新疆喀拉通克Y1含矿岩体的岩石化学特征及其与成矿的关系

喀拉通克Ｙ１含矿岩体岩石类型属铁质基性岩类，岩体为单式岩体，具富镁、铁、碱、低钙贫铝的特点。组成岩体的各岩相是同一母岩浆结晶分异的产物。原始岩浆为来自上地幔的拉斑玄武岩浆。岩体锶初始比值约为０．７０３３，形成时代约为２９１Ｍａ。在岩浆结晶分异作用下，氧化物组分的变化使硫化物熔浆与硅酸盐熔浆发生分离，并在重力作用下聚积形成铜镍硫化物富矿。     

论内蒙古额仁陶盖银矿床成岩成矿模式

额仁陶盖银矿床是次火山热液作用产物。燕山晚期本区受太平洋板块边缘的影响,在已存断裂复活条件下,产生壳幔混合作用形成花岗质岩浆,该岩浆在地下浅处发生强烈的结晶分异作用,形成花岗岩和石英斑岩,两者是同一岩浆不同成岩阶段的产物。石英斑岩是成岩阶段的最后产物。分异作用导致银在成岩期及期后成矿热液中富集。矿床地质地球化学证据表明石英斑岩是矿体的直接母岩。地表大气水在成岩成矿中起着重要作用:①有助于发生基底岩石的部分熔融;②有助于岩浆的结晶分异并导致银在石英斑岩( 浆) 中的富集;③有利于形成大量的矿液。     

Pegmatite fluids of different origins and their implications for mineralization

Characteristics of ore-forming fluids as inferred from detailed studies of inclusions indicate that pegmatites may have different origins.For example,the granitic pegmatite at Mufushan is originated from magma differentiation at 1100-200℃,while the No.3 Pegmatite Vein in Xinjiang may owe its origin to a pegmatitic magma produced via metamorphic anatexis at 1140-200℃.Pegmatite fluids of the above two types are a melt-liquid system and may evolve into a solid-melt or solid-liquid system that would have a critical bearing on metasomatism and intergranular solutions.The Minxi pegmatite,on the oter hand,resulted from metamorphic differentiation,with its fluid(formed at 400-180℃）exhibiting many features of metamorphism.Pegmatites of different origins are distributed in tectonic units of different characters and are different bot in the nature of ore-foming fluid and in the source of ore-metals.This concept of polygene launches a challenge to the traditional belief that pegmatite is exclusively originated from magma differentiation and may be helphfou for the establishment of a new theory of pegmatite genesis.     

Experimental Test of Possible Formation of Diamond under the Differentiation of the Earth

The first results are presented for the synthesis of diamond at 6.5 GPa and 1600°C during migration of molten iron through a silicate matrix, which is composed of olivine crystals with interstitial graphite. The experiment shows that diamonds in the Earth’s mantle and the terrestrial planets could have formed during differentiation. Diamond crystals, which were formed during iron segregation of the Earth’s differentiation, could be centers for further crystallization of mantle diamonds.

     

The crystallisation and differentiation of a layered intrusion of hydrated alkali olivine-basalt parentage at Rhiw,North Wales

Three outcrops of hornblende-bearing basic intrusives at Rhiw, S.W. Lleyn, are considered to represent faulted remnants of a single larger intrusion. The layered rock series evolved by fractional crystallisation of hydrated alkali olivine-basalt magma which was emplaced as a number of distinct pulses. The trend of differentiation is similar to that for the Hawaiian series: alkali olivine basalt- hawaiite-trachyte. Consideration is given to the respective roles of pO₂ and pH₂O in controlling the course of differentiation.     

A high-pressure experimental study on the evolution of the silicic magmatism of the Main Ethiopian Rift

In this contribution we report the results of an experimental study that investigated equilibrium and fractional crystallization of hydrous, transitional alkaline basalt at low oxygen fugacity, under lower to middle crustal conditions to constrain the generation of subaluminous and peralkaline differentiation products that typically occur in rift systems. The experiments reveal that liquids produced by equilibrium crystallization in the range 0.7–1 GPa cannot cross the subaluminous/peralkaline compositional divide. In contrast, fractional crystallization experiments under isobaric and polybaric conditions approach closer the naturally observed trend from subaluminous to evolved peralkaline products suggesting that polybaric differentiation starting at elevated pressures can indeed lead to the transition from subaluminous to peralkaline derivative liquids. The presence of water in the parental magmas of silicic derivative products is of prime importance for the fractionation equilibria as well as for the mobility of such magmas toward shallow crustal levels.

