Relation between mantle shear zone deformation and metasomatism in spinel peridotite xenoliths of Jeju Island (South Korea): Evidence from olivine CPO and trace elements

This study presents geochemical and fabric analysis of coarse-grained, porphyroclastic and mylonitic spinel peridotite xenoliths derived from the shallow subcontinental lithospheric mantle of Jeju Island (South Korea). Fabric analysis of olivines in the studied peridotites shows activation of the high temperature (0 1 0)[1 0 0] slip system; however, in the porphyroclastic and mylonitic peridotites, activation of (0 k l)[1 0 0] slip system results in a weaker fabric. Formation of porphyroclastic and mylonitic fabrics are thought to form in a shear-dominated environment. The results of the trace element analysis reveal that the smaller the grain size and weaker the fabric, the more enriched in LREE and HFSE are the peridotites, which indicates a strong relationship between metasomatic agents and mantle shear zones.     

伊通地堑上地幔剪切带

通过研究糜棱岩型幔源包体的变形显微构造、位错亚构造及组构特征，确定它是上地幔剪切带的代表物质。该带形成温度为７２９～８２８℃、压力为１．１０～１．３８ＧＰａ、差异应力为９７～１５０ＭＰａ、应变速率为ＩＯ￣（－１４）～１Ｏ￣（－１２）ｓ￣（－１）、等效粘滞度为１０～１０００ＥＰａ·ｓ和深度为３７～４５ｋｍ。这是一种与地幔底辟作用有关的规模较小的缓倾斜剪切带，也是应变集中带，能导致上地幔地震波速各向异性，并与地震活动有关     

The Fluid Dynamics of Solid Mechanical Shear Zones

Shear zones in outcrops and core drillings on active faults commonly reveal two scales of localization, with centimeter to tens of meters thick deformation zones embedding much narrower zones of mm-scale to cm-scale. The narrow zones are often attributed to some form of fast instability such as earthquakes or slow slip events. Surprisingly, the double localisation phenomenon seem to be independent of the mode of failure, as it is observed in brittle cataclastic fault zones as well as ductile mylonitic shear zones. In both, a very thin layer of chemically altered, ultra fine grained ultracataclasite or ultramylonite is noted. We present an extension to the classical solid mechanical theory where both length scales emerge as part of the same evolutionary process of shearing the host rock. We highlight the important role of any type of solid-fluid phase transitions that govern the second degree localisation process in the core of the shear zone. In both brittle and ductile shear zones, chemistry stops the localisation process caused by a multiphysics feedback loop leading to an unstable slip. The microstructural evolutionary processes govern the time-scale of the transition between slow background shear and fast, intermittent instabilities in the fault zone core. The fast cataclastic fragmentation processes are limiting the rates of forming the ultracataclasites in the brittle domain, while the slow dynamic recrystallisation prolongs the transition to ultramylonites into a slow slip instability in the ductile realm.     

Melt-filled hybrid fractures in the oceanic mantle: Melt enhanced deformation during along-axis flow beneath a propagating spreading ridge axis

Mid-ocean ridges represent important locations for understanding the interactions between deformation and melt production, transport, and emplacement. Melt transport through the mantle beneath mid-ocean ridges is closely associated with deformation. Currently recognized transport and emplacement processes at ridges include: 1) dikes and sills filling stress-controlled fractures, 2) porous flow in a divergent flow field, 3) self-organizing porous dunite channels, and 4) shear zones. Our recent observations from the sub-oceanic mantle beneath a propagating ridge axis in the Oman ophiolite show that gabbronorite and olivine gabbro dikes fill hybrid fractures that show both shear and extensional components of strain. The magnitudes of shear strain recorded by the dikes are significant and comparable to the longitudinal extensions across the dikes. We suggest that the hybrid dikes form from the interactions between shear deformation and pressurized melt in regions of along-axis flow at mid-ocean ridges. The displacement across the dikes is kinematically compatible with high temperature flow recorded by plastic fabrics in host peridotites. Field observations and mechanical considerations indicate that the dikes record conditions of higher stress and lower temperature than those recorded by the plastic flow fabrics. The features of hybrid dikes suggest formation during progressive deformation as conditions changed from penetrative plastic flow to strain localization along melt-filled fractures. The combined dataset indicates that the dikes are formed during along-axis flow away from regions of diapiric upwelling at propagating ridge segments. Hybrid dikes provide a potentially powerful kinematic indicator and strain recorder and define a previously unrecognized mechanism of melt migration. Our calculations show that hybrid dikes require less melt pressure to form than purely tensile dikes and thus may provide a mechanism to tap melt reservoirs that are under-pressurized with respect to lithostatic pressure.     

