南大西洋洋中脊附近沉积物中烃类分布和组成研究

我们利用气相色谱-质谱联用仪(GC-MS)测试了南大西洋洋中脊附近采集的沉积物样品中烃类的分布和组成。通过分析发现,样品中烃类表现出明显的双峰分布,同时明显的富集3-甲基烷烃、8-甲基烷烃以及2,4,(n-1)-三甲基烷烃,这可能是海底微生物代谢作用的结果。样品中也富集萜烷、藿烷和甾烷等生物标志物,这也支持样品中烃类主要为微生物来源的观点。样品中沥青和烃类显示出距离热液区近的2V-TVG10和26V-TVG05站位含量高,而距离热液区远的22IV-TVG01、22V-TVG11和22V-TVG14站位含量低的趋势,暗示出样品中沥青以及烃类的分布和组成可能受到海底热液活动的影响。     

南大西洋洋中脊调查区小型底栖生物丰度和生物量研究

“大洋一号”调查船于2011年5—6月在南大西洋中脊14°S附近进行了7个站位的小型底栖生物采样。共鉴定出小型底栖生物10个类群。小型底栖生物平均丰度为(60.63±54.77) ind/10 cm²,平均干重生物量为(9.42±8.92) μg/10 cm²。线虫是其中的优势类群,丰度为(47.42±47.99)ind/10 cm²,占总丰度的78.21%,另外,肉鞭动物和桡足类分别占总丰度的16.63%和3.91%。生物量前3位的类群依次为桡足类、线虫和肉鞭动物。小型底栖生物密度随沉积物深度增加而减少,约73.55%的生物丰度分布在0～2 cm层内。个体大小方面,有75.32%的小型底栖生物粒径处于32～125 μm范围内。     

Geologic controls of hydrothermal activity in the Mid-Atlantic Ridge rift valley: Tectonics and volcanics

The rift valley at three widely separated sites along the Mid-Atlantic Ridge is characterized using geological and geophysical data. An analysis of bottom photographs and fine-scale bathymetry indicates that each study area has a unique detailed geology and structure. Spreading rates are apparently asymmetric at each site. Relationships between tectonic and volcanic structure and hydrothermal activity show that various stages in the evolution of the rift valley are most favorable for seafloor expression of hydrothermal activity. In a stage found at 26°08 N, site 1 (TAG), the rift valley is narrow, consisting of both a narrow volcanically active valley floor and inner walls with small overall slopes. High-temperature hydrothermal venting occurs along the faster spreading eastern inner wall of this U-shaped rift valley. Site 2 (16°46 N) has a narrow valley floor and wide block faulted walls and is at a stage where the rift valley is characterized by a V-shape. No neovolcanic zone is observed within the marginally faulted, predominantly sedimented floor and hydrothermal activity is not observed. The rift valley at site 3 (14°54 N), with postulated extrusive volcanic activity and a stage in valley evolution tending toward a U-shape, shows evidence of hydrothermal activity within the slightly faster spreading eastern inner wall. Evidence for tectonic activity (inward- and outward-facing faults and pervasive fissuring) exists throughout the wide inner wall. Hydrothermal activity appears to be favored within a U-shaped rift valley characterized by a narrow neovolcanic zone and secondarily faulted inner walls.     

Two- and three-dimensional inversions of magnetic anomalies in the MARK area (Mid-Atlantic Ridge 23° N)

