Reaction-induced weakening of plagioclase–olivine composites

The localisation of strain into natural ductile shear zones is often associated with the occurrence of metamorphic reactions. In order to study the effects of solid–solid mineral reactions on plastic deformation of rocks, we have investigated the shear deformation of plagioclase–olivine composites during the reaction plagioclase + olivine → orthopyroxene + clinopyroxene + spinel (± garnet). Microstructures of plagioclase–olivine composites were studied after shear deformation experiments in a Griggs apparatus. Experiments were performed on anorthite–forsterite (An–Fo) and labradorite–forsterite (Lab–Fo) composites at 900 °C, confining pressures between 1000–1600 MPa and with constant shear strain rates of 5 × 10⁻⁵ s⁻¹.In absence of reaction, Lab–Fo composites are stronger than pure olivine and labradorite end-members that deform with a high temperature plasticity mechanism. Lab–Fo composites strain–harden due to the inhibition of extensive recrystallisation by interphase boundaries.In An–Fo composites, the reaction induces strain weakening by a switch from dislocation creep to grain size sensitive deformation mechanisms through the development of fine-grained (size < 0.5 μm) polyphase reaction products. Interconnecting layers of reaction products accommodate most of the applied strain by grain size sensitive creep. Recovery processes are pronounced during syndeformational reaction: original anorthite and olivine dynamically recrystallise by subgrain rotation and bulging recrystallisation. Presumably, the dynamic recrystallisation is caused by reduced stress conditions and partitioning of strain and strain rates between the new reaction products and the relict An–Fo grains. The results of our experiments are in good agreement with natural observations of shear localisation in the lower crust and upper mantle, and imply that anhydrous mineral reactions can be important causes for localisation of deformation.     

Variable involvements of mantle plumes in the genesis of mid-Neoproterozoic basaltic rocks in South China: A review

Ca. 825–720 Ma global continental intraplate magmatism is generally linked to mantle plumes or a mantle superplume that caused rifting and fragmentation of the supercontinent Rodinia. Widespread Neoproterozoic igneous rocks in South China are dated at ca. 825–760 Ma. There is a hot debate on their petrogenesis and tectonic affiliations, i.e., mantle plume/rift settings or collision/arc settings. Such competing interpretations have contrasting implications to the position of South China in the supercontinent Rodinia and in Rodinia reconstruction models.Variations in the bulk-rock compositions of primary basaltic melts can provide first order constraints on the mantle thermal–chemical structure, and thus distinguish between the plume/rift and arc/collision models. Whole-rock geochemical data of 14 mid-Neoproterozoic (825–760 Ma) basaltic successions are reviewed here in order to (1) estimate the primary melts compositions; (2) calculate the melting conditions and mantle potential temperature; and (3) identify the contributions of subcontinental lithosphere mantle (SCLM) and asenthospheric mantles to the generation of these basaltic rocks.In order to quantify the mantle potential temperatures and percentages of decompression melting, the primary MgO, FeO, and SiO₂ contents of basalts are calculated through carefully selecting less-evolved samples using a melting model based on the partitioning of FeO and MgO in olivine. The mid-Neoproterozoic (825–760 Ma) potential temperatures predicted from the primary melts range from 1390 °C to 1630 °C (mostly > 1480 °C), suggesting that most 825–760 Ma basaltic rocks in South China were generated by melting of anomalously hot mantle sources with potential temperatures 80–200 °C higher than the ambient Middle Ocean Ridge Basalt (MORB)-source mantle.The mantle source regions of these Neoproterozoic basaltic rocks have complex histories and heterogeneous compositions. Enriched mantle sources (e.g., pyroxenite and eclogite) are recognized as an important source for the Bikou and Suxiong basalts, suggesting that their generations may have involved recycled components. Trace elements variations show that interactions between asthenospheric mantle (OIB-type mantle) and SCLM played a very important role in generation of the 825–760 Ma basalts. Our results indicate that the SCLM metasomatized by subduction-induced melts/fluids during the 1.0–0.9 Ga orogenesis as a distinct geochemical reservoir that contributed significantly to the trace-elements and isotope inventory of these basalts.The continental intraplate geochemical signatures (e.g., OIB-type), high mantle potential temperatures and recycled components suggest the presence of a mantle plume beneath the Neoproterozoic South China block. We use the available data to develop an integrated plume-lithosphere interaction model for the ca. 825–760 Ma basalts. The early phases of basaltic rocks (825–810 Ma) were most likely formed by melting within the metasomatized SCLM heated by the rising mantle plume. The subsequent continental rift allowed adiabatic decompression partial melting of an upwelling mantle plumes at relatively shallow depth to form the widespread syn-rifting basaltic rocks at ca. 810–800 Ma and 790–760 Ma.     

