Voluminous lava-like precursor to a major ash-flow tuff: low-column pyroclastic eruption of the Pagosa Peak Dacite, San Juan volcanic field, Colorado

The Pagosa Peak Dacite is an unusual pyroclastic deposit that immediately predated eruption of the enormous Fish Canyon Tuff (5000 km³) from the La Garita caldera at 28 Ma. The Pagosa Peak Dacite is thick (to 1 km), voluminous (>200 km³), and has a high aspect ratio (1:50) similar to those of silicic lava flows. It contains a high proportion (40–60%) of juvenile clasts (to 3–4 m) emplaced as viscous magma that was less vesiculated than typical pumice. Accidental lithic fragments are absent above the basal 5–10% of the unit. Thick densely welded proximal deposits flowed rheomorphically due to gravitational spreading, despite the very high viscosity of the crystal-rich magma, resulting in a macroscopic appearance similar to flow-layered silicic lava. Although it is a separate depositional unit, the Pagosa Peak Dacite is indistinguishable from the overlying Fish Canyon Tuff in bulk-rock chemistry, phenocryst compositions, and ⁴⁰Ar/³⁹Ar age.The unusual characteristics of this deposit are interpreted as consequences of eruption by low-column pyroclastic fountaining and lateral transport as dense, poorly inflated pyroclastic flows. The inferred eruptive style may be in part related to synchronous disruption of the southern margin of the Fish Canyon magma chamber by block faulting. The Pagosa Peak eruptive sources are apparently buried in the southern La Garita caldera, where northerly extensions of observed syneruptive faults served as fissure vents. Cumulative vent cross-sections were large, leading to relatively low emission velocities for a given discharge rate. Many successive pyroclastic flows accumulated sufficiently rapidly to weld densely as a cooling unit up to 1000 m thick and to retain heat adequately to permit rheomorphic flow. Explosive potential of the magma may have been reduced by degassing during ascent through fissure conduits, leading to fracture-dominated magma fragmentation at low vesicularity. Subsequent collapse of the 75×35 km² La Garita caldera and eruption of the Fish Canyon Tuff were probably triggered by destabilization of the chamber roof as magma was withdrawn during the Pagosa Peak eruption.     

Changes in magma composition at Arenal volcano,Costa Rica, 1968–1985: Real-time monitoring of open-system differentiation

Arenal volcano in Costa Rica has been erupting nearly continuously, but at a diminishing rate, since 1968, producing approximately 0.35 km³ of lavas and tephras that have shown consistent variations in chemistry and mineralogy. From the beginning of the eruption in July 1968 to early 1970 (stage 1, vol.=0.12 km³) tephras and lavas became richer in Ca, Mg, Ni, Cr, Fe, Ti, V, and Sc and poorer in Al₂O₃ and SiO₂. Concentrations of incompatible trace elements (including Sr) decreased by 5%–20%. Phenocryst contents increased 20–50 vol%. During stage 2 (1970–1973, vol. = 0.13 km³) concentrations of compatible trace elements rose, and concentrations of incompatible trace elements either remained constant or also rose. Al₂O₃ contents decreased by 1 wt%. Phenocryst content increased slightly, principally due to increased orthopyroxene. During stage 3 (mid-1974 to the present, vol.= 0.10 km³) concentrations of SiO₂ increased by 1 wt%, compatible trace elements decreased slightly, and incompatible trace element concentrations increased by 5% to 10%. Although crystals increased in size during stage 3, their overall abundance stayed roughly constant.Our modeling suggests that early stage-1 magmas were produced by boundary layer fractionation under high-p H₂O conditions of an unseen basaltic andesitic magma that intruded into the Arenal system after approximately 500 B.P. Changes in composition during stage 2 resulted from mixing of this more mafic original magma with new magma that had a similar SiO₂ content, but higher compatible and incompatible element concentrations. The changes during stage 3 resulted from continued influx of the same magma plus crystal removal.We conclude that the eruption proceeded in the following way. Before 1968 zoned stage-1 magma resided in the deep crust below Arenal. A new magma intruded into this chamber in July 1968 causing ejection of the stage-1 magmas. The intruding magma mixed with mafic portions of the original chamber producing the mixed lavas of stage 2. Continued mixing plus crystal fractionation along the chamber and conduit walls produced stage-3 lavas. The time scales of crustal level magmatic processes at Arenal range 10⁰–10³ years, which are 3–6 orders of magnitude shorter than those of larger, more silicic systems.     