Magnetic data collected in conjunction with a Sea Beam bathymetric survey of the Mid-Atlantic Ridge south of the Kane Fracture Zone are used to constrain the spreading history of this area over the past 3 Ma. Two-dimensional forward modeling and inversion techniques are carried out, as well as a full three-dimensional inversion of the anomaly field along a 90-km-long section of the rift valley. Our results indicate that this portion of the Mid-Atlantic Ridge, known as the MARK area, consists of two distinct spreading cells separated by a small, zero-offset transform or discordant zone near 23°10′ N, The youngest crust in the median valley is characterized by a series of distinct magnetization highs which coalesce to form two NNE-trending bands of high magnetization, one on the northern ridge segment which coincides with a large constructional volcanic ridge, and one along the southern ridge segment that is associated with a string of small axial volcanos. These two magnetization highs overlap between 23° N and 23°10° N forming a non-transform offset that may be a slow spreading ridge analogue of the small ridge axis discontinuities found on the East Pacific Rise. The crustal magnetizations in this overlap zone are generally low, although an anomalous, ESE-trending magnetization high of unknown origin is also present in this area. The present-day segmentation of spreading in the MARK area was inherited from an earlier ridge-transform-ridge geometry through a series of small (∼ 10 km) eastward ridge jumps. These small ridge jumps were caused by a relocation of the neovolcanic zone within the median valley and have resulted in an overall pattern of asymmetric spreading with faster rates to the west (14 mm yr⁻¹) than to the east (11 mm yr⁻¹). Although the detailed magnetic survey described in this paper extends out to only 3 Ma old crust, a regional compilation of magnetic data from this area by Schoutenet al. (1985) indicates that the relative positions and dimensions of the spreading cells, and the pattern of asymmetric spreading seen in the MARK area during the past 3 Ma, have characterized this part of the Mid-Atlantic Ridge for at least the past 36 Ma.     

南大西洋沉积物中多环芳香化合物的组成特征研究

10 samples of sediments obtained from the South Mid-Atlantic Ridge were measured for the abundances and distributions of polycyclic aromatic compounds(PAHs). The total concentrations of PAHs(∑PAHs) ranged from 2.768 to 9.826 μg/g dry sediment. The ∑PAHs was higher in sample 22V-TVG10 and sample 26V-TVG05 which were close to hydrothermal fields, with the lowest value in sample 22V-TVG14 which was farthest from hydrothermal fields, suggesting a probable hydrothermal origin of ∑PAHs of samples. Approximately nine kinds of PAHs were identified, and low molecular mass tricyclic and tetracyclic aromatic compounds were predominant in the samples. The concentrations of fluoranthene which were typical as hydrothermal alteration compounds were the highest among PAHs with dry weight between 0.913–3.157 μg/g. The phenanthrene homologue was most abundant in the samples, and the ratios between parent phenanthrene and methylphenanthrene which probably reflected the degree of hydrothermal alteration ranged from 0.097 to 1.602. The sample 22V-TVG10 possessing a maximum ratio value showed the intense influence of the hydrothermal alteration on this sample, which might further imply that PAHs in sediments were mainly derived from the hydrothermal alteration.     

Variations in axial processes on the Mid-Atlantic Ridge: The median valley of the MARK area

Submersible observations and photogeology document dramatic variations in the distribution of young volcanic rocks, faulting, fissuring, and hydrothermal activity along an 80 km-long segment of the Mid-Atlantic Ridge south of the Kane Transform (MARK Area). These variations define two spreading cells separated by a cell boundary zone or a small-offset transform zone. The northern spreading cell is characterized by a median ‘neovolcanic’ ridge which runs down the axis of the median valley floor for 40 km. This edifice is as much as 4 km wide and 600 m high and is composed of very lightly sedimented basalts inferred to be < 5000 years old. It is the largest single volcanic constructional feature discovered to date on the Mid-Atlantic Ridge. The active Snake Pit hydrothermal vent field is on the crest of this ridge and implies the presence of a magma chamber in the northern spreading cell. In contrast, the southern cell is characterized by small, individual volcanos similar in size to the central volcanos in the FAMOUS area. Two of the volcanos that were sampled appear to be composed of dominantly glassy basaltic rocks with very light sediment cover; whereas, other volcanos in this region appear to be older features. The boundary zone between the two spreading cells is intensely faulted and lacks young volcanic rocks. This area may also contain a small-offset ( < 8 km) transform zone. Magmatism in the northern cell has been episodic and tens of thousands of years have lapsed since the last major magmatic event there. In the southern cell, a more continuous style of volcanic accretion appears to be operative. The style of spreading in the southern cell may be much more typical for the Mid-Atlantic Ridge than that of the northern cell because the latter is adjacent to the 150 km-offset Kane Transform that may act as a thermal sink along the MAR. Such large transforms are not common on the MAR, therefore, lithosphere produced in a spreading cell influenced by a large transform may also be somewhat atypical.     

