Tidal pump at the shelf edge

Material transport through the shelf edge to the deep ocean determines the fate of particulate matter generated in productive coastal seas. In stratified estuaries, onshore flow in the bottom layer generally keeps particulate matter generated in the upper layer and settled down to the bottom layer within the estuaries. AT the shelf edge of Tokyo Bay under the condition of average onshore flow in the bottom layer, we observed higher vertical sediment flux during ebb than flood tidal currents. The on-shelf and off-shelf differences in turbulent mixing and water depth mainly cause such difference in sediment flux. We propose to call this export process of particulate matter the tidal pump at the shelf edge.     

Hydrocarbon gases in deposits from mud volcanoes in the Sorokin Trough, north-eastern Black Sea

Hydrocarbon gases were determined in sediments from three mud volcanoes in the Sorokin Trough. In comparison to a reference station outside the mud volcano area, the deposits are characterized by an enrichment of high-molecular hydrocarbons (C₂–C₄), an absence of unsaturated homologues, a predominance of iso-butane in comparison with n-butane, and the presence of gas hydrate. The molecular composition of the hydrocarbon gases suggests their deep sources and thermogenic origin. In the pelagic sediments at the reference station, the methane concentration is relatively low (up to 49 ml/l); maximum concentrations are reached in deposits of the Dvurechenskii mud volcano (up to 400 ml/l). It was the first time that gas hydrate was sampled at the Dvurechenskii mud volcano. The gas extracted by dissociation of hydrate samples was dominated by methane (99.5%) with low amounts of ethane and propane (less than 0.5%). The isotopic composition of the methane varies between –62 and –66 PDB in ¹³C, and between –185 and –209 SMOW in D, indicating a mainly biogenic origin with an admixture of thermogenic gas.     

Variation of water system distribution in the Sanriku Coastal Area

We analyzed hydrographic data obtained monthly by the Iwate Prefectural Fisheries Laboratory during 1977–1981. Our attention was focussed on the classification of waters based on the Temperature-Salinity (T-S) scatter diagram analyses, and on the extraction of the mean state of their distribution for each season. The water system was defined as all waters occupying some specific region on the T-S plane, and the mean state for each season was expressed by the distribution of the mode water systems (i.e., the most commonly occuring water system).Because of the coexistence of the Tsugaru Warm Current, the Oyashio and the Kuroshio, and their large seasonal variability, the sea waters had a wide variety of T-S combinations. The detailed T-S scatter diagram analyses allowed us to classify the waters into six water systems. A time-longitude diagram of water systems and the distribution of mode water systems are presented. The latter showed clear seasonal variations of the Tsugaru Warm Current and the Oyashio.Though the water system analysis was successfully able to present the distribution of the various waters in the Sanriku Coastal Area and to clearly extract the mean state of sea conditions, it was found that the classification of water systems on the T-S plane was not complete in all cases for this area.     

High-resolution seismic study of modern fine-grained deposits: Inner shelf off the southeastern coast of Korea

The geometry and internal structures of modern sediments on the inner shelf off the southeastern coast of Korea were investigated by means of analysing high-frequency (3.5 kHz) seismic records. The records reveal a wedge-shaped sediment body, tapering off toward the sea. On the basis of reflection patterns, the sediments can be classified into two units; foreset (prodelta) unit and bottomset unit, consisting of sandy muds and clays, respectively. The lateral transition from foreset to bottomset deposits suggests a prograding delta system of the Nakdong River since the late Holocene.     

Vertical distribution of smaller macrobenthos and larger meiobenthos in the sediment profile in the deep-sea system of Suruga Bay (central Japan)

The vertical distribution of benthic organisms in the sediment profile was studied using horizontally sliced sediments collected at five stations at depths from 115 to 472 m in Suruga Bay, central Japan. Using sieves of 1.0 and 0.5 mm mesh, benthic organisms were divided into two size classes, smaller macrobenthos (>1mm, <1g wet weight) and larger meiobenthos (1.0 mm0.5 mm). The maximum depth of vertical distribution of organisms in the sediment profile was expressed by the 95 % intercept of the cumulative % curve of the number of individuals drawn with respect to depth in the sediment. It has long been supposed that benthic animals are concentrated in the surface centimeters of sediment in the deep-sea system, and the present study clearly substantiated this. Most benthic organisms of both of these two size classes were concentrated in the upper 5 cm of sediment. The vertical distribution was almost always deeper in the case of smaller macrobenthos than for larger meiobenthos. However the difference could not be substantiated statistically since the number of samples was insufficient. The maximum depth indices of polychaetes were found to be significantly larger than those of crustaceans in the case of macrobenthos, while in the case of meiobenthos, the difference was not significant. The maximum depth index of all benthic organisms was positively and significantly correlated with water-depth and the possible cause for this relationship is discussed.     

