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1.
利用高密度电阻率法监测地下介质污染问题的数值模拟   总被引:4,自引:0,他引:4  
对地下介质不同污染模式的电性分布特征,给出了不同的地电模型。针对不同的地电模型,利用2.5维有限元正演模拟的方法计算出了不同监测装置形式下的异常分布特征,并给出了针对不同污染模式的最优监测装置形式和异常分析方法。同时模拟分析了对于不同污染程度监测的可行性。  相似文献   

2.
Application of a groundwater contamination index in Finland and Slovakia   总被引:11,自引:3,他引:11  
A methodology is presented for evaluating and mapping the degree of groundwater contamination by applying the contamination index C d . The applicability of the contamination index was tested in two distinctly different geological regions: the area between Uusikaupunki and Yläne in southwestern Finland and the Brezno area in central Slovakia. The index takes into account both the number of parameters that exceed the upper permissible concentrations of contaminants or potentially harmful elements and the part of the concentrations exceeding those values. The water-quality parameters reflect the effect of diverse natural (topographical, climatical, geological, biological) and anthropogenic (type of land use, local pollution) environmental factors on groundwater quality. In Finland, technical-aesthetic contamination was found over more than half the test area. These quality problems were most often related to acidity and high concentrations of organic carbon and Al and Fe in wells. Health-risk-based contamination, mainly caused by elevated concentrations of fluoride, radon, or nitrate, was found in only a few separate areas. In Slovakia, naturally contaminated and anthropogenically polluted groundwaters could be distinguished. The geogenic pollution is mainly derived from sulfide mineralizations. In both countries the strongest anthropogenic pollution was found in intensively cultivated areas.  相似文献   

3.
Industrial development, intensive agriculture and fast urbanization have caused the metal contents of soils to increase to many times the allowable limits. To assess this impact on urban and rural soils, we quantified the Cd, Cr, Cu, Pb, Ni and Zn contents of 258 soil samples from the Recife metropolitan region (RMR). The objectives of the study were to estimate the probability of ecological risk, to determine the spatial pattern of the metals’ accumulation in the soil and to identify potential sources for the metals using a multivariate geostatistical approach. Mean concentrations of Zn, Cr, Pb, Cu, Ni and Cd in soils were 65.2, 17.9, 16.5, 12.8, 6.3 and 1.5 mg kg?1, respectively. The results demonstrated that the Cd was anthropogenic in origin, the Cr and Ni were lithogenic (natural) in origin and the Cu, Pb and Zn were mixed in origin. Cd contaminated 91% of the samples; the median content of Cd (1.4 mg kg?1) was three times the quality reference value for soil. The Cd contents of sugarcane fields exceeded the allowable limit (3.0 mg kg?1) for agricultural areas. The spatial variability of the metals in the RMR showed that metallurgy, cement production, vehicle exhaust and vehicular traffic were the main sources of metals in urban areas, while phosphate-based fertilizers were the main sources in rural areas. More than 80% of the metropolitan region surveyed in the study was at moderate to high ecological risk.  相似文献   

4.
This article compares the efficiency of induced polarization (IP) and resistivity in characterizing a contamination plume due to landfill leakage in a typical tropical environment. The resistivity survey revealed denser electrical current flow that induced lower resistivity values due to the high ionic content. The increased ionic concentration diminished the distance of the ionic charges close to the membrane, causing a decrease in the IP phenomena. In addition, the self-potential (SP) method was used to characterize the preferential flow direction of the area. The SP method proved to be effective at determining the flow direction; it is also fast and economical. In this study, the resistivity results were better correlated with the presence of contamination (lower resistivity) than the IP (lower chargeability) data.  相似文献   

