Sr and Nd isotope systematics of Francistown plutonic rocks, Botswana: implications for Neoarchaean crustal evolution of the Zimbabwe craton

The Francistown plutonic rocks at the south-western margin of the Zimbabwe craton consist of three igneous suites: Sanukitoid, Tonalite–Trondhjemite–Granite (TTG) suites and High-K granites. The TTG suite is subdivided into High Aluminum-TTG (HA-TTG) and Low Aluminum-TTG (LA-TTG) sub-suites. Their Rb–Sr isotope systems were partially homogenized by post-crystallization thermo–tectonic events, in which hydrothermal solutions and migmatization played an important role. Therefore, the Rb–Sr isochron age of 2427±54 Ma can only be regarded as a lower limit to the Francistown plutonic rock age. The large errors in the Sm–Nd isochron dates of Francistown granitoids indicate that these dates are not really constrained. In this study we compared the rock types of Francistown and adjacent areas, adopting the precise U, Th–Pb single zircon SHRIMP ages from the Vumba area as references. For TTG and Sanukitoid suites, the age we adopted is ca. 2.7 Ga, which is close to their depleted-mantle Sm–Nd model ages (T _DM). For High-K granites, the age adopted is ca. 2.65 Ga, which is also close to their Sm–Nd isochron age. The highest ε _Nd ^t values of Sanukitoids and TTG are +2.1 and +2.3, respectively. The positive ε _Nd ^t values and trace element geochemistry support partial melting of a depleted mantle and young oceanic crust for the genesis of Sanukitoid and the TTG suites respectively. The lowest ε _Nd ^t values of Sanukitoids and TTGs are −1.0 and −1.1, respectively, indicating contamination by continental crust, up to 10 and 14%, respectively. The ε _Nd ^t values of TTG decrease with decreasing Al₂O₃ and Sr contents and increasing Eu negative anomalies (Eu*–Eu), suggesting that the TTG magmas underwent a coupled fractionation crystallization and crustal contamination, and that the LA-TTG was the product of the fractionation and contamination of the HA-TTG sub-suite. In contrast, negative ε _Nd ^t values for the High-K granites (from −0.4 to −3.5) indicate the involvement of LA-TTG and some materials from an old continental crust in their genesis. The products of partial melting of both oceanic and continental crusts at the south-western margin of the Zimbabwe craton occurred within a short time interval (from 2.7 to 2.65 Ga ago) suggesting that the Francistown plutonic rocks were formed in a active continental margin environment, where a young ocean plate (Limpopo oceanic plate) subducted underneath an old continental plate (Zimbabwe craton).     

苏鲁造山带胶东区段花岗片麻岩类的常量与微量元素地球化学：扬子克拉通北缘新元古代活动大陆边缘的证据

胶东东部地区的基底片麻岩以牟平-海阳断裂为界,两侧在岩性组合和地球化学性质上完全不同,本文认为该断裂应代表苏鲁造山带的西北边界（北段）。断裂西侧岩性包括花岗闪长质、奥长花岗质和花岗质,地球化学上表现为低硅（SiO2：64．16～71．76％）、高铝（Al2O3=15．60-18．51％）、显著的Ba和Sr正异常、强烈的稀土元素分馏程度（LaN／YbN=15．77～68．19）和贫重稀土元素（YbN=2．9-4．4）、Eu异常不明显（δEu=0．86～1．02）,具典型的太古代高铝TTG岩石组合的特征。而东侧新元古代的基底片麻岩从地球化学上可分为高钾的Ⅰ型花岗质片麻岩和富钠的A型花岗质片麻岩。前者总体表现为富钾（K2O／Na2O比接近或大于1）和亚铝质,强烈亏损Sr、Nb和Ta,轻稀土元素之间的分馏程度强（LaN／SmN=4．21～5．37）,而重稀土元素之间几乎无分馏（GdN／YbN：0．78～1．54）,负Eu异常较强（δEu=0．47～0．61）,岩石地球化学特征显示它们的原岩类似于活动大陆边缘的Ⅰ型花岗岩类。而后者则以偏碱和富钠（Na2O／K2O=1．06～1.77）,高Y（20.4～52．9μg／g）、Zr（218～39μg/g）、Ga（18．8～22．9μg／g）及稀土元素丰度为特征,稀土元素分馏程度强（LaN／YbN=11．30～19．09）,弱到中等程度的负Eu异常（δEu=0．94～0．65）,强烈亏损Sr为显著特征,Nb和Ta相对于La也强烈亏损,而Ba则表现出明显的正异常。推测Ⅰ型花岗岩是在与俯冲有关的构造环境下,压力0．8～1．0Gpa条件下,由受俯冲板片脱水交代的镁铁质下地壳（26～33km）部分熔融形成的。而A型花岗岩则是在Ⅰ型花岗质岩浆形成后,由脱水的紫苏辉石质残留下地壳在温度大于900℃的条件下再一次部分熔融形成的。相对于Ⅰ型花岗岩,A型花岗岩中可能有更多的大洋岩石圈的组份被卷入。     

A review of Palaeoarchaean felsic volcanism in the eastern Kaapvaal craton:Linking plutonic and volcanic records

