Titan: Far-infrared and microwave remote sensing of methane clouds and organic haze

It is shown that Titan's surface and plausible atmospheric thermal opacity sources—gaseous N₂, CH₄, and H₂, CH₄ cloud, and organic haze—are sufficient to match available Earth-based and Voyager observations of Titan's thermal emission spectrum. Dominant sources of thermal emission are the surface for wavelenghts λ ? 1 cm, atmospheric N₂ for 1 cm ? λ ? 200 μm,, condensed and gaseous CH₄ for 200 μm ? λ ? 20 μm, and molecular bands and organic haze for λ ? 20 μm. Matching computed spectra to the observed Voyager IRIS spectra at 7.3 and 52.7° emission angles yields the following abundances and locations of opacity sources: CH₄ clouds: 0.1 g cm^? at a planetocentric radius of 2610–2625 km, 0.3 g cm^?2 at 2590–2610 km, total 0.4 ± 0.1 g cm^–2 above 2590 km; organic haze: $\text{4 ± 2 × 10}{}^{\mathrm{?6}}\text{,}\text{g cm}\text{,}{}^{\mathrm{?2}}$ above 2750 km; tropospheric H₂: 0.3 ± 0.1 mol%. This is the first quantitative estimate of the column density of condensed methane (or CH₄/C₂H₆) on Titan. Maximum transparency in the middle to far IR occurs at 19 μm where the atmospheric vertical absorption optical depth is $\text{?0.6}$ A particle radius $\text{r}\text{? 2 μ}\text{m}$ in the upper portion of the CH₄ cloud is indicated by the apparent absence of scattering effects.     

Production and condensation of organic gases in the atmosphere of Titan

The rates and altitudes for the dissociation of atmospheric constituents of Titan are calculated for solar UV, solar wind protons, interplanetary electrons, Saturn magnetospheric particles, and cosmic rays. The resulting integrated synthesis rates of organic products range from 10²–10³ g cm^?2 over 4.5 × 10⁹ years for high-energy particle sources to 1.3 × 10⁴ g cm^?2 for UV at $\text{λ < 1550}\text{A}\text{?}$, and to 5.0 × 10⁵ g cm^?2 if $\text{λ > 1550}\text{A}\text{?}$ (acting primarily on C₂H₂, C₂H₄, and C₄H₂) is included. The production rate curves show no localized maxima corresponding to observed altitudes of Titan's hazes and clouds. For simple to moderately complex organic gases in the Titanian atmosphere, condensation occurs below the top of the main cloud deck at 2825 km. Such condensates comprise the principal cloud mass, with molecules of greater complexity condensing at higher altitudes. The scattering optical depths of the condensates of molecules produced in the Titanian mesosphere are as great as ～ 10²/(particulate radius, μm) if column densities of condensed and gas phases are comparable. Visible condensation hazes of more complex organic compounds may occur at altitudes up to ～ 3060 km provided only that the abundance of organic products declines with molecular mass no faster than laboratory experiments indicate. Typical organics condensing at 2900 km have molecular masses = 100–150 Da. At current rates of production the integrated depth of precipitated organic liquids, ices, and tholins produced over 4.5 × 10⁹ years ranges from a minimum ～ 100 m to kilometers if UV at $\text{λ > 1550}\text{A}\text{?}$ is important. The organic nitrogen content of this layer is expected to be ～ 10^?1?10^?3 by mass.     

Properties of the clouds of Venus,as inferred from airborne observations of its near-infrared reflectivity spectrum

