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1.
The freezing temperatures of single supercooled drops of binary and ternary sulfuric and nitric acid solutions were measured while varying the acid concentration. An acoustic levitator was used which allows to freely suspend single solution drops in air without electrical charges thereby avoiding any electrical influences which may affect the freezing process. The drops of typically 500 µm in radius were monitored by a video camera during cooling cycles down to − 85 °C to simulate the upper tropospheric and stratospheric temperature range. The present data confirm that liquid solution droplets can be supercooled far below the equilibrium melting point by approximately 35 °C. They follow the general trend of the expected freezing temperatures for homogeneous ice nucleation.  相似文献   

2.
Supercooled drizzle (freezing drizzle) was observed at Inuvik, N.W.T., Canada (68°22′N, 133°42′W) on December 20, 21 and 27, 1995. Meteorological conditions in which the supercooled drizzle could form under low temperatures (colder than −20°C) in the mid-winter season of the Canadian Arctic were examined from the sounding data and data measured by a passive microwave radiometer at ground level. The following results were obtained. (1) Supercooled drizzle fell to the ground with ice pellets and frozen drops on snow crystals. (2) The maximum size of supercooled drizzle particles increased as the depth of cloud layer saturated with respect to water increased. (3) Because a layer of air temperature higher than 0°C was not detected from the sounding data at Inuvik, melting of snow particles was impossible. It was concluded, therefore, that supercooled drizzle was formed by the condensation–coalescence process below freezing temperature.  相似文献   

3.
Measurements of natural ice nuclei with a continuous flow diffusion chamber   总被引:1,自引:0,他引:1  
Measurements of natural ice nuclei were made in winter continental airmasses with a continuous flow thermal gradient diffusion chamber (described in a separate paper). Over the range of temperatures −7°C to −20°C, the concentration of ice nuclei was closely related to ice supersaturation (SSi) for humidities both below and above water saturation. Measurements below water saturation were interpreted as deposition nuclei with average concentrations (per liter) approximately 0.32 SSi(%)0.81. Measurements were made up to 5% above water saturation and activated both deposition and condensation-freezing nuclei. The average concentration of condensation-freezing nuclei was 0.25 e−0.15 T(°C). Sample residence time in the chamber was probably too small to detect contact nuclei, unless the nucleating aerosols are extremely small. There was large variability in nucleus concentrations, as much as two orders of magnitude at −15°C. Comparisons are made between these ice nuclei measurements and aircraft observations of ice crystal concentrations in winter orographic clouds.  相似文献   

4.
To further investigate the influence of cloud base temperature, updraft velocity and precipitation particle constitution on cloud electrification, five thunderstorms in various regions of China were simulated by using the three-dimensional compressible hailstorm numerical model including inductive and non-inductive charging mechanisms. The results indicate that changes of cloud base temperature have an influence on the initial electrification. Comparison of the above cases shows that in the case of warm cloud base and moderate updraft velocity (< 20 m s−  1), active electrification occurred below the − 10 °C level before moving upward to the − 20 °C level. In contrast, when cloud base is cold and updraft velocity is intensive, the main charging region is at the − 20 °C or even higher level. In that case, the vertical extent of the main negative charge region becomes larger with the increase of cloud base temperature. Apart from the main dipolar or tripolar charge structure, some smaller charge regions with relatively high values of charge density may also appear. Frozen drops, originating mainly from supercooled raindrops, mainly get electrified through charging interactions with snow at or below the − 20 °C level. They are responsible for the negative charge region near the melting level at the initial stage of precipitation if there is a large supercooled raindrop content. Non-inductive charging during hail-snow collisions is rather weak, resulting in the charge density on hail of no more than − 0.01 nC m− 3.  相似文献   