The Pomici di Avellino eruption of Somma-Vesuvius (3.9 ka bp). Part I: stratigraphy, compositional variability and eruptive dynamics

The stratigraphic succession of the Pomici di Avellino Plinian eruption from Somma-Vesuvius has been studied through field and laboratory data in order to reconstruct the eruption dynamics. This eruption is particularly important in the Somma-Vesuvius eruptive history because (1) its vent was offset with respect to the present day Vesuvius cone; (2) it was characterised by a distinct opening phase; (3) breccia-like very proximal fall deposits are preserved close to the vent and (4) the pyroclastic density currents generated during the final phreatomagmatic phase are among the most widespread and voluminous in the entire history of the volcano. The stratigraphic succession is, here, divided into deposits of three main eruptive phases (opening, magmatic Plinian and phreatomagmatic), which contain five eruption units. Short-lived sustained columns occurred twice during the opening phase (H_t of 13 and 21.5 km, respectively) and dispersed thin fall deposits and small pyroclastic density currents onto the volcano slopes. The magmatic Plinian phase produced the main volume of erupted deposits, emplacing white and grey fall deposits which were dispersed to the northeast. Peak column heights reached 23 and 31 km during the withdrawal of the white and the grey magmas, respectively. Only one small pyroclastic density current was emplaced during the main Plinian phase. In contrast, the final phreatomagmatic phase was characterised by extensive generation of pyroclastic density currents, with fallout deposits very subordinate and limited to the volcano slopes. Assessed bulk erupted volumes are 21 × 10⁶ m³ for the opening phase, 1.3–1.5 km³ for the main Plinian phase and about 1 km³ for the final phreatomagmatic phase, yielding a total volume of about 2.5 km³. Pumice fragments are porphyritic with sanidine and clinopyroxene as the main mineral phases but also contain peculiar mineral phases like scapolite, nepheline and garnet. Bulk composition varies from phonolite (white magma) to tephri-phonolite (grey magma).     

Apoyo caldera, Nicaragua: A major quaternary silicic eruptive center

Apoyo caldera, near Granada, Nicaragua, was formed by two phases of collapse following explosive eruptions of dacite pumice about 23,000 yr B.P. The caldera sits atop an older volcanic center consisting of lava flows, domes, and ignimbrite (ash-flow tuff). The earliest lavas erupted were compositionally homogeneous basalt flows, which were later intruded by small andesite and dacite flows along a well defined set of N—S-trending regional faults. Collapse of the roof of the magma chamber occurred along near-vertical ring faults during two widely separated eruptions. Field evidence suggests that the climactic eruption sequence opened with a powerful plinian blast, followed by eruption column collapse, which generated a complex sequence of pyroclastic surge and ignimbrite deposits and initiated caldera collapse. A period of quiescence was marked by the eruption of scoria-bearing tuff from the nearby Masaya caldera and the development of a soil horizon. Violent plinian eruptions then resumed from a vent located within the caldera. A second phase of caldera collapse followed, accompanied by the effusion of late-stage andesitic lavas, indicating the presence of an underlying zoned magma chamber. Detailed isopach and isopleth maps of the plinian deposits indicate moderate to great column heights and muzzle velocities compared to other eruptions of similar volume. Mapping of the Apoyo airfall and ignimbrite deposits gives a volume of 17.2 km³ within the 1-mm isopach. Crystal concentration studies show that the true erupted volume was 30.5 km³ (10.7 km³ Dense Rock Equivalent), approximately the volume necessary to fill the caldera. A vent area located in the northeast quadrant of the present caldera lake is deduced for all the silicic pyroclastic eruptions. This vent area is controlled by N—S-trending precaldera faults related to left-lateral motion along the adjacent volcanic segment break. Fractional crystallization of calc-alkaline basaltic magma was the primary differentiation process which led to the intermediate to silicic products erupted at Apoyo. Prior to caldera collapse, highly atypical tholeiitic magmas resembling low-K, high-Ca oceanic ridge basalts were erupted along tension faults peripheral to the magma chamber. The injection of tholeiitic magmas may have contributed to the paroxysmal caldera-forming eruptions.     

Magma mingling in the ∼50 ka Rotoiti eruption from Okataina Volcanic Centre: implications for geochemical diversity and chronology of large volume rhyolites

Examination of glass and crystal chemistry in the Rotoiti Pyroclastics (>100 km³ of magma) demonstrates that compositional diversity was produced by mingling of the main rhyolite magma body with small volumes of other magmas that had been crystallizing in separate stagnant magma chambers. Most (>90%) of the Rotoiti deposits were derived from a low-K₂O, cummingtonite-bearing, rhyolitic magma (T1) discharged throughout the eruption sequence. T1 magma is homogeneous in composition (melt SiO₂=77.80±0.28 wt.%), temperature (766±13 °C) and oxygen fugacity (NNO+0.92±0.09). Most T1 phenocrysts formed in a shallow (∼200 MPa), near water-saturated (a_water=0.8) storage chamber shortly before eruption. Basaltic scoria erupted immediately before the rhyolites, and glass-bearing microdiorite inclusions within the rhyolite deposits, suggest that basalt emplaced on the floor of the chamber drove vigorous convection to produce the well-mixed T1 magma. Lithic lag breccias contain melt-bearing biotite granitoid inclusions that are compositionally distinct from T1 magma. The breccias which overlie the voluminous T1 pyroclastic flow deposits resulted from collapse of the syn-Rotoiti caldera. Post-collapse Rotoiti pumices contain T1 magma mingled with another magma (T2) that is characterized by high-K glass and biotite, and was cooler and less oxidised (712±16 °C; NNO−0.16±0.16). The mingled clasts contain bimodal disequilibrium populations of all crystal phases. The granitoid inclusions and the T2 magma are interpreted as derived from high-K magma bodies of varying ages and states of crystallization, which were adjacent to but not part of the large T1 magma body. We demonstrate that these high-K magmas contaminated the erupting T1 magma on a single pumice clast scale. This contamination could explain the reported wide range of zircon U–Th ages in Rotoiti pumices, rather than slow crystallization of a single large magma body.     