We suggest that peralkaline magmas in rift environments are indicative for differentiation under relatively low oxygen fugacity conditions in an extensional environment characterized by a high degree of crustal fracturing that allows rapid upward migration of mafic parental magmas and formation of shallow magma reservoirs. Crystallization–differentiation of parental, hydrous transitional alkaline basalt in such reservoirs is controlled by low pressure phase equilibria that typically evolve through early saturation of anorthite-rich plagioclase and suppressed amphibole crystallization resulting in ‘low-alumina’, peralkaline derivative liquids.     

二红洼镁铁-超镁铁杂岩体特征及成因

新疆哈密二红洼镁铁-超镁铁杂岩体地表分南北两个岩体,深部可能连为一体,可划分为两个侵入期、四个岩相.第一侵入期构成岩体的主体部分,分异良好,由重力结晶分异形成自橄揽岩相、橄榄辉长岩相向含石英苏长辉长岩相的分异趋势,基性程度依次降低.岩浆多次贯入使得纵向上橄榄岩相和橄榄辉长岩相重复出现.第二侵入期辉长苏长岩相分异程度低,岩性稳定,为岩浆快速冷凝的产物.岩浆属于拉斑玄武岩系列,发生过金属硫化物熔离,有利于铜镍硫化物成矿.     

新疆哈密黄山铜镍硫化物矿床地质特征

黄山铜镍硫化物矿床产于黄山镁铁—超镁铁杂岩体中.岩体分异良好,由七个岩相带组成,主要矿体产于辉橄岩相底部,呈盆状;主要金属矿物有镍黄铁矿、黄铜矿、紫硫镍矿及磁黄铁矿;矿石大都为浸染状贫矿石.文中着重讨论成矿物质来源、成矿元素丰度.成矿物化条件及成矿过程和成矿模式.     

铜镍硫化物矿床成矿理论的新进展

岩浆深部液态重力分异成矿作用、岩浆同化混染成矿作用、矿浆成矿作用、岩浆分离结晶作用和热液作用对铜镍硫化物成矿有重要影响。岩浆深部液态重力分异成矿作用是原始含矿岩浆产生多样性岩浆和铜镍等成矿元素原始富集的重要原因,矿浆成矿作用则与岩浆深部液态重力分异成矿作用密切相关,是含矿岩浆成矿过程中的特殊地质事件。     

Lithological-geochemical differentiation of bottom deposits in the Angara cascade reservoirs

A long-term complex study of the Angara cascade reservoirs, the largest artificial reservoirs, showed that the bottom deposits were formed at the predominance of terrigenous influx. The compositional-structural and geochemical characteristics of various lithodynamic types of bottom sediments along a generalized transverse profiles testify that they represent a complex system with varying proportions of sandy, silty, and clayey particles and associations of chemical elements. As is indicated by the composition of the abraded rocks, the sedimentation settings, and the type of the lithological-geochemical differentiation of the bottom deposits, the scattering and differentiation of abrasion fluxes occurred simultaneously with the formation of new types of bottom sediments, whose composition was partially inherited from precursor rocks. It was established that the change in the lithodynamic settings in the Angara cascade reservoirs and the trend of the lithological-geochemical differentiation of the bottom sediments are governed by the same laws as in natural basins.     

津巴布韦大岩墙南段两翼铬铁矿床特征及成因探讨

津巴布韦大岩墙蕴含丰富的铬铁矿资源，不同部位成矿特征存在差异。钙碱性铁质基性-超基性岩浆结晶分异过程中伴随着铬铁矿的成矿作用，南部岩浆房两翼300 m深度范围内共赋存7个不连续的铬铁矿层，矿层垂向间距30~50 m，南部矿层发育优于北部；铬铁矿层厚度多为0.2~1 m，铬铁矿层发育于辉橄岩系和辉石岩系的接触部位，三者呈渐变式过渡接触，共同构成典型的韵律结构；两翼矿层产状呈对称状倾向于岩墙的轴部，倾角约为10°~20°；矿石多为自形-半自形微细粒结构，稀疏浸染状及中等浸染状构造，矿石为需选贫铬矿石，w（Cr₂O₃）=5%~30%，且矿体内Pt+Pd含量可观。大岩墙南段两翼铬铁矿为典型的早期岩浆结晶分异矿床，后期构造运动加剧了矿层的不连续性，并对局部岩矿层产状产生改造，蛇纹石化蚀变形成了指示矿体的标志性斑杂构造岩。     