Deformation mechanism maps for feldspar rocks

Deformation mechanism maps for feldspar rocks were constructed based on recently published constitutive laws for dislocation and grain boundary diffusion creep of wet and dry plagioclase aggregates. The maps display constant temperature contours in stress-grain size space for strain rates ranging from 10⁻¹⁶ to 10⁻¹² s⁻¹.Two fields of dominance of grain boundary diffusion-controlled creep and dislocation creep are separated by a strongly grain size-sensitive transition zone. For wet rocks, diffusion-controlled creep dominates below a grain size of about 0.1–1 mm, depending on temperature, stress, strain rate and feldspar composition. Plagioclase aggregates containing up to 0.3 wt.% water as often found in natural feldspars are more than 2 orders of magnitude weaker than dry rocks. The strength of water-bearing feldspar rocks is moderately dependent on composition and water fugacity.For a grain size range of about 10–50 μm commonly observed in natural ultramylonites, the deformation maps predict that diffusion-controlled creep is dominant at greenschist to granulite facies conditions. Low viscosity estimates of 10¹⁸–10¹⁹ Pa·s from modeling postseismic stress relaxation and channel flow of the continental lower crust can only be reconciled with laboratory experiments assuming dislocation creep at high temperatures >900 °C or, at lower temperatures, diffusion creep of fine-grained rocks possibly localized in abundant high strain shear zones. For similar thermodynamic conditions and grain size, lower crustal rocks are predicted to be less than order of magnitude weaker than upper mantle rocks.     

Influence of supercontinents on deep mantle flow

The assembly of supercontinents should impact mantle flow fields significantly, affecting the distribution of subduction, upwelling plumes, lower mantle chemical heterogeneities, and thus plausibly contributing to voluminous volcanism that is often associated with their breakup. Alternative explanations for this volcanism include insulation by the continent and thus elevated subcontinental mantle temperatures. Here we model the thermal and dynamic impact of supercontinents on Earth-like mobile-lid convecting systems. We confirm that insulating supercontinents (over 3000 km extent) can impact mantle temperatures, but show the scale of temperature anomaly is significantly less for systems with strongly temperature-dependent viscosities and mobile continents. Additionally, for continents over 8000 km, mantle temperatures are modulated by the development of small-scale convecting systems under the continent, which arise due to inefficient lateral convection of heat at these scales. We demonstrate a statistically robust association between rising plumes supercontinental interiors for a variety of continental configurations, driven largely by the tendency of subducting slabs to lock onto continental margins. The distribution of slabs also affects the spatial positioning of deep mantle thermochemical anomalies, which demonstrate stable configurations in either the sub-supercontinent or intraoceanic domains. We find externally forced rifting scenarios unable to generate significant melt rates, and thus the ultimate cause of supercontinent breakup related volcanism is probably related to dynamic continental rifting in response to mantle reconfiguration events.     

Simulating coseismic deformation of quartz in the middle crust and fabric evolution during postseismic stress relaxation — An experimental study

Non-steady state deformation and annealing experiments on vein quartz are designed to simulate earthquake-driven episodic deformation in the middle crust. Three types of experiments were carried out using a modified Griggs-type solid medium deformation apparatus. All three start with high stress deformation at a temperature of 400 °C and a constant strain rate of 10^− 4 s^− 1 (type A), some are followed by annealing in the stability field of α-quartz for 14–15 h at zero nominal differential stress and temperatures of 800–1000 °C (type A + B), or by annealing for 15 h at 900 °C and at a residual stress (type A + C).The quartz samples reveal a very high strength > 2 GPa at a few percent of permanent strain. The microstructures after short-term high stress deformation (type A) record localized brittle and plastic deformation. Statisc annealing (type A + B) results in recrystallisation restricted to the highly damaged zones. The new grains aligned in strings and without crystallographic preferred orientation, indicate nucleation and growth. Annealing at non-hydrostatic conditions (type A + C) results in shear zones that also develop from deformation bands or cracks that formed during the preceding high stress deformation. In this case, however, the recrystallised zone is several grain diameters wide, the grains are elongate, and a marked crystallographic preferred orientation indicates flow by dislocation creep with dynamic recrystallisation. Quartz microstructures identical to those produced in type A + B experiments are observed in cores recovered from Long Valley Exploratory Well in the Quaternary Long Valley Caldera, California, with considerable seismic activity.The experiments demonstrate the behaviour of quartz at coseismic loading (type A) and subsequent static annealing (type A + B) or creep at decaying stress (type A + C) in the middle crust. The experimentally produced microfabrics allow to identify similar processes and conditions in exhumed rocks.     