Eruptive patterns for the volcano piton de la fournaise, Reunion Island

A study of the historic record of activity of Piton de la Fournaise has revealed a cyclic pattern of eruption involving effusion of oceanite lava from major-flank centers every 20–40 years. Calculated volumes of the recent lava flows and pyroclastic ejecta have established an effusion rate of 3.9 m³ s⁻¹ since 1931 and 6.2 m³ s⁻¹ since 1951. Flank eruptions outside the present caldera define a distribution maximum which is expected to correlate with the depth range of a high-level magma reservoir.A model has been constructed which requires replenishment of a high-level magma chamber at a constant rate and regular eruption from summit and minor-flank centers, acting as “safety valves” to the magma chamber; when the magma chamber reaches its maximum expansion, a major-flank outburst of oceanitic lava occurs.The fact that calculated effusion rates are not consistent with radiometric dates implies an increase in effusion volume with time for the volcano.     

Magma mixing and magma plumbing systems in island arcs

Petrographic features of mixed rocks in island arcs, especially those originating by the mixing of magmas with a large compositional and temperature difference, such as basalt and dacite, suggest that the whole mixing process from their first contact to the final cooling (= eruption) has occurred continuously and in a relatively short time period. This period is probably less than several months, considerably shorter than the whole volcanic history. There may also be a prolonged quiescent interval, lasting longer than several days, between the magmas' contact and the mechanical mixing. This interval will allow the basic magma to cool and produce a semi-solidified boundary which is later disrupted by flow movements to produce basic inclusions.Mixing of magmas of contrasting chemical composition need not be the inevitable consequence of the contact of the magmas. It is, however, made more probable by forced convection caused by motive force such as the injection of a basic magma into an acidic magma chamber. A short interval between their initial contact and the final eruption requires that the acid magma chamber has a small volume, of the same order or less than that the introduced basic magma.The volcanic activity of Myoko volcano, central Japan, of the last 100,000 years shows alternate eruptions of hybrid andesite by mixing of basaltic and dacitic magmas, and non-mixed basalt to basaltic andesite. There was a repose period of 20,000 to 30,000 years between eruptions. The acidic chamber, eventually producing the mixed andesite activity, is formed during the repose period by the « in situ » solidification of the original basic magma against its wall. The volume of the chamber is very small, probably about 10^–2 km³. Basaltic magma with constant chemical composition is supplied to the shallow chamber from another deep seated basaltic chamber. The volume of the shallow magma chamber may be critical to the characteristics of volcanic activity and its products.     

The caldera-forming eruption of Ksudach volcano about cal. A.D. 240: the greatest explosive event of our era in Kamchatka, Russia

The largest Plinian eruption of our era and the latest caldera-forming eruption in the Kuril-Kamchatka region occurred about cal. A.D. 240 from the Ksudach volcano. This catastrophic explosive eruption was similar in type and characteristics to the 1883 Krakatau event. The volume of material ejected was 18–19 km³ (8 km³ DRE), including 15 km³ of tephra fall and 3–4 km³ of pyroclastic flows. The estimated height of eruptive column is 22–30 km. A collapse caldera resulting from this eruption was 4 × 6.5 km in size with a cavity volume of 6.5–7 km³. Tephra fall was deposited to the north of the volcano and reached more than 1000 km. Pyroclastic flows accompanied by ash-cloud pyroclastic surges extended out to 20 km. The eruption was initially phreatomagmatic and then became rhythmic, with each pulse evolving from pumice falls to pyroclastic flows. Erupted products were dominantly rhyodacite throughout the eruption. During the post-caldera stage, when the Shtyubel cone started to form within the caldera, basaltic-andesite and andesite magma began to effuse. The trigger for the eruption may have been an intrusion of mafic magma into the rhyodacite reservoir. The eruption had substantial environmental impact and may have produced a large acidity peak in the Greenland ice sheet.     

Erratum to Compositional variations and magma mixing in the 1991 eruptions of Hudson volcano,Chile