5.
Observations have been made of the ice-crystal morphology of snow which fell at two sampling sites during a warm front followed by a cold front in the Sierra Nevada of the western United States. The snow sampling and ice crystal observations were conducted at Kingvale (KV) and Hobart Mills (HM), California, which are located at almost identical elevations on the upwind and down wind sides of the Sierra Nevada crest, respectively.These observations and several mesoscale features of one of the storms, have been used to study the substantial changes which occurred in the stable oxygen isotopic composition (δ18O) of the precipitation at the two sites.At the beginning of the period of observation, a low level warm front lay across the region and its elevation lowered with time from 2.5 km to 1.7 km. This decrease of the frontal surface height was accompanied by a steady increase in the δ18O values.In the pre-cold frontal passage time periods, the δ18O values at the upwind site signified warmer origin ice crystal morphology than the downwind site. This is explained by orographic effects and the production of supercooled liquid water at low elevations on the upslope side of the Sierra Nevada.During the passage of the surface cold front, the differences in δ18O at the two sites were quite small probably because the orography plays a less significant role in the precipitation production process during such events.The δ18O peaked around −13% which translates to an “equivalent temperature” of −10.7°C for ice phase water capture at the upwind site KV. At site HM downwind of the Sierra crest, and 25 km east of KV, the weighted mean ice phase water capture occurred at elevations some 5 to 6°C colder than at KV, because of subsidence and loss of supercooled liquid water in the lower elevations on the lee side.  相似文献   

6.
On February 8, 1993, the NASA DC-8 aircraft profiled from 10,000 to 37,000 feet (3.1–11.3 km) pressure altitude in a stratified section of tropical cyclone “Oliver” over the Coral Sea northeast of Australia. Size, shape and phase of cloud and precipitation particles were measured with a 2-D Greyscale probe. Cloud/ precipitation particles changed from liquid to ice as soon as the freezing level was reached near 17,000 feet (5.2 km) pressure altitude. The cloud was completely glaciated at −5°C. There was no correlation between ice particle habit and ambient temperature. In the liquid phase, the precipitation-cloud drop concentration was 4.0 × 103 m−3, the geometric mean diameter Dg=0.5−0.7 mm, and the liquid water content 0.7−1.9 g m−3. The largest particles anywhere in the cloud, dominated by fused dendrites at concentrations similar to that of raindrops (2.5 × 103 m−3) but a higher condensed water content (5.4 g m−3 estimated) were found in the mixed phase; condensed water is removed very effectively from the mixed layer due to high settling velocities of the large mixed particles. The highest number concentration (4.9 × 104 m−3), smallest size (Dg=0.3−0.4 mm), largest surface area (up to 2.6 × 102 cm2 m−3 at 0.4−1.0 g m−3 of condensate) existed in the ice phase at the coldest temperature (−40°C) at 35,000 feet (10.7 km). Each cloud contained aerosol (haze particles) in addition to cloud particles. The aerosol total surface area exceeded that of the cirrus particles at the coldest temperature. Thus, aerosols must play a significant role in the upscattering of solar radiation. Light extinction (6.2 km−1) and backscatter (0.8 sr−1 km−1) was highest in the coldest portion of the cirrus cloud at the highest altitude.  相似文献   

