Rock moisture content in the field and the laboratory and its relationship to mechanical weathering studies

Rock moisture content is a major control of mechanical weathering, particularly freeze-thaw, and yet almost no data exist from field situations. This study presents moisture content values for rocks, taken from a variety of positions and conditions, in the maritime Antarctic. Additional information regarding the amount of water the rock could take up, as observed from laboratory experiments, is also presented. The results show that the approaches used in simulation experiments, particularly that of soaking a rock for 24 hours, may produce exaggerated results. It was found that the saturation coefficient (S-value) was a good indicator of frost susceptibility (based on water content) but that the derivation of that value may underestimate the potential of some rocks. The distribution of moisture within rocks is seen as an important, but unkown, factor. The results of these field moisture contents suggest that for simulations of freeze-thaw or hydration to be meaningful then they should have rock water contents based on field observations.     

Frost weathering and the saturation of coastal rocks

Measurements were made of the water content in coastal rocks, by simulating tidal oscillations in the laboratory, and by field measurement in eastern Canada. If rapid freezing takes place upon exposure to the air, saturation levels may be high enough to permit frost weathering in fine grained rocks in the lower portions of the intertidal zone. Near the high tidal level, however, it may be dependent upon a supply of water from the ice foot and from melting snow. If freezing is slow, frost action may be inhibited by desorption of the rocks while they are exposed by the ebb tide. There was no evidence of a level of permanent sea water saturation within the intertidal zone. Ambient temperature and humidity may affect the rate of rock desorption.     

青海省扎日根结扎群火山岩形成时代及构造背景分析

青海扎日根结扎群火山岩中基性岩以贫硅、钾,高钛、钙,中性岩类以低硅、中钾、钛、钙,酸性岩类以高硅、钾,中钛,低钙为特征。根据Fe＊/MgO-TiO2图解上显示出本区火山岩绝大多数火山岩落在岛弧区。微量元素中Th/Nb=0.9〉0.11,Nb/Zr〉0.04显示出其构造背景为陆-陆碰撞形成的岛弧区。扎日根结扎群火山岩时代Rb-Sr同位素等时线给出的年龄为231±28Ma和225±8 Ma,属晚三叠世。另外Sr同位素的初始比值ISr=0.70522±0.00023,小于0.719,表明岩浆（原始）来源于上地幔,并且在上升的过程中受到地壳的混染。     

南海北部陆区岩石磁化率的矿物学研究

基于2517套现场测量资料,245块岩石样品的体积磁化率测量和详细的岩矿鉴定及硅酸盐全分析结果,结合单矿物磁化率特征及各岩石之间的对比研究,发现岩石磁化率主要受组成岩石的矿物磁化率控制.即岩石磁化率(κr)与组成岩石各个矿物磁化率(κ1)及其体积含量(C2)成正比.例如侵入岩磁化率,κr=-5.68×102Cq+2.8...     

Continental hydrothermal sedimentary siliceous rock and genesis of superlarge germanium (Ge) deposit hosted in coal: A study from the Lincang Ge deposit,Yunnan, China

The study on marine hydrothermal sedimentationtends to be perfect at present, and a suit of hydrother-mal sedimentary distinguishing criterions (includingstructure, conformation, geochemistry, etc.) has beenfound[1—12]. While it is unsubstantial on the study ofhydrothermal sedimentation in continental deposi-tional environment, and little was known about therelation between continental hydrothermal sedimenta-tion and metal mineralization. The Lincang Ge deposit,hosted in coal with independent…     

Ultrahigh pressure (>7 GPa) gneissic K-feldspar (-bearing) garnet clinopyroxenite in the Altyn Tagh, NW China: Evi- dence from clinopyroxene exsolution in garnet

Since the ultra-high pressure metamorphic rocks with coesite and diamond indicators,which are formed under the condition of deep-subduction of continental crust,have been recognized[1―4],exsolution structures of the ultra-high pressure minerals such as pyroxene,olivine,garnet and sphene in the various kinds of rocks have attracted the great interests and attention of many researchers[5―18].Some exsolution structures,such as clinopyroxene+rutile+apatite[13]or quartz+rutile+apatite[15]exsolutio…     

Presence of carboxylate salts in marine carbonate strata of the Ordos Basin and their impact on hydrocarbon generation evaluation of low TOC, high maturity source rocks

