Determination of carbon monoxide pollution of the atmosphere over Moscow with a spectroscopic method

The results of measurements of the total content of carbon monoxide in an atmospheric column over Moscow and the Zvenigorod Scientific Station (ZSS) are given for the period 1993–2005. The simultaneous measurements of the regional background contents of carbon monoxide over a rural area (ZSS) and over Moscow made it possible to isolate an urban portion of the CO content. The total content of CO over the city varies significantly from day to day from values close to the background value to values that are 2.5–3 times greater than the background value. The number of days with such a CO content is 5% of the total number of measurement days. Such a CO content is most often observed during the cold seasons. During the warm seasons, in most of the cases, slight excesses of the CO background value are observed in the urban atmosphere. Variations in the CO content are determined mainly by wind-velocity variations and temperature inversions. In 2002, the high CO concentrations were due to forest and peatbog fires. On some days, over the ZSS, the concentrations of CO were high as never before. Over this period (12 years), the CO content in the surface air layer over the city did not increase.     

Variations in the total column amounts of carbon monoxide and methane in the Antarctic atmosphere

The results of measuring the total contents of carbon monoxide and methane via the method of solar-absorption spectroscopy are presented. The measurements were performed at the Molodezhnaya Station in 1977–1978, at the Mirny Observatory from 1982 to 1992, and at the Novolazarevskaya Station from 2003 to 2006. The character of seasonal variations in the contents of these gases in the Antarctic atmosphere is described and compared to the intra-annual variation of their surface concentrations measured at the Syowa Station (Japan). Synchronous intra-annual variations in the contents of carbon monoxide in the atmospheric column and in its surface concentrations are observed, while the spring maximum content of methane is observed three months after the maximum of its surface concentration. Synchronous seasonal variations in the total content of methane and ozone are observed, which makes it possible to suggest that the Antarctic circumpolar vortex has a significant influence on the characteristics of the vertical distribution of methane during Antarctic spring. Quantitative estimates of the parameters of multiyear variations in the contents of CO and CH₄ are given. The content of methane was increasing (although with different rates) during the entire observation period 1977–2006. The content of CO was observed to increase until 1992 and to decrease during 2003–2006.     

Total content of carbon monoxide in the atmosphere over Russian regions according to satellite data

Carbon monoxide (CO) total columns over European Russia (ER) and western Siberia (WS) have been analyzed using MOPITT (V5, TIR/NIR, L3) IR-radiometer data obtained in 2000–2014. High CO contents are revealed over large urban and industrial agglomerations and over regions of oil-and-gas production. A stable local CO maximum is observed over the Moscow agglomeration. Statistical characteristics of CO total columns observed in the atmosphere over ER and WS in 2000–2014 are presented. An analysis of long-term changes in CO content reveals nonlinear changes in the CO total column over northern Eurasia in 2000–2014. Results of a comparative analysis of annual variations in atmospheric CO contents over ER and WS are given. Based on Fourier analysis, empirical models of annual variations in total CO contents over ER and WS are proposed. Relations between regional CO contents and fire characteristics and between spatial CO distributions and features of large-scale atmospheric dynamics under conditions of weather and climate anomalies in the summers of 2010 in ER and 2012 in WS are analyzed. Data on total CO contents measured with a MOPITT satellite radiometer and a ground-based spectrometer operating at the Zvenigorod Scientific Station of the Obukhov Institute of Atmospheric Physics are compared.     

Analysis of the quasi-biennial variability of carbon monoxide total column

On the basis of satellite observations of column carbon monoxide (CO) and total ozone (TO), an analysis has been performed of the connection of the interannual variability of CO with the quasi-biennial oscillation (QBO) of the equatorial stratospheric wind and the QBO of total ozone. It is found that the CO total colomn over most of the globe in the westerly phase of the QBO is greater than that in the easterly phase. The global distribution of the CO QBO amplitudes exhibits a local maximum over Indonesia, where the peak-to-peak amplitude of the CO QBO signal averages 15% of the local annual mean CO in this region. Analysis shows that the QBOs of CO are well synchronized with the QBO of wind at 50 hPa. At the same time, a joint analysis of the characteristics of the CO QBO and TO QBO demonstrates no direct photochemical coupling between of the quasi-biennial variations of TO and CO.     