Recrystallisation,phase mixing and strain localisation in peridotite during rapid extrusion of sub-arc mantle lithosphere

The Anita Peridotite, in southwestern New Zealand, is a ∼1 × 20 km ultramafic massif that was rapidly extruded from beneath a Cretaceous arc within the 4 km wide mylonitic Anita Shear Zone. The peridotitic body contains a spectacular array of textures that preserve evidence for changing temperature, stress, and deformation mechanisms during the exhumation process. Olivine and orthopyroxene microstructures and lattice-preferred orientations (LPO) record a three-phase deformation history. Dislocation glide on the C- and E-type slip systems is recorded by coarse pre-mylonitised olivine grains, and occurred under hydrous conditions at T ∼650 °C, stress ∼200–700 MPa and strain rate ∼10⁻¹⁵ s⁻¹, probably within hydrated sub-arc mantle lithosphere. Rare protomylonite pods record deformation by dislocation creep in porphyroclasts and dislocation-accommodated grain boundary sliding in the matrix on {0kl}[100] in olivine and (100)[001] in orthopyroxene, under conditions of T ∼730–770 °C, stress ∼52–700 MPa and strain rate ∼10⁻¹⁵ s⁻¹. The massif, however, is dominated by mylonite and ultramylonite that wrap the protomylonite pods, comprising mostly fine-grained olivine neoblasts that lack internal distortions and have uniform LPOs. These textures indicate deformation occurred by grain-size sensitive (GSS) creep at T ∼650 °C, stress ∼69–137 MPa and strain rate ∼10⁻¹⁵ s⁻¹, and thus during conditions of cooling and decreasing stress. GSS creep became more dominant with time, as the proportion of randomly-oriented neoblasts increased and formed interlinked networks that accommodated much of the strain. Grain boundary pinning allowed GSS creep to be maintained in polyphase regions, following mixing of olivine and orthopyroxene, which may have occurred by grain boundary transport in a fluid phase during a “creep cavitation” process. The results indicate that the Anita Peridotite recrystallised and underwent rheological weakening at a constant strain rate, with strain distributed across the entire section. This widespread deformation caused rapid exhumation of the peridotite from the lithospheric mantle into the overlying arc crust. The massif therefore records multiple overprinting phases of deformation under mantle and crustal conditions associated with the rapid exhumation of a large orogenic peridotite.     

岩石扩散蠕变及其地质意义

总结了近十年来岩石扩散蠕变显微构造鉴别特征，研究方法的最新进展，矿物颗粒大小和流体（包括熔体和水）等是影响扩散蠕变的重要因素。扩散蠕变与位错蠕变和超塑性变形有密切关系，它的研究对大陆裂谷化过程，大陆碰撞带中岩石圈地幔强度弱化，中下地壳韧性剪切应变局限化以及与相变有关的矿物粒度细小化作用的分布有重要应用意义。     