5.
A modified DRASTIC model for groundwater vulnerability assessment (abbreviated as DRARCH model by combining the first letters of its six assessment indices) was proposed. It is essentially the specific application of DRASTIC model rather than a new model. Both natural hydrogeological conditions that prevent groundwater from contamination and important intrinsic hydrogeochemical properties of sediments in vadose zone that are related to the retardation of contaminants were considered as vulnerability indices. The DRARCH model consists of six indices: (1) Depth to the water table, (2) net Recharge, (3) Aquifer thickness, (4) Ratio of cumulative thickness of clay layers to total thickness of vadose zone, (5) Contaminant adsorption coefficient of sediment in vadose zone, and (6) Hydraulic conductivity of aquifer. The rating values and the weights of these vulnerability indices were obtained by contaminant transport simulation and factor analysis method respectively. Furthermore, the DRARCH model was applied to evaluate the groundwater vulnerability to arsenic contamination in Taiyuan basin, northern China, where groundwaters with high arsenic concentration occur in some localities. GIS-based mapping of groundwater vulnerability using this model indicates that the distribution of very high and high-vulnerability areas corresponds well to that of high-arsenic groundwaters. The DRARCH model is therefore reliable and useful for guiding groundwater environment management.  相似文献   

6.
大同盆地地下水砷异常及其成因研究   总被引:14,自引:0,他引:14       下载免费PDF全文
大同盆地是中国典型的原生高砷地下水分布区。笔者对大同盆地高砷地下水的分布特征、水化学演化过程、砷的来源以及控制高砷地下水形成的地球化学过程等近期研究成果进行了总结。盆地周边石炭—二叠纪煤系地层是盆地高砷环境的主要原生物源,含水层系统中铁磁性矿物为砷的主要载体,盆地内富含有机质的湖相沉积物是次生富砷介质。在盆地中心,地下水径流受阻,蒸发成为主要的排泄方式,浓缩作用使得地下水中TDS含量增大。在富含有机质的地层中,有机质在细菌或微生物作用下不断发生分解,使得地下水环境呈还原性。在高pH、低Eh条件下,由于铁锰氧化物或氢氧化物等水合物或粘土矿物对砷的吸附性降低,一部分被吸附的砷从这些矿物表面解吸;同时部分铁锰氧化物可被还原为低价态可溶性铁锰,从而使与其结合的砷也得以释放进入地下水中。在还原条件下,水中的SO24-和有机碳可被还原成H2S和CH4等低价态化合物,尽管生成的硫化物达到一定浓度时可与水中的亚铁离子和砷反应生成FeAsS沉淀,降低了地下水中砷含量,但由于地下水中Fe和硫酸盐含量有限,Fe普遍含量较低,硫酸盐耗尽后,CH4生成细菌就会成为主导力量,砷就会继续在地下水中积聚。此外,由于pH的升高,还可引起其他不同的酸根离子的解吸,如磷酸根、钒酸根、铀酰和钼酸根等也趋向于在溶液中积累,这些被吸附的阴离子以竞争吸附方式,进一步促进砷的解吸。  相似文献   

7.
Singh  Sushant K.  Vedwan  Neeraj 《Natural Hazards》2015,75(2):1883-1908
Natural Hazards - Groundwater arsenic (As) contamination affects millions of people in South Asia. In this paper, we propose a composite vulnerability framework to identify, for mitigation, the...  相似文献   

8.
Using a two-dimensional fluid-flow/compaction code an investigation is given of the influence of dynamically evolving curved faults in impacting the overpressure development of a sedimentary basin. Four synthetic cases are examined: an homogeneous sandy-shale section, and a mixed layered section of sand and shale, with fault conditions investigated being open to fluid flow, and closed to fluid-flow, respectively. Fault throws can be instantaneous either in time (such as a gravity slump) or can be progressive in time (such as a growth fault). A case history from south Louisiana also is examined to illustrate typical response patterns.  相似文献   

