Petrography and stable isotope aspects of cold-vent activity imprinted on Miocene-age “calcari aLucina” from Tuscan and Romagna Apennines,Italy

Over 20 occurrences of discontinuous limestone blocks, locally called calcari aLucina, were mapped in the Tuscan—Romagna region of the northern Italian Apennines. The limestones, consisting of a variable mixture of authigenic carbonates (calcite, dolomite, and aragonite), sulfides (primarily pyrite), and allogenic silicates, occur in association with turbidite and hemipelagite units that were deposited in foredeep basins during early to late Miocene times. The limestone blocks are interpreted to represent relicts of carbonate buildups formed around methane-rich fluid vents on the basis of their (1) striking petrographic similarities to carbonates from cold vents in the modern oceans; (2) unique chemosynthetic-like fauna, and (3) anomalously negative ¹³C values ( ¹³C = – 16 to – 58 PDB). The contemporaneous tectonism of the Apennine orogeny is likely to be the primary cause for the expulsion of the methane-rich fluids to the seabed in a manner analogous to the fluid-flow processes occurring at modern accretionary prisms.     

The “calcari aLucina” macrofauna reconsidered: Deep-sea faunal oases from Miocene-age cold vents in the Romagna Apennine,Italy

Recent suggestions that the Miocene-age calcari aLucina blocks scattered in the Apennine chain of the Italian peninsula are methanogenic in nature (paleo cold vents) calls for a reexamination of their macrofauna. Two Tortonian-age outcrops of such limestones (Case Rovereti and Montepetra) have been analyzed for their mollusk content and shown to host a diverse vent fauna. The paleoassemblages show remarkable similarities with modern counterparts associated with hydrocarbon venting on the Gulf of Mexico continental slope. Faunal data from both sites lend support to the hypothesis that methane/hydrocarbon venting was active during the Miocene and sustained specialized bathyal chemosynthetic communities in the ancient Mediterranean.     

A stratigraphic and tectonofacies framework of the “calcari aLucina” in the Apennine Chain,Italy

The Apennine Chain provides the first example of stratigraphic (time) and synsedimentary tectonic (space) distribution of the calcari aLucina Miocene equivalents of modern cold-vent carbonates. Chemosynthetic faunal assemblages and related carbonate deposits are found at different stratigraphic levels, with peaks during Langhian-Serravallian and late Tortonian-early Messinian times. A general increase in frequency and volume occurs with time. A genetic link between venting and the Messinian Evaporite event is difficult to demonstrate. However,Lucina limestones are limited to preevaporitic times, and their maximum abundance is reached just before the onset of the Messinian Evaporite accumulation.Lucina limestones occur in almost all tectofacies of the orogen, from backland to foreland.     

Trends in oxygen content 1911–1984 and occurrence of benthic mortality in the northern Adriatic Sea

Trends of dissolved oxygen content of the surface and bottom layers of the northern Adriatic Sea are analysed for the period 1911–1984. An increase in the surface layer and a decrease in the bottom layer are observed in all seasons except winter. Although the oxygen content of the water column as a whole has not changed significantly, it is inferred, from the increasing difference between the surface and the bottom layer, that the primary productivity of the northern Adriatic Sea is increasing. As the average midsummer oxygen content of the bottom layer decreases, the frequency of mass mortality in the benthic fauna is expected to increase, especially in the northern and western subareas.     

The pilot project “Patterns and processes of the ecosystems of the northern Mid-Atlantic”: aims,strategy and status

The Mid-Atlantic Ridge is the target of an emerging international ecosystem study under the Census of marine life programme. This pilot project shall gather new knowledge on biodiversity, distribution patterns, and ecological processes, and the overriding aim is “to describe and understand the patterns of distribution, abundance and trophic relationships of the organisms inhabiting the mid-oceanic North Atlantic, and identify and model ecological processes that cause variability in these patterns”. The project will focus on pelagic, benthopelagic and epibenthic macrofauna, and analyse distribution and abundance patterns in relation to the abiotic and biotic environment, as well as trophic relationships and life history strategies. Fish, crustaceans, cephalopods and gelatinous plankton and nekton have the highest priority in the study. A major challenge of the project is to overcome observation difficulties at large depths and in rugged terrain. A central aim is thus to utilise modern remote sensing technology (acoustics, optics) using advanced instrument carriers (e.g. towed vehicles, ROVs, AUVs, etc.). The project will be carried out as a multi-ship operation in 2003–2005, and the ongoing planning is a collaborative effort involving many nations around the North Atlantic. The project will work on the Mid-Atlantic Ridge and in adjacent waters from the Azores to Iceland, both by surveying large areas by acoustics and mid-water trawling, and by focusing on three selected sub-areas for intensive sampling and observation by traditional and novel methods and technology. Overlapping with the field seasons, the period 2004–2008 will be an analytical phase, also including submission of data to OBIS.     

