Preferential exchange rate effect of isotopic fractionation in a melting snowpack

Stable isotope exchange processes between solid and liquid phases of a natural melting snowpack are investigated in detail by separating the liquid water from snow grains at different depths of the snowpack and collecting the bottom discharge using a lysimeter. In the melting–freezing mass exchange process between the two phases, the theoretical slope of the δD? δ¹⁸O line for newly refrozen ice is calculated to be nearly that of pore water. However, based on observations of the isotopic evolution and snow grain coarsening of the snowpack, it is demonstrated that the slope of the δD? δ¹⁸O line for newly refrozen ice is equal to that of the original ice. This is proved to be due to preferential water flow in the snowpack, which leads to relatively more deuterium and less oxygen‐18 in the mobile water than the immobile water because of the kinetic effect. Higher mass exchange rate in the mobile water region results in excess deuterium in the bulk refrozen ice, compared with the fractionation of uniform fractionation factors and exchange rate. This effect, which is termed the ‘preferential exchange rate effect of isotopic fractionation’, is shown to be larger in the lower part than the upper part of the snowpack. Copyright © 2008 John Wiley & Sons, Ltd.     

The effect of refreezing on the isotopic composition of melting snowpack

The isotopic composition of solid and liquid portions of natural melting snowpack is investigated in detail by the separating of liquid water from snow grains at different depths of the snowpack. The slope of the δD–δ¹⁸O line for the liquid phase is found to be lower than for the solid phase. This is proved to be due to the isotopic fractionation occurring in the melt–freeze mass exchange within the snowpack. Melting of the snowpack has no clear impact on the δD–δ¹⁸O line for the solid phase, but the slope of the δD–δ¹⁸O line for the liquid shows an overall slight decrease in the melting period. When the snowpack is refrozen, the refreezing process would inevitably cause the slope of the solid phase to decrease because of the discrepancy between the slopes of the two phases. Thus the slope of the solid would become lower and lower as the diurnal melt–freeze episodes cycle throughout the melting season. This effect is then demonstrated by looking into the isotopic composition changes of glacier firn. The extent of the effect depends on the snowpack properties and environmental conditions. The slope changes also result in a decreasing trend in deuterium excess. Copyright © 2007 John Wiley & Sons, Ltd.     

Interannual variability in glacier contribution to runoff from a high‐elevation Andean catchment: understanding the role of debris cover in glacier hydrology

We present a field‐data rich modelling analysis to reconstruct the climatic forcing, glacier response, and runoff generation from a high‐elevation catchment in central Chile over the period 2000–2015 to provide insights into the differing contributions of debris‐covered and debris‐free glaciers under current and future changing climatic conditions. Model simulations with the physically based glacio‐hydrological model TOPKAPI‐ETH reveal a period of neutral or slightly positive mass balance between 2000 and 2010, followed by a transition to increasingly large annual mass losses, associated with a recent mega drought. Mass losses commence earlier, and are more severe, for a heavily debris‐covered glacier, most likely due to its strong dependence on snow avalanche accumulation, which has declined in recent years. Catchment runoff shows a marked decreasing trend over the study period, but with high interannual variability directly linked to winter snow accumulation, and high contribution from ice melt in dry periods and drought conditions. The study demonstrates the importance of incorporating local‐scale processes such as snow avalanche accumulation and spatially variable debris thickness, in understanding the responses of different glacier types to climate change. We highlight the increased dependency of runoff from high Andean catchments on the diminishing resource of glacier ice during dry years.     

Effect of dust event timing on glacier runoff: sensitivity analysis for a Tibetan glacier

The impact of the timing of dust deposition on glacier runoff was evaluated using a glacier mass‐balance model with a newly improved scheme to track a dusted layer in a snow layer of a glacier. The lowering of surface albedo due to the dusted layer appearing leads to a drastic increase of glacier runoff even under the same meteorological conditions. Calculations of seasonal sensitivity, the relationship between dusted date and resulting runoff, have shown that dust deposition during a melting season might cause a drastic mass outflow from a glacier through changing the surface albedo during the melting season. Copyright © 2006 John Wiley & Sons, Ltd.     

