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1.
During the early part of a seismic swarm preceding eruption and caldera formation at Miyakejima Volcano, discoloured sea surfaces were observed 1.5 km off the western coast of Miyakejima on 27 June 2000. A later survey of the area using a multi-beam side scan sonar and a remotely operated small submarine revealed four craters of 20–30 m diameter aligned east-west in a 100×10–30 m area on the seafloor, with hot water at 140°C being released from one of the centres. Each crater consists of submarine spatter overlain in part by scoria lapilli. Dredged spatter from the craters was fresh, and there was no evidence of activity of marine organisms on the spatter surface, indicating that the discoloured sea surface resulted from magmatic eruption on the seafloor. This eruption occurred when a westward-propagating seismic swarm, initiated beneath Miyakejimas summit, passed through the area. Finding new magma on the seafloor demonstrates that this seismic swarm was associated with intruding magma, moving outward from beneath Miyakejima. Submarine spatter shows flattened shapes with a brittle crust formed by cooling in water, and its composition is aphyric andesite of 54 wt% SiO2. The spatter is similar in whole rock and mineral composition to spatter erupted in 1983. However, the wide range of Cl in melt inclusions in plagioclase of the 27 June submarine spatter shows that it is not simply a remnant of the 1983 magma, which has only high Cl melt inclusions in plagioclase. The mixed character of melt inclusions suggests involvement of a magma with low Cl melt inclusions. The magma erupted explosively on 18 August from Miyakejimas summit, considered as the second juvenile magma in this eruption, contains low Cl melt inclusions in plagioclase. Based on these observations and the eruption sequence, we present the following model: (1) A shallow magma chamber was filled with a remnant of 1983 magma that had evolved to a composition of 54–55 wt% SiO2. (2) Injection of the 18 August magma into this chamber generated a mixed magma having a wide range of Cl in melt inclusions contained plagioclase. The magma mixing might have occurred shortly before the submarine eruption and could have been a trigger for the initiation of the removal of magma from the chamber as an extensive dyke, which eventually led to caldera subsidence.Editorial responsibility: S Nakada, T Druitt  相似文献   

2.
Lateral migration of magma away from Miyakejima volcanic island, Japan, generated summit subsidence, associated with summit explosions in the summer of 2000. An earthquake swarm beneath Miyakejima began on the evening of 26 June 2000, followed by a submarine eruption the next morning. Strong seismic activity continued under the sea from beneath the coast of Miyakejima to a few tens of kilometers northwest of the island. Summit eruptive event began with subsidence of the summit on 8 July and both explosions and subsidence continued intermittently through July and August. The most intense eruptive event occurred on 18 August and was vulcanian to subplinian in type. Ash lofted into the stratosphere fell over the entire island, and abundant volcanic bombs were erupted at this time. Another large explosion took place on 29 August. This generated a low-temperature pyroclastic surge, which covered a residential area on the northern coast of the island. The total volume of tephra erupted was 9.3×106 m3 (DRE), much smaller than the volume of the resulting caldera (6×108 m3). Migration of magma away from Miyakejima was associated with crustal extension northwest of Miyakejima and coincident shrinkage of Miyakejima Island itself during July–August 2000. This magma migration probably caused stoping of roof rock into the magma reservoir, generating subsurface cavities filled with hydrothermal fluid and/or magmatic foam and formation of a caldera (Oyama Caldera) at the summit. Interaction of hydrothermal fluid with ascending magma drove a series of phreatic to phreatomagmatic eruptions. It is likely that new magma was supplied to the reservoir from the bottom during waning stage of magmas migration, resulting in explosive discharge on 18 August. The 18 August event and phreatic explosions on 29 August produced a conduit system that allowed abundant SO2 emission (as high as 460 kg s–1) after the major eruptive events were over. At the time of writing, inhabitants of the island (about 3,000) have been evacuated from Miyakejima for more than 3 years.  相似文献   

3.
The 2000 AD eruption of Miyakejima was characterized by a series of phreatomagmatic eruptions from the subsiding caldera. Six major eruptive events occurred, and they can be divided into the first and second periods separated by a 25-day hiatus. The phreatomagmatic eruptions produced a total of ~ 2 × 1010 kg of tephra, which mainly comprised fine-grained volcanic ash. The tephra layers could be divided into six fall units corresponding to the six major eruptive events.  相似文献   