The total organic carbon(TOC)in the marine source rock of the Ordos Basin mostly ranges from 0.2%to 0.5%.The industrial standard commonly states that the TOC value has to be no less than 0.5%(0.4%for high mature or over-mature source rock)to form large petroleum reservoirs.However,gas source correlation indicates that the natural gas in the Jingbian gas field does receive contribution from marine source rocks.In order to determine the effect of carboxylate salts(or called as organic acid salts)on TOC in highly mature source rocks with low TOC value,we sampled the Ordovician marine source rock and the Permian transitional facies source rock in one drilled well in the southern Ordos Basin and performed infrared and GC-MS analysis.It is found that both kerogen-derived organic acids and carboxylate salt-conversed organic acids exist in both marine and transitional facies source rocks.The carboxylate salt-conversed organic acids mainly come from the complete acidification of carboxylate salts,which confirms the presence of carboxylate salts in the marine source rocks.Although the C16:O peak is the main peak for the organic acids both before and after acidification,the carboxylate salt-conversed organic acids have much less relative abundance ahead of C16:O compared with that of the kerogen-based and free organic acids.This observation suggests that the kerogen-based and free organic acids mainly decarboxylate to form lower carboxylic acids,whereas the carboxylate salt-conversed organic acids mainly break down into paraffins.By using calcium hexadecanoate as the reference to quantify the kerogen-derived and carboxylate salt-conversed organic acids,the high TOC(>2.0%)marine source rocks have low carboxylate salt content and the low TOC(0.2%–0.5%)marine source rocks contain high content of carboxylate salt.Therefore,for the marine source rocks with 0.2%–0.5%TOC,the carboxylate salts may be a potential gas source at high maturity stage.     

Domains and enrichment mechanism of the lithospheric mantle in western Yunnan: A comparative study on two types of Cenozoic ultrapotassic rocks

West Yunnan is made of the Yangtze Craton, theSouth China Block, the Indochina Block and severalother micro-terranes formed at different times. It iscross-cut by the NW-SE-trending Ailao Shan-RedRiver (ASRR) fault, which runs over 1000 km fromthe eastern margin of the Qinghai-Tibet Plateau,through Vietnam and to the North Gulf (fig. 1). TheASRR fault is an important geological and topog-raphic boundary in East Asia. The sinistral movementof the Indochina Block along this fault ev…     

Characteristics of hydrocarbon generation and expulsion in matrix and stylolite of carbonate rocks

Characteristics of organic matter content, hydrocarbon generation and expulsion of carbonate rocks are discussed by analysis of organic carbon and pyrolysis. There is a strong inhomogeneity in distribution of organic matter in carbonate rocks. The organic matter abundance is higher in stylolites, carbonate varves or marls, while it is the lowest in matrixes (purer carbonate rocks around stylolites). Because of stable thickness and broad area, marls and carbonate varves may become good source rocks. At the same depth, stylolites, carbonate varves and matrixes generate and expel hydrocarbons almost at the same time. Expulsion efficiency of carbonate varve is the highest; that of rnatrixes is the lowest and that of stylolites is between marl’s or carbonate varve’s and matrix’s. Project supported by the Science and Technology Research of the 9th Five-Year Plan from China National Petroleum & Gas Company.     

泥质含量及其分布形式对岩电关系影响的数字岩心仿真(英文)

由于泥质所造成的附加导电现象,泥质含量及其分布形式对电阻率增大系数I和含水饱和度Sw关系具有重要影响,由于岩石物理实验中岩心孔隙结构及其组分构成、分布的微观不可调性,因而泥质分布形式所造成的影响很难通过岩心实验来单独研究。基于数字岩心的格子气自动机方法是一种有效的微观数值模拟方法,本研究利用储层岩心薄片的骨架颗粒尺寸信息资料建立数字岩心模型,结合格子气自动机技术对数字岩心不同饱和流体情况下电的传输特性进行数值模拟研究,揭示了不同泥质含量和泥质分布形式对孔隙介质导电特性非阿尔奇现象产生的影响,建立饱和度指数和泥质含量之间的关系模型,其良好的吻合性表明该方法在岩石物理研究中是一种十分有效的研究方法,而新模型适于在非阿尔奇储层进行准确的饱和度评价。     

Origin of volcanic rocks from Stromboli (Italy)

Quaternary volcanic rocks of Stromboli (Italy) can be divided into older calc-alkaline and younger shoshonitic series. The SiO₂ contents of the rocks range from 50% to 61% but the majority of them are basalts. The rocks show systematic variations in chemical composition which correlate with the volcanic stratigraphy, such that, at a given SiO₂ content, K and other incompatible elements such as REE increase with decreasing age. In addition, the La/Yb ratio increases while the K/Rb, K/Ba, Zr/Ce and Zr/Nb ratios decrease towards the top of the volcanic pile. On the other hand, the abundances of transition elements, V, Co, Sc and Zn, like most major elements are broadly similar in comparable rocks of different ages. It is suggested that the parent magmas were derived by partial melting from upper mantle peridotite enriched in incompatible elements by fluids released from the descending oceanic lithosphere. The temporal chemical variations may probably be related to the lengths of time during which fluids were in contact with the upper mantle source.     

