High frequency stream bed mobility of a low‐gradient agricultural stream with implications on the hyporheic zone

Little Kickapoo Creek (LKC), a low‐gradient stream, mobilizes its streambed–fundamentally altering its near‐surface hyporheic zone–more frequently than do higher‐gradient mountain and karst streams. LKC streambed mobility was assessed through streambed surveys, sediment sampling, and theoretical calculations comparing basal shear stress (τ_b) with critical shear stress (τ_c). Baseflow τ_b is capable of entraining a d₅₀ particle; bankfull flow could entrain a 51·2 mm particle. No particle that large occurs in the top 30 cm of the substrate, suggesting that the top 30 cm of the substrate is mobilized and redistributed during bankfull events. Bankfull events occur on average every 7·6 months; flows capable of entraining d₅₀ and d₈₅ particles occur on average every 0·85 and 2·1 months, respectively. Streambed surveys verify streambed mobility at conditions below bankfull. While higher gradient streams have higher potential energy than LKC, they achieve streambed‐mobilization thresholds less frequently. Heterogeneous sediment redistribution creates an environment where substrate hydraulic conductivity (K) varies over four orders of magnitude. The frequency and magnitude of the substrate entrainment has implications on hyporheic zone function in fluid, solute and thermal transport models, interpretations of hyporheic zone stability, and understanding of LKC's aquatic ecosystem. Copyright © 2008 John Wiley & Sons, Ltd.     

Seasonal and interannual variations of nitrate and chloride in stream waters related to spatial and temporal patterns of groundwater concentrations in agricultural catchments

Nitrate concentrations in streamwater of agricultural catchments often exhibit interannual variations, which are supposed to result from land‐use changes, as well as seasonal variations mainly explained by the effect of hydrological and biogeochemical cycles. In catchments on impervious bedrock, seasonal variations of nitrate concentrations in streamwater are usually characterized by higher nitrate concentrations in winter than in summer. However, intermediate or inverse cycles with higher concentrations in summer are sometimes observed. An experimental study was carried out to assess the mechanisms that determine the seasonal cycles of streamwater nitrate concentrations in intensive agricultural catchments. Temporal and spatial patterns of groundwater concentrations were investigated in two adjacent catchments located in south‐western Brittany (France), characterized by different seasonal variations of streamwater nitrate concentrations. Wells were drilled across the hillslope at depths ranging from 1·5 to 20 m. Dynamics of the water table were monitored and the groundwater nitrate and chloride concentrations were measured weekly over 2 years. Results highlighted that groundwater was partitioned into downslope domains, where denitrification induced lower nitrate concentrations than into mid‐slope and upslope domains. For one catchment, high subsurface flow with high nitrate concentrations during high water periods and active denitrification during low water periods explained the higher streamwater nitrate concentrations in winter than in summer. For the other catchment, the high contribution of groundwater with high nitrate concentrations smoothed or inverted this trend. Increasing bromide/chloride ratio and nitrate concentrations with depth argued for an effect of past agricultural pressure on this catchment. The relative contribution of flows in time and correlatively the spatial origin of waters, function of the depth and the location on the hillslope, and their chemical characteristics control seasonal cycles of streamwater nitrate concentrations and can influence their interannual trends. Copyright © 2004 John Wiley & Sons, Ltd.     

Above‐stream microclimate and stream surface energy exchanges in a wildfire‐disturbed riparian zone

Stream temperature and riparian microclimate were characterized for a 1·5 km wildfire‐disturbed reach of Fishtrap Creek, located north of Kamloops, British Columbia. A deterministic net radiation model was developed using hemispherical canopy images coupled with on‐site microclimate measurements. Modelled net radiation agreed reasonably with measured net radiation. Air temperature and humidity measured at two locations above the stream, separated by 900 m, were generally similar, whereas wind speed was poorly correlated between the two sites. Modelled net radiation varied considerably along the reach, and measurements at a single location did not provide a reliable estimate of the modelled reach average. During summer, net radiation dominated the surface heat exchanges, particularly because the sensible and latent heat fluxes were normally of opposite sign and thus tended to cancel each other. All surface heat fluxes shifted to negative values in autumn and were of similar magnitude through winter. In March, net radiation became positive, but heat gains were cancelled by sensible and latent heat fluxes, which remained negative. A modelling exercise using three canopy cover scenarios (current, simulated pre‐wildfire and simulated complete vegetation removal) showed that net radiation under the standing dead trees was double that modelled for the pre‐fire canopy cover. However, post‐disturbance standing dead trees reduce daytime net radiation reaching the stream surface by one‐third compared with complete vegetation removal. The results of this study have highlighted the need to account for reach‐scale spatial variability of energy exchange processes, especially net radiation, when modelling stream energy budgets. Copyright © 2010 John Wiley & Sons, Ltd.     

