Improving strategies with constraints regarding non-Gaussian statistics in a three-dimensional variational assimilation method

We assess validity of a Gaussian error assumption, the basic assumption in data assimilation theory, and propose two kinds of constraints regarding non-Gaussian statistics. In the mixed water region (MWR) off the east coast of Japan exhibiting complicated frontal structures, a probability density function (PDF) of subsurface temperature shows double peaks corresponding to the Kuroshio and Oyashio waters. The complicated frontal structures characterized by the temperature PDF sometimes cause large innovations, bringing about a non-Gaussianity of errors. It is also revealed that assimilated results with a standard three-dimensional variational (3DVAR) scheme have some issues in MWR, arising from the non-Gaussianity of errors. The Oyashio water sometimes becomes unrealistically cold. The double peaks seen in the observed temperature PDF are too smoothed. To improve the assimilated field in MWR, we introduce two kinds of constraints, J _c1 and J _c2, which model the observed temperature PDF. The constraint J _c1 prevents the unrealistically cold Oyashio water, and J _c2 intends to reproduce the double peaks. The assimilated fields are significantly improved by using these constraints. The constraint J _c1 effectively reduces the unrealistically cold Oyashio water. The double peaks in the observed temperature PDF are successfully reproduced by J _c2. In addition, not only subsurface temperature but also whole level temperature and salinity (T–S) fields are improved by adopting J _c1 and J _c2 to a multivariate 3DVAR scheme with vertical coupled T–S empirical orthogonal function modes.     

Seasonal variations of alkenones and U37 in the Chesapeake Bay water column

Alkenone unsaturation indices (U^K₃₇ and U^K′₃₇) have long been used as proxies for surface water temperature in the open ocean. Recent studies have suggested that in other marine environments, variables other than temperature may affect both the production of alkenones and the values of the indices. Here, we present the results of a reconnaissance field study in which alkenones were extracted from particulate matter filtered from the water column in Chesapeake Bay during 2000 and 2001. A multivariate analysis shows a strong positive correlation between U^K₃₇ (and U^K′₃₇) values and temperature, and a significant negative correlation between U^K₃₇ (and U^K′₃₇) values and nitrate concentrations. However, temperature and nitrate concentrations also co-vary significantly. The temperature vs. U^K₃₇ relationships (U^K₃₇=0.018 (T)−0.162, R²=0.84, U^K′₃₇=0.013 (T)−0.04, R²=0.80) have lower slopes than the open-ocean equations of Prahl et al. [1988. Further evaluation of long-chain alkenones as indicators of paleoceanographic conditions. Geochimica et Cosmochimica Acta 52, 2303–2310] and Müller et al. [1998. Calibration of the alkenone paleotemperature index U^K′₃₇ based on core-tops from the eastern South Atlantic and the global ocean (60°N–60°S). Geochimica et Cosmochimica Acta 62, 1757–1772], but are similar to the relationships found in controlled studies with elevated nutrient levels and higher nitrate:phosphate (N:P) ratios. This implies that high nutrient levels in Chesapeake Bay have either lowered the U^K₃₇ vs. temperature slope, or nutrient levels are the main controller of the U^K₃₇ index. In addition, particularly high abundances (>5% of total C₃₇ alkenones) of the tetra-unsaturated ketone, C_37:4, were found when water temperatures reached 25 °C or higher, thus posing further questions about the controls on alkenone production as well as the biochemical roles of alkenones.     

The thermodynamics and kinetics of the hydrogen sulfide system in natural waters

The thermodynamics and kinetics of the H₂S system in natural waters have been critically reviewed. Equations have been derived for the solubility and ionization of H₂S in water and seawater as a function of salinity, temperature and pressure. Pitzer parameters for the interaction of the major cations (Na⁺, Mg²⁺ and Ca²⁺) with HS⁻ have been determined to allow one to calculate values of pK₁^* in various ionic media. The limited data available for the interaction of trace metals for HS⁻ are summarized and future work is suggested.The kinetics of oxidation of H₂S have also been examined as a function of pH, temperature, and salinity. The discrepancies in the available data are largely due to the different [O₂]/[HS−] ratios used in various studies. Over a limited pH range (6–8) the pseudo first order rate constant for the oxidation is shown to be directly proportional to the activity of HS⁻. Further studies are suggested to examine the effect of ionic media and temperature on the rate of oxidation.     