We have measured the shape and absolute value of Venus' reflectivity spectrum in the 1.2-to 4.0-μm spectral region with a circular variable filter wheel spectrometer having a spectral resolution of 1.5%. The instrument package was mounted on the 91-cm telescope of NASA Ames Kuiper Airborne Observatory, and the measurements were obtained at an altitude of about 41,000 feet, when Venus had a phase angle of 86°. Comparing these spectra with synthetic spectra generated with a multiple-scattering computer code, we infer a number of properties of the Venus clouds. We obtain strong confirmatory evidence that the clouds are made of a water solution of sulfuric acid in their top unit optical depth and find that the clouds are made of this material down to an optical depth of at least 25. In addition, we determine that the acid concentration is 84 ± 2% H_2SO4 by weight in the top unit optical depth, that the total optical depth of the clouds is 37.5 ± 12.5, and that the cross-sectional weighted mean particle radius lies between 0.5 and 1.4 μm in the top unit optical depth of the clouds. These results have been combined with a recent determination of the location of the clouds' bottom boundary [Marov et al., Cosmic Res.14, 637–642 (1976)] to infer additional properties about Venus' atmosphere. We find that the average volume mixing ratio of H₂SO₄ and H₂O contained in the cloud material both equal approximately 2× 10^?6. Employing vapor pressure arguments, we show that the acid concentration equals 84 ± 6% at the cloud bottom and that the water vapor mixing ratio beneath the clouds lies between 6 × 10^?4 and 10^?2.     

The upper Jovian atmosphere aerosol content determined from a satellite eclipse observation

The Galilean satellite eclipse technique for measuring the aerosol distribution in the upper Jovian atmosphere is described and applied using 30 color observations of the 13 May 1972 eclipse of Ganymede obtained with the 5-m Hale telescope. This event probes the South Temperate Zone. The observed aerosol lies above the visible cloud tops, is very tenuous and varies with altitude, increasing rapidly with downward passage through the tropopause. The aerosol extinction coefficient, κ_a (λ1.05 μm), is ～1.1 × 10^?9 cm^?1 in the lower stratosphere and ～1.1 × 10^?8 cm^?1 at the tropopause. The 1σ uncertainty in these values does not exceed 50% The observations require some aerosol above the tropopause but do not clearly determine its structure. The present analysis emphasizes an extended haze distribution, but the alternate possibility is not excluded that the stratospheric aerosol resides in a thin layer. The aerosol extinction increases with decreasing wavelength and indicates the particle radius to be ?0.2 μm. Larger radii are impossible. These overall results confirm Axel's (1972) suggestion of a small quantity of dust above the Jovian cloud tops and the optical depths are consistent with those required to explain the low uv albedo.     

The structure and microphysical properties of the Venus clouds: Venera 9, 10, and 11 data

Data processing and interpretation of the nephelometer measurements made in the Venus atmosphere aboard the Venera 9, 10 and 11 landers in the sunlit hemisphere near the equator are discussed. These results were used to obtain the aerosol distribution and its microphysical properties from 62 km to the surface. The main aerosol content is found in the altitude range between 62 km (where measurements began) and 48 km, the location of the cloud region. Three prominent layers labeled as I (between 62 and 57 km), II (between 57 and 51 km) and III (between 51 and 48 km), each with different particle characteristics are discovered within the clouds. The measured light-scattering patterns can be intrepreted as having been produced by particles with effective radii from 1 to 2 μm depending on height and indices of refractivity from 1.45 in layer I to 1.42 in layer III. These values do not contradict the idea that the droplets are made of sulfuric acid. In layers II and III the particle size distribution is at least bimodal rather than uni-modal. The index of refraction is found to decrease to 1.33 in the lower part of layer II, suggesting a predominant abundance of larger particles of different chemical origin, and chlorine compounds are assumed to be relevant to this effect. In the entire heightrange of the Venera 9–11 craft descents, the clouds are rather rarefied and are characterized by a mean volume scattering coefficient σ ～ 2 × 10^?5 cm^?1 that corresponds to the mean meteorological range of visibility of about 2 km. The average mass content of condensate is estimated to be equal to 4 × 10^?9 g/cm³, and the total optical depth of clouds to τ ～ 35. Near the bottom of layer III clouds are strongly variable. In the subcloud atmosphere a haze was observed between 48 and 32 km; that haze is mainly made of submicron particles, r_eff ～ 0.1μm. The atmosphere below that is totally transparent but separate (sometimes possibly disappearing) layers may be present up to a height of 8 km above the surface. A model of this region with a very low particle density (N ? 2–3 cm^?3) strongly refractive large particles (r_eff ? 2.5 μm; 1.7 < n < 2.0) provided satisfactory agreement. The optical depth of aerosol in the atmosphere below the subcloud haze does not exceed 2.5.     

