were higher than those (5.3–15.7 μg/L) measured in the winter season, while the concentrations of total As species in the solid phase varied between 10.97 and 25.32 mg/kg and between 7.84 and 30.52 mg/kg on a dry weight basis in summer and winter, respectively. Seasonal profiles of dissolved As suggest downward and upward diffusion, and the flux of dissolved As across the sediment–water interface (SWI) in summer and winter were estimated at 3.88 mg/m² a and 0.79 mg/m² a, respectively. Based on porewater profiles and sediment phase data, the main geochemical behavior of As was controlled by adsorption/desorption, precipitation and molecular diffusion. The solubility and migration of inorganic As are controlled by Fe–Mn oxyhydroxides in summer whereas they appear to be more likely controlled by both amorphous Fe–Mn oxyhydroxides and sulfides in winter. A better knowledge of the cycle of As in Poyang Lake is essential to a better management of its hydrology and for the environmental protection of biota in the lake.     

Characteristics and Classification of the Geothermal Gradient in the Beijing–Tianjin–Hebei Plain,China

Mathematical Geosciences - Study of the characteristics and classification of geothermal gradients can effectively guide the exploration and development of geothermal resources. In this paper, we...     

Hydrogen sulfide and organic carbon at the sediment–water interface in coastal brackish Lake Nakaumi, SW Japan

The relationship among H₂S, total organic carbon (TOC), total sulfur (TS) and total nitrogen contents of surface sediments (0–1 cm) was examined to quantify the relationship between H₂S concentrations and TOC content at the sediment water interface in a coastal brackish lake, Nakaumi, southwest Japan. In this lake, bottom water becomes anoxic during summer due to a strong halocline. Lake water has ample dissolved SO₄ ^2? and the surface sediments are rich in planktic organic matter (C/N 7–9), which is highly reactive in terms of sulfate reduction. In this setting the amount of TOC should be a critical factor regulating the activity of sulfate reduction and H₂S production. In portions of the lake where sediment TOC content is less than 3.5 %, H₂S was very low or absent in both bottom and pore waters. However, in areas with TOC >3.5 %, H₂S was correlated with TOC content (pore water H₂S (ppm) = 13.9 × TOC (%) ? 52.1, correlation coefficient: 0.72). H₂S was also present in areas with sediment TS above 1.2 % (present as iron sulfide), which suggests that iron sulfide formation is tied to the amount of TOC. Based on this relationship, H₂S production has progressively increased after the initiation of land reclamation projects in Lake Nakaumi, as the area of sapropel sediments has significantly increased. This TOC–H₂S relationship at sediment–water interface might be used to infer H₂S production in brackish–lagoonal systems similar to Lake Nakaumi, with readily available SO₄ ^2? and reactive organic matter.     

Arsenic in the water–soil–plant system and the potential health risks in the coastal part of Chianan Plain,Southwestern Taiwan

The present study investigates the bioavailability, soil to plant transfer and health risks of arsenic (As) in the coastal part of Chianan Plain in southwestern Taiwan. Groundwater used for irrigation, surface soils from agricultural lands and locally grown foodstuffs were collected from eight locations and analyzed for As to assess the risks associated with consuming these items. The concentration of As in groundwater ranged from 13.8 to 881 μg/L, whereas surface soil showed total As content in the range of 7.92–12.7 mg/kg. The available As content in surface soil accounted for 0.06–6.71% of the total As content, and was significantly correlated with it (R² = 0.65, p < 0.05). Among the leachable fraction, the organic matter (3.23–54.8%) and exchangeable portions of oxides (6.03–38.4%) appear to be the major binding phases of As. The average As content in fourteen studied crops and vegetables varied from 10.3 to 151 μg/kg with maximum in mustard and minimum in radish. All the plants showed considerably higher As content (21.5 ± 3.64–262 ± 36.2 μg/kg) in their roots compared to the edible parts (9.15 ± 1.44–75.8 ± 22.9 μg/kg). The bioaccumulation factor (BAF) based on total As (ranging from 0.0009 to 0.144) and available As in soil (ranging from 0.039 to 0.571) indicate that mustard, rice, amaranth and spinach are the highest accumulators of As. Although the health risk index (HRI) of the studied crops and vegetables ranged from only 0.0068–0.454, with the maximum in rice, the combined HRI indicates an alarming value of 0.88. Therefore, the possible health risks due to long-term consumption of rice and other As-rich foodstuffs could be overcome by controlling the contamination pathways in the water–soil–plant system.     

