The threat to climate change mitigation posed by the abundance of fossil fuels

This article analyses the trends in primary demand for fossil fuels and renewables, comparing regions with large and small domestic fossil fuel reserves. We focus on countries that hold 80% of global fossil fuel reserves and compare them with key countries that have meagre fossil fuel reserves. We show that those countries with large domestic fossil fuel reserves have experienced a large increase in primary energy demand from fossil fuels, but only a moderate or no increase in primary energy from renewables, and in particular from non-hydro renewable energy sources (NHRES), which are assumed to represent the cornerstone of the future transformation of the global energy system. This implies a tremendous threat to climate change mitigation, with only two principal mitigation options for fossil-fuel-rich economies if there is to be compliance with the temperature goals of the Paris Agreement: (1) leave the fossil fuels in the ground; and (2) apply carbon capture and storage (CCS) technologies. Combinations of these two options to exploit their respective possibilities synergistically will require strong initiatives and incentives to transform a certain amount of the domestic fossil fuel reserves (including the associated infrastructure) into stranded assets and to create an extensive CCS infrastructure. Our conclusion is that immediate and disruptive changes to the use of fossil fuels and investments in non-carbon-emitting technologies are required if global warming is to be limited to well below 2°C. Collective actions along value chains in business to divert from fossil fuels may be a feasible strategy.

Key policy insights

• The main obstacle to compliance with any reasonable warming target is the abundance of fossil fuels, which has maintained and increased momentum towards new fossil-fuelled processes.

• So far, there has been no increase in the share of NHRES in total global primary energy demand, with a clear decline in the NHRES share in India and China.

• There is an immediate need for the global community to develop fossil fuel strategies and policies.

• Policies must account for the global trade flow of products that typically occurs from the newly industrialized fossil fuel-rich countries to the developed countries.

     

All adrift: aviation,shipping, and climate change policy

All sectors face decarbonization for a 2 °C temperature increase to be avoided. Nevertheless, meaningful policy measures that address rising CO₂ from international aviation and shipping remain woefully inadequate. Treated with a similar approach within the United Nations Framework Convention on Climate Change (UNFCCC), they are often debated as if facing comparable challenges, and even influence each others’ mitigation policies. Yet their strengths and weaknesses have important distinctions. This article sheds light on these differences so that they can be built upon to improve the quality of debate and ensuing policy development. The article quantifies ‘2 °C’ pathways for these sectors, highlighting the need for mitigation measures to be urgently accelerated. It reviews recent developments, drawing attention to one example where a change in aviation mitigation policy had a direct impact on measures to cut CO₂ from shipping. Finally, the article contrasts opportunities and barriers towards mitigation. The article concludes that there is a portfolio of opportunities for short- to medium-term decarbonization for shipping, but its complexity is its greatest barrier to change. In contrast, the more simply structured aviation sector is pinning too much hope on emissions trading to deliver CO₂ cuts in line with 2 °C. Instead, the solution remains controversial and unpopular – avoiding 2 °C requires demand management.

Policy relevance

The governance arrangements around the CO₂ produced by international aviation and shipping are different from other sectors because their emissions are released in international airspace and waters. Instead, through the Kyoto Protocol, the International Civil Aviation Authority (ICAO) and the International Maritime Organization (IMO) were charged with developing policies towards mitigating their emissions. Slow progress to date, coupled with strong connections with rapidly growing economies, has led to the CO₂ from international transport growing at a higher rate than the average rate from all other sectors. This article considers this rapid growth, and the potential for future CO₂ growth in the context of avoiding a 2 °C temperature rise above pre-industrial levels. It explores similarities and differences between these two sectors, highlighting that a reliance on global market-based measures to deliver required CO₂ cuts will likely leave both at odds with the overarching climate goal.     