9.
The levels of lead, cadmium, copper, nickel and zinc were determined in the roadside topsoil in Osogbo, Nigeria, with the view to determining the effect of traffic density and vehicular contribution to the soil heavy metal burden. The levels of the metals at the high density roads were significantly higher than the corresponding levels at the medium and low traffic density roads. The average levels of Pb, Cd, Cu, Ni, and Zn in all road locations at a distance of 5 m from the roads were 68.74ᆶ.82, 0.60ǂ.31, 21.19ᆟ.34, 8.38DŽ.40, and 42.45ᆥ.68 mg/kg, respectively. Pb, Cd, and Cu were of average levels of 92.07ᆩ.25, 0.76ǂ.35 and 27.69 mg/kg, respectively at a distance of 5 m from the road at high traffic density roads, while the levels of Ni and Zn averaged 9.65DŽ.61 and 56.27ᆟ.58 mg/kg, respectively. There was a rapid decrease in the level of the metals with distance, with the metal levels at a distance of 50 m from the road almost reaching the natural background levels of the metals at the control sites. The levels of the metals were also determined at the four major motor parks and at the seven mechanic workshop settlements. The levels of the metals at the motor parks and mechanic workshops were far above the levels at the control sites. The levels of Pb, Cd, Cu, Ni, and Zn at the motor parks were 519ᇝ.0, 3.6ǂ.8, 37.9ᆠ.5, 17.3dž.6 and 71.9ᆟ.3 mg/kg, respectively, with the levels of Pb, Cd, Cu, Ni, and Zn at the mechanic workshops averaging 729.57뀶.93, 4.59ǃ.01, 116.6ᆮ.8, 30.21Nj.40, and 88.74ᆰ.11 mg/kg, respectively.  相似文献   

10.
We compiled information about the distribution of exotic organisms in the fresh waters of the Hudson River basin. At least 113 nonindigenous species of vertebrates, vascular plants, and large invertebrates have established populations in the basin. Too little was known about the past or present distributions of algae and most small invertebrates to identify exotic species in these groups. Most established exotic species in the Hudson River basin originated from Eurasia or the Mississippi-Great Lakes basins, and were associated with vectors such as unintentional, releases (especially escapes from cultivation), shipping activities (especially, solid ballast or ballast water), canals, or intentional releases. Rates of species invasions of fresh and oligohaline waters in the basin have been high (ca. one new species per year) since about 1840. For many well-studied groups, introduced species constitute 4% to nearly 60% of the species now in the basin. Although the ecological impacts of the invaders in the Hudson River basin have not been well studied, we believe that about 10% of the exotic species, have had major ecological impacts in the basin. Since, the rates, of entry and composition of exotic species in the Hudson basin are similar to those observed., previously for the Laurentian Great Lakes, invasions tended to occur earlier in the Hudson basin, probably reflecting the earlier history of human commerce. While most exotics have had negative impacts on local flora and fauna, some fish species have provided unique angling opportunities and important economic benefits.  相似文献   

11.
To reconstruct trace metal contamination history in the Yangtze River Delta region, annual growth rings of native hardwood species, Kalopanax septemlobus, were studied as the potential archive of the past Pb and Zn pollution events. Wide distribution of K. septemlobus trees in the study area and clear annual tree rings are advantages of this potential geochemical archive. In this research, tree ring increments for 48 years, from 1960 to 2007, were analyzed for Pb and Zn concentrations. Trees were sampled in two sites, Xiaoyingpan, a contaminated area around a mine (Pb, Zn, Ag) in the Yangtze River Delta region, and a reference site 19 km away. The results show that: (1) distinct Pb and Zn concentrations increasing from 1960 to 1974 in the polluted site were coincident with increasing historical open mining activities; (2) from 1974 to 1986, Pb and Zn concentrations dramatically decreased during a conversion from above-ground exploitation to below-ground extraction; and (3) after 1992, the concentration of Zn decreased gradually, but Pb concentrations initially increased with automobile traffic from 1986 to 2004, then decreased when the number of automobiles was controlled from 2004 to 2007. In particular, Pb and Zn concentrations in tree rings had no effect on K. septemlobus growth. Pb and Zn concentrations in tree rings were linearly related with those in soils. Growth rings of K. septemlobus around the Pb, Zn, Ag mine accurately recorded historical changes in Pb and Zn deposition.  相似文献   

12.
为了建立断陷盆地的低煤阶煤层气成藏模式,从二连盆地群的霍林河盆地地质条件与煤层气地质特征入手,探讨该类盆地煤层气富集规律。研究结果显示:霍林河盆地煤层厚度可达80 m,煤层含气量为1.6~5.62 m3/t,瓦斯风化带深度为450~500 m;煤层的分布特征受同沉积构造与沉积环境控制,盆地内部小型凹陷与隆起决定着煤层的发育位置和煤层埋藏深度,基底的整体抬升确定了瓦斯风化带的位置;翁能花向斜与西南部向斜处,煤层厚度和埋藏深度均较大,煤层顶底板岩性为泥岩,其受到后期构造影响小,是煤层气成藏的有利地带。  相似文献   