In the Kaapvaal craton of southern Africa, as well as other Archaean cratons worldwide, the progression from dominant tonalite-trondhjemite-granodiorite(TTG) to granite-monzogranite-syenogranite(GMS)rock types is interpreted to reflect progressive reworking and differentiation of the continental crust.Here we re-evaluate the early Archaean evolution of the Kaapvaal craton and propose a unified view of the plutonic and volcanic records based on elemental and isotopic(Nd, Hf) data and zircon U-Pb ages.We also report new whole-rock major and trace element analyses, zircon U-Pb ages and Hf-in-zircon analyses of igneous clasts from a conglomerate of the 3.2 Ga Moodies Group of the Barberton Greenstone Belt. Many of these clasts are derived from shallow intrusive rocks of granitic composition, which are scarcely represented in outcrop. Despite alteration, the volcanic rocks can be classified based on their trace element contents into two main groups by comparison with plutonic rocks. One group has characteristics resembling TTGs: relatively low and fractionated rare earth element concentrations with no Eu anomaly and relatively low concentrations of high field strength elements(Nb mostly ≤12 ppm). The second group has GMS-like characteristics: less fractionated REE, marked negative Eu anomalies and HFSE-increasing trends with progressing fractionation(Nb ≤ 50 ppm or more, Th up to 30-40 ppm). In addition, igneous clasts of Moodies Group conglomerate have chemical, mineralogical and isotopic characteristics that link them to GMS. New analyses of some of these clasts indicate elevated high field strength elements(Nb up to 20 ppm) and_(εHf)(t)of zircon down to -3.5. These rocks imply the presence of an already differentiated felsic crust at 3.5 Ga, which has Nd and Hf model ages indicating mantle extraction ages extending back to the Eoarchaean. The combined record of plutonic and volcanic rocks of the Kaapvaal craton provides a more complex scenario than previously suggested and indicates that TTG and GMS-like felsic magmas were emplaced broadly coevally in multiple pulses between ~3.5 Ga and 3.2 Ga.     

华北克拉通胶东地区～2.7Ga TTG岩石的成因及地质意义

胶东是华北克拉通保存~2.7Ga岩石的主要地区之一。通过地质调查和锆石SHRIMP测年,我们在胶东5个地方识别出2.7Ga的岩石,这些岩石包括片麻状英云闪长岩、片麻状花岗闪长岩以及片麻状高硅奥长花岗岩。SHRIMP测年结果显示,除样品QX12126外,其他样品中的锆石大多具有清晰的岩浆环带,207Pb/206Pb加权平均年龄为2718~2743Ma,指示这些样品的原岩结晶年龄为~2.7Ga。样品QX12126中锆石大多遭受后期改造,核部获得的最老的207Pb/206Pb年龄(2710±11Ma)应最接近原岩的结晶年龄。根据地球化学结果,胶东~2.7Ga岩石可以分为两组。组1以高的(La/Yb)N、Sr/Y,低的Yb、Y为特征,并表现出无Eu异常或正Eu异常;组2则具有低的(La/Yb)N和Sr/Y,高Yb、Y的特征,并具有负的Eu异常。这些地球化学特征指示组1可能来自以榴辉岩或斜长石很少的石榴角闪岩为残留的源区,而组2源区残留可能为几乎不含石榴石的角闪岩。结合放射性同位素数据,我们认为组1可能起源于加厚的中太古代玄武质下地壳,榴辉岩下地壳发生拆沉作用,上涌的热的软流圈加热浅部残留的地壳物质,形成高HREE(组2)的TTG岩石。胶东与霍邱地区新太古代早期岩石成因、更早期地质记录存在相似性,两者可能为同一古老陆块。出露~2.7Ga岩石的地区在华北分布分散,不同地区~2.7Ga岩石的成因可能存在差异,在探讨华北克拉通新太古代早期构造演化过程时应充分考虑这些因素。     

Petrogenesis of the Swartruggens and Star Group II kimberlite dyke swarms,South Africa: constraints from whole rock geochemistry

Thirty-seven samples from the Swartruggens and Star Group II kimberlite dyke swarms, emplaced through the Kaapvaal craton, have been analysed for their major and trace element and Sr, Nd and Hf isotope compositions. The samples are all MgO-rich (~12–35 wt%) with high Mg# (0.72–0.90) and Ni (~610–2700 ppm) contents. The kimberlites are strongly enriched in incompatible elements (Zr = 140–668 ppm; La = 124–300 ppm; Nb = 68–227 ppm; Ba = 1500–7000), and have high and variable chondrite normalised La/Yb ratios (Swartruggens = 94 ± 21; Star = 202 ± 36). ⁸⁷Sr/⁸⁶Sr (0.70718–0.71050) ratios are elevated, whereas εNd (−11.95 to −7.84) and ¹⁷⁶Hf/¹⁷⁷Hf ratios (0.282160–0.282564) are low. Inter- and intra-dyke compositional variation is significant, and there are systematic differences between the kimberlites found at the two localities. Intra-locality differences can largely be attributed to a combination of the effects of alteration, crustal contamination, macrocryst entrainment and phenocryst fractionation. There is some evidence for distinct parental magmas formed through variable and low degrees (0.5–2%) of partial melting, as illustrated by crossing rare earth element patterns. The Star kimberlites have derived from a less radiogenic source, with higher LREE enrichment than the Swartruggens kimberlites. Inferred primary magmas at each locality have high Mg# (~0.83), are Ni-rich (850–1220 ppm) and are strongly enriched in incompatible elements. Calculated mantle source compositions are strongly enriched in incompatible elements (La/Yb_n ~ 10–50), but refractory in terms of Mg# and Ni contents. Incompatible element ratios such as Ba/Nb (>13.5), La/Nb (> 1.1) and Ce/Pb (< 22) are unlike those characteristic of Group I kimberlites or ocean island basalts, but indistinguishable from calc-alkaline magmas. Taken together with extremely low εNd and εHf, these compositional characteristics are used to argue for derivation of these Group II kimberlite magmas from the deep subcontinental lithospheric mantle, metasomatised during the Proterozoic by calc-alkaline fluids/melts.     