Designing policy for deployment of CCS in industry

Attaining deep greenhouse gas (GHG) emission reductions in industry in order to support a stringent climate change control target will be difficult without recourse to CO₂ capture and storage (CCS). Using the insights from a long-term bottom-up energy systems model, and undertaking a sectoral assessment, we investigated the importance of CCS in the industrial sector. Under climate policy aimed at limiting atmospheric concentration of GHGs to 650 ppm CO₂e, costs could increase fivefold when CCS is excluded from the portfolio of mitigation option measures in the industry sector as compared to when CCS is excluded in the power sector. This effect is driven largely by the lack of alternatives for deep emission reductions in industry. Our main policy conclusion is that a broader recognition of CCS in industrial applications in both current policy discussions and research, development, and demonstration funding programmes is justified. In recognition of the heterogeneity of the many types of industrial production processes, the size and location of industrial CO₂ sources, the specific need for CCS-retrofitting, and the exposure of most industrial sectors to international trade, policies aimed at supporting CCS must distinguish between the different challenges faced by the power and industrial sectors.     

Greenhouse gas emission mitigation plan for the State of Israel: strategies,incentives and reporting

In the context of the negotiations under the United Nations Framework Convention on Climate Change and its accompanying Kyoto Protocol, participating nations have recognized the need for formulating Nationally Appropriate Mitigation Actions (NAMAs). These NAMAs allow countries to take into account their national circumstances and to construct measures to mitigate GHG emissions across economic sectors. Israel has declared to the UN that it would strive to reduce its GHG emissions by 20% in the year 2020 relative to a ‘business as usual' scenario. With its growing population and an expanding economy, the national GHG mitigation plan was developed to draw a course for steering the Israeli economy into a low-carbon future while accommodating continued economic growth. The article describes relevant policy measures, designed to aid in the implementation of the plan and compares them with measures being undertaken by different countries. Emphasis is placed on analysing the progress to date, opportunities and barriers to attaining the ultimate GHG emissions reduction goals. The objective of this article is to contribute to the knowledge base of effective approaches for GHG emissions reduction. We emphasize the integrated approach of planning and implementation that could be especially useful for developing countries or countries with economies in transition, as well as for developed countries. Yet, in the article we argue that NAMAs’ success hinges on structured tracking of progress according to emerging global consensus standards such as the GHG Protocol Mitigation Goals Standard.

Policy relevance:

The study is consistent with the NAMA concept, enabling a country to adopt a ‘climate action plan’ that contributes to its sustainable development, while enabled by technology and being fiscally sound.

The analysis shows that although NAMAs have been framed in terms of projects, policies, and goals, current methodologies allow only the calculation of emission reductions that can be attributed to distinct projects. Currently, no international guidance exists for quantifying emissions reduction from policy-based NAMAs, making it difficult to track and validate progress. This gap could be addressed by an assessment framework that we have tested, as part of a World Resources Institute pilot study for an emerging voluntary global standard.     

Slovenia's climate policy efforts: CO2 tax and implementation of EU ETS

Slovenia is required to reduce its greenhouse gas emissions to an average of 8% below the base year 1986 in the period 2008–2012, due to the ratification of the Kyoto Protocol in 2002. It was the first of the transition countries to implement a CO₂ tax in 1997. At the beginning of 2005, Slovenia joined other EU Member States by implementing the Emissions Trading Scheme. In contrast with other new EU Member States, Slovenia will be a net buyer of allowances. Therefore future movements on the emissions market will play an important role in the compliance costs of achieving the Kyoto target. The main purpose of this article is to present the establishment and characteristics of the first national allocation plan (NAP1) and to describe the main elements of the second national allocation plan (NAP2) for Slovenia within the EU Emissions Trading Scheme, the expected movements on the emissions allowances market in Slovenia, the expected compliance cost of achieving the Kyoto target and to present the main characteristics and efficiency of the CO₂ tax in Slovenia.     