Significance of processes in the near‐stream zone on stream water acidity in a small acidified forested catchment

The near‐stream zone has received increasing attention owing to its influence on stream water chemistry in general and acidity in particular. Possible processes in this zone include cation exchange, leaching of organic matter and redox reactions of sulphur compounds. In this study the influences of processes in the near‐stream zone on the acidity in runoff from a small, acidified catchment in central southern Sweden were investigated. The study included sampling of groundwater, soil water and stream water along with hydrological measurements. An input–output budget for the catchment was established based on data from the International Co‐operative Programme on Integrated Monitoring at this site. The catchment was heavily acidified by deposition of anthropogenic sulphur, with pH in stream water between 4·4 and 4·6. There was also no relationship between stream flow and pH, which is indicative of chronic acidification. Indications of microbial reduction of sulphate were found in some places near the stream, but the near‐stream zone did not have a general impact on the sulphate concentration in discharging groundwater. The near‐stream zone was a source of dissolved organic carbon (DOC) in the stream, which had a median DOC of 6·8 mg L¹. The influence on stream acidity from organic anions was overshadowed by the effect of sulphate, however, except during a spring flow episode, when additional organic matter was flushed out and the sulphate‐rich ground water was mixed with more diluted event water. Ion exchange was not an important process in the near‐stream zone of the Kindla catchment. Different functions of the near‐stream zone relating to discharge acidity are reported in the literature. In this study there was even a variation within the site. There is therefore a need for more case studies to provide a more detailed understanding of the net effects that the near‐stream zone can have on stream chemistry under different circumstances. Copyright © 2001 John Wiley & Sons, Ltd.     

Travel time controls the magnitude of nitrate discharge in groundwater bypassing the riparian zone to a stream on Virginia's coastal plain

Groundwater that bypasses the riparian zone by travelling along deep flow paths may deliver high concentrations of fertilizer‐derived NO₃^? to streams, or it may be impacted by the NO₃^? removal process of denitrification in streambed sediments. In a study of a small agricultural catchment on the Atlantic coastal plain of Virginia's eastern shore, we used seepage meters deployed in the streambed to measure specific discharge of groundwater and its solute concentrations for various locations and dates. We used values of Cl^? concentration to discriminate between bypass water recharged distal to the stream and that contained high NO₃^? but low Cl^? concentrations and riparian‐influenced water recharged proximal to the stream that contained low NO₃^? and high Cl^? concentrations. The travel time required for bypass water to transit the 30‐cm‐thick, microbially active denitrifying zone in the streambed determined the extent of NO₃^? removal, and hydraulic conductivity determined travel time through the streambed sediments. At all travel times greater than 2 days, NO₃^? removal was virtually complete. Comparison of the timescales for reaction and transport through the streambed sediments in this system confirmed that the predominant control on nitrate flux was travel time rather than denitrification rate coefficients. We conclude that extensive denitrification can occur in groundwater that bypasses the riparian zone, but a residence time in biologically active streambed sediments sufficient to remove a large fraction of the NO₃^? is only achieved in relatively low‐conductivity porous media. Instead of viewing them as separate, the streambed and riparian zone should be considered an integrated NO₃^? removal unit. Copyright © 2011 John Wiley & Sons, Ltd.     

Variability of in‐stream and riparian storage in a beaded arctic stream

The extent and variability of water storage and residence times throughout the open water season in beaded arctic streams are poorly understood. Data collected in Imnavait Creek, a beaded stream located north of the Brooks Range in Alaska, were used to better understand the effects of in‐pool and riparian storage on heat and mass movement through beaded streams. Temperature data of high spatial resolution within the pools and surrounding sediments were used with volumetric discharge and electrical conductivity to identify storage areas within the pools, banks, and other marshy areas within the riparian zone, including subsurface flow paths that connect the pools. These subsurface flows were found to alter water conductivity and the character of dissolved organic matter (DOM) in short reaches (10 s of m) while influencing the chemistry of downstream pools. During low flow periods, persistent stratification occurred within the pools due to absorption of solar radiation by DOM coupled with permafrost below and low wind stress at the pool surface. Additionally, one of the shallow pools (<0.5 m depth) remained stratified during higher flow periods and lower radiation inputs due to dense subsurface flows entering the bottom of the pools. This consistent separation of surface and bottom water masses in each pool will increase the travel times through this and similar arctic watersheds, and therefore will affect the evolution of water chemistry and material export. Copyright © 2011 John Wiley & Sons, Ltd.     