Strain localisation in bimineralic rocks: Experimental deformation of synthetic calcite–anhydrite aggregates

Deformation of synthetic calcite–anhydrite aggregates to large shear strains (up to γ = 12.4 at 600 °C, 300 MPa confining pressure and a constant angular displacement rate corresponding to a shear strain rate of 10^− 3 s^− 1) resulted in the first experimental observation of strain localisation from initially homogeneous rocks. In contrast to experiments on pure calcite and anhydrite, which deformed homogeneously to large strains (γ ≥ 5), all experiments on calcite–anhydrite mixtures resulted in heterogeneous deformation at γ > 1 and the formation of narrow localised bands in the microstructures at γ > 4. In these bands, the amount of strain is at least twice as large as in the rest of the sample and individual grains of the same phase cluster and align, thereby forming microstructural layering similar to planar fabrics in natural mylonites. A switch in deformation mechanism in anhydrite from dislocation creep to diffusion creep and/or grain boundary sliding occurs simultaneously with strain localisation. It is concluded that deformation-induced heterogeneous phase distributions cause local strength differences initiating strain localisation in the calcite–anhydrite mixtures. The study suggests that the presence of two phases in combination with a change in deformation mechanism may be responsible for strain localisation in natural poly-mineralic mylonites.     

Fluid infiltration into fault zones: Chemical,isotopic, and mechanical effects

Fluid infiltration into fault zones and their deeper-level counterparts, brittle-ductile shear zones, is examined in diverse tectonic environments. In the 2.7 Ga Abitibi greenstone belt, major tectonic discontinuities, with lateral extents of hundreds of kilometres initiated as listric normal faults accommodating rift extension and acted as sites for komatiite extrusion and locally intense metasomatism. During reverse motion on the structures, accommodating shortening of the belt, these transcrustal faults were utilised as a conduit for the ascent of trondhjemitic magmas from the base of the crust and of alkaline magmas from the asthenosphere and for the discharge of thousands of cubic kilometres of hydrothermal fluids. Such fluids were characterised by ¹⁸O=+6±2, D=–50±20, ¹³C=–4±4, and temperatures of 270 to 450°C, probably derived from devolatilisation of crustal rocks undergoing prograde metamorphism. Hydrothermal fluids were more radiogenic (⁸⁷Sr/⁸⁶Sr=0.7010 to 0.7040) and possessed higher than did contemporaneous mantle, komatiites or tholeiites, and thus carried a contribution from older sialic basement. A provinciality of⁸⁷Sr/⁸⁶Sr and ¹³C is evident, signifying that fault plumbing sampled lower crust which was heterogeneous at the scale of tens of kilometres. Mineralised faults possess enrichments of large ion lithophile (LIL), LIL elements, including K, Rb, Ba, Cs, B, and CO₂, and rare elements, such as Au, Ag, As, Sb, Se, Te, Bi, and W. Fluids were characterised by X_{CO 2}0.1, neutral to slightly acidic pH, low salinity 3 wt-%, K/Na=0.1, they carried minor CH₄, CO, and N₂, and they underwent transient effervescence of CO₂ during decompression. Clastic sediments occupy graben developed at fault flexures. The⁴⁰Ar/³⁹Ar release spectra indicate that fault rocks experienced episodic disturbance on time scales of hundreds of millions of years.At the Grenville front, translation was accommodated along two mylonite zones and an intervening boundary fault. The high-temperature (580°C) and low-temperature (430 to 490°C) mylonite zones, formed in the presence of deep-level crust-equilibrated fluids of metamorphic origin. Late brittle faults contain quartz veins precipitated from fluids with extemely negative ¹⁸O (–14 per mil) at 200 to 300°C. The