13.
We report analyses of 14 group IVA iron meteorites, and the ungrouped but possibly related, Elephant Moraine (EET) 83230, for siderophile elements by laser ablation ICP-MS and isotope dilution. EET was also analyzed for oxygen isotopic composition and metallographic structure, and Fuzzy Creek, currently the IVA with the highest Ni concentration, was analyzed for metallographic structure. Highly siderophile elements (HSE) Re, Os and Ir concentrations vary by nearly three orders of magnitude over the entire range of IVA irons, while Ru, Pt and Pd vary by less than factors of five. Chondrite normalized abundances of HSE form nested patterns consistent with progressive crystal-liquid fractionation. Attempts to collectively model the HSE abundances resulting from fractional crystallization achieved best results for 3 wt.% S, compared to 0.5 or 9 wt.% S. Consistent with prior studies, concentrations of HSE and other refractory siderophile elements estimated for the bulk IVA core and its parent body are in generally chondritic proportions. Projected abundances of Pd and Au, relative to more refractory HSE, are slightly elevated and modestly differ from L/LL chondrites, which some have linked with group IVA, based on oxygen isotope similarities.Abundance trends for the moderately volatile and siderophile element Ga cannot be adequately modeled for any S concentration, the cause of which remains enigmatic. Further, concentrations of some moderately volatile and siderophile elements indicate marked, progressive depletions in the IVA system. However, if the IVA core began crystallization with ∼3 wt.% S, depletions of more volatile elements cannot be explained as a result of prior volatilization/condensation processes. The initial IVA core had an approximately chondritic Ni/Co ratio, but a fractionated Fe/Ni ratio of ∼10, indicates an Fe-depleted core. This composition is most easily accounted for by assuming that the surrounding silicate shell was enriched in iron, consistent with an oxidized parent body. The depletions in Ga may reflect decreased siderophilic behavior in a relatively oxidized body, and more favorable partitioning into the silicate portion of the parent body.Phosphate inclusions in EET show Δ17O values within the range measured for silicates in IVA iron meteorites. EET has a typical ataxitic microstructure with precipitates of kamacite within a matrix of plessite. Chemical and isotopic evidence for a genetic relation between EET and group IVA is strong, but the high Ni content and the newly determined, rapid cooling rate of this meteorite show that it should continue to be classified as ungrouped. Previously reported metallographic cooling rates for IVA iron meteorites have been interpreted to indicate an inwardly crystallizing, ∼150 km radius metallic body with little or no silicate mantle. Hence, the IVA group was likely formed as a mass of molten metal separated from a much larger parent body that was broken apart by a large impact. Given the apparent genetic relation with IVA, EET was most likely generated via crystal-liquid fractionation in another, smaller body spawned from the same initial liquid during the impact event that generated the IVA body.  相似文献   

14.
The contribution of nitrogen and phosphorus due to precipitation constitutes the second most important route after superficial runoff. The sampling carried out during a two-year period by means of a precipitation collector allows us to determine the contribution of this route both qualitatively and quantitatively. Nitrogen is mainly supplied in an inorganic form, while phosphorus is principally supplied as orthophosphate. During the period of this study (March 1986–February 1988) it was found that in the Santillana Reservoir Watershed the level of nitrogen supplied by precipitation constitutes an average of 4.87% and the level of phosphorus constitutes 8.01%. The contribution of nitrogen varies in inverse ratio to precipitation and the contribution of phosphorus varies in direct ratio.  相似文献   

15.
The Messinian Vena del Gesso Basin in the Northern Apennines is filled by very thick (up to 35 m) beds of coarse crystalline gypsum (selenite) associated with thinner carbonate and shaly (euxinic) intercalations. The conventional Usiglio model of salt fractionation does not apply to this evaporitic sequence for the following reasons: carbonate which underlies gypsum is not evaporitic but algal in origin; most gypsum did not precipitate from surface brines but at and below a sediment-water interface occupied by algal mats; a significant portion (10–80%) of gypsum beds is composed of redeposited selenite which was removed from the margins and transported toward the centre of the basin by slope-controlled currents and gravity flows (debris flows). We call this process cannibalistic because of its intraformational character (connected with evaporative fall of water level) and volumetric importance. A recurrent vertical pattern of six main facies (euxinic to gypsum fanglo-merates) is interpreted as a bathymetric, regressive cycle controlled by both sedi-mentological and tectonic-eustatic factors. The inferred environmental setting is a residual turbidite trough (Marnoso-arenacea) evolving abruptly toward lagoonal conditions and filled up to sea level by evaporitic and mechanical (mostly fluvial) processes. Repeated inundations of restricted-marine water started the depositional cycle thirteen or fourteen times.  相似文献   