Phosphorus adsorption characteristics at the sediment–water interface and relationship with sediment properties in FUSHI reservoir, China

This study was designed to survey the reservoir sediment properties, assess the phosphorus (P) sorption isotherm, and analyze the relationship between sediment properties and sorption parameters. Physicochemical analysis indicated that sediment from the FUSHI reservoir in Zhejiang Province, China, has similar physical and chemical properties and has been contaminated by P. Sorption isotherm experiments showed that the sorption process could be described by Langmuir and Freundlich models. The parameters of Q _max (Phosphorus sorption maximum) and K (Freundlich adsorption isotherm constant) ranged from 618.98 to 825.70?mg?kg^?1 and 114.18 to 170.74?l?kg^?1, respectively. EPC₀ (zero P equilibrium concentration) ranged from 0.14 to 0.24?mg?l^?1, more than the total P concentration in the water of the reservoir. Thus, the reservoir sediment releases P into the water and acts as a ??P resource??. The clay, Fe_o, Al_t, and Fe_t?+?Al_t content were the main active components in P sorption. Q _max had a highly significant positive relationship with some properties and could be estimated by a combination of these.     

Synchronous release of labile phosphorus,labile ferrum,and labile arsenic in water–sediment interface using ZrO–Chelex measured in the Aibi Lake of Northwest China

In the work presented here, a Zr-oxide diffusive gradients in thin films (DGT) was used to monitor the release flux of phosphorus (P), ferrum (Fe), and arsenic (As) in the water–sediment interface of Aibi Lake—a typical shallow lake located in the arid regions of Northwest China. Results showed that: (1) In the water–sediments interface of Aibi Lake, the ranges (average values) of labile As, labile P, and labile Fe levels in DGTs are 3.846–101.840 (43.934) µg L^?1, 0.006–0.232 (0.070) mg L^?1, and 0.202–52.984 (15.832) mg L^?1, respectively. Among 0–20 cm of the vertical profile there was a stable distribution of three elements, while below the interface as 0 cm–(??80) cm there were relatively large changes of these. (2) Fitting analysis showed that there were significant correlations between labile Fe and labile P, and labile As in four DGTs, which showed that in the water–sediments of Aibi Lake, Fe, P, and As are released simultaneously. (3) Combined with former research, we found that the redox of Fe³⁺ to Fe²⁺ may cause the release of P and As to the sediments and water body from the former Fe–P and Fe–As; the proportion of P/Fe of four DGTs was all relatively lower than 1, suggesting that the redox of Fe³⁺ caused the P to be released. (4) This research showed that the concentrations of P, Fe, and As of the water–sediments interface of the lake was obviously lower than that of the water body and sediments of Aibi Lake as well as others of central and eastern China. ZrO-DGT can accurately reflect the distribution of P, Fe, and As of Aibi Lake. These findings can provide initial verification for the use of ZrO-DGT technology in the research of elements at the water–sediment interface in lakes of Xinjiang Province in Northwest China.     

Age and General Characteristics of the Calimicrobialite near the Permian-Triassic Boundary in Chongyang, Hubei Province

INTRODUCTIONCali microbialites near the Permian-Triassicboundary are a special sedi mentary framework whichis formed on the top of reefs or isolated carbonateplatforms after the end-Permian extinction. Cali mi-crobialite in South China was first found by Lehr-mann (1999) in Bianyang, Guizhou. Al most si multa-neously , Kershawet al .(1999) reported cali microbi-alites in East Sichuan. Discovery of Permian-Triassiccali microbialites in South China has attracted muchattention. Based o…     

Geochemical Characteristics and Origin of Natural Gases in the Qaidam Basin, China

Sixty-five natural gas samples were collected from 19 oil-gasfields in the Qaidam basin, China. The chemical composition and carbon isotope values of the samples were measured, and the geochemical characteristics and origin of the natural gases were studied. The gases can be divided into biogenic gases, sapropelic oil-type gases, mixed type oil-type gases, coal-type gases and mixed gas. The δ13Ci values of the biogenic gases are very small and the C2+ contents of them are very low, ranging from -68.2‰ to -61.8‰ and 0.06% to 0.20% respectively. They have heavy δD and δ13Cco2> showing a CC>2 reduction pathway. They are distributed in the East depression region and derived from the Quaternary source rocks. The sapropelic oil-type gases have small δ13C2 values and high C2+ ranging from -36.6‰ to -28.6‰ and from 33.01% to 47.15% respectively. The mixed type oil-type gases have <5I3C2 values and C2+ contents varying from -28.6‰ to -24.8‰ and from 4.81% to 26.06% respectively. Both sapropelic oil-typ