Post-deformational annealing of calcite rocks

The evolution of microstructure and crystallographic preferred orientation (CPO) during post-deformational annealing was studied on three calcite rock types differing in purity and grain size: Carrara marble (98% calcite, mean grain size of 115 μm), Solnhofen limestone (96%, 5 μm) and synthetic calcite aggregates (99%, 7 μm). Samples were first deformed in torsion at 727 °C at a shear strain rate of 3 × 10^{− 4} s^{− 1} to a shear strain of 5 and subsequently heat-treated at 727 °C for various durations between 0 and 24 h. Microstructures and CPOs were analysed by optical microscopy, image analysis and electron backscatter diffraction (EBSD).All rock types deformed in the dislocation creep field at the same applied conditions, but their microstructures and CPOs after deformation and after annealing differed depending on starting grain size and material composition. In Carrara marble and in the synthetic calcite aggregate, a strong CPO developed during deformation accompanied by dynamic recrystallisation with significant changes in grain size. During annealing, widespread grain growth and subtle changes of CPO occurred, and equilibrated foam microstructures were approached after long annealing times. The CPO is the only feature in annealed samples indicating an earlier deformation phase, although it is not always identical to the CPO formed during deformation. In the more impure Solnhofen limestone, secondary phases on grain boundaries suppressed grain boundary mobility and prevented both the formation of a recrystallisation CPO during deformation and grain size modification during deformation and annealing.     

Dynamic recrystallization of wet synthetic polycrystalline halite: dependence of grain size distribution on flow stress, temperature and strain

It is often observed that dynamic recrystallization results in a recrystallized grain size distribution with a mean grain size that is inversely related to the flow stress. However, it is still open to discussion if theoretical models that underpin recrystallized grain size–stress relations offer a satisfactorily microphysical basis. The temperature dependence of recrystallized grain size, predicted by most of these models, is rarely observed, possibly because it is usually not systematically investigated. In this study, samples of wet halite containing >10 ppm water (by weight) were deformed in axial compression at 50 MPa confining pressure. The evolution of the recrystallized grain size distribution with strain was investigated using experiments achieving natural strains of 0.07, 0.12 and 0.25 at a strain rate of 5×10⁻⁷ s⁻¹ and a temperature of 125 °C. The stress and temperature dependence of recrystallized grain size was systematically investigated using experiments achieving fixed strains of 0.29–0.46 (and one to a strain of 0.68) at constant strain rates of 5×10⁻⁷–1×10⁻⁴ s⁻¹ and temperatures of 75–240 °C, yielding stresses of 7–22 MPa. The microstructures and full grain size distributions of all samples were analyzed. The results showed that deformation occurred by a combination of dislocation creep and solution-precipitation creep. Dynamic recrystallization occurred in all samples and was dominated by fluid assisted grain boundary migration. During deformation, grain boundary migration results in a competition between grain growth due to the removal of grains with high internal strain energy and grain size reduction due to grain dissection (i.e. moving boundaries that crosscut or consume parts of neighbouring grains). At steady state, grain growth and grain size reduction processes balance, yielding constant flow stress and recrystallized grain size that is inversely related to stress and temperature. Evaluation of the recrystallized grain size data against the different models for the development of mean steady state recrystallized grain size revealed that the data are best described by a model based on the hypothesis that recrystallized grain size organizes itself in the boundary between the (grain size sensitive) solution-precipitation and (grain size insensitive) dislocation creep fields. Application of a piezometer, calibrated using the recrystallized grain size data, to natural halite rock revealed that paleostresses can vary significantly with temperature (up to a factor of 2.5 for T=50–200 °C) and that the existing temperature independent recrystallized grain size–stress piezometer may significantly underestimate flow stresses in natural halite rock.     

Grain size reduction by dynamic recrystallization: can it result in major rheological weakening?

It is widely believed that grain size reduction by dynamic recrystallization can lead to major rheological weakening and associated strain localization by bringing about a switch from grain size insensitive dislocation creep to grain size sensitive diffusion creep. Recently, however, we advanced the hypothesis that, rather than a switch, dynamic recrystallization leads to a balance between grain size reduction and grain growth processes set up in the neighborhood of the boundary between the dislocation creep field and the diffusion creep field. In this paper, we compare the predictions implied by our hypothesis with those of other models for dynamic recrystallization. We also evaluate the full range of models against experimental data on a variety of materials. We conclude that a temperature dependence of the relationship between recrystallized grain size and flow stress cannot be neglected a priori. This should be taken into account when estimating natural flow stresses using experimentally calibrated recrystallized grain size piezometers. We also demonstrate experimental support for the field boundary hypothesis. This support implies that significant weakening by grain size reduction in localized shear zones is possible only if caused by a process other than dynamic recrystallization (such as syntectonic reaction or cataclasis) or if grain growth is inhibited.     