Brixenbach research catchment: Quantification of runoff process proportions in a small Alpine catchment depending on soil moisture states and precipitation characteristics

The Brixenbach valley is a small Alpine torrent catchment (9.2 km², 820–1950 m a.s.l., 47.45°, 12.26°) in Tyrol, Austria. Intensive hydrological research in the catchment since more than 12 years, including a hydrogeological survey, pedological and land use mapping, measurements of precipitation, runoff, soil moisture and infiltration as well as the conduction of rainfall simulations, has contributed to understand the hydrological response of the catchment, its subcatchments and specific sites. The paper presents a synthesis of the research in form of runoff process maps for different soil moisture states and precipitation characteristics, derived with the aid of a newly developed Soil-hydrological model. These maps clearly visualize the differing runoff reaction of different subcatchments. The pasture dominated areas produce high surface flow rates during short precipitation events (1 h, 86 mm) with high rainfall intensity, whilst the forested areas often develop shallow subsurface flow. Dry preconditions lead to a slight reduction of surface flow, long rainfall events (24 h, 170 mm) to a dominance of deep subsurface flow and percolation.     

Quantifying the contribution of climate and underlying surface changes to alpine runoff alterations associated with glacier melting

Climate variability and underlying surface changes are strongly associated with runoff alterations. The Yarlung Zangbo River Basin (YZRB) is a typical alpine region located in the southeast Qinghai–Tibet Plateau, where runoff is particularly sensitive and vulnerable to climate and environmental changes. Here, we conducted a quantitative assessment of the contributions of climate variability and underlying surface changes to runoff alterations from 1966 to 2015 in the upper, middle, and lower regions of the YZRB. The year 1997 was identified as the runoff breakpoint in all three sub-regions, which divided the runoff time series into the baseline period (1966–1997) and change period (1998–2015). An adjusted Budyko framework accounting for glacier runoff was developed to conduct a runoff alteration attribution analysis. The results indicated that the increase in runoff in the upper region was dominated by changes in the underlying surface and glacier runoff, whose contribution accounted for 59.61 and 49.18%, respectively. The runoff increase in the middle and lower regions was mainly attributed to the increase in precipitation, accounting for 39.36 and 129.21% of the total runoff alteration, respectively. Moreover, due to the little variation in vegetation and degradation of permafrost in the upper region, increases in runoff might be largely attributed to increases in subsurface runoff caused by the melting of permafrost. In the middle region, in addition to increased precipitation, vegetation degradation had positive effects on runoff increases. The lower region exhibited far higher water consumption rates due to its extensive and dense vegetation coverage accompanied by rising temperature, which resulted in a negative contribution (−58.74%) to runoff alteration. Our findings may therefore have important implications for water resource security and sustainable development in alpine regions.     

Effects of hillslope topography on runoff response in a small catchment in the Fudoji Experimental Watershed,central Japan

We investigated the role of different hillslope units with different topographic characteristics on runoff generation processes based on field observations at two types of hillslopes (0·1 ha): a valley‐head (a convergent hillslope) and a side slope (a planar hillslope), as well as at three small catchments having two types of slopes with different drainage areas ranging from 1·9 to 49·7 ha in the Tanakami Mountains, central Japan. We found that the contribution of the hillslope unit type to small catchment runoff varied with the magnitude of rainfall. When the total amount of rainfall for a single storm event was < 35 mm, runoff in the small catchment was predominantly generated from the side slope. As the amount of rainfall increased (>35 mm), the valley‐head also began to contribute to the catchment runoff, adding to runoff from the side slope. Although the direct runoff from the valley‐head was greater than that from the side slope, the contribution from the side slope was quantitatively greater than that from the valley‐head due to the proportionally larger area occupied by the side slope in the small catchment. The storm runoff responses of the small catchments reflected the change in the runoff components of each hillslope unit as the amount of rainfall increased and rainfall patterns changed. However, similar runoff responses were found for the small catchments with different areas. The similarity of the runoff responses is attributable to overlay effects of different hillslope units and the similar composition ratios of the valley‐head and side slope in the catchments. This study suggests that the relative roles of the valley‐head and side slope are important in runoff generation and solute transport as the catchment size increases from a hillslope/headwater to a small catchment. Copyright © 2011 John Wiley & Sons, Ltd.     