Effects of pre-deformation on the martensitic transformation and magnetocaloric property in Ni-Mn-Co-Sn ribbons

This paper investigates the martensitic transformation and magnetocaloric effect in pre-deformed Ni-Mn-Co-Sn ribbons. The experimental results show that the reverse martensitic transformation temperature T_M increases with the increasing pre-pressure, suggesting that pre-deformation is another effective way to adjust T_M in ferromagnetic shape memory alloys. Large magnetic entropy changes and refrigerant capacities are obtained in these ribbons as well. It also discusses the origin of the enhanced martensitic transformation temperature and magnetocaloric property in pre-deformed Ni-Mn-Co-Sn ribbons.     

Temporal and spatial variability in phytoplankton ammonium and nitrate uptake in the Delaware Estuary

Phytoplankton NH₄⁺ and NO₃⁻ uptake was examined along the longitudinal salinity gradient of the Delaware Estuary over several seasonal cycles using ¹⁵N-tracer techniques. Saturated nitrogen uptake rates increased directly with water temperature and reached a maximum of 380 nmol Nl⁻¹h⁻¹ during summer. This temperature dependence was related primarily to changes in the rate of maximum chlorophyll specific uptake, which varied exponentially between 2 and 70 nmol N [μg Chl h]⁻¹ over a temperature range of 2–28°C. Despite these high uptake rates, balanced growth (C:N7:1) could be maintained over the diel light cycle only by highly efficient nitrogen uptake at low light intensities and dark uptake below the photic zone and at night (dark UPTAKE=25% maximum uptake).Ammonium fulfilled 82% of the annual phytoplankton nitrogen demand in the estuary despite dominance of NO₃⁻ in the ambient dissolved inorganic nitrogen pool. The predominance of NH₄⁺ uptake occurred because of the general suppression of NO₃⁻ assimilation at NH₄⁺ concentrations in excess of 2 μ . This suppression, however, was not as universal as has been reported for other systems, and it is suggested that the extremely high NO₃⁻ concentrations found in the estuary contribute to this pattern. Nitrate was a significant source of nitrogen only during periods of high phytoplankton production in summer, and when NH₄⁺ concentrations were low towards the end of the spring bloom.     

Changes of cooling near mesopause under global warming from observations and model simulations

The results of joint analysis of temperature variations near mesopause from long-term measurements at the Zvenigorod Scientific Station of the Obukhov Institute of Atmospheric Physics RAS in 1960–2015 and variations of surface air temperature characterizing global climate change. Together with variations of temperature at the mesopause T _ms from measurements of the hydroxyl emissions we analyzed the temperature variations near mesopause T _m reduced to the same level of solar activity. The observed strong decrease in temperature near mesopause during last decades, particularly in winter, with its tendency to slow down since the 1980’s is was detected against the background of general increase in the surface air temperature of the Northern Hemisphere T _NHs and the Earth as a whole. It was revealed a sharp drop in winter temperature near mesopause in 1970s. and its synchronicity with the shift in climatic features at the surface associated with changes in formation of El Nino events and their impact on the global climate. The general significant negative correlation of temperature variations near mesopause and T _NHs detected from 56-year observational data was not accompanied by any significant coherence between the most long-period temperature variations from the cross-wavelet analysis. To assess the possible manifestation of this coherence the results of numerical simulations with a global climate model were used. According to model simulations for the 20–21 centuries taking into account anthropogenic forcings for significant coherence between long-term variations T _m and T _NHs the prolonged observations are required for temperature near mesopause–about a century or more.     

A method for correcting the temperature effect on uCPT measurements in seabed sediments

Abstract

The zero load readings of cone resistance (q_c) and sleeve friction (f_s) measured by a piezocone (uCPT) shift with the ambient temperature. A method of correcting the effect of temperature on uCPT measurements in seabed sediments has been proposed for the case where there is no temperature sensor in the uCPT probe. This method is based on the assumption that the “actual” profile of f_s of soft shallow seabed sediments linearly increases with depth, and a rate of increase of α?=?0.2?kPa/m was obtained using measured ground temperatures and f_s values in seabed sediments in Isahaya Bay, Japan. An “actual” f_s profile can then be constructed using the measured f_s value at the shallow surface and the value of α. Using the differences between the measured and the estimated “actual” f_s profiles, the ground temperature profile can be obtained, and then the effect of temperature on the uCPT measurements can be corrected. The proposed method was used for temperature corrections on uCPT measurements in Isahaya Bay, Japan. The values of undrained shear strength (s_u) from the temperature-corrected uCPT measurements agree well with the laboratory measured values of s_u using the undisturbed soil samples.     