The morphology and tectonics of the Mark area from Sea Beam and Sea MARC I observations (Mid-Atlantic Ridge 23° N)

High-resolution Sea Beam bathymetry and Sea MARC I side scan sonar data have been obtained in the MARK area, a 100-km-long portion of the Mid-Atlantic Ridge rift valley south of the Kane Fracture Zone. These data reveal a surprisingly complex rift valley structure that is composed of two distinct spreading cells which overlap to create a small, zero-offset transform or discordant zone. The northern spreading cell consists of a magmatically robust, active ridge segment 40–50 km in length that extends from the eastern Kane ridge-transform intersection south to about 23°12′ N. The rift valley in this area is dominated by a large constructional volcanic ridge that creates 200–500 m of relief and is associated with high-temperature hydrothermal activity. The southern spreading cell is characterized by a NNE-trending band of small (50–200 m high), conical volcanos that are built upon relatively old, fissured and sediment-covered lavas, and which in some cases are themselves fissured and faulted. This cell appears to be in a predominantly extensional phase with only small, isolated eruptions. These two spreading cells overlap in an anomalous zone between 23°05′ N and 23°17′ N that lacks a well-developed rift valley or neovolcanic zone, and may represent a slow-spreading ridge analogue to the overlapping spreading centers found at the East Pacific Rise. Despite the complexity of the MARK area, volcanic and tectonic activity appears to be confined to the 10–17 km wide rift valley floor. Block faulting along near-vertical, small-offset normal faults, accompanied by minor amounts of back-tilting (generally less than 5°), begins within a few km of the ridge axis and is largely completed by the time the crust is transported up into the rift valley walls. Features that appear to be constructional volcanic ridges formed in the median valley are preserved largely intact in the rift mountains. Mass-wasting and gullying of scarp faces, and sedimentation which buries low-relief seafloor features, are the major geological processes occurring outside of the rift valley. The morphological and structural heterogeneity within the MARK rift valley and in the flanking rift mountains documented in this study are largely the product of two spreading cells that evolve independently to the interplay between extensional tectonism and episodic variations in magma production rates.     

Mineralogical characteristics of polymetallic sulfides from the Deyin-1 hydrothermal field near 15°S,southern Mid-Atlantic Ridge

A seafloor hydrothermal field, named Deyin-1 later, near 15°S southern Mid-Atlantic Ridge(SMAR) was newly found during the 22 nd cruise carried out by the China Ocean Mineral Resources Research Development Association(COMRA). Sulfide samples were collected at three stations from the hydrothermal field during the26 th cruise in 2012. In this paper, mineralogical characteristics of the sulfides were analyzed with optical microscope, X-ray diffractometer, scanning electron microscope and electron microprobe to study the crystallization sequence of minerals and the process of hydrothermal mineralization. According to the difference of the ore-forming metal elements, the sulfide samples can be divided into three types:(1) the Ferich sulfide, which contains mainly pyrite and chalcopyrite;(2) the Fe-Cu-rich sulfide consisting predominantly of pyrite, chalcopyrite and isocubanite, with lesser amount of sphalerite, marmatite and pyrrhotine; and(3) the Fe-Zn-rich sulfide dominated by pyrite, sphalerite and marmatite, with variable amounts of chalcopyrite, isocubanite, pyrrhotine, marcasite, galena and gratonite. Mineral precipitations in these sulfides are in the sequence of chalcopyrite(isocubanite and possible coarse pyrite), fine pyrite,sphalerite(marmatite), galena, gratonite and then the minerals out of the dissolution. Two morphologically distinct generations(Py-I and Py-II) of pyrite are identified in each of the samples; inclusions of marmatite tend to exist in the coarse pyrite crystals(Py-I). Sphalerite in the Fe-Zn-rich sulfide is characterized by a"chalcopyrite disease" phenomenon. Mineral paragenetic relationships and a wide range of chemical compositions suggest that the environment of hydrothermal mineralization was largely changing. By comparison, the Fe-rich sulfide was formed in a relatively stable environment with a high temperature, but the conditions for the formation of the Fe-Cu-rich sulfide were variable. The Fe-Zn-rich sulfide was precipitated during the hydrothermal venting at relatively low temperature.     