Microfabrics of calcite ultramylonites as records of coaxial and non-coaxial deformation kinematics: Examples from the Rocher de l'Yret shear zone (Western Alps)

Microfabrics were analysed in calcite mylonites from the rim of the Pelvoux massif (Western Alps, France). WNW-directed emplacement of the internal Penninic units onto the Dauphinois domain produced intense deformation of an Eocene-age nummulitic limestone under lower anchizone metamorphic conditions (slightly below 300 °C). Two types of microfabrics developed primarily by dislocation creep accompanied by dynamic recrystallisation in the absence of twinning. Coaxial kinematics are inferred for samples exhibiting grain shape fabrics and textures with orthorhombic symmetry. Their texture (crystallographic preferred orientation, CPO) is characterised by two c-axis maxima, symmetrically oriented at 15° from the normal to the macroscopic foliation. Non-coaxial deformation is evident in samples with monoclinic shape fabrics and textures characterised by a single oblique c-axis maximum tilted with the sense of shear by about 15°. From the analysis of suitably oriented slip systems for the main texture components under given kinematics it is inferred that the orthorhombic textures, which developed in coaxial kinematics, favour activity of <10–11> and <02–21> slip along the f and r planes, respectively, with minor contributions of basal-<a> slip. In contrast, the monoclinic textures, which developed during simple shear, are most suited for duplex <a> slip along the basal plane. The transition between the dominating slip systems for the orthorhombic and monoclinic microfabrics is interpreted to be due to the effects of dynamic recrystallisation upon texture development. Since oblique c-axis maxima documented in the literature are most often rotated not with but against the shear sense, calcite textures alone should not be used as unequivocal shear sense indicators, but need to be complemented by microstructural criteria such as shape preferred orientations, grain size estimates and amount of twinning.     

Strength and stability of frictional sliding of gabbro gouge at elevated temperatures

To investigate the strength of frictional sliding and stability of mafic lower crust, we conducted experiments on oven-dried gabbro gouge of 1 mm thick sandwiched between country rock pieces (with gouge inclined 35° to the sample axis) at slip rates of 1.22 × 10^− 3 mm/s and 1.22 × 10^− 4 mm/s and elevated temperatures up to 615 °C. Special attention has been paid to whether transition from velocity weakening to velocity strengthening occurs due to the elevation of temperature.Two series of experiments were conducted with normal stresses of 200 MPa and 300 MPa, respectively. For both normal stresses, the friction strengths are comparable at least up to 510 °C, with no significant weakening effect of increasing temperature. Comparison of our results with Byerlee's rule on a strike slip fault with a specific temperature profile in the Zhangbei region of North China shows that the strength given by experiments are around that given by Byerlee's rule and a little greater in the high temperature range.At 200 MPa normal stress, the steady-state rate dependence a − b shows only positive values, probably still in the “run-in” process where velocity strengthening is a common feature. With a normal stress of 300 MPa, the values of steady-state rate dependence decreases systematically with increasing temperature, and stick-slip occurred at 615 °C. Considering the limited displacement, limited normal stress applied and the effect of normal stress for the temperatures above 420 °C, it is inferred here that velocity weakening may be the typical behaviour at higher normal stress for temperature above 420 °C and at least up to 615 °C, which covers most of the temperature range in the lower crust of geologically stable continental interior. For a dry mafic lower crust in cool continental interiors where frictional sliding prevails over plastic flow, unstable slip nucleation may occur to generate earthquakes.     

