Assessment of Metal Contamination in Surface Sediments of Jiaozhou Bay,Qingdao, China

An assessment of metal contamination in surface sediments of the Jiaozhou Bay, Qingdao, one of the rapidly developing coastal economic zones in China, is provided. Sediments were collected from 10 stations and a total of 15 heavy metals were analyzed. Concentrations of metals show significant variability and range from 210 to 620 ppm for Ti, 2.7 to 23 ppm for Ni, 4.2 to 28 ppm for Cu, 5.2 to 18 ppm for Pb, 12 to 58 ppm for Zn, 0.03 to 0.11 ppm for Cd, 5 to 51 ppm for Cr, 1.5 to 9.9 ppm for Co, 5.3 to 19 ppm for As, 12 to 32 ppm for Se, and 19 to 97 ppm for Sr. Based on concentration relationships and enrichment factor (EF) analyses, the results indicate that sediment grain size and organic matter played important roles in controlling the distribution of the heavy metals in surface sediments of the Jiaozhou Bay. The study shows that the sediment of the Jiaozhou Bay has been contaminated by heavy metals to various degrees, with prominent arsenic contributing the most to the contamination. The analysis suggests that the major sources of metal contamination in the Jiaozhou Bay are land‐based anthropogenic ones, such as discharge of industrial waste water and municipal sewage and run‐off. Notably, the elevated heavy metal concentrations of the Jiaozhou Bay sediments could have a significant impact on the bay's ecosystem. With the rapid economic development and urbanization around the Jiaozhou Bay, coastal management and pollution control should focus on these contaminant sources, as well as provide ongoing monitoring studies of heavy metal contamination within the bay.     

Seasonal controls on stream chemical export across diverse coastal watersheds in the USA

The current study focuses on understanding key factors controlling geochemical export in eight diverse coastal watersheds at seasonal and annual time scales. Geochemical, atmospheric and hydrologic data across a range of hydro‐climatic regimes and varying land uses were investigated and relationships analysed. A hyperbolic dilution model was fitted for each watershed system to evaluate discharge–concentration relationships. Nitrate concentration effects were observed in watersheds exposed to high atmospheric deposition rates as well as agricultural watersheds, whereas urban watersheds showed nitrate dilution effects. Dilution patterns were observed for calcium, magnesium and sulfate for almost all watersheds. Seasonal loads for almost all constituents were noted to be mainly driven by hydrologic seasonality, but are also dependent on inputs (atmospheric deposition and land use sources). Understanding the primary controls on hydro‐chemical interactions is critical for developing and refining predictive water quality models, especially in coastal watersheds where sensitive downstream ecosystems act as receiving waters for upstream pollutant loads. Copyright © 2012 John Wiley & Sons, Ltd.     

基于SWAT模型的南四湖流域非点源氮磷污染模拟

本文利用SWAT模型结合实测数据,对南四湖流域2001-2010年年均非点源氮磷污染进行模拟,分析了南四湖流域非点源氮磷负荷空间分布特征,计算各河流流域对南四湖湖区污染的贡献率,并对非点源氮磷污染严重的关键区进行识别.研究表明:(1)先模拟湖东和湖西的两个典型小流域的非点源氮磷污染,并将模型推及整个南四湖流域,该方法不仅提高了计算效率,且得到了较好的模拟结果.通过对比发现,湖东的模拟效果要好于湖西,一定程度上说明SWAT模型在起伏较大的地区能取得更高的精度.(2)南四湖流域非点源氮磷污染严重,几乎所有区域的氮负荷超标,40%以上的区域磷负荷超标严重.湖东非点源氮磷污染较湖西严重,其中洸府河流域是南四湖湖区非点源氮磷污染的主要贡献者.(3)通过对径流量、泥沙负荷、氮负荷、磷负荷的相关分析可以得出,南四湖流域非点源氮负荷以溶解态为主,随径流进入水体;非点源磷负荷以吸附态为主,随泥沙进入水体.     