Extensional faulting and segmentation of the Mid-Atlantic Ridge north of the Kane Fracture Zone (24° 00′ N to 24° 40′ N)

The combination of multi-beam echo-sounder swath bathymetry and high-resolution deep-towed sidescan sonar provides a powerful database from which to examine mid-ocean ridge processes. We have used such a database, gathered from the Mid-Atlantic Ridge north of the Kane Fracture Zone (the MARNOK area), to examine the relationship between tectonic, volcanic, and bathymetric segmentation. We have identified structural domains, with different fault distributions, and neovolcanic segments that are distinct from the 2nd or 3rd order bathymetric segmentation.From their mutual relationships, a model is proposed for the magmatic accretion of oceanic crust at slow spreading ridges that relates the local melt supply to the tectonic style. We suggest that these are mutually interactive, and determine whether volcanic extrusion along the ridge is continuous and slow, or episodic and rapid.     

Structure and Stability of Non-Transform Discontinuities on the Mid-Atlantic Ridge between 24° N and 30° N

Observations of the median valley within the 24–30° N area ofthe Mid-Atlantic Ridge (MAR), using the IOSDL high resolutionside-scan sonar instrument TOBI, image four separate areas of themedian valley, containing part or all of nine spreading segments, and fivenon-transform discontinuities between spreading segments (NTDs).These high resolution side scan images were interpreted in parallel withmultibeam bathymetry (Purdy et al., 1990), giving a greater degree ofstructural precision than is possible with the multibeam data alone. Threedistinct types of NTD were identified, corresponding in part to typespreviously identified from the multibeam bathymetric survey of the area.Type 1 NTDs are termed septal offsets, and are marked by a topographic ridgeseparating the two spreading segments. The offset between the spreadingsegments ranges from 9 to 14 km. These can be further subdivided into Type1A in which the septa run parallel to the overall trend of the MAR and Type1B in which the septa lie at a high angle to the bulk ridge trend. Type 1ANTDs are characterised by overlap of the neovolcanic zones of the segmentson each side, and strong offaxis traces, while Type 1B NTDs show no overlapof neovolcanic zones, and weak offaxis traces. Type 2 NTDs arebrittle/ductile extensional shear zones, marked by oblique extensionalfractures, and associated with rotation of tectonic and volcanic structuresaway from the overall trend of the MAR. Type 3 NTDs are associated withoffsets of less than 5 km, and show no sign of any accommodating structure.In this type of NTD, the offset zone is covered with undeformed volcanics.The type of NTD developed at any locality along the ridge axis appears todepend on the amount of segment offset and segment overlap, the overalltrend of the mid-ocean ridge, the width of the zone of discontinuity, themedian valley offset and the longevity of the offset. These factorsinfluence the mechanical properties of the lithosphere across thediscontinuity, and ultimately the tectonic style of the NTD that can besupported. Thus brittle/ductile extensional shear zones are long-livedstructures favoured by large segment offsets, and small or negative segmentoverlaps. Septa can be short or long lived, and are associated with largesegment offsets. Segment overlaps vary from negative (an along axis gap) tozero, for Type 1B septal offsets, or positive to zero for Type 1A septaloffsets. Non-tectonised NTDs are generally short lived structures,characterised by small segment offsets and zero or positive overlaps.     