Vodyanitskii mud volcano,Sorokin trough,Black Sea: Geological characterization and quantification of gas bubble streams

Vodyanitskii mud volcano is located at a depth of about 2070 m in the Sorokin Trough, Black sea. It is a 500-m wide and 20-m high cone surrounded by a depression, which is typical of many mud volcanoes in the Black Sea. 75 kHz sidescan sonar show different generations of mud flows that include mud breccia, authigenic carbonates, and gas hydrates that were sampled by gravity coring. The fluids that flow through or erupt with the mud are enriched in chloride (up to ∼650 mmol L⁻¹ at ∼150-cm sediment depth) suggesting a deep source, which is similar to the fluids of the close-by Dvurechenskii mud volcano. Direct observation with the remotely operated vehicle Quest revealed gas bubbles emanating at two distinct sites at the crest of the mud volcano, which confirms earlier observations of bubble-induced hydroacoustic anomalies in echosounder records. The sediments at the main bubble emission site show a thermal anomaly with temperatures at ∼60 cm sediment depth that were 0.9 °C warmer than the bottom water. Chemical and isotopic analyses of the emanated gas revealed that it consisted primarily of methane (99.8%) and was of microbial origin (δD-CH₄ = −170.8‰ (SMOW), δ¹³C-CH₄ = −61.0‰ (V-PDB), δ¹³C-C₂H₆ = −44.0‰ (V-PDB)). The gas flux was estimated using the video observations of the ROV. Assuming that the flux is constant with time, about 0.9 ± 0.5 × 10⁶ mol of methane is released every year. This value is of the same order-of-magnitude as reported fluxes of dissolved methane released with pore water at other mud volcanoes. This suggests that bubble emanation is a significant pathway transporting methane from the sediments into the water column.     

Gravity anomalies and deep structure of the Ninetyeast Ridge north of the equator,eastern Indian Ocean — a hot spot trace model

The Ninetyeast Ridge north of the equator in the eastern Indian Ocean is actively deforming as evidenced by seismicity and its eastward subduction below the Andaman Trench. Basement of the ridge is elevated nearly 2 km with respect to the Bengal Fan; seismic surveys demonstrate continuity of the ridge beneath sediment for 700 km north of 10° N where the ridge plunges below the Fan sediment. The ridge is characterised by a free-air gravity high of 50 mgal amplitude and 350 km wavelength, and along-strike continuity of 1500 km in a north-south direction, closely fringing (locally, even abutting) the Andaman arc-trench bipolar gravity field. Regression analysis between gravity and bathymetry indicates that the ridge gravity field cannot be explained solely by its elevation. The ridge gravity field becomes gradually subdued northwards where overlying Bengal Fan sediments have a smaller density contrast with the ridge material. Our gravity interpretation, partly constrained by seismic data, infers that the ridge overlies significant crustal mass anomalies consistent with the hot spot model for the ridge. The anomalous mass is less dense by about 0.27 g cm^–3 than the surrounding oceanic upper mantle, and acts as a cushion for isostatic compensation of the ridge at the base of the crust. This cushion is up to 8 km thick and 400–600 km wide. Additional complexities are created by partial subduction of the ridge below the Andaman Trench that locally modifies the arc-trench gravity field.     