Magnitude,distribution and causes of terrestrial carbon sinks and some implications for policy

Abstract

Recent analyses continue to modify our understanding of terrestrial carbon sinks. The sinks are large and variable enough to account for much of the variability in the growth rate of atmospheric CO₂. They are distributed throughout both northern mid-latitudes and the tropics. Identification of the factors influencing an observed sink is extremely difficult; methods for attribution are reviewed. Although various ecological mechanisms (e.g. CO₂ fertilization, nitrogen deposition, climatic variability) have been shown experimentally to have short-term effects on physiological processes controlling the amount of carbon in terrestrial ecosystems, it is unclear which of these mechanisms has been most important in the past 10–100 years and which will be most important in the future. The decades-long supposition that CO₂ fertilization has been a major driver of terrestrial carbon uptake is being challenged. A major portion of the sink in the northern mid-latitudes (although probably not in the tropics) is a result of recovery from past changes in land use and management. To the extent that these direct human actions explain most of the current (and future) sink, attribution and thus accounting become more tractable, but the continued functioning of the sink is limited and largely dependent on deliberate actions (e.g. afforestation, sustainable forest management and preservation).     

Alternative climate policy pathways in the US

Although it is likely that the political–economic coalition required for implementing a federal cap-and-trade programme for GHGs in the US is now sufficiently strong, the structural impediments that have prevented its legislative passage remain impressively durable and can be expected to continue to lay waste to congressional proposals for the foreseeable future. Indeed, given the complex history of environmental policy gridlock in Washington since the early 1980s, any expectations that a cap-and-trade programme could have been realistically achieved through the traditional legislative passage in Congress are fundamentally misplaced. Building on previous research, it is argued that – as with most other forms of environmental policy in the US over the past three decades – a national carbon market is more plausible given alternative policy pathways, which if taken are capable of circumventing the Federal Congress altogether. In particular, the interaction between litigation against the federal government and the ‘rulemaking’ authority possessed by the Executive Branch provides the potential space for the current administration to unilaterally establish a model rule for a national carbon-trading programme.

Policy relevance

This article aims to contribute to American climate policy debates by re-thinking the policy mechanisms most capable of establishing a national carbon market in the US. By taking into account the array of structural factors that have prevented the legislative passage of such a programme in federal Congress, a range of alternative policy ‘pathways’ is considered that have historically allowed progressive environmental policies to endure in Washington (despite increased Congressional gridlock over the past few decades). Two specific alternative strategies and the relationship between them are assessed: the use of litigation to impose legal obligations on federal agencies to regulate effluents, and the use of executive authority to define the nature and scope of environmental regulation. The administration's current potential to unilaterally develop a model-rule for a cap-and-trade programme under the Clean Air Act is emphasized, and the political implications of such a strategy are considered.     

Extending timber rotations: carbon and cost implications

A number of studies have suggested that incentives for carbon sequestration could lead to longer rotation periods for even-aged managed forests. In this article we examine the potential costs and quantity of sequestered carbon from extending rotation ages in softwood forests of the southern and western USA. A model of optimal rotations when carbon is a valued asset was developed to show how optimal rotations adjust when carbon is priced. Data on 324 types and site classes of softwood forests in southern and western states of the USA were used to examine the costs of extending rotations. The results were then aggregated by applying the marginal cost curves to inventory data within each county in these states. The results indicate that in these 12 states, about 15 million tCO₂ could be sequestered for less than $7/tCO₂ (1 tCO₂ = 1,000 kg CO₂), although for substantially higher carbon prices of $55/tCO₂, up to 209 million tCO₂ could be sequestered. Timber prices were found to have an important influence on the marginal costs of carbon sequestration, with site quality being of secondary importance. The results also showed that at $55/tCO₂ potentially 1 million ha of softwood forests could be set aside, mostly in the western states.     