Titan aerosols: Optical properties and vertical distribution

An analysis of Titan's solar phase variation as a function of wavelength together with the continuum geometric albedo makes it possible to set limits on the real part of the refractive index and on the average particle size of the aerosol component of Titan's atmosphere: $\text{1.5 ?n}{}_{\mathrm{r}}\text{< 2.0}\text{and}\text{0.20 μm <}\text{r}\text{?0.35 μm}$. If n_ris known $\text{r}$ can be determined to within a few percent, and varies inversely with n_r. Using this information in a two-layer model of a methane-aerosol atmosphere and comparing the result with Titan's visible and near-infrared methane spectrum leads to the conclusion that the top layer of Titan's atmosphere contains 0.01 km atm of methane and 2.5 extinction optical depths of aerosol, while the data are consistent with a bottom layer containing 2.2 km atm of methane and about 7.5 aerosol optical depths for $\text{n}{}_{\mathrm{<mtext>r</mtext>}}\text{= 1.7,}\text{r}\text{= 0.25 μ}\text{m}$.     

The Galilean satellites as a source of CO in the Jovian upper atmosphere

Material from the Galilean satellites of Jupiter ejected by energetic particles in the Jovian magnetosphere may provide large sources of oxygen to the parent planet. Formation of a CO molecule is the ultimate fate of an oxygen atom in the upper Jovian atmosphere. This high altitude source of CO supports Beer and Taylor's (1978, Astrophys. J.221) observations and analysis, provided that the globally averaged O atom input flux is ～10⁷ cm^?2 sec^?1 and the eddy diffusion coefficient at the tropopause is ～10³ cm² sec^?1. Implications for the possible presence of other atoms and molecules derived from the satellites are discussed.     

A constraint on the distribution of Titan's atmospheric aerosol

The physics of aerosols in Titan's atmosphere is examined, and a simple relatioshi particle size, optical depth, and aerosol replacement rate is derived. The consequences for current models of Titan's aerosol distribution are discussed.     

Ultraviolet reflectivity and geometrical albedo of Titan

Intermediate resolution (6Å) photoelectric spectral scans of Titan, Saturn, Saturn's Rings and the Moon appear in two forms: ratio spectra of Titan vs the Rings and of Saturn vs the Rings, and relative reflectivities, which are compared to previously published results. Titan's geometrical albedo of 0.094 ± 0.012 was measured at 4255Å with a 50Å bandpass. From this and the spectral measurements, we derived the geometrical albedo as a function of wavelength. We find that the wavelength dependences of Titan's uv spectrum and the spectrum of Saturn's Rings are remarkably similar. No trace of any absorption bands is apparent. These results imply that uv gaseous absorption and Rayleigh scattering play a strongly subdued role in Titan's atmosphere. Any homogeneous atmospheric model implies that the absorber responsible for Titan's uv spectral albedo varies strongly with wavelength. On the other hand, we find that the uv observations can be satisfied by an absorber having a relatively weak dependence upon wavelength if an inhomogeneous atmospheric model is employed. In particular, a fine dust, which absorbs as 1/λ, can explain the uv observations provided that it is preferentially distributed high up in Titan's atmosphere where the optical depth from Rayleigh scattering is low. The likely presence of such a dust in Jupiter's atmosphere and the difficulty in explaining the nature of a continuous uv absorber which varies rapidly with wavelength suggest that the gas and aerosol in Titan's atmosphere are inhomogeneously distributed.     

Spectral imaging of martian water ice clouds and their diurnal behavior during the 1999 aphelion season (Ls = 130°)