Characterization of the Mefjell plutonic complex from the Sør Rondane Mountains, East Antarctica: Implications for the petrogenesis of Pan-African plutonic rocks of East Gondwanaland

Abstract The Mefjell plutonic complex consists of 500–550‐Ma Pan‐African plutonic rocks, which intrude into the Precambrian crystalline basement in the Sør Rondane Mountains, East Antarctica, and forms part of the Sør Rondane Suture Zone. The complex comprises syenitic and granitic (mostly monzogranitic) rocks, and is characterized by the presence of iron‐rich hydrous mafic minerals and primary ilmenite, both of which imply its formation at high temperature and under low oxygen fugacity conditions. The syenitic rocks are metaluminous, and are high in alkalis, K₂O/Na₂O, Al₂O₃, FeO_t/(FeO_t + MgO) (0.88–0.98), K/Rb (800–1000), Ga (18–28 p.p.m.), Zr (up to 2100 p.p.m.) and Ba. They also have a low Mg? (Mg/[Mg + Fe²⁺]), Rb, Sr, Nb, Y and F, low to moderate light rare earth element (LREE)/heavy rare earth element (HREE) ratios and positive Eu anomalies in their rare earth element (REE) patterns. The granitic rocks are metaluminous to peraluminous, and have a high Rb content, high Sr/Ba and LREE/HREE ratios, low K/Rb and negative Eu anomalies. Most of the syenitic and granitic rocks have Y/Nb ratios greater than 1.2, and are depleted in Nb, Ti and Sr on the primitive mantle‐normalized spider diagrams, indicating a crustal origin with subduction zone signatures. We interpret both the syenitic and granitic rocks to be derived from an iron‐rich lower crustal source by dehydration melting induced by the heat of mantle‐derived basaltic intrusion, after which they then underwent limited fractional crystallization. The Mefjell plutonic complex has a high Zr content and tectonic discrimination diagram signatures indicative of normal A‐type granitic rocks. Both rock suites may have been generated under the same postorogenic tectonic setting. The Mefjell syenitic rocks are chemically comparable to charnockites in the Gjelsvikjella and western Mühlig‐Hofmannfjella areas of East Antarctica, whereas the granitic rocks are comparable to aluminous A‐type granitic rocks in South India, which were emplaced during formation and evolution of the Gondwanaland supercontinent.     

AN EXPERIMENTAL STUDY ON WAVE VELOCITIES IN ROCKS FROM THE YANHUAI BASIN AND ITS GEOLOGICAL IMPLICATIONS

依据延怀盆地深部的地温地压条件，用模拟实验方法测定了该区代表性岩石的纵波和横波速度以及石英、角闪石在一定深度相变引起的波速变化，提出在中地壳同时具备低速高导的物质可能不是含石英多的岩石而可能是含水矿物多的岩石；讨论了研究区的地壳组成，认为上地壳的上部可能是由泥质灰岩一类的岩石组成，下部可能是由花岗闪长岩一类的岩石组成，没有低速高导层的地区可能是由花岗闪长岩和石英岩等组成，有低速高导层的地区可能由角闪岩相的岩石组成，下地壳可能由角闪片麻岩、中长麻粒岩、辉石麻粒岩等组成     

The seismomagnetic effect

Summary Local variations in the geomagnetic field, which are produced by stress changes in crustal rocks, are calculable from the stress patterns and the piezomagnetic properties of the rocks down to the Curie point isotherm. Release of stress during movement along a section of a transcurrent fault at an angle , measured clockwise with respect to the direction of magnetization of the rocks, produces a change in field similar to that which would be produced by the addition of a buried dipole of orientation (2±/2), the alternative signs applying to right- and left-lateral faults. Computed seismomagnetic anomalies of horizontal, vertical and total field are plotted for different fault orientations in simple geological environments. Time-dependent magnetic anomalies with magnitudes of the order 10 gammas may commonly accompany the build-up of stress before an earthquake and provide a pre-indication of it.     

