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金含量较高,采用高铈盐容量法。铁、铜、银采有原子吸收,硅采用等离子光谱,铋和砷采用氩化物原子荧光法测定。 相似文献
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形变、畸变、应变和变形等词汇是连续介质力学中描述物体变形的、最基本的术语,它们包含着不同的概念,我国力学家们对这些力学中最基本的概念都有着明确的含义。物体在外力的作用下要发生两种运动,一种运动是物体在空间位置的变化,我们叫刚性运动,另一种运动是物体自身形状和大小的变化,称力变形。 相似文献
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吨(ton),重量单位,与公吨(tonne)同,其通用符号为t。1公吨=1t=1000kg。欧洲大陆及不用英语的各国常用。短吨(short ton),美国常用,其符号为shton,1sh ton=2000磅(pound)=907.18486kg。磅为英制重量单位,其符号为1b,1b=0.45359237kg。长吨(1ong ton),英国常用,1长吨=2240 1b=1016.047kg。 相似文献
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本法是在样品中加入适量的缓冲剂,使难发挥元素Be形成易挥发的氟化物,与B、Pb、Mo、Sn、Cu、Ag、Zn等元素在同一时间内蒸发,利用深电孔极的分馏效应,有效地降低光谱背景以及被测元素的检出限。加入内标元素,提高了方法的准确度和精密度。采用深孔电极,取样量大,代表性好。一次摄谱,同时检测多个元素,大大提高了工作效率,又减少了测试费用。方法操作简便,适合于大批量样品的测试。检出限ω(B)/10-6分别达到:Be:0.50、B:0.91、Sn:0.50、Ag:0.02等,均满足《覆盖区多目标地球化学调查样品测试及质量监控暂行规定》规定。 相似文献
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介绍了采用以电弧为光源的发射光谱法测定银、硼、铅、钼、锡的应用过程;认为通过对仪器的适当改造,应用现代的研究成果,可以快速提升实验室检测能力。 相似文献
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尹福光 《沉积与特提斯地质》2003,23(4):79-83
康滇地区裂谷作用已得到证实,但形成这种地堑地垒的格局有多种解释,以传统的地质力学分析为主。笔者借以热力学的自由热对流原理来加以论述:攀西巨厚的火山岩体在下覆异常地幔热作用下,发生自由热对流,引起热量散失,使地壳沉降与隆起不均衡,生成地堑地垒的格局。自由对流单元的侧向迁移,使盆地形成非对称性。 相似文献
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Gengxin Zhang Shelly D. Kelly Kenneth M. Kemner 《Geochimica et cosmochimica acta》2009,73(12):3523-250
To assess the dynamics of microbially mediated U-clay redox reactions, we examined the reduction of iron(III)-rich nontronite NAu-2 and uranium(VI) by Shewanella oneidensis MR-1. Bioreduction experiments were conducted with combinations and varied concentrations of MR-1, nontronite, U(VI) and the electron shuttle anthraquinone-2,6-disulfonate (AQDS). Abiotic experiments were conducted to quantify U(VI) sorption to NAu-2, the reduction of U(VI) by chemically-reduced nontronite-Fe(II), and the oxidation of uraninite, U(IV)O2(s), by nontronite-Fe(III). When we incubated S. oneidensis MR-1 at lower concentration (0.5 × 108 cell mL−1) with nontronite (5.0 g L−1) and U(VI) (1.0 mM), little U(VI) reduction occurred compared to nontronite-free incubations, despite the production of abundant Fe(II). The addition of AQDS to U(VI)- and nontronite-containing incubations enhanced both U(VI) and nontronite-Fe(III) reduction. While U(VI) was completely reduced by S. oneidensis MR-1 at higher concentration (1.0 × 108 cell mL−1) in the presence of nontronite, increasing concentrations of nontronite led to progressively slower rates of U(VI) reduction. U(VI) enhanced nontronite-Fe(III) reduction and uraninite was oxidized by nontronite-Fe(III), demonstrating that U served as an effective electron shuttle from S. oneidensis MR-1 to nontronite-Fe(III). The electron-shuttling activity of U can explain the lack or delay of U(VI) reduction observed in the bulk solution. Little U(VI) reduction was observed in incubations that contained chemically-reduced nontronite-Fe(II), suggesting that biologic U(VI) reduction drove U valence cycling in these systems. Under the conditions used in these experiments, we demonstrate that iron-rich smectite may inhibit or delay U(VI) bioreduction. 相似文献
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The major chemical components of bauxite deposits of Belgaum (76° 24′E : 15° 54′N) and Yercaud (78° 14′E : 11° 48′N) areas
have been determined. A chemical continuity between parent rocks (zone I) to bauxites (zone IV) via clay (zone II) and laterites
(zone III) clearly indicates that bauxites have been derived byin situ weathering of the respective parent rocks. 相似文献
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Arsenite adsorption on galena (PbS) and sphalerite (ZnS) 总被引:1,自引:0,他引:1
Benjamin C. Bostick 《Geochimica et cosmochimica acta》2003,67(5):895-907
Arsenite, As(III), sorption on galena (PbS) and sphalerite (ZnS) was investigated as a function of solution composition and characterized using X-ray absorption spectroscopy (XAS). Adsorption conformed to a Langmuir isotherm except at the highest surface loadings, and it was not strongly affected by changes in ionic strength. Arsenite sorbed appreciably only at pH > ∼5 for PbS and pH ∼4.5 for ZnS, behavior distinct from its adsorption on other substrates. Arsenite adsorption on PbS and ZnS resulted in the conversion from As-O to As-S coordination. Arsenite does not adsorb through ligand-exchange of surface hydroxyl or sulfhydryl groups. Rather, it forms a polynuclear arsenic sulfide complex on ZnS and PbS consistent with the As3S3(SH)3 trimer postulated by Helz et al. (1995) for sulfidic solutions. This complex was unstable in the presence of oxidizing agents and synchrotron light—it quickly converted to As(V), which was largely retained by the surface. These data illustrate the complexity of As(III) adsorption to even simple sulfide minerals. 相似文献