We report high-spectral-resolution (λ/δλ = 800-2300) near-infrared mapping observations of Mars at L_s = 130° (April 1999), which were obtained by drift-scanning the cryogenic long-slit spectrometer at the KPNO 2.2-m telescope across the disk. Data were reformatted into calibrated spectral image cubes (x,y,λ) spanning 2.19 to 4.12 μm, which distinguish atmospheric CO₂ features, solar lines, and surface and aerosol features. Maps of relative band depth between 3.0 and 3.5 μm trace water ice clouds and show the diurnal evolution of features in the persistent northern summer aphelion cloud belt, which was mapped contemporaneously but at fixed local time by the Mars Global Surveyor Thermal Emission Spectrometer (MGS/TES). Cloud optical depth, particle sizes, and ice aerosol content were estimated using a two-stream, single-layer scattering model, with Mie coefficients derived from recently published ice optical constants, followed by a linear spectral deconvolution process. A comparison of data and model spectra shows evaporating nighttime clouds in the morning followed by afternoon growth of a prominent orographic cloud feature on the west flank of Elysium Mons. Cloud optical depth at 3.2 μm evolved to 0.28 ± 0.13 and ice aerosol column abundance to 0.9 ± 0.3 pr μm in the afternoon. Column abundances as large as 0.17 pr μm were retrieved in nonorographic clouds within the aphelion cloud band around midday. These clouds exhibit a modest decline in optical depth during the afternoon. Results show that ice particle radii from <2 μm to >4 μm exist in both cloud types. However, large particles dominate the spectra, consistent with recent MGS/TES emission phase function measurements of aphelion cloud aerosol properties.     

Inhomogeneous models of Titan's aerosol distribution

A model of Titan's aerosol is presented which allows the particle size to vary with height. The model assumes a refractive index appropriate to an ethylene polymer and a mass flux independent of height equal to the value derived from laboratory measurements. The free parameters of the model are determined by fitting to the observed geometric albedo at 4000 and 6000 Å. A methane spectrum is derived which is in excellent agreement with observations. An aerosol optical depth of ～5 is found in the visible, with the particle radius varying from 0.01 to 8 μm. The presence of an optically thick methane cloud at the temperature minimum is indicated.     

Theoretical interpretation of the 0.7820 μm CO2 band and 0.8226 μm H2O line on Venus

We have analyzed the P6, P8, and P10 lines in the 0.7820 μm CO₂ band of Venus using a scattering model. Our new results compare favorably with previous results from the 1.05 μm CO₂ band. We considered nonabsorbing and absorbing clouds. We found that the anisotropic scattering mean free path for both models at the 0.2atm level is between 0.55 and 0.73km, a range close to the value of 1 km for terrestrial hazes. We used our scattering models to synthesize the 0.8226 μm H₂O line, assuming that the clouds are composed of sulfuric acid drops, and found our nonabsorbing cloud required a sulfuric acid concentration of 82% by weight, while our thicker absorbing cloud required a concentration of 89%. A comparison of the variation of optical depth with height for our cloud models with the variation reported by Prinn (1973, Science182, 1132–1134) showed that, within a factor of 2, the variation for Prinn's thinnest cloud agreed with ours. Whitehill and Hansen (1973, Icarus20, 146–152) have recently confirmed the work of Regas et al. (1973a, J. Quant. Spectry. Radiative Transfer13, 461–463) which showed that two cloud layers are not required to explain the CO₂ phase variation of Venus. Prinn's recent photochemical study of sulfuric acid clouds further supports a single, continuous cloud layer in the line formation region instead of two cloud layers with an extensive clear region between. The single layer model appears more likely because the maximum particle density in Prinn's cloud occurs in the clear region between the two layers in the models of Hunt (1972, J. Quant. Spectry. Radiative Transfer12, 405–419) and Carleton and Traub (1972, Bull. Amer. Astron. Soc.4, 362.).     

Axel dust on Saturn and Titan

The scattering and absorption properties of Axel dust were investigated by means of Mie theory. We find that a flat distribution of particle radii between 0 and 0.1 μm, and an imaginary part of the index of refraction which varies as λ^?2.5 produce a good fit to the variation of Titan's geometric albedo with wavelength (λ) provided that τ_ext, the extinction optical depth of Titan's atmosphere at 5000 Å, is about 10. The real part of the complex index is taken to be 2.0. The model assumes that the mixing ratio of Axel dust to gas is uniform above the surface of Titan. The same set of physical properties for Axel dust also produces a good fit to Saturn's albedo if τ_ext = 0.7 at 5000 Å. To match the increase in albedo shortward of 3500 Å, a clear layer (containing about 7 km-am H₂) is required above the Axel dust. Such a layer is also required to explain the limb brightening in the ultraviolet. These models can be used to analyze the observed equivalent widths of the visible methane bands. The analysis yields an abundance of the order of 1000 m-am CH₄ in Titan's atmosphere. The derived CH₄/H₂ mixing ratio for Saturn is about 3.5 × 10^?3 or an enhancement of about 5 over the solar ratio.     