Spatial patterns of soil nitrate in Japanese forested watersheds: importance of the near-stream zone as a source of nitrate in stream water

Spatial patterns of N dynamics in soil were evaluated within two small forested watersheds in Japan. These two watersheds were characterized by steep slopes (>30°) and high stream NO⁻₃ drainage rates (8·4 to 25·1 kg N ha⁻¹ yr⁻¹) that were greater than bulk precipitation N input rates (7·5 to 13·5 kg N ha⁻¹ yr⁻¹). Higher rates of nitrification potential at near-stream zones were reflected in greater NO⁻₃ contents for soil at the near-stream zones compared with ridge zones. Both stream discharge rates and NO⁻₃ concentrations in deep unsaturated soil at the near-stream zones were positively correlated to NO⁻₃ concentrations in stream water. These relationships, together with high soil NO⁻₃ contents at the near-stream zones, suggest that the near-stream zone was an important source of NO⁻₃ to stream water. Nitrate flux from these near-stream zones was also related to the drainage of cations (K⁺, Ca²⁺ and Mg²⁺). The steep slope of the watersheds resulted in small saturated areas that contributed to the high NO⁻₃ production (high nitrification rates) in the near-stream zone. © 1998 John Wiley & Sons, Ltd.     

Groundwater cation concentrations in the riparian zone of a forested headwater stream

Groundwater cation concentrations in relation to hydrologic flow paths were studied in the riparian forest zone of a small headwater catchment near Toronto, Ontario. Groundwater entering the riparian zone from uplands showed significant differences in cation concentrations between slope-foot and near-stream locations. Mean Ca, Mg, K, and Na concentrations in shallow groundwater at the upland perimeter of the riparian forest were 65-0, 11-2, 0-7, and 1-8 mg L^?1 respectively. Mean Ca, Mg, K, and Na concentrations in deep groundwater flowing upwards through glacial sands beneath the riparian zone were 52-1, 15-1, 1-3, and 2-6 mg L^?1 respectively. Shallow groundwater emerged as slope-foot springs producing surface rivulets which crossed the riparian zone to the streams. Deep groundwater flowed upward through organic soils into the rivulets and also discharged directly to the streams as bed and bank seepage. Springs had higher Ca concentrations and lower Mg, K, and Na values than rivulets entering the streams. Conversely, Mg, K, and Na concentrations were higher and Ca concentrations were lower in bank seeps in comparison to rivulets. These results suggest that differences in cation concentrations in groundwater entering the streams result from initial contrast in the chemistry of shallow and deep groundwater rather than from the effects of riparian soils and vegetation.     

Hydrological flowpaths and nitrate removal rates within a riparian floodplain along a fourth‐order stream in Brittany (France)

Three main reservoirs were identified that contribute to the shallow subsurface flow regime of a valley drained by a fourth‐order stream in Brittany (western France). (i) An upland flow that supplied a wetland area, mainly during the high‐water period. It has high N‐NO₃^? and average Cl^? concentrations. (ii) A deep confined aquifer characterized by low nitrate and low chloride concentrations that supplied the floodplain via flow upwelling. (iii) An unconfined aquifer under the riparian zone with high Cl^? and low N‐NO₃^? concentrations where biological processes removed groundwater nitrate. This aquifer collected the upland flow and supplied a relict channel that controlled drainage from the whole riparian zone. Patterns of N‐NO₃^? and Cl^? concentrations along riparian transects, together with calculated high nitrate removal, indicate that removal occurred mainly at the hillslope–riparian zone interface (i.e. first few metres of wetland), whereas dilution occurred in lower parts of the transects, especially during low‐water periods and at the beginning of recharge periods. Stream flow was modelled as a mixture of water from the three reservoirs. An estimation of these contributions revealed that the deep aquifer contribution to stream flow averaged 37% throughout the study period, while the contribution of the unconfined reservoir below the riparian zone and hillslope flow was more variable (from ca 6 to 85%) relative to rainfall events and the level of the riparian water table. At the entire riparian zone scale, NO₃^? removal (probably from denitrification) appeared most effective in winter, despite higher estimated upland NO₃^? fluxes entering the riparian zone during this period. Copyright © 2003 John Wiley & Sons, Ltd.     