Magma–carbonate interaction: An experimental study on ultrapotassic rocks from Alban Hills (Central Italy)

The Alban Hills ultrapotassic volcanic district is one of the main districts emplaced during Quaternary time along the Tyrrhenian margin of Italy. Alban Hills lava flows and scoria clasts are made up essentially of clinopyroxenes and leucites and their chemical composition is mostly K-foiditic. Differentiated products (MgO < 3 wt.%) are characterised by low SiO₂ concentration (< 50 wt.%) and geochemical features indicate that this unique differentiation trend is driven by crystal fractionation plus carbonate crust interaction. Notably, the Alban Hills Volcanic District was emplaced into thick limestone units. With the aim of constraining the magmatic differentiation, we performed experiments on the Alban Hills parental composition (plagioclase-free phono-tephrite) under anhydrous, hydrous, and hydrous-carbonated conditions. Experiments were carried out at 1 atm, 0.5 GPa and 1 GPa, temperatures ranging from 1050 to 1300 °C, and H₂O and CaCO₃ in the starting material up to 2 and 7 wt.%, respectively. The experiments performed at 0.5 GPa are the most representative of the Alban Hills plumbing system. Clinopyroxene and leucite are the main phases occurring under all the investigated conditions and the liquidus phases. Nevertheless, our experimental results demonstrate that the occurrence of CaCO₃ in the starting material strongly affects phase relations. Experiments performed under hydrous conditions crystallize magnetite and phlogopite at relatively high temperature. This early crystallization drives the glass composition towards a silica enrichment, resulting in a differentiation trend moving from phono-tephritic (Alban Hills parental composition) to phonolitic compositions. This is in contrast with micro-textural evidence showing late crystallization of magnetite and phlogopite in the natural products and with the composition of the juvenile products. On the contrary, in the CaCO₃-bearing experiments (i.e., simulating magma–carbonate interaction) the magnetite and phlogopite stability fields are strongly reduced. As a consequence, the melt differentiation is mainly controlled by the cotectic crystallization of clinopyroxene and leucite, resulting in a differentiation trend moving towards K-foiditic compositions. These experimental results are in agreement with micro-textural features and chemical compositions of Alban Hills natural products and with the magmatic differentiation model inferred by geochemical data. Magma–carbonate interaction is not a rare process and its occurrence has been demonstrated for different plumbing systems. However, the uniqueness of the Alban Hills liquid line of descent suggests that the efficacy of the carbonate contamination process is controlled by different factors, the dynamics of the plumbing system being one of the most important.     

月球的化学演化

月球是一个发生了化学分异的星球,它由月壳、月幔±一个小的金属月核组成。大量观察事实显示月球曾经有过岩浆洋,岩浆洋的结晶分异主导了月球的化学演化。目前主流观点认为,月球是在太阳系演化的早期,至少45亿年前,一个火星大小的星球,与即将完成原始吸积的地球胚胎发生偏心撞击,造成地球的熔融,形成岩浆洋,飞溅出来的物质迅速吸积形成绕地球运动的月球,并且在月球上形成了全球规模的岩浆洋,进而发生了结晶分异。,由于月球上没有海洋和板块俯冲,岩浆洋分异是其化学演化的主要途径。月球岩浆洋的80％～85％在大撞击后的100Ma内已经固化,这可能是由于月球体积小、表面没有大气包裹所致。月球极贫水,因此在岩浆结晶过程中斜长石首先结晶。斜长石由于密度小于玄武质岩浆而漂浮在岩浆洋的表层,橄榄石等密度大的矿物则堆积在岩浆洋的底部。随着结晶分异的进行,残余岩浆不断富集不相容元素,包括K、U等放射性元素;与此同时,密度较大的钛铁矿开始结晶,造成高钛堆晶岩密度大于其下的橄榄石堆晶岩的不稳定结构,进而发生月幔翻转,引发一系列岩浆活动,进而形成月球上特有的镁质系列、碱质系列等岩石。由于月球氧逸度较低,Eu主要以＋2价形式存在,因此斜长石高度富集Eu,相应地除高地斜长岩外,其他岩石均表现为Eu高度亏损的特点。与此同时,Re在低氧逸度下表现为强亲铁元素的特点,Re／Os在月球岩浆过程中不发生分异。月球的体积远小于地球,因而其演化时间远远短于地球,很多原始的分异被完整地保留下来。因此月球的化学演化是类地行星早期演化过程的“化石”,尽管与现代的地球存在较大差异,但是对于认识地球早期演化具有借鉴意义。     