The effect of Razdol’naya River on the environmental state of Amur Bay (the Sea of Japan)

Seasonal variations in biogenic substances (nitrates, nitrites, ammonium, phosphates, and silicates), dissolved oxygen, dissolved organic matter, chlorophyll, humus, and suspended matter at seven stations on the Razdol’naya River are examined. Based on seasonal variations, the local sources of river water pollution by biogenic substances were identified. The annual and daily fluxes of biogenic substances through the Razdol’naya River into Amur Bay are calculated. A diffuse pollution source—agricultural fields in river valley—are shown to be the main source of biogenic substance fluxes. The vast hypoxia in the bottom water of Amur Bay, detected by the authors in 2007 and 2008, is supposed to be mostly caused by floods on the Razdol’naya R., which create favorable conditions of water blooming in Amur Bay in summer. The biomass of dead phytoplankton, experiencing microbiological decomposition and oxidation, causes hypoxia of bottom waters in the bay.     

Decoupling the effects of deforestation and climate variability in the Tapajós river basin in the Brazilian Amazon

Tropical river basins are experiencing major hydrological alterations as a result of climate variability and deforestation. These drivers of flow changes are often difficult to isolate in large basins based on either observations or experiments; however, combining these methods with numerical models can help identify the contribution of climate and deforestation to hydrological alterations. This paper presents a study carried out in the Tapaj?s River (Brazil), a 477,000 km² basin in South‐eastern Amazonia, in which we analysed the role of annual land cover change on daily river flows. Analysis of observed spatial and temporal trends in rainfall, forest cover, and river flow metrics for 1976 to 2008 indicates a significant shortening of the wet season and reduction in river flows through most of the basin despite no significant trend in annual precipitation. Coincident with seasonal trends over the past 4 decades, over 35% of the original forest (140,000 out of 400,000 km²) was cleared. In order to determine the effects of land clearing and rainfall variability to trends in river flows, we conducted hindcast simulations with ED2 + R, a terrestrial biosphere model incorporating fine scale ecosystem heterogeneity arising from annual land‐use change and linked to a flow routing scheme. The simulations indicated basin‐wide increases in dry season flows caused by land cover transitions beginning in the early 1990s when forest cover dropped to 80% of its original extent. Simulations of historical potential vegetation in the absence of land cover transitions indicate that reduction in rainfall during the dry season (mean of ?9 mm per month) would have had an opposite and larger magnitude effect than deforestation (maximum of +4 mm/month), leading to the overall net negative trend in river flows. In light of the expected increase in future climate variability and water infrastructure development in the Amazon and other tropical basins, this study presents an approach for analysing how multiple drivers of change are altering regional hydrology and water resources management.     

Assessment and impact of microbial fecal pollution and human enteric pathogens in a coastal community

The goals of this study were to assess watersheds impacted by high densities of OSDS (onsite sewage disposal systems) for evidence of fecal contamination and evaluate the occurrence of human pathogens in coastal waters off west Florida. Eleven stations (representing six watersheds) were intensively sampled for microbial indicators of fecal pollution (fecal coliform bacteria, enterococci, Clostridium perfringens and coliphage) and the human enteric pathogens, Cryptosporidium, Giardia, and enteroviruses during the summer rainy season (May-September 1996). Levels of all indicators ranged between < 5 and > 4000 CFU/100 ml. Cryptosporidium and Giardia were detected infrequently (6.8% and 2.3% of samples tested positive, respectively). Conversely, infectious enteroviruses were detected at low levels in 5 of the 6 watersheds sampled. Using cluster analysis, sites were grouped into two categories, high and low risks, based on combined levels of indicators. These results suggest that stations of highest pollution risk were located within areas of high OSDS densities. Furthermore, data indicate a subsurface transport of contaminated water to surface waters. The high prevalence of enteroviruses throughout the study area suggests a chronic pollution problem and potential risk to recreational swimmers in and around Sarasota Bay.     