4.
Magma plumbing system of the 2000 eruption of Miyakejima Volcano, Japan   总被引:1,自引:0,他引:1  
During the 2000 eruption at Miyakejima Volcano, two magmas with different compositions erupted successively from different craters. Magma erupted as spatter from the submarine craters on 27 June is aphyric basaltic andesite (<5 vol% phenocrysts, 51.4–52.2 wt% SiO2), whereas magma issued as volcanic bombs from the summit caldera on 18 August is plagioclase-phyric basalt (20 vol% phenocrysts, 50.8–51.3 wt% SiO2). The submarine spatter contains two types of crystal-clots, A-type and A-type (andesitic type). The phenocryst assemblages (plagioclase, pyroxenes and magnetite) and compositions of clinopyroxene in these clots are nearly the same, but only A-type clots contain Ca-poor plagioclase (An < 70). We consider that the A-type clots could have crystallized from a more differentiated andesitic magma than the A-type clots, because FeO*/MgO is not strongly influenced during shallow andesitic differentiation. The summit bombs contain only B-type (basaltic type) crystal-clots of Ca-rich plagioclase, olivine and clinopyroxene. The A-type and B-type clots have often coexisted in Miyakejima lavas of the period 1469–1983, suggesting that the magma storage system consists of independent batches of andesitic and basaltic magmas. According to the temporal variations of mineral compositions in crystal-clots, the andesitic magma became less evolved, and the basaltic magma more evolved, over the past 500 years. We conclude that gradually differentiating basaltic magma has been repeatedly injected into the shallower andesitic magma over this period, causing the andesitic magma to become less evolved with time. The mineral chemistries in crystal-clots of the submarine spatter and 18 August summit bombs of the 2000 eruption fall on the evolution trends of the A-type and B-type clots respectively, suggesting that the shallow andesitic and deeper basaltic magmas existing since 1469 had successively erupted from different craters. The 2000 summit collapse occurred due to drainage of the andesitic magma from the shallower chamber; as the collapse occurred, it may have caused disruption of crustal cumulates which then contaminated the ascending, deeper basalt. Thus, porphyritic basaltic magma could erupt alone without mixing with the andesitic magma from the summit caldera. The historical magma plumbing system of Miyakejima was probably destroyed during the 2000 eruption, and a new one may now form.Editorial responsibility: S Nakada, T Druitt  相似文献   

5.
The model for the 2000 dike intrusion event between Kozushima and Miyakejima volcano, Japan, was reinvestigated. After the sudden earthquake swarm in Miyakejima volcano, a dike intrusion of large volume was detected by the nationwide GPS network (Geonet). The displacements detected with GPS stations over an area with a radius of about 200 km shows a distribution that is consistent with the dike source being located near Miyakejima volcano.The dike was intruded northwestwards between Miyakejima and the neighboring Kozushima volcano. We searched for the parameters in the models that reproduce the regional displacements due to dike intrusion between Miyakejima and Kozushiima islands. We tested three models, (1) the model with a single dike, (2) the model with a dike and a point dislocation source which represents a creep dislocation source and (3) the model with a dike and a deflation source which represents a magma reservoir. Though all three models can match the horizontal displacements near the source area, model 1 fails to reproduce the regional displacements in the central part of Japan. Both models 2 and 3 can reproduce the regional displacement for horizontal components. Model 3 produces slightly better results than model 2 for vertical components. The balance in the volume budget for models 2 and 3 is also consistent with the observations. These results show that we cannot distinguish between the two models using only GPS observation. As there is no direct evidence for such a large creep or ductile source (corresponds to M7 or more) as proposed in model 2 and the active seismic region migrated back and forth within the linear swarm region, the model with a dike and a deep magma source is preferable. For the deflation point source, we obtained a deflation volume of 1.5 km3 at the depth of 20 km below the dike. An additional ~0.95 km3 of volume loss through caldera collapse and edifice deflation took place at Miyakejima. We conclude that the magma that intruded the dike came in part from below Miyakejima and in part from below the sea floor between Miyakejima and Kozushima, perhaps from reservoirs at the Moho.Editorial responsibility: S Nakada, T Druitt  相似文献   