Thermotectonic evolution of Precambrian basement rocks of the Kuruktag uplift,NE Tarim craton,China: evidence from apatite fission-track data

The Kuruktag uplift is located directly northeast of the Tarim craton in northwestern China. Neoarchaean-to-Neoproterozoic metamorphic rocks and intrusive rocks crop out widely in the uplift; thus, it is especially suited for a more complete understanding of the thermal evolution of the Tarim craton. Apatite fission-track (AFT) methods were used to study the exhumation history and cooling of these Precambrian crystalline rocks. Nine apatite-bearing samples were collected from both sides of the Xingdi fault transecting the Kuruktag uplift. Pooled ages range from 146.0 ± 13.4 to 67.6 ± 6.7 Ma, with mean track lengths between 11.79 ± 0.14 and 12.48 ± 0.10 μm. These samples can be divided into three groups based on age and structural position. Group A consists of five samples with AFT apparent ages of about 100–110 Ma and is generally associated with undeformed areas. Group B comprises three specimens with AFT apparent ages lower than 80 Ma and is mostly associated with hanging wall environments close to faults. Group C is a single apatite sample with the oldest relative apparent age, 146.0 ± 13.4 Ma. The modelled thermal history indicates four periods of exhumation in the Kuruktag uplift: late-Early Jurassic (180 Ma); Late Jurassic–Early Cretaceous (144–118 Ma); early-Late Cretaceous (94–82 Ma); and late Cenozoic (about 10 Ma). These cooling events, identified by AFT data, are assumed to reflect far-field effects from multi-stage collisions and accretions of terranes along the south Asian continental margin.     

Isotopic (O, Sr, Nd) and trace element geochemistry of the Laouni layered intrusions (Pan-African belt, Hoggar, Algeria): evidence for post-collisional continental tholeiitic magmas variably contaminated by continental crust

The three layered intrusions studied in the Laouni area have been emplaced within syn-kinematic Pan-African granites and older metamorphic rocks. They have crystallized at the end of the regional high-temperature metamorphism, but are free from metamorphic recrystallization, revealing a post-collisional character. The cumulate piles can be interpreted in terms of two magmatic liquid lines of descent: one is tholeiitic and marked by plagioclase–olivine–clinopyroxene cumulates (troctolites or olivine bearing gabbros), while the other is calc-alkaline and produced orthopyroxene–plagioclase rich cumulates (norites). One intrusion (WL (West Laouni)-troctolitic massif), shows a Lower Banded Zone where olivine-chromite orthocumulates are interlayered with orthopyroxene-rich and olivine–plagioclase–clinopyroxene cumulates, whereas the Upper Massive Zone consists mainly of troctolitic and gabbroic cumulates. The other two massifs are more homogeneous: the WL-noritic massif has a calc-alkaline differentiation trend whereas the EL (East Laouni)–troctolitic massif has a tholeiitic one. Separated pyroxene and plagioclase display similar incompatible trace element patterns, regardless of the cumulate type. Calculated liquids in equilibrium with the two pyroxenes for both noritic and troctolitic cumulates are characterized by negative Nb, Ta, Zr and Hf anomalies and light REE enrichment inherited from the parental magmas. Troctolitic cumulates have mantle-derived δ¹⁸O (+5 to +6‰), initial ⁸⁷Sr/⁸⁶Sr (Sr_i=0.7030 to 0.7054), _Nd (+5 to −1) values whereas noritic cumulates are variably enriched in δ¹⁸O (+7 to +9‰), show negative _Nd (−7 to −12) and slightly higher Sr_i (0.7040–0.7065). Based on field, isotopic ratios are interpreted as resulting from a depleted mantle source (Sr_i=0.7030; _Nd=+5.1; δ¹⁸O=+5.1‰) having experience short term incompatible element enrichment and variable crustal contamination. The mantle magma was slightly contaminated by an Archaean lower crust in troctolitic cumulates, more strongly and with an additional contamination by an Eburnian upper crust in noritic cumulates. Lower crust input is recorded mainly by Sr and Nd isotopes and upper crust input by O isotopes. This is probably due to the different water/rock ratios of these two crust types. Assimilation of low amounts (<10%) of quartz-bearing felsic rocks, coming from both lower and upper crust, can explain the rise of SiO₂ activity, the enrichment in ¹⁸O and ⁸⁷Sr and the lowering of _Nd in the noritic cumulates compared to troctolitic ones. The geodynamic model proposed to account for the Laouni tholeiitic magmatism involves a late Pan-African asthenospheric rise due to a rapid lithospheric thinning associated with functioning of shear zones, which allowed tholeiitic magmas to reach high crustal levels while experiencing decreasing degrees of crustal contamination with time.     