Diel discharge variations in dormant and growing seasons in a headwater catchment suggest potential sources of an evapotranspiration signal

Diel fluctuations in discharge not associated with precipitation have been identified in streams around the world and attributed to evapotranspiration of both hillslope and near-stream vegetation. Several mechanisms have been hypothesized to explain the generation of these signals, but a consensus has not been reached. In order to investigate the origin of these daily discharge fluctuations, we measured discharge and groundwater levels in a 43-ha headwater catchment near Cullowhee, NC, USA. The catchment was logged at least twice in the past 120 years, allowing the evergreen invasive Chinese privet (Ligustrum sinense) to become established in near-stream areas. Stream discharge was measured at the outlet, and stream stage and near-stream groundwater level were measured at a second location higher in the catchment. Daily fluctuations in discharge were quantified and found to increase in magnitude with daily mean discharge. Interestingly, daily discharge fluctuations were observed in the dormant season, and our analysis suggests that their magnitude may increase more with discharge than during the growing season. Two previously hypothesized processes may explain our observations. A decrease in signal dampening due to faster transmission of an evapotranspiration signal at elevated flows may explain the increased diel fluctuation magnitude at higher flows. Additionally, because the primary active vegetation in our catchment in the dormant season is in near-stream areas, we suggest that this indicates most of the evapotranspiration signal in stream discharge is derived from near-stream vegetation, not hillslopes.     

Bedload tracing in a high‐sediment‐load mountain stream

This paper reports a radiofrequency identification (RFID) tracing experiment implemented in a high‐sediment‐load mountain stream typical of alpine gravel‐bed torrents. The study site is the Bouinenc Torrent, a tributary to the Bléone River in southeast France that drains a 38·9‐km² degraded catchment. In spring 2008, we deployed 451 tracers with b‐axis ranging from 23 to 520 mm. Tracers were seeded along eight cross‐sections located in the upstream part of the lowest 2·3 km of the stream. Three tracer inventories were implemented in July 2008, 2009 and 2010. Recovery rates calculated for mobile tracers declined from 78% in 2008 to 45% in 2009 and 25% in 2010. Observations of tracer displacement revealed very high sediment dispersion, with frontrunners having travelled more than 2 km only three months after their deployment. The declining recovery rate over time was interpreted as resulting from rapid dispersion rather than deep burial. We evaluated that 64% of the tracers deployed in the active channel were exported from the 2·3‐km study reach three years after the onset of the tracing experiment. Travel distances were characterized by right‐skewed and heavy‐tailed distributions, correctly fitted by a power‐law function. This supports the idea that in gravel‐bed rivers with abundant sediment supply relative to transport capacity, bedload transport can be viewed as a superdiffusive sediment dispersion process. It is also shown that tracers initially deployed in the low‐flow channel were characterized by a 15‐ to 30‐fold increase of mobility compared to tracers deployed in gravel bars. Copyright © 2011 John Wiley & Sons, Ltd.     

Beaver dams along an agricultural stream in southern Ontario,Canada: their impact on riparian zone hydrology and nitrogen chemistry

The hydrology and nitrogen biogeochemistry of a riparian zone were compared before and after the construction of beaver dams along an agricultural stream in southern Ontario, Canada. The beaver dams increased surface flooding and raised the riparian water table by up to 1·0 m. Increased hydraulic gradients inland from the stream limited the entry of oxic nitrate‐rich subsurface water from adjacent cropland. Permeable riparian sediments overlying dense till remained saturated during the summer and autumn months, whereas before dam construction a large area of the riparian zone was unsaturated in these seasons each year. Beaver dam construction produced significant changes in riparian groundwater chemistry. Median dissolved oxygen concentrations were lower in riparian groundwater after dam construction (0·9–2·1 mg L^?1) than in the pre‐dam period (2·3–3·9 mg L^?1). Median NO₃‐N concentrations in autumn and spring were also lower in the post‐dam (0·03–0·07 mg L^?1) versus the pre‐dam period (0·1–0·3 mg L^?1). In contrast, median NH₄‐N concentrations in autumn and spring months were higher after dam construction (0·3–0·4 mg L^?1) than before construction (0·13–0·14 mg L^?1). Results suggest that beaver dams can increase stream inflow to riparian areas that limit water table declines and increase depths of saturated riparian soils which become more anaerobic. These changes in subsurface hydrology and chemistry have the potential to affect the transport and transformation of nitrate fluxes from adjacent cropland in agricultural landscapes. Copyright © 2009 John Wiley & Sons, Ltd.     

