“Andesitic water”: a phantom of the isotopic evolution of water-silicate systems. Comment on “Isotopic shifts in waters from geothermal and volcanic systems along convergent plate boundaries and their origin” by W.F. Giggenbach

On account of the low porosity of the lithosphere, intracrustal fluids behave very differently from surface fluids, in that they are changing their geochemical and isotopic labels according to the geological environment. Given a heat source, meteoric waters can be supplied plentifully and their rates of throughput in geothermal systems are sufficiently high to exhaust the compositional signals of a given rock buffer. In contrast, fluids exsolved from magma, and subducted fluids, would be supplied at less than about one tenth of the meteoric rate over the life time of a system. Based on up-to-date flow models, the isotopic evolution of meteoric water interacting with crustal rock follows a curved to L-shaped track in the δD versus δ¹⁸O plot. Instantaneous (present-day) tie-lines between recharge and discharge are secants of such tracks and can have a range of slopes. At the start of an interaction, waters have δD and δ¹⁸O values approaching equilibrium with the original rock composition (water “W1”). Using known hydrogen isotope fractionation factors, W1 values generally plot in the region of “andesite” or “andesitic” waters of various authors. Since the W1 waters have δD values that are on average more positive, and also less variable than those of the meteoric recharges, most tracks and tie-lines have positive slopes, and the plotting of a large number of tie-lines will produce a focus on the field of W1 waters, regardless of the original water source.     

Magmatismes basiques dits “orogeniques” et “anorogeniques” et teneurs entro2: Les associations “Isotitanees” et “anisotitanfes”

The patterns of variation of TiO₂ conent during magmatic evolution are different in the so called “orogenic” and “anorogenie” basic associations; these last terms, which are the cause of much misunderstanding, can be replaced by the terms “isotitaniferous” and “anisotitaniferous”.     

Determination of hydraulic conductivity from auger holes and pits — An approximation

A steady-state solution is developed which relates saturated hydraulic conductivity to rate of rise in auger holes and pits of arbitrary geometries. The analysis assumes axial symmetric cavities and steady-state conditions and uses the solution for a disc source in infinite space together with the method of images. Numerical results and a table are presented for “arc” and “trapezoidal” shaped pits.     

The “wave turbopause”

The “wave turbopause” is defined as the mesospheric altitude level where the temperature fluctuation field indicates a substantial increase in wave amplitudes in the vertical direction.The turbopause altitude is analyzed on the basis of four years of SABER data (2002–2005, Version 1.06). Substantial seasonal and latitudinal variations are found, with some interannual variability also present. Seasonal changes are annual at high latitudes, semi-annual at low latitudes, and a mixture of both at middle latitudes. Southern hemisphere data are similar as in the North if shifted by half a year. Latitudinal variations show a minimum in the tropics and two relative maxima at middle latitudes.The “wave turbopause” is found near to zero-wind lines or low-wind zones (zonal wind). It is compared to rocket and other measurements, and interesting similarities are obtained. The wave turbopause can also be found in the HAMMONIA GCM. A preliminary analysis shows results similar to those of the SABER measurements.     

The measurement of water losses from a forested area using a “natural” lysimeter

Water losses due to transpiration and evaporation of intercepted water were measured using a “natural” lysimeter in the Hafren forest of central Wales, and were compared with estimates of potential evaporation calculated from meteorological observations. Given certain assumptions concerning the forest canopy, the lysimeter observations were used to estimate runoff from the experimental catchment of the Upper Severn, within which the lysimeter is sited; this estimate agreed well with observation.     

Use of Seismotectonic Information for the Seismic Hazard Analysis for Surat City, Gujarat, India: Deterministic and Probabilistic Approach

Surat, the financial capital of Gujarat, India, is a mega city with a population exceeding five millions. The city falls under Zone III of the Seismic Zoning Map of India. After the devastating 2001 Bhuj earthquake of Mw 7.7, much attention is paid towards the seismic microzonation activity in the state of Gujarat. In this work, an attempt has been made to evaluate the seismic hazard for Surat City (21.170?N, 72.830?E) based on the probabilistic and deterministic seismic hazard analysis. After collecting a catalogue of historical earthquakes in a 350?km radius around the city and after analyzing a database statistically, deterministic analysis has been carried out considering known tectonic sources; a further recurrence relationship for the control region is found out. Probabilistic seismic hazard analyses were then carried out for the Surat region considering five seismotectonic sources selected from a deterministic approach. The final results of the present investigations are presented in the form of peak ground acceleration and response spectra at bed rock level considering the local site conditions. Rock level Peak Ground Acceleration (PGA) and spectral acceleration values at 0.01?s and 1.0?s corresponding to 10% and 2% probability of exceedance in 50 years have been calculated. Further Uniform Hazard Response Spectrum (UHRS) at rock level for 5% damping, and 10% and 2% probability of exceedance in 50 years, were also developed for the city considering all site classes. These results can be directly used by engineers as basic inputs in earthquake-resistant design of structures in and around the city.     