Effect of catchment properties on runoff coefficient in a karst area of southwest China

Frequent human activities and climate change in the karst region of southwest China since the 1950s have led to the investigation of response of runoff to climate and catchment properties. Runoff coefficient (Rc) as an expression variable of the catchment response to rainfall is important to describe runoff dynamics and to estimate available streamflow for utilization. In this study, the equations of Rc associated with its attributors of climate condition and catchment property were derived using the Budyko framework. The equations were used to estimate relationship between the Rc and the attributors in the karst catchments in Guizhou province of southwest China. Analysis in the selected 23 karst catchments demonstrates that the spatial distribution of Rc is dominated by the catchment properties, such as the catchment properties of geology, slope and land use and land cover, rather than climate condition of drought index. Correlation analysis indicates that the catchment with a large slope usually has a high value of Rc, and a large proportion of carbonate rock in a catchment reduces Rc in the study area. Temporal increasing trend of Rc during 1961–2000 was found for most catchments in the study area. This increasing trend was primarily resulted from changes of catchment properties, e.g. deforestation in large areas of Guizhou province during the 1950s–1980s. Copyright © 2013 John Wiley & Sons, Ltd.     

Hydrological behaviour of a drained agricultural peat catchment in the tropics. 1: Rainfall,runoff and water table relationships

Abstract

Hydrological data of a drained tropical peat catchment have been analysed through conventional quantitative hydrological approaches to characterize its hydrological behaviours and changes due to continuous drainage for a long period. The results show that the hydrology of the catchment is extremely dynamic and the catchment is flashy in nature. A decreasing trend in peak flow amount and an increasing trend in baseflow amount was observed in the catchment, indicating that continuous drainage has reduced the risk of both flooding and water scarcity in the catchment. Correlation analysis among rainfall, runoff and groundwater table reveals that saturation excess-near surface flow is the dominant mechanism responsible for rapid runoff generation in the catchment. Therefore, any physical alterations or disturbances to the upper part of the peat profile would definitely affect the overall hydrological behaviour of the peat catchment.

Editor Z.W. Kundzewicz; Associate editor D. Hughes

Citation Katimon, A., Shahid, S., Abd Wahab, A.K., and Ali, M.H., 2013. Hydrological behaviour of a drained agricultural peat catchment in the tropics. Part 1: Rainfall, runoff and water table relationships. Hydrological Sciences Journal, 58 (6), 1297–1309.     

Development and application of a catchment scale diffuse nitrate modelling tool

Water pollution from diffuse sources is a problem of increasing concern. Efforts to control diffuse pollution have been confined mainly to agricultural land and forests. Little attention has been paid to sources of diffuse pollution from urban areas. A diffuse nitrate modelling tool (DNMT) has been developed for modelling the fate of nitrate in urban areas. This tool works at the catchment scale and has a modular structure that consists of three components: the hydrological module, the nitrogen cycle module and the nitrate transport module. The hydrological model describes the possible flow pathways. The nitrogen cycle model accounts for the mass balance of nitrate and calculates the amount of nitrate for potential loss. The nitrate transport module simulates the movement of nitrate within and from the soil to the receiving water. This paper demonstrates the development of the tool and its application in the White Cart Water catchment. This implementation of the tool shows that it has a good capability for simulating the fate of nitrate in urban catchments. Copyright © 2005 John Wiley & Sons, Ltd.     