Neogene-Quaternary contourite and related deposition on the West Shetland Slope and Faeroe-Shetland Channel revealed by high-resolution seismic studies

The Neogene and Quaternary sediments of the Faeroe-Shetland Channel and West Shetland shelf and slope rest upon a major regional unconformity, the Latest Oligocene Unconformity (LOU), and have been deposited through the interaction of downslope and parallel-to-slope depositional processes. The upper to middle continental slope is dominated by mass-transport deposits (debris flows), which progressively diminish downslope, and were largely generated and deposited during glacial cycles when ice sheets supplied large quantities of terrigeneous sediment to the upper slope and icebergs scoured sea-floor sediments on the outer shelf and uppermost slope. Large-scale sediment failures have also occurred on the upper slope and resulted in deposition of thick, regionally extensive mass-transport deposits on portions of the lower slope and channel floor. In contrast, large fields of migrating sediment waves and drift deposits dominate most of the middle to lower slope below 700 m water depth and represent deposition by strong contour currents of the various water masses moving northeastward and southwestward through the channel. These migrating sediment waves indicate strong northeastward current flow at water depths shallower than 700 m and strong southwestward current flow at water depths from 700 to >1,400 m. These flow directions are consistent with present-day water-mass flow through the Faeroe-Shetland Channel. The Faeroe-Shetland Channel floor is underlain by thin conformable sediments that appear to be predominantly glacial marine and hemipelagic with less common turbidites and debris flows. No evidence is observed in seismic or core data that indicates strong contour-current erosion or redistribution of sediments along the channel floor.     

Organic geochemistry of the Japan Sea sediments-1: Bulk organic matter and hydrocarbon analyses of Core KH-79-3, C-3 from the Oki Ridge for paleoenvironment assessments

Organic geochemical study of bulk organic matter (OM), hopanoid hydrocarbon and normal hydrocarbon (C₂₃C₃₅) was conducted for a 936-cm-long sediment core sample from the Oki Ridge of the Japan Sea (Core KH-79-3, C-3; 37°03.5 N, 134°42.6E, water depth 935 m). Stable carbon isotopic ratios were also measured for both bulk OM and individual hydrocarbons. The following results were obtained: (1) The weight ratios of total organic carbon to total nitrogen range from 6.2 to 9.4 in the core. The ¹³C values of bulk OM range from –25.1–20.7%.. The ¹³C values of OM in the sections of 140190 cm are lower (–25–24) than those in the other sections (–23–21). This result indicates that OM in the core except for the 140190 cm sections is essentially of marine origin. (2) The ¹³C value of diploptene (a hopanoid hydrocarbon) in the last glacial maximum (LGM), is –66.3 (vs. PDB), which indicates it originating in methanotrophic bacteria. This result provides evidence to support for the previous ideas (Oba et al., 1980, 1984; Masuzawa and Kitano, 1984) that the bottom waters in the Japan Sea were anoxic in LGM. (3) Long chain (C₂₃C₃₅) n-alkanes of higher-plant wax origin were found throughout the core. Their concentration is high in 140190 cm in depth, suggesting that eolian dust load was high in LGM. (4) The n-alkane/TOC ratio increases with decreasing ¹³C values of bulk OM. This result indicates that the load of terrestrial (probably eolian dust-derived) OM to the Japan Sea became higher in colder climates. (5) The CPI values of long-chain n-alkanes are different in different ¹³O stages of paleoclimate, probably reflecting variations in species of terrestrial higher plants as a result of climatological adaptations.     

Occurrence of coprostanol, 24-ethylcoprostanol and 5α-stanols in the marine sediments

The present study deals with the elucidation of sterol composition of the marine sediments in Kagoshima Bay. The identification of each sterol was performed by gas-liquid chromatography, Ag⁺ impregnated column chromatography, mass spectrometry, and nuclear magnetic resonance spectrometry. The sediment obtained near the estuary of River Koutsuki contained large portions of 5-stanols such as coprostanol and 24-ethylcoprostanol basides 5-stanols such as cholestanol, 24-methylcholestanol, and 24-ethylcholestanol in the sterol fraction. These 5-stanols in the marine sediment may be derived from the fecal contamination by domestic sewages.     