The August 1991 eruptions of Hudson volcano produced ~2.7 km³ (dense rock equivalent, DRE) of basaltic to trachyandesitic pyroclastic deposits, making it one of the largest historical eruptions in South America. Phase 1 of the eruption (P1, April 8) involved both lava flows and a phreatomagmatic eruption from a fissure located in the NW corner of the caldera. The paroxysmal phase (P2) began several days later (April 12) with a Plinian-style eruption from a different vent 4 km to the south-southeast. Tephra from the 1991 eruption ranges in composition from basalt (phase 1) to trachyandesite (phase 2), with a distinct gap between the two erupted phases from 54–60 wt% SiO₂. A trend of decreasing SiO₂ is evident from the earliest part of the phase 2 eruption (unit A, 63–65 wt% SiO₂) to the end (unit D, 60–63 wt% SiO₂). Melt inclusion data and textures suggest that mixing occurred in magmas from both eruptive phases. The basaltic and trachyandesitic magmas can be genetically related through both magma mixing and fractional crystallization processes. A combination of observed phase assemblages, inferred water content, crystallinity, and geothermometry estimates suggest pre-eruptive storage of the phase 2 trachyandesite at pressures between ~50–100 megapascal (MPa) at 972 ± 26°C under water-saturated conditions (log fO₂ –10.33 (±0.2)). It is proposed that rising P1 basaltic magma intersected the lower part of the P2 magma storage region between 2 and 3 km depth. Subsequent mixing between the two magmas preferentially hybridized the lower part of the chamber. Basaltic magma continued advancing towards the surface as a dyke to eventually be erupted in the northwestern part of the Hudson caldera. The presence of tachylite in the P1 products suggests that some of the magma was stalled close to the surface (<0.5 km) prior to eruption. Seismicity related to magma movement and the P1 eruption, combined with chamber overpressure associated with basalt injection, may have created a pathway to the surface for the trachyandesite magma and subsequent P2 eruption at a different vent 4 km to the south-southeast. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Temporal variations in magma composition at Merapi Volcano (Central Java, Indonesia): magmatic cycles during the past 2000 years of explosive activity

Merapi Volcano (Central Java, Indonesia) has been frequently active during Middle to Late Holocene time producing basalts and basaltic andesites of medium-K composition in earlier stages of activity and high-K magmas from 1900 ¹⁴C yr BP to the present. Radiocarbon dating of pyroclastic deposits indicates an almost continuous activity with periods of high eruption rates alternating with shorter time spans of distinctly reduced eruptive frequency since the first appearance of high-K volcanic rocks. Geochemical data of 28 well-dated, prehistoric pyroclastic flows of the Merapi high-K series indicate systematic cyclic variations. These medium-term compositional variations result from a complex interplay of several magmatic processes, which ultimately control the periodicity and frequency of eruptions at Merapi. Low eruption rates and the absence of new influxes of primitive magma from depth allow the generation of basaltic andesite magma (56–57 wt% SiO₂) in a small-volume magma reservoir through fractional crystallisation from parental mafic magma (52–53 wt% SiO₂) in periods of low eruptive frequency. Magmas of intermediate composition erupted during these stages provide evidence for periodic withdrawal of magma from a steadily fractionating magma chamber. Subsequent periods are characterised by high eruption rates that coincide with shifts of whole-rock compositions from basaltic andesite to basalt. This compositional variation is interpreted to originate from influxes of primitive magma into a continuously active magma chamber, triggering the eruption of evolved magma after periods of low eruptive frequency. Batches of primitive magma eventually mix with residual magma in the magmatic reservoir to decrease whole-rock SiO₂ contents. Supply of primitive magma at Merapi appears to be sufficiently frequent that andesites or more differentiated rock types were not generated during the past 2000 years of activity. Cyclic variations also occurred during the recent eruptive period since AD 1883. The most recent eruptive episode of Merapi is characterised by essentially uniform magma compositions that may imply the existence of a continuously active magma reservoir, maintained in a quasi-steady state by magma recharge. The whole-rock compositions at the upper limit of the total SiO₂ range of the Merapi suite could also indicate the beginning of another period of high eruption rates and shifts towards more mafic compositions.     

Volcanology of trachytic and associated basaltic pyroclastic deposits at Roccamonfina volcano, Roman Region, Italy

The 274 ka “Basalt-Trachytic Tuff of Tuoripunzoli” (TBTT) from Roccamonfina volcano (Roman Region, Italy) consists of a basaltic scoria lapilli fall (Unit A) overlain by a trachytic sequence formed by a surge (Unit B), repetitive pumice lapilli and ash-rich layers both of fallout origin (Unit C) and a pyroclastic flow deposit (Unit D). The TBTT is widespread (40 km²) in the northern sector of the volcano, but limited to a small area on the southern slopes of the main cone. Interpolation between the northern deposits and the latter one yields a minimum depositional area of 123 km², and an approximate bulk volume of 0.2-0.3 km³. Isopach and isopleth maps are consistent with a source vent within the main caldera of Roccamonfina.Unit A shows a fairly good sorting and a moderate grain size; glass fragments are cuspate and vesicular. Unit B is fine grained and poorly sorted; shards are blocky and nonvesicular. Pumice lapilli of Unit C are moderately sorted and moderately coarse grained. Glass shards are equant and vesicular. Lithic clasts are strongly comminuted to submillimetric sizes. By contrast, the ash-rich internal divisions are very fine grained and poorly sorted. They consist of a mixture of equant shards which are prevailingly blocky and poorly vesicular. Unit D is a massive, poorly sorted, moderately coarse-grained deposit. Glass fragments are nearly equant and slightly or nonvesicular.The TBTT is interpreted as due to eruption of a basaltic magma followed in rapid succession by one trachyte magma. Unit A formed by Subplinian fallout of a moderate, purely magmatic column. Interaction between a trachyte magma and water resulted in eruption of surge Unit B. A high-standing eruption column erupted alternating fallout pumice lapilli and fallout ashes. Pumice lapilli originated prevailingly from the inner part of the eruption column, whereas magma-water interaction on the external parts of the column resulted in ash fallout. The uppermost pyroclastic flow Unit D is interpreted as due to final collapse of the eruption column.     