7.
Electrical charges on aerosol particles and droplets modify the droplet–particle collision efficiencies involved in scavenging, and the droplet–droplet and particle–particle collision efficiencies involved in coalescence of droplets and particles, even in only weakly electrified clouds and aerosol layers. This work places electrically enhanced scavenging, and the electrical inhibition of scavenging in the context of the microphysics of weakly electrified clouds.Collision efficiencies are calculated by numerical integration to obtain particle trajectories, that are determined by the complex interplay of electrical, gravitational and phoretic forces together with inertia. These modify the trajectory of a particle as it is carried by flow around the falling droplet. Conversely, the flow around the particle also modifies the trajectory of the droplet. The flows are specified analytically, using a hybrid of the Proudman–Pearson stream function for that region close to the droplet or particle, where it is accurate, merging into the exact Oseen stream function for larger distances, where that becomes accurate. The effect of the flow around the particle on the motion of the droplet was simulated using Langmuir's superposition technique on the hybrid stream functions. The treatment of inertia in the present calculations allows an extension of the scope of our previous work by a factor of 10 larger in particle size (103 in mass). The coverage is extended to a wide range of atmospheric conditions and particle densities.The pressures and temperatures used in the models ranged from a representation of the lower troposphere at  1 km altitude (900 hPa, 10 °C) to that of the middle stratosphere at  30 km altitude (12 hPa, − 47 °C). The particles considered range from 0.1 μm to 10 μm radius; the droplet radii range from 4 μm to 50 μm; particle densities range from 300 kg m 3 to 2500 kg m 3; particle charges range from 2e to 100e with droplet charges of like sign of 100e; and relative humidities range from 10% to 100%.For the larger particles (radii greater than about 3 μm) interacting with the larger droplets (radii greater than about 15 μm) the effects of inertia increase with particle density and dominate at the larger densities. For particles with radii in the range 1–3 μm the ‘Greenfield Gap’ of very low collision efficiencies was found, and was determined to be due to the effects of the gravitational force causing a reduction of collisions of particles with the front of the droplet, and the effect of inertia overcoming the tendency for the weight to produce a collision in the slow velocity region in the rear. When the electrical or phoretic forces are sufficiently large the Greenfield Gap is closed.When the particles have radii < 3 μm inertial effects no longer dominate the collisions, although inertia modifies the weight effects for particles with radii down to about 0.5 μm. For charged aerosol particles with radii smaller than about 0.1 μm interacting with droplets or background aerosol particles smaller than a radius of about 15 μm, the long range electrical repulsive force is effective in opposing the phoretic forces and keeping the particle out of range of the short range attractive image force. Thus ‘electroscavenging’ gives way to ‘electroprotection’ against the scavenging or coagulation processes otherwise caused by Browninan diffusion or phoretic forces.In an atmosphere of temperature 10 °C and pressure 900 hPa the net phoretic force reduces to zero and becomes repulsive for particles with radii above about 2 μm (depending on particle conductivity). This enhances the development of the Greenfield Gap. However, the value of this radius (at which the net phoretic force is zero) increases strongly with decreasing temperature and pressure (increasing altitude) as expected from theory, and is about 5 μm in the middle troposphere and more than 10 μm in the stratosphere. Thus a net attractive phoretic force on particles extends into the 1–3 μm radius range in the upper troposphere; however, the weight and inertial effects can ensure the presence of the Greenfield Gap in that range for 2000 kg m 3 particles up to the middle stratosphere.  相似文献   

8.
Some cloud condensation nuclei (CCN) constitute a reservoir of latent ice-forming nuclei (IFN) active by condensation-followed-by-freezing and by sorption. Evaporated droplets occasionally left aerosol particles that acted as sorption IFN at temperatures as high as −5°C and water vapor supersaturation over ice of 0.2%. The newly formed aerosol particles (residues of evaporated droplets) are all mixed particles. The discovery of IFN produced from CCN promotes new insights into the process of ice formation in clouds; in an evaporating parcel of a cloud the rate of formation of ice particles will be enhanced by continuous production of IFN. Aerosol particles left behind after evaporation of a cloud may provide a source of IFN for formation of some of the cirrus clouds.  相似文献   

9.
The paper focuses on the redistribution of aerosol particles (APs) during the artificial nucleation and subsequent growth of ice crystals in a supercooled cloud. A significant number of the supercooled cloud droplets during icing periods (seeding agents: C3H8, CO2) did not freeze as was presumed prior to the experiment but instead evaporated. The net mass flux of water vapour from the evaporating droplets to the nucleating ice crystals (Bergeron–Findeisen mechanism) led to the release of residual particles that simultaneously appeared in the interstitial phase. The strong decrease of the droplet residuals confirms the nucleation of ice particles on seeding germs without natural aerosol particles serving as ice nuclei. As the number of residual particles during the seedings did not drop to zero, other processes such as heterogeneous ice nucleation, spontaneous freezing, entrainment of supercooled droplets and diffusion to the created particle-free ice germs must have contributed to the experimental findings. During the icing periods, residual mass concentrations in the condensed phase dropped by a factor of 1.1–6.7, as compared to the unperturbed supercooled cloud. As the Bergeron–Findeisen process also occurs without artificial seeding in the atmosphere, this study demonstrated that the hydrometeors in mixed-phase clouds might be much cleaner than anticipated for the simple freezing process of supercooled droplets in tropospheric mid latitude clouds.  相似文献   