Methane in the East China Sea water

Methane in the East China Sea water was determined four times at a fixed vertical section along PN line consisting of 11–14 stations, in February 1993, October 1993, June 1994 and August 1994. The mean concentration of methane in the surface water was not significantly higher than that in the open ocean. The methane concentration below the pycnocline increased during the stratified period in summer to autumn and reached to 15 nmoles/l at most in October. The concentration of methane was fairly well correlated with AOU in the layer below the pycnocline in the stratified season. This means that methane in the bottom water has only a single source, which is expected to be anoxic sediments near the coast, and that the oxidation rate of methane in the water is extremely slow in the oxic water. The high methane observed in October completely disappeared in February, indicating that the methane was escaped to the atmosphere or transported to the pelagic ocean by the Kuroshio current. The East China Sea, therefore, is not a large direct and stationary source for the atmospheric methane, but may have some role as a source by supplying it sporadically to the atmosphere in early winter or indirectly from the surface of the pelagic ocean.     

Turbid bottom water layer and bottom sediment in the Seto Inland Sea

Measurement of the vertical distribution of total suspended matter (TSM) was carried out during summer throughout the Seto Inland Sea. TSM concentration near the bottom is influenced significantly by water movement and turbid bottom water is observed in all areas where median grain size (Md) of the bottom sediment is more than 47gf. The high concentration of TSM near the bottom may be due to resuspension of the surface layer of bottom sediments. Comparison of the organic content of the resuspended matter with that of the bottom sediment shows that the resuspended matter contains more organic matter with a lower C : N ratio than the bottom sediment. The C : N ratio of the resuspended matter is similar to that of TSM in the surface layer of the water column. It is thought that TSM in surface waters sinks and settles on the surface of the bottom sediment. This deposited material is then easily resuspended in the water column by tidal currents before becoming permanently incorporated into the bottom sediment.     

On nonlinear sea waves and the induced mean flow

The nonlinear modulation of water wave groups is investigated and the interaction equations with induced flows are obtained. The analysis is performed up to the third order of the wave steepness a by treating it as a small parameter in the singular perturbation technique by means of the Krylov-Bogoliubov-Mitropolski method. The equation which governs the development of the wave envelope is found by a modification of the ordinary nonlinear Schroedinger equation for the case of uniform depth. The equations governing the behavior of the induced mean flow are examined by deriving the second order flow when the form of the modulated wave train is prescribed. The present theory can describe the mean flow caused by the radiation stress. Some applications containing the monochromatic wave instability are given to confirm the theoretical results.An outline of this paper was presented at The Ocean Surface Symposium (Sendai, 1984).     

Gas hydrates from the continental slope,offshore Sakhalin Island,Okhotsk Sea

Ten gas-vent fields were discovered in the Okhotsk Sea on the northeast continental slope offshore from Sakhalin Island in water depths of 620—1040 m. At one vent field, estimated to be more than 250 m across, gas hydrates, containing mainly microbial methane (¹³C = –64.3), were recovered from subbottom depths of 0.3–1.2 m. The sediment, having lenses and bedded layers of gas hydrate, contained 30–40% hydrate per volume of wet sediment. Although gas hydrates were not recovered at other fields, geochemical and thermal measurements suggest that gas hydrates are present.     

Thermolability of dehydrogenases from a psychrophilic marine bacterium

The heat lability of succinic dehydrogenase, malic dehydrogenase and lactate dehydrogenase in cell-free extracts ofVibrio marinus MP-1 grown at 15C was compared for the tris buffer suspended enzymes and the NaCl suspended enzymes. The tris buffer suspended enzymes lost 50 percent activity at low thermal exposure between 5C and 27C. No activity was evident on thermal exposure between 32C and 39C. The enzyme extracts suspended in NaCl at 36 % were more heat stable, losing 50 percent activity after exposure between 16C and 40C. The enzymes lost all activity on thermal exposure between 33C and 42C in the presence of NaCl.     

Intrusive Stratification of the Gulf-Stream Frontal Zone According to the Results of Investigations Performed during Cruise 43 of the R/V Akademik Vernadskii

We analyze the data of investigation of the intrusive structure of the Gulf-Stream frontal zone obtained in making frequent drift sections with the help of an MGI-8102 probing complex, study the regularities of variation of temperature, salinity, and density along separate intrusions, and present a series of results connected with the specific features of initiation and development of intrusions and the types of exchange processes determining their transformations. It is shown that the T-diagrams of all intrusions are well separated into segments with different slopes. Moreover, by comparing the slopes and locations of these segments with each other and with the T-diagrams of the Gulf Stream and slope waters, we can fairly reliably attribute the corresponding segments of intrusions to one of the following four types: initial dynamic folds of the frontal zone, layers of domestic water separating the intrusive segments of foreign water from each other, intrusive segments characterized by the penetration of ambient water, and segments not intrusive initially but getting the required slope as a result of interaction with upper and lower intrusive segments. For segments of the last two types, it is possible to specify the predominant type of exchange.     