活动大陆边缘岩浆作用及构造演化——以敦煌地块为例

大陆边缘弧是汇聚板块边界与俯冲有关的岩浆作用产物, 通常记录了造山带弧岩浆作用、造山过程和大陆地壳形成与演化等诸多重要的地质过程。作为中亚造山带中段最南部的构造单元, 敦煌地块为传统定义上具有早前寒武纪变质结晶基底的微陆块, 其后在古生代时期经历了多期次、多阶段的与中亚造山带造山相关的构造热事件并使其发生再活化, 进而产生了一系列广泛的弧岩浆-变质作用事件。然而, 对于该陆块古生代弧岩浆作用机制和地壳构造演化历史缺乏系统的研究。本文综合近十多年来对敦煌地块的诸多最新研究进展, 系统梳理了古生代岩浆岩岩石组合类型、年代格架、地球化学组成以及同时期变质-沉积构造热事件演化特征, 得到以下认识: (1)敦煌地块古生代岩浆作用过程呈现阶段性特征, 即幕式岩浆作用, 构造位置上从东北部逐渐迁移到南部再折返到中部, 大致可划分为五期: ~510Ma、440~410Ma、390~360Ma、~330Ma和280~245Ma, 而变质作用事件主要集中在450~360Ma; (2)古生代岩浆岩类型主要以钙碱性Ⅰ型花岗岩、埃达克质岩石、少量S型花岗岩和高钾花岗岩为主, 且岩石成分从寒武纪低钾拉斑系列逐渐转变为二叠纪高钾、富硅特征; (3)同位素地球化学特征表明, 敦煌地块中-北部寒武纪-泥盆纪发育的与俯冲相关的弧岩浆对新生地壳的生长起了重要贡献, 并伴随古老地壳再造事件; 而南部泥盆纪-石炭纪岩浆作用则以古老地壳物质重熔为主; (4)基于埃达克质岩石的证据, 敦煌地块在古生代时期经历了两次显著的地壳增厚事件, 早期可能是与北山南部石板山地体/弧碰撞以及幔源岩浆底侵有关, 而晚期可能是与俯冲板片后撤或回卷相关, 地壳厚度可达~55km; (5)敦煌地块属于中亚造山带中段最南部一个具有前寒武纪基底的古老微陆块, 后期卷入了古亚洲洋南向俯冲相关的造山事件使其被强烈破坏与改造。该微陆块作为古亚洲洋南部的活动大陆边缘弧, 被与俯冲作用有关的阶段性弧岩浆底侵、部分熔融、增厚地壳和区域性变质作用等机制改造与活化, 产生了阶段性侵位的陆缘弧岩浆作用。这些认识为探究中亚造山带微陆块的起源和造山带的构造演化提供新的约束。

     

Geochemistry and geochronology of mafic rocks from the Vespor suite in the Juruena arc,Roosevelt-Juruena terrain,Brazil: Implications for Proterozoic crustal growth and geodynamic setting of the SW Amazonian craton

This study presents new geochemical data on rocks from the Vespor suite, an important mafic unit from the Juruena arc, Roosevelt-Juruena terrain, SW Amazonian craton, northwest Mato Grosso, Brazil, attempting to define their tectonic setting and type of mantle source. The Juruena arc may be part of a magmatic belt (Jamari and Juruena arcs) at the southwestern Amazonian craton during assembly of the Columbia supercontinent. The investigated rocks represent a Paleoproterozoic subduction-related mafic suite of sigmoidal bodies, composed mainly of gabbro, norite, gabbronorite and diorite, that underwent amphibolite facies metamorphism. Here we present also preliminary petrology aspects and zircon U–Pb geochronology. Geochemical character and variation trends of major and trace elements as well as selected trace element ratios suggest that Vespor suite rocks have a tholeiitic lineage of arc affinity controlled by fractional crystallization with a prominent iron enrichment trend. Gabbros, norites and gabbronorites are characterized by enrichment of LILE and weakly to moderately differentiated HFSE patterns, suggesting their deviation from an enriched heterogeneous lithospheric mantle source. Vespor suite rocks are characterized by depletion of Nb–Ta, P and Ti, with flat distribution of HFSE, markedly large variations in most of the LILE, positive anomalies displayed by Ba, K, Th, Sr, Pb and weak negative anomalies of Hf–Zr. These features reflect limited degrees of crustal contamination associated with a subduction-related magma process where the mantle wedge was chemically modified. In addition, the enrichment in LILE and Pb, low values of the ratios (La_n/Sm_n – 0.83 to 4.58) and (Nb_n/La_n – 0.04 to 0.45), but high Th/Yb ratios, gently to moderately sloping REE profiles (La/Yb_n = 2.53–7.37), negative anomalies in HFSE (Ta, Zr, Hf, and Ti), and positive anomalies in LILE (Th, Ba, Sr), suggest derivation from a metasomatized lithospheric mantle source above a subduction zone with weak crustal contamination. Both the composition of the mantle source and the degree of partial melting that produced the parental magmas of these rocks, determined by using REE abundance and ratios, indicate that gabbroic/dioritic melts were generated at different degrees of melting of the source: about 5–20% partial melting of a garnet-spinel lherzolite, around 1–10% partial melting of spinel lherzolite source, and approximately 1–5% partial melting of intermediate source composition, and crystallizing between 1.773 and 1.764 Ma.     