Comparison of stormflow responses of surface‐mined and forested watersheds in the Appalachian Mountains,USA

The results of a hydrological analysis that was conducted as part of a larger, multifaceted, collaborative effort to quantify ecosystem functions in watersheds subjected to land‐use and land‐cover change are presented. The primary goal of the study was to determine whether a small watershed in the Appalachian region (USA) that was recently subjected to surface mining and reclamation practices produces stormflow responses to rain events that are different from those produced by a nearby reference watershed covered by young, second‐growth forest. Water balances indicated that runoff yields did not vary significantly between the two watersheds on an annual basis. Statistically significant differences (p?0·05) in runoff responses were observed on an event basis, however, with the mined/reclaimed watershed producing, on average (a) higher storm runoff coefficients (2·5×), (b) greater total storm runoff (3×), and (c) higher peak hourly runoff rates (2×) when compared with the reference watershed. Results of a unit hydrograph analysis also showed, unexpectedly, that the modelled unit responses of the two watersheds to effective rainfall pulses were similar, despite the noted differences in land cover. Differences in stormflow responses were thus largely explained by dramatic reductions in cumulative rates of rainfall abstraction (measured using infiltrometers) attributable to soil compaction during land reclamation. Additional field hydrological measurements on other mined watersheds will be needed to generalize our results, as well as to understand and predict the cumulative hydrological impacts of widespread surface mining in larger watersheds and river basins. Copyright © 2006 John Wiley & Sons, Ltd.     

Unraveling complex hydrogeological processes in Andean basins in south‐central Chile: An integrated assessment to understand hydrological dissimilarity

Groundwater storage, drainage, and interbasin water exchange are common hydrological processes but often difficult to quantify due to a lack of local observations. We present a study of three volcanic mountainous watersheds located in south‐central Chile (~36.9 ° S) in the Chillán volcanic complex (Chillán, Renegado, and Diguillín river basins). These are neighboring basins that are similar with respect to the metrics normally available for characterization everywhere (e.g., precipitation, temperature, and land cover). In a hydrological sense, similar (proportional) behavior would be expected if these catchments would be characterized with this general information. However, these watersheds show dissimilar behavior when analyzed in detail. The surface water balance does not fit for any of these watersheds individually; however, the water balance of the whole system can be explained by likely interbasin water exchanges. The Renegado river basin has an average annual runoff per unit of area on the order of 60–65% less than those of the Diguillín and Chillán rivers, which is contradictory to the hydrological similarity among the basins. To understand the main processes that control streamflow generation, two analyses were performed: (a) basin metrics (land cover, geologic, topographic, and climatological maps) and hydro‐meteorological data analyses and (b) a water balance model approach. The analyses contribute to a plausible explanation for the hydrogeological processes in the system. The soils, topography, and geology of the Chillán–Renegado–Diguillín system favor the infiltration and groundwater movements from the Renegado river basin, mainly to the neighboring Diguillín basin. The interbasin water exchanges affect hydrological similarity and explain the differences observed in the hydrological processes of these three apparently similar volcanic basins. The results highlight the complexity of hydrological processes in volcanic mountainous systems and suggest that a simple watershed classification approach based on widely available data is insufficient. Simple local analyses such as specific flow analysis with a review of the geology and morphology can contribute to a better understanding of the hydrology of volcanic mountainous areas.     

Distribution,characteristics and potential impacts of chromophoric dissolved organic matter (CDOM) in Hudson Strait and Hudson Bay,Canada