water may have been derived from downward penetration into fault zones of precipitation of low¹⁸O on a mountain range induced by continental collision, with uplift accommodated at deep levels by the mylonite zones coupled with rebound on the boundary faults.Archean gneisses overlie Proterozoic sediments along thrust surfaces at Lagoa Real, Brazil; the gneisses are transected by brittle-ductile shear zones locally occupied by uranium deposits. Following deformation at 500 to 540°C, in the presence of metamorphic fluids and under conditions of low water-to-rock ratio, shear zones underwent local intense oxidation and desilication. All minerals undergo a shift of –10 per mil, indicating discharge of meteoric-water-recharged formation brines in the underlying Proterozoic sediments up through the Archean gneisses, during overthrusting; 1000 km³ of solutions passed through these structures. The shear zones and Proterozoic sediments are less radiogenic (⁸⁷Sr/⁸⁶Sr=0.720) than contemporaneous Archean gneisses (0.900), corroborating the transport of fluids and solutes through the structure from a large external reservoir.Major crustal detachment faults of Tertiary age in the Picacho Cordilleran metamorphic core complex of Arizona show an upward transition from undeformed granitic basement through mylonitic to brecciated and hydrothermally altered counterparts. The highest tectonic levels are allochthonous, oxidatively altered Miocene volcanics. This transition is accompanied by an increase of 12 per mil in ¹⁸O, from +7 to +19, and a 400°C decrease in temperature. Lower tectonic levels acted as aquifers for the expulsion of large volumes of higher-temperature reduced metamorphic fluids and/or evolved formation brines. The Miocene allochthon was influenced by a lower-temperature reservoir inducing oxidative potassic alteration; mixing occurred between cool downward-penetrating thermal waters and the hot, deeper aqueous reservoir.In general, flow regimes in these fault and shear zones follow a sequence, from conditions of high temperature and pressure with locally derived fluids at low water-to-rock ratios, during initiation of the structures, to high fluxes of reduced formation or metamorphic fluids along conduits as the structures propagate and intersect hydrothermal reservoirs. Later in the tectonic evolution and at shallower crustal levels there was incursion of oxidising fluids from near-surface reservoirs into the faults. In general, magmatism, tectonics, and fluid motion are intimately related.     

Amphibolitized sheared gabbros from ophiolites as indicators of the evolution of the oceanic crust: Bay of Islands,Newfoundland

In the Bay of Islands ophiolite complex both the basal part of the cumulate gabbro sequence and the underlying peridotites have been plastically deformed. Higher in the series the cumulate gabbros are undeformed except in localized shear zones slightly to strongly oblique to the layering. The resulting shear bands are narrow and composed either of mylonitic amphibole-bearing gabbros or of highly foliated amphibolites.The amphibole composition and nature, and the chemistry of coexisting minerals combined with structural evidence imply that a first episode of shearing subhorizontal in the crust occurred at decreasing temperatures ranging from 750 to 450°C. This shearing probably represent the response of the lithosphere to stresses also responsible of asthenospheric flow in the upper mantle. A second episode of shearing oblique to the first one and probably related to cooling of the crust away from the ridge, occurred at lower temperatures ranging from 500 to 300°C. The surrounding gabbros have undergone static hydrothermal metamorphism at temperatures decreasing from 650 to 450°C. All metamorphic events occurred in hydrous conditions in the vicinity of the ridge axis.     