6.
Akira  Imai  Nobuo  Geshi  Taketo  Shimano  Setsuya  Nakada 《Island Arc》2007,16(1):83-92
Abstract   The variation of sulphur isotopic composition during the 2000 eruption of the Miyakejima Volcano was examined in order to monitor the temporal change of the volcanic activity. The δ34S values of water-soluble sulphate leached from volcanic ash effused during intermittent eruptions from July to September 2005 range from +5 to +11‰ with a fluctuation of ca 3‰ within a single eruption. The δ34S value of sulphuric acid mist collected with 'Cu-metal trap' placed on the flank of the volcano from December 2000 to January 2001 is +6.2‰. These sulphur isotopic compositions of sulphate, which were isotopically equilibrated in the subvolcanic hydrothermal system, indicate that the temperature of the hydrothermal system beneath the caldera increased after the period of intermittent phreatic and phreatomagmatic eruptions. Then, the δ34S value of sulphuric acid trapped from January to March 2001 was +9.0‰ and the δ34S value of water-soluble sulphate on volcanic ash emitted with minor eruption in May 2001 was +11.0‰, suggesting a decrease in temperature of the subvolcanic hydrothermal system.  相似文献   

7.
8.
Among the series of eruptions at Miyakejima volcano in 2000, the largest summit explosion occurred on 18 August 2000. During this explosion, vesiculated bombs and lapilli having cauliflower-like shapes were ejected as essential products. Petrological observation and chemical analyses of the essential ejecta and melt inclusions were carried out in order to investigate magma ascent and eruption processes. SEM images indicate that the essential bombs and lapilli have similar textures, which have many tiny bubbles, crystal-rich and glass-poor groundmass and microphenocrysts of plagioclase, augite and olivine. Black ash particles, which compose 40% of the air-fall ash from the explosion, also have similar textures to the essential bombs. Whole-rock analyses show that the chemical composition of all essential ejecta is basaltic (SiO2=51–52 wt%). Chemical analyses of melt inclusions in plagioclase and olivine phenocrysts indicate that melt in the magma had 0.9–1.9 wt% H2O, <0.011 wt% CO2, 0.04–0.17 wt% S and 0.06–0.1 wt% Cl. The variation in volatile content suggests degassing of the magma during ascent up to a depth of about 1 km. The ratio of H2O and S content of melt inclusions is similar to that of volcanic gas, which has been intensely and continuously emitted from the summit since the end of August 2000, indicating that the 18 August magma is the source of the gas emission. Based on the volatile content of the melt inclusions and the volcanic gas composition, the initial bulk volatile content of the magma was estimated to be 1.6–1.9 wt% H2O, 0.08–0.1 wt% CO2, 0.11–0.17 wt% S and 0.06–0.07 wt% Cl. The basaltic magma ascended from a deeper chamber (10 km) due to decrease in magma density caused by volatile exsolution with pressure decrease. The highly vesiculated magma, which had at least 30 vol% bubbles, may have come into contact with ground water at sea level causing the large explosion of 18 August 2000.Editorial responsibility: S. Nakada, T. DuittAn erratum to this article can be found at  相似文献   

9.
The first sign of magma accumulating beneath Miyakejima, an island volcano in the northern Izu islands, Japan, came at around 18:00 on 26 June 2000, when a swarm of earthquakes was detected by a volcano seismic network on the island. Earthquakes occurred initially beneath the southwest flank near the summit and gradually migrated west of the island, where a submarine eruption occurred the next morning. Earthquakes then migrated further to the northwest between Miyakejima and Kozushima, another volcanic island and developed to the most intense earthquake swarm ever observed in and around Japanese archipelago. To better image how the initial magma intrusion occurred, we relocated hypocenters by using a station-correction method and a double-difference method. The relocated epicenters are generally concentrated near the upper bound of dyke intrusions inferred from geodetic studies throughout the initial stages of the 2000 eruption at Miyakejima from 26 to 27 June 2000. As for seismic activity westward off Miyakejima in the morning on 27 June, hypocenters from both a nationwide seismic network that were relocated by the double-difference method, and those from the volcano seismic network relocated by the station-correction method, formed a very shallow cluster that ascended slowly with time as it propagated northwestward from Miyakejima. This suggests that the dykes have both a radial and upward component of movement.Editorial responsibility: S. Nakada, T. Druitt  相似文献   