Grain-size distribution and rheology of the upper mantle

The physical processes that govern the grain size of rocks in the upper mantle are examined. The analysis is based on the experimental data on creep, recrystallization, and grain growth in dunites and on a theoretical model for the thermomechanical structure of the cooling moving lithosphere. The grain size of rocks is shown to be determined by the in situ stress only at the deeper part where the temperature is high enough to allow significant strain rate. Above this depth, the microstructures record the thermomechanical history of rocks rather than the in situ stress.In the case of the oceanic lithosphere where the thermomechanical history is best known, the following features of grain-size distribution are found. At the uppermost mantle, where the amount of grain growth is limited, the grain size is determined by the initial value and the growth rate, and, where the effect of grain growth dominates, it increases with depth. When the amount of grain growth becomes large and the grain size reaches the steady state size corresponding to the ambient stress while the rock is hot enough to deform, the grain size is then determined by the applied stress. This grain size is, however, frozen, when the rock gets cool and the strain rate becomes too small to induce any further dynamic recrystallization. Thus, at the intermediate depth region, the grain size records the fossil (frozen) stress at which the microstructures of rock have been frozen. Since the frozen stress increases with age, the grain size in this depth interval decreases with depth. Finally, the grain size below this level reflects the in situ stress, and increases with depth, its extent being dependent on the nature of return flow in the deep mantle.Thus the grain size versus depth relation may show a sigmoid curve. The qualitative features of this curve may be similar also in the case of the continental lithosphere, if a similar thermal event (i.e., the intrusion of hot material and subsequent cooling) occurs. The results are quite consistent with the observed depth variation of olivine grain size in peridotite nodules (Avé Lallemant et al., 1980). The present model suggests that the depth of minimum grain size (65 and 150 km at the continental rift zone and the shield region respectively) corresponds to that where the mechanical properties of the upper mantle change from elastic to ductile at tectonic stress levels (~ 1 MPa) and in the geological time scale. This result leads to a new definition of the thickness of lithosphere in terms of its rheological properties. This thickness is about twice as large as that inferred from the flexure of lithosphere but approximately equal to seismic thickness. The model suggests the importance of grain growth as well as dynamic recrystallization and plastic flow in determining the texture of upper mantle rocks and therefore seismic anisotropy.     

A very hydrous mantle under the western Pacific region: Implications for formation of marginal basins and style of Archean plate tectonics

The western Pacific region has been refrigerated by the subducting cold oceanic plates since 450 Ma. However, the region is also characterized by the presence of many oceanic microplates less than 1300 km across, as well as active magmatism; the Philippine Sea plate is representative. We have compiled and examined petrochemical characters of drilled basalts of DSDP from the Philippine Sea plate, and conclude that the source mantle for oceanic basalts is rich in water ca. 0.2 wt.%, and is 50–60 °C lower than that for MORB. The extensive melting is due to the high water content in the source mantle.It is well known that some marginal basins apparently have greater depths than the major oceans. We calculated the age–depth correlation based on a model of transient half-space cooling at given parameters of temperatures of mantle and surface, 1280 and 0 °C, and the thermal diffusivity, 1 mm² s^− 1. The calculation shows the correlation of age-residual depth from a mid-oceanic ridge is 367 for the Philippine Sea, consistent with the bathymetric data. Moreover, the mid-oceanic ridge may be relatively deep because this region is underlain by the cooler mantle.Addition of water to the mantle peridotite lowers the solidus temperature and viscosity. Melting experiments of hydrous peridotite show that addition of 0.2 wt.% H₂O content lowers the solidus temperature by 150 °C. As a result, the mantle under the region may practically correspond to a ca. 90 °C hotter mantle than normal MORB-source mantle in terms of magmatism and rheology. Numerical simulation for a hotter mantle suggests that many small plates should be formed because of extensive heat release by active magmatism, consistent with many microplates in this region. The presence of many oceanic microplates may be analogous to Archean plate tectonics, characterized by a hotter mantle.     

Large-strain deformation and strain partitioning in polyphase rocks: Dislocation creep of olivine–magnesiowüstite aggregates

Aggregates composed of olivine and magnesiowüstite have been deformed to large strains at high pressure and temperature to investigate stress and strain partitioning, phase segregation and possible localization of deformation in a polyphase material. Samples with 20 vol.% of natural olivine and 80 vol.% of (Mg_0.7Fe_0.3)O were synthesized and deformed in a gas-medium torsion apparatus at temperatures of 1127 °C and 1250 °C, a confining pressure of 300 MPa and constant angular displacement rates equivalent to constant shear strain rates of 1–3.3 × 10^− 4 s^− 1. The samples deformed homogeneously to total shear strains of up to γ  15. During constant strain rate measurements the flow stress remained approximately stable at 1250 °C while it progressively decreased after the initial yield stress at the lower temperature. Mechanical data, microstructures and textures indicate that both phases were deforming in the dislocation creep regime. The weaker component, magnesiowüstite, controlled the rheological behavior of the bulk material and accommodated most of the strain. Deformation and dynamic recrystallization lead to grain refinement and to textures that were not previously observed in pure magnesiowüstite and may have developed due to the presence of the second phase. At 1127 °C, olivine grains behaved as semi-rigid inclusions rotating in a viscous matrix. At 1250 °C, some olivine grains remained largely undeformed while deformation and recrystallization of other grains oriented for a-slip on (010) resulted in a weak foliation and a texture typical for pure dry olivine aggregates. Both a-slip and c-slip on (010) were activated in olivine even though the nominal stresses were up to 2 orders of magnitude lower than those needed to activate these slip systems in pure olivine at the same conditions.     