我国甲烷排放情景分析:IPAC模型结果

近期发布的IPCC第六次评估报告再次强调了短寿命期温室气体减排对温升减缓的作用。甲烷是最重要的短寿命期非CO₂温室气体。在各国提出各自新的减排目标之后,针对甲烷减排的行动方案也越来越多。甲烷减排正在成为下一阶段各国和全球合作的重点领域之一。本文在我国碳减排目标下的能源转型基础上,结合其他非能源活动的减排排放源的减排技术选择基础上,利用IPAC模型对未来甲烷的排放情景进行了分析。在模型设定的两个情景分析基础之上,研究发现,到2050年的能源转型可明显减少能源活动的甲烷排放,和2015年相比能源活动的排放可减少67％。和其他行业相比,能源部门的甲烷减排具有更好的协同性。如果考虑进一步减排甲烷,则需要在考虑其他大气污染物减排的基础上,可通过实现天然气的进一步减排来实现。同时其他部门的甲烷减排也具有很大潜力,低甲烷排放情景可以实现到2050年将甲烷排放减少到1 494万吨,和2015年相比全范围排放可减排58％。     

The impact of the Tokyo Metropolitan Emissions Trading Scheme on reducing greenhouse gas emissions: findings from a facility-based study

This paper provides a detailed analysis of the Tokyo Metropolitan Emissions Trading Scheme (Tokyo ETS), Japan’s first emissions trading scheme with mandatory cap initiated by the government of Tokyo. Unlike trading schemes in other countries, the Tokyo ETS covers indirect emissions from the commercial sector. It is well known that a variety of market barriers impede full realization of energy efficiency opportunities, especially in the commercial sector. Experiences with the Tokyo ETS should therefore provide important lessons for the design of climate change mitigation policies, especially when targeting the commercial sector. The emissions from covered entities have been drastically reduced from those at the scheme’s outset, with an average 14% reduction as of the end of the first commitment period of five years (2010–2014) compared with 2009 levels. This paper shows that the Tokyo ETS alone did not cause these reductions; there were other drivers. Among them, the energy savings triggered by the Great East Japan Earthquake in 2011 were crucial. The contribution of credit trading, in contrast, was limited since most of the covered entities reduced emissions by themselves. Through an investigation of official reports, an assessment of the emissions data from the covered entities compared to those of uncovered entities and in-depth interviews with firms covered by the scheme, this paper confirms that the main drivers of emissions reductions by covered entities were separate from the ETS. In fact, the advisory aspect of the scheme seems to be much more important in encouraging energy-saving actions.

Key policy insights

• Most of the observed emission reductions were not caused by the Tokyo ETS alone.

• An advisory instrument was crucial to the effectiveness of the Tokyo ETS.

• The experience of the Tokyo ETS suggests that making full use of the advantages of emissions trading is difficult in the case of the commercial sector.

• Price signals have not provided a stimulus to climate change mitigation actions, which implies that establishing a cap to yield effective carbon prices poses a challenge.

     

Post-Kyoto energy strategy of the Russian Federation,outlooks and prerequisites of the Kyoto mechanisms implementation in the country

Abstract

Energy sector emissions from Russia have declined by about 33% from 1990 levels. We estimate that some 60–70% of the reduction is due to economic decline, and about 8–12% of it is due to reforms in the energy sector; the remainder being due to the wider use of natural gas and structural changes in the economy. Vigorous institutional and technological measures to promote energy efficiency could lead to savings of over 100 million t.c.e. per year by 2010, and keep CO₂ emissions fairly close to current levels over the decade. In our view, international emissions trading should not lead to global emissions growth, but should facilitate the best energy saving and efficiency. Consequently, we propose that the available assigned amount should be divided into two components. That part arising from ‘type 1’ reductions, produced by special projects and measures relating to GHG reduction taken since 1990, should be freely traded; whereas the remaining ‘type 2’ surplus, without a clear link to real emission reduction activity, should only be traded if the revenues are recycled into special projects resulting in emissions reduction equal to or more than the amount of emissions sold.     