Aerosol optical thickness and the total carbon monoxide content over the European Russia territory in the 2010 summer period of mass fires: Interrelation between the variation in pollutants and meteorological parameters

The spatial and temporal variabilities of the aerosol optical thickness (AOT) and the total carbon monoxide content (CO) in the period of development and weakening of mass forest and peatbog fires in the European Russia territory (ERT) in the summer of 2010 are investigated from data of the AOT and CO satellite observations. The intensities of aerosol and CO emissions in the period of mass fires and the ratio of the emission factors of aerosol particles and CO are estimated on the basis of calculations of the smoke and CO masses over the ERT. The interrelation between variations in the levels of the regional pollution by combustion products and the variability of meteorological parameters is investigated. Various aspects of the manifestation of radiation effects of aerosols are discussed. The synchronization of weekly signals of the AOT, CO, and meteorological parameters in the period of mass fires is noted.     

Variations in gaseous pollutants in the air basin of Moscow

Variations in the concentrations of gaseous pollutants in the air basin of Moscow are statistically analyzed. The basic statistical characteristics of variations in the concentrations of carbon monoxide, nitric oxide, nitrogen dioxide, ozone, formaldehyde, and a number of aromatic compounds are calculated. The main properties of intradiurnal, synoptic, seasonal, and interannual variations in the concentrations of gaseous pollutants are described. The power spectral densities of variations in the concentrations of carbon monoxide and nitrogen oxides are analyzed. The contributions made by variations in the concentration of carbon monoxide on different time scales to the total variance are calculated. The effect of the atmospheric air polluted with carbon monoxide and nitrogen oxides on the ecological situation in the city is estimated. The probabilities of an excess over the single maximum allowable concentrations are determined for carbon monoxide and nitrogen oxides. The absorption of shortwave solar radiation by nitrogen dioxide in the atmospheric boundary layer is estimated.     

Effects of the equatorial quasi-biennial oscillation in the total ozone content over Russia

On the basis of ground-based measurements of total ozone content (TOC) over Russia and a number of neighboring states during 1973–2002, the amplitudes and phases of TOC variations caused by the quasi-biennial oscillation (QBO) of wind in the equatorial stratosphere are estimated for different regions and for the whole area. The seasonal dependence of the QBO effect in the TOC is analyzed. It is shown that the magnitude and even the sign of the effect depend on the relation between the equatorial QBO phase and the season. The regional empirical models of seasonally dependent QBO effects are constructed. It is found that the seasonal dependence of regional effects accounts for 4% (in the north of the area) to 20% (in the south) of the interannual variability of the TOC. The relation between the QBO effect and the 11-year cycle of solar activity is analyzed. Significant differences are revealed in the effects under the conditions of maximum and minimum solar activity. The QBO effects obtained from observations at Russian stations, satellite measurements with a TOMS instrument, and spectrometric observations of the TOC at western European stations are compared, and their satisfactory agreement is shown. An analysis of the results suggests that the QBO effects in the TOC over Russia are caused by several interacting factors and apparently reflect their regional properties.     

Methane, carbon monoxide, and carbon dioxide concentrations measured in the atmospheric surface layer over continental Russia in the TROICA experiments

The principal statistical regularities typical of the behaviors of the CH₄, CO, and CO₂ concentrations in the atmospheric surface layer over the continental Russian territory are revealed from the measurements performed in 1997–2004 along the Trans-Siberian Railroad from Moscow to Khabarovsk with a mobile laboratory. The data obtained under the conditions of the atmosphere free of anthropogenic pollutants are analyzed. For near-background conditions, the typical continental methane, carbon monoxide, and carbon dioxide concentrations and characteristic features of their large-scale spatial distributions and daily variations, including those caused by surface inversions, are determined. Variations in the concentrations of these trace gases over industrial regions are analyzed. Our results are compared to the data obtained at background stations of the world network of atmospheric monitoring and to the data of a numerical simulation.     

Analysis of satellite observations of the tropospheric NO<Subscript>2</Subscript> content over the Moscow region

The tropospheric NO₂ content over the Moscow region is analyzed on the basis of data of the satellite Ozone Monitoring Instrument (OMI) in the period 2004–2009. The spatial distributions of NO₂ are presented, and some of their features are interpreted. The characteristics of the seasonal and weekly cycles of NO₂ are described, as are its interannual and long-term variations. The relationship between the variabilities of the NO₂ content and the aerological parameters is investigated on different time scales. The mutual influence of regional pollution and meteorological regimes is discussed. The seasonal and weekly NO₂ cycles over Moscow are compared with those over the largest worldwide agglomerations.     

Time Variations in the Composition of Atmospheric Aerosol in Moscow in Spring 2020

Izvestiya, Atmospheric and Oceanic Physics - The results of an intensive complex experiment carried out from March 25 to May 3, 2020, to study the composition and time variability of urban aerosol...     