Subduction-zone peridotites and their records of crust-mantle interaction

Subduction is the core process of plate tectonics. The mantle wedge in subduction-zone systems represents a key tectonic unit, playing a significant role in material cycling and energy exchange between Earth's layers. This study summarizes research progresses in terms of subduction-related peridotite massifs, including supra-subduction zone(SSZ) ophiolites and mantle-wedge-type(MWT) orogenic peridotites. We also provide the relevant key scientific questions that need be solved in the future. The mantle sections of SSZ ophiolites and MWT orogenic peridotites represent the mantle fragments from oceanic and continental lithosphere in subduction zones, respectively. They are essential targets to study the crust-mantle interaction in subduction zones. The nature of this interaction is the complex chemical exchanges between the subducting slab and the mantle wedge under the major control of physical processes. The SSZ ophiolites can record melt/fluid-rock interaction, metamorphism,deformation, concentration of metallogenic elements and material exchange between crust and mantle, during the stages from the generation of oceanic lithosphere at spreading centers to the initiation, development, maturation and ending of oceanic subduction at continental margins. The MWT orogenic peridotites reveal the history of strong metamorphism and deformation during subduction, the multiple melt/fluid metasomatism(including silicatic melts, carbonatitic melts and silicate-bearing C-HO fluids/supercritical fluids), and the complex cycling of crust-mantle materials, during the subduction/collision and exhumation of continental plates. In order to further reveal the crust-mantle interaction using subduction-zone peridotites, it is necessary to utilize high-spatial-resolution and high-precision techniques to constrain the complex chemical metasomatism, metamorphism,deformation at micro scales, and to reveal their connections with spatial-temporal evolution in macro-scale tectonics.     

Variations in the distribution of magma in the lower crust and at the Moho beneath the East Pacific Rise at 9°-10°N

Measurements of the seafloor deformation under ocean waves (compliance) reveal an asymmetric lower crustal partial melt zone (shear velocity less than 1.8 km/s) beneath the East Pacific Rise axis between 9° and 10°N. At 9°48′N, the zone is less than 8 km wide and is centered beneath the rise axis. The zone shifts west of the rise axis as the rise approaches the westward-stepping 9°N overlapping spreading center discontinuity and is anomalously wide at the northern tip of the discontinuity. The ratio of the compliance determined shear velocity to the compressional velocities (estimated by seismic tomography) suggests that the melt is well-connected in high-aspect ratio cracks rather than in isolated sills. The shear and compressional velocities indicate less than 18% melt in the lower crust on average. The compliance measurements also reveal a separate lower crustal partial melt zone 10 km east of the rise axis at 9°48′N and isolated melt bodies near the Moho beneath four of the 39 measurement sites (three on-axis and one off-axis). The offset of the central melt zone from the rise axis correlates strongly with the offset of the overlying axial melt lens and the inferred center of mantle melting, but its shape appears to be controlled by crustal processes.     

Correlated Crust and Mantle Strain Field in China

INTRODUCTION Moststudiesonactiveblockshavebeenfocusedonidentificationofblockboundariesandtheiractivity;inotherwords,mostoftheworkwaslimitedtothehorizontalmovementoftheblocks.Inreality,theblocksarenotonlysurroundedbyactivefaultsofhorizontalmotion,butalsoco…     

CRYSTALLOGRAPHIC PREFERRED ORIENTATION(CPO) OF ANISOTROPIC MINERALS IN THE LITHOSPHERE AND ITS SIGNIFICANCE TO THE STUDY OFLITHOSPHERE DYNAMICS