Interference fringes on GLORIA side-scan sonar images from the Bering Sea and their implications

GLORIA side-scan sonographs from the Bering Sea Basin show a complex pattern of interference fringes sub-parallel to the ship's track. Surveys along the same trackline made in 1986 and 1987 show nearly identical patterns. It is concluded from this that the interference patterns are caused by features in the shallow subsurface rather than in the water column. The fringes are interpreted as a thin-layer interference effect that occurs when some of the sound reaching the seafloor passes through it and is reflected off a subsurface layer. The backscattered sound interferes (constructively or desctructively) with the reflected sound. Constructive/destructive interference occurs when the difference in the length of the two soundpaths is a whole/half multiple of GLORIA's 25 cm wavelength. Thus as range from the ship increases, sound moves in and out of phase causing bands of greater and lesser intensity on the GLORIA sonograph. Fluctuations (or wiggles) of the fringes on the GLORIA sonographs relate to changes in layer thickness. In principle, a simple three dimensional image of the subsurface layer may be obtained using GLORIA and bathymetric data from adjacent (parallel) ship's tracks. These patterns have also been identified in images from two other systems; SeaMARC II (12 kHz) long-range sonar, and TOBI (30 kHz) deep-towed sonar. In these, and other cases world-wide, the fringes do not appear with the same persistence as those seen in the Bering Sea.     

From oblique subduction to intra-continental transpression: Structures of the southern Kermadec-Hikurangi margin from multibeam bathymetry,side-scan sonar and seismic reflection

The southern Kermadec-Hikurangi convergent margin, east of New Zealand, accommodates the oblique subduction of the oceanic Hikurangi Plateau at rates of 4–5 cm/yr. Swath bathymetry and sidescan data, together with seismic reflection and geopotential data obtained during the GEODYNZ-SUD cruise, showed major changes in tectonic style along the margin. The changes reflect the size and abundance of seamounts on the subducting plateau, the presence and thickness of trench-fill turbidites, and the change to increasing obliquity and intracontinental transpression towards the south. In this paper, we provide evidence that faulting with a significant strike-slip component is widespread along the entire 1000 km margin. Subduction of the northeastern scrap of the Hikurangi Plateau is marked by an offset in the Kermadec Trench and adjacent margin, and by a major NW-trending tear fault in the scarp. To the south, the southern Kermadec Trench is devoid of turbidite fill and the adjacent margin is characterized by an up to 1200 m high scarp that locally separates apparent clockwise rotated blocks on the upper slope from strike-slip faults and mass wasting on the lower slope. The northern Hikurangi Trough has at least 1 km of trench-fill but its adjacent margin is characterized by tectonic erosion. The toe of the margin is indented by 10–25 km for more than 200 km, and this is inferred to be the result of repeated impacts of the large seamounts that are abundant on the northern Hikurangi Plateau. The two most recent impacts have left major indentations in the margin. The central Hikurangi margin is characterized by development of a wide accretionary wedge on the lower slope, and by transpression of presubduction passive margin sediments on the upper slope. Shortening across the wedge together with a component of strike-slip motion on the upper slope supports an interpretation of some strain partitioning. The southern Hikurangi margin is a narrow, mainly compressive belt along a very oblique, apparently locked subduction zone.     

High-resolution seafloor mapping using the DSL-120 sonar system: Quantitative assessment of sidescan and phase-bathymetry data from the Lucky Strike segment of the Mid-Atlantic Ridge