Formation of diamond with mineral inclusions of “mixed” eclogite and peridotite paragenesis

Two unusual diamonds were studied from kimberlites from China, which contain both ultramafic and eclogitic mineral inclusions in the same diamond hosts. Diamond L32 contains seven Fe-rich garnets, four omphacites and one olivine inclusion. Four olivine, one sanidine and one coesite were recovered from diamond S32. Both garnet and omphacite inclusions have similar compositions as those from other localities of the world, and show basaltic bulk composition. All the garnet and omphacite inclusions in diamond L32 have positive Eu anomalies (Eu/Eu^*1.64 1.79). These observations support the proposal that mantle eclogite is the metamorphic product of subducted ancient oceanic crust. The Mg/(Mg + Fe) ratio of the olivine inclusions from the two diamonds (91-92) are evidently lower than the normal olivine inclusions in diamonds from the same kimberlite pipe (92-95). The following model is proposed for the formation of diamonds with “mixed” mineral inclusions. Ascending diamond-bearing eclogite (recycled oceanic crust) entrained in mantle plumes may experience extensive partial melting, whereas the ambient peridotite matrix remains subsolidus in the diamond stable field. This provides a mechanism for the transport of diamond from its original eclogitic host to an ultramafic one. Subsequent re-growth of diamond in the new environment makes it possible to capture mineral inclusions of different lithological suites. Partial melts of basaltic sources may interact with the surrounding peridotite, resulting in the relatively lower Mg/(Mg + Fe) ratios of the coexisting olivine inclusions from the studied diamonds. Diamonds with “mixed” mineral inclusions demonstrate that plume activity also occurred in the Archean cratons.     

Estimation of Seismic Site Coefficient and Seismic Microzonation of Imphal City,India, Using the Probabilistic Approach

Seismic site coefficients (F _s ) for Imphal city have been estimated based on 700 synthetically generated earthquake time histories through stochastic finite fault method, considering various combinations of magnitudes and fault distances that may affect Imphal city. Seismic hazard curves and Uniform Hazard Response Spectra (UHRS) are presented for Imphal city. F _s have been estimated based on site response analyses through SHAKE-91 for a period range of engineering interest (PGA to 3.0 s), for 5% damping. F _s were multiplied by UHRS values to obtain surface level spectral acceleration with 2 and 10% probability of exceedance in 50 year (～2500 and ～500 year) return period. Comparison between predicted mean surface level response spectra and IS-1893 code shows that spectral acceleration value is higher for longer periods (i.e., >1.0 s), for ～500 year return period, and lower for periods shorter than 0.2 s for ～2500 year return period.     

On the interest and the limits of using combined ESR/U-series model in the case of very late uranium uptake

Before ESR/U-series models were applied to ungulate teeth, it is generally assumed that calculated ages are close to the “real” ages when they range between the values obtained with the EU and LU models. When the samples show signs of uranium-leaching, a realistic mathematical modelling of the age is not possible. On the other hand, some samples have undergone a very late U-uptake “affecting” directly the U-series ages and rendering the calculated ages younger.

We present results obtained on two open-air sites, which show the limits of such combined models in the case of late uranium incorporation. For the Middle Pleistocene site of Isernia la Pineta (Italy), the ESR dates are expected to fall within the limits imposed by the Ar–Ar results. The other site, the Lower Palaeolithic deposits of Ambrona (Spain), yielded two sets of samples: some at the top of the sequence with uranium uptake ranging between EU and LU limits and thus giving a good idea of the “real” age of the site; others at the base displaying a very late U-uptake, which render an age determination difficult.     