Galilean satellite eclipse studies II. Jovian stratospheric and tropospheric aerosol content

The Galilean satellite eclipse technique for measuring the aerosol distribution in the Jovian lower stratosphere and upper troposphere is described and applied using 30 color observations of 12 natural satellite eclipses obtained with the 200-in Hale telescope. These events probe the North and South Polar Regions, the North Temperate Belt, the South Equatorial Belt, the South Tropical Zone, the South Temperate Zone, and the Great Red Spot. Aerosol is found above the visible cloud tops in all locations. It is very tenuous and varies with altitude, increasing rapidly with downward passage through the tropopause. The aerosol extinction coefficient at 1.05 μm is 1.0 ± 0.05 × 10^?8 cm^?1 at the tropopause and the mass density is a few times 10^?13 g cm^?3. The observations require some aerosol above the tropopause but do not clearly determine its structure. The present analysis emphasizes an extended haze distribution, but the alternate possibility that the stratospheric aerosol resides in a thin layer is not excluded. The vertical aerosol optical depth above the tropopause at 1.05 μm exceeds 0.04 in the NPR, SPR, NTB, SEB, and StrZ, is ～0.006 ± 0.003 in the STZ, and is ～ 0.003 ± 0.001 above the GRS. The aerosol extinction increases with decreasing wavelength in the STZ and NTB and indicates a particle radius of 0.2–0.5 μm; a radius of ～0.9 μm is indicated in the STrZ.     

Io's sodium emission cloud

Strong evidence that Io's sodium emission is due to resonant scattering is given by our observations which show a monotonic increase of emission intensity with residual solar intensity. In addition we detected no emission during three eclipse observations of Io. We propose a resonant scattering model with two spacial components comprising an optically thick atmosphere extending 10³ km above Io's surface surrounded by an optically thin cloud which forms a partial torus around Jupiter. In this model a flux of 10⁷ cm^?2 sec^?1 sodium atoms are sputtered from Io's surface by heavy energetic ions which are accelerated in a plasma sheath around Io. The atoms sputtered from the surface collide with atoms in Io's atmosphere so the equipartition of kinetic energy is established. The total sodium abundance is about 3 × 10¹³ cm^?2. During Io's day, sodium and other atmospheric constituents are ionized, giving rise to the ionosphere observed by Pioneer 10. Atoms escape by means of Jeans escape from the critical level, which is at the top of the atmosphere and the base of the cloud. We have observed sodium emission 6arcsec (6 Io diameters) above and below Io's orbital plane and 23arcsec toward Jupiter in Io's orbital plane. No emission was detected at maximum elongation 180° from Io. We interpret these results to mean that atoms escaping from Io form a partial torus whose thickness is about 12 arcsec and whose length is at least one-fifth of Io's orbital circumference.     

The effect of ammonia ice on the outgoing thermal radiance from the atmosphere of Jupiter

We examine the effects of NH₃ ice particle clouds in the atmosphere of Jupiter on outgoing thermal radiances. The cloud models are characterized by a number density at the cloud base, by the ratio of the scale height of the vertical distribution of particles (H_p) to the gas scale height (H_g), and by an effective particle radius. NH₃ ice particle-scattering properties are scaled from laboratory measurements. The number density for the various particle radius and scale height models is inferred from the observed disk average radiance at 246 cm^?1, and preliminary lower limits on particle sizes are inferred from the lack of apparent NH₃ absorption features in the observed spectral radiances as well as the observed minimum flux near 2100 cm^?1. We find lower limits on the particle size of 3 μm if H_p/H_g = 0.15, or 10μmif H_p/H_g = 0.50 or 0.05. NH₃ ice particles are relatively dark near the far-infrared and 8.5-μm atmospheric windows, and the outgoing thermal radiances are not very sensitive to various assumptions about the particle-scattering function as opposed to radiances at 5 μm, where particles are relatively brighter. We examined observations in these three different spectral window regions which provide, in principle, complementary constraints on cloud parameters. Characterization of the cloud scale height is difficult, but a promising approach is the examination of radiances and their center-to-limb variation in spectral regions where there is significant opacity provided by gases of known vertical distribution. A blackbody cloud top model can reduce systematic errors due to clouds in temperature sounding to the level of 1K or less. The NH₃ clouds provide a substantial influence on the internal infrared flux field near the 600-mbar level.     

