冀西北宣化晚三叠世中期流纹斑岩的发现及其地质意义

冀西北宣化东部地区ZY1井揭露在中元古界下马岭组页岩中,夹有4层流纹斑岩（浅成侵入）,本文测得其LA-ICPMS锆石U-Pb年龄为226.5±1.9 Ma,表明其侵入阶段为晚三叠世中期。本区流纹斑岩不含碱性铁镁矿物,应不属于碱性岩。本区发现的晚三叠世中期流纹斑岩,丰富了华北克拉通北缘中晚三叠世构造体制由碰撞后/造山后伸展向板内伸展转变过程中较少的非碱性岩类及其测年数据,对华北地块印支期活动历史的分析研究具有重要理论意义,对寻找矿产资源具有现实意义。     

东昆仑那更康切尔银多金属矿床流纹斑岩锆石U-Pb年代学、地球化学特征及其地质意义

那更康切尔银多金属矿床是青海省目前发现的首个大型银矿床,通过对赋矿流纹斑岩进行岩石学、地球化学、锆石U-Pb定年及Hf同位素研究,结果表明:流纹斑岩LA-ICP-MS锆石U-Pb年龄为217.4±3.1 Ma,形成于晚三叠世;流纹斑岩SiO₂的含量在73.08%~75.78%,Al₂O₃含量介于14.05%~16.04%,Na₂O+K₂O含量为4.31%~4.77%,K₂O含量为4.20%~4.61%,K₂O/Na₂O比值远大于1,属于钙碱性强过铝钾质火山岩.岩石具有高硅、富铝、富钾的特征,Mg#值介于45~54,具有明显的轻稀土元素富集,重稀土元素亏损的特征;富集大离子亲石元素Rb、Th、K,亏损Ta、Nb、P、Ti等高场强元素;ε_Hf（t）介于－4.4~－9.7,二阶段Hf模式年龄T_DM2为1 533~1 864 Ma.综上表明流纹斑岩主要源于中元古代－古元古代下地壳重熔,同时混入幔源物质;赋矿流纹斑岩形成于东昆仑晚三叠世造山后伸展环境.那更康切尔大型银矿床的发现,是东昆仑晚三叠世成矿作用的表现,为区域上寻找同期侵入岩或陆相火山岩有关的多金属矿床奠定基础.      

内蒙古宝音图晚二叠世—晚三叠世花岗岩岩石化学特征及其构造环境

宝音图花岗岩基位于华北地台北缘西段,针对其中牙马图岩体、罕乌拉岩体及布格道苏绍崩岩体等的岩石地球化学研究与年代学测定,结果表明岩体时代分别为261Ma±1.3 Ma,220.9 Ma±0.3 Ma和204.9 Ma±5.9 Ma,系晚二叠世—晚三叠世侵入岩体,其岩石类型主要为黑云母花岗闪长岩、斑状黑云母花岗岩和二云母花岗岩,其中晚二叠世花岗闪长岩Na2O/K2O平均值为2.06,A/CNK为0.96~1.15,平均值为1.03,里特曼指数(σ)平均值为1.9,总体属过铝质钙碱性岩;晚三叠世花岗岩Na2O/K2O平均值为0.82,A/CNK为0.92~1.16,平均值为1.03,里特曼指数(σ)为2.18,属过铝质钙碱性岩。岩石化学构造环境分析表明,晚二叠世—晚三叠世早期岩浆活动是俯冲造山过程中形成的具有岛弧性质的闪长岩类和花岗岩类,而晚三叠世晚期岩浆作用是与之有关的造山晚期陆缘花岗岩类。     

辽宁花坤头营子旋卷构造中侵入岩特征与构造演化的关系

花坤头营子侵入岩是花坤头营子旋卷构造的重要组成部分,共分出4个侵入体,分别为早石炭世辉绿岩、早三叠世闪长岩、中侏罗世二长花岗岩、早白垩世花岗斑岩,最晚还有一期流纹斑岩脉侵入.岩浆来源除早石炭世辉绿岩来自上地幔,余下几个序次来源于下地壳,并熔融了部分陆壳物质.以被动就位机制为特征.     

青海祁漫塔格中晚三叠世花岗岩:年代学、地球化学及成矿意义

地处柴达木盆地西南缘的青海祁漫塔格地区不仅是一个特征显著的构造-岩浆岩带,而且也是重要的多金属成矿带。本文对该区中晚三叠世花岗岩开展了详细的年代学、岩石地球化学及Sr-Nd-Pb同位素组成研究,并探讨了成矿意义。结果表明,本区中晚三叠世花岗岩均系准铝质到弱过铝质高钾钙碱性花岗岩类,晚三叠世花岗岩具有更高的K2O/Na2O比值,富集大离子亲石元素(LILE)和轻稀土元素(LREE),明显亏损高场强元素(HFSE),中等初始锶比值和偏负的εNd(t)值表明它们主要源于古老地壳物质的深熔或重熔,并可能有幔源物质的加入;发育闪长质暗色微粒包体的中三叠世花岗岩锆石U-Pb年龄为230～237Ma,大多具斑状或似斑状结构的晚三叠世高分异富钾花岗岩形成于204～228Ma,表明大约240Ma祁漫塔格主造山已由挤压转入伸展并伴有幔源岩浆活动,晚三叠世后演化到后碰撞阶段;中晚三叠世花岗岩与本区密集产出的矽卡岩型和斑岩型多金属矿床的时空与成因关系密切,具有重要找矿指示意义。     