High-resolution, side-looking sonar data collected near the seafloor (100 m altitude) provide important structural and topographic information for defining the geological history and current tectonic framework of seafloor terrains. DSL-120 kHz sonar data collected in the rift valley of the Lucky Strike segment of the Mid-Atlantic Ridge near 37° N provide the ability to quantitatively assess the effective resolution limits of both the sidescan imagery and the computed phase-bathymetry of this sonar system. While the theoretical, vertical and horizontal pixel resolutions of the DSL-120 system are <1 m, statistical analysis of DSL-120 sonar data collected from the Lucky Strike segment indicates that the effective spatial resolution of features is 1–2 m for sidescan imagery and 4 m for phase-bathymetry in the seafloor terrain of the Mid-Atlantic Ridge rift valley. Comparison of multibeam bathymetry data collected at the sea-surface with deep-tow DSL-120 bathymetry indicates that depth differences are on the order of the resolution of the multibeam system (10–30 m). Much of this residual can be accounted for by navigational mismatches and the higher resolving ability of the DSL-120 data, which has a bathymetric footprint on the seafloor that is 20 times smaller than that of hull-mounted multibeam at these seafloor depths (2000 m). Comparison of DSL-120 bathymetry with itself on crossing lines indicates that residual depth values are ±20 m, with much of that variation being accounted for by navigational errors. A DSL-120 survey conducted in 1998 on the Juan de Fuca Ridge with better navigation and less complex seafloor terrain had residual depth values half those of the Lucky Strike survey. The quality of the bathymetry data varies as a function of position within the swath, with poorer data directly beneath the tow vehicle and also towards the swath edges.Variations in sidescan amplitude observed across the rift valley and on Lucky Strike Seamount correlate well with changes in seafloor roughness caused by transitions from sedimented seafloor to bare rock outcrops. Distinct changes in sonar backscatter amplitude were also observed between areas covered with hydrothermal pavement that grade into lava flows and the collapsed surface of the lava lake in the summit depression of Lucky Strike Seamount. Small features on the seafloor, including volcanic constructional features (e.g., small cones, haystacks, fissures and collapse features) and hydrothermal vent chimneys or mounds taller than 2 m and greater than 9 m² in surface area, can easily be resolved and mapped using this system. These features at Lucky Strike have been confirmed visually using the submersible Alvin, the remotely operated vehicle Jason, and the towed optical/acoustic mapping system Argo II.     

西南印度洋中脊热液产物稀土元素组成变化及其来源

对西南印度洋中脊热液区不同热液产物稀土元素(REE)进行了分析,探讨了热液产物形成过程中稀土元素组成变化及其来源。研究结果表明:不同热液产物稀土元素总量变化范围从3.47×10-7到4.80×10-5,轻重稀土比值(LREE/HREE)从2.06到6.16,表明轻重稀土有较大程度分异,δEu异常(δEu=0.86~3.88)和δCe异常(δCe=0.40~0.86)显示热液产物中REE呈Eu富集和Ce亏损特征。稀土元素球粒陨石标准化模式呈现两种类型:(1)呈轻微富集LREE的平坦模式,REE大于2×10-5;(2)呈显著富集LREE和正Eu异常模式,REE小于5×10-7。模式1类似于洋壳火山岩REE配分模式,而模式2与西南印度洋中脊黑烟囱REE模式相似,也与典型洋中脊热液喷口流体和硫化物LREE富集和正Eu异常模式类似。热液产物中稀土元素含量变化和模式特征以及Mg与LREE极强正相关关系可能反映了西南印度洋中脊硫化物形成在热液流体与海水混合沉淀的初始阶段,后期经历了广泛的热液流体再循环和海水蚀变过程。     

Terrestrial flux in sediments from the Okinawa Trough estimated using geochemical compositional data and its response to climate changes over the past 35 000 a

Terrestrial supply to marginal seas is a function of interaction between land and ocean in response to climate changes. Terrestrial flux in sediments, therefore, is potential not only to reflect the paleoceanographic evolution of sedimentary basin, but also to reveal the paleoclimatic changes in source regions. Sediments from the Okinawa Trough were quantitatively partitioned into terrestrial, volcanic and biogenitic end members using constrained leastsquares technique for geochemical compositional data. Combined with the density of bulk sediments and sedimentation rate, the terrestrial flux in sediments from the Okinawa Trough since the last 35 000 a was estimated. Based on surface seawater temperature (SST) and sea level changes over the past 35 000 a, the response of terrestrial flux to the climate changes was discussed. It is demonstrated that the terrestrial supply to the Okinawa Trough mainly derived from Chinese landmass via the Changjiang (Yangtze) River and controlled by sea level changes. During the postglaciation, the terrestrial flux was the lowest in response to the highest sea level stand. During the last glacial maximum (LGM), the terrestrial flux was not so high as previously expected, indicating the arid climatic condition in source region was responsible for lowering the Changjiang River’s runoff during that time. During the deglaciation, the terrestrial flux increased in response to a quick rising of the sea level, probably implicating occurrence of downslope transport. The four events characterized by slight increase in terrestrial flux exactly correspond to the LGM, Heinrich events (H1, H2, H3), respectively.