Dynamic recrystallization near the brittle-plastic transition in naturally and experimentally deformed quartz aggregates

The electron backscattering diffraction technique (EBSD) was used to analyze bulging recrystallization microstructures from naturally and experimentally deformed quartz aggregates, both of which are characterized by porphyroclasts with finely serrated grain boundaries and grain boundary bulges set in a matrix of very fine recrystallized grains. For the Tonale mylonites we investigated, a temperature range of 300–380 °C, 0.25 GPa confining pressure, a flow stress range of ~ 0.1–0.2 GPa, and a strain rate of ~ 10^− 13 s^− 1 were estimated. Experimental samples of Black Hills quartzite were analyzed, which had been deformed in axial compression at 700 °C, 1.2–1.5 GPa confining pressure, a flow stress of ~ 0.3–0.4 GPa, a strain rate of ~ 10^− 6 s^− 1, and to 44% to 73% axial shortening. Using orientation imaging we investigated the dynamic recrystallization microstructures and discuss which processes may contribute to their development. Our results suggest that several deformation processes are important for the dismantling of the porphyroclasts and the formation of recrystallized grains. Grain boundary bulges are not only formed by local grain boundary migration, but they also display a lattice misorientation indicative of subgrain rotation. Dynamic recrystallization affects especially the rims of host porphyroclasts with a hard orientation, i.e. with an orientation unsuitable for easy basal slip. In addition, Dauphiné twins within porphyroclasts are preferred sites for recrystallization. We interpret large misorientation angles in the experimental samples, which increase with increasing strain, as formed by the activity of fluid-assisted grain boundary sliding.     

A fission-track and (U–Th)/He thermochronometric study of the northern margin of the South China Sea: An example of a complex passive margin

Zircon fission track (ZFT), apatite fission track (AFT) and (U–Th)/He thermochronometric data are used to reconstruct the Cenozoic exhumation history of the South China continental margin. A south to north sample transect from coast to continental interior yielded ZFT ages between 116.6 ± 4.7 Ma and 87.3 ± 4.0, indicating that by the Late Cretaceous samples were at depths of 5–6 km in the upper crust. Apatite FT ages range between 60.9 ± 3.6 and 37.3 ± 2.3 Ma with mean track lengths between 13.26 ± 0.16 µm and 13.95 ± 0.19 µm whilst AHe ages are marginally younger 47.5 ± 1.9–15.3 ± 0.5 Ma. These results show the sampled rocks resided in the top 1–1.5 km of the crust for most of the Cenozoic. Thermal history modeling of the combined FT and (U–Th)/He datasets reveal a common three stage cooling history which differed systematically in timing inland away from the rifted margin. 1) Initial phase of rapid cooling that youngs to the north, 2) a period of relative (but not perfect) thermal stasis at ~ 70–60 °C which increases in duration from the south to the north; 3) final-stage cooling to surface temperatures that initiated in all samples between 15 and 10 Ma. The timing and pattern of rock uplift and erosion does not fit with conventional passive margin landscape models that require youngest exhumation ages to be concentrated at or close to the rifted margin. The history of South China margin is more complex aided by weakened crust from the active margin period that immediately preceded rifting and opening of the South China Sea. This rheological inheritance created a transition zone of steeply thinned crust that served as a flexural filter disconnecting the northern margin of the South China block and site of active rifting to the south. Consequently whilst the South China margin displays many features of a rifted continental margin its exhumation history does not conform to conventional images of a passive margin.     