The characteristics of chromophoric dissolved organic matter (CDOM) were studied in Hudson Bay and Hudson Strait in the Canadian Arctic. Hudson Bay receives a disproportionately large influx of river runoff. With high dissolved organic matter (DOM) concentrations in Arctic rivers the influence of CDOM on coastal and ocean systems can be significant, yet the distribution, characteristics and potential consequences of CDOM in these waters remain unknown. We collected 470 discrete water samples in offshore, coastal, estuarine and river waters in the region during September and October 2005. Mixing of CDOM appeared conservative with salinity, although regional differences exist due to variable DOM composition in the rivers discharging to the Bay and the presence of sea-ice melt, which has low CDOM concentrations and low salinity. There were higher concentrations of CDOM in Hudson Bay, especially in coastal waters with salinities <28$<28$, due to river runoff. Using CDOM composition of water masses as a tracer for the freshwater components revealed that river runoff is largely constrained to nearshore waters in Hudson Bay, while sea-ice melt is distributed more evenly in the Bay. Strong inshore–offshore gradients in the bio-optical properties of the surface waters in the Hudson Bay cause large variation in penetration of ultraviolet radiation and the photic depth within the bay, potentially controlling the vertical distribution of biomass and occurrence of deep chlorophyll maxima which are prevalent only in the more transparent offshore waters of the bay. The CDOM distribution and associated photoprocesses may influence the thermodynamics and stratification of the coastal waters, through trapping of radiant heating within the top few meters of the water column. Photoproduction of biologically labile substrates from CDOM could potentially stimulate the growth of biomass in Hudson Bay coastal waters. Further studies are needed to investigate the importance of terrestrial DOM in the Hudson Bay region, and the impact of hydroelectric development and climate change on these processes.     

Effect of land‐use changes on nonpoint source pollution in the Xizhi River watershed,Guangdong, China

The Annualized Agricultural Non‐point Source (AnnAGNPS) pollution model has been widely used to assess and predict runoff, soil erosion, sediment and nutrient loading with a geographic information system. This article presents a case study of the effect of land‐use changes on nonpoint source (NPS) pollution using the AnnAGNPS model in the Xizhi River watershed, eastern Pearl River Delta of Guangdong province, China. The land‐use changes in the Xizhi River watershed between 1998 and 2003 were examined using the multitemporal remote sensing data. The runoff, soil erosion, sediment transport and nutrient loading 1998 and 2003 were assessed using AnnAGNPS. The effects of land‐use changes on NPS were studied by comparing the simulation results of each year. Our results showed that (i) the NPS loadings increased when forest and grass land converted into paddy, orchard and farmland land, and population size and gross domestic product size as well as the usage amounts of fertilizer and pesticide in the entire watershed were firmly correlated with the NPS loadings; (ii) the land‐use change during fast urbanization in particular when other land types were converted into the development land and buildup land led to increasing of NPS pollution; and (iii) urban land expansion showed more important effects on total organic carbon (TOC) loading compared with nitrogen and phosphorus loadings. Copyright © 2012 John Wiley & Sons, Ltd.     

Effects of land cover change on streamflow in the interior Columbia River Basin (USA and Canada)

An analysis of the hydrological effects of vegetation changes in the Columbia River basin over the last century was performed using two land cover scenarios. The first was a reconstruction of historical land cover vegetation, c. 1900, as estimated by the federal Interior Columbia Basin Ecosystem Management Project (ICBEMP). The second was current land cover as estimated from remote sensing data for 1990. Simulations were performed using the variable infiltration capacity (VIC) hydrological model, applied at one‐quarter degree spatial resolution (approximately 500 km² grid cell area) using hydrometeorological data for a 10 year period starting in 1979, and the 1900 and current vegetation scenarios. The model represents surface hydrological fluxes and state variables, including snow accumulation and ablation, evapotranspiration, soil moisture and runoff production. Simulated daily hydrographs of naturalized streamflow (reservoir effects removed) were aggregated to monthly totals and compared for nine selected sub‐basins. The results show that, hydrologically, the most important vegetation‐related change has been a general tendency towards decreased vegetation maturity in the forested areas of the basin. This general trend represents a balance between the effects of logging and fire suppression. In those areas where forest maturity has been reduced as a result of logging, wintertime maximum snow accumulations, and hence snow available for runoff during the spring melt season, have tended to increase, and evapotranspiration has decreased. The reverse has occurred in areas where fire suppression has tended to increase vegetation maturity, although the logging effect appears to dominate for most of the sub‐basins evaluated. Predicted streamflow changes were largest in the Mica and Corralin sub‐basins in the northern and eastern headwaters region; in the Priest Rapids sub‐basin, which drains the east slopes of the Cascade Mountains; and in the Ice Harbor sub‐basin, which receives flows primarily from the Salmon and Clearwater Rivers of Idaho and western Montana. For these sub‐basins, annual average increases in runoff ranged from 4·2 to 10·7% and decreases in evapotranspiration ranged from 3·1 to 12·1%. In comparison with previous studies of individual, smaller sized watersheds, the modelling approach used in this study provides predictions of hydrological fluxes that are spatially continuous throughout the interior Columbia River basin. It thus provides a broad‐scale framework for assessing the vulnerability of watersheds to altered streamflow regimes attributable to changes in land cover that occur over large geographical areas and long time‐frames. Copyright © 2000 John Wiley & Sons, Ltd.     