A seasonal model of the Saturnian upper troposphere: Comparison with Voyager infrared measurements

An extension of the seasonal climate model of R. D. Cess and J. Caldwell (1979, Icarus, 38, 349–357) to Saturn's upper troposphere is presented. The ring-modulated latitudinal dependence of the insolation, the ring thermal emission, the oblateness of the planet, the orbit eccentricity, and the latitudinal variation of the internal heat flux are taken into account. Calculations agree closely with the temperature—latitude profiles retrieved from Voyager IRIS measurements at atmospheric levels located above the 0.2-bar pressure level; they reproduce the observed large-scale hemispheric asymmetry which is then shown to result from the seasonally variable insolation. Aerosol absorption is found to be the dominant source of atmospheric solar heating in the troposphere and the model suggests an aerosol mean unit optical depth around the 0.25-bar level in the equatorial region and around the 0.35-bar level at other latitudes. The model fails to predict the retrieved temperature—latitude profiles below the 0.3-bar level. This discrepancy is attributed to the existence of clouds at these levels which are responsible for an additional far-infrared opacity not taken into account in the temperature retrieval. The cloud-top altitude would be about 0.3 bar except in the 20 to 40°N region where these clouds would be confined below the 0.6-bar level. The poor correlation between infrared measurements and visible images is discussed and a possible model of Saturn's cloud structure is proposed.     

The Jovian atmospheric window at 2.7 μm: A search for H2S

The atmospheric transmission window at 2.7 μm in Jupiter's atmosphere was observed at a spectral resolution of 0.1 cm^?1 from the Kuiper Airborne Observatory. From analysis of the CH₄ abundance (～80m-am) and the H₂O abundance (<0.0125cm-am) it was determined that the penetration depth of solar flux at 2.7 μm is near the base of the NH₃ cloud layer. The upper limit to H₂O at 2.7 μm and other recent results suggest that photolytic reactions in Jupiter's lower troposphere may not be as significant as was previously thought. The search for H₂S in Jupiter's atmosphere yielded an upper limit of ～0.1cm-am. The corresponding limit to the elemental abundance ratio [S]/[H] was ～1.7 × 10^?8, about 10^?3 times the solar value. Upon modeling the abundance and distribution of H₂S in Jupiter's atmosphere it was concluded that, contrary to expectations, sulfur-bearing chromophores are not present in significant amounts in Jupiter's visible clouds. Rather, it appears that most of Jupiter's sulfur is locked up as NH₄SH in a lower cloud layer. Alternatively, the global abundance of sulfur in Jupiter may be significantly depleted.     

Radial growth of an extended spoke in Saturn's B ring

The pattern of radial growth of an extended spoke recorded in the Voyager 2 low-resolution ring movie has been examined. This feature is atypical in that it orbits Saturn at the corotational rate for 1½hr after the onset of its formation and then undergoes a 40-min acceleration to sustained Keplerian velocities. The spoke exhibits two modes of radial growth. The first is a diffusion of material radially inward (at a rate of 101 ± 4m sec^?1) and outward (at a rate of 40 ± 5m sec^?1) that occurs throughout the feature's life. The second mode is a short-lived, rapid outward propagation of material (at a rate of 730 ± 70m sec^?1) that occurs for approximately the first 50 min of the spoke's Keplerian dynamical phase. This rapid propagation, presumably driven by Lorentz forces acting on the negatively charged spoke particulates, allows charge-to-mass ratios for these particulates to be calculated at the onset of the propagation (?60 ± 1C kg^?1), the termination of the propagation (?22 ± 2C kg^?1), and the final dissipation of the spoke (?1.5 ± 0.2C kg^?1). The value at the termination of the rapid propagation can be taken as an upper limit on the particulate charge-to-mass ratios of spokes which exhibit Keplerian velocities throughout their lifetimes. A correlation between the dynamical phases and the radial growth modes of the atypical spoke is observed, one that seems consistent with the plasma cloud model of spoke formation and evolution proposed by C. K. Goertz and G. Morfill (1983, Icarus53, 219–229), taken in the limit of high charge density.