10.
11.
Water was sampled from eight springs and a lake in volcanic Miyakejima Island of Japan after the 2000 eruption. Major chemical and isotopic compositions of the water were analyzed. Significant increases of sulfate ion are observed in several springs where the thickness of ejecta exceeds 32 mm. A good relationship of Cl/S mole ratios between spring water and leachate of the ejecta is observed. Sulfur isotopic compositions of the spring water become close to that of leachate of the ejecta as time elapses after the eruption. Consequently the sources of the added sulfate ion in the spring water after the eruption are interpreted to be anhydrite and adhered sulfur of the ejecta.  相似文献   

12.
13.
The 1986 eruption of B fissure at Izu-Oshima Volcano, Japan, produced, among other products, one andesite and two basaltic andesite lava flows. Locally the three flows resemble vent-effused holocrystalline blocky or aa lava; however, remnant clast outlines can be identified at most localities, indicating that the flows were spatter fed or clastogenic. The basaltic andesite flows are interpreted to have formed by two main processes: (a) reconstitution of fountain-generated spatter around vent areas by syn-depositional agglutination and coalescence, followed by extensional non-particulate flow, and (b) syn-eruptive collapse of a rapidly built spatter and scoria cone by rotational slip and extensional sliding. These processes produced two morphologically distinct lobes in both flows by: (a) earlier non-particulate flow of agglutinate and coalesced spatter, which formed a thin lobe of rubbly aa lava (ca. 5 m thick) with characteristic open extension cracks revealing a homogeneous, holocrystalline interior, and (b) later scoria-cone collapse, which created a larger lobe of irregular thickness (<20 m) made of large detached blocks of scoria cone interpreted to have been rafted along on a flow of coalesced spatter. The source regions of these lava flows are characterized by horseshoe-shaped scarps (<30 m high), with meso-blocks (ca. 30 m in diameter) of bedded scoria at the base. One lava flow has a secondary lateral collapse zone with lower (ca. 7 m) scarps. Backward-tilted meso-blocks are interpreted to be the product of rotational slip, and forward-tilted blocks the result of simple toppling. Squeeze-ups of coalesced spatter along the leading edge of the meso-blocks indicate that coalescence occurred in the basal part of the scoria cone. This low-viscosity, coalesced spatter acted as a lubricating layer along which basal failure of the scoria cone occurred. Rotational sliding gave way to extensional translational sliding as the slide mass spread out onto the present caldera floor. Squeeze-ups concentrated at the distal margin indicate that the extensional regime changed to one of compression, probably as a result of cooling of the flow front. Sliding material piled up behind the slowing flow front, and coalesced spatter was squeezed up from the interior of the flow through fractures and between rafted blocks. The andesite flow, although morphologically similar to the other two flows, has a slightly different chemical composition which corresponds to the earliest stage of the eruption. It is a much smaller lava flow emitted from the base of the scoria cone 2 days after the eruption had ceased. This lava is interpreted to have been formed by post-depositional coalescence of spatter under the influence of the in-situ cooling rate and load pressure of the deposit. Extrusion occurred through the lower part of the scoria cone, and subsequent non-particulate flow of coalesced material produced a blocky and aa lava flow. The mechanisms of formation of the lava flows described may be more common during explosive eruptions of mafic magma than previously envisaged. Received: 30 May 1997 / Accepted: 19 May 1998  相似文献   

14.
The formation of ring faults yields important implications for understanding the structural and dynamic evolution of collapse calderas and potentially associated ash-flow eruptions. Caldera collapse occurred in 2000 at Miyakejima Island (Japan) in response to a lateral intrusion. Based on geophysical data it is inferred that a set of caldera ring faults was propagating upward. To understand the kinematics of ring-fault propagation, linkage, and interaction, we describe new laboratory sand-box experiments that were analyzed through Digital Image Correlation (DIC) and post-processed using 2D strain analysis. The results help us gain a better understanding of the processes occurring during caldera subsidence at Miyakejima. We show that magma chamber evacuation induces strain localization at the lateral chamber margin in the form of a set of reverse faults that sequentially develops and propagates upwards. Then a set of normal faults initiates from tension fractures at the surface, propagating downwards to link with the reverse faults at depth. With increasing amounts of subsidence, interaction between the reverse- and normal-fault segments results in a deactivation of the reverse faults, while displacement becomes focused on the outer normal faults. Modeling results show that the area of faulting and collapse migrates successively outward, as peak displacement transfers from the inner ring faults to later developed outer ring faults. The final structural architecture of the faults bounding the subsiding piston-like block is hence a consequence of the amount of subsidence, in agreement with other caldera structures observed in nature. The experimental simulations provide an analogy to the observations and seismic records of caldera collapse at Miyakejima volcano, but are also applicable to caldera collapse in general.  相似文献   