Technique and Results of Measurements of Turbulent Helicity in a Stratified Surface Layer

In August 2014, measurements of the turbulent velocity rotor, turbulent temperature gradient, turbulent helicity, and turbulent potential vortex were performed at the Obukhov Institute of Atmospheric Physics testing ground in Tsimlyansk under different stratification conditions. The measurements were carried out using the technique first used in the Tsimlyansk expedition in 2012 [1]. The measuring facility consisted of four three-component acoustic Gill Windmaster anemometers–thermometers placed at the vertices of a rectangular tetrahedron with a base scale of 0.7 m (in contrast to the experiment in 2012, when the base scale was 5 m). The measuring facility was placed on top of a mast with an adjustable height of 3.5, 5, 13.5, and 25 m and was equipped with a rotator. The temperature profile in the 10–600 m layer was continuously recorded by the Kadygrov microwave profiler [2]. The series of density of instantaneous helicity He = u_i'ω'_i = u₁'ω₁' + u₂'ω'₂ + u₃'ω'₃ and average values of the total and its summands were calculated for 12 daytime and 10 daytime 2-hour intervals. The helicity value averaged over 12 day realizations is about 0.2 m/s², and the average cosine is close to 0.08 ± 0.03. At night, the helicity is estimated as 0.07 ± 0.03 m/s², and the cosine is close to 0.025 ± 0.03. For the abovementioned 12 daytime and 10 daytime 2-hour intervals, the covariance and correlation matrices of temperature components, velocity rotor, velocity, and temperature gradient are calculated. The off-diagonal terms of the covariance matrix exceed by absolute values the diagonal terms several times. Similar characteristics of a potential vortex were estimated in the incompressibility approximation. The systematic error due to spatial averaging of the measured quantities is discussed.     

Transverse mixing and surface heat exchange in the Waikato River: A comparison of two models

Abstract

Two mathematical models of different complexity were used to study transverse dispersion and surface heat transfer in the lower Waikato River. A simple analytical streamtube model (HPLUME) gave adequate temperature predictions in a reach where the channel was fairly regular but performed poorly where there were extensive shallows. In the latter reach, a two‐dimensional numerical model (SYSTEM21) gave good temperature and flow predictions once properly calibrated. Model calibration proved to be difficult in the Waikato River because the natural river temperature varied significantly along the channel. A search method was developed to estimate both the transverse dispersion and surface heat exchange coefficients from measured plume temperature profiles based on the observation that transverse variations in natural temperature were small. This method was used to calibrate SYSTEM21 in two separate reaches. Coefficient estimates were sensitive to measurement errors and slight departures in homogeneity of natural temperature and it would be desirable to corroborate the estimates of E_z using dye tests. In the upper reach, the average transverse dispersion coefficient was E_z/hu? = 1 which is high but within the range of published values. A sharp bend and buoyant spreading contributed to the high E_z value. E_z increased with river flow because both h and u? increase with flow. In the lower reach, E_z/hu? = 0.1 which is lower than expected but islands may have affected the model calibration. The surface heat exchange coefficient averaged K = 84–167 W m^?2 s^?1 °C^?1 which falls within the range of published values. No significant relationship could be found between surface heat exchange coefficient and meteorological variables.     

Diurnal and seasonal variation in physico-chemical conditions within intertidal rock pools

A study of the diurnal and seasonal variation in the physico-chemical conditions within intertidal rock pools on the West coast of Scotland was undertaken to provide data on the environmental conditions experienced by animals inhabiting these pools. The temperature, pH, partial pressure of oxygen (P_O2) and salinity were measured every hour for 24 h and the total alkalinity, partial pressure of carbon dioxide (P_CO2) and carbon dioxide content (C_CO2) calculated. This sampling regime was carried out once a month for 12 months to determine the extent of seasonal variation in conditions within temperate pools.Large diurnal variations were recorded in nearly all the physico-chemical parameters measured. The greatest variation was recorded in the temperature and P_O2 of the water but significant changes in pH and P_CO2 were also recorded. Total alkalinity varied little during any 24 h period but carbonate alkalinity, which was always lower than total alkalinity, showed slightly greater variation. There was also considerable variation in the magnitude of these diurnal changes between pools at different heights on the shore.Diurnal variation in the physico-chemical conditions within the pools were observed throughout the year although the magnitude of these changes varied seasonally. Detailed studies on individual pools demonstrated that appreciable local variation existed in the physico-chemical conditions within each pool.     

