The role of vegetation in the retention of fine sediment and associated metal contaminants in London's rivers

Many urban rivers receive significant inputs of metal‐contaminated sediments from their catchments. Restoration of urban rivers often creates increased slack water areas and in‐channel vegetation growth where these metal‐contaminated sediments may accumulate. Quantifying the accumulation and retention of these sediments by in‐channel vegetation in urban rivers is of importance in terms of the planning and management of urban river restoration schemes and compliance with the Water Framework Directive. This paper investigates sediment properties at four sites across three rivers within Greater London to assess the degree to which contaminated sediments are being retained. Within paired restored and unrestored reaches at each site, four different bed sediment patch types (exposed unvegetated gravel, sand, and silt/clay (termed ‘fine’) sediments, and in‐channel vegetated sediments) were sampled and analysed for a range of metals and sediment characteristics. Many samples were found to exceed Environment Agency guidelines for copper (Cu), lead (Pb) and zinc (Zn) and Dutch Intervention Values for Cu and Zn. At all sites, sediments accumulating around in‐channel vegetation were similar in calibre and composition to exposed unvegetated fine sediments. Both bed sediment types contained high concentrations of pseudo‐total and acetic acid extractable metal concentrations, potentially due to elevated organic matter and silt/clay content, as these are important sorbtion phases for metals. This implies that the changed sediment supply and hydraulic conditions associated with river restoration may lead to enhanced retention of contaminated fine sediments, particularly around emergent plants, frequently leading to the development of submerged and emergent landforms and potential river channel adjustments. High pseudo‐total metal concentrations were also found in gravel bed sediments, probably associated with iron (Fe) and manganese (Mn) oxyhydroxides and discrete anthropogenic metal‐rich particles. These results highlight the importance of understanding the potential effects of urban river restoration upon sediment availability and channel hydraulics and consequent impacts upon sediment contaminant dynamics and storage. Copyright © 2014 John Wiley & Sons, Ltd.     

Concentrations and annual fluxes of sediment‐associated chemical constituents from conterminous US coastal rivers using bed sediment data

Coastal rivers represent a significant pathway for the delivery of natural and anthropogenic sediment‐associated chemical constituents to the Atlantic, Pacific and Gulf of Mexico coasts of the conterminous USA. This study entails an accounting segment using published average annual suspended sediment fluxes with published sediment‐associated chemical constituent concentrations for (1) baseline, (2) land‐use distributions, (3) population density, and (4) worldwide means to estimate concentrations/annual fluxes for trace/major elements and total phosphorus, total organic and inorganic carbon, total nitrogen, and sulphur, for 131 coastal river basins. In addition, it entails a sampling and subsequent chemical analysis segment that provides a level of ‘ground truth’ for the calculated values, as well as generating baselines for sediment‐associated concentrations/fluxes against which future changes can be evaluated. Currently, between 260 and 270 Mt of suspended sediment are discharged annually from the conterminous USA; about 69% is discharged from Gulf rivers (n = 36), about 24% from Pacific rivers (n = 42), and about 7% from Atlantic rivers (n = 54). Elevated sediment‐associated chemical concentrations relative to baseline levels occur in the reverse order of sediment discharges: Atlantic rivers (49%) > Pacific rivers (40%) > Gulf rivers (23%). Elevated trace element concentrations (e.g. Cu, Hg, Pb, Zn) frequently occur in association with present/former industrial areas and/or urban centres, particularly along the northeast Atlantic coast. Elevated carbon and nutrient concentrations occur along both the Atlantic and Gulf coasts but are dominated by rivers in the urban northeast and by southeastern and Gulf coast (Florida) ‘blackwater’ streams. Elevated Ca, Mg, K, and Na distributions tend to reflect local petrology, whereas elevated Ti, S, Fe, and Al concentrations are ubiquitous, possibly because they have substantial natural as well as anthropogenic sources. Almost all the elevated sediment‐associated chemical concentrations found in conterminous US coastal rivers are lower than worldwide averages. Copyright © 2012 John Wiley & Sons, Ltd.     