Cumulative CO2 emissions: shifting international responsibilities for climate debt

In contrast to many discussions based on annual emissions, this article presents calculations and projections of cumulative contributions to the stock of atmospheric CO₂ by the major players, China, Europe, India, Japan and the USA, for the period 1900–2080. Although relative contributions to the climate problem are changing dramatically, notably due to the rapid industrialization of China, long-term responsibilities for enhanced global warming have not been transparently quantified in the literature. The analysis shows that if current trends continue, by the middle of this century China will overtake the USA as the major cumulative contributor to atmospheric concentrations of CO₂. This has enormous implications for the debate on the ethical responsibilities of the major greenhouse gas emitters. Effective climate policy will require both the recognition of shared responsibility and an unprecedented degree of cooperation.     

Vehicle tax policies and new passenger car CO2 performance in EU member states

This article explores the causes for differences in the average CO₂ emissions intensity of the new passenger car (NPC) fleet in member states (MS) across Europe. Although EU policies mitigating CO₂ emissions from NPCs have been in place since 1999, MS strongly diverge in the absolute amount and relative change in emissions over the last decade. The authors employ a qualitative approach to analyse the factors, in particular national vehicle taxes, contributing to this divergence and the relative contribution of national and European policies in reducing national CO₂ emissions from NPCs. The analysis shows that there has been a significant reduction in CO₂ emissions intensity of NPCs since 2007 across most MS, compared with the six years previous to that date. This would indicate that EU-wide policies, such as the CO₂ vehicles regulation, along with the economic recession in 2008, have influenced national NPC CO₂ emissions. Generally, countries with CO₂-differentiated vehicle taxes are observed as more likely to have achieved greater reductions in CO₂ emissions. However, over the same period there have been many confounding factors, such as economic instability in the EU, that also influence NPC emissions. Using more detailed case study analyses of six countries, the authors find that there is scope for well-designed national vehicle tax policies to drive NPC emissions down further than the EU average. In countries with the highest success rate, such as the Netherlands, the design of the vehicle tax, as part of a well-aligned policy package, has been very important in delivering the biggest reductions in CO₂ emissions from NPCs.

POLICY RELEVANCE

The transport sector continues to be an intractable source of CO₂ emissions. Governments around the world are seeking effective policies to deal with the increase in passenger car CO₂ emissions appropriate to their own circumstances. This article examines the experience of EU MS with CO₂-differentiated vehicle taxes in reducing CO₂ emissions in the context of other national and international contributing factors. It should therefore both be useful to policy makers and contribute to climate policy research in general.     

Commitments through financial options: an alternative for delivering climate change obligations

Governments willing to commit themselves to maintain carbon prices at or above a certain level face the challenge that their commitments need to be credible both for investors in low-carbon technology and for foreign governments. This article argues that governments can make such commitments by issuing long-term put option contracts on the price of CO₂ allowances. This mechanism gives investors the right, but not the obligation, to sell allowances to the government at the strike price. From the investors' point of view, a government is therefore fully committed to a price floor for allowances in the future. This proposed approach alters the incentives that a government faces when considering noncompliance and serves to prevent non-compliance. The proposal fares well when assessed against criteria to determine its suitability in legitimacy, enforcement, proportionality, lack of interference from other contracting States, and transparency. It also allows for fine-tuning through the number and duration of issued options and the strike price. A robust contract structure is proposed to protect against government interference that might threaten the credibility of commitments.     

山西省城市大气CO2本底筛分对比及特征分析

基于典型城市站太原站2018年3月—2019年2月的大气CO₂在线观测资料,利用筛分法(Meteorological filtering method, MET)和黑碳示踪法(Black Carbon tracer, BC)进行本底/非本底的筛分,得到了本底浓度的变化特征。结果表明,太原大气CO₂浓度季均值冬季最高,夏季最低;不同季节呈“单峰型”日变化特征,日振幅均在26.0×10^-6以上;4个季节CO₂浓度与地面风速存在显著负相关关系;CO₂浓度抬升区域主要受当地工业布局的影响,最大抬升幅度在秋季达17.4×10^-6;使用气象筛分法(MET)得到年均本底浓度为(431.4±19.9)×10^-6,人为排放等对其影响为23.5×10^-6,年振幅比同纬度其它本底站大,为34.5×10^-6;黑碳示踪法(BC)得到冬季季均本底浓度为(445.0±22.9)×10^-6,比MET筛...     