Magma mixing model for the genesis of middle crust in the Izu–Bonin–Mariana arc: evidence from plutonic rocks in the Mineoka-Setogawa ophiolitic mélange,central Japan

ABSTRACT

A Paleogene accretionary complex, the Mineoka–Setogawa belt is distributed adjacent to the northern portion of the collision zone between Honshu and Izu–Bonin–Mariana (IBM) arcs in central Japan, comprising a mélange of ophiolitic fragments of various sizes. The Eocene-Oligocene plutonic rocks in this belt (gabbro, diorite, and tonalite) have been interpreted as fragments brought from the deep crust beneath the IBM arc through tectonic collisions. The geochemical characteristics of the gabbro and associated basaltic dike are similar to those of the Eocene IBM tholeiitic basalt; thus, the gabbro was likely formed via the crystallization of the Eocene tholeiitic basaltic magmas, which was produced by the partial meltings of a depleted mantle wedge. A comparison with experimental results and geochemical modeling indicates that the tonalite was generated by 10–30% dehydration melting of the gabbro. Actually, Eocene–Oligocene felsic veins, which are coeval with the plutonic rocks, occur in the Mineoka–Setogawa gabbro. Plagioclase crystals in the diorite comprise Ca-rich and -poor parts in a single crystal. Their compositional characteristics are consistent with those of plagioclase in the gabbro and tonalite, respectively. The textures and chemical composition of plagioclase indicate that the diorite was formed by the mixing between mafic and silicic magmas. The whole-rock composition of the diorite also indicates the evidence for the mixing between basaltic magmas which were fractionated to variable degrees and homogeneous silicic magma. The mixing model proposed from the first direct observations of the IBM middle crust exposed on the Mineoka–Setogawa belt is applied to the genesis of the Eocene to present intermediate rocks in the IBM arc. If the continental crust were created at intra-oceanic arc settings such as the IBM arc, the magma mixing model would be one of the most likely mechanisms for the genesis of the continental crust.     

西藏冈底斯带石炭纪—二叠纪岛弧造山作用：火山岩及地球化学证据

系统研究了西藏冈底斯带石炭纪—二叠纪火山岩的时空分布、岩相学、元素及Sr、Nd、Pb 同位素地球化学和构造环境、源区性质,并与喜马拉雅带二叠纪火山岩进行了对比研究。冈底斯带石炭纪—二叠纪火山岩近东西向集中分布在冈底斯构造带中北部地带,空间上从东至西火山活动的强度和规模渐次减小,时间上从早至晚火山活动的强度和规模总体由弱到强。冈底斯带石炭纪—二叠纪火山岩形成于活动大陆边缘的岛弧构造环境,从早到晚岛弧造山作用经历了初始岛弧→早期岛弧→成熟岛弧的发展演变过程,火山岩浆来源于富集型地幔部分熔融作用,原始岩浆在形成和演化的过程中有俯冲洋壳及随带的深海沉积物和再循环进人地慢的地壳物质组分的强烈混染,明显不同于受地壳物质组分强烈混染的喜马拉雅带二叠纪陆缘裂陷型火山岩。综合研究冈底斯带及其邻区近年来的最新调查与研究成果,从北向南拟建了石炭纪—二叠纪冈底斯岛弧→雅鲁藏布江弧后裂谷盆地→喜马拉雅陆缘裂陷盆地的弧盆系时空结构演化模式,探讨了冈瓦纳大陆北缘石炭纪—二叠纪活动大陆边缘的岛弧造山作用与青藏高原古特提斯演化的耦合关系及其动力学机制,讨论了冈底斯带松多乡榴辉岩的形成过程。     

福建金山花岗质复式岩体的元素和同位素地球化学及其成因研究

金山复式岩体位于福建南部华安县和南靖县交界地区,为一燕山晚期的花岗质复式大岩基,由早白垩世早期的华安洋竹径单元（锆石U-Pb年龄为140.3±1.2Ma）和早白垩世晚期的南靖龙山单元（锆石U-Pb年龄为105.1±0.8Ma）组成。复式岩体东部的洋竹径单元主体岩性为中粒钾长花岗岩,在中心部位发育部分黑云母花岗岩,地球化学特征上,该单元岩石总体为弱过铝质（A/NKC值变化于1.00~1.05）,富硅,碱含量中等（K2O+Na2O介于8.30%~8.84%）,碱铝指数（AKI值）变化于0.80~0.90,富钾（K2O含量变化于4.59%~5.58%,K2O/Na2O比值介于1.18~1.95）,富轻稀土和大离子亲石元素（如Rh、Th等）,贫Ba、Sr、Ti、P,Rb/Sr比值高,具中到强的铕负异常。复式岩体西部的龙山单元主体岩性为黑云母二长花岗岩,与洋竹径单元相比,其硅、碱含量及Rb/Sr比值均相对偏低,轻重稀土比值更高,而铕负异常相对不明显。复式岩体各单元岩石的Ga/Al比值以及Zr、Nb、Ce、Y等高场强元素含量较之典型的A型花岗岩均偏低,综合地质地球化学资料指示该复式岩体应属高钾钙碱性I型花岗岩。洋竹径单元黑云母花岗岩和钾长花岗岩具有一致的Nd同位素组成,Nd(t)值分别为-1.13和-1.16~-1.94,表明它们具有相同的岩浆源区,二者应为同源岩浆经分异演化的产物。龙山单元的成岩年龄晚于洋竹径单元,Nd(t)值略低（＝-2.22）,其岩石学和元素地球化学特征与洋竹径单元存在较明显的差别,相关的元素演变趋势表明龙山单元不可能为洋竹径单元岩浆分异演化的产物,而应具独立的岩浆起源。金山复式岩体极可能是在弧后伸展背景下,由于持续的幔源岩浆底侵作用导致早期底侵物质（初生地壳）与古老基底地壳混合的地壳原岩叠次熔融复合的产物。     