Geomagnetic field variations between chrons 33r and 19r (83–41 Ma) from sea-surface magnetic anomaly profiles

Sea-surface magnetic profiles exhibit coherent short wavelength “micro-anomalies” (or “tiny wiggles”) superimposed to the main anomalies due to reversals. In this study, we investigate the nature and distribution of these tiny wiggles on oceanic crust formed during the  42 Myr-long period following the Cretaceous Normal Superchron. To this end, we compute stacks of anomaly profiles from different areas in the Indian and the Pacific oceans. Using a simple method based on upward continuation, we demonstrate that, the tiny wiggles are consistent worldwide although their patterns exhibit different resolutions at different spreading rates. They are therefore confidently ascribed to past fluctuations of the geomagnetic dipole moment. A high resolution record of these fluctuations is obtained by selecting and stacking profiles from areas with the highest spreading rates. Modeling the micro-anomalies as short magnetic polarity intervals yields durations for these intervals generally shorter than 10 kyr, likely too short to be indeed “true” subchrons. Moreover, the number of detected tiny wiggles clearly depends on the spreading rate. These results support geomagnetic intensity fluctuations as being the cause of most tiny wiggles, as also suggested by recent magnetostratigraphic data. The tiny wiggles are uniformly distributed within chrons, indicating that paleointensity fluctuations are neither inhibited after, nor enhanced before, a reversal beyond a “blind” zone of about 10 km (corresponding to 80 to 250 kyr depending on the spreading rate) for which the anomalies due to reversals prevent the detection of tiny wiggles. Most tiny wiggles probably represent a filtered record of a uniform secular variation regime, as suggested by their uniform spatial distribution over the whole investigated period.     

Evidence of nonlinear site response in HVSR from SMART1 (Taiwan) data

Deamplification of strong motion and the increase of the effective period of soil deposits are typical nonlinear effects; we seek them in SMART1-array data by applying the horizontal-to-vertical spectral ratio (HVSR) technique. The recordings, from four soil and one rock stations, represent 23 earthquakes (M_L 4.9–7.0); PGA varies between 20–260 cm/s². For each station, mean HVSR curves are calculated for two PGA ranges: <75 cm/s² and >100 cm/s² (weak and strong motion). At the soil stations, the “weak” (linear) and “strong” (nonlinear) responses are significantly different. Below 1–1.8 Hz, the nonlinear response exceeds the linear one. Above 2 Hz, the nonlinear response drops below the linear one and above 4–6 Hz below unity (deamplification). From 10 to 16 Hz, the two responses converge. One soil site shows significant negative correlation between resonance frequency and ground acceleration. Such behaviour agrees with other empirical studies and theoretical predictions. Our results imply that the HVSR technique is sensitive to ground-motion intensity and can be used to detect and study nonlinear site response.     

Upon closer inspection…

Article VII of the Antarctic Treaty opens “all areas of Antarctica, including all stations, installation and equipment… at all times” to inspection by observers of all Contracting Parties. Article VII guarantees this right of inspection as a means to “promote the objectives and ensure the observance of the provisions” of the Treaty. Freedom of inspection strengthens the Treaty's core principles of peace and international cooperation and more importantly, the provisions of Article IV temporarily reconcile the sovereignty issue between claimant and non-claimant states. To date, however, Article VII has been greatly underutilized as a means to better protect the Antarctic environment. Green-peace, through its experience in the Antarctic, has come to realize that a formal international inspectorate and regulatory authority is needed for compliance monitoring, comprehensive and long-term environmental baseline monitoring, information management and exchange, and the effective management of the natural resources and values of the entire Antarctic.     

Seismic hazard assessment of the Province of Murcia (SE Spain): analysis of source contribution to hazard

A probabilistic seismic hazard assessment of the Province of Murcia in terms of peak ground acceleration (PGA) and spectral accelerations [SA(T)] is presented in this paper. In contrast to most of the previous studies in the region, which were performed for PGA making use of intensity-to-PGA relationships, hazard is here calculated in terms of magnitude and using European spectral ground-motion models. Moreover, we have considered the most important faults in the region as specific seismic sources, and also comprehensively reviewed the earthquake catalogue. Hazard calculations are performed following the Probabilistic Seismic Hazard Assessment (PSHA) methodology using a logic tree, which accounts for three different seismic source zonings and three different ground-motion models. Hazard maps in terms of PGA and SA(0.1, 0.2, 0.5, 1.0 and 2.0 s) and coefficient of variation (COV) for the 475-year return period are shown. Subsequent analysis is focused on three sites of the province, namely, the cities of Murcia, Lorca and Cartagena, which are important industrial and tourism centres. Results at these sites have been analysed to evaluate the influence of the different input options. The most important factor affecting the results is the choice of the attenuation relationship, whereas the influence of the selected seismic source zonings appears strongly site dependant. Finally, we have performed an analysis of source contribution to hazard at each of these cities to provide preliminary guidance in devising specific risk scenarios. We have found that local source zones control the hazard for PGA and SA(T ≤ 1.0 s), although contribution from specific fault sources and long-distance north Algerian sources becomes significant from SA(0.5 s) onwards.     