Non‐point source pollution estimation using a modified approach

Non‐point source (NPS) pollution from agricultural land is increasing exponentially in many countries of the world, including India. A modified approach based on the conservation of mass and reaction kinetics has been derived to estimate the inflow of non‐point source pollutants from a river reach. Two water quality variables, namely, nitrate (NO₃) and ortho‐phosphate (o‐PO₄), which are main contributors as non‐point source pollution, were monitored at four locations of River Kali, western Uttar Pradesh, India, and used for calibration and validation of the model. Extensive water quality sampling was done with a total of 576 field data sets collected during the period from March 1999 to February 2000. Remote sensing and geographical information system (GIS) techniques were used to obtain land use/land cover of the region, digital elevation model (DEM), delineation of basin area contributing to non‐point source pollution at each sampling location and drainage map. The results obtained from a modified approach were compared with the existing mass‐balance equations and distributed modelling, and the performances of different equations were evaluated using error estimation viz. standard error, normal mean error, mean multiplicative error and correlation statistics. The developed model for the River Kali minimizes error estimates and improves correlation between observed and computed NPS loads. Copyright © 2007 John Wiley & Sons, Ltd.     

Coastal circulation near kakinada bay during monsoon period

Summary With a view of understanding the various processes responsible for the deposition of sand in the vicinity of Kakinada Bay and Godavari Point, an intensive study of currents in the coastal waters has been made using floats. The circulation has high variability in both magnitude and direction related to the three current components namely wind currents, tidal currents and wave currents. The circulation pattern rapidly changes with the change in the phase of the tide and local winds of land and see breeze. The littoral currents directed up-coast during premonsoon and monsoon seasons have insignificant effect across the bay opening due to the sheltering effect of the sand bar. The study is found helpful for understanding the geomorphological changes of the shoreline in this region from time to time.     

Variations in the response of the dune coast of northern France to major storms as a function of available beach sediment volume

A series of airborne topographic LiDAR data were obtained from May 2008 to January 2014 over two coastal sites of northern France (Bay of Wissant and east of Dunkirk). These data were used with wind and tide gauge measurements to assess the impacts of storms on beaches and coastal dunes, and particularly of the series of major storms that hit western Europe during the fall and early winter of 2013. Our results show a high variability in shoreline response from one site to the other, but also within each coastal site. Coastal dune erosion and shoreline retreat occurred at both sites, particularly on the coast of the Bay of Wissant where shoreline retreat up to about 40 m was measured. However, stability or even shoreline advance were also observed despite the occurrence of an extreme water level with a return period >100 years during the storm Xaver in early December 2013. Comparison of shoreline change with variations of coastal dune and upper beach volumes revealed only weak relationships. Our results nevertheless showed that shoreline behavior seems to strongly depend on the initial sediment volume on the upper beach before the occurrence of the storms. According to our measurements, an upper beach volume of about 30 m³ m^?1 between the dune toe and the mean high water level is sufficient at these sites to protect the coastal dunes from storm waves associated with high water levels with return periods >10 years. The identification of such thresholds in terms of upper beach width or sediment volume may represent valuable information for improving the management of shoreline change by providing an estimate of the minimum quantity of sand on the upper beach necessary to ensure shoreline stability in this region. Copyright © 2016 John Wiley & Sons, Ltd.     