Eruption and emplacement of a basaltic welded ignimbrite during caldera formation on Gran Canaria

The 14.1 Ma old composite ignimbrite cooling unit P1 (45 km³) on Gran Canaria comprises a lower mixed rhyolite-trachyte tuff, a central rhyolite-basalt mixed tuff, and a slightly rhyolite-contaminated basaltic tuff at the top. The basaltic tuff is compositionally zoned with (a) an upward change in basalt composition to higher MgO content (4.3–5.2 wt.%), (b) variably admixed rhyolite or trachyte (commonly <5 wt.%), and (c) an upward increasing abundance of basaltic and plutonic lithic fragments and cognate cumulate fragments. The basaltic tuff is divided into three structural units: (I) the welded basaltic ignimbrite, which forms the thickest part (c. 95 vol.%) and is the main subject of the present paper; (II) poorly consolidated massive, bomb- and block-rich beds interpreted as phreatomagmatic pyroclastic flow deposits; and (III) various facies of reworked basaltic tuff. Tuff unit I is a basaltic ignimbrite rather than a lava flow because of the absence of top and bottom breccias, radial sheet-like distribution around the central Tejeda caldera, thickening in valleys but also covering higher ground, and local erosion of the underlying P1 ash. A gradual transition from dense rock in the interior to ash at the top of the basaltic ignimbrite reflects a decrease in welding; the shape of the welding profile is typical for emplacement temperatures well above the minimum welding temperature. A similar transition occurs at the base where the ignimbrite was emplaced on cold ground in distal sections. In proximal sections the base is dense where it was emplaced on hot felsic P1 tuff. The intensity of welding, especially at the base, and the presence of spherical particles and of mantled and composite particles formed by accretion and coalescence in a viscous state imply that the flow was a suspension of hot magma droplets. The flow most likely had to be density stratified and highly turbulent to prevent massive coalescence and collapse. Model calculations suggest eruption through low pyroclastic fountains (<1000 m high) with limited cooling during eruption and turbulent flow from an initial temperature of 1160°C. The large volume of 26 km³ of erupted basalt compared with only 16 km³ of the evolved P1 magmas, and the extremely high discharge rates inferred from model calculations are unusual for a basaltic eruption. It is suggested that the basaltic magma was erupted and emplaced in a fashion commonly only attributed to felsic magmas because it utilized the felsic P1 magma chamber and its ring-fissure conduits. Evolution of the entire P1 eruption was controlled by withdrawal dynamics involving magmas differing in viscosity by more than four orders of magnitude. The basaltic eruption phase was initially driven by buoyancy of the basaltic magma at chamber depth and continued degassing of felsic magma, but most of the large volume of basalt magma was driven out of the reservoir by subsidence of a c. 10 km diameter roof block, which followed a decrease in magma chamber pressure during low viscosity basaltic outflow.     

Variation of volatile concentration in a magma system of Satsuma-Iwojima volcano deduced from melt inclusion analyses

Chemical analyses of 30 melt inclusions from Satsuma-Iwojima volcano, Japan, were carried out to investigate volatile evolution in a magma chamber beneath the volcano from about 6300 yr BP to the present. Large variations in volatile concentrations of melts were observed. (1) Water concentration of rhyolitic melts decreases with time; 3–4.6 wt.% at the time of latest caldera-forming eruption of Takeshima pyroclastic flow deposit (ca. 6300 yr BP), 3 wt.% for small pyroclastic flow (ca. 1300 yr BP) of Iwodake, post-caldera rhyolitic dome, and 0.7–1.4 wt.% for submarine lava eruption (Showa-Iwojima) in 1934. (2) Rhyolitic melts of the Takeshima and Iwodake eruptions contained CO₂ of less than 40 ppm, while the Showa-Iwojima melt has higher CO₂ concentration of up to 140 ppm. (3) Water and CO₂ concentrations of basaltic to andesitic melt of Inamuradake, a post-caldera basaltic scoria cone, are 1.2–2.8 wt.% and ≤290 ppm, respectively.Volatile evolution in the magma chamber is interpreted as follows: (1) the rhyolitic magma at the time of the latest caldera-forming eruption (ca. 6300 yr BP) was gas-saturated due to pressure variation in the magma chamber because the large variation in water concentration of the melt was attributed to exsolution of volatile in the magma prior to the eruption. Iwodake eruption (ca. 1300 yr BP) was caused by a remnant of the caldera-forming rhyolitic magma, suggested from the similarity of major element composition between these magmas. (2) Volatile composition of the Showa-Iwojima rhyolitic melt agrees with that of magmatic gases presently discharging from a summit of Iwodake, indicating the low pressure degassing condition. (3) The degassing of the magma chamber by magma convection in a conduit of Iwodake during non-eruptive but active degassing period for longer than 800 years decreased water concentration of the rhyolitic magma. (4) Geological and petrological observations indicate that a stratified magma chamber, which consists of a lower basaltic layer and an upper rhyolitic layer, might have existed during the post-caldera stage. Addition of CO₂ from the underlying basaltic magma to the upper gas-undersaturated (degassed) rhyolitic magma increased CO₂ concentration of the rhyolitic magma.     