Time variability of the total methane content in the atmosphere over the vicinity of St. Petersburg

The results of measuring the methane content in the entire atmospheric thickness over the St. Petersburg region are given for 1991–2007. It is shown that, within this period, the mean annual cycle of the total methane content is characterized by its maximum values in December–January and its minimum values in June–August when the annual-cycle amplitude amounts to ∼3.6%. In this case, the annual variations in the total methane content may differ significantly from the mean annual cycle obtained in some years. A statistically significant linear trend of the total CH₄ content has not been revealed for 1991–2007. The obtained values of the linear-trend index have opposite signs in the winter and summer months (positive for January 0.6 ± 0.2%/year and February 0.4 ± 0.2%/year and negative for July 0.3 ± 0.2%/year and August 0.2 ± 0.1%/year). This fact suggests the tendency for an increase in the amplitude of the annual cycle of the total CH₄ content. The results of a spectral analysis of a series of data on the total CH₄ content show that, for 1991–2007, the following harmonics are pronounced with a confidence of 95%: 12 months (annual harmonic), 32 months (quasi-biennial oscillations), and 55 months (4.5 years), which are also pronounced in the series of meteorological parameters and total ozone content.     

Structure of carbon monoxide time variations in the atmospheric thickness over Central Eurasia (Issyk Kul Monitoring Station)

The results of measurements of the CO content in the atmospheric thickness by the method of solar molecular-absorption spectroscopy are presented. Over 87 months of observations, the annual mean CO content decreased by ～19% at a mean rate of changes equal to ?(0.14 ± 0.02) atm cm per year. Maxima and minima of seasonal variations most often fall on February and September, respectively. The mean overall amplitude of changes in the CO content during the annual cycle is about 50% of the mean value. The Fourier analysis revealed variations in the CO composition with periods from 3 to 84 months. A simple statistical model satisfactorily describes time changes in the CO content in the atmospheric thickness. The results of measurements of the CO content in the atmospheric thickness are compared with the data of CO measurements in samples of surface air at stations of the Global Atmospheric Watch.     

Gaseous admixtures in the atmosphere over Moscow during the 2010 summer

In the summer of 2010, the Moscow megacity during two months was within the zone of action of a blocking anticyclone. The accumulation of pollutants in a closed air mass sharply changed the surface air quality. At the end of July-the first half of August, the extreme situation became even more complicated, because the air from regions of turf and grass fires came into Moscow. According to measurement data of the Moscow IAP RAS station, the maximal hourly mean concentrations of chemically active gases NO, NO₂, CO, O₃, and SO₂ were 175.9, 217.4, 15.8, 134.2, and 15.2 ppb, respectively. For NO₂ and CO, these values are largest over the entire decadal period of observations at the station and many times exceed the MPC level (see table). The concentrations of greenhouse gases CO₂, CH₄, and nonmethane hydrocarbons also sharply increased. Analysis of the variability of gas contents in the surface air and in the atmospheric boundary layer showed a close relation between extreme changes in the atmospheric composition and its vertical stratification.     

Spatiotemporal Variations in the Content of Pollutants in the Moscow Air Basin and Their Emissions

Izvestiya, Atmospheric and Oceanic Physics - The location of Moscow on a plain within higher latitudes when compared to other megacities creates conditions for the chemical transformation of...     

Study of the factors determining anomalous variability of carbon dioxide total column amount over St. Petersburg

Results of spectroscopic measurements of the carbon dioxide total column amount near St. Petersburg during forest fires in the period from August to September 2002 are analyzed. The HYSPLIT model is used to calculate air-mass trajectories and CO distribution on a mesoscale in this period. The HYSPLIT model simulations and measurements of carbon dioxide total column amount yield an estimate of the specific intensity of CO emission in a Pskov forest fire on August 28–September 8, 2002, equal to 0.17–0.26 kg m². This estimate can be used for an estimation of the integral CO emission from fires in northwestern Russian forests and for model simulations of atmospheric CO concentration fields. The estimate of the CO emission from forest fires that is obtained from ground-based measurements can also be made on the basis of satellite measurements if they contain information on CO in the lower tropospheric layers (0 to 2 km).     