中尺度流域次降雨洪水过程模拟——以太湖上游西苕溪流域为例

古近系沙河街组是阳信洼陷最重要的生烃层段.其湖盆充填具阶段性和沉积演化的旋回性,形成了由沙四段、沙三段与沙一段组成的复合生烃系统和不同的地球化学特征.利用Rock-Eval生油岩评价仪、色谱-质谱仪等实验分析技术对不同层系样品进行了地球化学特征分析研究,其中生烃潜力指标包括有机碳含量(TOC)、残余生烃潜量(S1 S2)、氢指数IH、氯仿沥青"A";成熟度指标包括热解峰温Tmax、奇偶优势参数OEP、饱和烃轻重比(C21 C22)/(C28 C29)及∑C21-/∑C22 、镜质体反射率Ro、莫烷/藿烷及甾烷生物标志物参数C29ββ(ββ αα)、C29ααα20S(20S 20R);古环境指标包括异构烷烃参数Pr/Ph、Pr/n-C17、Ph/n-C18及伽马蜡烷等.结果表明,沙四段为弱还原-还原性的半深湖沉积,沉积了一套中等厚度、分布局限的烃源岩(TOC平均为1.5%),其较深位置的烃源岩基本进入成熟阶段,多形成成熟油;沙三段属弱还原-还原性的半深湖-深湖环境,其烃源岩中有机质丰度较高(TOC平均为3.5%),大部分烃源岩处于未成熟-低成熟状态,主要形成未熟油;沙一段为湖水咸化、还原性的半深湖相环境,其烃源岩中有机质丰度高(TOC平均为5%左右),但处于未成熟阶段,主要生成生物气.     

Molecular and carbon isotopic compositions of gas inclusions of deep carbonate rocks in the Tarim Basin

Gaseous components of gas inclusions in deep carbonate rocks (>5700 m) from the Tacan 1 well were analyzed by online mass spectrometry by means of either the stepwise heating technique or vacuum electromagnetism crushing. The carbon isotopic compositions of gases released by vacuum electromagnetism crushing were also measured. Although the molecular compositions of gas inclusions show differences between the two methods, the overall characteristics are that gas inclusions mainly contain CO2, whilst hydrocarbon gases, such as CH4, C2H6 and C3H8, are less abundant. The content of CO is higher in the stepwise heating experiment than that in the method of vacuum electromagnetism crushing, and there are only minor amounts of N2, H2 and O2 in gas inclusions. Methane δ13C values of gas inclusions in Lower Ordovician and Upper Cambrian rocks (from 5713.7 to 6422 m; -52‰-63‰) are similar to those of bacterial methane, but their chemical compositions do not exhibit the dry character in comparison with biogenic gases. These characteristics of deep gas inclusions may be related to the migration fractionation. Some deep natural gases with light carbon isotopic characteristics in the Tazhong Uplift may have a similar origin. The δ13C1 values of gas inclusions in Lower Cambrian rocks (7117-7124 m) are heavier (-39‰), consistent with highly mature natural gases. Carbon isotopic compositions of CO2 in the gas inclusions of deep carbonate rocks are similar (from -4‰ to -13‰) to those of deep natural gases, indicating predominantly an inorganic origin.     

Rapid assessment of beta dose variation inside cobbles,and implications for rock luminescence dating

Variation in beta dose rate within rocks may impact the results of rock surface luminescence dating, for both the burial age of cobbles and exposure age of rock surfaces. Current methods of rock surface luminescence dating assume that radionuclides are homogeneously distributed inside rocks. In this study, two rapid methods based on beta counting and on a portable XRF instrument were developed to measure the radioactivity of rock slices. These methods were applied to rock slices from four glaciofluvial granite cobbles that had previously been used for equivalent dose determination to test whether beta dose variation could be observed. Results from beta counting and K content from XRF show similar patterns and both vary along the depth profiles, but the magnitude of this variability is very different amongst the four cobbles. In rocks where the dose rate is highly variable, bleaching may not be the only source of variation of L_n/T_n or equivalent dose (D_e) along the luminescence-depth profile of cobbles, and it may be necessary to measure the beta dose rate for every single slice to determine whether multiple bleaching events are recorded or variations in D_e are due to dose rate heterogeneity.     

Chemical characteristics of chromian spinel in plutonic rocks: Implications for deep magma processes and discrimination of tectonic setting

We summarize chemical characteristics of chromian spinels from ultramafic to mafic plutonic rocks (lherzolites, harzburgites, dunites, wehrlites, troctolites, olivine gabbros) with regard to three tectonic settings (mid‐ocean ridge, arc, oceanic hotspot). The chemical range of spinels is distinguishable between the three settings in terms of Cr# (= Cr/(Cr + Al) atomic ratio) and Ti content. The relationships are almost parallel with those of chromian spinels in volcanic rocks, but the Ti content is slightly lower in plutonics than in volcanics at a given tectonic environment. The Cr# of spinels in plutonic rocks is highly diverse; its ranges overlap between the three settings, but extend to higher values (up to 0.8) in arc and oceanic hotspot environments. The Ti content of spinels in plutonics increases, for a given lithology, from the arc to oceanic hotspot settings by mid‐ocean ridge on average. This chemical diversity is consistent with that of erupted magmas from the three settings. If we systematically know the chemistry of chromian spinels from a series of plutonic rocks, we can estimate their tectonic environments of formation. The spinel chemistry is especially useful in dunitic rocks, in which chromian spinel is the only discriminating mineral. Applying this, discordant dunites cutting mantle peridotites were possibly precipitated from arc‐related magmas in the Oman ophiolite, and from an intraplate tholeiite in the Lizard ophiolite, Cornwall.     