Multi-proxy reconstructions of hydrological changes from continental shelf sediments in the northern South China Sea during the interval 9200–6200 cal a BP

Past hydroclimatic conditions in southern China are poorly constrained owing to the lack of high-resolution marine-sediment records. In this study, we present high-resolution geochemical and grain-size records of marine sediments from the coastal shelf of the northern South China Sea to investigate regional hydrological variations.Results suggest a warm and humid climate during the interval 9 200–7 600 cal a BP, followed by a cold and dry climate from 7 600 cal a BP to 6 500 cal a BP, and progre...     

Bathymetric distribution of chaetognaths and their association with water masses off the coast of Valparaı́so,Chile

The bathymetric distribution of chaetognaths was studied at an oceanic station located 14 nautical miles off Valparaı́so. During an annual cycle between July 1994 and September 1995, vertical samples of plankton were taken between 0 and 900 m depth. Temperature, salinity and dissolved oxygen showed temporal and spatial fluctuations within the surface layer (0–100 m), mainly affected by Subantarctic Water and in certain periods by Subtropical Water. Between 150 and 400 m low dissolved oxygen content and higher salinity were found, characteristic of Equatorial Subsurface Waters, and between 400 and 800 m Antarctic Intermediate Water, characterized by its higher content of dissolved oxygen and lower temperature and salinity was present. Fifteen species of chaetognaths were identified: Sagitta bierii, S. enflata, S. minima, S. pacifica, S. lyra, S. planctonis, S. marri, S. macrocephala, S. maxima, S. decipiens, S. tasmanica, S. gazellae, Krohnitta subtilis, Eukrohnia hamata and E. fowleri. The most abundant and frequent species were Sagitta enflata, S. bierii and Eukrohnia hamata. The greatest density of chaetognaths was confined to the 0–200 m water column and the species diversity gradually decreased from the epiplanktonic to the mesoplanktonic domain. The vertical distribution of the chaetognaths showed a strong association with the water masses present. The epipelagic species (0–200 m) S. enflata, S. bierii, S. minima and Krohnitta subtilis are associated mainly with Subantarctic Water and occasionally with Subtropical Water; the mesopelagic species (200–1000 m) S. lyra, S. planctonis, S. macrocephala, S. marri and E. fowleri are associated with Equatorial Subsurface Water and Antarctic Intermediate Water. There is another species assemblage of broad bathymetric distribution (0–900 m) consisting of E. hamata, S. decipiens and S. maxima, which does not show a distinctive association with a given water mass. E. hamata is an indicator species of upwelling events off the Chilean coast, showing an association with waters of low temperatures, greater salinity, and low contents of dissolved oxygen, which are characteristic of Equatorial Subsurface Water.     

Aerobic ammonium oxidation in the oxycline and oxygen minimum zone of the eastern tropical South Pacific off northern Chile (∼20°S)

Aerobic NH₄⁺ oxidation rates were measured along the strong oxygen gradient associated with the oxygen minimum zone (OMZ) of the eastern tropical South Pacific off northern Chile (∼20°S) during 2000, 2003, and 2004. This process was examined by comparing NH₄⁺ rates of change during dark incubations, with and without the addition of allylthiourea, a classical inhibitor of the ammonia monooxygenase enzyme of ammonium-oxidizing bacteria. The contribution of aerobic NH₄⁺ oxidation in dark carbon fixation and NO₂⁻ rates of change were also explored. Thirteen samples were retrieved from the oxycline (252 to ⩽5 μM O₂; 15 to ∼65 m depth) and three from the oxygen minimum core (⩽5 μM O₂; 100–200 m depth). Aerobic NH₄⁺ oxidation rates were mainly detected in the upper part (15–30 m depth) of the oxycline, with rates ranging from 0.16 to 0.79 μM d⁻¹, but not towards the oxycline base (40–65 m depth). In the oxygen minimum core, aerobic NH₄⁺ oxidation was in the upper range and higher than in the upper part of the oxycline (0.70 and 1.0 μM d⁻¹). Carbon fixation rates through aerobic NH₄⁺ oxidation ranged from 0.18 to 0.43 μg C L⁻¹ d⁻¹ and contributed between 33% and 57% of the total dark carbon fixation, mainly towards the oxycline base and, in a single experiment, in the upper part of the oxycline. NO₂⁻ consumption was high (up to 10 μM d⁻¹) towards the oxycline base and OMZ core, but was significantly reduced in experiments amended with allylthiourea, indicating that aerobic NH₄⁺ oxidation could contribute between 8% and 76% of NO₂⁻ production, which in turn could be available for denitrifiers. Overall, these results support the important role of aerobic NH₄⁺ oxidizers in the nitrogen and carbon cycling in the OMZ and at its upper boundary.     