Projection of runoff characteristics as a response to regional climate change in a Central/Eastern European catchment

ABSTRACT

The impact of climate change on runoff characteristics is investigated for the Upper Tisza basin, in eastern Central Europe. For a reliable estimation of uncertainty, an appropriate stochastic weather generator is embedded into a Monte Carlo cycle capable of generating any large number of independent, equally probable, 100-year-long daily sequences of synthetic data with which a hydrological model is driven in order to obtain the hydrological responses to the meteorological data sequences. According to our results, a decrease of daily average runoff is likely to occur in the future in the Upper Tisza basin, especially in July and August. The occurrence of water levels below the critical low level is estimated to increase between July and October. Level-3 flood warnings are projected to be less frequent in the future; however, they will tend to be more severe than in the historical period.     

Characteristics and climatic sensitivities of runoff from a cold‐type glacier on the Tibetan Plateau

Model calculations are made in order to understand the characteristics and response to climate change of runoff from a cold glacier on the Tibetan Plateau. Some 20% of meltwater is preserved at the snow–ice boundary due to refreezing, since the glaciers in mid to northern Tibet are sufficiently cooled during the previous winter. Sensitivity to alterations in meteorological parameters has revealed that a change in air temperature would cause not only an increase in melting by sensible heat, but also a drastic increase in melting due to lowering of the albedo, since some of the snowfall changes to rainfall. In addition, it was suggested that a decrease in precipitation would cause a lowering of the surface albedo, with a resulting increase in the contribution of glacier runoff to the total runoff of river water. This study shows the first quantitative evaluation of the above effects, though they have been suggested qualitatively. The seasonal sensitivity of glacier runoff was examined by changing the dates given for a meteorological perturbation for a period of only 5 days. It was revealed that changes in both air temperature and precipitation during the melting season strongly affected glacier runoff by changing the surface albedo, though these perturbations only slightly altered the annual averages. Copyright © 2006 John Wiley & Sons, Ltd.     

Isotopic composition of precipitation in a topographically steep,seasonally snow‐dominated watershed and implications of variations from the global meteoric water line

The local meteoric water line (LMWL), the functional relationship between locally measured values of δ¹⁸O and δ²H in precipitation, represents the isotopic composition of water entering hydrologic systems. The degree to which the LMWL departs from the global meteoric water line (GMWL), moreover, can reveal important information about meteoric sources of water (e.g. oceanic or terrestrial) and atmospheric conditions during transport. Here we characterize the isotopic composition of precipitation within an experimental watershed in the Western US that is subject to large topographic and seasonal gradients in precipitation. Interpreting the hydrometeorologic and spatial controls on precipitation, we constructed a seasonally weighted LMWL for southwestern Idaho that is expressed by the equation δ²H = 7.40 × δ¹⁸O ? 2.17. A seasonally weighted LMWL that is based on weighting isotopic concentrations by climatic precipitation volumes is novel, and we argue better represents the significant seasonality of precipitation in the region. The developed LMWL is considerably influenced by the semiarid climate experienced in southwest Idaho, yielding a slope and y‐intercept lower than the GMWL (δ²H = 8 × δ¹⁸O + 10). Moderate to strong correlations exist between the isotopic composition of precipitation from individual events and surface meteorologic variables, specifically surface air temperature, relative humidity, and precipitation amount. A strong negative correlation exists between the annual average isotopic composition of precipitation and elevation at individual collection sites, with a lapse rate of ?0.22‰/100 m. Copyright © 2016 John Wiley & Sons, Ltd.     

Boron isotopic fractionation in laboratory inorganic carbonate precipitation: Evidence for the incorpora-tion of B(OH)_3 into carbonate

A laboratory inorganic carbonate precipitation experiment at high pH of 8.96 to 9.34 was conducted, and the boron isotopic fractionations of the precipitated carbonate were measured. The data show that boron isotopic fractionation factors (αcarb-3) between carbonate and B(OH)3 in seawater range 0.937 and 0.965, with an average value of 0.953. Our results together with those reported by Sanyal and collabo-rators show that the αcarb-3 values between carbonate and B(OH)3 in solution are not constant but are negatively correlated with the pH of seawater. The measured boron isotopic compositions of carbonate precipitation (δ11Bcarb) do not exactly lie on the best-fit theoretical δ 11B4-pH curves and neither do they exactly parallel any theoretical δ 11B4-pH curves. Therefore, it is reasonable to argue that a changeable proportion of B(OH)3 with pH of seawater should also be incorporated into carbonate except for the dominant incorporation of B(OH)4- in carbonate . Hence, in the reconstruction of the paleo-pH of sea-water from boron isotopes in marine biogenic carbonates, the use of theoretical boron isotopic frac-tionation factor (α4-3) between B(OH)4- and B(OH)3 is not suitable. Instead, an empirical equation should be established.     