16.
The main target of the present study is an objective and automated regionalization of Rayleigh wave dispersion data for the Mediterranean basin, without a priori seismotectonic constraints, and to determine the corresponding regional shear-velocity structures. The database used is formed by almost 200 Rayleigh wavetrains corresponding to 42 regional events, with surface-wave magnitude greater than 4.5, recorded at the MedNet very-broad-band stations in the Mediterranean area. Path-averaged group velocities for the Rayleigh wave fundamental mode are derived for each available epicentre-station trajectory crossing the Mediterranean basin. After this, a principal component analysis and a clustering process are applied to local group velocities, obtained for 13 different periods from 10 to 70 s, in order to classify the Mediterranean basin into several homogeneous regions. The stochastic inversion of the averaged group velocity dispersion curve obtained for each region provides the respective shear-velocity structures, down to a depth of 150–160 km. The characteristics of these areas and their possible correlation with the main seismotectonic features of the Mediterranean region are discussed. The regional models reveal significant lateral changes in the elastic structure, with the main differences concerning particularly the upper 35–40 km. Within this depth range, low shear velocities, varying from 2.8 to 3.9 km s−1, characterize the Eastern Mediterranean, whereas higher velocities, ranging from 3.0 to 4.2 km s−1, are deduced for the Western Mediterranean. These results suggest a thicker crust in the eastern part, but with a greater thickness of sedimentary layers. However, for depths of between 80 and 110 km, lower shear velocities are obtained in the Western part, while higher shear velocities are derived for the Eastern Mediterranean Sea, in the Aegean Sea, Greece, the south of Italy, Sicily and Tunisia. This velocity pattern suggests an averaged thicker lithosphere under the latter areas, as the top of the asthenosphere is detected at a mean depth of 75 km for the remaining regions. This thicker lithosphere can be related to processes associated with the convergence of the Eurasian and African plates and subduction under the Calabrian and Hellenic Arcs.  相似文献   

17.
There are several suspected sources of lead contamination in the Dominican Republic (DR) to which populations, to a greater or lesser extent, may be exposed. These sources include: a lead battery recycling plant, a gold mine and vehicles using leaded gasoline. In this paper we create and compare indices of spatial vulnerability using different index construction methods including: the weighted average, ordered weighted average, and Data Envelopment Analysis. The vulnerability attributes used to create these indices include: exposure to lead effluents in water from the gold mine as measured by distance from potentially contaminated water, point source lead air emissions from the battery recycling plant estimated by air plume analysis; and mobile source exposure to lead emissions from road transportation measured by potential traffic impacts. The intensities of vulnerability to lead of the towns and cities in the DR, produced by each of the different index construction methods, are compared and evaluated.  相似文献   