Live (stained) benthic foraminifera from the Rhône prodelta (Gulf of Lion,NW Mediterranean): Environmental controls on a river-dominated shelf

In this paper, we investigate the ecology of live (rose Bengal stained) benthic foraminifera collected at 20 stations ranging from 15 to 100 m depth in the Rhône prodelta (Gulf of Lions, NW Mediterranean). These sites were sampled in September 2006, five months after the Rhône River annual flood. Statistical analyses based on foraminiferal communities (> 150 μm) divide our study area into six main biofacies directly related to environmental conditions. Miliolid species are abundant in the relict prodeltaic lobe which is characterised by sand with low organic matter content. Close to the river mouth, the limited oxygen penetration in the sediment combined with important hydro-sedimentary processes constitute stressful conditions for foraminiferal faunas dominated by opportunistic species (e.g. Leptohalysis scottii). With increasing distance from the river mouth, foraminiferal faunas (e.g. Nonionella turgida, Eggerella scabra) adapted to thrive in sediments enriched in Rhône-derived organic matter under more stable hydro-sedimentary conditions appear. In the distal part of the Rhône River influence, benthic species (e.g. Valvulineria bradyana, Textularia agglutinans) living in fine sediment enriched in both continental and marine organic compounds emerge. At the deepest stations located in the south-eastern part of our study area, benthic foraminiferal faunas (e.g. Bulimina aculeata, Melonis barleeanus, Bigenerina nodosaria) are highly diverse, underlining stable environmental conditions characterised by marine-derived organic matter supplies and relatively deep oxygen penetration depth in the sediment. We also compare foraminiferal faunas sampled in September 2006 with communities sampled in June 2005, one month after the Rhône River annual flood (Mojtahid et al., 2009). This comparison suggests that opportunistic species (e.g. B. aculeata, Cassidulina carinata, V. bradyana) have responded to organic matter inputs related to marine primary production in June 2005.     

Radon and radium isotopes as tracers of submarine groundwater discharge – Results from the Ubatuba,Brazil SGD assessment intercomparison

We determined groundwater flow rates shortly after the wet season into an embayment near Ubatuba, Brazil as part of an international intercomparison experiment for submarine groundwater discharge (SGD) assessment techniques. Our estimated rates were determined by the combined use of continuous radon measurements and assessment of radium isotope patterns. The spatial distribution of the short-lived radium isotopes (²²³Ra and ²²⁴Ra) provided the means for independent evaluations of radon losses by mixing and atmospheric evasion. We were thus able to construct a well-constrained mass balance for radon that included a groundwater flux term. Our results showed that the groundwater discharge into this embayment from the fractured crystalline rock aquifer is not steady-state but varies with tidal modulation and rain-induced forcing. Tidally modulated and rain-induced flow rates were comparable during this period. The SGD rates estimated from radon ranged from 1 cm/day to 29 cm/day (cm³/cm² day) with a mean and standard deviation of 13 ± 6 cm/day. These estimates were mostly similar to a dye-dilution automatic seepage meter (15 ± 19 cm/day) and were within the broad ranges estimated by manual and continuous heat seepage meters but lower than indicated by an artificial tracer test performed nearshore.     

Does compaction-induced subsidence control accommodation space at the top of prograding carbonate platforms? Constraints from the numerical modelling of the Triassic Esino Limestone (Southern Alps,Italy)