Determination of runoff components using path analysis and isotopic measurements in a glacier‐covered alpine catchment (upper Hailuogou Valley) in southwest China

Monitoring of stable water isotopes (δ¹⁸O and δ²H) at the watershed scales can improve our understanding of complex hydrology and hydroclimatology of the watershed, especially in remote regions. Previous studies that used tracers for hydrograph separation are largely based on end‐member mixing approach (EMMA), but one drawback of this approach is that at least two independent tracers are required for multi‐component separation. Here we introduce a new approach—path analysis, in combination with isotopic measurements to investigate the runoff generation in a glacier‐covered alpine catchment (upper Hailuogou Valley) in southwest China. This newly developed method can not only provide a multi‐component hydrograph separation with the aid of only one tracer but also determine the direct and indirect influence of sources on streamflow. Path analysis show that the majority of streamflow is dominated by ice/snow meltwater that represents about 63–78% of the total discharge, whereas precipitation and groundwater contribute approximately 19–39% and 2–4% of the streamflow discharge, respectively. These results are in good agreement with those derived from EMMA (using ¹⁸O and Cl^? as tracers), corroborating that our proposed approach is successful in hydrograph separation of the catchment. This approach may provide new opportunities for the hydrograph separation of catchment with sparse data and be of interest to catchment hydrologists who seek to understand the behaviour of hydrologic systems. Copyright © 2015 John Wiley & Sons, Ltd.     

Exploring effects of rainfall intensity and duration on soil erosion at the catchment scale using openLISEM: Prado catchment,SE Spain

In semi‐arid areas, high‐intensity rainfall events are often held responsible for the main part of soil erosion. Long‐term landscape evolution models usually use average annual rainfall as input, making the evaluation of single events impossible. Event‐based soil erosion models are better suited for this purpose but cannot be used to simulate longer timescales and are usually applied to plots or small catchments. In this study, the openLISEM event‐based erosion model was applied to the medium‐sized (～50 km²) Prado catchment in SE Spain. Our aim was to (i) test the model's performance for medium‐sized catchments, (ii) test the ability to simulate four selected typical Mediterranean rainfall events of different magnitude and (iii) explore the relative contribution of these different storms to soil erosion using scenarios of future climate variability. Results show that because of large differences in the hydrologic response between storms of different magnitudes, each event needed to be calibrated separately. The relation between rainfall event characteristics and the calibration factors might help in determining optimal calibration values if event characteristics are known. Calibration of the model features some drawbacks for large catchments due to spatial variability in K_sat values. Scenario calculations show that although ～50% of soil erosion occurs as a result of high frequency, low‐intensity rainfall events, large‐magnitude, low‐frequency events potentially contribute significantly to total soil erosion. The results illustrate the need to incorporate temporal variability in rainfall magnitude–frequency distributions in landscape evolution models. Copyright © 2011 John Wiley & Sons, Ltd.     