Water source characterization through spatiotemporal patterns of major,minor and trace element stream concentrations in a complex,mesoscale German catchment

The link between spatiotemporal patterns of stream water chemistry and catchment characteristics for the mesoscale Dill catchment (692 km²) in Germany is explored to assess the catchment scale controls on water quality and to characterize water sources. In order to record the spatiotemporal pattern, ‘snapshot sampling’ was applied during low, mean and high flow, including 73 nested sites throughout the catchment. Water samples were analysed for the elements Li, B, Na, Mg, Al, K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Mo, Ba, Pb and U using inductively‐coupled‐plasma mass spectrometry, and for electric conductivity and pH. Principle component analysis and hierarchical cluster analysis were used to find typical element associations and to group water samples according to their hydrochemical fingerprints. This revealed regional hydrochemical patterns of water quality which were subsequently related to catchment attributes to draw conclusions about the controls on stream chemistry. It was found that various lithologic signals and anthropogenic point source inputs controlled the base flow hydrochemistry. During increased flows, stream waters were diluted causing additional hydrochemical variability in response to heterogeneous precipitation inputs and differences in aquifer storage capacities. The hydrochemical patterns further displayed in‐stream mixing of waters. This implied, that stream waters could be apportioned to the identified water sources throughout the catchment. The basin‐wide hydrochemical variability has the potential to outrange the tracer signatures typically inferred in studies at the hillslope scale and is able to strongly influence the complexity of the catchment output. Both have to be considered for further catchment scale tracer and modelling work. Despite the likelihood of non‐conservative behaviour, the minor and trace elements enhanced the rather qualitative discrimination of the various groundwater types, as the major cations were strongly masked by point source inputs. Copyright © 2007 John Wiley & Sons, Ltd.     

Dynamics of evapotranspiration from a riparian pond complex in the Western Boreal Forest,Alberta, Canada

The relative contributions to total actual evapotranspiration (AET) from pond and riparian areas in a pond‐wetland complex in the Western Boreal Plain (WBP) of northern Alberta are measured using the Bowen ratio energy balance technique. Measurements show that a pond typical of the WBP evaporates at a rate more than twice that of the adjacent riparian peatland. Relating the actual to potential evapotranspiration over both surfaces yields Priestley–Taylor α coefficients of 0·69 and 1·11 for the peatland and pond respectively. Further results demonstrate that the sheltering and turbulent influences of the adjacent forested areas must be considered in the processes governing the permanence of WBP ponds. That is, forestry practices may inadvertently enhance the evaporative losses from the ponds, over and above the controls exerted by the regional climate. Copyright © 2006 John Wiley & Sons, Ltd.     

Methane in the hyporheic zone of a small lowland stream (Sitka, Czech Republic)

Methane concentrations and selected chemical parameters in interstitial water were examined along subsurface flowpath in two subsystems (hyporheic and parafluvial sediments) in the Sitka stream, Czech Republic. Interstitial methane concentrations exhibited a distinct spatial pattern. In the hyporheic downwelling zone where the sediments are relatively well oxygenated due to high hydrologic exchange with the surface water, low interstitial methane concentrations, averaging 9.3 μg CH₄/l, were found. In contrast, upwelling sediments and parafluvial sediments (active channel sediments lateral to the wetted channel) had significantly higher methane concentrations (p < 0.05, and p < 0.01, respectively), averaging 43.2 μg CH₄/l and 160.5 μg CH₄/l, respectively. Dissolved oxygen was the highest where surface water entered hyporheic/parafluvial sediments and decreased with water residence time in the sediments (p < 0.01). Nitrate concentrations decreased along the flowpath and were significantly lower at downstream end of the riffle (p < 0.001). Sulfate concentrations also show a slight decline with the water residence time, but differences were not significant. Effect of both nitrate and sulfate on methanogenesis is also discussed. The interstitial methane concentration significantly increased with surface water temperature (p < 0.001) and was negatively correlated with redox potential (p < 0.01) and dissolved oxygen (p < 0.05).     