The transition between deformation regimes dominated by intercrystalline diffusion and intracrystalline creep evaluated by oxygen isotope thermometry

The dominant flow mechanism in tectonic processes depends on the rheological properties of geological materials and the physical conditions prevailing during deformation. We have evaluated the relative importance of intercrystalline diffusion and intracrystalline creep in crustal deformation in terms of temperature and grain size.Oxygen isotope thermometry has been used to elucidate the thermal environment obtaining during deformation and contemporaneous metamorphism of Dalradian rocks from Southwest Scotland. The temperature and grain size data, applied in conjunction with microstructural criteria for evaluating independent mechanisms of steady-state flow, allow recognition of a low-temperature deformation regime dominated by intercrystalline diffusion, and a high-temperature regime dominated by dislocation processes.The transition between the fields of intercrystalline diffusion and dislocation creep for quartz and calcite of 100 Mm grain size occurs at about 450° C and about 300° C, respectively. These empirically derived results are consistent with the temperature intervals over which intercrystalline diffusion and dislocation creep, respectively, are predicted to be dominant at geologically reasonable strain rates, as derived from theoretically formulated deformation mechanism maps for quartz and calcite.Grain growth may play an important role in delimiting the higher-temperature boundary of the intercrystalline diffusion field. Intercrystalline diffusion is the only deformation mechanism that involves mass transfer over distances that are large in relation to the grain size. This result has important consequences for geochemical transport phenomena.     

Influence of the precollisional stage on subduction dynamics and the buried crust thermal state: Insights from numerical simulations

At continental subduction initiation, the continental crust buoyancy may induce, first, a convergence slowdown, and second, a compressive stress increase that could lead to the forearc lithosphere rupture. Both processes could influence the slab surface P–T conditions, favoring on one side crust partial melting or on the opposite the formation of ultra-high pressure/low temperature (UHP-LT) mineral. We quantify these two effects by performing numerical simulations of subduction. Water transfers are computed as a function of slab dehydration/overlying mantle hydration reactions, and a strength decrease is imposed for hydrated mantle rocks. The model starts with an old oceanic plate ( 100 Ma) subducting for 145.5 Myr with a 5 cm/yr convergence rate. The arc lithosphere is thermally thinned between 100 km and 310 km away from the trench, due to small-scale convection occuring in the water-saturated mantle wedge. We test the influence of convergence slowdown by carrying on subduction with a decreased convergence rate (≤ 2 cm/yr). Surprisingly, the subduction slowdown yields not only a strong slab warming at great depth (> 80 km), but also a significant cooling of the forearc lithosphere at shallower depth. The convergence slowdown increases the subducted crust temperature at 90 km depth to 705 ± 62 °C, depending on the convergence rate reduction, and might thus favor the oceanic crust partial melting in presence of water. For subduction velocities ≤ 1 cm/yr, slab breakoff is triggered 20–32 Myr after slowdown onset, due to a drastic slab thermal weakening in the vicinity of the interplate plane base. At last, the rupture of the weakened forearc is simulated by imposing in the thinnest part of the overlying lithosphere a dipping weakness plane. For convergence with rates ≥ 1 cm/yr, the thinned forearc first shortens, then starts subducting along the slab surface. The forearc lithosphere subduction stops the slab surface warming by hot asthenosphere corner flow, and decreases in a first stage the slab surface temperature to 630 ± 20 °C at 80 km depth, in agreement with P–T range inferred from natural records of UHP-LT metamorphism. The subducted crust temperature is further reduced to 405 ± 10 °C for the crust directly buried below the subducting forearc. Such a cold thermal state at great depth has never been sampled in collision zones, suggesting that forearc subduction might not be always required to explain UHP-LT metamorphsim.     

Continental rifting as a function of lithosphere mantle strength

The role of the uppermost mantle strength in the pattern of lithosphere rifting is investigated using a thermo-mechanical finite-element code. In the lithosphere, the mantle/crust strength ratio (S_M/S_C) that decreases with increasing Moho temperature T_M allows two strength regimes to be defined: mantle dominated (S_M > S_C) and crust dominated (S_M < S_C). The transition between the two regimes corresponds to the disappearance of a high strength uppermost mantle for T_M > 700 °C. 2D numerical simulations for different values of S_M/S_C show how the uppermost mantle strength controls the style of continental rifting. A high strength mantle leads to strain localisation at lithosphere scale, with two main patterns of narrow rifting: “coupled crust–mantle” at the lowest T_M values and “deep crustal décollement” for increasing T_M values, typical of some continental rifts and non-volcanic passive margins. The absence of a high strength mantle leads to distributed deformations and wide rifting in the upper crust. These numerical results are compared and discussed in relation with series of classical rift examples.