原子吸收光谱法测定氰化液中的铅

通过对比实验，选用柠檬酸钠做络合剂，实现了在碱性介质中用原子吸收光谱测定铅的方法。应用该方法测定实际样品的结果与其他方法相符，对于2.19mg/L Pb浓度的试液10次测定的RSD为1.8%。     

金矿含氰废水中氰化物的降解方法

含氰废水的排放造成严重的环境污染,处理废水中的氰化物具有重要的实际意义,特别是对采用氰化法提金的黄金矿山尤为重要。本文系统介绍了国内外处理含氰废水中氰化物的几种应用效果较好的方法,阐述其原理、工艺流程等,并对其处理效果作了具体比较。     

Application of water pinch technology for water and wastewater minimization in aluminum anodizing industries

This study aims to describe the application of water pinch technology in industrial water consumption management in aluminum anodizing industry. Water pinch analysis is a systematic technique for designing, optimization and retrofitting of energy, mass and water recovery networks. The selection of different operations existing in an industry has an important role in correctness of application of pinch technology. Water usages in anodizing industry are various, but researches have been shown that, it has the best efficiency on the selection of rinsing chambers to pinch technology. There are different methods in pinch technology mostly based on mass transfer of single or multiple contaminants. In this research, a new method is used to select effective contaminant to be applied to pinch analysis. This research is based on Mann and Liu’s method in single contaminant. But “the guide for classification of raw water, wastewater and recycled water for industrial and recreation” is chosen to use a complex of index contaminants as a single contaminant. This method is very simple and applicable for various industrial processes. By an index contaminant like total dissolved solids, the water usage reduced about 6.7 %. Using pinch technology and this new approach in three rinsing chambers, water usage reduced about 14.4 %.     

用扫描电镜技术识别广州市大气颗粒物主要种类

利用扫描电镜技术对大气颗粒物的来源进行识别，采取手动分析与自动分析两种方法，得出的结果在总趋势上相互一致。手动方法和自动方法各有特点。自动分析在细颗粒，特别是含硫颗粒分析方面有优势，而手动分析在形貌观测和确定有机粗颗粒污染状况方面有独到之处。实验结果表明，大气颗粒物的来源是多样的，治理措施也应是综合性的，既要注意工业点源的污染治理和排放控制，如燃煤飞灰，钙质颗粒富铁颗粒等，也要注意面源排放，如土壤扬尘和碳质颗粒，碳质颗粒的来源复杂，可以是工业过程，燃烧过程，机动车尾气，生物质燃，树木自然排放。     

Removal of cyanide from aqueous solutions by plain and metal-impregnated granular activated carbons

In this study, the removal of free cyanide from aqueous solutions by activated carbon was investigated. Effects of metal impregnation (Cu and Ag), aeration, and concentrations of adsorbent and cyanide on the rate and extent of the removal of cyanide were studied. The results have shown that the capacity of activated carbon for the removal of cyanide can be significantly improved (up to 6.3-fold) via impregnation of activated carbon with metals such as copper and silver. Silver-impregnated activated carbon was found to be the most effective at the reduction of cyanide level in solution. This appeared to be coupled with its comparatively high metal content after impregnation process where silver (5.07%) could be more readily loaded on activated carbon than copper (0.43%). Kinetics and equilibrium data for cyanide removal by plain and metal-impregnated activated carbons were determined to be consistent with the pseudo second-order kinetics and the Langmuir adsorption isotherms, respectively. Aeration (0.27 l/min) was found to exert a profound effect on the process leading to a 5.5–49.1% enhancement in the performances of plain and metal-impregnated activated carbons. This enhancement could be attributed to the increase in the availability of active sites on activated carbon for adsorption and the catalytic oxidising activity of activated carbon in the presence of oxygen. Practical limiting capacity of plain, copper- and silver-impregnated activated carbons for the removal of cyanide were experimentally determined to be 19.7, 22.4 and 29.6 mg/g, respectively.     