10.
Data for this study were collected by the instruments mounted on the NCAR King Air and rawinsonde during the First ISCCP (International Satellite Cloud Climatology Project) Regional Experiment (FIRE) on 19 October, 1986. The main purpose of this study is to understand the basic concept of evaporative cooling in a dry layer below a cirrus generating cell. Relative humidity with respect to liquid water RHW and temperature lapse rate γe below the cirrus base at about 6.7 km were about 40% and 3.7°C km−1, respectively. Evaporative cooling rate (ECR) in the 1.5 km thick subcloud layer was estimated to be approximately 0.1 to 2°C h−1 and it was found to be comparable with the infrared heating rate calculated from radiation measurements. Because of ice crystal evaporation, RHW in the same layer may reach saturation with respect to ice in 1.5 hours.  相似文献   

11.
运用中尺度数值模式WRF3.5.1对2011年1月1日贵州境内的一次冻雨天气过程进行了数值模拟,研究了本次过程的大气层结、冻雨区云系的宏微观结构和云物理特征,初步分析了冻雨形成的云微物理过程和成因。结果表明,贵州境内的冻雨区(26°N~29°N)具有冷性和部分"冷—暖—冷"的温度层结,在高层没有显著的冰相粒子,冻雨区是相对较强的水汽辐合中心,丰富的水汽输送在冷性的环境条件下形成云滴,进而碰并产生雨滴,过冷雨水主要通过暖雨过程形成;雨滴继续下落至近地层并保持过冷雨水形式,最后接触到低于0°C的物体或地面,迅速冻结而产生地面冻雨。  相似文献   

12.
The concentrations of submicron aerosols in the size range 10−7 to 10−5 cm, also called Aitken nuclei (AN) were measured over the Indian Ocean enroute India-Antarctica-India within the 10°E–70°E longitude zone from about 10°N to 70°S latitude on board MV Thuleland during the period from November 26, 1986 to March 18, 1987 as part of the scientific activities on the Sixth Indian Antarctic Expedition. Our analyses showed that only in about 25% of the cases, AN count fell below 1000 cm−3. Throughout the tropical trade wind region, the concentrations of AN were relatively stable with an average of about 3000 cm−3 (medians of 2600 and 1700 cm−3 in Northern and Southern Hemispheres, respectively). Large AN concentrations were found to be associated with higher sea surface temperatures and stronger surface winds in this region. In contrast, the scatter of single observations was found to be remarkable over South Indian Ocean and in Antarctic waters. The average AN concentration over the Indian Ocean to the south of 30°S was of the order of 1500 cm−3. No definite correlation could be established between large AN concentration and sea surface temperature, wind speed or wave height. Period with very low concentrations were, however, associated with clear sky conditions and calm winds or light breeze. Many events of sudden short-lived but large increase in AN concentrations were observed over the south Indian Ocean and in Antarctic waters and these were always associated with the approach of frontal systems. It is likely that particle production by bursting bubbles and sea spray as well as photochemical reactions and gas-to-particle conversions play important role in the observed high concentration of AN over South Indian Ocean.  相似文献   

13.
The influence of freezing drizzle on wire icing during freezing fog events   总被引:2,自引:0,他引:2  
Both direct and indirect effects of freezing drizzle on ice accretion were analyzed for ten freezing drizzle events during a comprehensive ice thickness, fog, and precipitation observation campaign carried out during the winter of 2008 and 2009 at Enshi Radar Station (3017'N, 10916'E), Hubei Province, China. The growth rate of ice thickness was 0.85 mm h-1 during the freezing drizzle period, while the rate was only 0.4 mm h-1 without sleet and freezing drizzle. The rain intensity, liquid water content (LWC), and diameter of freezing drizzle stayed at low values. The development of microphysical properties of fog was suppressed in the freezing drizzle period. A threshold diameter (Dc) was proposed to estimate the inuence of freezing drizzle on different size ranges of fog droplets. Fog droplets with a diameter less thanDc would be affected slightly by freezing drizzle, while larger fog droplets would be affected signicantly. Dc had a correlation with the average rain intensity, with a correlation coefficient of 0.78. The relationships among the microphysical properties of fog droplets were all positive when the effect of freezing drizzle was weak, while they became poor positive correlations, or even negative correlations during freezing drizzle period. The direct contribution of freezing drizzle to ice thickness was about 14.5%. Considering both the direct and indirect effects, we suggest that freezing drizzle could act as a catalyst causing serious icing conditions.  相似文献   