18.
19.
The Late Ordovician Solund-Stavfjord ophiolite in western Norway represents a remnant of the Iapetus oceanic lithosphere that developed in a Caledonian marginal basin. The ophiolite contains three structural domains that display distinctively different crustal architecture that reflects the mode and nature of magmatic and tectonic processes operated during the multi-stage seafloor spreading evolution of this marginal basin. Domain I includes, from top to bottom, an extensive extrusive sequence, a transition zone consisting of dike swarms with screens of pillow breccias, a sheeted dike complex, and plutonic rocks composed mainly of isotropic gabbro and microgabbro. Extrusive rocks include pillow lavas, pillow breccias, and massive sheet flows and are locally sheared and mineralized, containing epidosites, sulfide-sulfate deposits, Fe-oxides, and anhydrite veins, reminiscent of hydrothermal alteration zones on the seafloor along modern mid-ocean ridges. A fossil lava lake in the northern part of the ophiolite consists of a >65-m-thick volcanic sequence composed of a number of separate massive lava units interlayered with pillow lavas and pillow breccia horizons. The NE-trending sheeted dike complex contains multiple intrusions of metabasaltic dikes with one- and two-sided chilled margins and displays a network of both dike-parallel normal and dike-perpendicular oblique-slip faults of oceanic origin. The dike-gabbro boundary is mutually intrusive and represents the root zone of the sheeted dike complex. The internal architecture and rock types of Domain I are analogous to those of intermediate-spreading oceanic crust at modern mid-ocean ridge environments. The ophiolitic units in Domain II include mainly sheeted dikes and plutonic rocks with a general NW structural grain and are commonly faulted against each other, although primary intrusive relations between the sheeted dikes and the gabbros are locally well preserved. The exposures of this domain occur only in the northern and southern parts of the ophiolite complex and are separated by the ENE-trending Domain III, in which isotropic to pegmatitic gabbros and dike swarms are plastically deformed along ENE-striking sinistral shear zones. These shear zones, which locally include fault slivers of serpentinite intrusions, are crosscut by N20°E-striking undeformed basaltic dike swarms that contain xenoliths of gabbroic material. The NW-trending sheeted dike complex in the northern part of Domain II curves into an ENE orientation approaching Domain III in the south. The anomalous nature of deformed crust in Domain III is interpreted to have developed within an oceanic fracture zone or transform fault boundary.REE chemistry of representative extrusive and dike rocks from all three domains indicates N- to E-MORB affinities of their magmas with high Th/Ta ratios that are characteristic of subduction zone environments. The magmatic evolution of Domain I encompasses closed-system fractional crystallization of high-Mg basaltic magmas in small ephemeral chambers, which gradually interconnected to form large chambers in which mixing of primary magmas with more evolved and fractionated magma caused resetting of magma compositions through time. The compositional range from high-Mg basalts to ferrobasalts within Domain I is reminiscent of modern propagating rift basalts. We interpret the NE-trending Domain I as a remnant of an intermediate-spread rift system that propagated northeastwards (in present coordinate system) into a pre-existing oceanic crust, which was developed along the NW-trending doomed rift (Domain II) in the marginal basin. The N20°E dikes laterally intruding into the anomalous oceanic crust in Domain III represent the tip of the rift propagator. The inferred propagating rift tectonics of the Solund-Stavfjord ophiolite is similar to the evolutionary history of the modern Lau back-arc basin in the SW Pacific and suggests a complex magmatic evolution of the Caledonian marginal basin via multi-stage seafloor spreading tectonics.  相似文献   

20.
Channel‐scale sedimentary units associated with bedrock‐controlled riffle‐pool morphology are examined in detail along Sandy Creek gorge, an ephemeral stream in arid south‐eastern central Australia. Pool‐fills comprise cut‐and‐fill assemblages of poorly sorted sediments ranging in texture from muds to boulders. Five unit types are defined based on particle size, sedimentary structures, geometry and bounding surface character: (1) coarse‐grained bar platform; (2) fine‐grained bar supraplatform; (3) fine‐grained pool‐fill; (4) fine‐grained bench; and (5) modern pool‐fill. The last coarse‐grained unit currently lining the pools suggests an altered sedimentation style over the post‐settlement period (post‐ad 1860s). Situated at bedrock valley constrictions, pool‐fills are compared with other sedimentary units associated with recirculating currents: eddy bars and slackwater deposits. But only the fine‐grained bench units reflect eddy recirculation; the pool‐fills are principally forced‐bars associated with bedrock‐controlled or ‘forced’ riffle‐pool morphology. A late Holocene palaeoflood history is proposed based on radiocarbon ages from the pool‐fills: multiple phases of cut‐and‐fill activity were preceded by a superflood 3400–1900 years ago that eroded the pool‐fills to bedrock. The resilience of the pool‐fills was illustrated by the passage of a 1‐in‐100‐year flood in 1992, which caused only minor erosion. The presence of pool‐fills may provide a window to past phases of river activity that cannot be extracted from either historical records/observations or palaeoflood slackwater sediment analyses. The formation and sedimentary preservation potential of these landforms reflect a combination of hydraulic and structural influences, but the occurrence of high‐magnitude floods exerts the dominant control.  相似文献   

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