Density and viscosity gradients in zoned magma chambers, and their influence withdrawal dynamics

The liquid being sampled from a draining reservoir of density-stratified fluid, such as an erupting zoned magma chamber, is derived from a relatively thin withdrawal layer adjacent to the level of the chamber outlet. This is a consequence of the buoyancy force associated with the density gradient inhibiting vertical motion so that the opportunity for widely separated density levels (compositions) to be tapped and mingled syneruptively is suppressed.Density gradients in zoned chambers of 0.02 – 10 kgm⁻³/m are suggested by data from caldera-forming eruptions. Viscosity gradients can be specified for a given density gradient using calculated relationships between viscosity and density. Published compositional and geothermometric data are used to show that zoned high-silica rhyolites decrease in viscosity upward because of the roofward concentration of dissolved volatiles. Other zoned calc-alkaline magmas increase in viscosity upward because of decreasing temperature and concentration of network modifying cations.A method is developed of calculating the scale of the withdrawal layer thickness, δ, for given kinematic viscosity, eruption rate, and density and viscosity gradients. The method is systematized by the identification of specific flow regimes describing the action of either viscous or inertial forces in balancing the buoyancy force. Thin withdrawal layers are favoured by small eruption rates, small viscosity, and by large density gradients. For particularly steep density gradients, however, the consequently large viscosity gradient plays a role in determining the withdrawal layer thickness. Withdrawal layer thicknesses of the order of 100 m are calculated for typical pyroclastic eruptions of zoned acid magma, and are mostly independent of the viscosity gradient.The vertical scale at which a zoned chamber is instantaneously being tapped during an eruption is equal to the scale of the withdrawal layer thickness. Thus, an eruption that causes collapse of a caldera block through a height that is less than that of the withdrawal layer scale will produce magmas from deeper levels than that to which the chamber roof sinks. In this case the eruption is said to oversample the chamber with respect to the amount of caldera collapse and will produce an essentially constant range of compositions throughout. Alternatively, if the caldera collapse distance is much greater than δ then the selective withdrawal process leads to successive levels of the chamber being “skimmed off” (on a scale δ). This allows the compositional stratigraphy of the chamber to be inverted by the eruptive process, with little opportunity for syneruptive mixing between diverse magma compositions. The geological record shows that most calderas associated with zoned magmas collapsed through vertical distances in excess of 100 m (the characteristic estimate for δ) and, in agreement with our modelling of selective withdrawal, show smooth correlations between composition, or temperature, and the order of eruption.     

Petrology and sulfur and chlorine emissions of the 1963 eruption of Gunung Agung,Bali, Indonesia

 The 1963 eruption of Gunung Agung produced 0.95 km³ dense rock equivalent (DRE) of olivine±hornblende-bearing, weakly phyric, basaltic andesite tephra and lava. Evidence for magma mixing in the eruptive products includes whole-rock compatible and incompatible trace element trends, reverse and complex compositional zoning of mineral phases, disequilibrium mineral assemblages, sieve-textured plagioclase phenocrysts, and augite rims on reversely zoned orthopyroxene. Basalt magma mixed with pre-existing andesite magma shortly before eruption to yield basaltic andesite with a temperature of 1040–1100  °C at an assumed pressure of 2 kb, f O₂>NNO, and an average melt volatile content (H₂O±CO₂) of 4.3 wt.%. Magma-mixing end members may have provided some of the S and Cl emitted in the eruption. Glass inclusions in phenocrysts contain an average of 650 ppm S and 3130 ppm Cl as compared with 70 ppm and 2220 ppm, respectively, in the matrix glass. Maximum S and Cl contents of glass inclusions approach 1800 and 5000 ppm, respectively. Application of the petrologic method to products of the 1963 eruption for estimating volatile release yields of 2.5×10¹²g (Mt) of SO₂ and 3.4 Mt of Cl released from the 0.65 km³ of juvenile tephra which contributed to stratospheric injection of H₂SO₄ aerosols on 17 March and 16 May, when eruption column heights exceeded 20 km above sea level. An independent estimate of SO₂ release from atmospheric aerosol loading (11–12 Mt) suggests that approximately 7 Mt of SO₂ was injected into the stratosphere. The difference between the two estimates can be most readily accounted for by the partitioning of S, as well as some Cl, from the magma into a water-rich vapor phase which was released upon eruption. For other recent high-S-release eruptions of more evolved and oxidized magmas (El Chichón, Pinatubo), the petrologic method gives values two orders of magnitude less than independent estimates of SO₂ emissions. Results from this study of the Agung 1963 magma and its volatile emissions, and from related studies on eruptions of more mafic magmas, suggest that SO₂ emissions from eruptions of higher-S-solubility magma may be more reliably estimated by the petrologic method than may those from more-evolved magma eruptions. Received: 29 June 1994 / Accepted: 25 April 1996     