华南与花岗岩有关的一种新类型的锡成矿作用：矿物化学、元素和同位素地球化学证据

华南是我国最重要的锡成矿省,产有大量的与花岗岩有关的大型-超大型锡多金属矿床。近年来,在湘南新探明一个超大型锡矿床-芙蓉锡矿床,其中,最重要的锡矿化产在骑田岭花岗岩体西南部的破碎蚀变带内,与绿泥石化密切相关。骑田岭花岗岩富含角闪石,具有较高的氧逸度,显示出准铝的地球化学特征,在花岗岩形成过程中发生过壳-幔岩浆混舍作用。这些特点都表明骑田岭花岗岩并不同于一般的S型含锡花岗岩,而显示出A型花岗岩的地球化学特征。同位素定年分析表明,芙蓉锡矿床主成矿阶段的形成时代要晚于骑田岭花岗岩侵位年龄近20Ma。氢、氧同位素分析表明,发生过水-岩反应的大气降水在成矿流体中占有很重要的地位。硫同位素分析表明花岗岩和地层都提供了成矿所需的硫。因此,用花岗岩浆结晶分异过程中分离出富锡的岩浆流体来形成锡矿的传统模式并不适合于解释芙蓉锡矿的形成。我们认为芙蓉锡矿的形成主要与骑田岭花岗岩的绿泥石化蚀变有关,循环的大气降水与花岗岩发生水-岩反应,富锡的铁镁矿物在蚀变成绿泥石的同时释放出Sn和Ti等金属到流体中,当物理化学条件改变时,沉淀形成锡矿体。这是一种比较独特的锡矿化模式,丰富了华南与花岗岩有关的锡矿化类型。     

松嫩-张广才岭地块东缘晚二叠纪构造演化历史:来自德裕花岗岩地质年代学和地球化学的证据

松嫩-张广才岭地块位于我国东北兴蒙造山带东段,受古亚洲洋构造域及濒太平洋构造域叠加转换的影响,该区构造演化十分复杂,因此,对区内花岗岩进行研究能够有效反演该区的构造演化历史。德裕花岗岩体位于松嫩-张广才岭地块东缘张广才岭岩浆岩带北段,样品岩性为二云二长花岗岩,主要由石英、斜长石、钾长石、黑云母、白云母、角闪石等矿物组成。锆石U-Pb定年结果显示其侵位时代为254±1Ma,形成于晚二叠世。岩石具有高硅(71.26%～75.34%),中铝(12.23%～14.71%),低镁(0.33%～0.52%)的特点,K₂O/Na₂O为0.85～1.17,铝饱和指数A/CNK为0.99～1.05,属于弱过铝质高钾钙碱性岩石。样品稀土元素含量较低(∑REE=54.7×10^-6～82.0×10^-6),轻稀土富集而重稀土亏损(LREE/HREE=8.49～10.46),显示负Eu异常(δEu=0.69～0.80)。样品岩石学特征和地球化学特征暗示其为Ⅰ型花岗岩。德裕花岗岩样品的Nb/Ta值为10.42～15.12,Zr/...     

新疆谢米斯台地区晚古生代俯冲作用: 来自塞勒肯特岩体的岩石学、年代学及地球化学证据

塞勒肯特岩体出露于谢米斯台中东部,岩性主要为二长花岗岩、石英闪长岩及花岗闪长岩。本文通过锆石U-Pb年代学、岩石地球化学和Sr-Nd-Hf同位素等研究,探讨其形成的构造环境及岩石成因。结果表明,二长花岗岩(400.9±4.3Ma)和石英闪长岩(398.1±4.5Ma)形成于早泥盆世,花岗闪长岩(381.7±2.9Ma)形成于晚泥盆世。岩体整体富碱,属于准铝质-弱过铝质高钾钙碱性花岗岩类。轻重稀土分馏较明显且富集轻稀土((La/Yb)_N=5.09~9.22),Eu异常不明显,相对富集Rb、Th、U、K等元素,亏损Nb、Ta、Ti等高场强元素;二长花岗岩和石英闪长岩具有低的(⁸⁷Sr/⁸⁶Sr)_i值(0.7040~0.7043),正ε_Nd(t)值(+4.85~+6.18),年轻的t_DM1(Nd)年龄(663~732Ma),二长花岗岩锆石ε_Hf(t)值为+7.94~+12.12,t_DM2(Hf)=648~889Ma;花岗闪长岩也具有低的(⁸⁷Sr/⁸⁶Sr)_i值(0.7045~0.7046),正ε_Nd(t)值(+4.61~+4.80),年轻的t_DM1(Nd)年龄(731~749Ma),花岗闪长岩锆石ε_Hf(t)值为+4.26~+11.69,t_DM2(Hf)=631~1103Ma。综合研究表明,塞勒肯特岩体形成于俯冲背景下的大陆边缘弧环境,可能是俯冲板片脱水交代地幔楔产生的玄武质岩浆上涌,导致新生下地壳发生部分熔融。二长花岗岩及石英闪长岩均来源于新生下地壳的部分熔融;花岗闪长岩主要来源于新生下地壳的部分熔融,并有少量幔源物质的加入,花岗闪长岩中的暗色微粒包体可能是幔源物质与新生下地壳部分熔融的岩浆未发生完全混合,最终冷凝结晶的产物。谢米斯台地区与俯冲相关的中酸性岩浆活动至少从晚奥陶世一直延续至晚泥盆世。