14.
《Atmospheric Research》1988,22(2):149-181
A supercooled continuous flow, thermal gradient diffusion chamber has been developed to study the ice nucleating properties of natural or artificial aerosols. The chamber has concentric cylinder geometry with the cylinder axis alignment and airflow vertically downward. Sample airflow is 1 l min−1 and occupies the central 10% of the annular lamina; it is separated from the ice-covered walls by filtered sheath air. The wall temperatures are independently controlled over the range from about −4°C to −25°C, so that the vapor concentration at the location of the sample lamina can be set to a well defined value between ice saturation and a few percent water supersaturation. There is a range of temperature and supersaturation values across the sample region; for lamina center conditions of −15°C and +1% with respect to water, the range is −14.6 to −15.4°C and +0.53 to +1.31%. Errors in temperature control produce variations estimated as ±0.1°C and ±0.23%. Typical sample residence time is about 10 s. Ice crystals which form on active nuclei are detected optically at the outlet end of the chamber. To enhance the size difference between ice crystals and cloud droplets, the downstream 25% of the warm ice wall is covered with a thermally insulating vapor barrier which reduces the vapor concentration to ice saturation at the cold wall temperature, so cloud droplets evaporate.A mathematical model was developed to describe the temperature and vapor fields and to calculate the growth, evaporation, and sedimentation of water and ice particles. At 1% water supersaturation, the model predicts that ice particles will grow to about 5 μm diameter, and cloud droplets will achieve about 1 μm before they reach the evaporation section of the chamber. A different model was developed to describe the steady state airflow profile and location of the sample lamina.Experimental tests of the chamber were performed to characterize the airflow, to assess the ability of the technique to detect silver iodide ice nucleating aerosols and to distinguish ice crystals from water droplets.  相似文献   

15.
This study employed numerical simulations to explore the impact of varying ice nucleation processes on the microphysics and electrification within thunderstorm clouds. A two-dimensional cumulus model, incorporating both non- inductive and inductive charge separation schemes, was utilized. The findings revealed that the freezing nucleation mechanism significantly influenced the microphysical development, electrification, and charge structure of thunderstorms. Homogeneous freezing generated a large quantity of small ice crystals near the cloud tops, which were primarily re- sponsible for the development of positive charge regions through a non-inductive charging process. Conversely, hetero- geneous freezing resulted in larger ice crystals, enhancing graupel formation and leading to a more rapid and intense charge separation rate of around ?15°C. Ice crystals formed heterogeneously and charged negatively during the development stage, resulting in an inverted dipole charge structure. When both immersion and homogeneous freezing processes were considered, the competition between these two distinct freezing processes resulted in reduced cloud water content and weaker electrification. Under conditions of low cloud water content at lower storm levels, graupel particles were negatively charged through non-inductive charging, causing the charge structure to quickly revert to a normal dipole structure.  相似文献   

16.
Nitrite oxidation in the tropospheric aqueous phase by freezing was evaluated by freezing a field sample. Nitrite oxidation by dissolved oxygen in the freezing process is much faster than by other oxidation processes, such as reactions with ozone, hydrogen peroxide or dissolved oxygen in an aqueous solution at pHs 3 to –6. At pH 4.5 and 25°C, the lifetime of nitrite in the aqueous phase is ca. 1 hr in oxidation by ozone (6×10-10 mol dm-3), ca. 10 hr in oxidation by H2O2 (2×10-4 mol dm-3), and 7.5 hr (Fischer and Warneck, 1996) in photodissociation at midday in summer. Under the same conditions at a temperature below 0°C, the lifetime of nitrite in the freezing process is estimated as ca. 2 sec when the droplets are frozen within a second. The reaction by freezing is affected by the presence of salts, such as NaCl or KCl, or orgnaic compounds, such as methanol or acetone. The results of freezing a field rain or fog sample showed that nitrite oxidation proceeds below pH 6, and the conversion ratio of nitrate from nitrite increases with decreasing pH. The oxidation of nitrite by freezing was also observed in freezing fog particles generated by an ultrasonic humidifier. The ratios of the concentrations of ions in the winter sample to those in the summer sample (or those in the fog sample) were almost the same values. However, the concentration of nitrite in the winter sample was lower than that estimated by the ratios of other ions. From the present study, it seems that the freezing process plays an important role in the nitrite sink process in the tropospheric aqueous phase.  相似文献   