15.
Processes generating block and ash flows by gravitational dome collapse (Merapi-type pyroclastic flow) were observed in detail during the 1990–1995 eruption of Unzen volcano, Japan. Two different types were identified by analysis of video records and observations during helicopter flights. Most of the block and ash flows erupted during the 1991–1993 exogenous dome growth stage initially involved crack propagation due to cooling and flowage of the dome lava lobes. The mass around the crack became unstable, locally decreasing in tensile strength. Finally, a slab separated from the lobe front, fragmented progressively from the base to the top within a few seconds, and became a block and ash flow. Rock falls immediately followed, in response to local instability of the lobe front. Clasts in these rock falls fragmented and merged with the preceding flow. In contrast, block and ash flows during the endogenous dome growth stage in 1994 were generated due to local bulge of the dome. Unstable lava blocks collapsed and subsequently fragmented to produce block and ash flows.  相似文献   

16.
The vesiculation of magma during the 1983 eruption of Miyakejima Volcano, Japan, is discussed based on systematic investigations of water content, vesicularity, and bubble size distribution for the products. The eruption is characterized by simultaneous lava effusion and explosive sub-plinian (‘dry’) eruptions with phreatomagmatic (‘wet’) explosions. The magmas are homogeneous in composition (basaltic andesite) and in initial water content (H2O = 3.9±0.9 wt%), and residual groundmass water contents for all eruption styles are low (H2O <0.4 wt%) suggestive of extensive dehydration of magma. For the scoria erupted during simultaneous ‘dry’ and ‘wet’ explosive eruptions, inverse correlation was observed between vesicularity and residual water content. This relation can be explained by equilibrium exsolution and expansion of ca. 0.3 wt% H2O at shallow level with different times of quenching, and suggests that each scoria with different vesicularity, which was quenched at a different time, provides a snapshot of the vesiculation process near the point of fragmentation. The bubble size distribution (BSD) varies systematically with vesicularity, and total bubble number density reaches a maximum value at vesicularity Φ ∼ 0.5. At Φ  ∼ 0.5, a large number of bubbles are connected with each other, and the average thickness of bubble walls reaches the minimum value below which they would rupture. These facts suggest that vesiculation advanced by nucleation and growth of bubbles when Φ < 0.5, and then by expansion of large bubbles with coalescence of small ones for Φ > 0.5, when bubble connection becomes effective. Low vesicularity and low residual water content of lava and spatter (Φ  < 0.1, H2O  < 0.1 wt%), and systematic decrease in bubble number density from scoria through spatter to lava with decrease in vesicularity suggest that effusive eruption is a consequence of complete degassing by bubble coalescence and separation from magma at shallow levels when magma ascent rate is slow.
T. ShimanoEmail:
  相似文献   

17.
Scoria cones are common volcanic features and are thought to most commonly develop through the deposition of ballistics produced by gentle Strombolian eruptions and the outward sliding of talus. However, some historic scoria cones have been observed to form with phases of more energetic violent Strombolian eruptions (e.g., the 1943–1952 eruption of Parícutin, central Mexico; the 1975 eruption of Tolbachik, Kamchatka), maintaining volcanic plumes several kilometers in height, sometimes simultaneous with active effusive lava flows. Geologic evidence shows that violent Strombolian eruptions during cone formation may be more common than is generally perceived, and therefore it is important to obtain additional insights about such eruptions to better assess volcanic hazards. We studied Irao Volcano, the largest basaltic monogenetic volcano in the Abu Monogenetic Volcano Group, SW Japan. The geologic features of this volcano are consistent with a violent Strombolian eruption, including voluminous ash and fine lapilli beds (on order of 10?1 km3 DRE) with simultaneous scoria cone formation and lava effusion from the base of the cone. The characteristics of the volcanic products suggest that the rate of magma ascent decreased gradually throughout the eruption and that less explosive Strombolian eruptions increased in frequency during the later stages of activity. During the eruption sequence, the chemical composition of the magma became more differentiated. A new K–Ar age determination for phlogopite crystallized within basalt dates the formation of Irao Volcano at 0.4?±?0.05 Ma.  相似文献   