Channel‐planform evolution in four rivers of Olympic National Park,Washington, USA: the roles of physical drivers and trophic cascades

Identifying the relative contributions of physical and ecological processes to channel evolution remains a substantial challenge in fluvial geomorphology. We use a 74‐year aerial photographic record of the Hoh, Queets, Quinault, and Elwha Rivers, Olympic National Park, Washington, USA, to investigate whether physical or trophic‐cascade‐driven ecological factors – excessive elk impacts after wolves were extirpated a century ago – are the dominant drivers of channel planform in these gravel‐bed rivers. We find that channel width and braiding show strong relationships with recent flood history. All four rivers widened significantly after having been relatively narrow in the 1970s, consistent with increased flood activity since then. Channel planform also reflects sediment‐supply changes, evident from landslide response on the Elwha River. We surmise that the Hoh River, which shows a multi‐decadal trend toward greater braiding, is adjusting to increased sediment supply associated with rapid glacial retreat. These rivers demonstrate transmission of climatic signals through relatively short sediment‐routing systems that lack substantial buffering by sediment storage. Legacy effects of anthropogenic modification likely also affect the Quinault River planform. We infer no correspondence between channel evolution and elk abundance, suggesting that trophic‐cascade effects in this setting are subsidiary to physical controls on channel morphology. Our findings differ from previous interpretations of Olympic National Park fluvial dynamics and contrast with the classic example of Yellowstone National Park, where legacy effects of elk overuse are apparent in channel morphology; we attribute these differences to hydrologic regime and large‐wood availability. Published 2016. This article is a U.S. Government work and is in the public domain in the USA     

Delivery of upper-basin sediment to the lower neuse river,North Carolina,U.S.A.

Extensive storage of upper-basin Piedmont sediment and apparent low sediment supply to streams in lower-basin Coastal Plain areas generates questions as to the source of alluvium in lower reaches of rivers of the U.S. Atlantic drainage. This was investigated on the Neuse River, North Carolina, using a mineralogical indicator of sediment source areas. The utility of mica flakes for discriminating between Piedmont and non-Piedmont sources of sediment in the lower Coastal Plain reaches of the Neuse was established on the basis of an examination of the U.S. National Soils Database and of 26 soil surveys of the North Carolina Coastal Plain. From the Neuse River estuary to 48 km upstream there are no mica flakes in floodplain soils or in river bank and channel shelf sediments. Mica flakes become more common upstream. This suggests that a very small proportion of the sediment eroded in the Piedmont portion of the watershed is delivered to the river mouth. The small amounts which presumably do reach the lower Coastal Plain are so diluted by Coastal Plain-derived alluvium that no Piedmont origin can be discerned. This demonstrates a dominantly Coastal Plain source and underscores the importance of storage and discontinuous transport in fluvial sediment systems. More importantly, results suggest that upper- and lower-basin sediment dynamics are not only non-linearly related, but may be virtually decoupled.     

Assessment of erosion and settling properties of fine sediments stored in cobble bed rivers: the Arc and Isère alpine rivers before and after reservoir flushing

Cohesive sediment dynamics in mountainous rivers is poorly understood even though these rivers are the main providers of fine particles to the oceans. Complex interactions exist between the coarse matrix of cobble bed rivers and fine sediments. Given that fine sediment load in such environments can be very high due to intense natural rainfall or snowmelt events and to man‐induced reservoir or dam flushing, a better understanding of the deposition and sedimentation processes is needed in order to reduce ecohydrological downstream impacts. We tested a field‐based approach on the Arc and Isère alpine rivers combining measurements of erosion and settling properties of river bed deposits before and after a dam flushing, with the U‐GEMS (Gust Erosion Microcosm System) and SCAF (System Characterizing Aggregates and Flocs), respectively. These measurements highlight that critical shears, rates of erosion, settling velocities and propensity of particles to flocculate are highly variable in time and space. This is reflective of the heterogeneity of the hydrodynamic conditions during particle settling, local bed roughness, and nature and size of particles. Generally the deposits were found to be stable relative to what is measured in lowland rivers. It was, however, not possible to make a conclusive assessment of the extent to which the dynamics of deposits after reservoir flushing were different from those settled after natural events. The absence of any relationships between erosion and deposition variables, making it impossible to predict one from another, underlined the need to measure all of them to have a full assessment of the fine sediment dynamics and to obtain representative input variables for numerical models. While the SCAF was found to be effective, an alternative to the U‐GEMS device will have to be found for the erodibility assessment in cobble bed rivers, in order to make more rapid measurements at higher shears. Copyright © 2017 John Wiley & Sons, Ltd.     