17.
In the present study, the precipitation near Büyükçekmece Lake, which is one of the important drinking water sources of Istanbul city, was studied during October 2001–July 2002. Seventy-nine bulk precipitation samples were collected at two sampling stations near the Lake (41°2′35″N, 28°35′25″E and 41°5′30″N, 28°37′7″E). The study comprised the determination of H+, Cl, NO3, SO42−, NH4+, Na, K, Mg, Ca, Al, Ba, Fe, Cu and Mn concentrations in bulk deposition rain event samples. The average volume-weighted pH value was found to be 4.81, which points out that the rain is slightly acidic. High sulfate concentrations were observed together with high H+ ion values. Sulfur emissions were the major cause for the observed high hydrogen ion levels. On the basis of factor analysis and correlation matrix analysis, it has been found that in this region, acid neutralization is brought about by calcium rather than the ammonium ion. The varimax rotated factor analysis grouped the variables into four factors, which are crustal, marine and two anthropogenic sources.  相似文献   

18.
Deposition of atmospheric particulate PCBs in suburban site of Turkey   总被引:2,自引:1,他引:2  
Dry deposition and air concentration samples were collected from July 2004 to May 2005 at a suburban site in Turkey. A water surface sampler (WSS) was used to measure directly the dry deposition flux of particulate polychlorinated biphenyls (PCBs) while a high volume air sampler (HVAS) was employed to collect air samples. Particulate PCB concentrations accounted for 15% of total PCBs (gas + particle phase) at the site. The overall particulate phase PCB flux ranged from 2 to 160 ng m− 2 d− 1 with an average of 46.3 ± 40.6 ng m− 2 d− 1. Forty one PCB congeners were targeted in the samples while twenty one congeners were found to be higher than detection limits in deposition samples. Fluxes for homolog groups ranged between 0.9 (7-CBs) and 21.0 (3-CBs) ng m− 2 d− 1. Measured dry deposition fluxes were lower than the ones usually reported for urban sites. Average PCB dry deposition velocity, calculated using flux values and concurrently measured atmospheric concentrations, was 1.26 ± 1.86 cm s− 1 depended on size distribution of particles, atmospheric PCB concentrations and meteorological conditions.  相似文献   

19.
GPS-synchronized measurements of electric (E) field changes induced by lightning flashes were recorded at six stations in the northeastern verge of the Tibetan Plateau. The height and magnitude of charge neutralized by 65 return strokes, including 16 negative cloud-to-ground (CG) flashes and 2 positive CG flashes, have been fitted with the nonlinear least-square method based on the E field changes of CG flashes observed in a typical thunderstorm with larger-than-usual lower positive charge center (LPCC). Results show that the height of the charge region neutralized by negative CG flashes ranges from 3 km to 5 km above the ground, corresponding to an ambient temperature between − 2 °C and − 15 °C. For the two positive CG flashes, the neutralized charge regions are located at a height of about 5.5 km and the ambient temperature is about − 18 °C, indicating the existence of upper positive charge in the thunderstorm.  相似文献   

20.
Land Surface Processes Experiment (LASPEX) was conducted over semi-arid region of western India in 1997. As a part of this program, wind and temperature observations were taken using slow as well as fast response sensors over a semi-arid station Anand (22°35′N, 72°55′E) situated in Gujarat state of India. Turbulent parameters such as drag coefficient and sensible heat flux were estimated using eddy correlation method and aerodynamic roughness length was estimated using wind profiles. The analysis has been carried out for the data representing summer, monsoon and winter seasons. It was found that the wind speed does not exceed 5 ms− 1 during the observational period considered in this study. Relationship of aerodynamic drag coefficient and roughness length with wind speed and stability has been investigated. Aerodynamic roughness length was greater in the stable conditions when the wind speed was low and it reduced drastically during convective conditions. The resulting values of aerodynamic roughness length and drag coefficient for the monsoon period agree well with values reported in literature over Indian subcontinent for homogeneous grass covered surfaces.  相似文献   

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