The demise of the high-relief, steep-slope, prograding Ladinian-Early Carnian carbonate platforms of the Esino Limestone (Central Southern Alps of Italy) is marked by subaerial exposure of the platform top associated with different erosional (mainly karst-related), depositional and diagenetic processes (Calcare Rosso). The exposure-related deposits consist of three major facies associations: 1) residual soils with thin lenses of conglomerates with black pebbles, and, locally, weathered vulcanites; 2) chaotic breccia lenses irregularly distributed in the uppermost part of the Esino Limestone carbonate platform, interpreted as collapse breccias in karstic setting: 3) inter-supratidal carbonate cycles with dissolution and development of paleosols and tepee structures.Facies distribution follows the sub-environments of the underlying Esino Limestone. Facies 1 and 2 typically characterize the core of the platform, covering the underlying inner platform facies. Facies 3 instead develops toward the edge of the platform, above reef-upper slope facies of the prograding facies of the Esino Limestone. The thickness of facies 3 decreases toward the core of the platform. Facies distribution reflects differences in the accommodation space and sedimentary processes from the rim (highest accommodation, favouring the deposition of peritidal-supratidal carbonates) to the core (reduced accommodation, causing pedogenesis and karstification) of the carbonate system.The observed thickness changes may be controlled by different factors: 1) syndepositional tectonics, 2) subsidence induced by magmatic activity or 3) differential subsidence controlled by the stratigraphic architecture of the Esino Limestone platform and adjoining basins. As evidence of tectonics was not observed and the presence of volcanic bodies is only documented tens of km away from the study area, the scenario involving the creation of accommodation space by compaction of the basinal sediments (resedimented, fine-grained calciturbidites) during the progradation of the carbonate platform is here investigated. Numerical modelling was performed to verify the compatibility of compaction-induced subsidence with the observed depositional architecture. The models were built to simulate the architectural evolution of the platform by progressively adding layers from deepest to shallowest, while compacting the underlying sediments, in order to evaluate compaction-induced subsidence (and accommodation space for the Calcare Rosso) after the deposition of the youngest platform strata. Modelling results allow us to conclude that the wedge geometry of the Calcare Rosso, deposited on top of the extinct Esino carbonate platform, can be explained by subsidence controlled by compaction of the basinal sediments present below the early-cemented, fast prograding platform slope deposits.     

Fouling in offshore areas southeast of the Zhujiang (Pearl) River Delta, the northern South China Sea

Abstract-In order to understand the type and extent of marine fouling in offshore areas southeast ofthe Zhujiang (Pearl) River delta, within the period form May 1986 to June 1987, two biologicalbuoys were deployed at water depths of 95 m and 113 m located in 114 km and 160 km off the coast ofHong Kong, respectively. Moreover, the fouling community of a Marex hydrological buoy located in115 m depth water 172 km off Hong Kong was also surveyed. The results show that a total of 78species were collected and identified. The panels exposed for 3 months were mainly dominated bystalked barnacles Conchoderma hunteri and Lepas anatifera and hydroids Orthopyxis sp. As for thebuoys, including the subsurface buoy, and their mooring systems exposed for 6 and 12 months, respec-tively, some hard foulers such as common oysters, pearl oysters, acorn barnacles and bryozoans werealso found. The compositions of fouling communities also varied greatly with depth.     

Palynology and petroleum potential of the Kazhdumi Formation (Cretaceous: Albian–Cenomanian) in the South Pars field,northern Persian Gulf

The Kazhdumi Formation of the Bangestan Group is a well-known source rock that has produced abundant oil in most petroleum fields in the Zagros Basin, which stretches from northwest to southwest Iran over hundreds of kilometres. The formation reaches a thickness of 230 m at the type section in northwest Zagros but thins out to 40–50 m in wells studied from the South Pars giant petroleum field, where it comprises mainly grey shales with occasional intercalations of marls and sandstones. South Pars, best known as the Iranian part of the world's largest non-associated gas field, contains small quantities of oil above and below the Kazhdumi Formation.     

Standing crop and primary production of benthic microalgae on tidal flats in the Sanggou and Jiaozhou Bays, China

The standing crop and primary production of benthic microalgae on tidal flats have seasonally been observed in the Sanggou and Jiaozhou Bays of the northern China coast during 1999 - 2000. The results show that the annual primary productions of benthic microalgae on tidal flats in the two bays are 2 532 and 7 542 tons carbon, which would be able to support 3.1 x 103 and 9.2 x 103 tons shellfish meat, respectively. The nature of sediment is essential for governing the biomass and primary production of benthic microalgae on tidal flats. The biomass and primary production of benthic microalgae on tidal flats with muddy sediments are higher than those with sandy sediments, which resulted from higher nutrient concentration and lower grazing pressure. That is the reason why in comparison with Xiangshan Bay the standing crop and production of benthic microalgae on tidal flats of the Sanggou and Jiaozhou Bays are low. Light was a key factor controlling vertical distribution of biomass and production of benthic     

Formation of Isotope Parameters (δD, δ18O,and d) of Glaciers and Water Runoff from Severny Island of the Novaya Zemlya Archipelago

Oceanology - Isotope studies (δD and δ18O) were performed for the glaciers of Severny Island (Novaya Zemlya Archipelago). The studied glaciers were characterized by narrow range-of...     