Analysis of bedload transport characteristics of Idaho streams and rivers

Field data are essential in evaluating the adequacy of predictive equations for sediment transport. Each dataset based on the sediment transport rates and other relevant information gives an increased understanding and improved quantification of different factors influencing the sediment transport regime in the specific environment. Data collected for 33 sites on 31 mountain streams and rivers in Central Idaho have enabled the analysis of sediment transport characteristics in streams and rivers with different geological, topographic, morphological, hydrological, hydraulic, and sedimentological characteristics. All of these streams and rivers have armored, poorly sorted bed material with the median particle size of surface layer coarser than the subsurface layer. The fact that the largest particles in the bedload samples did not exceed the median particle size of the bed surface material indicates that the armor layer is stable for the observed flow discharges (generally bankfull or less, and in some cases two times higher than bankfull discharge). The bedload transport is size‐selective. The transport rates are generally low, since sediment supply is less than the ability of flow to move the sediment for one range of flow discharges, or, the hydraulic ability of the stream is insufficient for entrainment of the coarse bed material. Detailed analyses of bedload transport rates, bedload and bed material characteristics were performed for each site. The obtained results and conclusions are used to identify different influences on bedload transport rates in analyzed gravel‐bed rivers. Copyright © 2008 John Wiley & Sons, Ltd.     

A field investigation of the sediment transport characteristics of a high sediment load intermittent river in Taiwan

Most rivers in Taiwan are intermittent rivers with relatively steep slopes and carry rapid sediment‐laden flows during typhoon or monsoon seasons. A series of field experiments was conducted to collect suspended load data at the Tzu‐Chiang Bridge hydrological station of the lower Cho‐Shui River, which is a major river with the highest sediment yield in Taiwan. The river reach was aggrading with a high aspect ratio during the 1980s. Because of sand mining and extreme floods, it was incised and has had a relatively narrow main channel in recent years. The experimental results indicated that typical sediment transport equations can correctly predict the bed material load for low or medium sediment transport rates (e.g. less than about 1000 tons/day‐m). However, these equations far underestimate the bed material load for high sediment transport rates. The effects of cross‐sectional geometry change (i.e. river incision) and earthquakes on the sediment load were investigated in this study. An empirical sediment transport equation with consideration of the aspect ratio was also derived using the field data collected before and after river incision. Copyright © 2012 John Wiley & Sons, Ltd.     

A new sampler for extracting bed material sediment from sand and gravel beds in navigable rivers

Grain‐size distributions of bed material sediment in large alluvial rivers are required in various scientific and management applications, but characterizing gravel beds in navigable rivers is hampered by difficulties in sediment extraction. The newly developed and preliminarily tested sampler reported here can extract sediment from a range of riverbeds. The 36 × 23 × 28 cm stainless steel toothed sampler is deployed from and dragged downstream by the weight of a jet boat, and it improves upon previous samplers that are unable to penetrate gravel bed surfaces, have small apertures, and/or cannot retain fine sediment. The presented sampler was used to extract 167 bed material sediment samples of up to 16 kg (dry weight) with an average sample size of ～6 kg from 67 cross‐sections spanning 160 river kilometres along the Sacramento River. It was also tested at three sites on a subaerial bar to compare surface, subsurface, and sampler distributions. Sampler penetration is ～5 cm. The device collects individual samples that satisfy the criterion for bed material sediment whereby the largest particle comprises no more than 5% of the total sample mass in gravel and sand beds, except where the degree of surface armouring is large (e.g. armor ratios >> 2) and where more than 10% of bed material sediment is composed of grains larger than 64 mm. When aggregated samples exceed 15 kg, all satisfy the criterion whereby the largest particle comprises no more than 1% of the total sample mass. Samples closely resemble surface size distributions, except where armouring is strong. The sampler should be subject to more rigorous field testing, but many of its current limitations are expected to become negligible with the advent a larger, heavier version of the sampling device. Copyright © 2008 John Wiley & Sons, Ltd.     