Seismic anisotropy has been widely used to constrain deformation and mantle flow within the upper mantle of the Earth's interior, and is mainly affected by crystallographic preferred orientation(CPO)of anisotropic mineral in lithosphere. Anisotropy of peridotites caused by deformation is the main source of seismic anisotropy in the upper mantle. Olivine is the most abundant and easily deformed mineral to form CPO in peridotite, thus the CPO of olivine controls seismic anisotropy in the upper mantle. Based on simple shear experiments and studies of natural peridotites deformation, several CPO types of olivine have been identified, including A, B, C, D, E and AG-type. Studies on the deformation of olivine have shown that the CPO of olivine is mainly related to stress, water content, temperature, pressure, partial melting and melt/fluid percolation. Most of the seismic anisotropy has been explained by the A-type olivine CPO in the upper mantle, which is commonly found in upper-mantle peridotites and produced by the simple shear in dry conditions. Previous studies showed that anisotropy was attributed to the CPO of mica and amphibole in the middle-lower crust. The comparison between mantle anisotropy calculated from mineral CPO and regional anisotropy deduced from geophysical methods is therefore particularly useful for interpreting the deformation mechanisms and geodynamic processes which affect the upper mantle in different tectonic units such as subduction system, continental rift and continental collision zone in the world. The paper summarizes the characteristics of CPO and anisotropy of major anisotropic minerals in the upper mantle. Taking the lithosphere mantle xenoliths in the southeastern Tibetan plateau as an example, we perform detailed studies on the microstructures and seismic anisotropy to better understand the deformation mechanisms and upper mantle anisotropy in this region. Results show that the CPO of olivine in peridotite xenoliths in southeastern Tibetan plateau are A-type and AG-type. The mechanisms proposed for the formation of AG-type are different from that for the A-type. Therefore, the occurrence of AG-type olivine CPO pattern suggests that this CPO may record a change in deformation mechanism and tectonic environment of the lithosphere in southeastern Tibetan plateau. Provided that the strong SKS(shear wave splitting)observed in southeastern Tibetan plateau results from lithosphere mantle, the lithosphere mantle in this region is expected to be at least 130km thick and characterized by vertical foliation. Considering that the thickness of lithosphere in southeastern Tibetan plateau is much less than 130km and the lithosphere mantle cannot explain the anisotropy measured by SKS, other anisotropy sources should be considered, such as anisotropy in the asthenosphere and the oriented melt pockets(MPO)in the upper mantle. Therefore, detailed study of CPO of anisotropic mineral is essential for constraining geophysical measurements and analyzing the dynamic process of the lithosphere reasonably.     

Grain growth in the forsterite-diopside system

Grain growth experiments in dunite, clinopyroxenite, and wehrlites with various forsterite/diopside ratios were performed to investigate the effect of modal composition on grain growth kinetics in the Earth's uppermost mantle. The experiments were conducted using a piston-cylinder apparatus at 1200 °C and 1.2 GPa for 2-763 h under dry conditions. Normal grain growth (NGG) occurred in dunite, clinopyroxenite, and relatively forsterite-poor wehrlites (≤70 vol.% of forsterite). Grain growth rates of forsterite and diopside in relatively forsterite-poor wehrlites were much slower than those in dunite and clinopyroxenite. In the forsterite-rich wehrlites (≥80 vol.% of forsterite), NGG of diopside and abnormal grain growth (AGG) of forsterite occurred. The growth rate of diopside was significantly slower than that in clinopyroxenite, while the growth rate of forsterite by AGG was found to be similar to that by NGG in dunite. The presence of ≤20 vol.% diopside had the effect of inhibiting the forsterite grain growth during the initial stage, resulting in AGG of forsterite, thus overtaking the growth rate in dunite. Our experimental results suggest that there would be a significant difference in grain growth rate and consequently in effective viscosity between olivine-rich peridotites (depleted mantle) and relatively olivine-poor peridotites (fertile mantle) in the case of grain size-sensitive creep. Variation of mean grain sizes in the upper mantle would result not only from differences in temperature and phase assemblage, but also from the variation of modal compositions.     

Thermally induced brittle deformation in oceanic lithosphere and the spacing of fracture zones