A new seismic hazard assessment in the region of Andalusia (Southern Spain)

A probabilistic seismic hazard assessment of Andalusia (Southern Spain) in terms of peak ground acceleration, PGA, and spectral accelerations, SA(T), is presented in this paper. In contrast to most of the previous studies in the region, which were performed for PGA, making use of Intensity-to-PGA relationships, hazard was here calculated in terms of magnitude, using published spectral ground-motion models. Moreover, we considered different ground-motion models for the Atlantic sources, since the attenuation of those motions seems to be slower, as evidenced in the case of the extensive macroseismic areas of earthquakes like those occurred in the years 1755, 1969 and 2007. A comprehensive review of the seismic catalogue and of the seismogenic models proposed for the region was carried out, including those for Northern Africa, which is part of the influence area. Hazard calculations were performed following the Probabilistic Seismic Hazard Assessment (PSHA) methodology using a logic tree, which accounts for six different seismic source zonings and five different ground-motion attenuation relationships. Hazard maps in terms of PGA and SA (0.2 s) and SA (1 s) and coefficient of variation (COV) maps, for the 475-year return period were first obtained in rock sites. A geotechnical classification and amplification factors were proposed and new hazard maps including local effects were represented, showing PGA values ranging from 24 to 370 cm/s² for the whole Andalusian territory, with the highest expected values (PGA > 300 cm/s²) in some parts of the Granada Province and in the town of Vélez Málaga. Lowest values (PGA < 50 cm/s²) correspond to some towns of the Huelva and Córdoba provinces. The inclusion of soil effects provides a more detailed picture of the actual hazard the region is subjected to.     

From regional seismic hazard to “scenario earthquakes” for seismic microzoning: A new methodological tool for the Celano Project

We present the results of a probabilistic seismic hazard assessment and disaggregation analysis aimed to understand the dominant magnitudes and source-to-site distances of earthquakes that control the hazard at the Celano site in the Abruzzo region of central Italy. Firstly, we calculated a peak ground acceleration map for the central Apennines area, by using a model of seismogenic sources defined on geological-structural basis. The source model definition and the probabilistic seismic hazard evaluation at the regional scale (central Apennines) were obtained using three different seismicity models (Gutenberg–Richter model; characteristic earthquake model; hybrid model), consistent with the available seismological information. Moreover, a simplified time-dependent hypothesis has been introduced, computing the conditional probability of earthquakes occurrence by Brownian passage time distributions.Subsequently, we carried out the disaggregation analysis, with a modified version of the SEISRISK III code, in order to separate the contribution of each source to the total hazard.The results show the percentage contribution to the Celano hazard of the various seismogenic sources, for different expected peak ground acceleration classes. The analysis was differentiated for close (distance from Celano <20 km) and distant (distance from Celano >20 km) seismogenic sources. We propose three different “scenario earthquakes”, useful for the site condition studies and for the seismic microzoning study: (1) large (M=6.6) local (Celano-epicentre distance 16 km) earthquake, with mean recurrence time of 590 years; (2) moderate (M=5.5) local (Celano-epicentre distance 7.5 km) earthquake, with mean recurrence time of 500 years; and (3) large (M=6.6) distant (Celano-epicentre distance 24 km) earthquake, with mean recurrence time of 980 years.The probabilistic and time-dependent approach to the definition of the “scenario earthquakes” changes clearly the results in comparison to traditional deterministic analysis, with effects in terms of engineering design and seismic risk reduction.     

Review study on near-natural conditions of Central European mountain streams, with particular reference to debris and beaver dams: Results of the “REG meeting” 2000

This paper summarises the results of the “Rhithron Ecology Group” meeting in Essen (March 2000), supplemented by a literature evaluation.An extended view of small mountain streams in Central Europe under “potentially natural conditions” is presented. We focus on the potential impact of natural transverse structures (debris dams and beaver dams) on stream morphology, hydrology, habitat composition and communities. Furthermore, impact of other stream morphological features, which are presently lacking in the Central European landscape, is described.We suggest that Central European mountain streams are characterised by a higher proportion of lentic zones under “potentially natural conditions”. Morphological degradation leads to a loss of lentic zones and to an increase of current velocities and corresponding changes in faunal composition, particularly higher abundance and proportion of rheophilic species and a decrease of species preferring lentic zones. This should be regarded in future stream assessment.     