The correct form of the Webb,Pearman and Leuning equation for eddy fluxes of trace gases in steady and non-steady state,horizontally homogeneous flows

The original density corrections proposed by Webb et al. [Webb EK, Pearman GI, Leuning R (1980) Quart J Roy Meteorol Soc 106:85–100] for calculating the eddy fluxes of trace gases are shown to be correct for both steady and non-steady state, horizontally homogeneous flows. The revised theory replaces the original assumption of zero vertical flux of dry air with the requirement of no sources or sinks of dry air in the layer below the height of measurement.     

Climatic changes in Eurasia and Africa at the last glacial maximum and mid-Holocene: reconstruction from pollen data using inverse vegetation modelling

In order to improve the reliability of climate reconstruction, especially the climatologies outside the modern observed climate space, an improved inverse vegetation model using a recent version of BIOME4 has been designed to quantitatively reconstruct past climates, based on pollen biome scores from the BIOME6000 project. The method has been validated with surface pollen spectra from Eurasia and Africa, and applied to palaeoclimate reconstruction. At 6 cal ka BP (calendar years), the climate was generally wetter than today in southern Europe and northern Africa, especially in the summer. Winter temperatures were higher (1–5°C) than present in southern Scandinavia, northeastern Europe, and southern Africa, but cooler in southern Eurasia and in tropical Africa, especially in Mediterranean regions. Summer temperatures were generally higher than today in most of Eurasia and Africa, with a significant warming from ∼3 to 5°C over northwestern and southern Europe, southern Africa, and eastern Africa. In contrast, summers were 1–3°C cooler than present in the Mediterranean lowlands and in a band from the eastern Black Sea to Siberia. At 21 cal ka BP, a marked hydrological change can be seen in the tropical zone, where annual precipitation was ∼200–1,000 mm/year lower than today in equatorial East Africa compared to the present. A robust inverse relationship is shown between precipitation change and elevation in Africa. This relationship indicates that precipitation likely had an important role in controlling equilibrium-line altitudes (ELA) changes in the tropics during the LGM period. In Eurasia, hydrological decreases follow a longitudinal gradient from Europe to Siberia. Winter temperatures were ∼10–17°C lower than today in Eurasia with a more significant decrease in northern regions. In Africa, winter temperature was ∼10–15°C lower than present in the south, while it was only reduced by ∼0–3°C in the tropical zone. Comparison of palaeoclimate reconstructions using LGM and modern CO₂ concentrations reveals that the effect of CO₂ on pollen-based LGM reconstructions differs by vegetation type. Reconstructions for pollen sites in steppic vegetation in Europe show warmer winter temperatures under LGM CO₂ concentrations than under modern concentrations, and reconstructions for sites in xerophytic woods/scrub in tropical high altitude regions of Africa are wetter for LGM CO₂ concentrations than for modern concentrations, because our reconstructions account for decreased plant water use efficiency.     

Public policy and financial resource mobilization for wind energy in developing countries: A comparison of approaches and outcomes in China and India

We analyze and contrast how China and India mobilized financial resources to build domestic technological innovation systems in wind energy. To that end, we identify distinct stages of technology diffusion in the two countries in the period 1986–2012, and analyze the interplay between public policies and the development of the technological innovation system across the different stages. We show that the two countries’ distinct development strategies for wind energy – China developed wind energy largely through its state-owned enterprises, while India opened up wind energy investment to the private sector in the early 1990s – influenced system outcomes in terms of technology diffusion, domestic industry structure, competitiveness, and ownership. By unraveling the interplay between public policies, investment risks and returns, and actor characteristics, we explain the differences in system outcomes and identify important policy trade-offs between the two strategies. Our analysis provides novel insights about the process of financial resource mobilization in technological innovation systems, the dynamics of innovation-system growth, and the policy trade-offs that must be reconciled by countries that aim to promote the diffusion of a particular technology.     