F-phlogopites in the Alban Hills Volcanic District (Central Italy): indications regarding the role of volatiles in magmatic crystallisation

A systematic analysis of micas contained in effusive, pyroclastic and hypabyssal rocks of the Alban Hills Volcanic District (AHVD) (Central Italy) was made in order to characterise minerals of pyroclastic units for tephrostratigraphy and to obtain as much information as possible on the activity of volatiles in this magmatic system. The phlogopite shows a large range of F contents (between 0.50 and 7.50 wt%) that make it possible to discriminate different AHVD lithologies; in particular, micas of lava groundmass are characterised by extremely high F (up to 7.50 wt%) and Ba (up to 9.70 wt%) contents, seldom or never found in other magmatic ultrapotassic rocks. Moreover, the micas of pyroclastics, ultramafic cumulates and holocrystalline inclusions made up of leucite, clinopyroxene and phlogopite (hereafter italites) show Mg/(Mg+Fe) values between 0.65 and 0.90 that are not correlated with F contents. The variations in F contents observed in the AHVD micas do not appear to be due to a “temperature” effect or pressure changes, but they may be due to variations in the H₂O and CO₂ activities in the magma chamber. They make it possible to differentiate three crystallisation environments in the AHVD magmatic system. The first one had elevated CO₂ activity and formed the italites near the carbonate contact; these rocks represent, at least those enriched in clinopyroxene without skarn-minerals, the hypabyssal crystallisation of the AHVD magmas at the periphery of magma chamber. The second one, characterised by a higher water activity, is represented by the micas of the ultramafic cumulates and pyroclastic scorias, and is located in the inner part of magma chamber. The third environment, the groundmass of the lavas, it is not related with the previous ones and is characterised by the absence of water and by a high F activity. In general, our results suggest that the compositional variations observed in the micas (Al, Si, Ti, Ba) reflect different H₂O activities (inversely correlated with F activity) in the magma chamber.     

Magma mingling in an andesite pyroclastic flow of the Pourahu Member, Ruapehu volcano, New Zealand

We describe a magma mingling episode from Ruapehu volcano between two andesite magmas, one very much minor in volume relative to the other. The event acted to trigger eruption of the andesitic Pourahu pyroclastic flow which is preserved in a thick sequence of tephras and laharic deposits in the southeastern ring plain of the volcano. The predominant andesite is pale brown coloured and porphyritic containing phenocrysts of plagioclase-clinopyroxene-orthopyroxene-Fe-Ti oxides. Rare clasts of a darker andesite are different texturally, less vesicular, and contain distinctive microphenocrysts of plagioclase and quench olivine. Equally rare clasts, of streaky pumice consisting of interbanded ‘dark’ and ‘light’ andesite attest to mingling between these two andesite components.Chemical analyses of discrete clasts demonstrate that the Pourahu pyroclastic flow andesites span much of the compositional spectrum of Ruapehu andesites. This observation demonstrates heterogeneity in the products of a relatively small eruption. The darker clast analyses and those from associated distal fall deposits lie within the fields defined by the dominant light coloured clasts. Phenocryst and microphenocryst geothermometry suggest slightly higher temperatures in the dark component. However, glasses from groundmass and phenocryst inclusions in the same specimen may differ considerably, leading us to conclude that many phenocrysts are in fact xenocrystic and were incorporated in the melts as they migrated towards the surface.We prefer a model in which a small volume of hot andesite magma injects a vent-feeding magma chamber, triggering vesiculation and eruption. We infer that the process of magma withdrawal extended downward into the magma body causing the dark component to intermingle with the lighter (dominant) component, ‘sucking’ more dark magma into the chamber. Our observations are entirely consistent with the existence of a plexus of small, possibly interlinked magma chambers beneath Ruapehu.     

Magma contamination by direct wall rock interaction: constraints from xenoliths from the walls of a carbonate-hosted magma chamber (Vesuvius 1944 eruption)

During the 1944 eruption of Vesuvius different types of xenoliths were ejected. They represent fragments of the walls of a low volume (<0.5 km³) shallow (3–4 km depth) magma chamber. The study of these xenoliths enables us to estimate the amount of contamination occurring at the boundary of a high-T alkaline magma chamber hosted in carbonate rocks. The process of contamination of the magma by carbonates can be modelled, using isotopic and chemical data, as a mixing between magma and marbles. Mass exchanges occur at the boundary between the crystallizing magma and marble wall rocks, where endoskarn forms. The contamination of the solidification front of the chamber is very limited. The solidification front and the skarn shell effectively isolate the interior of the magma chamber from new inputs of contaminants from the carbonate wall rocks. Therefore, the main volume of magma, hosted in the magma chamber, did not undergo any significant mass exchange with the wall rocks.     