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本文用强功率四圆单晶衍射仪精确地修正了独居石和磷钇矿的晶体结构。独居石[Monazite-(Ce),CePO4]属单斜晶系,a=6.7843(17),b=6.9891(12),c=6.4592(10),β=103.626(16)°,Z=4,空间群为P21/n。使用1106个[F≥3σ(F)]的独立衍射点,经多轮最小二乘法修正后,最终获得偏离因子R=0.060。独居石的结构由孤立的[PO4]四面体构成,Ce位于[PO4]四面体包围之中,Ce的配位数为9,独居石的Ce—O平均键长为2.552,P—O平均键长为1.528。磷钇矿(Xenotime,YPO4)属四方晶系,其晶格常数为:a=6.8791(24),c=6.0147(19),Z=4,空间群为I4I/amd(No.141)。使用142个[F≥3σ(F)]的独立衍射点,经多轮最小二乘法修正后,最终获得偏离因子R为0.0483。磷和氧形成四面体配位,其P—O平均键长为1.543;稀土钇与氧原子相连构成八次配位,其Y—O平均键长为2.333。 相似文献
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The Fe(II) adsorption by non-ferric and ferric (hydr)oxides has been analyzed with surface complexation modeling. The CD model has been used to derive the interfacial distribution of charge. The fitted CD coefficients have been linked to the mechanism of adsorption. The Fe(II) adsorption is discussed for TiO2, γ-AlOOH (boehmite), γ-FeOOH (lepidocrocite), α-FeOOH (goethite) and HFO (ferrihydrite) in relation to the surface structure and surface sites. One type of surface complex is formed at TiO2 and γ-AlOOH, i.e. a surface-coordinated Fe2+ ion. At the TiO2 (Degussa) surface, the Fe2+ ion is probably bound as a quattro-dentate surface complex. The CD value of Fe2+ adsorbed to γ-AlOOH points to the formation of a tridentate complex, which might be a double edge surface complex. The adsorption of Fe(II) to ferric (hydr)oxides differs. The charge distribution points to the transfer of electron charge from the adsorbed Fe(II) to the solid and the subsequent hydrolysis of the ligands that coordinate to the adsorbed ion, formerly present as Fe(II). Analysis shows that the hydrolysis corresponds to the hydrolysis of adsorbed Al(III) for γ-FeOOH and α-FeOOH. In both cases, an adsorbed M(III) is found in agreement with structural considerations. For lepidocrocite, the experimental data point to a process with a complete surface oxidation while for goethite and also HFO, data can be explained assuming a combination of Fe(II) adsorption with and without electron transfer. Surface oxidation (electron transfer), leading to adsorbed Fe(III)(OH)2, is favored at high pH (pH > ∼7.5) promoting the deprotonation of two FeIII-OH2 ligands. For goethite, the interaction of Fe(II) with As(III) and vice versa has been modeled too. To explain Fe(II)-As(III) dual-sorbate systems, formation of a ternary type of surface complex is included, which is supposed to be a monodentate As(III) surface complex that interacts with an Fe(II) ion, resulting in a binuclear bidentate As(III) surface complex. 相似文献
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This paper deals with the effects of thermal and collision events which had been experienced by the Jilin(H5) and Qingzhen(EH3) chondrites before they fell to the earth .The HRTEM and opti-cal microscopic investigations show that the Jilin chondrite has undergone more extensive thermal heating and two stages of collision,while the Qingzhen chondrite has experienced weak thermal events after the accretion of its parent body and one stage of moderate collision.The schematic dia-grams of the process of formation and evolution of these two meteorites are given in the present pa-per. 相似文献
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J. Götze M. Plötze Th. Götte R. D. Neuser D. K. Richter 《Mineralogy and Petrology》2002,76(3-4):195-212
Summary ?Sheet silicates of the serpentine–kaolin-group (serpentine, kaolinite, dickite, nacrite, halloysite), the talc–pyrophyllite-group
(talc, pyrophyllite), the smectite-group (montmorillonite), and illite (as a mineral of the mica-group) were investigated
to obtain information concerning their cathodoluminescence behaviour. The study included analyses by cathodoluminescence (CL
microscopy and spectroscopy), electron paramagnetic resonance (EPR), X-Ray diffraction (XRD), scanning electron microscopy
(SEM) and trace element analysis.
In general, all dioctahedral clay minerals exhibit a visible CL. Kaolinite, dickite, nacrite and pyrophyllite have a characteristic
deep blue CL, whereas halloysite emission is in the greenish-blue region. On the contrary, the trioctahedral minerals (serpentine,
talc) and illite do not show visible CL.
The characteristic blue CL is caused by an intense emission band around 400 nm (double peak with two maxima at 375 and 410 nm).
EPR measurements indicate that this blue emission can be related to radiation induced defect centres (RID), which occur as
electron holes trapped on apical oxygens (Si–O centre) or located at the Al–O–Al group (Al substituting Si in the tetrahedron).
Additional CL emission bands were detected at 580 nm in halloysite and kaolinite, and between 700 and 800 nm in kaolinite,
dickite, nacrite and pyrophyllite.
Time-resolved spectral CL measurements show typical luminescence kinetics for the different clay minerals, which enable differentiation
between the various dioctahedral minerals (e.g. kaolinite and dickite), even in thin section.
Received December 3, 2001; revised version accepted February 27, 2002 相似文献