Impact of redox and transport processes in a riparian wetland on stream water quality in the Fichtelgebirge region,southern Germany

Biologically mediated redox processes in the riparian zone, like denitrification, can have substantially beneficial impacts on stream water quality. The extent of these effects, however, depends greatly on the hydrological boundary conditions. The impact of hydrological processes on a wetland's nitrogen sink capacity was investigated in a forested riparian fen which is drained by a first‐order perennial stream. Here, we analysed the frequency distributions and time‐series of pH and nitrogen, silica, organic carbon and oxygen concentrations in throughfall, soil solution, groundwater and stream water, and the groundwater levels and stream discharges from a 3‐year period. During baseflow conditions, the stream was fed by discharging shallow, anoxic groundwater and by deep, oxic groundwater. Whereas the latter delivered considerable amounts of nitrogen (～0·37 mg l^?1) to the stream, the former was almost entirely depleted of nitrogen. During stormflow, near‐surface runoff in the upper 30 cm soil layer bypassed the denitrifying zone and added significant amounts to the nitrogen load of the stream. Nitrate‐nitrogen was close to 100% of deep groundwater and stream‐water nitrogen concentration. Stream‐water baseflow concentrations of nitrate, dissolved carbon and silica were about 1·6 mg l^?1, 4 mg l^?1 and 7·5 mg l^?1 respectively, and >3 mg l^?1, >10 mg l^?1 and <4 mg l^?1 respectively during discharge peaks. In addition to that macroscale bypassing effect, there was evidence for a corresponding microscale effect: Shallow groundwater sampled by soil suction cups indicated complete denitrification and lacked any seasonal signal of solute concentration, which was in contrast to piezometer samples from the same depth. Moreover, mean solute concentration in the piezometer samples resembled more that of suction‐cup samples from shallower depth than that of the same depth. We conclude that the soil solution cups sampled to a large extent the immobile soil‐water fraction. In contrast, the mobile fraction that was sampled by the piezometers exhibited substantially shorter residence time, thus being less exposed to denitrification, but predominating discharge of that layer to the stream. Consequently, assessing the nitrogen budget based on suction‐cup data tended to overestimate the nitrogen consumption in the riparian wetland. These effects are likely to become more important with the increased frequency and intensity of rainstorms that are expected due to climate change. Copyright © 2006 John Wiley & Sons, Ltd.     

Application of a confluence‐based sediment‐fingerprinting approach to a dynamic sedimentary catchment,New Zealand

Fine sediment is a dynamic component of the fluvial system, contributing to the physical form, chemistry and ecological health of a river. It is important to understand rates and patterns of sediment delivery, transport and deposition. Sediment fingerprinting is a means of directly determining sediment sources via their geochemical properties, but it faces challenges in discriminating sources within larger catchments. In this research, sediment fingerprinting was applied to major river confluences in the Manawatu catchment as a broad‐scale application to characterizing sub‐catchment sediment contributions for a sedimentary catchment dominated by agriculture. Stepwise discriminant function analysis and principal component analysis of bulk geochemical concentrations and geochemical indicators were used to investigate sub‐catchment geochemical signatures. Each confluence displayed a unique array of geochemical variables suited for discrimination. Geochemical variation in upstream sediment samples was likely a result of the varying geological source compositions. The Tiraumea sub‐catchment provided the dominant signature at the major confluence with the Upper Manawatu and Mangatainoka sub‐catchments. Subsequent downstream confluences are dominated by the upstream geochemical signatures from the main stem of Manawatu River. Variability in the downstream geochemical signature is likely due to incomplete mixing caused in part by channel configuration. Results from this exploratory investigation indicate that numerous geochemical elements have the ability to differentiate fine sediment sources using a broad‐scale confluence‐based approach and suggest there is enough geochemical variation throughout a large sedimentary catchment for a full sediment fingerprint model. Combining powerful statistical procedures with other geochemical analyses is critical to understanding the processes or spatial patterns responsible for sediment signature variation within this type of catchment. Copyright © 2015 John Wiley & Sons, Ltd.     