铜官山地区矽卡岩型铜金矿床稀土元素特征及其成因意义

铜官山地区不同成因类型的矽卡岩发育，各自对应着不同成因类型的铜金矿床，且具有不同的稀土元素分布模式及演化特征，提供了矽卡岩矿床多成因的信息。     

小松山超基性杂岩体橄榄石的岩组分析

沿贺兰山台褶带北部西缘深大断裂带分布的小松山超基性杂岩体属岩浆结晶分异形成的似层状含铬岩体，岩组分析表明岩体中橄榄石具有高度的定向性。笔者通过研究认为，这种定向性系岩浆上侵过程中的流动分异作用影响造成，反映了小松山岩体系构造动荡环境下的产物。     

The behaviour of platinum-group elements in basalts from the East Greenland rifted margin

. The continental flood basalts of the East Greenland volcanic rifted margin were extruded during continental breakup above the ancestral Iceland mantle plume at 55 Ma. Three distinct magma types, the low-Ti, high-Ti and very high-Ti series (LTS, HTS and VHTS respectively), are found intercalated in the ~6-km-thick Plateau Lava sequence. Incompatible trace elements indicate that the LTS are derived from a more depleted mantle source compared to HTS and VHTS. The LTS is characterised by increasing Cu (105 to 248 ppm) and Pd (7 to 24 ppb), constant Cu/Pd ratio (~10,000), and decreasing Ir (1.1 to <0.05 ppb) and Ru (1.8 to <0.3 ppb) concentrations during magmatic differentiation (16 to 7 wt% MgO). The constant Cu/Pd ratio reflects silicate- and chromite-dominated fractionation without concurrent segregation of sulphide. S-undersaturated differentiation is also indicated in the HTS, which also displays increasing Pd (6-16 ppb) and decreasing Ir concentrations (1 to <0.05 ppb) during differentiation, and the Cu/Pd ratios for the entire series average 21,000. However, some HTS samples have elevated Cu/Pd ratios (up to 33,000). Cu/Pd ratios in the HTS do not correlate with MgO, and this is interpreted to reflect varying Cu/Pd ratios of HTS parental magmas rather than S-saturated differentiation. During S-undersaturated differentiation of the LTS and HTS, Pt/Pd ratios decrease from 1.3 to 0.11 and 1.1 to 0.2 respectively, which indicates that Pd is much more incompatible than Pt during S-undersaturated differentiation. The VHTS consists exclusively of highly evolved samples with low MgO (6.6-6.1 wt%) and Pd/Ir ratios 98-228. Here, Cu/Pd ratios increase from 17,500 to 35,000 with decreasing Cr concentrations which indicate that these magmas experienced silicate fractionation with concurrent segregation of sulphide. The LTS represent melting of a depleted source and show high PGE concentrations and constant Cu/Pd ratios during S-undersaturated differentiation. Melting of a normal depleted upper mantle source generates S-saturated melts (MORB), and the depleted LTS source is therefore considered an extraordinary S-poor component within the ancestral Iceland plume. Of the three series, the VHTS contain the largest contribution from enriched mantle portions. The VHTS have similar PGE but much higher Nb concentrations for instance compared to the most evolved LTS and HTS samples, indicating that the enriched source contributes Nb but not PGE.     