Brittle deformation of oceanic lithosphere due to thermal stress is explored with a numerical model, with an emphasis on the spacing of fracture zones. Brittle deformation is represented by localized plastic strain within a material having an elasto-visco-plastic rheology with strain softening. We show that crustal thickness, creep strength, and the rule governing plastic flow control the formation of cracks. The spacing of primary crack decreases with crustal thickness as long as it is smaller than a threshold value. Creep strength shifts the threshold such that crust with strong creep strength develops primary cracks regardless of crustal thicknesses, while only a thin crust can have primary cracks if its creep strength is low. For a thin crust, the spacing of primary cracks is inversely proportional to the creep strength, suggesting that creep strength might independently contribute to the degree of brittle deformation. Through finite versus zero dilatation in plastic strain, associated and non-associated flow rule results in nearly vertical and V-shaped cracks, respectively. Changes in the tectonic environment of a ridge system can be reflected in variation in crustal thickness, and thus related to brittle deformation. The fracture zone-free Reykjanes ridge is known to have a uniformly thick crust. The Australian-Antarctic Discordance has multiple fracture zones and thin crust. These syntheses are consistent with enhanced brittle deformation of oceanic lithosphere when the crust is thin and vice versa.     

Relicts of deformed lithospheric mantle within serpentinites and weathered peridotites from the Godzilla Megamullion,Parece Vela Back‐arc Basin,Philippine Sea

Relicts of deformed lithospheric mantle have been identified within serpentinites and weathered peridotites recovered from nine dredge sites and one submersible dive site from across the Godzilla Megamullion, which was emplaced at the now‐extinct Parece Vela Rift in the Parece Vela Basin, a back‐arc basin in the Philippine Sea. The serpentinites consist dominantly of lizardite ± chrysotile and magnetite with minor relict primary minerals that include pyroxene, spinel, and rare olivine. The weathered peridotites consist of pyroxene, spinel, lizardite ± chrysotile, and magnetite as well as weathering products of olivine. These rocks were classified in hand specimen into three types with different structures: massive, foliated, and mylonitic. In thin‐section the serpentine minerals show no sign of deformation, whereas relict primary minerals show evidence of plastic deformation such as undulose extinction, kink bands, dynamic recrystallization, and weak to moderate crystallographic preferred orientations. Therefore, the serpentinites and weathered peridotites result from the static replacement and weathering of previously ductile‐deformed peridotite. Given their location close to or on the detachment surface that exposed them, the relicts of peridotite provide evidence of deformation in the lithospheric mantle that could be related to the formation and emplacement of the Godzilla Megamullion in the Parece Vela Rift.     

Shallow seismicity, stress distribution and crustal deformation pattern in the Andaman-West Sunda arc and Andaman Sea, northeastern Indian Ocean

Shallow seismicity and available source mechanisms in the Andaman–westSunda arc and Andaman sea region suggest distinct variation in stressdistribution pattern both along and across the arc in the overriding plate.Seismotectonic regionalisation indicates that the region could be dividedinto eight broad seismogenic sources of relatively homogeneousdeformation. Crustal deformation rates have been determined for each oneof these sources based on the summation of moment tensors. The analysisshowed that the entire fore arc region is dominated by compressive stresseswith compression in a mean direction of N23^°, and the rates ofseismic deformation velocities in this belt decrease northward from 5.2± 0.65 mm/yr near Nias island off Sumatra and 1.12 ±0.13 mm/yr near Great Nicobar islands to as much as 0.4 ±0.04 mm/yr north of 8^°N along Andaman–Nicobar islandsregion. The deformation velocities indicate, extension of 0.83 ±0.05 mm/yr along N343^° and compression of 0.19 ±0.01 mm/yr along N73^° in the Andaman back arc spreadingregion, extension of 0.18 ± 0.01 mm/yr along N125^° andcompression of 0.16 ± 0.01 mm/yr along N35^° in NicobarDeep and west Andaman fault zone, compression of 0.84 ±0.12 mm/yr N341^° and extension of 0.77 ± 0.11 mm/yralong N72^° within the transverse tectonic zone in the Andamantrench, N-S compression of 3.19 ± 0.29 mm/yr and an E-Wextension of 1.24 ± 0.11 mm/yr in the Semangko fault zone ofnorth Sumatra. The vertical deformation suggests crustal thinning in theAndaman sea and crustal thickening in the fore arc and Semangko faultzones. The apparent stresses calculated for all major events range between0.1–10 bars and the values increase with increasing seismic moment.However, the apparent stress estimates neither indicate any significantvariation with faulting type nor display any variation across the arc, incontrast to the general observation that the fore arc thrust events showhigher stress levels in the shallow subduction zones. It is inferred that theoblique plate convergence, partial subduction of 90^°E Ridge innorth below the Andaman trench and the active back arc spreading are themain contributing factors for the observed stress field within the overridingplate in this region.     