Winter Mixed Layer and Formation of Dichothermal Water in the Bering Sea

The temperature minimum layer, called “dichothermal water”, is a characteristic feature of the North Pacific subarctic gyre. In particular, dichothermal water having a density of approximately 26.6 sigma-theta (σ_θ), which corresponds to the densest water outcropping in winter in the North Pacific, is seen in the Bering Sea. In order to clarify the water properties, and the area in which and the process by which the dichothermal water is formed, a new seasonal mean gridded climatological dataset with a fine resolution for the Bering Sea and adjacent seas has been prepared using historically accumulated hydrographic data. Although the waters of the Alaskan Stream have temperature minimum layers, their temperature inversions are very weak in climatologies and the core densities of the temperature minimum layers are much lighter than 26.6σ_θ. On the other hand, in the Bering Sea one can see the robust structure of temperature minimum layers, the core density of the dichothermal water being around 26.6σ_θ. In addition, it has been found that the properties of the dichothermal water observed in the warming season are almost the same as those in the winter mixed layer. That is, the dichothermal waters are formed in the winter mixed layer in the Bering Sea. Since these waters are found in the Kamchatka Strait, i.e., the main exit of the Bering Sea waters, it can be supposed that the dichothermal waters are exported from the Bering Sea to the Pacific Ocean by the Kamchatka Current. This revised version was published online in July 2006 with corrections to the Cover Date.     

Estimation of hydrocarbon biodegradation rates in marine environments: A critical review of the Q10 approach

Offshore oil & gas industry is moving exploration and production activities into Arctic and deep water regions. Governmental regulations require environmental impact assessments before operations to evaluate the possible effects of accidental oil releases. These are often performed by numerical fate models, like the Oil Spill Contingency and Response (OSCAR) model, which has become an industry standard in Norway. In this model, biodegradation rates are adjusted to local conditions by temperature compensation according to a Q₁₀ approach. Q₁₀ is the multiplier by which rates of enzymatic reactions increase at a 10 °C temperature rise. Herein, this Q₁₀ approach implemented in the OSCAR model is investigated based on published data and novel obtained results. Overall, biodegradation rate predictions calculated by temperature compensation are found to be questionable, and choosing one universal Q₁₀ value is considered not feasible. The high variation in Q₁₀ values is herein attributed to indirect effects of temperature.     

Effects of rapid changes in temperature on two estuarine crustaceans

Weight specific oxygen consumption (Q_O2) patterns of the amphipod, Gammarus sp. (acclimated to 5°, 15° and 25°C) and of juvenile blue crabs, Callinectes sapidus (15° and 25°C) were used to evaluate the potential effect of exposure to rapid temperature changes simulating once-through power plant pumped entrainment. Amphipods at all acclimation temperatures and blue crabs at 15°C responded to the temperature changes by increasing Q_O2 above pre-exposure levels after the thermal increase and then returning to pre-exposure levels. The response was judged to be a normal physiological compensation response, not a thermal stress response, as suggested by some investigators. Significant differences were found among seasonal Q_O2, patterns in both species; Q_O2, increased with increasing acclimation temperature. However, no seasonal stress effects were found as a result of exposure to the temperature changes. This implies that the effects of ΔT's up to 10°C from power plants of this design should have no significant impact on these organisms.     

白令海BR断面海-气CO2通量及其参数特征

通过对2008年夏季白令海大气和海水pCO2连续观测资料,结合BR断面上站位水体垂直采样测量,对白令海不同海区pCO2的分布特征及其与理化参数的关系进行了初步研究,结果表明,将白令海划分为4个具有不同CO2吸收能力的海区,其中陆坡流区碳通量高达-18.72 mmol/(m2·d),是海盆北区的近2倍,比海盆南区高一个量...     

Characteristics of individual reactions of the cardiovascular system of healthy people to changes in meteorological factors in a wide temperature range

Based on the results of 4-year observations of daily variations in blood pressure (BP) and heart rate (HR) in seven healthy volunteers, two distinct types of reaction of physiological indicators (PIs) to changes in meteorological parameters (first and foremost, atmospheric temperature T _atm) are revealed. The first type is a monotonic (but nonuniform with respect to speed) decrease in systolic BP with increasing temperature, which is most pronounced for T _atm < ?5°C and T _atm > 15°C, with a weaker reaction of diastolic BP and no reaction of HR (in four volunteers). The second type is a two-phase nonmonotonic dependence of BP indicators on T _atm, which coincides with the first type in the range T _atm < ?5°C and is characterized by a positive correlation of BP and HR indicators with T _atm for T _atm > ?5°C (in two volunteers). The physiological mechanisms that can provide the observed compensatory-adaptive reactions of healthy individuals to atmospheric factors in different temperature ranges are analyzed in detail. It has been shown that the revealed regularities can explain the results obtained by the authors in earlier studies.     