Nutrient fluxes at the river basin scale. I: the PolFlow model

Human activity has resulted in increased nutrient levels in rivers and coastal seas all over Europe. Models that can describe nutrient fluxes from pollution sources to river outlets may help policy makers to select the most effective source control measures to achieve a reduction of nutrient levels in rivers and coastal seas. Part I of this paper describes the development of such a model: PolFlow. PolFlow was specially designed for operation at the river basin scale and is here applied to model 5‐year average nitrogen and phosphorus fluxes in two European river basins (Rhine and Elbe) covering the period 1970–1995. Part II reports an error analysis and model evaluation, and compares PolFlow to simpler alternative models. Copyright © 2001 John Wiley & Sons, Ltd.     

山东半岛及附近海域地震活动特征及近期地震危险性趋势分析

本文通过对山东半岛及附近海域地质构造分析、地震学参数时空扫描计算、地震背景形势分析等认为：山东半岛及附近海域有发生5级左右地震的异常背景。预测区域为：胶东及北部海域3-4级地震条带及边缘有发生4.5级左右地震的可能;渤海海域自1969年7.4级地震后,其地震能量释放呈下降趋势,近20年活动水平为4级左右,渤海海域近期发生大于5级以上地震的可能性较小。北黄海海域近几年地震活动水平明显高于渤海海域。北黄海未来一、二年或稍长时间有发生5级左右地震的可能,应注意山东半岛及北部海域地震活动趋势的发展。     

Factors controlling nitrogen and dissolved organic carbon exports across timescales in two watersheds with different land uses

Investigating factors controlling the temporal patterns of nitrogen (N) and dissolved organic carbon (DOC) exports on the basis of a comparative study of different land uses is beneficial for managing water resources, especially in agricultural watersheds. We focused our research on an agricultural watershed (AW) and a forested watershed (FW) located in the Shibetsu watershed of eastern Hokkaido, Japan, to investigate the temporal patterns of N and DOC exports and factors controlling those patterns at different timescales (inter‐annual, seasonal, and hydrological event scales). Results showed that the annual patterns of N and DOC exports significantly varied over time and were probably controlled by climate. Higher discharge volumes in 2003, a wet year, showed higher N and DOC loadings in both watersheds. However, this process was also regulated by land use associated with N inputs. Higher concentrations and loadings were shown in the agricultural watershed. At the seasonal scale, N and DOC exports in the AW and the FW were more likely controlled by sources associated with land use. The Total N (TN) and Nitrate‐N (NO₃^?‐N) had higher concentrations during snowmelt season in the AW, which may be attributed to manure application in late autumn or early winter in the agricultural watershed. Concentrations of TN, NO₃^?‐N, dissolved organic nitrogen (DON), and DOC showed higher values during the summer rainy season in the FW, related to higher litter decomposition during summer and autumn and the fertilizer application in the agricultural area during summer. Higher DOC concentrations and loadings were observed during the rainy season in the AW, which is probably attributed to higher DOC production related to temperature and microbial activity during summer and autumn in grasslands. Correlations between discharge and concentrations differed during different periods or in different watersheds, suggesting that weather discharge can adequately represent the fact that N export depends on N concentrations, discharge level, and other factors. The differing correlations between N/DOC concentrations and the Si concentration indicated that the N/DOC exports might occur along different flow paths during different periods. During baseflow, the high NO₃^?‐N exports were probably derived from deep groundwater and might have percolated from uplands during hydrological events. During hydrological events, NO₃^?‐N exports may occur along near‐surface flow paths and in deep groundwater, whereas DOC exports could be related to near‐surface flow paths. At the event scale, the relationships between discharge and concentrations of N and DOC were regulated by antecedent soil moisture (shallow groundwater condition) in each watershed. These results indicated that factors controlling N and DOC exports varied at different timescales in the Shibetsu area and that better management of manure application during winter in agricultural lands is urgently needed to control water pollution in streams. Copyright © 2013 John Wiley & Sons, Ltd.     