Development of faults as zones of deformation bands and as slip surfaces in sandstone

Three forms of fault are recognized in Entrada and Navajo Sandstones in the San Rafael Desert, southeastern Utah; deformation bands, zones of deformation bands, and slip surfaces. Small faults occur asdeformation bands, about one millimeter thick, in which pores collapse and sand grains fracture, and along which there are shear displacements on the order of a few millimeters or centimeters. Two or more deformation bands adjacent to each other, which share the same average strike and dip, form azone of deformation bands. A zone becomes thicker by addition of new bands, side by side. Displacement across a zone is the sum of displacements on each individual band. The thickest zones are about 0.5 m and total displacement across a thick zone rarely exceeds 30 cm. Finally,slip surfaces, which are through-going surfaces of discontinuity in displacement, form at either edge of zones of highly concentrated deformation bands. In contrast with individual deformation bands and zones of deformation bands, slip surfaces accommodate large displacements, on the order of several meters in the San Rafael Desert.The sequence of development is from individual deformation bands, to zones, to slip surfaces, and each type of faulting apparently is controlled by somewhat different processes. The formation of zones apparently involves strain hardening, whereas the formation of slip surfaces probably involves strain softening of crushed sandstone.     

Seismic Anisotropy in the Deep Mantle, Boundary Layers and the Geometry of Mantle Convection

—An attempt is made to explore the geodynamical significance of seismic anisotropy in the deep mantle on the basis of mineral physics. The mineral physics observations used include the effects of deformation mechanisms on lattice and shape preferred orientation, the effects of pressure on elastic anisotropy and the nature of lattice preferred orientation in deep mantle minerals in dislocation creep regime. Many of these issues are still poorly constrained, but a review of recent results shows that it is possible to interpret deep mantle seismic anisotropy in a unified fashion, based on the solid state processes without invoking partial melting. The key notions are (i) the likely regional variation in the magnitude of anisotropy as deformation mechanisms change from dislocation to diffusion creep (or superplasticity), associated with a change in the stress level and/or grain-size in the convecting mantle with a high Rayleigh number, and (ii) the change in elastic anisotropy with pressure in major mantle minerals, particularly in (Mg, Fe)O. The results provide the following constraints on the style of mantle convection (i) the SH > SV anisotropy in the bottom transition zone and the SV > SH anisotropy in the top lower mantle can be attributed to anisotropy structures (lattice preferred orientation and/or laminated structures) caused by the horizontal flow in this depth range, suggesting the presence of a mid-mantle boundary layer due to (partially) layered convection, (ii) the observed no significant seismic anisotropy in the deep mantle near subduction zones implies that deformation associated with subducting slabs is due mostly to diffusion creep (or superplasticity) and therefore slabs are weak in the deep mantle and hence easily deformed when encountered with resistance forces, and (iii) the SH > SV anisotropy in the cold thick portions of the D" layer is likely to be due to horizontally aligned shape preferred orientation in perovskite plus magnesiowüstite aggregates formed by strong horizontal shear motion in the recent past.     

Petrology of the Green Knobs diatreme and implications for the upper mantle below the Colorado Plateau