陆相盆地源－汇系统要素耦合研究进展

源－汇系统研究已成为世界范围内地球科学领域广为关注的重要课题.陆相盆地作为源－汇系统研究的重要方面,相对于洋陆边缘源－汇系统,其源－汇系统要素多样、过程复杂、沉积体系多变,耦合模型预测难度大,且尚处于起步阶段.陆相盆地源－汇系统研究主要集中于驱动机制及地球动力学过程、深时古气候、沉积盆地古物源区演化恢复与古水系重建、源－汇系统要素分析及剥蚀－搬运－沉积过程单因素分析与耦合模式探讨.基于钻井、岩心、分析化验数据的多方法物源示踪分析与三维地震数据的地震地貌学或地震沉积学分析,为地下陆相盆地古源区恢复、古水系重建及沉积体系的沉积地貌和沉积过程研究提供了重要的技术支撑.关注不同母岩区源－汇系统差异,开展现代考察与古代源－汇相结合,并尝试定量化源－汇系统耦合－过程研究,最终形成工业化标准与规范是陆相盆地源－汇研究的发展趋势.      

Revealing forms of iron in river-borne material from major tropical rivers of the Amazon Basin (Brazil)

The present study deals with the direct determination of colloidal forms of iron in river-borne solids from main rivers of the Amazon Basin. The contribution of different forms of colloidal iron have been assessed using ultrafiltration associated with various techniques including electron paramagnetic resonance spectroscopy (EPR), high resolution transmission electron microscopy (HRTEM), and micro proton-induced X ray emission analysis (μPIXE). EPR shows the presence of Fe³⁺ bound to organic matter (Fe³⁺-OM) and colloidal iron oxides. Quantitative estimate of Fe³⁺-OM content in colloidal matter ranges from 0.1 to 1.6 weight % of dried solids and decreases as the pH of the river increases in the range 4 to 6.8. The modeling of the field data with the Equilibrium Calculation of Speciation and Transport (ECOSAT) code demonstrates that this trend is indicative of a geochemical control resulting from the solubility equilibrium of Fe oxyhydroxide phase and Fe binding to organic matter. Combining EPR and μPIXE data quantitatively confirms the presence of colloidal iron phase (min. 35 to 65% of iron content), assuming no divalent Fe is present. In the Rio Negro, HRTEM specifies the nature of colloidal iron phase mainly as ferrihydrite particles of circa 20 to 50 Å associated with organic matter. The geochemical forms of colloidal iron differentiate the pedoclimatic regions drained by the different rivers, corresponding to different major weathering/erosion processes. Modeling allows the calculation of the speciation of iron as mineral, organic and dissolved phases in the studied rivers.     

气态膜回收氰化物的研究

气态膜是一种新型的膜分离技术,适用于从水溶液中分离提取挥发性物质。本文对气态膜回收氰化物的迁移机理及各种影响因素进行了研究,结果表明：传质速率与料液浓度呈现线性递增关系;吸收液浓度、流速和料液浓度、流速在一定范围内影响传质速率;温度升高,传质加快;膜孔径及孔隙率增大,传质速率也随之增大。     

地表过程研究进展与趋势

地表过程复杂多样、涉及广泛。针对当前地表过程研究现状,从地球系统科学和全球变化的视角讨论了与地表过程相关的一些概念及研究内涵。在分析单要素地表过程和多要素地表过程的基础上,从研究内容的综合性、多国合作的国际性、针对区域突出问题的区域性、以过程变化为核心的动态性及研究方法的多样性等方面论述了地表过程研究的特点,总结性地给出了国内外研究的总体趋势。在上述分析基础上,进一步从国际科学发展趋势、国家需要和信息、技术等方面分析了中国地表过程研究所面临的机遇;从多学科交叉、自然与人文过程的定量与有机耦合等方面讨论了地表过程研究所面临的挑战。     