     

Secular evolution of the lithospheric mantle beneath the eastern North China craton: evidence from peridotitic xenoliths from Late Cretaceous mafic rocks in the Jiaodong region,east-central China

The Mesozoic lithospheric mantle beneath the North China craton remains poorly constrained relative to its Palaeozoic and Cenozoic counterparts due to a lack of mantle xenoliths in volcanic rocks. Available data show that the Mesozoic lithospheric mantle was distinctive in terms of its major, trace element, and isotopic compositions. The recent discovery of mantle peridotitic xenoliths in Late Cretaceous mafic rocks in the Jiaodong region provides an opportunity to further quantify the nature and secular evolution of the Mesozoic lithospheric mantle beneath the region. These peridotitic xenoliths are all spinel-facies nodules and two groups, high-Mg# and low-Mg# types, can be distinguished based on textural and mineralogical features. High-Mg# peridotites have inequigranular textures, high Mg# (up to 92.2) in olivines, and high Cr# (up to 55) in spinels. Clinopyroxenes in the high-Mg# peridotites are generally LREE-enriched ((La/Yb)_N>1) with variable REE concentrations, and have enriched Sr–Nd isotopic compositions (⁸⁷Sr/⁸⁶Sr = 0.7046–0.7087; ¹⁴³Nd/¹⁴⁴Nd = 0.5121–0.5126). We suggest that the high-Mg# peridotites are fragments of the Archaean and/or Proterozoic lithospheric mantle that underwent extensive interaction with both carbonatitic and silicate melts prior to or during Mesozoic time. The low-Mg# peridotites are equigranular, are typified by low Mg# ( < 90) in olivines, and by low Cr# ( < 12) in spinels. Clinopyroxenes from low-Mg# peridotites have low REE abundances (ΣREE = 12 ppm), LREE-depleted REE patterns ((La/Yb)_N < 1), and depleted Sr–Nd isotopic features, in contrast to the high-Mg# peridotites. These geochemical characteristics suggest that the low-Mg# peridotites represent samples from the newly accreted lithospheric mantle. Combined with the data of mantle xenoliths from the Junan and Daxizhuang areas, a highly heterogeneous, secular evolution of the lithosphere is inferred for the region in Late Cretaceous time.     

Late Archaean mantle metasomatism below eastern Indian craton: Evidence from trace elements,REE geochemistry and Sr—Nd—O isotope systematics of ultramafic dykes

Trace, rare earth elements (REE), Rb-Sr, Sm-Nd and O isotope studies have been carried out on ultramafic (harzburgite and lherzolite) dykes belonging to the newer dolerite dyke swarms of eastern Indian craton. The dyke swarms were earlier considered to be the youngest mafic magmatic activity in this region having ages not older than middle to late Proterozoic. The study indicates that the ultramafic members of these swarms are in fact of late Archaean age (Rb-Sr isochron age 2613 ± 177 Ma, Sri ∼ 0.702 ± 0.004) which attests that out of all the cratonic blocks of India, eastern Indian craton experienced earliest stabilization event. Primitive mantle normalized trace element plots of these dykes display enrichment in large ion lithophile elements (LILE), pronounced Ba, Nb and Sr depletions but very high concentrations of Cr and Ni. Chondrite normalised REE plots exhibit light REE (LREE) enrichment with nearly flat heavy REE (HREE; (ΣHREE)_N ∼ 2–3 times chondrite, (Gd/Yb)_N ∼ 1). The ε^Nd(t) values vary from +1.23 to -3.27 whereas δ¹⁸O values vary from +3.16‰ to +5.29‰ (average +3.97‰±0.75‰) which is lighter than the average mantle value. Isotopic, trace and REE data together indicate that during 2.6 Ga the nearly primitive mantle below the eastern Indian Craton was metasomatised by the fluid (± silicate melt) coming out from the subducting early crust resulting in LILE and LREE enriched, Nb depleted, variable ε^Nd, low Sr_i(0.702) and low δ¹⁸O bearing EMI type mantle. Magmatic blobs of this metasomatised mantle were subsequently emplaced in deeper levels of the granitic crust which possibly originated due to the same thermal pulse.     