Effect of bedrock flow on catchment rainfall‐runoff characteristics and the water balance in forested catchments in Tanzawa Mountains,Japan

In this paper, we examined the role of bedrock groundwater discharge and recharge on the water balance and runoff characteristics in forested headwater catchments. Using rigorous observations of catchment precipitation, discharge and streamwater chemistry, we quantified net bedrock flow rates and contributions to streamwater runoff and the water balance in three forested catchments (second‐order to third‐order catchments) underlain by uniform bedrock in Japan. We found that annual rainfall in 2010 was 3130 mm. In the same period, annual discharge in the three catchments varied from 1800 to 3900 mm/year. Annual net bedrock flow rates estimated by the chloride mass balance method at each catchment ranged from ?1600 to 700 mm/year. The net bedrock flow rates were substantially different in the second‐order and third‐order catchments. During baseflow, discharge from the three catchments was significantly different; conversely, peak flows during large storm events and direct runoff ratios were not significantly different. These results suggest that differences in baseflow discharge rates, which are affected by bedrock flow and intercatchment groundwater transfer, result in the differences in water balance among the catchments. This study also suggests that in these second‐order to third‐order catchments, the drainage area during baseflow varies because of differences between the bedrock drainage area and surface drainage area, but that the effective drainage area during storm flow approaches the surface drainage area. Copyright © 2012 John Wiley & Sons, Ltd.     

Modeling the runoff and glacier mass balance in a small watershed on the Central Tibetan Plateau,China, from 1955 to 2008

The glaciers on Tibetan Plateau play an important role in the catchment hydrology of this region. However, our knowledge with respect to water circulation in this remote area is scarce. In this study, the HBV light model, which adopts the degree‐day model for glacial melting, was employed to simulate the total runoff, the glacier runoff and glacier mass balance (GMB) of the Dongkemadi River Basin (DRB) at the headwater of the Yangtze River on the Tibetan Plateau, China. Firstly, the daily temperature and precipitation of the DRB from 1955 to 2008 were obtained by statistical methods, based on daily meteorological data observed in the DRB (2005–2008) and recorded by four national meteorological stations near the DRB (1955–2008). Secondly, we used 4‐year daily air temperature, precipitation, runoff depth and monthly evaporation, which were observed in the DRB, as input to obtain a set of proper parameters. Then, the annual runoff, the glacier runoff and GMB (1955–2008) were calculated using the HBV model driven by interpolated meteorological data. The calculated GMB fits well with the observed results. At last, using the temperature and precipitation predicted by climate models, we predicted the changes of runoff depth and GMB of the DRB in the next 40 years. Under all climate‐change scenarios, annual glacier runoff shows a significant increase due to intensified ice melting. Copyright © 2011 John Wiley & Sons, Ltd.     

The sensitivity of runoff generation to spatial snowpack uniformity in an alpine watershed: Green Lakes Valley,Niwot Ridge Long-Term Ecological Research station

Seasonal water storage in high-elevation alpine catchments are critical sources of water for mountainous regions like the western U.S. The spatial distribution of snow in these topographically complex catchments is primarily governed by orography, solar radiation, and wind redistribution. While the effect of solar shading is relatively consistent from year-to-year, the redistribution of snow due to wind is more variable – capable of producing snowpacks that have varying degrees of uniformity across these hydrologically-important catchments. A reasonable hypothesis is that a warmer climate will cause snowfall to become more dense (i.e. wetter and heavier), possibly leading to less wind redistribution and thus produce a more uniformly distributed snowpack across the landscape. In this study, we investigate the role of increasingly uniform spatial snowpack distributions on streamflow generation in the Green Lakes Valley Niwot Ridge Long Term Ecological Research station, within the headwaters of the Boulder Creek watershed in Colorado. A set of idealized hydrologic simulation experiments driven by reconstructed snowpacks spanning 2001–2014 show that more a more uniform spatial snowpack distribution leads to an earlier melt-out of 31 days on average and tends to produce less total streamflow, with maximum decreases as large as 7.5%. Isolating the role of snowpack heterogeneity from melt-season precipitation, we find that snowpack uniformity reduces total streamflow by as much as 13.2%. Reductions in streamflow are largely explained by greater exposure to solar radiation in the uniformly distributed case relative to a more heterogeneous snowpack, with this exposure driving shifts towards earlier snowmelt and changes in soil water storage. Overall, we find that the runoff efficiency from shallower snowpacks is more sensitive to the effects of uniformity than deeper snowpacks, which has potential implications for a warming climate where shallower snowpacks and enhanced sensitivities may be present.