湿法冶锰废渣中锰的形态分析与应用

将湿法冶锰废渣经过烘干、研细等预处理,按其所使用的原材料进行形态研究,通过筛选和实验,确定了废渣中的锰可用形态分析方法。在弄清废渣中锰的各种形态及含量的基础上,将其成果进行转化,用于指导工业生产、环境评价和废渣处理,具有很好的经济效益和社会效益。     

Quantitative determination of cerussite (lead carbonate) by X-ray powder diffraction and inferences for lead speciation and transport in stream sediments from a former lead mining area in Scotland

Most current investigations of sites contaminated with heavy metals (e.g. Pb, Zn, Cu) emphasise the importance of determining the amounts of physical and chemical forms of metals rather than just the total amounts present. Chemical extraction techniques used for this purpose are inevitably operationally defined. A more direct approach to the identification of crystalline forms can be made by mineralogical techniques such as X-ray powder diffraction (XRPD), but quantitative determination of a particular form is not often attempted. Recent advances in methods of analysis and sample preparation for XRPD mean that it is now a relatively simple matter to obtain quantitative XRPD data. Here, it is applied to the quantitative determination of the forms of Pb in different size-fractions of stream sediment samples from Leadhills/Wanlockhead, SW Scotland, an historic Pb mining area. Comparison of the XRPD analyses with determinations of Pb by atomic absorption spectrophotometry demonstrates that a large proportion of the Pb present in the stream sediments is in the form of cerussite (PbCO₃). Furthermore, the cerussite tends to be concentrated in the silt fraction and is even a minor component of the clay-size fraction. However, quantitative analysis of fractions <6 μm indicates that cerussite alone cannot account for all the Pb in this size range. Indirectly, this result suggests that Pb adsorbed to clay minerals, organic matter and/or amorphous Fe and Mn oxides may be proportionally more important for the <6 μm materials. Sediment in this size range, however, typically accounts for no more than 1% by weight of the total stream bed sediment samples collected in the study area. In relation to its size distribution, the mobility of Pb within the wider environment is most likely to occur principally through physical transport of fine particles.     

Protocol for Quantitative Detection of Elemental Sulfur and Polysulfide Zero-Valent Sulfur Distribution in Natural Aquatic Samples

A HPLC-based protocol has been developed for the determination of zero-valent sulfur (ZVS) speciation, including solid, colloidal elemental sulfur and individual inorganic polysulfides in natural aquatic samples. The protocol includes four experimental procedures: (1) determination of polysulfide speciation by rapid single-phase derivatisation with methyl trifluoromethanesulfonate; (2) determination of the sum of polysulfide and colloidal sulfur by reaction with hydrogen cyanide (cyanolysis); (3) determination of total zero-valent sulfur by treatment with zinc chloride followed by extraction with chloroform; and (4) chromatographic determination of polythionates without sample pre-treatment. With proper sampling and preservation techniques in the field or on board ship, this combination of methods allowed the quantitative determination of: (a) individual polysulfide species; (b) dispersed colloidal sulfur; (c) dispersed solid elemental sulfur; and (d) tetra-, penta- and hexathionates. With minor modification, the method could be expanded to include other polythionates. Sixteen various wet chemical and liquid chromatographic methods were tested on nine synthetic reference samples (including solid elemental sulfur, colloidal elemental sulfur, inorganic polysulfides and polythionates) to establish the optimal protocol. The protocol was further evaluated by analysing the zero-valent sulfur content in microbially-produced sulfur and in sulfur from two natural samples of sulfide-rich seawater from tidal flats pools of the Wadden Sea (Germany).     