The differentiation of the Skaergaard Intrusion

Previous interpretations of the Skaergaard Intrusion suggested that differentiation involved extreme iron-enrichment but no silica-enrichment until a very late stage. This model is difficult to reconcile with petrological and geochemical evidence, with the behaviour of tholeiitic volcanic suites and with phase equilibria. We propose that the Skaergaard magma evolved on a trend of pronounced silica-enrichment after cumulus magnetite appeared at the top of the Lower Zone. At that stage, the magma was of ferrobasaltic composition with close to 50% SiO₂. The Middle and Upper Zones of the intrusion dominantly represent crystal accumulation during differentiation from ferrobasalt through iron-rich basaltic andesite and icelandite to rhyolite, a fractionation sequence common in tholeiitic volcanic provinces. This interpretation requires re-appraisal of the physical processes responsible for the differentiation. In particular, residual liquids became lower in density with fractionation and would have caused the Skaergaard magma chamber to have become compositionally zoned.     

The influence of primary magma composition,H2O and pressure on mid-ocean ridge basalt differentiation

MORB suites display variations in their chemical differentiation trends which are closely related to the incompatible element enrichment of the basalts. We examine suites of primitive to evolved basalts from the Pacific-Nazca Ridge at 28° S (mostly depleted); from the Juan Fernandez microplate region (depleted) and from the Explorer Ridge, northeast Pacific (mostly enriched). Trends for incompatible element enriched MORBs consistently show less depletion of Al₂O₃ and less enrichment of FeO when plotted on MgO variation diagrams.Least squares modeling indicates that enriched basalts have undergone less plagioclase crystallization than depleted basalts especially in the early stages of differentiation. Using thermodynamic modelling, we show that variations between MORB differentiation trends result largely from differences in the major element chemistry and H₂O content of primary magmas. Our chosen enriched and depleted near-primary magmas are similar in major element chemistry but the enriched near-primary magma has higher H₂O and lower Al₂O₃ than the depleted near-primary magma. The MORB crystallization sequence is: olivineolivine+plagioclase olivine+plagioclase+high-Ca pyroxene; and the separate and combined effects of lower Al₂O₃ and higher H₂O are to cause plagioclase to crystallize later (lower temperature), and to make the interval of olivine+plagioclase crystallization shorter. As a result, enriched differentiates have higher Al₂O₃ and lower FeO than depleted MORBs at a given MgO content, even though their parents' Al₂O₃ is lower. Crystallization of enriched basalts at higher pressure than depleted basalts is not able to account for differences between the differentiation trends because the proportion of plagioclase is higher during three-phase crystallization at high pressure.The variations in trends do not depend on geographic location and thus are superimposed on any regional variations in MORB chemistry or mantle source. Nor are they related to spreading rate. Depleted basalts from the fast-spreading 28° S and Juan Fernandez ridges have differentiation trends similar to depleted basalts from the medium-spreading Galapagos Spreading Center, whereas differentiation trends for enriched basalts from the medium-spreading Explorer Ridge are quite different. Fe³⁺/Fe_total is similar (and quite low) for enriched and depleted basalts, indicating that neither oxidation state nor early magnetite crystallization are important.     

Water-saturated melting relations to 5 kilobars of three Leucite Hills lavas

The water-saturated phase relations of three Leucite Hills lavas have been determined at pressures up to 5 kb. Phlogopite is the major primary liquidus phase in orendite and wyomingite at pressures, > 1 kb, but clinopyroxene and olivine are the major primary liquidus phases in madupite at pressures up to 5 kb. Leucite is a liquidus phase in all three magmas at pressures <0.5kb. The experimental results are in reasonable agreement with the inferred crystallization sequences for the Leucite Hills lavas and have applications to the crystallization and differentiation of potassium-rich magmas within the crust.     

甘肃金川硫化铜镍矿床地质特征

金川矿床是我国知名的硫化铜镍矿床。它由四个矿区组成(图1)。该矿床除含有丰富的镍、铜外,还含有一些贵金属及钴等,为一含多种金属元素的硫化物矿床。本文是笔者在对该区多年积累的大量地质资料进行分析研究的基础上写成的,谬误之处,敬请指正。一、区域地质背景矿床位于阿拉善台块南西边缘,龙首山隆起东段北东侧深断裂的上盘(即南西侧)。龙首山基底为前长城系,盖层为长城—蓟县系和震旦系。前长城系内的八个伟晶花岗岩之云母样的同位素年龄为16.57—17.41亿年,一个片麻状花岗岩之白云母样的同位素年龄为17.86亿年。故这套深变质岩系的年龄应不小于18亿年。