Reduced bed material stability and increased bedload transport caused by foraging fish: a flume study with juvenile Barbel (Barbus barbus)

The plants and animals that inhabit river channels may act as zoogeomorphic agents affecting the nature and rates of sediment recruitment, transport and deposition. The impact of benthic‐feeding fish, which disturb bed material sediments during their search for food, has received very little attention, even though benthic feeding species are widespread in rivers and may collectively expend significant amounts of energy foraging across the bed. An ex situ experiment was conducted to investigate the impact of a benthic feeding fish (Barbel Barbus barbus) on particle displacements, bed sediment structures, gravel entrainment and transport fluxes. In a laboratory flume changes in bed surface topography were measured and grain displacements examined when an imbricated, water‐worked bed of 5.6 to 16 mm gravels was exposed to feeding juvenile Barbel (on average, 0.195 m in length). Grain entrainment rates and bedload fluxes were measured under a moderate transport regime for substrates that had been exposed to feeding fish and control substrates which had not. On average, approximately 37% of the substrate, by area, was modified by foraging fish during a four‐hour treatment period, resulting in increased microtopographic roughness and reduced particle imbrication. Structural changes by fish corresponded with an average increase in bedload flux of 60% under entrainment flows, whilst on average the total number of grains transported during the entrainment phase was 82% higher from substrates that had been disturbed by Barbel. Together, these results indicate that by increasing surface microtopography and undoing the naturally stable structures produced by water working, foraging can increase the mobility of gravel‐bed materials. An interesting implication of this result is that by increasing the quantity of available, transportable sediment and lowering entrainment thresholds, benthic feeding might affect bedload fluxes in gravel‐bed rivers. The evidence presented here is sufficient to suggest that further investigation of this possibility is warranted. Copyright © 2014 John Wiley & Sons, Ltd.     

Highly conservative behaviour of bed sediment‐associated metals following extreme flooding

On December 26, 2015 (Boxing Day), an exceptional flood event occurred in the Irwell catchment, United Kingdom, when the neighbouring Mersey catchment experienced a much more typical winter run‐off event. This provided an opportunity to examine the influence of high‐magnitude hydrological processes on the behaviour of fine‐grained metal‐contaminated bed sediments. Forty sites across the two catchments were sampled for channel bed fine sediment storage and sediment‐associated metal(loid) concentrations prior to, and following, the flooding. Sediments were analysed for total As, Cr, Cu, Pb, and Zn and then subjected to a five‐step sequential extraction procedure. Despite a significant reorganisation of fine‐grained (<63 μm) sediment storage, metal(loid) concentrations demonstrated markedly conservative behaviour with no significant difference observed between pre‐flooding and post‐flooding values across both catchments. Estimates of the channel bed storage of sediment‐associated metal(loid)s also showed minimal change as a result of the flooding. The metal partitioning data reveal only minor changes in the mobility of bed sediment‐associated metal(loid)s, indicating that such flood events do not increase the availability of sorbed contaminants in these catchments. Post‐flooding bed sediment metal(loid) loadings remain high, indicating persistent and long‐lasting sources of contamination within the Irwell and upper Mersey fluvial network.     

Downstream fining in contrasting reaches of the sand‐bedded Yellow River

Compared to downstream fining of a gravel‐bedded river, little field evidence exists to support the process of downstream fining in large, fine sand‐bedded rivers. In fact, the typically unimodal bed sediments of these rivers are thought to produce equal mobility of coarse and fine grains that may discourage downstream fining. To investigate this topic, we drilled 200 sediment cores in the channel beds of two fine‐grained sand‐bedded reaches of the Yellow River (a desert reach and a lower reach) and identified a fine surface layer (FSL) developed over a coarse subsurface layer (CSL) in the 3‐m‐thick bed deposits. In both reaches downstream, the thickness of the FSL increased, while that of the CSL decreased. Comparison of the depth‐averaged median grain sizes of the CSL and the FSL separately in both reaches shows a distinct downstream fining dependence to the median grain size, which indicates that at a large scale of 600‐800 km, the CSL shows a significant downstream fining, but the FSL shows no significant trends in downstream variations in grain size. This result shows that fine sediment supply (<0·08 mm median grain size) from upstream, combined with lateral fine sediment inputs from tributaries and bank erosion, can cause a rapid fining of the downstream channel bed surface and can develop the FSL layer. However, in the desert reach, lateral coarse sediment supply (>0·08 mm median grain size) from wind‐borne sediments and cross‐desert tributaries can interrupt the FSL and coarsen the channel bed surface locally. Copyright © 2011 John Wiley & Sons, Ltd.     