元素活动态测量法在鄂尔多斯盆地砂岩型铀矿勘查中的应用

常规化探方法勘查砂岩型铀矿难以奏效。应用深穿透地球化学方法系列中的元素活动态测量法在鄂尔多斯盆地砂岩型铀矿上的试验结果表明,几种U元素活动态在矿体上方都有异常出现,特别是其中的粘土吸附态U含量级别高、异常衬度大。因此,土壤粘土吸附态U测量法是本区化探找铀矿的有效方法;取样深度和取样粒级分别以60～90cm和-120目为宜;采用400m的取样点距基本不影响本区砂岩型铀矿的找矿效果。在盆地东北部应用土壤粘土吸附态U测量法预测了3个有利地段,并在其中1个地段的深部发现了较好的铀矿化。     

A method of characterizing the thermal relations in mountainous areas / the lower Beskid range in the Polish Carpathians as example

The method discussed in the present paper permits the determination in detail of the mesoclimatic conditions on the basis of standard data provided by a network of a measurement stations. The passage from the data available at certain points and obtained from meteorological stations to spatial conceptions leads along the determination of the relationships between the altitude, various forms of the relief, and the thermal indices of climate. Resulting from these data, the duration of the frostless period is a sensitive index in the scale of mesoclimate, besides all the other indices connected with the minimum air temperatures. The nomographs applied by the authors make it possible to construct detailed climatic maps, which — with the maps of other elements of the geographical environment — form a basis for the elaboration e.g. an agrocological map of habitats. Presented method of the evaluation of climate conditions can be applied to all mountain territories, in which a network of measurement stations enables the determination of the interdependencies between the chosen thermal parameters and the altitude, and the distinction of the impact of the convex and concave forms.     

A method of characterizing the thermal relations in mountainous areas / the lower Beskid range in the Polish Carpathians as example

The method discussed in the present paper permits the determination in detail of the mesoclimatic conditions on the basis of standard data provided by a network of a measurement stations. The passage from the data available at certain points and obtained from meteorological stations to spatial conceptions leads along the determination of the relationships between the altitude, various forms of the relief, and the thermal indices of climate. Resulting from these data, the duration of the frostless period is a sensitive index in the scale of mesoclimate, besides all the other indices connected with the minimum air temperatures. The nomographs applied by the authors make it possible to construct detailed climatic maps, which — with the maps of other elements of the geographical environment — form a basis for the elaboration e.g. an agrocological map of habitats. Presented method of the evaluation of climate conditions can be applied to all mountain territories, in which a network of measurement stations enables the determination of the interdependencies between the chosen thermal parameters and the altitude, and the distinction of the impact of the convex and concave forms.     

Simulation of the interactions between gravity processes and contour currents on the Algarve Margin (South Portugal) using the stratigraphic forward model Sedsim

The margin of the Gulf of Cadiz is swept by an intermediate current the Mediterranean Outflow Water (MOW) flowing from the Mediterranean to the Atlantic. On the northern margin of the Gulf (Algarve Margin, South Portugal) the MOW intensity is low, and fine-grained contourite drifts are built up with an alongslope alignment. Recent sedimentological studies emphasize the presence of complex process interactions resulting in the formation of a unique depositional architecture. Alongslope processes related to contour currents generate contourite drift, while downslope processes form canyons and channels aligned on deep faults. This paper uses a combined oceanographic and geological dataset to simulate the different types of interactions between gravity processes and contour currents, which were evidenced on this margin. An extrapolation of the contour current intensity has been used based on the present day velocity field and sea-level fluctuations over the simulated geological time-scale. According to our model results, the construction of the contourite drift is closely linked to contour current velocities and directions, the types of sediments transported and the existing topography. Using modern sedimentological understanding of the area, we have correlated gravity flow's strongest activity to sea level lowstand periods mainly due to a closer connection between canyon's mouth and river or deltaic systems. The simulated gravity flows are initialized at different locations and times on the margin depending on the preserved lobes retrieved from seismic analysis. Their resulting morphological features are identified as perched-lobes with volumes and forms close to the ones observed on Portimão and Lagos Drifts. This study provides a process-based understanding of the construction of contourite system and a physical evaluation of the interactions between gravity flows perpendicular to the slope, and alongslope processes. In addition, it shows the influence of autocyclic factors in the construction of contourite sedimentation, which is important to consider in future sedimentary paleo-reconstruction interpretations.     