Mount St. Helens a decade after the 1980 eruptions: magmatic models,chemical cycles,and a revised hazards assessment

Available geophysical and geologic data provide a simplified model of the current magmatic plumbing system of Mount St. Helens (MSH). This model and new geochemical data are the basis for the revised hazards assessment presented here. The assessment is weighted by the style of eruptions and the chemistry of magmas erupted during the past 500 years, the interval for which the most detailed stratigraphic and geochemical data are available. This interval includes the Kalama (A. D. 1480–1770s?), Goat Rocks (A.D. 1800–1857), and current eruptive periods. In each of these periods, silica content decreased, then increased. The Kalama is a large amplitude chemical cycle (SiO₂: 57%–67%), produced by mixing of arc dacite, which is depleted in high field-strength and incompatible elements, with enriched (OIB-like) basalt. The Goat Rocks and current cycles are of small amplitude (SiO₂: 61%–64% and 62%–65%) and are related to the fluid dynamics of magma withdrawal from a zoned reservoir. The cyclic behavior is used to forecast future activity. The 1980–1986 chemical cycle, and consequently the current eruptive period, appears to be virtually complete. This inference is supported by the progressively decreasing volumes and volatile contents of magma erupted since 1980, both changes that suggest a decreasing potential for a major explosive eruption in the near future. However, recent changes in seismicity and a series of small gas-release explosions (beginning in late 1989 and accompanied by eruption of a minor fraction of relatively low-silica tephra on 6 January and 5 November 1990) suggest that the current eruptive period may continue to produce small explosions and that a small amount of magma may still be present within the conduit. The gas-release explosions occur without warning and pose a continuing hazard, especially in the crater area. An eruption as large or larger than that of 18 May 1980 (0.5 km³ dense-rock equivalent) probably will occur only if magma rises from an inferred deep (7 km), relative large (5–7 km³) reservoir. A conservative approach to hazard assessment is to assume that this deep magma is rich in volatiles and capable of erupting explosively to produce voluminous fall deposits and pyroclastic flows. Warning of such an eruption is expectable, however, because magma ascent would probably be accompanied by shallow seismicity that could be detected by the existing seismic-monitoring system. A future large-volume eruption (0.1 km³) is virtually certain; the eruptive history of the past 500 years indicates the probability of a large explosive eruption is at least 1% annually. Intervals between large eruptions at Mount St. Helens have varied widely; consequently, we cannot confidently forecast whether the next large eruption will be years decades, or farther in the future. However, we can forecast the types of hazards, and the areas that will be most affected by future large-volume eruptions, as well as hazards associated with the approaching end of the current eruptive period.     

Sr–Nd isotopic and chemical characteristics of the silicic magma reservoir of the Aira pyroclastic eruption, southern Kyushu, Japan

Sr and Nd isotope and geochemical investigations were performed on a remarkably homogeneous, high-silica rhyolite magma reservoir of the Aira pyroclastic eruption (22,000 years ago), southern Kyushu, Japan. The Aira caldera was formed by this eruption with four flow units (Osumi pumice fall, Tsumaya pryoclastic flow, Kamewarizaka breccia and Ito pyroclastic flow). Quite narrow chemical compositions (e.g., 74.0–76.5 wt% of SiO₂) and Sr and Nd isotopic values (⁸⁷Sr/⁸⁶Sr=0.70584–0.70599 and _Nd=−5.62 to −4.10) were detected for silicic pumices from the four units, with the exception of minor amounts of dark pumices in the units. The high Sr isotope ratios (0.7065–0.7076) for the dark pumices clearly suggest a different origin from the silicic pumices. Andesite to basalt lavas in pre-caldera (0.37–0.93 Ma) and post-caldera (historical) eruptions show lower ⁸⁷Sr/⁸⁶Sr (0.70465–0.70540) and higher _Nd (−1.03 to +0.96) values than those of the Aira silicic and dark pumices. Both andesites of pre- and post-caldera stages are very similar in major- and trace-element characteristics and isotope ratios, suggesting that the both andesites had a same source and experienced the same process of magma generation (magma mixing between basaltic and dacitic magmas). Elemental and isotopic signatures deny direct genetic relationships between the Aira pumices and pre- and post-caldera lavas. Relatively upper levels of crust (middle–upper crust) are assumed to have been involved for magma generation for the Aira silicic and dark pumices. The Aira silicic magma was derived by partial melting of a separate crust which had homogeneous chemistry and limited isotope compositions, while the magma for the Aira dark pumice was generated by AFC mixing process between the basement sedimentary rocks and basaltic parental magma, or by partial melting of crustal materials which underlay the basement sediments. The silicic magma did not occupy an upper part of a large magma body with strong compositional zonation, but formed an independent magma body within the crust. The input and mixing of the magma for dark pumices to the base of the Aira silicic magma reservoir might trigger the eruptions in the upper part of the magma body and could produce a slight Sr isotope gradient in the reservoir. An extremely high thermal structure within the crust, which was caused by the uprise and accumulation of the basaltic magma, is presumed to have formed the large volume of silicic magma of the Aira stage.