Physicochemical modeling of the behavior of microelements (As,V, Cr,Co, and Hg) under the mixing of riverine and marine waters (the Razdol’naya River-Amur Bay System)

By means of physicochemical modeling with the Selector software package, a model for the mixing of riverine water (pH = 7.02) and seawater was compiled and calculated. The Razdol’naya River-Amur Bay (Sea of Japan) system was assessed as an example. By means of the MINTEQA2/PRODEFA2 software package, the role of the sorption processes in riverine and marine waters, as well as in the zone of their mixing, was ascertained. The physicochemical migration forms of microelements (arsenic, vanadium, chromium, cobalt, and mercury) in the waters of the geochemical system considered and their behavior in passing through the geochemical barrier were established.     

Fluid expulsion from overpressured basins: Implications for Pb–Zn mineralisation and dolomitisation of the East Midlands platform,northern England

Our understanding of burial diagenesis within carbonates is often limited by poor constraints on available fluid volumes and geochemistry. However, regional stratigraphic and burial history data are often readily available. Using these data to develop numerical models which couple sedimentological and hydrological basin evolution, we estimate the volumes and geochemistry of fluids that were available to drive dolomitisation and Pb-ore genesis within the Carboniferous, Derbyshire Platform of northern England. Current conceptual models of these processes invoke tectonic release of burial-induced overpressure developed within adjacent Dinantian basins as a drive for reactive fluid flow to the platform. Our simulations show that compaction-driven flow may lead to a supply of fluids that is more complex in its temporal evolution than may be expected. Spatial variations in the rate of fluid expulsion from different sediments lead to a staggered delivery of fluids from different sources. Rapid fluid expulsion within deeper sediments leads to a downwards-decreasing pressure gradient that subsequently draws down fluid from within overlying sediments. Thus, early fluid supply to the platform is sourced from the deep basins while later fluid supply descends from above the platform as well as from the sides. We suggest that such a flow development may have important implications for the relative timing and distribution of a sequence of diagenetic products within the platform. This hypothesis is tested using volume estimates from our simulations. We conclude that although this staggered fluid supply model may be applicable generically, it appears that it is only valid for explaining mineralisation in the Derbyshire Platform. Fluid volumes supplied to the platform are insufficient to explain dolomitisation. Our simulations are supported by a sensitivity analysis that identifies that compaction-driven flow in this system is strongly controlled by the rate of burial and sediment permeabilities within the compacting basins.     

Basic characteristics and forming mechanism of the sharp thermocline in the Bohai Sea, Huanghai Sea and northern East China Sea

- On the basis of the fact that the sharp thermocHne in the Bohai Sea and the northern Huanghai Sea is often distributed in the deep valley areas, it has been long thought that the reason of the formation of the sharp thermocHne is that the cold water can be easily kept in valleys. But recent investigations carried out in the southern Huanghai Sea in summer show that all of the sharp thermocHne areas were distributed in the shallow sloping-bottom areas but not in the deep valley areas. Only in autumn would the sharp thermoclines translate to the deep valley areas. In summer, they are characterized by shallow upper mixing layer and thin thickness in the southern Huanghai Sea. In addition to entrainment coming from lower boundary of upper mixing layer the entrainment from upper border of bottom homogeneous layer induced by tidal mixing also plays an important role in the growth and decay of thermoclines in these seas.     

Impact of circulation on high phytoplankton blooms and fish catch in the northern Adriatic (1990–2004)

We analyzed oceanographic, hydrologic and atmospheric conditions in the northern Adriatic (section between the Po River delta and Rovinj) from 1990 to 2004 in which extreme phytoplankton blooms appeared. The largest blooms occurred in February, March, July and October, and were higher in surface layers and in the western, more eutrophic part of the region. They often appeared when the Istrian Coastal Countercurrent (ICCC; strong southward current indicating a “closure” of the northern Adriatic circulation system) was pronounced. They seem to be related to the intensities of surface fluxes and Po River discharge rates. The blooms can float over the northern Adriatic for a long period (up to 30 days; typical for March) and can appear simultaneously in separate circulation systems with a different species distribution. Finally, we present a hypothesis based on comparisons of geostrophic currents and fish stock that specific February northern Adriatic oceanographic conditions play the key role in the Adriatic anchovy stock.     

“Us” and “them”. Fishermen from Gandía and the loss of institutional legitimacy

This paper analyses, using a qualitative methodology, some of the possible causes of the recognised failure of fisheries policy concerning traditional fisheries. Through a case study in a Spanish Mediterranean port (Gandia), it concludes that the basic problem is the lack of legitimacy of political institutions for fishermen. Any attempt to implement an effective fisheries management must recover this legitimacy, by harnessing existing social capital of these communities through the adoption of new models of fisheries co-management and the revaluation of local knowledge.