土壤样品中贵金属活动态提取技术

介绍了土壤样品中贵金属铂、钯、金的水提取态、黏土吸附态与可交换态、有机质结合态以及铁锰氧化物结合态等不同相态的提取方法与测定方法。方法检出限为铂0.03 ng/g,钯和金0.01 ng/g。实验了铂、钯、金活动态金属各种提取液介质中痕量贵金属的稳定性、固-液分离方法、提取温度的影响及提取液的处理方法。通过在南非隐伏铂钯矿或矿化区的试验,结果表明所圈定的异常与实际矿(化)体相符,为识别隐伏贵金属铂钯矿床提供了有效信息,对寻找隐伏矿床具有一定的指导意义。     

波流边界层水沙运动数值模拟——II.泥沙运动模拟

为解析波流边界层内泥沙运动,建立了基于水动力-泥沙-床面互馈过程的波流边界层1DV泥沙数学模型,可用于模拟不同床面形态下粉沙-沙的含沙量过程。床面形态模块提供床面形态类型和相应参数;给出了平底和沙波床面粗糙高度和泥沙扩散系数的确定方法;采用了适宜粉沙及沙的制约沉速、底部参考浓度和起动剪切应力等公式;引入含沙量层化效应和制约沉降反映水动力与泥沙之间的相互影响。水槽试验资料验证表明,建立的模型较好地模拟了不同床面不同波流组合条件下的含沙量剖面。在此基础上,讨论了不同床面含沙量剖面模拟方法的差异,指出床面形态是决定含沙量变化的重要因素之一,仅通过改变床面粗糙高度不足以反映漩涡沙波床面的含沙量剖面特征。该模型可为研究波流边界层内泥沙运动和物质输运提供工具。     

A petrologic method of analysis of nonmaceral microstructures in coal

The petrographic maceral composition and vitrinoid reflectance of bituminous coals have been correlated with their carbonization characteristics and are widely used to predict how coals will perform in the coking process and to calculate the strength of the resulting coke. As a result, there is a growing dependence on coal petrographic data in characterizing coals for cokemaking. In addition, there is a growing awareness that there are other nonmaceral microstructures in coal such as material size, shape, association, fracturing, and weathering which should permit better characterization of coals when properly interpreted. These nonmaceral microstructures also give an insight into the metamorphic history and changes due to burial and exhumanation.To expand the use of coal petrologic and petrographic data, a new analytical procedure has been developed that requires the microscopic determination of such nonmaceral microstructures as normal coal, coal fines, pseudovitrinoids, microbrecciation, oxidation, coarse mineral matter, miscellaneous materials, and contamination. The occurrence of one or more of these microstructures in coal, depending on their kind and abundance, may have a significant effect on the coal performance in various processes. This work has resulted in formulation of a technique for determining the nonmaceral microstructures in coal and, if applied as a supplement to the routine maceral analysis of coals, should help in explaining the anomalous behavior of some coals.     

Quantitative determination of certain minerals in natural and artificial mixtures by DTA

Differential thermal analysis has been used in identifying individual minerals successfully; however, the use of DTA in identification of individual minerals in a mixture is not well accepted. This paper is divided into: introduction, terminology, history, derivation of the basic formula and thermograph. The various methods of determination are outlined and the advantages and disadvantages of each method discussed. Under separate-standard method the author considers the calibration curve method, the proportional method and the dilution method; the combined-standard method and the compensation-standard method are also treated. Piloyan concludes that the most reliable method is that of the calibration curve for quantitative analysis in a mixture, but this is contingent upon knowing the contained minerals to begin with. For poorly controlled experimental conditions the best results are obtained by using the combined-standard method. Advantages of DTA are the low cost of the apparatus, the fact that chemical analyses will not determine the minerals present. He also points out that DTA will not substitute for X-ray or chemical analyses but the three should be used in conjunction.—M.A. Klugman