Regime theories in gravel‐bed rivers: models,controlling variables,and applications in disturbed Italian rivers

Downstream hydraulic geometry relationships describe the shape of alluvial channels in terms of bankfull width, flow depth, flow velocity, and channel slope. Recent investigations have stressed the difference in spatial scales associated with these variables and thus the time span required for their adjustment after a disturbance. The aim of this study is to explore the consequences in regime models considering the hypothesis that while channel width and depth adjust quickly to changes in water and sediment supply, reach slope requires a longer time span. Three theoretical models were applied. One model incorporates an extremal hypothesis (Millar RG. 2005. Theoretical regime equations for mobile gravel‐bed rivers with stable banks. Geomorphology 64 : 207–220), and the other two are fully physically based (Ikeda S, Parker G, Kimura Y. 1988. Stable width and depth of straight gravel rivers with heterogeneous bed materials. Water Resources Research 24 : 713–722; Parker G, Wilcock PR, Paola C, Dietrich W, Pitlick J. 2007. Physical basis for quasi universal relations describing bankfull hydraulic geometry of single‐thread gravel‐bed rivers. Journal of Geophysical Research 112 , DOI: 10.1029/2006JF000549). In order to evaluate the performance of models introducing the slope as an independent variable, we propose two modifications to previous models. The performance of regime models was tested against published data from 142 river reaches and new hydraulic geometry data from gravel‐bed rivers in Patagonia (Argentina) and north‐eastern Italy. Models that assume slope as a control (Ikeda et al., 1988; or Millar, 2005) predict channel depth and width reasonably well. Parker et al.'s (2007) model improved predictions because it filters the scatter in slope data with a relation slope–discharge. The extremal hypothesis model of Millar (2005) predicts comparably to the other physically based models. Millar's model was chosen to describe the recent changes in the Piave and Brenta rivers due to human intervention – mainly in‐channel gravel mining. The change in sediment supply and recovery was estimated for these rivers. This study supports the interpretation that sediment supply is the key factor guiding morphological changes in these rivers. Copyright © 2013 John Wiley & Sons, Ltd.     

The particle size characteristics of fine‐grained channel deposits in the River Exe Basin,Devon, UK

Deposition and storage of fine‐grained (<62·5 μm) sediment in the hyporheic zone of gravel bed rivers frequently represents an important cause of aquatic habitat degradation. The particle size characteristics of such fine‐grained bed sediment (FGBS) exert an important control on its hydrodynamic properties and environmental impact. Traditionally, particle size analysis of FGBS in gravel bed rivers has focused on the absolute size distribution of the chemically dispersed mineral fraction. However, recent work has indicated that in common with fluvial suspended sediment, significant differences may exist between the absolute and the in situ, or effective, particle size composition of FGBS, as a result of the existence of aggregates, or composite particles. In the investigation reported in this paper, sealable bed traps that could be remotely opened to sample sediment deposited during specific storm runoff events and a laser back‐scatter probe were used to quantify the temporal and spatial variability of both the absolute and effective particle size composition of FGBS, and the associated suspended sediment from four gravel bed rivers in the Exe Basin, Devon, UK. The absolute particle size distributions of both the FGBS and suspended sediment evidenced c. >95%<62·5 μm sized primary particles and displayed a seasonal winter–summer fining, while the opposite trend was displayed by the effective particle size distribution of the FGBS and suspended sediment. The effective particle size distributions of both were typically highly aggregated, comprising up to 68%>62·5 μm sized particles. Spatial variation in the effective particle size and aggregation parameters was of secondary importance relative to temporal variation. The effective particle size distribution of the FGBS was consistently coarser and more aggregated than the associated suspended sediment and there was evidence of aggregate break‐up in samples of resuspended bed sediment. The implications of these findings for sediment transport modelling are considered. Copyright © 1999 John Wiley & Sons, Ltd.     

The response of a gravel‐bed river planform configuration to flow variations and bed reworking: a modelling study

A 2D depth‐averaged model has been developed for simulating water flow, sediment transport and morphological changes in gravel‐bed rivers. The model was validated with a series of laboratory experiments and then applied to the Nove reach of the Brenta River (Northern Italy) to assess its bed material transport, interpret channel response to a series of intensive flood events (R.I. ≈ 10 years) and provide a possible evolutionary scenario for the medium term. The study reach is 1400 m long with a mean slope of 0.0039 m m^?1. High‐resolution digital terrain models were produced combining LiDAR data with colour bathymetry techniques. Extensive field sedimentological surveys were also conducted for surface and subsurface material. Data were uploaded in the model and the passage of two consecutive high intensity floods was simulated. The model was run under several hypotheses of sediment supply: one considering substantial equilibrium between sediment input and transport capacity, and the others reducing the sediment supply. The sediment supply was then calibrated comparing channel morphological changes as observed in the field and calculated by the model. Annual bed material transport was assessed and compared with other techniques. Low‐frequency floods (R.I. ≈ 1.5 years) are expected to produce negligible changes in the channel while high floods may erode banks rather than further incising the channel bed. Location and distribution of erosion and deposition areas within the Nove reach were predicted with acceptable biases stemming from imperfections of the model and the specified initial, boundary and forcing conditions. A medium‐term evolutionary scenario simulation underlined the different response to and impact of a consecutive sequence of floods. Copyright © 2015 John Wiley & Sons, Ltd.     