岩石标本受压时氡和钍射气量的实验结果

本文叙述继续过去已进行的工作[1],对岩石标本在实验室内加压,观测其氡和钍的射气量.所用实验装置与过去基本相同. 实验结果仍说明地下水中氡含量的变化作为地震的一种前兆现象是与岩石破裂有关,但局部地区的破裂过程、岩性等有差异,可使地震前后氡含量异常变化呈现多种状态.      

Archaean metallogeny: A synthesis and review

Granitoid rocks interspersed with greenstone belts together comprise Archaean cratons throughout the world. The greenstone belts contain a wide variety of volcanic rocks which, despite cyclical variations in composition, generally change from ultramafic komatiites toward the stratigraphic base of the successions, upward through tholeiitic basalts and calc-alkaline andesites, to silici-alkalic rhyodacites toward the top. These extrusive rocks are intruded by rocks of a similar wide compositional range, which are probably comagmatic and subvolcanic to the former. The volcanic rocks are also intercalated with, and flanked by, volcaniclastic and distinctive immature sedimentary strata, including turbiditic greywacke and polymictic conglomerate. All are products of the prolonged volcanism that dominated Archaean supracrustal evolution and metallogenesis.Rare element pegmatites are associated with the Archaean granitic intrusions. Four important types of metalliferous ores, iron-manganese, nickel-chrome, gold-silver and copper-zinc occur in the greenstone belts, often co-regionally with one another in the same mining districts. Algoma type iron-formations of oxide, carbonate, silicate and sulfide facies occur throughout the volcano-sedimentary successions from base suggest common genetic processes for these ores. The Algoma type iron-formations are chemical sedimerare chromite deposits are restricted to the stratigraphically lower, ultramafic komatiites. Important gold ores are hosted primarily in the tholeiitic basalts, particularly where these are intercalated with ankeritic-pyritic chemical sedimentary strata, but smaller gold deposits are also known in stratigraphically lower ultramafic and higher felsic volcanic rocks. The largest massive base metal sulfide deposits occur in the stratigraphically higher felsic rhyodacitic members.The close spatial associations between deposits of these metals in Archaean rocks, particularly those of certain nickel, gold and base metal ores with iron-formation, together with their many similar geological characteristics, suggest common genetic processes for these ores. The Algoma type iron-formations are chemical sedimentary precipitates from ferruginous hydrothermal fluids that were periodically discharged on the sea floor during the prolonged Archaean subaqueous volcanism. The massive base metal deposits are of similar origin, essentially Cu-Zn-rich varieties of sulfide-facies iron-formation. The auriferous cherty, ankeritic or pyritic chemical sedimentary strata were also formed by similar sea floor exhalative hydrothermal activity. Although seldom of mineable gold content themselves, these constituted important, pre-enriched source rocks for later metamorphic generation of gold veins. Although many of the nickel sulfide and chromite bodies are of magmatic generation, others closely associated with iron-formation, and themselves delicately interbedded with cherty or talc-carbonate laminae, may be due to similar sea floor hydrothermal discharge that accompanied ultramafic extrusive activity. Considering their close spatial and genetic links, the occurrence of any one of these four types of deposit suggests the possibility of the others wherever the favourable Archaean host rocks are present.Different Archaean cratons however, have differing proportions of these four types of deposit, and of their distinctive host rocks. Greenstone belts in all cratons throughout the world contain the iron-formations and gold deposits. Greenstone belts of southern Africa and Western Austrialia, however, have more abundant ultramafic rocks and more important nickel-chrome deposits. Some of them may be older than comparable belts in Canada which contain more rhyodacitic rocks and more important copper-zinc ores. Some belts of Brazil and West Africa may be still younger, contain more pyroclastic-volcaniclastic rocks, lack both the nickel-chrome and copper-zinc ores, but contain important manganese in their iron-formations. These relations suggest worldwide diachroneity of Archaean greenstone belt generation, late-Archaean granitic orogeny and ensuing Proterozoic sedimentation.