Application of spatial EOF and multivariate time series model for evaluating agricultural drought vulnerability in Korea

This study proposed a methodology using the empirical orthogonal function (EOF) and multivariate time series model for the analysis of drought both in time and space. The methodology proposed was then applied to evaluate the vulnerability of agricultural drought of major river basins in Korea. First, the three-month SPI data from 59 rain gauge stations over the Korean Peninsula were analyzed by deriving and spatially characterizing the EOFs. The shapes of major estimated EOFs were found to well reflect the observed spatial pattern of droughts. Second, the coefficient time series of estimated EOFs were then fitted by a multivariate time series model to generate the SPI data for 10,000 years, which were used to derive the annual maxima series of areal average drought severity over the Korean Peninsula. These annual maxima series were then analyzed to determine the mean drought severity for given return periods. Four typical spatial patterns of drought severity could also be selected for those return periods considered. This result shows that the southern part of the Korean Peninsula is most vulnerable to drought than the other parts. Finally, the agricultural drought vulnerability was evaluated by considering the potential water supply from dams. In an ideal case, when all the maximum dam storage was assumed to be assigned to agriculture, all river basins in Korea were found to have the potential to overcome a 30-year drought. However, under more realistic conditions considering average dam storage and water allocation priorities, most of the river basins could not overcome a 30-year drought.     

Resistance of a coastal ecosystem to increasing eutrophic conditions: the Bay of Brest (France), a semi-enclosed zone of Western Europe

The Bay of Brest is a semi-enclosed coastal ecosystem receiving high nutrients loading from freshwater inputs. In order to analyse the response of phytoplankton stocks to increasing eutrophic conditions, a survey of the annual cycle of hydrographic properties, nutrients and chlorophyll a concentrations, and carbon uptake rates was performed at four stations in 1993. This database has been compared to earlier measurements performed during several comparable surveys within the last 20 years. As compared to the seventies, a doubled nitrate loading is now entering this ecosystem, which is related to increased agricultural activities on the drainage basins, while the geographical origin of the nitrate input has been modified. As a result of these anthropogenic modifications, summer averaged Si/N stoichiometric balance has decreased during the two last decades but, contrary to what has been observed in other coastal ecosystems, phytoplankton stocks have not increased. Several ecological factors have hindered eutrophication: the high hydrodynamic mixing with adjacent marine waters, caused by the macrotidal regime, induces important nutrients losses, temperature and mostly light limit primary production while Si and P high recycling maintain nitrogen limitation in this ecosystem. Conjunction of these non-anthropogenic factors explains the global stability of phytoplankton stocks.     

Modelling particle residence times in agricultural river basins using a sediment budget model and fallout radionuclide tracers

Contemporary patterns in river basin sediment dynamics have been widely investigated but the timescales associated with current sediment delivery processes have received much less attention. Furthermore, no studies have quantified the effect of recent land use change on the residence or travel times of sediment transported through river basins. Such information is crucial for understanding contemporary river basin function and responses to natural and anthropogenic disturbances or management interventions. To address this need, we adopt a process‐based modelling approach to quantify changes in spatial patterns and residence times of suspended sediment in response to recent agricultural land cover change. The sediment budget model SedNet was coupled with a mass balance model of particle residence times based on atmospheric and fluvial fluxes of three fallout radionuclide tracers (⁷Be, excess ²¹⁰Pb and ¹³⁷Cs). Mean annual fluxes of suspended sediment were simulated in seven river basins (38–920 km²) in south‐west England for three land cover surveys (1990, 2000 and 2007). Suspended sediment flux increased across the basins from 0.5–15 to 1.4–37 kt y^‐1 in response to increasing arable land area between consecutive surveys. The residence time model divided basins into slow (upper surface soil) and rapid (river channel and connected hillslope sediment source area) transport compartments. Estimated theoretical residence times in the slow compartment decreased from 13–48 to 5.6–14 ky with the increase in basin sediment exports. In contrast, the short residence times for the rapid compartment increased from 185–256 to 260–368 d as the modelled connected source area expanded with increasing sediment supply from more arable land. The increase in sediment residence time was considered to correspond to longer sediment travel distances linked to larger connected source areas. This novel coupled modelling approach provides unique insight into river basin responses to recent environmental change not otherwise available from conventional measurement techniques. © 2014 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.