Joint isotopic mass balance: a novel approach to quantifying channel bed to channel margins sediment transfer during storm events

The important role of floodplains and the broader riparian zone in providing temporary storage for a large fraction of the annual sediment load of rivers is well established, but this understanding is largely based on observations of the long‐term average behavior of the catchment. Here we combine measurements of the fallout radionuclides ⁷Be and ²¹⁰Pb and the stable isotopes of hydrogen in water to quantify fine sediment mobilization and storage in a stream and its channel margins during individual intermediate‐sized storm events with recurrence intervals of a few months or less. We demonstrate this method using five storm events in a small (~15 km²), undeveloped, gravel‐bedded tributary of the Connecticut River (USA). We estimate that in each storm, the mass of sediment deposited onto the margins accounts for almost 90% of the sediment mobilized from the bed, with the remainder of the mobilized bed sediment transported downstream as suspended load. The result that the bed is a net source of sediment to the stream and the margins a net sink is robust, but estimates of the mass of material eroded from the bed and deposited on the margins are less certain. The source of sediment to the bed remains unclear as, consistent with earlier studies, we observe only limited deposition of sediment to the bed during the storm events. The suspended sediment is organic‐rich and thus its source may be associated with in‐channel organic decay between storm events. Understanding the coupled interactions between discharge magnitude and frequency and sediment resupply at the event time scale has important implications for stream restoration efforts seeking to connect the channel and the broader riparian zone, and for the development of accurate sediment budgets and predictions of sediment flux from a watershed. Copyright © 2015 John Wiley & Sons, Ltd.     

Utilizing gamma isotope tracers to determine sediment source at reef sites near the Charleston Ocean Dredged Material Disposal Site

The Charleston, South Carolina Ocean Dredged Material Disposal Site (ODMDS) has been heavily utilized as a disposal site for dredged material resulting from maintenance and channel deepening in the Charleston Harbor. Continuous monitoring by the South Carolina Department of Natural Resources at the ODMDS has indicated the presence of fine-grained sediment within the monitoring zones. However, since the Charleston Harbor is formed by the conjunction of three rivers, it has been suggested that some of the fine-grained sediment surrounding the ODMDS could be due to river transport rather than solely by disposal activities. In order to trace the outflow of sediment from the harbor, natural and man-made isotopes were utilized. (7)Be (natural cosmogenic isotope) and (137)Cs (man-made isotope) are often associated with estuarine sediments. Both isotopes were used as tracers in an attempt to determine the extent of density driven sediment flow from the Charleston Harbor. (7)Be was detected in many of the offshore sampling stations indicating a direct correlation to the harbor. (137)Cs was only found in one sediment trap sample offshore, but none the less indicated some transport from the harbor. Further study for utilizing isotopic tracers in determining offshore sediment transport is still being conducted at the disposal site. It is anticipated that further (7)Be and (137)Cs isotopic monitoring offshore Charleston will aid in determining the role that tidal and density driven sediments play in the sediment budgets at the hard bottom reef sites.     

The source and fate of sediment and mercury in Hunza River basin,Northern Areas,Pakistan