Peridotite inclusions, crystal fragments, and kimberlite breccia at Green Knobs, New Mexico, have been studied to evaluate compositions and processes in the upper mantle below the Colorado Plateau. Most peridotite inclusions are spinel lherzolites and harzburgites, or their partly hydrated equivalents, in the Cr-diopside group. Orthopyroxene-rich websterites and olivine websterites comprise 3% of the peridotites and formed as cumulates. Typical anhydrous or slightly hydrated peridotites contain aluminous, calcic diopside (5–7% Al₂O₃), aluminous orthopyroxene (3–6% Al₂O₃), spinel, and olivine (near Fa₉). Geothermometers based on different mineral pairs yield temperatures from above 1100°C to below 700°C in single rocks. High values, derived from pyroxenes with included exsolution lamellae, may approximate temperatures of primary crystallization. Low values, based on olivine-spinel and olivine-clinopyroxene pairs, approach upper mantle temperatures before eruption. In rare samples, some spinel grains are rimmed by garnet while others are not rimmed; garnet formation was controlled by nucleation kinetics. About one-third of the peridotites were deformed shortly before eruption, with effects ranging from mild cataclasis to the production of ultramylonites.Discrete crystals of garnet, olivine (near Fa₈), and Cr-diopside represent garnet peridotite. Eclogites were not found. The garnet peridotite is more depleted than overlying spinel peridotite, and it is not a likely source for the minettes associated with the kimberlites.The mantle below Green Knobs consists of spinel peridotite from 45 to perhaps 60 km depth immediately underlain by more-depleted garnet peridotite. The position of the spinel-garnet transition may be fixed by kinetics. The kimberlite may have been produced when heat from ascending minette magma released volatiles from otherwise depleted garnet peridotite. Resulting gas-solid mixtures erupted along zones of deformation associated with Colorado Plateau monoclines. Sheared lherzolites formed during renewed movement along these zones.     

Metasomatic hydrous fluids in amphibole peridotites from Zabargad Island (Red Sea)

Combining textural, petrological, chemical and isotopic (Sr, H and O) data for amphiboles and whole rocks from the Zabargad peridotite diapir allows three different events to be distinguished. During each event, which can be related to a specific tectonic process of the rifting of the Red Sea, hydrous fluids produced amphiboles.

The first and the second generations of amphiboles have characteristics consistent with the involvement of mantle-derived hydrous fluids. The first generation consists of scarce Ti-pargasites which crystallized from small amounts of fluid at temperatures of around 900–1000°C. Their growth was linked to magma percolation in the peridotites before their deformation during diapiric uplift. The second generation consists of Cr-pargasites which crystallized locally (and abundantly) during reaction between the peridotites and a sodium/potassium-bearing hydrous fluid at temperatures of around 700–800°C. These amphiboles grew synchronously with the diapiric uplift. The hydrous fluids probably originated in the sub-continental mantle and were released during the diapiric uplift of the peridotites.

The third generation consists of amphiboles (pargasitic hornblende, hornblende sensu lato and tremolite) which are localized in shear zones and veins. They crystallized at temperatures estimated between 700°C and 450°C, again from a sodium/potassium-bearing hydrous fluid. However, this fluid is extraneous to the peridotites, as shown by the Sr, H and O isotope compositions which suggest seawater penetration either during or after the final emplacement of the peridotite diapir.

Although the peridotite diapir was emplaced in granulitic gneisses of the pan-African deep continental crust, no evidence was found for a contribution of hydrous continental fluids in the production of the amphiboles present in the peridotite bodies of Zabargad Island.     

Transient creep and semibrittle behavior of crystalline rocks

We review transient creep and semibrittle behavior of crystalline solids. The results are expected to be pertinent to crystalline rocks undergoing deformation in the depth range 5 to 20 km, corresponding to depths of focus of many major earthquakes. Transient creep data for crystalline rocks at elevated temperatures are analyzed but are poorly understood because of lack of information on the deformation processes which, at low to moderate pressure, are likely to be semibrittle in nature. Activation energies for transient creep at high effective confining pressure are much higher than those found for atmospheric pressure tests in which thermally-activated microfracturing probably dominates the creep rate. Empirical transient creep equations are extrapolated at 200° to 600°C, stresses from 0.1 to 1.0 kbar, to times ranging from 3.17×10² to 3.17×10⁸ years. At the higher temperatures, appreciable transient creep strains may take place but the physical significance of the results is in question because the flow mechanisms have not been determined. The purpose of this paper is to stimulate careful research on this important topic.