Studying internal gravity waves generated by atmospheric fronts over the Moscow region

Internal gravity wave (IGW) data obtained during the passage of atmospheric fronts over the Moscow region in June–July 2015 is analyzed. IGWs were recorded using a group of four microbarographs (developed at the Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences) located at distances of 7 to 54 km between them. Regularities of variations in IGW parameters (spatial coherence, characteristic scales, propagation direction, horizontal propagation velocity, and amplitudes) before, during, and after the passage of an atmospheric front over the observation network, when the observation network finds itself inside the cyclone and outside the front, are studied. The results may be useful in studying the relationships between IGW effects in different physical fields at different atmospheric heights. It is shown that, within periods exceeding 30 min, IGWs are coherent between observation points horizontally spaced at distances of about 60 km (coherence coefficient is 0.6–0.9). It is also shown that there is coherence between wave fluctuations in atmospheric pressure and fluctuations in horizontal wind velocity within the height range 60–200 m. A joint analysis of both atmospheric pressure and horizontal wind fluctuations has revealed the presence of characteristic dominant periods, within which cross coherences between fluctuations in atmospheric pressure and wind velocity have local maxima. These periods are within approximate ranges of 20–29, 37–47, 62–72, and 100–110 min. The corresponding (to these dominant periods) phase propagation velocities of IGWs lie within an interval of 15–25 m/s, and the horizontal wavelengths vary from 52 to 99 km within periods of 35 to 110 min, respectively.     

Variations of the geomagnetic dipole magnitude over the past 400 My

The international bank of the virtual dipole moment data supplemented by the values from more recent publications is used as the basis for an analysis of the behavior of the virtual dipole moment values over the last 400 My. The results obtained revealed a positive linear trend from 4.1 × 10²² to 5.7 × 10²² A m² during the last 400 My. Against the background of the linear increase, fluctuations with a periodicity of about 40 My were observed. In the Phanerozoic time, minimums within the intervals of 340–370, 290–300, 240–270, 190–210, 165-140 (chrons M17-M43), 130-120 (chrons M2-M10), 100–110 (chron 34), 75–85 (chron C33 and the beginning of chron C34), 70-60 (chrons C31-C27), and 40-15 (chrons C18-C5AD) My B.P. are found. The distribution of the virtual dipole moment is strictly related to the distribution of the ancient geomagnetic field and may be taken into consideration when modeling the magnetization of the inversive magnetic layer of the ocean.     

Thermal Inversions and Their Influence on the Composition of the Surface Air Layer over Moscow

Izvestiya, Atmospheric and Oceanic Physics - Thermal stratification of the lower 800-m air layer over Moscow, including distribution functions of inversion heights and duration, has been studied in...     

Variations in the surface ozone concentration in the atmosphere over Ulan-Ude

The results of regular measurements of the surface ozone concentration (SOC) in Ulan-Ude over an observation period of six years (1999–2004) are given. The maximum of daily variations in SOC is observed at local noon. The radiation regime is found to have a significant influence only on the minimum values in the SOC seasonal cycle. It is also found that the principal maxima of total ozone content (TOC) and SOC in the seasonal cycle are, on average, shifted by three months (the TOC maximum is reached at the end of March, and the SOC maximum is reached in June).     

Deep structure of the Moscow Aulacogene in the western part of Moscow

Geological and geomorphological studies of the Moscow Aulacogene in the western part of Moscow suburbs have been conducted. This deep structure has been studied by microseismic sounding. The resulting section presents the faults which frame the Teplostanskii Graben in the south (Ramenskii or Butovskii, expressed on the surface as a ledge in the relief) and in the north (Pavlovo-Posadskii, being traced on the surface as a series of lineaments and the valley of Setun’ River). The position of the surface Archean-Lower Proterozoic crystalline basement within the limits of the graben and within the limits of buried elevated blocks (Krasnogorskii and Tumsk-Shaturskii) frame it in the north and south, respectively. Additionally, another fault has been identified in the central part of the graben: the Solntsevskii fault, which has a north-western course and which separates the deflection of the basement in two blocks that are sunken in a slightly different degree. The low-velocity horizons of the Riphean-Vendian complex which make up the graben at depths of 2 to 4.5 km have been found. Down to depths of 15 km, as a component of the upper crust, the graben is underlain by a high-velocity material which also forms the upper part of the section of the crystalline basement in the neighboring elevated block. A low-velocity block of the lithosphere is located in the larger (northern) part of the graben deeper (down to 40 km) beneath the zones of Pavlovo-Posadskii and Solntsevskii faults; in the southern part there is a high-velocity block. In the fault zones framing the graben in the north and south, the surface layer and soil displays a flow of juvenile hydrogen and helium which exceeds several tenfold the background values. According to the collected data, the Teplostanskii Graben has roots traceable through the entire crust and penetrating into the upper mantle.