Biomonitoring the Health of Coastal Marine Ecosystems – The Roles and Challenges of Microscale Toxicity Tests

Coastal marine ecosystems in many parts of the world are under unrelenting stress caused by urban development, hazardous or toxic substances, overfishing, habitat destruction, the introduction of exotic species and natural toxins. Biomonitoring plays a vital role in governmental and industrial strategies to identify, assess, control and reduce these problems. Sensitive and practical techniques in biomonitoring are needed in all of the strategic approaches – from toxic chemical rating and classification, to pollution source control, status and trends monitoring, and assessments of “marine ecosystem health”. Due to the shear magnitude and scope of the challenge, biomonitoring coastal ecosystems demands new and innovative approaches that are relatively easy and cheap to deploy and that provide timely and accessible information to environmental managers and policy makers.

This paper explores recent developments in microscale toxicity testing – a branch of aquatic toxicology involving the discovery and application of small-scale, innovative, sensitive, practical, inexpensive and frequently automated biological techniques. Highlights of a recent unique synthesis ([Reference to Wells et al., 1998]) are given, describing microscale tests at various biological and phylogenetic levels. Many of these tests are marine and focus on gametes, embryos and other young life stages. They can be utilized in the field (in vivo), with field collected samples, and in the laboratory. Their low cost, sensitivity, practicality and speed are their strengths, and commercial test kits have been developed as a result. But being largely “single-species” and sub-individual-level biomonitors, do such microscale tests provide information directly useful to protecting vital ecosystem processes? Indeed, how can this question be addressed? The needs and challenges of matching the most promising of the microscale tests with higher level (population, community, ecosystem) measurements to protect habitats and biodiversity are discussed. Improving marine biomonitoring and protecting coastal ecosystem health demands such new techniques within the context of new paradigms and rigorous approaches for their application.     

Ökologische Bewertung von Tieflandbächen des Ladberger Mühlenbach-Systems im Norddeutschen Tiefland, basierend auf der Standorttypie der Trichopterenbiozönosen

In the last few years ecological evaluation of lowland freshwaters was controversely discussed. Due to the fact that most basic information of assessment systems derived from upland streams, the results could not be applied to the lowland situations. Additionally, it is not sufficient for an integral freshwater evaluation only to focus on the stream to show degradation in the tight coupling of running waters and their adjacent landscape. In this study we critically tested a new method, the Standorttypie-Index (STI), to assess lowland streams using caddis-fly communities.

During 1994 and 1996 we investigated the caddisfly community at 15 sampling sites of a river system in the “Westfälische Tieflandbucht” (Northrhine-Westphalia, Germany). As a result we found 72 species belonging to 16 families of the order Trichoptera. The calculation of the “Standorttypie-Index” is based on four defined ecological categories. Although the definitions were inaccurate, each species was classified into one category. In view of stream regulation and streamwidth, we calculated for all study sites the STI of the immature stages, the adults and a combined total STI.

Although there is a correlation between the “Standorttypie-Index” and the state of degradation of the study sites, the separate analysis of larval and adult communities showed that the results easily lead to misinterpretation. The STI of adults devalues the combined total STI of regulated as well as natural study sites. As a consequence, until now it is not possible to evaluate the state of degradation in the coupling of the stream and the adjacent landscape using the STI of the caddis-fly community.     

Errors and uncertainty in physically-based rainfall-runoff modelling of catchment change effects

The error in physically-based rainfall-runoff modelling is broken into components, and these components are assigned to three groups: (1) model structure error, associated with the model’s equations; (2) parameter error, associated with the parameter values used in the equations; and (3) run time error, associated with rainfall and other forcing data. The error components all contribute to “integrated” errors, such as the difference between simulated and observed runoff, but their individual contributions cannot usually be isolated because the modelling process is complex and there is a lack of knowledge about the catchment and its hydrological responses. A simple model of the Slapton Wood Catchment is developed within a theoretical framework in which the catchment and its responses are assumed to be known perfectly. This makes it possible to analyse the contributions of the error components when predicting the effects of a physical change in the catchment. The standard approach to predicting change effects involves: (1) running “unchanged” simulations using current parameter sets; (2) making adjustments to the sets to allow for physical change; and (3) running “changed” simulations. Calibration or uncertainty-handling methods such as GLUE are used to obtain the current sets based on forcing and runoff data for a calibration period, by minimising or creating statistical bounds for the “integrated” errors in simulations of runoff. It is shown that current parameter sets derived in this fashion are unreliable for predicting change effects, because of model structure error and its interaction with parameter error, so caution is needed if the standard approach is to be used when making management decisions about change in catchments.