Microstructure measurements in natural waters: Methodology and applications

Modern approaches to microstructure data processing, including wavelet denoising, are discussed. The wavelet procedure is applied to small-scale shear signals before estimating the dissipation rate ε and to the temperature/density profiles used to calculate Thorpe scales. Microstructure data obtained on the Mediterranean shelf of Catalonia are used to illustrate various approaches to the Thorpe displacement calculations. It is suggested that the Weibull probability function is an appropriate model for the Thorpe scale distribution. Microstructure measurements from the upper layer of the Boadella reservoir (Catalonia, Spain) support this finding.A new analytical approximation for the 1D Panchev–Kesich spectrum is deduced and the results of ε computation are compared with spectral fitting by the widely used Nasmyth spectrum. Applying the Kraichnan spectral model to compute ε from temperature spectra in the convective-viscous sub-range is examined as an alternative to the Batchelor spectrum. Microstructure measurements taken in Lake Banyoles (Catalonia, Spain) and in the North Atlantic were used for spectral calculations.Statistical analysis of eddy K_b and thermal K_θ diffusivities measured on a shallow shelf of the Black Sea shows the importance of process-orientated domain averaging of the diffusivities in obtaining good correspondence between K_b and K_θ in active turbulent regions. In weakly turbulent, stratified interior layers, the averaged K_b and K_θ differ significantly, which may point to the inapplicability of isotropic formulae used for ε and temperature dissipation χ_θ estimates, as well as to a dependence of the mixing efficiency γ on the Richardson number or in some cases on regions of fossil turbulence.     

Cu3 N弹性和热力学性质的第一性原理研究

利用基于密度泛函理论的第一性原理全势线性缀加平面波方法,研究了立方反ReO₃结构Cu₃N在零温(0 K)零压下的平衡晶格常数、体弹模量及其对压强的一阶导数,计算结果与其他实验及理论结果基本相符. 同时得出Cu₃N的弹性常数,Poisson比等,并分析出Cu₃N在零温零压下是稳定的. 通过准谐Debye模型计算Cu₃N的热力学性质,得到了Cu₃N的晶格常数、等压比热容、等容比热     

Association constant of fluoride and hydrogen ions in seawater

A method is described to obtain the association constant of fluoride and hydrogen ions and its influence on the total and free ion concentration. The following equation was found with an error of ± 0.05 for the salinity and temperature range 10–40 and 9–33°C, respectively In β_HF = -874/T - 0.111S^0.6 + 9.68 where T is the absolute temperature and S the salinity.     

东海中北部海域秋季表层海水中无机碳与海气界面碳的迁移

基于2010 年11 月对长江口外东海中北部海域的综合调查, 系统研究了该海域的无机碳体系参数的分布特征、海?气界面二氧化碳通量及其影响因素。研究结果表明, 该海域秋季溶解无机碳(DIC)高值区主要出现在调查海域东北部及长江口附近海域, 而调查海域南部DIC 含量较少且变化平缓, 其主要是受台湾东部流向东北方向的黑潮支流及长江冲淡水的影响; 表层海水CO₂分压(pCO₂)值变化范围为40.8～63.5 Pa, 呈现沿黑潮支流流入方向由东南向西北逐渐增高的趋势。秋季表层海水pCO₂与温度(T)、盐度(S)有较好的负相关性, 说明海水温度升高和盐度增加, pCO₂降低, 反之亦然。另外, 通过估算得出, 秋季CO₂海-气交换通量为2.69～33.66 mmol/(m²·d), 平均值为(14.35 ± 7.06 )mmol/(m²·d),其在长江口邻近海域相对较大, 而在调查海域南部相对较小; 2010 年秋季水体向大气释放CO₂的量(以碳计)为(2.35 ± 1.16)×104 t/d, 是大气CO₂较强的源, 说明东海中北部海域秋季总体上是CO₂的源。     

Factors influencing the magnitude of phytoplankton primary production in a high-energy surf zone

The main factors influencing phytoplankton primary production in the surf zone of the Sundays River Beach, Algoa Bay have been characterized. These factors include cell concentration, chlorophyll concentration, irradiance, temperature and salinity. Good relationships have been obtained between cell concentration, chlorophyll concentration and primary production. The P-I curves showed dependence on temperature with a linear regression between temperature and I_k values. Light saturation was shown to occur between 300 and 510 μmol m⁻² s⁻¹ at normal field temperatures. T_max and T_min were found to be 34°C and 0°C, respectively; P_max was 25°C. Salinity had a marked effect on primary production with S_max occurring at 60 ppt and an extrapolated S_min at 0 ppt. P_max was found to occur at 30 ppt.