The impact of compensatory measures on public support for carbon taxation: an experimental study in Sweden

This study aims at better understanding how, and to what extent, perceptions of a policy instrument’s distributional effects impact on policy support, focusing on the case of CO₂ taxes on petrol in Sweden. Through a large-scale (N?=?5000) randomized survey experiment with a 2?×?3 factorial design, the extent to which perceptions of fairness determine attitudes to a suggested increase of the Swedish CO₂ tax is explored. Furthermore, the study considers whether these effects change with the level of the suggested tax increase, as well as whether negative sentiments can be alleviated by combining it with a compensatory measure in the shape of a simultaneous income tax cut financed by the revenues from the tax increase. The results show that a higher tax increase is both viewed as more unfair and enjoys weaker support. Furthermore, compensatory measures can be a powerful policy design tool to increase perceptions of the policy as fair, but the effect of compensation on policy support is conditioned by the individual’s left–right ideological position. Whereas people self-identifying to the right react favourably to compensatory measures, people self-identifying to the left become less supportive of a tax increase when combined with a simultaneous cut in income taxes.

Key policy insights

• Perceptions of fairness are highly important for explaining public support for climate policy tools, specifically CO₂ taxes.

• Compensatory measures can be a powerful policy design tool to increase perceptions of the policy as less unfair.

• However, the effect of compensatory measures on policy support is conditioned by ideological position, and only successful among people to the ideological right.

• In contexts dominated by right-wing ideals, a combination of a tax and a compensatory scheme may be a successful route forward towards increased climate policy support.

• In left-oriented contexts the results imply that a CO₂ tax without compensation seems more likely to increase support.

     

The equilibrium constant of NO2 with N2O4 and the temperature dependence of the visible spectrum of NO2: A critical review and the implications for measurements of NO2 in the polar stratosphere

Measurements of stratospheric NO₂ by ground-based visible spectrometers rely on laboratory measurements of absorption cross-sections. We review low-temperature laboratory measurements, which disagree by amounts claimed to be significant. Our recalculation of their errors shows that in general disagreements are not significant and that errors in the ratios of cross-sections at low to room temperature are between ±3% and ±8.8%. Of these errors, up to ±3.5% was contributed by errors in the equilibrium constant,K _p, in those measurements where the pressure was above 0.1 mbar.We review measurements and calculations ofK _p, which were accurate to ±5% from 300 to 233 K. Each method was potentially flawed. For example, infrared measurements of the partial pressure of NO₂ ignored the dependence of absorption on total pressure. From thermodynamic theory, formulae forK _pcan be derived from expressions for the variation of heat capacity with temperature. Contrary to common belief, coefficients in the formulae used by spectroscopists were not derived from the thermodynamic quantities. Rather, they were fitted to measurements or to calculations. Hence, they are empirical and it is dangerous to extrapolate below 233 K, the lowest temperature of the measurements.There are no measurements of NO₂ cross-sections below 230 K. Extrapolation of these cross-sections to analysis of measurements of NO₂ at the low temperatures of the Arctic and Antarctic stratosphere is also dangerous. For satisfactory analysis of polar spectra, the NO₂ cross-sections should be measured at temperatures down to 190 K with a relative accuracy of ±1%. This difficult experiment would need a cell of minimum length 32 m whose length can be adjusted. Because their effects are circular, many errors cannot be removed simply. Although circular errors also arise in the measurements ofK _pand of the infrared spectrum, their weights differ from those in the visible spectrum. The optimum experiment might therefore simultaneously measure the visible and infrared spectra andK _p.