Vertical distribution of heavy metals and its seasonal variations in Beppu Bay

From July to November, the thermocline which has strong temperature gradient (0.7C m^–1) is formed in the bottom water of Beppu Bay, and it prevents the downward mixing of surface water. This has caused the bottom water of the basin to become depleted in oxygen, and in November the bottom water below about 60 m depth becomes anoxic. Accordingly manganese and iron are reduced and more soluble under the anoxic condition, those concentrations are high relative to surface water, and the maximums are 1,240g l^–1 and 80g l^–1. Under the anoxic condition, the flux of dissolved manganese from the sediment is about 10g cm^–2 day^–1.     

Deep convection in a lake triggered by wind: Two-dimensional numerical experiments with a nonhydrostatic model

We have investigated the fundamental processes of deep convection in a lake at high latitudes triggered by wind during spring or autumn and the associated deep water formation, executing vertically two-dimensional numerical experiments with a nonhydrostatic model. The water column in which a relatively cold mixed layer overlies a relatively warm layer becomes unstable, when the Ekman convergence on the shore due to along-shore wind deepens the mixed layer below the compensation depth, where water densities in both layers becomes equal to each other because of the thermobaric effect. At the onset of deep convection, the critical Rayleigh number agrees with that predicted by the linear theory. The onset time of deep convection is inversely proportional to the magnitude of wind stress. On the other hand, the onset time is minimal when water temperature in the mixed layer _m is 3.1°C because a change of _m has two effects oppositely acting on the stability of the water column. After the first onset, deep convection occurs intermittently for a few days. The sinking of the mixed layer water occurs in a thermal-like shape, and its amount is 4184% of the time-integrated Ekman transport when _m 3°C while it decreases to less than 10% for _m lower than 1.5°C. The present process can explain 30% of the amount of deep water renewal which is expected from the observation in Lake Baikal.     

Benthic boundary layer processes in coastal environments: An introduction

This special issue ofGeo-Marine Letters Benthic Boundary Layer Processes in Coastal Environments includes 20 papers devoted to results of recent near-shore experiments supported by the Coastal Benthic Boundary Layer (CBBL) program. Experiments were conducted in gas-rich muddy sediments of Eckernförde Bay of the Baltic Sea and on relict sandy sediments of the West Florida Sand Sheet. In this introductory paper we present scientific justification for experiments and summarize preliminary results.     

Control of Phosphate Concentration through Adsorption and Desorption Processes in Groundwater and Seawater Mixing at Sandy Beaches in Tokyo Bay, Japan

Field observation was conducted to monitor phosphate concentrations in groundwater and seawater mixing at two sandy beaches in Futtsu and Miura in Tokyo Bay, Japan. Dissolved phosphate concentrations were measured along transects from fresh groundwater aquifer to seawater adjacent the beaches. The concentrations were often high (up to 46 µM) in fresh groundwater samples (Cl^– < 0.2). Coastal seawater, on the other hand, exhibited low phosphate concentrations (1.5 µM or less). Along the transects, phosphate generally displayed non-conservative behavior during mixing of fresh and saline waters in the aquifer; concentrations as high as 100 µM were found around the upper limit of seawater intrusion (Cl^– = 2). Laboratory experiments were executed to identify the processes that control the phosphate behavior in the mixing processes. The results revealed that adsorption-desorption processes by the aquifer sand particles could significantly control the phosphate concentrations in the groundwater. Furthermore, the adsorption and/or desorption was found to be a function of salinity; the equilibrium concentration of dissolved phosphate in slurry of sand and water was the highest in freshwater and decreased considerably in saline water. The extreme concentration of phosphate may be caused by release from sand particles coinciding with the rapid change in salinity with tide.