昌都-思茅构造带晚三叠世构造环境的火山岩地球化学判别

青藏东缘昌都-思茅带构造环境的研究对其所蕴含的找矿潜力具有重要意义,中三叠世末,三江联合地体形成,昌都-思茅构造带进入陆内演化阶段.通过对昌都-思茅构造带晚三叠世火山岩地球化学特征及地层学的研究,指出本区晚三叠世火山岩具有堑垒相间的古地貌、双峰式火山岩的火山-沉积组合及显伸展因子的岩浆作用等特点.火山活动主要是沿着乡城形成了所谓滞后形的岛弧岩浆,但很多地质事实表明,这之后并不是挤压的,而是在短暂的挤压后的伸展.对此问题,我们搜集了大量的数据,分析发现火山岩具有双峰特征.并通过岩石地球化学图解投图,指出昌都-思茅构造带在晚三叠世属于伸展构造环境,综合得出本区为陆内裂谷环境.     

东昆仑楚鲁套海酸性侵入体年代学及地球化学特征

野马泉楚鲁套海岩体分布于昆北断裂以北祁漫塔格岩浆弧东部,侵位于奥陶纪祁漫塔格群—志留纪滩间山群碎屑岩组和晚三叠世鄂拉山组,岩石类型主要为花岗斑岩和花岗闪长斑岩。岩石地球化学结果表明该岩体属准铝质—过铝质的钙碱性岩石系列,为A型花岗岩;稀土元素球粒陨石标准配分图呈右倾式,轻稀土富集,重稀土较为平坦,出现强烈Eu亏损;由多种主量及微量元素进行相关的构造环境判别,为后造山的伸展构造环境。在楚鲁套海花岗斑岩中获得了U-Pb同位素年龄为(256.0±9.6)M a,确定其侵位时代为晚二叠世。     

延边地区晚三叠世火山岩的岩石地球化学特征及其构造意义

延边地区晚三叠世火山岩主要由安山岩和流纹岩构成，其中包括少量玄武安山岩。火山岩的岩石化学和地球化学研究表明，晚三叠世火山岩属于亚碱性系列，并具有钙碱性系列演化特征，位于中钾和高钾钙碱性岩系列范围。岩石组合、主要元素和稀土元素(REE)等显示晚三叠世火山岩的形成与活动大陆边缘伸展环境有关，它标志着泛太平洋板块(法拉隆板块)对欧亚大陆作用的开始，同时也标志着古亚洲枸造域的结束。     

沽源火山盆地燕山期次流纹斑岩地质地球化学特征

燕山期次流纹斑岩主要分布在沽源火山盆地盖层的上侏罗统张家口组火山岩中,活动时间以燕山晚期为主.次流纹斑岩体在空间分布上受断裂构造和燕山晚期火山构造控制,与铀钼矿化关系密切,矿化主要产在次流纹斑岩体接触带或其顶部的隐爆角砾岩中.次流纹斑岩与围岩呈侵入接触关系,呈岩株、岩墙、岩脉等形态产出.岩石地球化学研究表明:次流纹斑岩...     

金沙江造山带碰撞后地壳伸展背景——火山成因块状硫化物矿床的重要成矿环境

近年来对金沙江造山带区域地质、矿床地质和岩石地球化学新资料的研究和典型火山成因块状硫化物(VHMS)矿床的解剖,金沙江造山带的VHMS成矿作用主要发生于早二叠世晚期—晚二叠世海相弧火山岩和晚三叠世裂谷盆地海相火山岩中,构成西南三江地区一条重要的多金属块状硫化物成矿带。成矿带内晚三叠世碰撞后地壳伸展背景下形成的上叠裂谷盆地是其VHMS成矿作用的主体,盆地中火山活动从早期的双峰式火山岩演变为晚期的中酸性火山岩,岩石地球化学特征与孤火山岩有明显的区别,反映其形成于伸展背景。伸展盆地的早期阶段,在双峰火山岩组合的高钾流纹质火山岩系中产出鲁春式VHMS矿床,具有Zn-Cu-Pb-Ag金属组合特征,形成于深水环境;伸展盆地的晚期阶段,在中酸性火山岩系与上覆碳酸盐岩接触带中产出赵卡隆式VHMS矿床,具有Ag-Fe-Pb-Zn金属组合特征,形成于浅水环境;盆地的末期阶段,在滨浅海相磨拉石碎屑岩中产出里仁卡式石膏矿床。金沙江造山带碰撞后地壳伸展背景下VHMS成矿作用的研究,对于造山带中的找矿工作具有重要的指导意义。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.