Inter‐annual variability in the effects of riparian woodland on micro‐climate,energy exchanges and water temperature of an upland Scottish stream

The influence of riparian woodland on stream temperature, micro‐climate and energy exchange was investigated over seven calendar years. Continuous data were collected from two reaches of the Girnock Burn (a tributary of the Aberdeenshire Dee, Scotland) with contrasting land use characteristics: (1) semi‐natural riparian forest and (2) open moorland. In the moorland reach, wind speed and energy fluxes (especially net radiation, latent heat and sensible heat) varied considerably between years because of variable riparian micro‐climate coupled strongly to prevailing meteorological conditions. In the forested reach, riparian vegetation sheltered the stream from meteorological conditions that produced a moderated micro‐climate and thus energy exchange conditions, which were relatively stable between years. Net energy gains (losses) in spring and summer (autumn and winter) were typically greater in the moorland than the forest. However, when particularly high latent heat loss or low net radiation gain occurred in the moorland, net energy gain (loss) was less than that in the forest during the spring and summer (autumn and winter) months. Spring and summer water temperature was typically cooler in the forest and characterised by less inter‐annual variability due to reduced, more inter‐annually stable energy gain in the forested reach. The effect of riparian vegetation on autumn and winter water temperature dynamics was less clear because of the confounding effects of reach‐scale inflows of thermally stable groundwater in the moorland reach, which strongly influenced the local heat budget. These findings provide new insights as to the hydrometeorological conditions under which semi‐natural riparian forest may be effective in mitigating river thermal variability, notably peaks, under present and future climates. © 2014 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.     

Numerical modelling to evaluate the nitrogen removal rate in hyporheic zone and its implications for stream management

The hyporheic zone (HZ) plays a vital role in the stream ecosystem. Reactions in the HZ such as denitrification and nitrification have been examined in previous studies. However, no numerical model has yet been developed that can accurately simulate nitrogen concentration changes in the HZ, because the zones for the two reactions can change throughout the reactions. This study proposes a method of evaluating the nitrogen removal rate in the HZ through numerical modelling. First, a basic two‐dimensional numerical model coupling flow conditions with biochemical reactions is proposed to consider both nitrification and denitrification. The zones for different reactions are determined under the assumption that related environmental variables (i.e., the dissolved oxygen) will not change throughout the reactions. Next, to examine changes in environmental variables throughout the reactions, an improved model is proposed, and a method is developed for delineating the boundary between nitrification and denitrification zones and identifying a transition zone where either reaction might take place. However, more information about biochemical reactions in the HZ is required to use the improved model. To overcome this shortcoming, a new model that couples the basic model and genetic programming (GP) is proposed to optimize the simulation results of the basic model and allow for real‐time forecasting. The results show that the basic model obtains acceptable simulation results for nitrate concentration distribution in the HZ. The improved model performs better than the basic model, but the model coupling the basic model with GP performs best. In addition, the function of the HZ in nitrogen removal is examined through a case study of four scenarios, leading to the conclusion that the HZ has a higher nitrogen removal rate when water quality is neither too poor nor too good. Overall, this study enhances our understanding of the HZ and can benefit the restoration and management of HZs and streams in the face of the continual degradation caused by human activity.     

Suspended sediment dynamics in a steep,glacier‐fed mountain stream,Place Creek,Canada

This study examined suspended sediment concentration (SSC) during the ablation seasons of 2000 and 2001 in Place Creek, Canada, a steep, glacier‐fed mountain stream. Comparison of stream flow in Place Creek with that in an adjacent, almost unglacierized catchment provided a rational basis for separating the ablation seasons into nival, nival–glacial, glacial and autumn recession subseasons. Distinct groupings of points in plots of electrical conductivity against discharge supported the validity of the subseasonal divisions in terms of varying hydrological conditions. Relationships between SSC and discharge (Q) varied between the two study seasons, and between subseasons. Hysteresis in the SSC–Q relationship was evident at both event and weekly time‐scales. Some suspended sediment released from pro‐glacial Place Lake (the source of Place Creek) appeared to be lost to channel storage at low flows, especially early in the ablation season, with re‐entrainment at higher flows. Multiple regression models were derived for the subseasons using predictor variables including Q, Q², the change in Q over the previous 3 h, cumulative discharge over the ablation season, total precipitation over the previous 24 h and SSC measured at 1500 hours as an index value for each day. The models produced adjusted R² values ranging from 0·71 to 0·91, and provided tentative insights into the differences in SSC dynamics amongst subseasons. Introduction of the index value of SSC significantly improved the model fit during the nival–glacial and glacial subseasons for both years, as it adjusts the model to the current condition of sediment supply. Copyright © 2003 John Wiley & Sons, Ltd.