This article presents results of mercury in surface waters from Hunza River basin, Northern Areas, Pakistan. Small‐scale gold mining activities along the Hunza and Gilgit rivers are long known to be discharging mercury in the amalgamation and roasting processes. Previous studies reported high mercury concentrations in soils close to mining operations as well as serious health problems for miners. However, none of the studies have focused on the level of contamination in aqueous environments. This is the first study on the investigation of source and fate of sediment and river‐borne mercury in the Hunza River. The samples collected near gold panning sites showed higher mercury concentrations than critical levels established by the U.S. Environmental Protection Agency. The observed dissolved mercury concentrations ranged from 5.10 to 25.25 ng/l, whereas particulate‐bound mercury ranged from 4.85 to 154.62 ng/l. Particulate‐phase mercury corresponded to more than 75% of the total observed mercury concentrations for all of the sampled rivers. Thus, suspended sediments represented the major pathway of the riverine mercury transport. A mass balance calculation suggested an annual mercury flux of 48.6 g/km² into the Hunza River basin. The samples collected from the most affected river, the Shimsal River, averaged to have 108 ng/l total mercury. This amount was close to the average soil mercury data of 151 ng/l as reported by the Pakistan Mineral Development Corporation in 2001. The dominant source of contamination was shown to be the leaching of large quantities of mercury from the mercury‐rich sediment and flood plain soil into the rivers, rather than the direct release from mining activities. Significant decrease in both dissolved and particulate‐bound mercury concentration downstream of Attabad Lake suggested that mercury is being accumulated or consumed in the lake. Although minimization or elimination of mercury loses from the mining process seems important for the well‐being of the miners, preventing the remobilization of accumulated mercury is equally important in mercury control in this region. Copyright © 2014 John Wiley & Sons, Ltd.     

Establishing and validation of a standard for oil content of bottom sediments in surface water bodies

Model experiments with oil-polluted bottom sediments and aquatic organisms (bacteria, protozoa, rooted plants, worms, maggots insects, mollusks, crustaceans, benthos-eating fish), whose life cycle is associated with the bed of water bodies, where used to establish the lethal, sublethal, and threshold concentrations, as well as the maximal allowable oil concentration in bottom sediments as a standard established basing on the response of most sensitive test-organisms. The established standard??0.02 g/kg absolutely dry bottom sediment??was validated in rivers of the Ob basin and approved as a regional standard for water bodies of Khanty-Mansi Autonomous Area (Yugra).     

Test of Hack's slope to bed material relationship in the Southern Eifel Uplands,Germany

The local reach gradient of small gravel bed rivers (drainage area 0-8-110 km²) in the Eifel, West Germany, is adjusted to transport the river bed sediments. Transport of gravel becomes possible under high flow conditions (Shields entrainment factor ≈-03). Mean bed material size for riffle sections increases with distance downstream. For small drainage areas channel slope is a negative exponential function of drainage area, while for the larger region the additional influence of bedload size has to be considered. Good agreement with Hack's data (1957) for Virginia and Maryland, U.S.A., is achieved (S = 0.0066 (D₅₀/A)^{- 40.}, r = 0.67).     

In situ quantification of spatial and temporal variability of hyporheic exchange in static and mobile gravel‐bed rivers

Seepage meters modified for use in flowing water were used to directly measure rates of exchange between surface and subsurface water in a gravel‐ and cobble bed river in western Pennsylvania, USA (Allegheny River, Q_mean = 190 m³/s) and a sand‐ and gravel‐bed river in Colorado, USA (South Platte River, Q_mean = 9·7 m³/s). Study reaches at the Allegheny River were located downstream from a dam. The bed was stable with moss, algae, and river grass present in many locations. Median seepage was + 0·28 m/d and seepage was highly variable among measurement locations. Upward and downward seepage greatly exceeded the median seepage rate, ranging from + 2·26 (upward) to ? 3·76 (downward) m/d. At the South Platte River site, substantial local‐scale bed topography as well as mobile bedforms resulted in spatial and temporal variability in seepage greatly in exceedence of the median groundwater discharge rate of 0·24 m/d. Both upward and downward seepage were recorded along every transect across the river with rates ranging from + 2·37 to ? 3·40 m/d. Despite a stable bed, which commonly facilitates clogging by fine‐grained or organic sediments, seepage rates at the Allegheny River were not reduced relative to those at the South Platte River. Seepage rate and direction depended primarily on measurement position relative to local‐ and meso‐scale bed topography at both rivers. Hydraulic gradients were small at nearly all seepage‐measurement locations and commonly were not a good indicator of seepage rate or direction. Therefore, measuring hydraulic gradient and hydraulic conductivity at in‐stream piezometers may be misleading if used to determine seepage flux across the sediment‐water interface. Such a method assumes that flow between the well screen and sediment‐water interface is vertical, which appears to be a poor assumption in coarse‐grained hyporheic settings. Copyright © 2011 John Wiley & Sons, Ltd.