Geochronology,petrology and geochemistry of the Beiligaimiao magmatic sulfide deposit in a Paleozoic active continental margin,North China

The Beiligaimiao magmatic Ni-Cu sulfide deposit is located in the northern rim of the North China Block, which was an active continental margin related to the southward subduction of the Paleo-Asian oceanic plate to the north in the Paleozoic. This deposit has never been studied before but is an excellent example of sulfide mineralization in arc settings that have been commonly overlooked by exploration geologists worldwide. Sulfide mineralization in the deposit is hosted in a mafic-ultramafic complex that consists of a small ultramafic body surrounded by an older and much larger gabbroic intrusion. Disseminated sulfide zones are present in both intrusive bodies but only those close to the surface within the ultramafic body have been mined in the past. The sulfide-mineralized ultramafic body is composed of olivine websterite and orthopyroxenite with a gradational contact between them. SIMS U-Pb dating of zircon crystals from a large olivine websterite sample yields a crystallization age of 269.4 ± 2.1 Ma, which is ∼25 Ma younger than the Erbutu subduction-related magmatic Ni-Cu sulfide deposit that occurs ∼50 km to the north. Orthopyroxene crystals in the Beiligaimiao ultramafic rocks have Mg^# [100 Mg/(Mg + Fe), molar] of 77–78, significantly lower than those in the ultramafic rocks of the Erbutu deposit. Olivine crystals in the Beiligaimiao ultramafic rocks have forsterite (Fo) contents from 72 to 75 mol%, which are also significantly lower than those in the ultramafic rocks of the Erbutu deposit (Fo, 86–88 mol%). The mineral chemical data indicate a more fractionated parental magma for the former. Ca-depletion in olivine (i.e., <1000 ppm Ca), which is common for ultramafic cumulates in arc settings worldwide, is present in both deposits. Like Erbutu, the host rocks of the Beiligaimiao deposit are characterized by enrichments in light rare earth elements (REE) relative to heavy REE and pronounced negative Nb-Ta anomalies, consistent with ultramafic rocks in arc settings. The δ³⁴S values of sulfide separates from the Beiligaimiao deposit are 1.7 to 2.5‰, significantly lower than those for the Erbutu deposit but still slightly higher than the MORB value (−1.5 to 0.5‰). Olivine websterites in the Beiligaimiao deposit have ε_Nd from −8.9 to −9.5 and (⁸⁷Sr/⁸⁶Sr)_i close to 0.7075, which are similar to those of an enriched lithospheric mantle. An orthopyroxenite sample from the deposit has much lower ε_Nd (−12.6) coupled with much higher (⁸⁷Sr/⁸⁶Sr)_i ratio (0.7132), indicating ∼25% crustal contamination. The Sr-Nd-S isotope data support the premise that both crustal contamination and addition of crustal sulfur played a role in triggering sulfur saturation in the parental magma of the Beiligaimiao deposit. Since the immediate country rocks are exclusively gabbros, these processes likely took place at depth. The close temporal and spatial association of the Beiligaimiao and Erbutu deposits points to the possibility that more Permian arc-type magmatic sulfide deposits are yet to be discovered in the region.     

Metamorphism of the deepest exposed arc rocks in the Cretaceous to Paleogene Cascades belt, Washington: evidence for large-scale vertical motion in a continental arc

The Swakane Gneiss and the overlying Napeequa Complex in the North Cascade range, Washington, were metamorphosed and deformed during development of a Cretaceous‐Paleogene continental arc, and are among the structurally deepest exposed rocks within the Cordilleran arcs of North America. Peak metamorphic conditions in both the Swakane Gneiss and Napeequa Complex were c. 640–750 °C, 9–12 kbar. Clockwise paths and widespread evidence for high‐P metamorphism in meta‐supracrustal rocks (burial to >40 km) document major vertical tectonic motion during arc construction and unroofing. These and other moderately high‐pressure rocks in the North Cascades‐Coast Mountains experienced a dramatically different tectonometamorphic history than metamorphic rocks within other Cordilleran arcs. The exhumed arc complexes of the Sierra Nevada and Peninsular Ranges are dominated by relatively low‐P metamorphic and plutonic rocks (typically <6 kbar). There is no evidence that the northern Cordillera was thickened to a greater degree than these other belts, suggesting that the greater magnitude of vertical motion in the Cascades may have been related to exhumation mechanisms: Eocene extension in the northern Cordillera vs. erosional unroofing in the central and southern Cordillera.     

Neoproterozoic accretionary and collisional events on the western margin of the Siberian craton: new geological and geochronological evidence from the Yenisey Ridge

The geological, structural and tectonic evolutions of the Yenisey Ridge fold-and-thrust belt are discussed in the context of the western margin of the Siberian craton during the Neoproterozoic. Previous work in the Yenisey Ridge had led to the interpretation that the fold belt is composed of high-grade metamorphic and igneous rocks comprising an Archean and Paleoproterozoic basement with an unconformably overlying Mesoproterozoic–Neoproterozoic cover, which was mainly metamorphosed under greenschist-facies conditions. Based on the existing data and new geological and zircon U–Pb data, we recognize several terranes of different age and composition that were assembled during Neoproterozoic collisional–accretional processes on the western margin of the Siberian craton. We suggest that there were three main Neoproterozoic tectonic events involved in the formation of the Yenisey Ridge fold-and-thrust belt at 880–860 Ma, 760–720 Ma and 700–630 Ma. On the basis of new geochronological and petrological data, we propose that the Yeruda and Teya granites (880–860 Ma) were formed as a result of the first event, which could have occurred in the Central Angara terrane before it collided with Siberia. We also propose that the Cherimba, Ayakhta, Garevka and Glushikha granites (760–720 Ma) were formed as a result of this collision. The third event (700–630 Ma) is fixed by the age of island-arc and ophiolite complexes and their obduction onto the Siberian craton margin. We conclude by discussing correlation of these complexes with those in other belts on the margin of the Siberian craton.