18.
The Onano explosive eruption of the Latera Volcanic Complex (Vulsini Volcanoes, Quaternary potassic Roman Comagmatic Region, Italy) provides an interesting example of multiple changes of eruptive style that were concomitant with a late phase of collapse of the polygenetic Latera Caldera. This paper reports a reconstruction of the event based on field analysis, laboratory studies of grain size and density of juvenile clasts, and re-interpretation of available subsurface geology data. The Onano eruption took place in a structurally weak area, corresponding to a carbonate substrate high bordered by the pre-existing Latera caldera and Bolsena volcano-tectonic depression, which controlled the ascent and eruption of a shoshonitic-phonotephritic magma through intersecting rim fault systems. Temporal changes of magma vesiculation, fragmentation and discharge rate, and consequent eruptive dynamics, were strongly controlled by pressure evolution in the magma chamber and changing vent geometry. Initially, pumice-rich pyroclastic flows were emplaced, followed by spatter- and lithic-rich flows and fallout from energetic fire-fountaining. The decline of magma pressure due to the partial evacuation of the magma chamber induced trapdoor collapse of the chamber roof, which involved part of the pre-existing caldera and external volcano slopes and eventually led to the present-day caldera. The widening of the vent system and the emplacement of the main pyroclastic flow and associated co-ignimbrite lag breccia marked the eruption climax. A sudden drop of the confining pressure, which is attributed to a pseudo-rigid behaviour of the magma chamber wall rocks during a phase of rapid magma drainage, led to extensive magma vesiculation and fragmentation. The disruption of the magma chamber roof and waning magma pressure in the late eruption stage favoured the explosive interaction of residual magma with groundwater from the confined carbonate aquifer. Pulsating hydrostatic and magma pressures produced alternating hydromagmatic pyroclastic surges, strombolian fallout and spatter flows.  相似文献   

19.
A core drilled within the northern part of the city of Napoli has offered the unique opportunity to observe in one single sequence the superposition of the four pyroclastic flow units emplaced during the Campanian Ignimbrite (CI) eruption. Such a stratigraphic succession has never been encountered before in natural or in man made exposures. Therefore the CI sequence was reconstructed only on the basis of stratigraphic correlations and compositional data (in literature). The occurrence of four superposed CI flows, together with all the data available (in literature) allowed us to better constrain the chemical stratigraphy of the deposit and the compositional structure of the CI magma chamber. The CI magma chamber includes two cogenetic magma layers, separated by a compositional gap. The upper magma layer was contaminated by interaction with radiogenic fluids. The two magma layers were extruded either individually or simultaneously during the course of the eruption. In the latter case they produced a hybrid magma. But no evidence of input of new geochemically and isotopically distinct magma batches just prior or during the eruption has been found. Comparison with the exposed CI deposits has permitted reconstruction of variable eruption phases and related magma withdrawal and caldera collapse episodes. The eruption was likely to have began with phreatomagmatic explosions followed by the formation of a sustained plinian eruption column fed by the simultaneous extraction from both magma layers. Towards the end of this phase the upward migration of the fragmentation surface and the decrease in magma eruption rate and/or activation of fractures formed an unstable pulsating column that was fed only by the most-evolved magma layer. This plinian phase was followed by the collapse of the eruption column and the beginning of caldera formation. At this stage expanded pyroclastic flows fed by the upper magma layer in the chamber generated. During the following major caldera collapse episode, the maximum mass discharge rate was reached and both magma layers were tapped, generating expanded pyroclastic flows. Towards the end of the eruption, only the deeper and less differentiated magma layer was tapped producing more concentrated pyroclastic flows that traveled short distances.  相似文献   

20.
Kusakabe  M.  Mizutani  Y.  Kometani  M. 《Bulletin of Volcanology》1982,45(3):203-209

Sulphur isotopic compositions of pyrite, anhydrite and native sulphur in volcanic ashes discharged by the 1979 eruption of Ontake volcano, Nagano, Japan were determined. The isotopic data indicate that sulphate in anhydrite and a part of native sulphur were produced by the disproportionation reaction of sulphite formed by dissolution of SO2 in volcanic gases into water which filled a mud reservoir probably located just below the crater zone. Some part of H2S in volcanic gases was fixed as pyrite and some was oxidised to form native sulphur. Hydrothermal alteration of country rocks to form pyrite, anhydrite and clay minerals had proceeded in the mud reservoir before eruption at temperatures ranging from 110° to 185°C which were estimated by oxygen isotopic fractionation between anhydrite and water.

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